前苏联专利SU727153A3 Method of convertor reprocessing of high-phosphorus cast iron into steel

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专利摘要:
The invention relates to a method of refining pig iron, particularly with a high phosphorus component, in a bottom blown converter in which oxygen mixed with powdered lime is blown into the melt through the bottom of the converter. According to the invention the jets of oxygen mixed with suspended powdered lime blown into the melt through the bottom of the converter are protected by a surrounding sheath of a jacket gas which is preferably is inert or slow to react with the melt.
公开号:SU727153A3
申请号:SU691319455
申请日:1969-04-02
公开日:1980-04-05
发明作者:Кнюппель Хельмут；Бротцманн Карл；Фассбиндер Ханс-Георг
申请人:Максимилиансхютте М.Б.Х. (Фирма)；
IPC主号:

专利说明:

one
BACKGROUND OF THE INVENTION The invention relates to a feed mill of pig iron, in particular high phosphorus pig iron, in a converter.
Known repartition of pig iron with a high phosphorus content, carried out using the Thomas process or the developed method LDAC with the use of lime-rich slags. In the EDAS method, the smelting is blown with pure oxygen and lime dust from the top through a water-cooled tube, where the smelting consists of loading pig iron, scrap charge and part of the desired lime method IJ
In the process of conversion, the formation of ferrous oxide rich in iron and, consequently, of slag reactive in relation to the dephosphorization process, due to which, unlike the Thomas process, it is possible to carry out the dephosphorization at an earlier time, i.e. provide for the dephosphorization during decarburization. Although the ДАDAS method is increasingly replacing the traditional Thomas process, it is associated with a number of flaws. Thus, for example, oxygen is not directly introduced into the smelting, but indirectly through the slag, which leads to a high content of ferrous oxide in the slag and, in connection with this, to a high loss of iron, i.e. reduced performance. The high content of iron in the slag impairs the use of the sludge as a fertilizer, and, moreover, ferrous oxide-rich slag is prone to boiling, i.e. The high content of ferrous oxide in the slag and the relatively high content of carbon in the smelting, leads to a rapid release of iron and slag.
A further significant disadvantage of method IDAS is that a sufficiently low phosphorus content can only be achieved through two slags, which is due to the need to interrupt the process when the carbon content of 0.7 to 1% is reached and slag is removed. The slag from the first stage of the process, when the phosphorus content in the smelting is about 0.2%, is approximately 10% iron and 20% phosphoric acid. During the second stage of the process, a new slag is formed due to the further blown in of lime dust, with which the phosphorus content can be reduced to a value below 0.025%. The slag of the second stage of the process remains in the converter and is used for the supply with | e, pinch: it is loaded with its ;. At once, due to decarburization, the movement of the bath is dried up solely by the stream of oxygen and is therefore limited to a relatively non-excess surface and bathtub t Chromium. ;;: focal
1 .. K-; and; LOROD -.- Oy1 STRUCTURES:; -G: ax OUV 3etts significant xc-lucheelo iron, which not only worsens ETHOIZVODYTILA, but also leads to the formation of a large number of unsuitable brown.
