Method of preparing polymeric composition
专利摘要:
1518016 Polyolefin compositions LES PLASTIQUES DE CARMAUX 24 Aug 1976 [9 Sept 1975] 35247/76 Heading C3K A composition comprises a polymer of an olefin and from 1-15% by weight of the polymer of a dehydrated kaolinite containing 51-57 wt. per cent silica, 40-46 wt. per cent alumina, and up to 3 wt. per cent impurities. The kaolinite can be dickite, nacrite, halloysite, or anauxite. The composition absorbs infra-red radiation and can be used to make films for agricultural purposes. 公开号:SU736873A3 申请号:SU762396745 申请日:1976-09-09 公开日:1980-05-25 发明作者:Пье Жан-Филипп 申请人:Ле Пластик Де Кармо (Фирма); IPC主号:
专利说明:
one The invention relates to methods for producing polyolefin compositions used to produce films with improved infrared absorption parameters in the wavelength range from 5 to 15 µm, in particular, used to protect cereals and fruits. Many polyo pefins, especially low density polyethylene, are very well permeable to infrared radiation in the wavelength range from 5 to 15 µm. Usually, a polyethylene film, for example, when used as a film for closing cereals or fruits, cannot preserve heat and this sometimes leads to the fact that the temperature under the film is lower than the external temperature, i.e. grains or fruits are not protected from frost. Similarly, the usual plastic film does not protect the grains and fruits from the harmful effects of sunlight during the days. Therefore, it was usually practiced to use in agriculture for the purpose of covering grain and fruit - polyvinyl chloride films 1 (PVC) as having satisfactory absorption properties. However, PVC has the disadvantage that it is brittle in cold weather, and its plasticizing components tend to dissolve in wet weather. Moreover, PVC films usually have a higher cost than polyolefin films .. Thus, there is a need, and especially in agriculture, for polyolefin films with a minimum capacity 18 to transmit infrared rays. The closest to the invention according to the technical essence and the achieved result is a method for preparing compositions based on popiolefins by displacement with dehydrated kaolinite containing approximately 37% by weight silica and 63% by weight aluminum oxide. However, the resulting film is also permeable to infrared radiation, The invention is an increase in infrared absorption. radiation produced from the composite film. This is achieved by the method of obtaining a polymer composition by mixing polyethylene or copolymao-ethylene and vinyl acetate with 1-15% by weight of dehydrated kaolinite, as the latter using kaolinite containing from 51 to 57 weight.% Silicon dioxide, from 40 to 46% by weight of aluminum oxide and the rest is impurity. Kaolinite is used in an amount of from 1 to 15 wt.% To the weight of the polyolefin, preferably from 3 to 10 wt.%. The dehydrated kaolinite can be obtained by calcining, in its associated state, water, an alumina selected from the group consisting of kaolinite, dikite, nakrit, gallosite, and anoxic. Isolonit, dicit and nacrite are polymorphic forms of the formula De2O. 25iO2-2OOO; gallose is a hydrogenated kaolinite of the formula. X, anoxyt is similar, but contains slightly more silicon dioxide than kaolinite. The dehydrated product obtained by calcining aluminosilicates corresponds approximately to the formulas AB dO, 2 S-iO, and theoretically has the composition: 54 wt.% Silicon dioxide and 46 wt.% Alumina. Dehydrated kaolinite containing from 51 to 57 wt.% Of silicon dioxide and from 40 to 46 wt.% Of alumina, and the content of impurities such as magnesium oxide, limestone, sodium, titanium dioxide, iron oxide is less than 3 wt.