专利摘要:
A composition for drill bit bodies and a method for making drill bits from the composition are disclosed. The composition includes powdered tungsten carbide, and binder metal consisting of a composition by weight of manganese in a range of about zero to 25 percent, nickel in a range of about zero to 15 percent, zinc in a range of about 3 to 20 percent, tin in a range of more than 1 percent to about 10 percent, and copper making up the remainder by weight of the composition. In one embodiment, the composition includes about 6 to 7 percent tin therein. The composition is heated to at least the infiltration temperature in a mold for form a drill bit body.
公开号:US20010002557A1
申请号:US09/758,896
申请日:2001-01-11
公开日:2001-06-07
发明作者:Kuttaripalayam Kembaiyan;Thomas Oldham
申请人:Kembaiyan Kuttaripalayam T.;Oldham Thomas W.;
IPC主号:C22C29-067
专利说明:
[0001] This is a division of Ser. No. 09/372,896, filed on Aug. 12, 1999. [0001] BACKGROUND OF THE INVENTION
[0002] 1. Field of the Invention [0002]
[0003] The invention relates generally to the field of metal alloys used for various types of housings. More specifically, the invention relates to compositions of binder material used to bind metallic powders into solid housings or bodies for such purposes as petroleum wellbore drilling bits. [0003]
[0004] 2. Description of the Related Art [0004]
[0005] Petroleum wellbore drilling bits include various types that contain natural or synthetic diamonds, polycrystalline diamond compact (PDC) inserts, or combinations of these elements to drill through earth formations. The diamonds and/or PDC inserts are bonded to a bit housing or “body”. The bit body is typically formed from powdered tungsten carbide (“matrix”) which is bonded into a solid form by fusing a binder alloy with the tungsten carbide. The binder alloy is typically in the form of cubes, but it can also be in powdered form. To form the body, the powdered tungsten carbide is placed in a mold of suitable shape. The binder alloy, if provided in cube form is typically placed on top of the tungsten carbide. The binder alloy and tungsten carbide are then heated in a furnace to a flow or infiltration temperature of the binder alloy so that the binder alloy can bond to the grains of tungsten carbide. Infiltration occurs when the molten binder alloy flows through the spaces between the tungsten carbide grains by means of capillary action. When cooled, the tungsten carbide matrix and the binder alloy form a hard, durable, strong framework to which diamonds and/or PDC inserts are bonded or otherwise attached. Lack of complete infiltration will result in a defective bit body. Typically, natural or synthetic diamonds are inserted into the mold prior to heating the matrix/binder mixture, while PDC inserts can be brazed to the finished bit body. [0005]
[0006] The chemical compositions of the matrix and binder alloy are selected to optimize a number of different properties of the finished bit body. These properties include transverse rupture strength (TRS), toughness (resistance to impact-type fracture), wear resistance (including resistance to erosion from rapidly flowing drilling fluid and abrasion from rock formations), steel bond strength between the matrix and steel reinforcing elements, and strength of the bond (braze strength) between the finished body material and the diamonds and/or inserts. [0006]
[0007] One particular property of the binder alloy which is of substantial importance is its flow or infiltration temperature, that is, the temperature at which molten binder alloy will flow around all the matrix grains and attach to the matrix grains. The flow temperature is particularly important to the manufacture of diamond bits, in which case the diamonds are inserted into the mold prior to heating. The chemical stability of the diamonds is inversely related to the product of the duration of heating of the diamonds and the temperature to which the diamonds are heated as the bit body is formed. Generally speaking, all other properties of the bit body being equal, it is desirable to heat the mixture to the lowest possible temperature for the shortest possible time to minimize thermal degradation of the diamonds. While binder alloys which have low flow temperature are known in the art, these binder alloys typically do not provide the finished bit body with acceptable properties. [0007]
[0008] Many different binder alloys are known in the art. The mixtures most commonly used for commercial purposes, including diamond drill bit making, are described in a publication entitled, [0008] Matrix Powders for Diamond Tools, Kennametal Inc., Latrobe, Pa. (1989). A more commonly used binder alloy has a composition by weight of about 52 percent copper, 15 percent nickel, 23 percent manganese, and 9 percent zinc. This alloy has a melting temperature of about 1800 degrees F (968 degrees C) and a flow (infiltration) temperature of about 2150 degrees F (1162 degrees C). Other prior art alloys use combinations of copper, nickel and zinc, or copper, nickel and up to about 1 percent tin by weight.