The traditional thomas process, three of which air or air enriched with vCaopoflOM is blown into the smelt through Food in the bottom of the sopp converter, has both advantages and disadvantages compared to the LHC method. Advantages of Thomas: ggrotsessa. The fact that the hydrogen in the blast in front of the holes in the sulfur oxidizes the iron to the iron oxide and the latter in the oxygen carrier, removes the iron from the iron in the sequence of silicon, manganese, carbon and phosphorus with high efficiency. In this case, the total melting is thoroughly mixed by ballast nitrogen in the blast, so that. However, a high content (not less than 60%) of nitrogen in the blast leads to nitriding of sta-pi and. In addition, a significant1.1 heat loss is significant, so that scrap loading is relatively small. Excessive oxygen content in the blast is above 40%, however, is prohibited due to the resulting large amount of brown smoke and rapid wear of the building, even in the case of copper nozzle pipes. Another disadvantage of the Thomas process a is that phosphorus oxidation begins only at the end of decarburization, the so-called transition, and therefore numerous attempts have already been made to achieve an earlier onset of dephosphorization, the depophosphorization simultaneously with decarburization. This includes tests in which a test jet of a 50 kgr load of cast iron was injected with a lime with a lime lime through a copper plate in a water-cooled copper slab, too, about: a water nozzle 2 attached, although this test proved the usefulness of blowing lime dust to achieve an earlier onset of dephosphorization, they cannot be used for the manufacture of large hazards due to water cooling.
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In addition, this method due to the use of pure oxygen is associated with the extremely strong formation of brown .ma, which also prevents its use in practice. Finally, the supply of lime dust to the nozzles in a uniform distribution has not yet been possible, so that the Thomas process was limited to the use of oxygen-enriched
fi air and a known supply of lime through the throat of the converter.
The aim of the invention is to increase the 8th production: of the conversion process, in particular, high phosphorus pig iron.
5 and povshekie resistance of the bottom and nozzles.
This goal is achieved by the fact that bottom-blowing of oxygen and lime into the cast iron is carried out in a shell of a hydrocarbon gas. Suspension of oxygen and lime dust and gas jacket. it is also possible to blow in at an angle to the surface of the bath in order to achieve adequate circulation. This requires inclined nozzles, which allow the Edudu to penetrate the slag by means of a jet of combustible gas containing limestone dust when the converter is in the recumbent position. This modification of the proposed method turns out to be suitable, E. particular, when, in connection with extremely low contents. Neither fossil and low iron loss, the primary slag is removed after expiration. two-thirds of the purge time and then continue the process with increased addition of lime dust. Lime dust can be blown into the converter through all nozzles or through some nozzles you can apply clean
0 oxygen, and streams of pure oxygen to prevent the formation of brown smoke are also surrounded by a gas E. weight-shell.
You can be blown in during the wedding
5 also other suspensions of solids, for example, based on ore, fluorite, carbon dioxide or bauxite, by themselves or: s mud mixture with lime dust, which they or other influence
fi on the process
P; re / lag 1e -) ny method is carried out in an converter, the bottom of which is provided with at least one (preferably e. But several) nozzles consisting of two concentric tubes. The internal tube is used. For reaction, NO.H means, and external - for gas and - about the swamps.
The purging process is especially easy, without emissions, if you work with oxygen pressure ranging from 6 to 10 MPa and oxygen loading with lime dust from 1 to 2 kg.km3, and the tube diameter for the reaction means is not more than 1/35. bath height. Speed
