• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    The herbicide contains a compound of the formula I in which the individual substituents have the meaning given in Patent Claim 1. It has a broad spectrum of action against grass weeds and is tolerated by dicotyledon crop plants and various cereal species. <IMAGE>
    公开号:SU882403A3
    申请号:SU772462914
    申请日:1977-03-18
    公开日:1981-11-15
    发明作者:Хандте Райнхард；Кох Манфред；Херляйн Герхард；Кехер Хельмут；Лангелюддеке Петер
    申请人:Хехст Аг (Фирма)；
    IPC主号:
    专利说明:

    (54) HERBICID MEANS
    The invention relates to chemical agents for controlling weeds and undesirable plants, namely, agents containing active substances from the class of organic compounds and auxiliary components from among liquid or solid carrier surfactants, etc. Known herbicidal agents based on derivatives of diphenyl ether. These include, for example, an agent based on 2-halo-4-trifluoromethyl-4- (carboxyisopropyloxy) diphenyl ether f1, It is also known a herbicidal agent based on 4-nitro-2 -nitro-4-trifluoromethyldiphenyl ether (23. However, The herbicidal agents of this group are not sufficiently effective against some resistant species of weeds. The aim of the invention is a new herbicidal agent based on a diphenyl ether derivative, which has an increased herbicidal activity. e of the active substance of the bicidal agent use the common diphenyl ester of the total mule OCH-CH2-%, R is chlorine, bromine, trifluoromethyl, n 1 or 2, Z is a hydroxyl group, chlorine, ethoxycarbonyloxy group, -OCOR group, in which R is alkyl C - C, mono- or dihaloalkyl C | - Cj, cyclopropyl or lower alkanyl group p) US group, in which) is BT chlorine, methyl or nitro, P 1 0-2; , j is a group in which R is hydrogen or methyl, R is hydrogen, lower alkyl, phenyl or chlorophenyl; OSO, U group, in which R is methyl or phenyl; a group in which the R is a cation of an organic or inorganic base, "jHs O - (((a group in which Y is chlorine or trifluoromethyl, p 1 or 2, in an amount from 2 to 95% by weight. Usage forms of the herbicide agent are common: solutions , emulsions, pastes, powders, etc. They are prepared by known methods. Compounds of formula 1 are prepared by reacting the corresponding hydroxyl-containing diphenyl ethers with a compound of the general formula </ BR> where X is halogen) Z have the indicated values. Recommended doses of the active ingredient of formula 1 are within 0 , 1 - 10 kg / ha, will prefer 0.5 to 5 kg / ha of flax.Table 1 shows compounds of general formula 1 and examples illustrating the effectiveness of the proposed herbicidal agent.Example: Grass seeds are sown in pots and sprayed onto the ground surface in various dosages as dusts Immediately thereafter, the holes are not placed in the greenhouse at 4. The results of processing {as in the following examples are evaluated according to the following scale presented in Table. 2. As comparative herbicides, the following agents were tested: fluoridiphen (4-nitrophenyl-2-nitro-4-trifluoromethylphenyl ether) and mecoprop (2- / 4-chloro-2-methylphenoxide / -propionic acid). The results are shown in Table. 1 show that, in relation to herbs, the proposed compounds are more effective than the substances taken for comparison. Compound numbers correspond to their table numbers. 1. In uabl. 3 shows the evaluation of the effect of the drug upon treatment of the plant by germination. .Crimer2. Grass seeds are sown in pots and placed in a greenhouse. Three weeks after sowing, the plants are sprayed with the proposed preparations in the form of powders for spraying and, after 4 weeks after keeping the greenhouse, the effect of the preparations is assessed. In tab. Figure 4 shows the assessment of the effect of the preparations upon treatment of the plants after germination. Froze The seeds of cultivated plants are sown in pots. After that, one part of the seed pots is treated by a pre-emergence method (analogously to example 1), and the other in a post-emergence manner (analogous to example 2) at a dosage of 2.5 and 0.6 kg / ha. Results were calculated 4–4.5 weeks after treatment; they are given in table. 5. All dicotyledon cultivated plants at high dosages (2.5 kg / ha) are well compatible with the proposed compounds in both the pre-germination and the post-germination treatments. Example 6: The seeds of maize and rice and the seeds of the grass are planted separately from each other in pots and left in the greenhouse for 3 weeks to germinate. The proposed formulations prepared as sprinkling powders, and the comparative substances are sprayed independently of each other onto the plants in various dosages. After 4 weeks, the effect of the drugs is evaluated. The following compounds were taken as comparison substances: A- methyl ester of 2- [4 (2,4 dichlorophenoxy) phenoxy] -propionic acid, B-isobutyl ester 2-f4- (4-chlorophenoxy) - (phenoxy) propionic acid, C-methyl ester of 2- / 4 - / 4-trifluoromethylphenoxy / -phenoxy / -propionic acid. Compounds of the proposed compounds showed significantly better compatibility with known substances in the case of maize and / or rice. At dosages that are generally harmless to plants or cause little damage, these compounds have proven to be extremely effective against herbs. The substances taken for comparison with respect to rice and maize were not selective (see Table B, which provides a quantitative estimate for the treatment of plants after germination). ExampleB In an additional experience of the post-germination treatment, compounds 6.34, 61 and 65 were tested in comparison with compound C in accordance with Example 1. The results in Table. 7 show that the proposed compounds are superior in their compatibility with cultivated plants, the substances taken for comparison (Compound C) or, with equally good compatibility with soybeans, show greater efficacy in relation to test herbs. PRI me R 6. The effectiveness of the proposed compounds in the experience with the treatment before germination is presented in table. eight.