[0009] Tin is known in the art to reduce the melting and flowing temperature of the binder alloy. However, it was believed by those skilled in the art that tin concentrations exceeding about 1 percent by weight in the binder alloy would adversely affect the other properties of the finished bit body material, particularly the toughness, although transverse rupture strength and braze strength can also be adversely affected. [0009]
[0010] It is desirable to have a binder alloy having as low as possible a flowing temperature consistent with maintaining the toughness, transverse rupture strength and braze strength of the finished body material. [0010] SUMMARY OF THE INVENTION
[0011] One aspect of the invention is a matrix material used, for example, in drill bit bodies. The matrix material includes powdered tungsten carbide, and binder alloy consisting of a composition by weight of manganese in a range of about zero to 25 percent, nickel in a range of about zero to 15 percent, zinc in a range of about 3 to 20 percent, tin in a range of more than 1 percent to about 10 percent, and copper making up the remainder by weight of the alloy composition. In one embodiment, the alloy includes about 6 to 7 percent tin by weight. [0011]
[0012] Another aspect of the invention is a method for forming drill bit bodies. The method includes inserting into a mold a mixture including powdered tungsten carbide and a binder alloy consisting of a composition, by weight, of manganese in a range of about zero to 25 percent, nickel in a range of about zero to 15 percent, zinc in a range of about 3 to 20 percent, tin in a range of more than 1 percent to about 10 percent, and copper making up the remainder by weight of the alloy. The matrix material is heated to the flow temperature of the binder alloy to infiltrate through the powdered tungsten carbide. In one embodiment, the binder alloy includes about 6 to 7 percent tin by weight. [0012] BRIEF DESCRIPTION OF THE DRAWINGS
[0013] FIG. 1 shows an end view of a drill bit formed from a body material having binder according to the invention. [0013]
[0014] FIG. 2 shows a side view of the drill bit shown in FIG. 1. [0014] DESCRIPTION OF THE PREFERRED EMBODIMENT
[0015] FIG. 1 shows an end view of a so-called “impregnated diamond” drill bit [0015] 10. The drill bit 10 is formed into a generally cylindrically shaped body 11 which includes circumferentially spaced apart blades 12. The blades 12 include natural or synthetic diamonds (not shown in FIG. 1) embedded in the outer surfaces thereof. As is well known in the art, the drill bit 10 is coupled to a rotary power source such as a drill pipe (not shown) or an hydraulic motor (not shown) to rotate the drill bit 10 as it is axially pressed against earth formations to drill the earth formations. Such diamonds are one classification of so-called “cutters” which deform or scrape the earth formations to drill them. Another well known form of such cutters is polycrystalline diamond compact (PDC) inserts which are typically brazed to the body 11 after it is formed.
[0016] A side view of the drill bit [0016] 10 is shown in FIG. 2. The drill bit 10 can include, at the end of the body 11 opposite to the end shown in FIG. 1, a threaded coupling 16 for attachment to the drill pipe or hydraulic motor, and may include gauge pads 14 or the like to maintain the diameter of the hole drilled by the drill bit 10.
[0017] The invention concerns the composition of the material from which the body [0017] 11 is formed, and more specifically, concerns the composition of a binder alloy used to bond together grains of powdered metal to form the body 11.