%. Other silicates, sulfates or carbonates can be tolerated in the composition if their weight is small compared to the weight of dehydrogenated kaolinite. Such silicates can be biedelite.,, -, pyrophyllite, Ae2Oz-4 1O2-, talc 45iO2-H5, O, they can be either in hydrated form or in dehydrate form, JITO is more preferable. The polyolefin used is mixed with dehydrated kaolinite at a temperature of at least 736873 equal to the melting point of the polyolefin. The mixing is carried out in a Bendbury type mixer. The necessary stabilizing additives can also be incorporated into the polymer compositions. The kaolinite used must be dehydrated, which otherwise affects the quality of the films produced. Preferably, the kaolinite is in a finely divided form and has a particle size. 1 to 5 microns. Produced films with a thickness of 20 to 200 microns are used in agriculture to protect crops and fruits. It has been established that the nature of growth and the yield of a large number of plants can be significantly increased when they are grown under films. Among these plants are ground, melon, marinka, radish, beans, parsley, etc. For example, when splicing these films, the yield of melons increased by 1101, potatoes by 40%, and for tomatoes by 50% compared with the yield of the same crops grown without films. Example 1. 92.5 wt.% Polyethylene (density 0.92, melt flow rate 1 g. (10 min by ASTM method D-1238, mixed with 7.5 wt.% Dehydrogenated caolinite consisting of 1.5% HjO, 52.5% SiOj, 43.5% AE2.O, and 2.5% impurities.Kaolinite has an average particle size of 2 microns. Stirring is carried out in a Bendbury type mixer. Films of a thickness of 90 μm are formed from the mixture and examined spectrophotometrically in the infrared spectrum. The radiant energy, in the range from 5 ds to 15 microns, which was not kept in the patchwork, is equal to 30.5%, which is better than the indicator for polyvinyl chloride films (29%). Example 2. The mixture is prepared analogously to example 1, except for the type of dehydrogenated kaolinite, depending on the brand and fluctuations in the concentration of aluminosilicates within the specified limits, i The compositions of kaolinites and the results of spectrophotometric determinations of films in the infrared spectrum are given in Table. one. Table 1 92.5% by weight of polyethylene is mixed with 7.5% by weight of the aluminosilicate composition in a Bendbury type mixer. The Ytumosilikat (Tüboril, Siln et Kaolin of France) contains 62% SiOrj, 35% de dO and 2.6% of impurities with a particle size of 1.5 μm. From the mixture, films with a thickness of EOkmm are examined and their IR spectrophotometry is studied. It is established that the percentage of retained radiation energy, in pochPaket, (Czechoslovakia) Silus to Kaolin (France) 11.5 Vlan Minero de Paris (France) 13 not in the wavelength range from 5 to 15 microns is 38%. Etc. and measure 3. Similarly to example 2, but taking non-hydrated aluminosilicate compounds and different proportions of aluminum oxide and silicon dioxide. In tab. Table 2 shows kaolinite compositions and the results of spectrophotometric determination of films in the IR spectrum. Table 38 36.5 43 0.75 2.4 36 15 55 10.6 36.5 42
权利要求:
Claims (1) [1] Claim 1. A method of producing polymer compositions by mixing polyethylene 50 or a copolymer of ethylene and vinyl acetate with 1-15 wt.% Dehydrate. 40 kaolinite, characterized in that, in order to increase the absorption of infrared radiation made from the film composition, kaolinite containing, wt.%: Is used as dehydrated kaolinite 51-57 40-46 The rest. 1, the result of a join and the fact that they use dehydrated kaolinite having an average particle size of from 1 to 5 microns. 55 Sources of information taken into account during the examination 1. Ivanyukov D.V., Fridman M.L. Polypropylene, M., ’Chemistry’ (1974, from. 131-132 (prototype). Silica Alumina Impurity 2. Method for TSNIIIPI Order 2463/49 Circulation 549 f Subscription PPP ’’ Patent ’’ branch, Uzhhorod, st. Project, 4
