Versions of herbicide-antidote composition
专利摘要:
公开号:SU984394A3 申请号:SU803211173 申请日:1980-12-02 公开日:1982-12-23 发明作者:Рор Вольфганг;Ганзен Ганспетер;Плат Петер;Вюрцер Бруно 申请人:Басф Аг (Фирма); IPC主号:
专利说明:
i, RT hydrogen, methyl; K, hydrogen, methyl R —OD,,; :: -. zosom, the ratio of components; ; : .25. Ssg.asno. to the third variant::; - cj, dChO, antidote composition of soda 300-c: -: d based on acetanilide, - / yne do-dHzdi centrot on the basis of dichloroacetate Sbm. -CO-djlc i2j ES hydrogen, methyl, -hydrogen, methyl; -0.1, -0.1,; -p: d the weight ratio of components is 1: 0.125. According to the fourth variant of the 5a-1d-antidote composition of the sodade acetanilide-based herbicide., YHg-A; ovw C 0-C H2Cil strength, ethyl; i - hydrogen, methyl; S-methyl, ethyl. . - 1 2-diazole, unsubstituted substituted once or by a methoxy group or a multiple of methyl, ethoxy methoxymethyl, -DOT based on dichloroacetate, - j-1 en O O-i-T-dO-dHdl; sgie ii3 1: three weight ratios component 1; OD25. It is useful for a variant of this et-gidno-antidote composition of herbicide based on acetanilide fort (“tuly. R-itr methyl, ethyl; A - 1,2-diaeol, unsubstituted or once substituted by methyl or methoxy group, and antidote based on dichloracetamide of formula Y N -do-dHdi with a weight ratio of 1: 0.25, and herbicide anti-dotic compositions are shown in Tables 1 and 2. Example: Experiments in a greenhouse: Plastic boxes for seedlings are filled with ginous sand () and 1.5% humus In this substrate, maize (Zea mays) is shallowly sown, moreover, not thickly spreading in Echinochloa crus galli is planted as an undesirable plant. In unsterilized soil, weed seeds are susceptible to germination to replenish the composition of unwanted plants. Thus, the conditions are sown with crop plants and weed-infested. Herbicides and antidotes are used separately and as mixtures. Herewith, herbicides and antidotes: and mixtures thereof are used in the form of aqueous preparations. In some cases, preparations before sowing cultivated plants are mixed into the soil. After sowing and processing, the crates are irrigated and covered with transparent plastic caps before planting. This measure ensures the uniform germination and growth of plants. Placing them at a temperature in the region of 18 to an average. The experiments are completed after reaching the stage of maize development of 3 to 5 leaves. The activity of the agents is determined on a scale from 0 to 100. At the same time, O means normal germination and development of plants based on untreated control plants, 100 corresponds to the complete absence of germination or destruction of plants. Herbicides, antidotes, amounts of herbicides and antidotes and the results of the experiments are shown in Table 3-5. Thus, the proposed herbicidal antidote formulations exhibit lower phytotoxicity compared with the known herbicidal antidote formulations. Herbicide based on acetanilide derivatives Herbicide about -ABOUT . / -N -CLriH, Table 1 , -N .p3 cIo-ciH, L R Rsn. sun „ sn. C-1. sn. CHj sn. n S.N. . O r F-c o-clHCii; {-T / CH3 (io-dHc b U Antidote BUT. 9843948 Continued table. 2 T Structure I-l 0 "N-N-CiO-CJHC i2 driTclH, o iJ- N-do-CHciiz enz ciHj o N-F-c o-ciHdi2 u (Jhcjb o n- jsr-cio1 Greenhouse pre-emergence processing 4.0 4.0 4.0 1.0 2.0 1.0 + 0.1 1.0 + 0.25 2.0 + 0.5 usBecmt oJ V-Co-c H.di jj / j Table 3 Oh oh 100 100 100 100 100 Greenhouse pre-emergence processing Continued table. 3 Table 4 1.0 1.0 + 0.125 1 | 5. 2.5 1.5 + 0., 188 2.5 + 0.313 1.5 1.5 + 0.188 2.0 2.0 + 0.25 1.0 1.0 + 0.125 A 1.0 + 0.125 (Known) 1,0 + 0,25 Dovskhodova processing in the greenhouse (processing Ar 1.0 + 0.25 fHsBecTHOj Continued table. 4J 98 100 98 100 95 95 98 100 100 100 98 98 100 100 40
