Product for smoking

专利摘要:

公开号:SU1837815A3
申请号:SU914894831
申请日:1991-02-26
公开日:1993-08-30
发明作者:Frenklin Klirman Dzhek；Dzhik-Geng Chiou Dzhozef；Din Villyams Darrel；Dzhejms Kejsi Villyam；Liroj Dzhentri Tomas；Kempbell Skvajers Villyam；Tajron Konner Billi
申请人:Reynolds Tobacco Co R；
IPC主号:

专利说明:

The invention relates to articles for the day, such as cigarettes, and in particular to such articles for smoking, which have a heat source and are physically separated from the oil, forming an aerosol.
The present invention relates to cigarettes and other products for smoking> 1e comprising a fuel cell (i.e. a heat source) disposed interconnected by heat exchange with a physically separated means. In the most preferred product for smoking, the composition and configuration of the top / wives is to use the heat generated by this fuel cell. Essentially, in preference | the proportion of heat produced by the burning chicken aerosol-forming element of the willow element, as well as the molten-fuel element inside the product, are such that a highly fuel-efficient smoking product is transferred by the aerosol-forming means to create an aerosol. The smoking articles of the present invention also include some form of tobacco.
In one case, the preferred smoking article according to the present invention includes (!) A extruded combustible fuel element or heat source located inside the smoking article so that the extrusion axis of the fuel element is substantially perpendicular to the longitudinal axis of the smoking article, (I) physically separated azrosol forming agents comprising at least one aerosol forming material, and (iii) means for securing, holding or supporting the fuel cell inside the chicken article Niya.
Alternatively, a preferred smoking article according to the present.
1837815 AZ of the invention includes (I) a longitudinally divided combustible fuel element, (II) physically separated aerosol forming agents comprising at least one aerosol forming material, (III) means for securing, holding or supporting the fuel element inside smoking articles, and (IV) means for enclosing at least a portion of the longitudinal periphery of the fuel cell so as to limit the amount of atmospheric. oxygen that comes into contact with the fuel cell when the fuel cell burns during use (i.e., the fencing element). Typically, a fencing element is capable of transferring heat from a burning fuel cell to aerosol forming means.
A smoking article, in one case, includes a short, preferably carbon-containing, combustible "fuel" element or heat source. Typically, the fuel cell has a longitudinally divided structure such that only a portion or part of its length is intended to be burned, and a segment or portion of its length serves as a base that allows the fuel cell to be secured in place within the smoking article. A preferred fuel cell includes an insulating section or a portion located between its combustion portions and the base. A preferred isolation segment has both a peripheral periphery and a cross-sectional area that is smaller than the base area. The preferred insulating portion has a cross-sectional area, and in some circumstances, a peripheral cross-section that is less than the corresponding values of the burning section.
A typical fuel cell has a total length, before combustion, of less than about 20 mm, and a length of a section for combustion, of less than about 15 mm. Preferred fuel cells are designed to separate the continuous extrudate into lengths and are used so that the axis of extrusion of the fuel cell is substantially perpendicular to the longitudinal axis of the smoking article into which the fuel cell is inserted.
With respect to some features of the present invention, the fuel cell includes at least one hollow space extending through it in a direction transverse to the longitudinal axis of the smoking article into which the fuel cell is included. According to other features of the present invention, the fuel cell includes at least one channel for air flow (for example, at least one hollow space) elongated through it in a direction parallel to the longitudinal axis of the smoking article into which the fuel cell is included, and the channel for the passage of air flow can pass through the Central region of the fuel cell and / or in the form of grooves along the periphery of the fuel cell.
The smoking article includes holding means for holding the fuel cell in position within it. The restraining means are in contact with the fuel cell and fasten. This fuel cell is in the right position inside the smoking article. According to one preferred embodiment, the retaining element occupies the base of the fuel element, thus serving to hold the fuel element securely. in place, According to another preferred embodiment, the retaining means is provided with fibrous material, scrap (for example, fiberglass or a tobacco filler / fiberglass mixture), assembled together or crushed cigarette baking paper, assembled together or crushed charcoal paper or chopped tobacco filler, which contacts the longitudinal periphery of the fuel element over a considerable length, and the structure of the fuel element divided into sections in the longitudinal direction in combination with ntaktom bounding material with the longitudinal periphery of fuel element ensures retention of the fuel element securely in place within the fibrous material, paper or tobacco cut filler.