the flow of oxygen from the jet is about 30% lower than the velocity of the jet of oxygen. As a result, for example, at a pressure of 8 ati, the transmitted amount of oxygen per cm of the nozzle cross-section is 200 nm / cm / hour with pure oxygen and decreases to approximately 130 with oxygen loaded with lime. If, for example, the converter has a capacity of 30 tons with a bath height of 0.7 m, the specific oxygen consumption is 60 nm per ton of steel and the desired sweep time of 20 minutes, the passed oxygen amount is 5400 nm per hour. The required cross section for blowing is 5400: 130 and 42 cm. In view of the fact that with a given bath height of 0.7 m, the maximum permissible nozzle diameter is 2 cm, 42/3 is required, nozzles. At the end of the conversion process, a mixture of 10–20% oxygen and 90–80% nitrogen can be additionally blown in order to remove nastiry on the nozzles.
The suspension of the reaction medium is introduced into the converter, for example, by means of a conical vessel located under the bottom of the converter with a tangentially inserted drive tube and at least one radially spaced at a distance from the drive tube and the concentric tube for the reaction medium. shell. A very uniform distribution of lime dust is achieved if the drive tube is inserted into the upper part of the tank, and several tubes for the reaction media located at the same distance from each other are withdrawn from the lower part of the tank.
An example of the method.
A 60-ton symmetric converter made in the form of a ball is used. It contains the lower conical part with a height of 2 m. a cylindrical middle part with a height of 1.50 m and an upper conical part with a height of 2 m. The internal diameter of the converter without refractory lining is 5.50 m. The thickness of the refractory lining and lower conical part is 70 cm, and in the cylindrical middle part is 55 cm. upper conical part - 50 cm
The internal capacity of the converter is 48 m, which corresponds to a specific capacity of 0 steel.
The bottom of the converter with a height of 1 m and a diameter of 3 m is equipped with 10 nozzles installed in the middle lane, located at a distance of 0, 3 m from the diameter parallel to the tilting axis of the converter.
The nozzles are made of two concentric tubes. In this case, the inner tube for oxygen has an inner diameter of 24 mm, and the width of the annular
The gap between the two pipes is 1 mm.
50 tons of pig iron with a temperature of 1330 ° С, containing 4.2% of carbon, 1% of silicon, 0.9% of manganese, 0.1% of phosphorus and 0.04% of sulfur, and 15 tons of scrap are loaded into the converter. During the loading process, nitrogen in the amount of 8000 is fed through the inner tubes and in the amount of 600 nm / h through annular gaps.
0
Immediately after the end of the loading process, the converter is turned into the vertical position of the freeze. From this point on, 17,000 HMV4 oxygen is supplied through the inner tubes together with powdered lime taken on average 1.2 kg / nm of oxygen.
340 propane (2 vol.% In terms of oxygen) is supplied through annular gaps. The process of freezing is completed after 11 minutes. A total of 3000 nm of oxygen is supplied to the melt together with 3,600 kg of powdered lime.
five
After the end of the freezing process, steel with a temperature of 1650 ° C, containing 0.04% carbon, O, 25% manganese, 0.008% phosphorus, 0.02% sulfur and 0.002% nitrogen, is obtained.
Slag contains 16% FeO. The yield of molten steel is 93.5%. The total duration of the process (loading and freezing) is 28 minutes.
No ejection during the freezing process.
five
The wear of the bottom and nozzles is 1.7 mm / load.
When used as a protective shell for other gases, such as argon, carbon dioxide and
0 nitrogen, bottom and nozzle wear is 14 mm / load, 16 mm / load, and 18 mm / load, respectively.
The duration of the process is 45.47 and 44 minutes, respectively. Slag emissions are observed.

