• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    A process for preparing dimethylcarbonate by reacting methanol with mixtures of carbon monoxide and oxygen which also contain hydrogen. The catalyst is constituted by a salt of a metal of groups IB, IIB or VIII of the periodic system, dissolved or dispersed in the reaction medium. It has been found that the hydrogen does not interfere in the reaction, so that a hydrogen-enriched gaseous mixture (synthesis gas) is withdrawn from the reactor. It is therefore particularly advantageous in that it produces dimethylcarbonate and at the same time provides hydrogen-enriched synthesis gas.
    公开号:SU988186A3
    申请号:SU803261151
    申请日:1980-12-04
    公开日:1983-01-07
    发明作者:Романо Уго；Риветти Франко；Ди Музио Никола
    申请人:Аник С.П.А. (Фирма)；
    IPC主号:
    专利说明:

    t
    The invention relates to a method for producing dimethyl carbonate, which finds various applications in the chemical industry, for example, as a solvent for lacquers, for the synthesis of polymeric urethanes. as plasticizers.
    A known method for producing various carbonic esters by reacting phosgene with an oxo-containing compound or their alkaline or alkaline-earth salts in the presence of basic catalysts based on tertiary amines or their quaternary salts l.
    However, the use of poisonous phosgene limits the possibilities of wide practical application in industry. .
    Also known is a method for producing dimethyl carbonate by reacting methanol, carbon monoxide and oxygen in the presence of a catalyst — a copper chloride complex compound.
    trichloride vanadium or chromium, iron, etc. C2.
    These complexes increase the cost of production of the target product.
    5 The closest technical solution to the proposed method is to obtain dimethyl carbonate by reacting pure carbon monoxide, oxygen, and alcohol-methanol in the presence of a catalyst of copper monochloride at 90-135 ° C and a pressure of 15-50 kgf / cm.
    However, a good yield of 15 the desired product is not considered, its cost is quite high, since the need to use pure carbon monoxide (CO) considerably complicates and increases the cost of dimethylcarbonate production.
    权利要求:
    Claims (3)
    [1]
    The aim of the invention is to simplify the process and a corresponding reduction in the cost of the target product. 39 The goal is achieved by the fact that according to the method of producing dimethyl carbonate by the interaction of methanol, carbon monoxide and oxygen in the presence of copper monochloride, an extract of 90-135 ° C and a range of 15-50. kgf / cm. the latter is carried out in the presence of hydrogen contained in the initial carbon monoxide in an amount of 10-67% by volume. The use of hydrogen-containing carbon monoxide makes it possible to expand the raw material base of this process through various technical products of those industries, c. of which they are formed, for example, methanol synthesis. Along with this, it must be said that it is not a consideration of the possibility of side processes, such as the formation of water from hydrogen and oxygen, as well as the reduction of copper (+1) to metallic and dimethyl-. carbonate to alcohol and its hydrocarbon, in this case, due to certain conditions and the percentage of hydrogen in carbon monoxide, these reactions are not observed, since the yield of the target product on the converted methanol is almost quantitative. PRI me R 1. The autoclave is charged with -P methanol and 80 g of copper monochloride, the temperature of the system is increased up to 120 ° C and a stream of gas, carbon monoxide containing 33 o6.% Hydrogen, is fed at a rate of 140 nl / h while simultaneously supplying oxygen at a speed of 0 nl / h Par The carbon monoxide pressure is 16.75 kg / cm. Total pressure 25 kgf / cm. The system is continuously withdrawn from the TO l / h gas containing 65 vol. hydrogen, carbon monoxide 32 about., 3 about. carbon and impurities. oxygen (0.1-0.2%). The separation of the catalyst after work is carried out by choking the reaction pressure to atmospheric. As a result, the liquid evaporates almost instantaneously and the catalyst remains in a solid form. After condensation of the evaporated product by distillation, dimethyl carbonate is isolated. After i h of operation, the conversion of methanol is 32.5%, the selectivity to dimethyl carbonate is 100%, and the conversion of carbon monoxide is 95%. Example2. 3 liters of methanol and 480 g of copper monochloride are loaded. autoclave 6 l. The temperature is first maintained at about 70 ° C and oxygen is periodically supplied at a pressure of kgf / cm until copper is completely oxidized (about 30 minutes). Then, the excess oxygen is removed, the temperature is raised to 120 ° C, and a mixture of H2 and CO containing 33 vol% hydrogen is periodically fed into the autoclave, so that the total pressure is 25 kgf / cm. Partial carbon monoxide pressure 16.75. kg / cm Total entered 93 nl of the mixture. The reaction is complete after 20 minutes. Liquid analysis shows that dimethyl carbonate formed 8 wt.