• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    1442100 Phenolic antioxidants CIBA-GEIGY AG 6 Dec 1974 [10 Dec 1973] 52785/74 Heading C3P [Also in Division C2] Hydroxybenzyl malonic acid derivatives of the formula wherein X is oxygen or -NH-; Y is hydrogen, the radical O, (C 1 -C 12 ) alkyl; (C 3 or C 4 ) alkenyl, propargyl, benzyl or a group of the formula wherein R 6 is hydrogen, methyl or phenyl and R 7 is hydrogen or (C 1 -C 18 ) acyl; R 1 is a hydroxybenzyl group of the formula wherein R 3 and R 4 are (C 1 -C 8 ) alkyl, R 5 is hydrogen or methyl and if X is oxygen then R 2 is hydrogen or hydroxybenzyl of the above formula, or if X is -NH- then R 2 is hydrogen are stabilizers for polymers.
    公开号:SU708995A3
    申请号:SU742083824
    申请日:1974-12-09
    公开日:1980-01-05
    发明作者:Расбергер Михаель (Фрг)；Роди Жан (Швейцария)
    申请人:Циба-Гейги Аг (Фирма)；
    IPC主号:
    专利说明:

    Polymer 99-99 9 Hydroxybenzylmalonic acid ester 0.1-1; Compounds of structural formula (1) represent a molecular combination of both structures (1) and (2). In contrast to the mixture of antioxidant 1e and hydroxybenzylmalonic acid with a tetramethylpiperidine light stabilizer, the new compounds have a higher stabilizing effect, i.e. it is possible to use a smaller amount of stabilizer to achieve the same effect. K. stabilizers used according to the invention include, for example: bis (2, 2, b, 6-tetramethyl-4-piperidylnyl) ester, bis (3,5-di-tertiary butyl-4-hydroxybenzyl) -New acid, bis- (2,2, b, 6-tetramethyl 4-piperidinyl-1-oxyl) ester of bis- (3 tert-butyl 4-hydroxy-5-methylbenzyl) -malonic acid, bis- (2.2, b, 6-tetramethyl-4-piperidinyl-1-oxyl) 3,5-di-tert-butyl-4-hydroxybenzylmalonic acid ester. The compounds of formula (1) can be prepared by various methods. The most preferred method is that the malonic acid derivative of the formula CHjCHs CH2IO-X- (B - T) 2 (3) (JHjCHj if X is oxygen, is reacted with 1 or 2 moles, and if X is - NH-, then with one mole of N-dialkyl dithiocarbamine of the structural formula - 4) U or oxybekzylamine of the structural formula (5) in the presence of the main catalyst, moreover, in the above structural formulas X, V1I R have the previously mentioned values, -5 C atoms or both Rg together with the nitrogen atom form a morpholine piperidine and whether pyrrolidino ring. The starting materials of the structural formula (3) are the malonic acid esters or the malonic acid amides of 4-hydroxy- or, respectively, 4-amine tetramethylpiperidines. They are obtained, for example, by transesterification into an ester (using a base as a catalyst) diethylmalonate with 2 moles of 4-hydroxy or 4-amiotetramethylpiperidine. The compounds of structural formula (4) are obtained by reacting the phenol of the structural formula with formaldehyde, carbon disulfide and secondary amine (RQ) m. The reaction of the components of compounds (3) and (4) in the case of esters () can be carried out in a molar ratio of 1.: 1 or 1: 2. In the first case, monooxybenzyl compounds of structural formula (1) are formed, where RH is hydrogen; in the second case, di-oxybenzyl compounds of structural formula (1) are formed, where. In the case of amides (X - -NH-), the reaction ends in the first stage even when more than 1 mol of compound (4) is used, so that only the target products are formed, where Rg is hydrogen. For example, alkali metal hydroxides are suitable as basic catalysts. sodium or potassium hydroxide or alkaline earth metal alkoxides, alkali or alkaline earth metal hydrides and alkali metal amides. It is preferable to use alkali metal hydroxides in equimolar amounts, i.e. per 1 mole of dithiocarbaminate 1 mole equivalent of the base. The reaction is recommended to