A smoking article includes an aerosol forming agent; physically separated from the fuel cell and longitudinally disposed therein. The aerosol forming agent includes a substrate and at least one aerosol forming material. Preferred aerosol forming agents include aerosol forming material, such as some kind of tobacco (e.g. compressed tobacco granules, tobacco extract or tobacco dust) and other aerosol forming materials (e.g. glycerin and / or tobacco flavoring agents, such as cocoa, liquorice and various types of sugar) a). The aerosol forming material is usually found on a carrier such as collection paper, assembled pack paper for I cigarettes or a heat-resistant carrier such as alumina beads). When but: an object is material of type umagi, it is highly preferred that such a carrier be> positioned at intervals relative to the top element.
A smoking article, for one feature, includes a fencing element, which is preferably a heat-conducting element for transferring heat generated by the burning part of the fuel element, and an aerosol forming agent. Essentially, the conductive element is in relation to heat transfer, and is preferably in the relationship of heat transfer to thermal conductivity, with the carrier on which the aero3 | ol-forming material is located. The fencing element is radially placed with a gap relative to the longitudinal periphery of the fuel element. Typically, the fence element is in contact with (I) a portion of the aerosol forming agent, and (II) often the holding element. Preferably, the fencing element is radially P n cl n • offset with a clearance relative to the longitudinal periphery of the outer periphery of the fuel element; at least part of the length of the burning portion of the fuel cell, and ί is in contact with the aerosol by an L-forming agent. In essence, the fuel element and the fencing element form an air flow passage channel, and the air drawn through this channel heats up.
The fuel cell is thermally insulated from other areas or components of the smoking article. By this we mean that the burning section of the fuel elite is controlled by heat (i.e. heat removal), in particular as a result of heat transfer by heat conduction to other areas or components for smoking. Thermal tf Μι
Tdi ^T H insulation of a fuel cell is desirable, in particular during periods of smoldering fire, when the smoking article does not experience a tightening effect so that the fuel cell does not go out on its own as a result of heat dissipation to other parts of the smoking article.
I A preferred smoking article contains a mouthpiece for delivering an aerosol to a smoker's mouth. Typically, the mouthpiece has a common tubular shape and contains a roll of tobacco chopped filler and a filter element.
In this case, the expression aerosol is used in the sense that it includes vapors, gases, particles and the like, both visible and invisible, and in particular components perceived by the smoker as smoke-like, generated by the heat generated by the fuel cell on the materials contained inside an aerosol forming agent or elsewhere in a smoking article.
When used in this case, the expression carbon-containing refers to containing carbon.
1, a longitudinal sectional view of a cigarette according to the present invention is shown; in FIG. 2 is a longitudinal sectional view of the cigarette of FIG. 1, but rotated 90 ° around the longitudinal axis of the cigarette; in FIG. 3 is a radial cross-sectional view of the cigarette shown in FIG. 1 taken along lines 3-3 of FIG. 1; in FIG. 4 is an exploded perspective view of an unassembled fuel cell and components of the cigarette holding member shown in FIG. 1 and 2; in FIG. 5 is a perspective view of an assembled fuel cell and components of a holding member of a cigarette shown in FIG. 1 and 2; FIG. 6 is a longitudinal sectional view of a cigarette according to the present invention; in FIG. 7 is a longitudinal sectional view of the cigarette of FIG. 6, but rotated 90 ° relative to the longitudinal axis of the cigarette; FIG. 8 is a longitudinal sectional view of a cigarette according to the present invention; in FIG. 9 is a radial cross-sectional view of the cigarette shown in FIG. 8 taken along lines 9-9 of FIG. 8; in figures 10-15 are longitudinal views of an exemplary fuel cell for cigarettes according to the present invention.