%, 1.8 wt. water, methanol selectivity 100, and carbon monoxide 93%, -a gas analysis shows the content in% by volume by volume: Oj 20; C02 7; H2 73. Indicators after three cycles of operation are at the above level. By the end of the fourth cycle, the liquid phase contains 28.9% dimethyl carbonate and 5.9% water, and the rest is methanol. PRI me R 3. A mixture of methanol, 1670 g (67%), 1 dimethyl carbonate g (30%), water 65 g (2.7%), and 480 g of copper monochloride are charged into an autoclave. The temperature of the system is increased before and a CO gas mixture containing 33% by volume of hydrogen is supplied at a rate of 130 nl / h simultaneously with oxygen at a rate of 30 nl / h. CO partial pressure 16.75 kg / cm Total pressure 25 kgf / cm. A mixture (80 nl / h) containing,%: CO N353; COg 7; 02 0.2. Analysis of the liquid phase after a two-hour process shows the following composition: methanol — 51%, dimethyl carbonate — 3%, water — 6%. Se- Methanol lectures are 100%, CO are 89%, and 16, 9% for methanol conversion. After h, the analysis of the liquid phase shows, wt%: methanol 38; dimethyl carbonate water 8. Methanol conversion 35%. Example. Analogously to example 1, the process is conducted using a mixture of CO containing 33 vol. hydrogen and skorsty 11 nl / h and the rate of oxygen tO nl / h at a total pressure of 25 kgf / cm and a temperature of 135C. CO partial pressure 16.75 kgf / cm. Exhaust gas contains,%: CO 8; lij 85; CDj 7.6; Og 0.4. Dimethyl carbonate is formed in the process at a rate of 90 g "l / h, its selectivity is 100 by, and 9 by CO. PRI me R 5. Analogously to example 1, a process is carried out using a mixture of CO and H2 containing 10 6b.% Of hydrogen at a rate of 85 nl / h and oxygen at a speed of 0. The same reaction time. The partial pressure of CO is 13.5 kg / cm, the total pressure is 15 kgf / cm. A mixture is continuously withdrawn from the autoclave — a gas containing: CO 33; SOP 18; 02 0.2, with a speed of 18 nl / h. The selectivity and productivity of dimethyl carbonate is similar to example k, Example 6. Similarly to example 1, the process is carried out using a mixture of CO and H2 containing 67% by volume of hydrogen at a rate of 250 and l / h of oxygen at a rate of 40 n l / h CO partial pressure: 16.5 kg / cm, total pressure 50 kgf / cm, process temperature. A gas containing% H2: 91J is continuously removed from the autoclave. CO 7; SOS 2; ciji 0.3, at a rate of 180 nl / h Dimethyl carbonate is obtained with selectivity and productivity as in Example 4. EXAMPLE 7. Similarly to the example in 3, the process is performed using a mixture of Co and H containing 33% by volume of hydrogen, at a rate of 390 nl / h, oxygen at a rate of 90 nl / h. The partial pressure is CO 23.5 kg / cm, the total pressure is 35 kgf / cm, the process temperature is 120 C. The gas withdrawn from the autoclave contains,%: CO-40; COj-6.5; 02-0.5. Analysis of the liquid phase after 1 h of reaction. shows the composition, weight D: methanol 49; Dimethylcarbonate 45, water 6. Methanol conversion 20%. . The invention The method for producing dimethyl carbonate by reacting methanol,. OKI carbon and oxygen in the presence of-. copper monochloride at 90–135 ° C, and a pressure of 15–50 kgf / cm o m – 1, in order to simplify the process, the latter is carried out in the presence of hydrogen contained in the initial carbon monoxide in an amount of 10–67 o. Sources of information taken into account in the examination 1.Patent of Germany No. 1 210 853, cl. 12 о, 27, pub. 1966.
    [2]
    2. The patent of Great Britain 1,491 396, cl. C 07 S 68/00, publ. 19-77.
    [3]
    3. The patent of Belgium No. 859 272, l. C 07 S 69/00, published 1978 (prototype).
    类似技术:
    公开号 | 公开日 | 专利标题
    SU988186A3|1983-01-07|Process for producing dimethyl carbonate
    US5908963A|1999-06-01|Preparation of fuel grade dimethyl ether
    EP0801050B1|2001-06-20|Process for the preparation of acetic acid
    US9340494B2|2016-05-17|Process for producing ammonia and urea
    US20180222852A1|2018-08-09|Synthesis of Methyl Carbamate and Dimethyl Carbonate | in Presence of Stripping with Inert Gas or Superheated Vapours and a Reactor for the Same
    EP0601956B1|1997-03-19|Process for the preparation of carbon monoxide rich gas
    US3998884A|1976-12-21|Catalytic conversion of phenol to cyclohexanol and/or cyclohexanone
    AU774093B2|2004-06-17|Natural gas conversion to hydrocarbons and ammonia
    RU1838289C|1993-08-30|Method of methanol synthesis
    CA1231977A|1988-01-26|Production of carbon compounds from a carbon oxide/hydrogen synthesis gas
    US4216194A|1980-08-05|Method of producing methane and carbon
    EP0113709A1|1984-07-25|Method in the production of methyl formate and methanol in a liquid phase.