be carried out in solution in the case of using the initial components with a high melting point. Suitable solvents are, for example, methanol, ethanol, isopropanol or tertiary alcohols, butanol; aliphatic ethers or cyclic ethers like diethyl ether, tetrahydrofuran, dioxane; hydrocarbons like hexane, heptane, ligroin, decalin, cyclohexane, benzene, toluene or xylene, as well as polar aprotic solvents like dimethylformamide, dimethyl acetamide or dimethyl sulfoxide. The use of the latter group is recommended, first of all, when using malonic acid amides of the formula (3), where X means //N.M. In this case, the corresponding oxybenzylamines of the structural formula (5) can be used for dithiocarbaminates. In this case, it is possible to work with a dissolving solution. Lem or not, the listed solvents are applicable. The previously mentioned ones are also suitable as catalysts. It is preferable to use alkali metal amides and alkoxides in catalytic amounts, that is, e. 0.1-5 mol% The use of a larger amount of base does not give advantages. . Another method for preparing compounds of structural formula (1) is to react the malonic acid ester of structural formula (6) with 2 moles of a tetramethylpiperidine derivative of structural formula (7):; ({C001 9) 2H- 2NX - (1) + 2KeO R2 (6) Here Kf denotes an alkyl residue with 1-4 C. atoms. The following bases are applicable as a catalyst, the previously mentioned substances are used as a solvent, with the exception of alcohols. All the above reactions are carried out at elevated temperatures in order to accelerate them. and most full fate of the components. The products are produced by conventional methods, for example by evaporation and crystallization of the residue. It is advisable to neutralize the base before distilling off the solvent. The stabilizers can be introduced into the polymer melt after polymerization by methods used in the art, before or during molding, or deposited as dissolved or dispersed compounds on the polymer, followed by evaporation of the solvent. New compounds can be added to stabilized polymers and as a stock solution containing 2.5-25% by weight of these compounds.
     ("3) 4
    , Mr, Mr. 2NO- / Vdib -s-H-Klc Hsl.-f-yaOH
    CHD CHjBS
    (l /
    m
    {i H-Na $ d ($ l: s (CjH5) 2
    A table in the case of crosslinked polyethylene compounds is added before crosslinking. In addition to the compounds of structural formula (1), other known stabilizers or other additives used in plastics technology can be added to the polymers, for example, flame retardants, antistatic agents, softeners, pigments or fillers. The preparation and use of compounds of formula (1) is illustrated by examples. Parts and percentages are by weight, temperatures are given in degrees Celsius. ; Example 1, 12.3 g of 0.03 mol of bis (1,2,2,6, b-Pentamethyl-4-piperidinyl) -malonate and 19.5 g (0.06 mol) of N-diethyl-3- (3 methyl 5-tertiary, butyl-4-hydroxybenzyl) -dithiocarbaminate is dissolved in 100 ml of isopropanol. 2.4 g of sodium hydroxide are added dropwise (0.06 mol in 12 ml of water, stirring for 15 minutes at 60, then 2 hours. It is heated under reflux, cooled to 50, added, 72 ml of 1% - acetic acid and cooled to O. The product crystallizes out, which is recrystallized from ligroin; to obtain 18.7 g (85.7% of theoretical) bis (1,2,2,6,6-pentamethyl-4-aiperidinyl) complex bis- (3-methyl-5-tertiary butyl-4-hydroxybenzyl) -malonic acid ester, mp 150 °. Examples 2-5. In analogy to example 1, in each case 1 mol of malonic acid ester structure hydrochloric formula (Per) is reacted with 2 moles of N-Diethyl .pitiokarbamipata structural molding (4a) and 2 moles of sodium hydroxide, to give in Table 1 products.
    CH.