    /
    ) -odH-cJH | -z
    2,4-Dichlor
    4-chloro
    2-Chloro-4-bromo 4-Trifluoromethyl
    2-Chloro-4-trifluoromethyl
    4-Trifluoromethyl
    4-chloro
    4-chloro
    4-chloro
    4-chloro
    4-chloro
    4-chloro
    4-chloro-chloro
    2,4-Dichlor
    2,4-Dichlor
    2,4-Dichlor
    2,4-Dichlor
    2,4-Dichlor
    2,4-Dichlor
    2,4-Dichlor
    2,4-Dichlor
    2,4-Dichlor
    23 2,4-Dichlor
    24 2,4-Dichlor
    Hydroxyl
    Hydroxyl
    Hydroxyl
    Hydroxyl
    Hydroxyl
    Chlorine
    Benoyloxy
    4-Chlorobenzoyloxy
    2-Chlorbenoyloxy
    2-Nitrobenzoyloxy
    2- / 4 {4-Chlorophenoxy) fp. Propionyloxy
    2- / 4 (2, 4-Dichlorophen phenoxy- / propionyloxy
    Butyroyloxy
    Chloroacetyloxy
    Benzoyloxy
    4-methylbenzoyloxy
    2-Chlorbe Zoyloxy
    2,4-Dichlorobenzoyloxy
    2,4-Dichlorobenzoyloxy
    2-methylbenzoyloxy
    Acetyloxy
    Dichloroacetyloxy
    2- / 4 (-Chlorphenoxy) phenoxy- / propionyloxy
    2- / 4 (2, -Dichlorophenoxy phenoxy- / propionyloxy
    2- / 4 - (4 -Trifluoromethylphenoxy / propionyloxy
    4-trifluoromethyl
    4-Trifluoromethyl
    4-Trifluoromethyl
    2-Chloro-4-trifluoromethane
    4-chloro
    4-Trifluoromethyl
    4-Trifluoromethyl
    4-chloro
    2,4-Dichlor
    2,4-Dichlor
    2,4-Dichlor
    2,4-Dichlor
    4-Trifluoromethyl
    4-Trifluoromethyl
    4-Trifluoromethyl
    4-Trifluoromethyl
    2,4-Dichlor
    4-Trifluoromethyl
    4-4-dichloro
    4-Trifluoromethyl
    4-Trifluoromethyl
    4-chloro
    4-Trifluoromethyl
    Continued table. one
    phenoxy propionyloxy
    2- / 4 (4-Trifluoromethylphenoxy) phenoxy- / propionylxy
    Butyroyloxy Decyloyloxy Benzoyloxy 2,2-Dichloropropionyloxy 2-2-Dichloropropionyloxy Methylcarbamoyloxy
    Propylcarbamoyloxy
    4-Chlorophenylcarbamoylox
    Phenylcarbamoyloxy
    Methylcarbamoyloxy
    Propylk Arbgshoilok S
    Me tilk arb gshoilioxy
    Propylcarbamoyloxy
    Phenylcarbs1moyloxy
    4-Chlorophenylcarbamoylox
    Dimethylcarbs number 1yloxy
    Dimethylcarbamoyloxy
    Ethoxycarbonyloxy
    Methylsulfonyloxy
    Phenylsulfonyloxy
    Phenylsulfonyloxy
    OSO, Na
    Continued table. one
    Continued table. 3
    Continued table. four
    Continued table. five
    Table 6
    1 a b-l and c a
    Table 8
    Continued table. eight
    Continued table. eight
    Continued table. eight
    Continued tab. eight
    权利要求:
    Claims (2)
    [1]
    Claim
    A herbicidal agent containing a diphenyl ether derivative as an active substance, as well as auxiliary components selected from the group of liquid or solid carriers and surfactants, characterized in that, in order to enhance the herbicidal action, it contains a diphenyl ether derivative of the general formula
    G where R is chlorine, bromine, trifluoromethyl, η-1 or 2;
    Ζ - hydroxyl group, chloro / ethoxycarbonyloxy group, group - 0C0R ', in which R * means alkyl - Cj, mono - or dihaloalkyl C 4 - C a , cyclopropyl or lower alkenyl group,
    - a group in which X is chloro, methyl or nitro
    [2]
    2 group, m = 0-2,
    —OCNfl R is a group in which is hydrogen or methyl, ”R 3 is hydrogen, N-alkyl, phenyl or chlorophenyl,
    -OSO ^ R is a group in which R * is methyl or phenyl,
    -05 0 ^ R is a group in which R 5 is a cation of an organic or inorganic base,
    Str in which ¥ is chlorine or trifluoromethyl, η = 1 or 2, in an amount of 2-95 wt.%.