权利要求:
Claims (4)
[1]
1. Method of converter redistribution of high-phosphorus iron p steel,
0 including a bottom oxygen flush with lime dust, characterized in that
in order to increase the productivity of the process and increase the bottom stability
5 and nozzles, the injection of oxygen with lime is carried out in a shell of a hydrocarbon gas.
[2]
2. The method according to claim 1, wherein the oxygen and oxygen in the shell of the hydrocarbon gas are blown at an angle to the surface of the bath.
[3]
3. The method according to claim 1-2, characterized in that
5 blown oxygen into the shell of the gas.
"G27D53 8
[4]
4. Sph: about 1 to 3, differ-1. Turkebaev E.A., Application
u and with the fact that in the process of re-oxygen in metallurgy, Alma-ata,
affairs in a stream of oxygen blow ore, 1964, p. 372-379. fluorite, soda or bauxite.
. Sources of information, 2. Archiv fur das Eisenhutten brought into account during the examination of Wesen, 1, 39, 1968, p. 1-8.

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同族专利:

公开号 | 公开日

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DE1909779A1|1971-02-04|

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引用文献:

公开号 | 申请日 | 公开日 | 申请人 | 专利标题

BE632141A|

DE494011C|1928-02-19|1930-03-17|Eisen Und Stahlwerk Hoesch A G|Wind freshening method and device in which fuels, ores, limestone or other additives in powder form, each for itself, are introduced separately into the wind duct from below through the converter base|

US2977108A|1958-04-10|1961-03-28|United States Steel Corp|Tuyere assembly for a bessemer converter|

US3079249A|1959-02-27|1963-02-26|Air Liquide|Method for refining iron using technically pure oygen|

NL296346A|1962-08-07|

FR1362355A|1963-07-09|1964-05-29|Siderurgie Fse Inst Rech|Wind box for blowing a wind loaded with powdery materials into a converter|

FR1450718A|1965-07-12|1966-06-24|Air Liquide|Improvements in metallurgical processes|

FR90233E|1966-06-27|1967-11-03|Air Liquide|Improvement in injectors, nozzles and burners for metallurgical furnaces|US4165980A|1972-01-13|1979-08-28|Gfe Gesellschaft Fur Elektrometallurgie Mit Beschrankter Haftung|Method of rapidly decarburizing ferro- alloys with oxygen|

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US3907549A|1972-08-29|1975-09-23|United States Steel Corp|Method of refining in improved Q-BOP vessel|

SU605549A3|1973-03-03|1978-04-30|Эйзенверк-Гезельшафт Максимилиансхютте Гмбх |Tuyere|

CA1014753A|1973-03-30|1977-08-02|Karl Brotzmann|Process for lowering the iron content in nickel melts|

DE2316768B2|1973-04-04|1977-03-03|Fried. Krupp Gmbh, 4300 Essen|PROCESS FOR REFRESHING METALS, IN PARTICULAR PIG IRON, AND DEVICE FOR CARRYING OUT THE PROCESS|

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SE395911B|1974-04-16|1977-08-29|Uddeholms Ab|TREATMENT OF METAL MELTS IN CERAMIC REQUIRED REACTION VESSEL|

US3954445A|1974-08-30|1976-05-04|United States Steel Corporation|Method of controlling temperature in Q-BOP|

US3985550A|1975-01-23|1976-10-12|United States Steel Corporation|Method of producing low sulfur steel|

GB1554104A|1975-07-23|1979-10-17|British Steel Corp|Refining liquid metal|

US3999978A|1975-09-29|1976-12-28|Nippon Steel Corporation|Method for making steel by the use of a flux treated by carbon dioxide|

US4065297A|1976-09-28|1977-12-27|Sumitomo Metal Industries Limited|Process for dephosphorizing molten pig iron|

GB1592786A|1976-10-19|1981-07-08|Usinor|Bottom blown metallurgical converter|

GR59290B|1977-10-29|1977-12-08|Larco Sa|Process for the production of nickel alloys|

DE2825851C2|1978-06-13|1980-08-21|Maximilianshuette Eisenwerk|

US4272286A|1978-07-17|1981-06-09|Pennsylvania Engineering Corporation|Metallurgical vessel|

US4334921A|1979-04-16|1982-06-15|Nippon Steel Corporation|Converter steelmaking process|

US4242126A|1979-07-11|1980-12-30|Skw Trostberg Aktiengesellschaft|Process for the treatment of iron melts and for increasing the scrap portion in the converter|

DE3164362D1|1980-03-05|1984-08-02|Creusot Loire|Process for the simultaneous and separate introduction of at least one gas and a pulverulent material by means of a tuyere for metallurgical purpose|

AU6823981A|1980-03-21|1981-10-15|Nippon Steel Corporation|Multi-stage steel making|

JPS6154841B2|1980-06-28|1986-11-25|Kawasaki Steel Co|

US4388113A|1980-09-26|1983-06-14|Nippon Steel Corporation|Method of preventing damage of an immersed tuyere of a decarburization furnace in steel making|

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法律状态:

优先权:

申请号 | 申请日 | 专利标题

DE19691909779|DE1909779C3|1969-02-27|Device for introducing solid particles suspended in the oxygen stream for a converter operated according to the jacket gas process|

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