According to FIG. 1 and 2, an embodiment of the present invention is in the form of a cigarette 8. The cigarette includes a heat source or a fuel cell 10, a carrier 13 that carries an aerosol forming material and which is located behind the fuel cell, a fencing element 17 that encloses the carrier and radially has a gap around the longitudinal periphery of the fuel element, a holding element 23 that holds the fuel element securely in place inside the cigarette, and a tubular mouthpiece 28. A typical cigarette has a generally circular cross section a cross section and a circumference of about 20 mm to about mm, and a length of about 70 mm to about 100 mm.
The heat source of the fuel cell 10, which is preferably an extruded carbon-containing material, has a generally square or rectangular cross-sectional shape. A preferred fuel cell is a segmented fuel cell that includes three longitudinally spaced sections or segments (as shown in FIG. 1), a burning section 30 located near the extreme burning end 31 of the cigarette, a base or carrier section 32 on the opposite side the end (i.e., from the side of the mouth) of the fuel cell, and an insulating portion 33 located between the burning portion and the base. The fuel cell 10 is shaped so that (I) the periphery of the cross section of the base portion 32 is larger than the peripheral cross section of the insulating portion, and (II) the insulating portion includes at least one hollow space 35. that extends laterally through the fuel cell. The hollow space acts to reduce the cross-sectional area of the insulating section and · essentially acts to minimize heat conduction from the burning section 30 to the base section 33. In particular, the ncyioe space 35 acts to help in (I) ensuring separation of the combustion sections and the base (II) providing a selected length by which the fuel cell efficiently burns, and (111) ^ minimizing the heat conductivity from the burning portion of the fuel cell through the base portion of the fuel cell to other areas of the cigarette. The fuel cell 10 includes possible ribbed grooves 37, 38 elongated across the front surface of its burning part. Grooves 37. 38 help improve the ease of ignition of the fuel cell. The burning section and the base section of the fuel cell do not have any longitudinally elongated air passage channels that would completely pass through them.
According to FIG. 1, 2 and 3, the heat source or fuel element 10 is held in place inside the fencing element 17 by means of the holding element 23. including sections for gripping 40, 41 (shown in Fig. 1 and 3), which are in contact with the base segment 32 fuel cell. Preferably, the fencing element is a heat-conducting cartridge. In the most preferred case, the holding element 23 is dimensioned in cross section such that it (I) fits securely into the cartridge 17, preferably by friction fit, and (II) is in contact with the cartridge in regions 44, 45 (shown in Fig. 2 and 3) along the inner surface of the chamber. The retaining element also provides channels for air flow 47, 48 (shown in FIGS. 1 and 3) for the passage of air drawn through the cigarette. The holding member is made of a body resistant material, such as thin metal (e.g. aluminum) in a sheet.
According to FIG. 4, the fuel cell 10, which is shown to be longitudinally separated from the cup-shaped holding member 23, is inserted into the holding member, preferably so that a portion of the fuel cell base 32 abuts against the inner bottom surface 49 of the holding member. As shown in FIG. 4, a preferred holding member has a generally oval cross-sectional shape (i.e., two rounded side surfaces and two flat side surfaces). The shape and dimensions of the retaining element can be selected so as to provide the necessary channel for the flow of air through the cigarette.
. According to FIG. 5, when the fuel cell 10 (shown partially transparent) is inserted into the cup-shaped holding member 23, two portions of the holding member are folded inward so as to form gripping portions 40.41 that extend over adjacent parts of the base portion of the fuel cell.
Referring again to FIG. 1 and 2, we see that the carrier 13 is placed inside the cartridge 17, which includes (I) an open end 50 at one end (i.e., towards the extreme ignited end 31) of the cigarette, and (II) an opening 52 at the opposite end (t .e. towards the end to the mouth) of the cigarette. The carrier is enclosed and held inside the cigarette physically separated from the fuel cell. The retaining element 23 can also be extended through that portion of the fuel element 10 (i.e., the rear face of the fuel element), which is opposite the carrier 13 with the goal of (I) providing additional physical separation of the fuel element of the carrier), and (II) holding the carrier in place inside the chamber. A preferred holding element provides an obstruction to the flow of air and the movement of the aerosol forming material between the fuel element and the carrier. The number may have • various forms. One or more [types of carrier material may be included in the portion of cartridge chamber 17. For example, the carrier may include assembled paper B4, which carries glycerin and tobacco extract, is wrapped in a wrapping material 155 surrounding the circumference, and placed adjacent to the rear end surface of the holding member 23.