    Bis- (2,2,6,6-tetramethyl-4-piperidinyl) ester of bis- (3-methyl-5-tert-butyl-44-hydroxybenzyl) -malonic acid
    H
    t -
    PRI and, m. E r be 26 g (0.068 mol) of bis- (2,2,6,6-tetramethyl 4 piperidinyl) -malonate and. 17.8 g (0.068 mol) of N -. (3, 5-di-tertiary butyl-4-oxyben. Zil) -dimetilaglina are dissolved in 200 ml of toluene. 0.5 g of lithium amide is added, the mixture is heated under reflux for 3 hours. After cooling, it is neutralized with 1.5 ml of 1% acetic acid, the organic phase is washed several times with water. After drying with sodium sulfate, the solution is evaporated in vacuo to give the bis- (2.2, b, 6-tetramethyl-4-piperidinyl) complex as an oily residue,
    sn
    ABOUT :. N Bis (1,2,2,6, 6-pent, t - C 7-4-piperidinyl)
    SdNd Bis- (2,2,6,6-tetramethyl-4t NH-piperidinyl) -amide 3,5-diSN „
    NH
    Example 12. 24.5 g (0.076 mol) of dimethyl complex
    Continuation of table 1
    Bis- (2,2,6, b-tetramethyl-4-piperidinyl) ester of bis- (3,5-di-tert-butyl-4-hydroxybenzyl) -malonic acid
    3,5-di-tertiary butyl 4-hydroxybenzylmalonic acid ester.
    Example 7-11. Given in Table. 2, the products were prepared as in Example 5 by reacting in each case the malonic acid derivative of structural formula (3) with 1 mole of oxybenzylamine of structural formula (5a)
    (SNS) 5 (
    CH2-1G ((Nd) 2 (5a)
    table 2
    Bis (1,2,2,6,6 pentamethyl-4-piperidinyl) ester Z-methyl-5-tert-butyl-4-okoibenzylmalonic acid e-pentamethyl 3-di-tert-butyl hydroxybenzylmalonic acid ester
    253 tert-butyl-4-hydroxybenzyl-malonic acid
    200
    Vis- (2, 2,6,6 tetramethyl-4-4-piperidinyl) -amide 3-methyl-5-tert-butyl-4-hydroxybenzylmalonic acid
    3,5-di-iso-propyl-4-hydroxyben65 ester of zilmaloic acid and 23.8 g of Butyl-ff residue
    (0.15 mol) of 4-OXY-2/2, with ..6-tetrameuylpiperidine, is dissolved in 40 ml of α-xylene. By stirring it P when heated to 125-. the solution is added with 0.2 g of lithium amide, then heated under reflux for 2 hours. After cooling to about 50, it is neutralized with 1% acetic acid (0.8 ml), the organic phase is washed with water, dried over sodium sulfate. After evaporation in vacuo, a bis (2,2, 6,6-tetramethyl-4-piperidinyl) ester of 3 5-di-isopropyl-4-rxibenzylmalonic acid, m.p. 123 °,
    Example 13, 100 parts of polypropylene (melt index 3.2 g / 10 min
    Example 14. 100h. polypropylene (melt index 3.2 g / 10 min, 230С / 2160 g) for 10 min is intensively mixed in a vibratory apparatus with 40 0.1 h of one of the table below, 4 additives and 0.3 h of dilauryl thiodiropionate.
    The resulting mixture 10 minutes process when in plastograph Braben 5
    Stabilizer 1 pp "gannye in PRE", p2 s about raz1: ""
    230 ° / 21bOg) 10 minutes are intensively mixed in a vibrating device with 0.2 parts of one of the above, 3 additives. The resulting mixture is treated for 10 minutes at 200 ° in a Brabender plastograph, the processed mass is pressed, in a floor press at a temperature of 260 ° plates, to obtain plates with a thickness of 1 mm, from which strips of 1 cm wide and 17 cm long are stamped.
    Thermal aging test of the strips was carried out in an air circulating drying oven at 135 and 149, and an additive-free strip was used as a control.
    5 The test is completed when the test strip is easily dispersed.
    Table 3
    Dera, then pressed in a floor press at a temperature of iibO plates, npjaycha plates of 1 mgl thickness, from which strips 1 cm wide and 17 cm wide are punched. Tests are performed by thermostating in an air circulation oven at and 149. As a control A sample (band) containing only 0.3 h of dilauryl thiodipropionate is used.
    Table
    The number of days before the decomposition begins, stability, after the addition. ,,, o,.,: Pos.e 500 .. ool .. ™ „.