权利要求:
Claims (2) [1] 100 Table 5 Soil before maize sowing) Claim 1. Herbicidal antidote containing herbicide based on the lead of the formula (Ng-1 / P dO-ClHzdt and antidote based on production} Shoracets1mida, I distinguish with the fact that contains in to the dichloroacetamide derivative the general formula; o N-N-do-ciHtiiz () рRI B g where R to R-- is hydrogen, methyl; P is OD, with a weight ratio of 1: 0.1 o [2] 2. A herbicidal antidote containing nilide herbicide of the formula J-dO-dH di and an antidote based on the production of chloroacetamide, so that, in order to reduce toxicity, it contains derivative d and chlorine hydroxide amide a The general formula 1-u O -F-F-dO-dHdlz №) W: where R. and hydrogen, methyl Ra - hydrogen, methyl P - 0.1, with a weight ratio of comp equal to 1: 0.25 about 3 „ A herbicidal antidote containing nilid based herbicide of the formula N, NNG-KO: ou-to, and an antidote based on a dichloroacetamide derivative, characterized in that it contains to reduce phytotoxicity um as dichloroacetamido derivative compound of the general formula o N- F-do-dHdii №L ,, / J 6 where Rjj - hydrogen, methyl; and and f is hydrogen, methyl; m is 0.1, P is 0.1, with a weight ratio of components equal to 1: 0.125. 4. Herbicidal antidote composition containing herbicide based on gchetanilid general formula b1g-A -K. do-dH di where RT is methyl, ethyl; hydrogen, methyl ;. methyl, ethyl; 1,2-diazole, unlabelled or substituted once with methyl or methoxy or twice methyl, ethoxy, methoxymethyl, and the dichloroacetamide derivative antidote, characterized in that, in order to reduce phytotoxicity, it contains a compound of formula 1 as a dichloroacetamide derivative, dHj s1nz with a weight ratio of components, avnom 1: 0.125. 5. A herbicidal antidote composition containing an acetanilide herbicide of the general formula Vue cJHf-A YoVi nG "o-K" 1 de R ..- methyl, ethyl; A - 1,2-diazole, unsubstituted or singly substituted by methyl or methoxy group, an antidote based on a ichloroacetamide derivative, characterized in that, in order to reduce phytotoxicity, it contains 15 in KalecTse dichloroacetamide derivative a compound of the formula SNE TG dl, v vjizvj. . -. CHE CHZ 984394 16 with a weight ratio of components equal to 1: 025. Sources of information taken into account in the examination 51, Patent Germany 2245471, cl. 45 e 21/02, off 1973 (prototype).
类似技术:
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同族专利:
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引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题 US3334099A|1965-03-31|1967-08-01|Sandoz Ag|Novel pyrrolo-diazepines, pyrrolo-imidazolidines, and pyrrolo-pyrimidines| DE1802468A1|1968-10-11|1970-05-21|Bayer Ag|Diazabicycloalkanes, plant protection agents| US4021224A|1971-12-09|1977-05-03|Stauffer Chemical Company|Herbicide compositions| CA1174865A|1971-04-16|1984-09-25|Ferenc M. Pallos|Thiolcarbamate herbicides containing nitrogencontaining antidote| US4269618A|1971-12-09|1981-05-26|Stauffer Chemical Company|Herbicide compositions| US4033756A|1971-09-17|1977-07-05|Gulf Research & Development Company|Dichloroacetamide treated rice