    类似技术:
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    同族专利:
    公开号 | 公开日
    IE44653B1|1982-02-10|
    ZA771606B|1978-01-25|
    CH627916A5|1982-02-15|
    IT1125764B|1986-05-14|
    JPS52114020A|1977-09-24|
    PT66324B|1978-11-07|
    FR2360253B1|1983-10-07|
    IE44653L|1977-09-19|
    PL196753A1|1978-01-16|
    HU178576B|1982-05-28|
    AT354800B|1979-01-25|
    GB1577181A|1980-10-22|
    BR7701656A|1978-01-03|
    CA1117122A|1982-01-26|
    DD128799A5|1977-12-14|
    IL51685A|1981-11-30|
    DE2611695A1|1977-09-29|
    BE852701A|1977-09-21|
    AU509124B2|1980-04-24|
    IL51685D0|1977-05-31|
    FR2360253A1|1978-03-03|
    EG12622A|1981-12-31|
    PT66324A|1977-04-01|
    ATA181677A|1979-06-15|
    PL104153B1|1979-08-31|
    AU2341777A|1978-09-21|
    NL7702985A|1977-09-21|
    OA05607A|1981-04-30|
    AR224331A1|1981-11-30|
    BG27714A3|1979-12-12|
    GR71448B|1983-05-18|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    DE2415867A1|1974-04-02|1975-10-09|Merck Patent Gmbh|PHENOXY ALCANOL DERIVATIVES AND THE PROCESS FOR THEIR PRODUCTION|
    FR2285859B1|1974-09-30|1980-05-30|Lafon Labor|US4105435A|1975-10-29|1978-08-08|Ishihara Sangyo Kaisha Ltd.|Herbicidal compound, herbicidal composition containing the same, and method of use thereof|
    DE2748658A1|1977-10-29|1979-05-10|Hoechst Ag|HERBICIDES BETA-NAPHTHYL-PHENYL ETHER|
    EP0003114B1|1978-01-18|1982-01-27|Ciba-Geigy Ag|Herbicidal active unsaturated esters of 4- -oxy)-alpha-phenoxy propionic acids, process for their preparation, herbicidal compositions containing them and their use|
    WO1979000624A1|1978-02-15|1979-09-06|Ici Ltd|Herbicidal derivatives of 2-phenoxy)propane,processes for preparing them,and herbicidal compositions containing them|
    PH18417A|1981-06-25|1985-06-24|Nihon Tokushu Noyaku Seizo Kk|Substituted phenoxypropionates and herbicidal compositions|
    EP0072475B1|1981-08-17|1986-08-20|F. HOFFMANN-LA ROCHE & CO. Aktiengesellschaft|Carbamic esters, preparation thereof, pesticidal compositions on the basis of these compounds and their use in combating pests|
    US4625048A|1982-08-13|1986-11-25|Hoffmann-La Roche Inc.|Carbamic acid esters|
    JPS59199673A|1983-04-25|1984-11-12|Sumitomo Chem Co Ltd|Nitrogen-containing heterocyclic compound, its preparation and pesticide containing the same|
    US4550192A|1983-09-01|1985-10-29|The Dow Chemical Company|Fluorophenoxyphenoxypropionates and derivatives thereof|
    DE3823521A1|1988-07-12|1990-02-15|Basf Ag|CYCLOPROPANCARBOXAMIDES, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE FOR CONTROLLING Pests|
    US5012017A|1988-08-18|1991-04-30|Dowelanco|Phenoxyphenoxypropionates, intermediates thereof and methods of preparation|
    EP1377568A1|2001-01-31|2004-01-07|Warner-Lambert Company LLC|Method for carbamoylating alcohols|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    DE19762611695|DE2611695A1|1976-03-19|1976-03-19|HERBICIDAL AGENTS|
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