    In the device of the company Hanau, after treating with boiling water for 1 week.
    For table. 5, an empirical scale of color tones was used, in accordance with Example 16, 100 parts of polypropylene (melting index 19 g / 10 min. 230/2160 g) 10 min was intensively mixed in a vibrator with 0.1 h of the stabilizer obtained in Example 4 or 6. The mixture is processed in a laboratory single-screw extruder (PEamvo) at a temperature of mouthpieces, a screw rotation speed of 100 rpm and a productivity of 5 U g / min, followed by granulation,
    The granulate is treated in a spinning device at a temperature of the spinnerets and polyfilament yarns are obtained, which are then stretched in a ratio of 1: 5.5.
    Filament yarns exposed to butane flue gas
    Without a stabilizer. Example 18. Of the test plates 1 mm thick described in example 14, microtomes are obtained with a chip thickness of 25 microns, which is clamped between grids of
    According to which 5 is colorless, 4 is hardly noticeable color, 3, 2 and 1 is a consistently increasing color intensity.
    Table
    burners at for 24 hours
    The color score, by eye in both cases, shows that the test samples remained colorless.
    Example 17. Of the test plates 1 mm thick described in Example 13, microtomes are obtained with chips of 25 microns thick, which are clamped into stainless steel grids. The samples thus obtained on the substrate are suspended in an air circulation oven and subjected to testing aging at 135 and 147c. The test is completed when, with light blows on the gratings, scattered polypropylene (in the form of a powder) falls out, testing is carried out once or twice a day. The test results are shown in Table. 6. Tablata
    of stainless steel. Further, the tests were carried out as in Example 17.
    The test results are shown in Table. 7
    -Table 7
    Stabilizer as in Example No. Example 19. 100 parts of powdered polypropylene (MorEep, Pibre grade, Won tedifton). For H8 hours, they are homogenized in Branto tenderider at 0.2 h, octadecyl ester b (3, 5-di-tertiary butyl-4-hydroxyphenyl) -propionic acid and. 0.25 parts of one of the stabilizers listed in table. 8. The resulting mass is discharged as quickly as possible from the plastic of the raff and pressed in a crank-to-lever press, obtaining a plate with a thickness of 2-3 mm. A piece is cut out of the plate, which is pressed using a manual hydraulic laboratory press, placing the sample between two foils of solid aluminum of specular gloss, 6 minutes at 260 ° C, a pressure of 12 tons. Plenary primer 20, 100 parts of polystyrene granulate is obtained in dry form and mixed with 0.25 parts of stabilizer (see Table 9), re-granulated in an extruder, then 2 mm thick plates are prepared using an injection molding device. These plates for 2000 h are exposed to radiation in the Xeno device, the Stabilizer of the example,
    Without stabilizer
    Continuation of table 7
    Hours before decomposition begins
    furnace temperature
    at 147 ° C
    at
    Spreadsheets
    eight
    test 150, then determining the yellowing coefficient of the Kn according to the formula., uTC420) - & TU80) .- ..
    t T f 5601. where LT is the transmission loss at
    irradiation with radiation with a vapna length of 420 or 680 nm; T (560) - the value of the transmission,%, of the unirradiated sample at 560 nm.
    blitz 9
    TO,
    20.0
    4.5 1 6
    . 5.5 ku 0.5 mm thick, which is immediately abruptly cooled with water. Under the same conditions, a film with a thickness of 0.1 mm is made from this film, from which segments are sized with dimensions of 60 X 40 mm, the segments are tested in a Xenotest 150 device. At equal intervals of time, the test samples are unloaded from the irradiating device and subjected to carbonyl testing in the IR spectrum. An increase in carbonyl extinction is a measure of the photo-oxidative destruction of polymers, indicating a deterioration in the mechanical strength of the polymer. Thus, for example, upon reaching a carbonyl extinction of about 0.300, the film becomes completely brittle.