The cartridge 17 is made of heat-resistant heat-conducting material, such as a thin metal lyot (for example, aluminum). This cartridge is made of such a shape and located so in relation to the fuel element 10 that the letron (I) extends longitudinally along the length of the fuel element, and (I I) is placed with a gap relative to (for example, not in direct contact) the burning section 30 of the fuel element. The burning section of the fuel cell can be extended beyond the open end of the cartridge, can be extended from the open end of the cartridge or have such a length as to be flush with the open end of the cartridge (as shown in Fig. 1). The cartridge is open at the extreme end for ignition of the c-arm so that the extreme end for igniting the blasting element is fully exposed.
The cartridge 17 is radially arranged with a blockage relative to the longitudinal outer fuel element heirphere, and essentially (it is not in any contact with the longitudinal periphery of the fuel element). Thus, channel 57 for the air duct t is formed between the longitudinal outer periphery of the fuel element In addition, the configuration is such that the heat created by the burning section 30 of the fuel cell tends to radiate radially in order to heat the part of the cartridge that encloses (t ie, grabs this segment of the fuel cell.The radial clearance of the heat-conducting cartridge from the burning portion of the fuel element is preferably such that the amount of aerosol-forming material is emitted from the burning fuel cell to the cartridge. Usually, the cartridge has a length of between 8 mm and about 20 mm , and about friendliness from about 20 mm to about 2 ί mm.
ί heat sufficient to heat the nosiel and located on the m
The cartridge 17 is located at one end of the tubular mouthpiece 28. The mouthpiece is preferably made of paper coated with metal foil, insulating ceramic material, molded plastic, heavy weight paper or similar materials. The mouthpiece 28 preferably has such a shape and dimensions that the cartridge fits tightly inside it and can be held in place by friction fit. Part of the mouthpiece may surround or otherwise cover part of the length of the cartridge, or the entire length of the cartridge (as shown in Fig. 1 and 2). It is possible that a series of openings 58 or other types of openings for air inlet are provided through the mouthpiece and the cartridge in its area that surrounds the burning section 30 of the fuel element 10. The size, number and location of the holes can be chosen so as to provide an adjustable supply of oxygen to the burning section fuel cell during the smoking period.
Inside the mouthpiece 28, behind the cartridge 17, there is a piece of collected cigarette paper for cigarettes 60, wrapped with a wrapping paper wrapper 61. Also inside the mouthpiece, behind the collected cigarette paper for cigarettes, is a roll of tobacco cut filler 62. wrapped around the circumference of a paper wrapper 63. Also inside the mouthpiece and located at the end of the mouth of the cigarette is a low-performance filter element containing filter material 64 (for example, a assembled core of non-woven polypropylene fibers) and a circumferential wrapper 65 of a cork. A piece of collected cigarette pack paper, a roll of tobacco cut filler, and a filter element can be held in place inside the mouthpiece using a tight friction fit or using glue. If necessary, a hollow space 66 (for example, filling the mouthpiece length of about 10 mm or more) may be provided between the rear end of the cartridge case 17 and the collected cigarette pack paper 60. Typically, overlay paper 67 spans the circumference of an end region of a cigarette mouthpiece. In addition, a ring of perforation holes 68 for dilution with air may be provided near the end region of the cigarette holder using laser technology or mechanical perforation technology.