类似技术:
公开号 | 公开日 | 专利标题 SU736873A3|1980-05-25|Method of preparing polymeric composition US4895904A|1990-01-23|Plastic sheeting for greenhouse and the like US6441059B1|2002-08-27|Agricultural method and materials for screening solar radiation DE3302358C2|1994-09-08|Infrared radiation absorption film US6647662B2|2003-11-18|Plant treatment material and method US4134875A|1979-01-16|Polyolefin film for agricultural use US3857804A|1974-12-31|Thermoplastic film for controlling plant growth US5133909A|1992-07-28|Production of biologically degradable films FI92492B|1994-08-15|Film-forming compositions and film-producing anti-fogs US3738956A|1973-06-12|Polyvinyl chloride covering for a plant enclosure containing surface active agents to modify water-condensate droplet contact angle US3542710A|1970-11-24|Colored transparent thermoplastic sheet based on vinyl chloride polymer KR100416863B1|2004-05-06|Complex hydroxide condensed silicate, preparation method thereof, infrared absorber and agricultural film US4189866A|1980-02-26|Polymer-optical brightener combinations in transparent film form useful as glazing materials capable of modifying plant growth rate US6153665A|2000-11-28|Doped polymer sheeting for covering hotbeds and greenhouses and method of fabrication of such US3896585A|1975-07-29|Furnace or thermal black in degradable agricultural mulch US4071975A|1978-02-07|Method of promoting the growth of plants FR2470781A1|1981-06-12|POLYETHYLENE SHEETS FOR COVERING TUNNEL-TYPE STRUCTURES USED IN AGRICULTURE IL43981A|1977-01-31|Polymeric mixtures for the preparation of films for use in agriculture US4651467A|1987-03-24|Method for protecting plants using polymeric film containing anhydrous borax US4170087A|1979-10-09|Method for growing plants or crops utilizing polyolefin covering material RU2429189C1|2011-09-20|Polymeric nanocomposition for protection from uv radiation JP3137893B2|2001-02-26|Photo-degradable green mulching film JPH07163247A|1995-06-27|Soil-covering material RU2067987C1|1996-10-20|Polymer film material for guarding of greenhouse and method for its production HIRANO et al.1995|Comparison of the Effects of Sheet Mulch on Improvement of Satsuma Mandarin Cultivation among Several Materials
同族专利:
公开号 | 公开日 US4075784A|1978-02-28| DE2638273C2|1988-05-19| NL186519C|1990-12-17| PT65508B|1978-02-15| IE43800L|1977-03-09| DE2638273A1|1977-03-24| GB1518016A|1978-07-19| JPS5232938A|1977-03-12| HU174494B|1980-01-28| BE845925A|1977-03-08| ES451349A1|1978-05-16| US4115347A|1978-09-19| NL186519B|1990-07-16| DK404976A|1977-03-10| LU75739A1|1977-06-15| NL7609735A|1977-03-11| DK152438B|1988-02-29| CA1075927A|1980-04-22| IE43800B1|1981-06-03| BR7605803A|1977-08-16| PT65508A|1976-09-01| DK152438C|1988-07-25| RO70764A|1981-06-26|
引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题 US1930939A|1931-07-29|1933-10-17|Horner Albert|Soil covering and method of use| FR1112597A|1954-10-16|1956-03-15|Saint Gobain|Shelters for crops| US3088244A|1959-12-23|1963-05-07|Nat Distillers Chem Corp|Protective cover| FR1399567A|1963-07-30|1965-05-21|Pechiney Progil Sa|Improvement in flexible plastic films for floor protection| US3326847A|1964-07-14|1967-06-20|Mobil Oil Corp|Dyeable polyolefins| DE1482274A1|1964-12-22|1969-07-03|Continental Gummi Werke Ag|Protection device for cultivated plants against the