    Example 21. 100 g of a copolymer of acrylonitrile-butadiene-styrene (Dow AbC 500) are mixed with 0.2 g of 3,5-di-tert-butyl-4-hydroxytoluene and 0.3 g of tris (p-noni} tphenyl) phosphate as antioxidants and with 1 g of a light bridge abilizer (see, Table 10) and molded into granules in an extruder. The granulate in the injection molding machine is processed into sticks of 120 x 15 x 10 mm. The sample sticks are irradiated at Xenotest 450 and periodically their impact strength is measured according to DIN 53453. Table. 10 shows the irradiation period T, after which the impact strength decreases from 100 to. 20 kgf / cm.
    Table 10
    Stabilizer
    Tf h
    Example 22. To a solution of 250 g of polyurethane based on polyester complex (Estane 5707, Goodrich Kem, Co.)
    in 750 g of dimethylformamide-added -; are 1.25 g of bis- (2,2,6,6-tetramethyl) without stabilizer
    le
    f t (JO0, 15% J
    example 2)
    CH2-- (- (500СНз
    (connection from the calculations of the Federal Republic of Germany 1 643 393).
    And 0.075% i "3
    CHj-CO-0- / 1Г-С Hj
    Syznz
    connection from the patent of Germany 2 204 659)
    -4-piperidinyl) ester of bis- (3,5-di-tert-butyl-4-ox: ibenzyl) -malonic acid (example 5) as a light stabilizer. Using a film making apparatus, the solution is applied to glass plates with a thickness of about 500 microns. After drying in the drying cabinet before the films are removed, they are 6.0-70 microns thick and contain about 0.5% light stabilizer. The films were irradiated at Xenotest 1200 and periodically examined for their tensile and tensile strength. After 620 hours of irradiation, the stretch is 50% of the TI value, while the unstable film has the same stretch after 90 hours,
    . Example 23 Polypropylene yarns (polyfilaments) were made and stretched as described in Example 16, with the additions shown in Table 2 below. 1, stabilizers. The fiber is irradiated at Xenotest 1200 and its tensile strength is periodically measured. The measure of light fastness is the hours of irradiation to a decrease in strength by 50% from the initial value.
    After this, the fibers in the furnace are heated to. The measure of heat resistance is days to noticeable brittleness of the fibers.
    Table 11
    41
    725
    650
    From this table, it follows that the proposed polymer composition has a significantly better thermal stability, as well as slightly better light resistance than a mixture of hydroxybenyl malonate and pentamethylpiperidinol ether.
    Invention Formula
    A polymer composition comprising a polymer selected from the group consisting of polypropylene, polystyrene, acrylonitrile-butadiene-styrene copolymer and polyester-based polyurethane, and a stabilizer, which has a tl-ischamda, in order to increase the resistance to aging, it contains oxybenzylmalonic ester stabilizer
    acids of general formula
    cttj guide
    where X is oxygen or -NH-; 5 5Hj
    Y is hydrogen, -O or methyl;
     hydroxybenzyl formula
    V
    HO-L-CH2 (2)
    "I
    where 3 is tert-butyl;
    AND:
    methyl or tert-butyl if X is oxygen, water or oxybenzyl of the formula
    0 (2), and if X is —HH-, then only hydrogen,
    in the following ratio, wt.%:
    Polymer99-99.9
    Ester of benzylmalonic acid hydroxy5 0,1-1.
    Sources of information taken into account in the examination
    1, laid out for Germany
    0 №1643393, 124-31 / 02, published, 1970.
    2. The patent of FRG 2204659,
    cl. From 08 to 5/34, published 1973 (prototype).
    权利要求:
    Claims (1)
    [1]
    The invention is a polymer composition comprising a polymer selected from the group consisting of polypropylene, polystyrene, acrylonitrile-butadiene-styrene copolymer and a polyester based polyurethane, and a stabilizer, o t10 characterized in that, in order to increase resistance to aging, it contains as a stabilizer, an oxybeneylmalonic acid ester where X is of the general formula h
    .-) oxygen OR
    Y is hydrogen, a radical —O or methyl;
    where RJ is tert-butyl;
    Cd is methyl or tert-butyl;
    Rg - if X is oxygen, - hydrogen or oxybenzyl of the formula (2), and if X means -NH-, then only hydrogen, in the following ratio of components, wt.%:
    Polymer 99-99.9
    Oxybenzylmalonic acid ester 0.1-1.