[0018] As described in the Background section herein, the body [0018] 11 is typically formed by infiltrating powdered tungsten carbide with a binder alloy. The tungsten carbide and binder alloy are placed in a mold (not shown) of suitable shape, wherein the part of the mold having forms for the blades 12 will have diamonds mixed with the powdered tungsten carbide to form one of the so-called diamond impregnated drill bits. The mold having diamonds, carbide and binder alloy therein is then heated in a furnace to the flow or infiltration temperature of the binder alloy for a predetermined time to enable the molten binder alloy to flow around the grains of the tungsten carbide.
[0019] It has been determined that binder alloy compositions to be described below provide the finished body [0019] 11 with suitable combinations of transverse rupture strength (TRS), toughness, braze strength and wear resistance. A preferred binder alloy composition includes by weight about 57 percent copper, 10 percent nickel, 23 percent manganese, 4 percent zinc and 6 percent tin. This composition for the binder alloy has a melting temperature of about 1635 degrees F (876 degrees C) and a flow or infiltration temperature of about 1850 degrees F (996 degrees C).
[0020] Other compositions of binder alloy according to the invention can have, by weight, nickel in the range of about zero to 15 percent; manganese in the range of about zero to 25 percent; zinc in the range of about 3 to 20 percent, and tin more than 1 percent up to about 10 percent. The remainder of any such composition is copper. The preferred amount of tin in the binder alloy is about 6 to 7 percent. Although nickel and manganese can be excluded from the binder alloy entirely, is should be noted that nickel helps the mixture “wet” the tungsten carbide grains, and increases the strength of the finished bit body. Manganese, when included in the recommended weight fraction range of the binder alloy composition, also helps lower the melting temperature of the binder alloy. While it is known that tin will lower the melting and flowing temperature of the binder alloy, too much tin in the binder alloy will result in the finished body [0020] 11 having too low a toughness, that is, it will be brittle. Including tin in the recommended weight fraction in the binder alloy composition results in a substantial decrease in the infiltration temperature of the binder alloy, as well as improved wettability of the binder alloy, particularly of the diamonds. The other properties of the finished bit body material will be maintained with commercially acceptable limits, however.
[0021] While the example embodiment described herein is directed to an impregnated diamond bit, it should be clearly understood that PDC insert bits can have the bodies thereof formed from a composite material having substantially the same composition as described herein for diamond impregnated bits. It has been determined that the material described herein is entirely suitable for PDC insert bit bodies, and has the advantage of being formed at a lower temperature than materials of the prior art. Lowering the temperature can reduce energy costs of manufacture and can reduce deterioration of insulation on the furnace walls, and the furnace heating elements. Lowering the infiltration temperature also provide the advantage of minimizing the degradation of drill bit components such as reinforcement steel blanks and the matrix powders which can oxidize at higher furnace temperatures, thereby softening and losing strength. [0021]
[0022] Those skilled in the art will appreciate that other embodiments of the invention can be devised which do not depart from the spirit of the invention as disclosed herein. Accordingly, the scope of the invention should be limited only by the attached claims. [0022]
权利要求:
Claims (10)
[1" id="US-20010002557-A1-CLM-00001] 1. A drill bit, comprising:
a composite structural body comprising powdered tungsten carbide and binder alloy, said binder alloy comprising a composition by weight of manganese in a range of about zero to 25 percent, nickel in a range of about zero to 15 percent, zinc in a range of about 3 to 20 percent, tin in a range of more than 1 percent to about 10 percent, and copper making up the remainder by weight of said composition, said binder alloy infiltrated through said tungsten carbide; and
cutters bonded to said composite structural body.
[2" id="US-20010002557-A1-CLM-00002] 2. The drill bit as defined in
claim 1 wherein said tin comprises about 6 to 7 percent of said alloy composition.
[3" id="US-20010002557-A1-CLM-00003] 3. The drill bit as defined in
claim 1 wherein said copper comprises about 57 percent of said alloy composition, said manganese comprises about 23 percent of said alloy composition, said nickel comprises about 10 percent of said alloy composition, said zinc comprises about 4 percent of said alloy composition, and said tin comprises about 6 percent of said alloy composition.