seeds| US4124376A|1975-12-17|1978-11-07|Stauffer Chemical Company|Herbicide compositions| US4392884A|1978-08-04|1983-07-12|Stauffer Chemical Company|Herbicide compositions| FR2310348B1|1975-05-07|1978-06-09|Ugine Kuhlmann| DE2648008C3|1976-10-23|1980-09-04|Basf Ag, 6700 Ludwigshafen|Acetanilide| IL53938D0|1977-02-02|1978-04-30|Bayer Ag|Novel n-substituted halogenoacetanilides, their preparation and their use as herbicides| DE2744396A1|1977-10-03|1979-04-12|Basf Ag|ACETANILIDE| DE2807340A1|1978-02-21|1979-08-23|Egyt Gyogyszervegyeszeti Gyar|N,N-di:substd. di:chloro:acetamide herbicide antidotes prepn. - by reacting chloral and sec. amine in aq. or polar organic medium in presence of e.g. a cyanide| DE2832950A1|1978-07-27|1980-02-21|Basf Ag|HERBICIDAL AGENTS| GR66644B|1978-07-27|1981-04-03|Basf Ag| DE2938155A1|1979-09-21|1981-04-23|Bayer Ag, 5090 Leverkusen|N-ACYL-PIPERIDONES, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE AS AN AGAINST AGENT FOR THE PROTECTION OF CULTURAL PLANTS FROM DAMAGE FROM HERBICIDES|DE3120859A1|1981-05-26|1982-12-23|Basf Ag, 6700 Ludwigshafen|DIHALOGEN ACETAMIDES, METHOD FOR THE PRODUCTION THEREOF AND HERBICIDAL AGENTS THAT CONTAIN ACETANILIDES AS AN HERBICIDE ACTIVE SUBSTANCES AND THESE DIHALOGEN ACETAMIDES AS AN ANTAGONISTIC AGENTS| US4995899A|1986-01-15|1991-02-26|Basf Aktiengesellschaft|Optically active diazabicycloalkane derivatives and their use for protecting crops from the phytotoxic effect of herbicides| DE3600903A1|1986-01-15|1987-07-16|Basf Ag|OPTICALLY ACTIVE DIAZABICYCLOAL CANDERIVATIVES, A METHOD FOR THE PRODUCTION THEREOF AND THEIR USE FOR PROTECTING CULTURAL PLANTS FROM THE PHYTOTOXIC EFFECT OF HERBICIDES| DE4217846C1|1992-05-29|1993-12-23|Basf Ag|Process for the preparation of 5-dichloroacetyl-3,3,6-trimethyl-9-oxo-1,5-diazabicyclo [4,3,0] nonane| US5541148A|1992-07-08|1996-07-30|Ciba-Geigy Corporation|Selective safened herbicidal composition comprising 2-ethoxycarbonyl-3- oxy-pyridine and an acylsulfamoylphenyl-urea safener| ES2131656T3|1993-03-22|1999-08-01|Novartis Ag|SELECTIVE HERBICIDE AGENT.| EE9500018A|1994-06-03|1995-12-15|Ciba-Geigy Ag|Selective herbicide and method of application| JP3967431B2|1997-09-03|2007-08-29|株式会社トクヤマ|Ethenylamide herbicide composition| CN1310583A|1998-06-26|2001-08-29|诺瓦提斯药物公司|Herbicidal composition| EP1250047B9|2000-01-25|2005-05-18|Syngenta Participations AG|Herbicidal composition| US7662960B2|2001-04-26|2010-02-16|Choongwae Pharma Corporation|Beta-strand mimetics and method relating thereto| WO2002087322A2|2001-04-27|2002-11-07|Syngenta Participations Ag|Herbicidal composition| NZ543790A|2003-05-30|2009-09-25|Choongwae Pharma Corp|Beta-strand mimetics and methods relating thereto| DE102004054665A1|2004-11-12|2006-05-18|Bayer Cropscience Gmbh|Substituted bicyclic and tricyclic pyrazole derivatives Methods for the preparation and use as herbicides and plant growth regulators| DE102005002343A1|2005-01-18|2006-07-27|Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V.|Process for the specific or unspecific separation of cells and / or viruses from liquid media and its use|
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申请号 | 申请日 | 专利标题 DE19792948535|DE2948535A1|1979-12-03|1979-12-03|DICHLORACETAMIDES, HERBICIDE AGENTS THAT CONTAIN ACETANILIDES AS HERBICIDAL ACTIVE SUBSTANCES AND THESE DICHLORACETAMIDES AS AN ANTAGONISTIC AGENTS, AND THEIR USE FOR CONTROLLING UNWANTED PLANT GROWTH| 相关专利
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