    类似技术:
    公开号 | 公开日 | 专利标题
    SU708995A3|1980-01-05|Polymeric composition
    DE2661090C2|1990-02-08|
    US4335242A|1982-06-15|Triazine derivatives
    US4308362A|1981-12-29|Copolymers of substituted piperidines, their manufacture and use
    GB2042562A|1980-09-24|Stabilising polymers
    US3542729A|1970-11-24|Stabilization of synthetic polymers
    US4210576A|1980-07-01|Stabilizers for polymers and polymers stabilized thereby
    US4246198A|1981-01-20|Hindered phenolic amides
    DE4001397A1|1990-07-26|STABILIZERS FOR POLYMERE MATERIALS
    US4279804A|1981-07-21|Piperidine compounds and their use as stabilizers for synthetic polymers
    KR19990030237A|1999-04-26|Stabilizer mixture for organic materials
    SU544384A3|1977-01-25|Polymer composition
    KR100533188B1|2006-01-09|Compounds on the basis of polyalkyl-1-oxa-diazaspirodecane compounds, a process for preparing the same and the use of the same
    US4316837A|1982-02-23|Polyalkylated 4-aminopiperidine derivatives as stabilizers for synthetic polymers
    US4340533A|1982-07-20|Novel stabilizers
    US4197236A|1980-04-08|Piperidine stabilizers
    US4785107A|1988-11-15|3-tert-butyl-4-hydroxyphenylpropionic acid amino-alkylamide derivatives
    JP2622729B2|1997-06-18|Polymer material composition with improved light fastness
    SK20498A3|1998-09-09|Use of piperidine compounds
    US4239891A|1980-12-16|Substituted piperidine hydroxamides, their preparation, and their use as light stabilizers
    US4033957A|1977-07-05|Triazine derivatives as stabilizers for organic materials
    US4293466A|1981-10-06|Piperidine phosphite stabilizers for polymers and polymers stabilized thereby
    US3745163A|1973-07-10|2,2,6,6-tetramethyl piperidinyl-4-|hydrazones
    US4451400A|1984-05-29|Phosphazenes useful as stabilizers in polymers
    DE19713158A1|1997-10-02|Polyalkylpiperidinyloxy or polyalkylpiperidinylamino-containing polytriazine derivatives
    同族专利:
    公开号 | 公开日
    DE2456864C2|1989-03-09|
    ES432713A1|1976-12-16|
    FR2253742B1|1976-10-22|
    BE823114A|1975-06-09|
    US3993655A|1976-11-23|
    IL46203D0|1975-03-13|
    AR204430A1|1976-02-06|
    BR7410269A|1976-06-29|
    SE7413720L|1975-06-11|
    ZA747815B|1975-12-31|
    AU7619474A|1976-06-10|
    GB1442100A|1976-07-07|
    US4221701A|1980-09-09|
    JPS5817500B2|1983-04-07|
    DE2456864A1|1975-06-12|
    FR2253742A1|1975-07-04|
    JPS50116529A|1975-09-11|
    NL7416065A|1975-06-12|
    IT1026868B|1978-10-20|
    ATA982174A|1975-11-15|
    CA1032946A|1978-06-13|
    CH589056A5|1977-06-30|
    AT331522B|1976-08-25|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    US3721704A|1967-02-17|1973-03-20|Geigy Chem Corp|Esters of malonic acid and related compounds|
    US3640928A|1968-06-12|1972-02-08|Sankyo Co|Stabilization of synthetic polymers|
    NL154241C|1971-01-29|1900-01-01|
    GB1376438A|1971-11-30|1974-12-04|Ciba Geigy Ag|Piperidine derivatives|
    BE792043A|1971-11-30|1973-05-29|Ciba Geigy|PIPERIDINE DERIVATIVES USED TO STABILIZE ORGANIC MATERIALS|
    US3992390A|1971-11-30|1976-11-16|Brian Holt|Esters of piperidinols|US4110305A|1971-11-30|1978-08-29|Ciba-Geigy Corporation|Polymers stabilized by esters of piperidinols|