[4" id="US-20010002557-A1-CLM-00004] 4. The drill bit as defined in
claim 1 wherein said cutters comprise polycrystalline diamond compact inserts bonded to said composite structural body.
[5" id="US-20010002557-A1-CLM-00005] 5. The drill bit as defined in
claim 1 wherein said cutters comprise diamonds formed into blades in said composite structural metal body.
[6" id="US-20010002557-A1-CLM-00006] 6. A method for forming a drill bit body, comprising:
inserting into a mold a mixture comprising powdered tungsten carbide and a binder alloy consisting of a composition by weight of manganese in a range of about zero to 25 percent, nickel in a range of about zero to 15 percent, zinc in a range of about 3 to 20 percent, tin in a range of more than 1 percent to about 10 percent, and copper making up the remainder by weight of the alloy composition; and
heating the mixture to at least an infiltration temperature of the binder alloy to bind the alloy to the powdered tungsten carbide.
[7" id="US-20010002557-A1-CLM-00007] 7. The method as defined in
claim 6 wherein said tin comprises about 6 to 7 percent of said binder alloy.
[8" id="US-20010002557-A1-CLM-00008] 8. The method as defined in
claim 6 wherein said copper comprises about 57 percent of said composition, said manganese comprises about 23 percent of said composition, said nickel comprises about 10 percent of said composition, said zinc comprises about 4 percent of said composition, and said tin comprises about 6 percent of said composition.
[9" id="US-20010002557-A1-CLM-00009] 9. The method as defined in
claim 6 further comprising inserting diamonds into said mold prior to said heating, so that an impregnated diamond drill bit is formed thereby.
[10" id="US-20010002557-A1-CLM-00010] 10. The method as defined in
claim 6 further comprising bonding polycrystalline diamond compact inserts to said drill bit body to form a drill bit thereby.
类似技术:
公开号 | 公开日 | 专利标题
US6375706B2|2002-04-23|Composition for binder material particularly for drill bit bodies
US6461401B1|2002-10-08|Composition for binder material particularly for drill bit bodies
US8109177B2|2012-02-07|Bit body formed of multiple matrix materials and method for making the same
US7267187B2|2007-09-11|Braze alloy and method of use for drilling applications
US8360176B2|2013-01-29|Brazing methods for PDC cutters
US6725953B2|2004-04-27|Drill bit having diamond impregnated inserts primary cutting structure
US7128773B2|2006-10-31|Compositions having enhanced wear resistance
US7250069B2|2007-07-31|High-strength, high-toughness matrix bit bodies
US20040244540A1|2004-12-09|Drill bit body with multiple binders
CA2576072C|2010-03-30|High-strength, high-toughness matrix bit bodies
US20050089440A1|2005-04-28|Braze alloy
US20100166592A1|2010-07-01|Infiltration methods for forming drill bits
US20160348443A1|2016-12-01|Infiltrated diamond wear resistant bodies and tools
US7878273B2|2011-02-01|Ultra-hard drilling stabilizer
US20130153306A1|2013-06-20|Fixed cutter drill bit heel and back-ream cutter protections for abrasive applications
US20130140095A1|2013-06-06|Drill bit alloy
US20150240566A1|2015-08-27|Manufacture of low cost bits by infiltration of metal powders
US20190071931A1|2019-03-07|A drill bit, a method for making a body of a drill bit, a metal matrix composite, and a method for making a metal matrix composite
CA2488687A1|2006-05-30|Braze alloy for drilling applications
同族专利:
公开号 | 公开日