    EP0037586A1|1981-10-14|Process for the selective hydroformylation of methanol to acetaldehyde
    CA2031292A1|1991-06-02|Production of methanol
    EP0597151A1|1994-05-18|Method for preparing formic acid
    US6858751B1|2005-02-22|Process for preparing aliphatic fluorofomates
    US1924766A|1933-08-29|Process for the production of carboxylic acids
    US2518754A|1950-08-15|Process of synthesizing aliphatic amines
    US4224243A|1980-09-23|Process for producing dimethyl formamide
    WO2017085594A2|2017-05-26|Process and catalyst for conversion of co2 to syngas for a simultaneous production of olefins and methanol
    US4242283A|1980-12-30|Process for continuously producing oxygen-containing compounds
    KR920001987B1|1992-03-09|Process of the preparation for acetic acid used with by-product gas of iron making
    EP0058531B1|1985-11-21|Process for the production of ammonia
    US4656152A|1987-04-07|Catalyst for producing lower alcohols
    US4007254A|1977-02-08|Process for the manufacture of carbon oxysulfide
    同族专利:
    公开号 | 公开日
    NO152696B|1985-07-29|
    IT1127270B|1986-05-21|
    DK161248C|1991-12-02|
    ZA806994B|1981-10-28|
    AU542124B2|1985-02-07|
    AU6444980A|1983-01-20|
    DK495980A|1981-06-05|
    US4318862A|1982-03-09|
    NO152696C|1985-11-06|
    FR2471363B1|1984-03-02|
    JPS5695151A|1981-08-01|
    SE8008501L|1981-06-05|
    IT7927816D0|1979-12-04|
    BE886495A|1981-06-04|
    LU82971A1|1981-07-23|
    FR2471363A1|1981-06-19|
    CH645610A5|1984-10-15|
    NO803631L|1981-06-05|
    DK161248B|1991-06-17|
    DE3045767C2|1983-06-01|
    NL186510B|1990-07-16|
    NL186510C|1990-12-17|
    JPS6338018B2|1988-07-28|
    SE445827B|1986-07-21|
    GB2064525A|1981-06-17|
    DE3045767A1|1981-06-11|
    GB2064525B|1983-09-14|
    NL8006591A|1981-07-01|
    CA1158663A|1983-12-13|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    CA923139A|1970-03-04|1973-03-20|Snamprogetti S.P.A.|Process for the preparation of esters of the carbonic acid|
    DE2520708A1|1975-05-09|1976-11-25|Roehm Gmbh|PROCESS FOR THE MANUFACTURING OF CARBON ESTERS|
    US4113762A|1975-05-09|1978-09-12|Rohm Gmbh|Method of making carbonic acid esters|
    US4218391A|1976-09-30|1980-08-19|Anic, S.P.A.|Method for the preparation of esters of carbonic acid|
    US4234504A|1978-12-15|1980-11-18|General Electric Company|Carbonylation process|EP0071286B1|1981-07-30|1985-08-28|Shell Internationale Researchmaatschappij B.V.|Process for the preparation of carbonate esters|
    US5093513A|1983-06-20|1992-03-03|Texaco Inc.|Process for oxycarbonylation of lower alkanols|
    US4761467A|1985-10-21|1988-08-02|Texaco Inc.|Pyridine ligands for preparation of organic carbonates|
    US5149839A|1988-11-08|1992-09-22|Nitto Boseki Co., Ltd.|Silane coupling agent and glass fiber product for laminates|
    DE3926709A1|1989-08-12|1991-02-14|Basf Ag|METHOD FOR PRODUCING DIALKYL CARBONATES|
    US5171874A|1989-08-22|1992-12-15|Quantum Chemical Corporation|Process for making dihydrocarbyl carbonate|
    ES2059034T5|1990-03-09|1997-07-16|Enichem Spa|PROCEDURE FOR THE PREPARATION OF ORGANIC CARBONATES.|
    EP0463678B1|1990-06-29|1994-10-05|ENICHEM SYNTHESIS S.p.A.|Process and catalyst for preparing organic carbonates|
    DE4123603A1|1991-07-17|1993-01-21|Bayer Ag|METHOD FOR PRODUCING DIALKYL CARBONATES|
    US5183920A|1992-01-13|1993-02-02|The Dow Chemical Company|Integrated process for the production of dimethyl carbonate|
    DE4203796A1|1992-02-10|1993-08-12|Bayer Ag|METHOD FOR PRODUCING DIALKYL CARBONATES|
    IT1254226B|1992-02-26|1995-09-14|Enichem Sintesi|CATALYTIC PRODUCTION FOR THE PREPARATION OF ORGANIC CARBONATES|
    US5221761A|1992-04-29|1993-06-22|Instituto Guido Donegani|Melt transesterification process for the production of polycarbonates|