    US4052361A|1974-12-30|1977-10-04|American Cyanamid Company|N--4-piperidinyl)-amides of hindered 3,5-dialkyl-4-hydroxybenzoic acids and use as light stabilizers in polyolefins|
    GB1496844A|1975-05-28|1978-01-05|Ciba Geigy Ag|Stabilization of polymers|
    US4202816A|1975-06-19|1980-05-13|Ciba-Geigy Corporation|Novel light stabilizers|
    DE2647452C2|1975-11-07|1991-08-08|Ciba-Geigy Ag, Basel, Ch|
    CH601232A5|1975-12-08|1978-06-30|Ciba Geigy Ag|
    DE2656769A1|1975-12-29|1977-07-14|Ciba Geigy Ag|NEW PHENOL STABILIZERS|
    US4260537A|1976-02-12|1981-04-07|Mobay Chemical Corporation|Stabilized polycarbonate compositions|
    US4197236A|1976-04-28|1980-04-08|Ciba-Geigy Corporation|Piperidine stabilizers|
    DE2717087A1|1976-04-28|1977-11-10|Ciba Geigy Ag|NEW STABILIZERS|
    DE2718458C2|1976-05-04|1989-09-14|Ciba-Geigy Ag, Basel, Ch|
    JPS5645432B2|1976-07-12|1981-10-26|
    DE2755340A1|1976-12-23|1978-06-29|Ciba Geigy Ag|NEW POLYALKYLPIPERIDE DERIVATIVES|
    JPS6332784B2|1977-05-18|1988-07-01|Sankyo Kk|
    JPS6332782B2|1977-08-08|1988-07-01|Sankyo Kk|
    EP0002260B1|1977-12-02|1982-07-14|Ciba-Geigy Ag|Malonic acid derivatives of sterically hindered piperidines, process for their preparation and stabilised organic matter|
    US4164480A|1978-01-09|1979-08-14|Eastman Kodak Company|Polychromophoric ultraviolet stabilizers and their use in organic compositions|
    US4185003A|1978-02-16|1980-01-22|E. I. Du Pont De Nemours And Company|Stabilized copolyetheresters|
    DE2962873D1|1978-04-14|1982-07-08|Ciba Geigy Ag|Aminodibenzoxaphosphorines, process for their preparation and their use as stabilisators|
    DE2960925D1|1978-05-18|1981-12-17|Ciba Geigy Ag|Dioxaphosphepines, their preparation and use as stabilisers for organic materials|
    US4279720A|1978-07-13|1981-07-21|Ciba-Geigy Corporation|Photocurable composition|
    IT1110826B|1979-02-01|1986-01-06|Montedison Spa|N-ALCHIL-PIPERIDIN DERIVATIVES OF HYDROXY-BENZYL MALONIC ACID AND THEIR USE AS POLYMER STABILIZERS|
    DE2913853C2|1979-04-06|1989-04-13|Roehm Gmbh, 6100 Darmstadt, De|
    US4322527A|1979-05-15|1982-03-30|Ciba-Geigy Corporation|6-Amino-dibenz[d,g][1,3,2]dioxaphosphocines|
    US4377651A|1979-10-05|1983-03-22|Phillips Petroleum Company|Polyolefin stabilization|
    IT1193839B|1979-11-06|1988-08-24|Montedison Spa|N, N-DI-ALCANOL-AMINE POLYESTERS WITH MALONIC DI-ACIDS AND THEIR USE AS POLYMER STABILIZERS|
    WO1981002021A1|1980-01-14|1981-07-23|Gen Electric|Stabilization of polyphenylene ether-compositions by tetrasubstituted piperidines|
    US4402983A|1980-09-19|1983-09-06|E. I. Du Pont De Nemours & Co.|Powder coating composition for automotive topcoat|
    EP0112802B1|1982-12-16|1988-01-07|Ciba-Geigy Ag|Colour-photographic recording material|
    US4487870A|1982-12-27|1984-12-11|Exxon Research & Engineering Co.|UV Stabilizer system and UV stabilized polyolefins|
    US4751272A|1986-05-01|1988-06-14|Toray Industries, Inc.|Process for producing oxymethylene copolymer and resinous composition|