weather| US3353297A|1966-04-22|1967-11-21|Adrien C Gervais|Machine for laying a continuous protective sheet| FR1574088A|1968-04-16|1969-07-11| FR2036558A6|1968-04-16|1970-12-24|Ethylene Plastique Sa|Polyethylene or ethylen/vinyl acetate cop- - polymer sheets| FR2213954B2|1968-04-16|1976-08-27|Ethylene Plastique Sa| US3578629A|1968-05-21|1971-05-11|Monsanto Co|Process for preparing reinforced polyolefins| YU34314B|1968-07-05|1979-04-30|Montedison Spa|Process for preparing photoselective films from plastomers| US3592792A|1968-07-24|1971-07-13|Eastman Kodak Co|Agricultural plastic film| US3950303A|1974-03-11|1976-04-13|E. I. Du Pont De Nemours And Company|Polyolefin/chromium modified mineral compositions and process for their preparation|JPS5471147A|1977-11-18|1979-06-07|Mitsubishi Chem Ind Ltd|Film for agricultural application| FR2419955B1|1978-03-17|1981-11-13|Alcudia Empresa Ind Quimi| US4170087A|1978-03-17|1979-10-09|Alcudia, Empresa Para La Industria Quimica, S.A.|Method for growing plants or crops utilizing polyolefin covering material| US4266370A|1978-06-01|1981-05-12|Sekisui Kagaku Kogyo Kabushiki Kaisha|Agricultural covering film or sheet and method for thermal insulation| US4260534A|1979-02-08|1981-04-07|American Biltrite, Inc.|Asbestos-free vinyl floor tile composition and method for its manufacture| JPS625182B2|1979-05-15|1987-02-03|Sumitomo Chemical Co| US4490502A|1979-05-15|1984-12-25|Sumitomo Chemical Company, Limited|Agricultural plastic film| JPS625183B2|1979-05-15|1987-02-03|Sumitomo Chemical Co| US4250661A|1979-08-23|1981-02-17|Sekisui Kagaku Kogyo K.K.|Agricultural covering multilayer film or sheet structure and method for thermal insulation| IL62066A|1981-02-04|1984-10-31|Rami Bar|Polymeric films for agricultural use| JPH0148145B2|1982-01-27|1989-10-18|Sumitomo Chemical Co| JPS6231744B2|1983-11-12|1987-07-10|Kyowa Kagaku Kogyo Kk| US4651467A|1984-01-13|1987-03-24|Alcudia, Empresa Para La Industria Quimica, S.A.|Method for protecting plants using polymeric film containing anhydrous borax| JPH064727B2|1986-01-28|1994-01-19|水沢化学工業株式会社|Agricultural film| JP2932311B2|1990-10-03|1999-08-09|住化プラステック株式会社|Infrared absorbing film with excellent transparency| CA2197458A1|1995-06-23|1997-01-09|Kanemasa Takado|A novel hydroxide complex with condensed silicate, a process for its preparation, an infrared absorber and an agricultural film| ES2281109T3|1996-11-19|2007-09-16|Extenday Ip Limited|MATERIAL AND METHOD FOR TREATMENT OF PLANTS.| US20040088914A1|2002-08-05|2004-05-13|Warner Joel R.|Frost cover| JP2004359811A|2003-06-04|2004-12-24|Ceramission Kk|Composition having excellent heat-releasing and heat-shielding properties, and film| GB0505967D0|2005-03-23|2005-04-27|Imerys Minerals Ltd|Infrared absorbing polymer compositions and films| FR2917417B1|2007-06-13|2012-08-31|Commissariat Energie Atomique|USE OF A COMPOSITION COMPRISING A POLYMERIC MATRIX FOR NATURAL RADIATION COOLING AND WATER VAPOR CONDENSATION.| US20120129999A1|2008-11-14|2012-05-24|Boscia B Dillon|Nanocomposite including heat-treated clay and polymer| ES2729651T3|2010-10-25|2019-11-05|Imertech Sas|Expanded volcanic glass ground as a laminar filler| JP5938653B2|2012-05-11|2016-06-22|パナソニックIpマネジメント株式会社|Pest control lighting system|
法律状态:
优先权:
[返回顶部]
申请号 | 申请日 | 专利标题 US05/611,815|US4115347A|1975-09-09|1975-09-09|Polyolefin compositions| 相关专利
Sulfonates, polymers, resist compositions and patterning process
Washing machine
Washing machine
Device for fixture finishing and tension adjusting of membrane
Structure for Equipping Band in a Plane Cathode Ray Tube
Process for preparation of 7 alpha-carboxyl 9, 11-epoxy steroids and intermediates useful therein an
国家/地区
|