    JPH06239807A|1992-07-31|1994-08-30|Ube Ind Ltd|Production of carbonate ester|
    US5391803A|1992-09-30|1995-02-21|The Dow Chemical Company|Production of dimethyl carbonate using copper zeolite catalysts|
    JPH06192181A|1992-11-06|1994-07-12|Ube Ind Ltd|Production of carbonic diester|
    DE4339977A1|1993-11-24|1995-06-01|Bayer Ag|Process for working up the liquid reaction products from the copper-catalyzed production of dimethyl carbonate|
    IT1269883B|1994-06-03|1997-04-15|Enichem Sintesi|METHOD FOR REMOVAL OF ACID CONTAMINANTS CONTAINED IN A VAPORIZED CURRENT COMPOSED OF ORGANIC VAPORS AND WATER|
    IT1269884B|1994-06-03|1997-04-15|Enichem Sintesi|METHOD FOR THE REMOVAL OF ACID AND SALT CONTAMINANTS FROM THE CONDENSED PHASE OF THE REACTION EFFLUENT IN A PROCESS FOR THE SYNTHESIS OF DIMETHYL CARBONATE|
    US5563288A|1995-06-07|1996-10-08|Osi Specialties, Inc.|Process for the preparation of tertiary aminocarbonates and aminoethers|
    US6280519B1|1998-05-05|2001-08-28|Exxon Chemical Patents Inc.|Environmentally preferred fluids and fluid blends|
    US6818049B1|1998-05-05|2004-11-16|Exxonmobil Chemical Patents Inc.|Environmentally preferred fluids and fluid blends|
    US6008399A|1999-03-11|1999-12-28|Mobil Oil Corporation|Process for preparing organic carbonates|
    US6294684B1|1999-12-08|2001-09-25|General Electric Company|Method and apparatus for the continuous production of diaryl carbonates|
    JP3799968B2|2000-06-16|2006-07-19|東海ゴム工業株式会社|Manufacturing method of anti-vibration rubber with excellent durability|
    US7345187B2|2001-08-14|2008-03-18|General Electric Company|Method and apparatus for preparing a dialkyl carbonate, and its use in the preparation of diaryl carbonates and polycarbonates|
    US6784277B2|2001-08-14|2004-08-31|General Electric Company|Method for preparing a dialkyl carbonate, and its use in the preparation of diaryl carbonates and polycarbonates|
    US7514521B2|2001-08-14|2009-04-07|Sabic Innovative Plastics Ip B.V.|Method for preparing a dialkyl carbonate, and its use in the preparation of diaryl carbonates and polycarbonates|
    US6977308B2|2002-06-25|2005-12-20|General Electric Company|Method and apparatus for preparing a dialkyl carbonate|
    US7049457B2|2003-09-05|2006-05-23|Exxonmobil Chemical Patents Inc.|Use of an ionic halide free copper catalyst for the production of dialkyl carbonates|
    ES2245254B1|2004-06-11|2007-03-01|Universidad Politecnica De Valencia|PROCEDURE FOR OBTAINING POLY-OXYGEN ORGANIC COMPOUNDS.|
    US7622602B2|2005-10-12|2009-11-24|Sabic Innovative Plastics Ip B.V.|Method for preparing a dialkyl carbonate, and its use in the preparation of diaryl carbonates and polycarbonates|
    TWI357895B|2007-01-17|2012-02-11|China Petrochemical Dev Corp|
    TWI359134B|2007-05-28|2012-03-01|China Petrochemical Dev Corp|
    TWI367128B|2008-07-31|2012-07-01|China Petrochemical Dev Corp|
    CN104892423B|2015-05-18|2017-01-04|太原理工大学|The technique that a kind of methanol oxidative carbonylation prepares dimethyl carbonate|
    CN106478421B|2015-08-31|2019-09-13|亚申科技有限公司|DMC Processes|
    CN107335443B|2017-07-12|2018-08-21|太原理工大学|The method that explosion method quickly prepares graphene-supported multimetal reforming catalyst|
    WO2020127287A1|2018-12-20|2020-06-25|Haldor Topsøe A/S|A process for preparing dimethyl carbonate|
    CN111548273B|2020-05-09|2021-10-01|中国科学技术大学|Method for preparing dimethyl carbonate by using copper/cuprous oxide nanosheet catalyst to thermally catalyze methanol and carbon dioxide|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    IT27816/79A|IT1127270B|1979-12-04|1979-12-04|PROCESS FOR THE PRODUCTION OF DIMETHYLCARBONATE|
    [返回顶部]