    US4874391A|1986-07-29|1989-10-17|Ciba-Geigy Corporation|Process for photochemical stabilization of polyamide fiber material and mixtures thereof with other fibers: water-soluble copper complex dye and light-stabilizer|
    AT102666T|1988-06-14|1994-03-15|Ciba Geigy Ag|METHOD FOR PHOTOCHEMICALLY STABILIZING UNCOLORED AND COLORED POLYPROPYLENE FIBERS.|
    US4892784A|1988-07-27|1990-01-09|Kimberly-Clark Corporation|Surface treatment for inhibiting thermal oxidation of polypropylene fabrics|
    US5030243A|1989-01-05|1991-07-09|Ciba-Geigy Corporation|Process for the photochemical stabilization of undyed and dyeable artificial leather with a sterically hindered amine|
    US5932640A|1989-01-21|1999-08-03|Clariant FinanceLimited|Dyeability or mass coloration of synthetic polyamide|
    US5015683A|1989-03-21|1991-05-14|Ciba-Geigy Corporation|Bis-amine derivatives and stabilized compositions|
    EP0409771A3|1989-06-27|1991-06-12|Ciba-Geigy Ag|Process of photochemical and thermal stabilization of polyamide fibres, dyeable by acid and basic dyes, and of their mixtures amongst themselves and with other fibres|
    IT1247974B|1991-06-04|1995-01-05|Sigma Prod Chim|PIPERIDINE DERIVATIVES, THEIR PREPARATION AND USE|
    DE19545634A1|1995-12-07|1997-06-12|Bayer Ag|Solid-rich binder combinations|
    WO1997031964A1|1996-02-29|1997-09-04|Synthopol Chemie Dr. Rer. Pol. Koch Gmbh & Co. Kg|Novel polyester polyols and their use as the polyol component in two-component polyurethane paints|
    TWI224995B|1998-03-19|2004-12-11|Ciba Sc Holding Ag|Stabilization of wood substrates|
    DE19955129A1|1999-11-17|2001-05-23|Bayer Ag|New, high-solids binder combinations and their use|
    DE10322620A1|2003-05-20|2004-12-16|Bayer Materialscience Ag|High-solids binder combinations for scratch-resistant top coats|
    US20050137322A1|2003-12-17|2005-06-23|Roesler Richard R.|Silane modified two-component polyurethane coating|
    DE102004056849A1|2004-11-25|2006-06-08|Bayer Materialscience Ag|New polyisocyanate mixtures, a process for their preparation and their use as hardener component in polyurethane coatings|
    CN101160348B|2005-04-18|2010-12-08|柯尼卡美能达精密光学株式会社|Cellulose ester film, manufacturing method thereof, optical film, polarizing plate and liquid crystal display|
    UA91243C2|2005-11-10|2010-07-12|Ппг Б.В.|Metal substrate with epoxy based coating, process of coating, two layer coating system and use|
    ITMI20080739A1|2008-04-23|2009-10-24|3V Sigma Spa|STERICALLY PREVENTED OLIGOMERIC STAKES AND THEIR USE AS STABILIZERS FOR POLYMERS|
    ITMI20080747A1|2008-04-24|2009-10-25|3V Sigma Spa|MIXTURES OF STERICALLY PREVENTED AMINES FOR THE STABILIZATION OF POLYMERS|
    IT1399477B1|2010-03-15|2013-04-19|3V Sigma Spa|MIXTURES OF STERICALLY PREVENTED AMINES FOR THE STABILIZATION OF POLYMERS|
    ITMI20110802A1|2011-05-10|2012-11-11|3V Sigma Spa|MIXTURES OF STERICALLY PREVENTED AMINES FOR THE STABILIZATION OF POLYMERS|
    IT201700073726A1|2017-06-30|2018-12-30|3V Sigma Spa|IMPEDITE POLYMERIC AMINS|
    IT201700078234A1|2017-07-11|2019-01-11|3V Sigma Spa|IMPEDINE MINES|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    CH1727173A|CH589056A5|1973-12-10|1973-12-10|
    [返回顶部]