US6375706B2|2002-04-23|
引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题
US20110030283A1|2009-08-07|2011-02-10|Smith International, Inc.|Method of forming a thermally stable diamond cutting element|
US20110031037A1|2009-08-07|2011-02-10|Smith International, Inc.|Polycrystalline diamond material with high toughness and high wear resistance|
US20110031032A1|2009-08-07|2011-02-10|Smith International, Inc.|Diamond transition layer construction with improved thickness ratio|
US20110031033A1|2009-08-07|2011-02-10|Smith International, Inc.|Highly wear resistant diamond insert with improved transition structure|
US20110036643A1|2009-08-07|2011-02-17|Belnap J Daniel|Thermally stable polycrystalline diamond constructions|
US20110042147A1|2009-08-07|2011-02-24|Smith International, Inc.|Functionally graded polycrystalline diamond insert|
WO2013062536A1|2011-10-25|2013-05-02|Longyear Tm, Inc.|High-strength, high-hardness binders and drilling tools formed using the same|
WO2017027038A1|2015-08-13|2017-02-16|Halliburton Energy Services, Inc.|Drill bits manufactured with copper nickel manganese alloys|
CN107400816A|2017-08-10|2017-11-28|西迪技术股份有限公司|A kind of Cu-base composites and preparation method thereof|
CN110643880A|2019-11-07|2020-01-03|广东省材料与加工研究所|Drill bit matrix material and preparation method thereof|US3778238A|1972-04-14|1973-12-11|D Tyler|Composite metal article|
US4003715A|1973-12-21|1977-01-18|A. Johnson & Co. Inc.|Copper-manganese-zinc brazing alloy|
US3880678A|1974-03-27|1975-04-29|Olin Corp|Processing copper base alloy|
US3972712A|1974-05-29|1976-08-03|Brush Wellman, Inc.|Copper base alloys|
US3999962A|1975-05-23|1976-12-28|Mark Simonovich Drui|Copper-chromium carbide-metal bond for abrasive tools|
US4389074B1|1980-07-23|1993-09-07|Gte Products Corp.|Mine tools utilizing copper maganese nickel brazing alloy|
US4630692A|1984-07-23|1986-12-23|Cdp, Ltd.|Consolidation of a drilling element from separate metallic components|
GB8508621D0|1985-04-02|1985-05-09|Nl Petroleum Prod|Rotary drill bits|
DE3535659C1|1985-10-04|1987-04-02|Swarovski & Co|Use of a bronze alloy for sintered grinding bodies|
US5000273A|1990-01-05|1991-03-19|Norton Company|Low melting point copper-manganese-zinc alloy for infiltration binder in matrix body rock drill bits|US7044243B2|2003-01-31|2006-05-16|Smith International, Inc.|High-strength/high-toughness alloy steel drill bit blank|
US9428822B2|2004-04-28|2016-08-30|Baker Hughes Incorporated|Earth-boring tools and components thereof including material having hard phase in a metallic binder, and metallic binder compositions for use in forming such tools and components|
US20050211475A1|2004-04-28|2005-09-29|Mirchandani Prakash K|Earth-boring bits|
US20080101977A1|2005-04-28|2008-05-01|Eason Jimmy W|Sintered bodies for earth-boring rotary drill bits and methods of forming the same|
US7513320B2|2004-12-16|2009-04-07|Tdy Industries, Inc.|Cemented carbide inserts for earth-boring bits|
CA2538545C|2005-03-03|2013-01-15|Sidney J. Isnor|Fixed cutter drill bit for abrasive applications|
US8637127B2|2005-06-27|2014-01-28|Kennametal Inc.|Composite article with coolant channels and tool fabrication method|
US7687156B2|2005-08-18|2010-03-30|Tdy Industries, Inc.|Composite cutting inserts and methods of making the same|
US7703555B2|2005-09-09|2010-04-27|Baker Hughes Incorporated|Drilling tools having hardfacing with nickel-based matrix materials and hard particles|
EP2066864A1|2006-08-30|2009-06-10|Baker Hughes Incorporated|Methods for applying wear-resistant material to exterior surfaces of earth-boring tools and resulting structures|
US8002052B2|2005-09-09|2011-08-23|Baker Hughes Incorporated|Particle-matrix composite drill bits with hardfacing|
US7997359B2|2005-09-09|2011-08-16|Baker Hughes Incorporated|Abrasive wear-resistant hardfacing materials, drill bits and drilling tools including abrasive wear-resistant hardfacing materials|
US7597159B2|2005-09-09|2009-10-06|Baker Hughes Incorporated|Drill bits and drilling tools including abrasive wear-resistant materials|
US7776256B2|2005-11-10|2010-08-17|Baker Huges Incorporated|Earth-boring rotary drill bits and methods of manufacturing earth-boring rotary drill bits having particle-matrix composite bit bodies|
US7784567B2|2005-11-10|2010-08-31|Baker Hughes Incorporated|Earth-boring rotary drill bits including bit bodies comprising reinforced titanium or titanium-based alloy matrix materials, and methods for forming such bits|
US7807099B2|2005-11-10|2010-10-05|Baker Hughes Incorporated|Method for forming earth-boring tools comprising silicon carbide composite materials|
US7913779B2|2005-11-10|2011-03-29|Baker Hughes Incorporated|Earth-boring rotary drill bits including bit bodies having boron carbide particles in aluminum or aluminum-based alloy matrix materials, and methods for forming such bits|
US7802495B2|2005-11-10|2010-09-28|Baker Hughes Incorporated|Methods of forming earth-boring rotary drill bits|
RU2432445C2|2006-04-27|2011-10-27|Ти Ди Уай Индастриз, Инк.|Modular drill bit with fixed cutting elements, body of this modular drill bit and methods of their manufacturing|
US7637574B2|2006-08-11|2009-12-29|Hall David R|Pick assembly|
US7669674B2|2006-08-11|2010-03-02|Hall David R|Degradation assembly|
US8714285B2|2006-08-11|2014-05-06|Schlumberger Technology Corporation|Method for drilling with a fixed bladed bit|
US9145742B2|2006-08-11|2015-09-29|Schlumberger Technology Corporation|Pointed working ends on a drill bit|
US9051795B2|2006-08-11|2015-06-09|Schlumberger Technology Corporation|Downhole drill bit|
US8567532B2|2006-08-11|2013-10-29|Schlumberger Technology Corporation|Cutting element attached to downhole fixed bladed bit at a positive rake angle|
US8590644B2|2006-08-11|2013-11-26|Schlumberger Technology Corporation|Downhole drill bit|
US8622155B2|2006-08-11|2014-01-07|Schlumberger Technology Corporation|Pointed diamond working ends on a shear bit|
US8215420B2|2006-08-11|2012-07-10|Schlumberger Technology Corporation|Thermally stable pointed diamond with increased impact resistance|
KR101438852B1|2006-10-25|2014-09-05|티디와이 인더스트리스, 엘엘씨|Articles Having Improved Resistance to Thermal Cracking|
US9068410B2|2006-10-26|2015-06-30|Schlumberger Technology Corporation|Dense diamond body|
US7353893B1|2006-10-26|2008-04-08|Hall David R|Tool with a large volume of a superhard material|
US8960337B2|2006-10-26|2015-02-24|Schlumberger Technology Corporation|High impact resistant tool with an apex width between a first and second transitions|
US7775287B2|2006-12-12|2010-08-17|Baker Hughes Incorporated|Methods of attaching a shank to a body of an earth-boring drilling tool, and tools formed by such methods|
US7841259B2|2006-12-27|2010-11-30|Baker Hughes Incorporated|Methods of forming bit bodies|
US20080202814A1|2007-02-23|2008-08-28|Lyons Nicholas J|Earth-boring tools and cutter assemblies having a cutting element co-sintered with a cone structure, methods of using the same|
US7846551B2|2007-03-16|2010-12-07|Tdy Industries, Inc.|Composite articles|
US8540037B2|2008-04-30|2013-09-24|Schlumberger Technology Corporation|Layered polycrystalline diamond|
US8790439B2|2008-06-02|2014-07-29|Kennametal Inc.|Composite sintered powder metal articles|
UA103620C2|2008-06-02|2013-11-11|ТИ ДИ УАЙ ИНДАСТРИЗ, ЭлЭлСи|Composite sintered powder metal article and method for its production|
US7703556B2|2008-06-04|2010-04-27|Baker Hughes Incorporated|Methods of attaching a shank to a body of an earth-boring tool including a load-bearing joint and tools formed by such methods|
US8770324B2|2008-06-10|2014-07-08|Baker Hughes Incorporated|Earth-boring tools including sinterbonded components and partially formed tools configured to be sinterbonded|
US8261632B2|2008-07-09|2012-09-11|Baker Hughes Incorporated|Methods of forming earth-boring drill bits|
US8322465B2|2008-08-22|2012-12-04|TDY Industries, LLC|Earth-boring bit parts including hybrid cemented carbides and methods of making the same|
US8025112B2|2008-08-22|2011-09-27|Tdy Industries, Inc.|Earth-boring bits and other parts including cemented carbide|
US8701799B2|2009-04-29|2014-04-22|Schlumberger Technology Corporation|Drill bit cutter pocket restitution|
US8272816B2|2009-05-12|2012-09-25|TDY Industries, LLC|Composite cemented carbide rotary cutting tools and rotary cutting tool blanks|
US8201610B2|2009-06-05|2012-06-19|Baker Hughes Incorporated|Methods for manufacturing downhole tools and downhole tool parts|
US9004199B2|2009-06-22|2015-04-14|Smith International, Inc.|Drill bits and methods of manufacturing such drill bits|
US20110000718A1|2009-07-02|2011-01-06|Smith International, Inc.|Integrated cast matrix sleeve api connection bit body and method of using and manufacturing the same|
US8308096B2|2009-07-14|2012-11-13|TDY Industries, LLC|Reinforced roll and method of making same|
US9643236B2|2009-11-11|2017-05-09|Landis Solutions Llc|Thread rolling die and method of making same|
US8950518B2|2009-11-18|2015-02-10|Smith International, Inc.|Matrix tool bodies with erosion resistant and/or wear resistant matrix materials|
WO2011146752A2|2010-05-20|2011-11-24|Baker Hughes Incorporated|Methods of forming at least a portion of earth-boring tools, and articles formed by such methods|
RU2012155100A|2010-05-20|2014-06-27|Бейкер Хьюз Инкорпорейтед|METHOD FOR FORMING A LESS PART OF A DRILLING TOOL AND FORMED PRODUCT THEREOF|
EP2571646A4|2010-05-20|2016-10-05|Baker Hughes Inc|Methods of forming at least a portion of earth-boring tools|
US8800848B2|2011-08-31|2014-08-12|Kennametal Inc.|Methods of forming wear resistant layers on metallic surfaces|
US9016406B2|2011-09-22|2015-04-28|Kennametal Inc.|Cutting inserts for earth-boring bits|
US20140182948A1|2012-12-31|2014-07-03|Smith International, Inc.|Lower melting point binder metals|
法律状态:
2002-04-04| STCF| Information on status: patent grant|Free format text: PATENTED CASE |
2005-10-24| FPAY| Fee payment|Year of fee payment: 4 |
2009-10-23| FPAY| Fee payment|Year of fee payment: 8 |
2013-09-25| FPAY| Fee payment|Year of fee payment: 12 |
优先权:
申请号 | 申请日 | 专利标题
US37289699A| true| 1999-08-12|1999-08-12||
US09/758,896|US6375706B2|1999-08-12|2001-01-11|Composition for binder material particularly for drill bit bodies|US09/758,896| US6375706B2|1999-08-12|2001-01-11|Composition for binder material particularly for drill bit bodies|
[返回顶部]