In use, the smoker sets fire to a heat source or fuel cell 10 (for example, using a cigarette lighter), and the burning portion 30 of the fuel cell burns, producing heat. The heat generated by the fuel cell is radiated outward, heating the portion of the cartridge 17, which covers or covers the fuel cell, and the heat, in turn, is conducted through the cartridge to the part that is in contact with the carrier 13 and the aerosol forming material that is located on it. In addition, a certain amount of heat is conducted through the base of the fuel element and through the retaining element to the carrier and to the aerosol forming material thereon. During inhalation by the smoker, the air drawn in passes through the air passage channel 57 between the fuel element and the cartridge, and heats up upon contact with the hot fuel cell and the heated cartridge. The heated drawn-in air then passes through the channels 47, 48 for the passage of air between the holding element 23 and the cartridge, and comes into contact with the carrier 13, which is in a heat exchange relationship with the burning fuel element. The resulting heat supplied to the aerosol forming material acts to vaporize this material. The volatilized material inside the warm retractable air exits the chamber through the openings _e 52. Then, the retracted air and the volatilized material are cooled as they pass through the mouthpiece. Depending on the specific aerosol forming material, then a visible aerosol is formed. In particular, the drawn-in air and the escaping material pass through the assembled pack paper for cigarettes 60, through a roll of tobacco cut filler 62, through filter material 64 and into the mouth of a smoker. Since the base does not burn during use of the cigarette, and the fuel cell self-extinguishes after combustion of the burning portion, the fuel cell remains reliably in the cigarette and does not tend to shift beyond the limits of the cigarette during use. Typically, a cigarette tends to self-extinguish when the combustion of the burning part of the fuel cell is completed. When the fuel cell self-extinguishes and no longer produces heat, the cigarette is emitted.
According to FIG. 6 and 7, an alternative embodiment of the present invention is in the form of a cigarette 8, which is similar in many respects to the cigarette shown in FIG. 1, 2, and 3. The cigarette includes a transverse end defense assembly 69 including a fuel cell 10, a carrier 13 that contains aerosol forming material, a fencing element in the form of a heat-conducting cartridge 17 that contains the carrier, and a holding member that holds the fuel cell in place Inside the cigarette, the cigarette also includes a separate tubular mouthpiece 28.
The fuel cell 10, which preferably includes longitudinally spaced portions or segments, is limited to breathable insulating material 70, such as fiberglass. Exemplary breathable insulation materials are described in European Patent Application No. 339.690, pages 48-52 of the publication Chemical and biological studies of new prototypes of cigarettes that are heated instead of burning tobacco. R.J. Reynold Tabaccow Co., (1988), and U.S. Pat. The insulating material is preferably (I) such that the retracting air can pass through it, (II) is positioned and shaped to help keep the fuel cell in place, and (III) is of such a nature that the heat generated by the burning fuel cell, transferred to that part of the chamber, which has a radial clearance relative to the fuel cell.
The longitudinal outer periphery of the cartridge chamber 17 is limited by an insulating material 72, such as insulating fiberglass. The insulating material 72 is such that the heat generated by the burning fuel cell 10 and which is transferred to the cartridge 17 is used to efficiently heat the aerosol forming material of the aerosol generating means. The insulating material is limited to an outer wrap 74, such as cigarette paper,
Cartridge 17 contains two types of carrier materials. In particular, the carrier includes (I) balls of alumina 76, which contain glycerin and tobacco extract and which are adjacent to the back surface of the retaining element 23, and (II) collected paper 54, which does not support glycerin and tobacco extract, which wrapped in a bounding paper wrapper 55 and which is located behind the alumina balls. The cartridge may be corrugated 78 or otherwise deformed to assist in securing the retaining element within a foreign position within the cigarette.
The tubular mouthpiece 23 is positioned end-to-end with an assembly 7 of the front end 69. Preferably, the cross-sectional shape and dimensions of the mouthpiece are substantially identical to the shape and dimensions of the front end assembly. The front end assembly 69 and the piece mouthpiece 28 are attached to each ipyry using the female material of the tip 67.
According to FIG. 8, an alternative embodiment of the present invention is in the form of a cigarette 8, which in many respects is similar to the cigarette shown in FIG. 1 and 2, a carrier 13, which carries an aerosol-forming material, a tubular heat-conducting element of the fence 17, into which a fuel element, a heat-conducting cartridge 80, located behind the fuel element and inside the element of the fence, and containing the carrier and the tubular mouthpiece 28, are inserted.
The fuel cell 10 is generally circular in radial cross-section and includes a base portion 32 and a combustible portion 30. The circumference of the base since 32 is larger than the circumference of the combustible portion 30. The preferred fuel cell 10 is formed by molding so as to have a hollow 5 area 82 extending from the base with the base towards the burning element, it is possible that a number of channels for the passage of air (not shown) can pass through the fuel element rodolno. At least one hollow area 83 can pass into the burning unit of the fuel cell, so that when the fuel cell is lit when used, at least one channel can be formed for the air to pass through the fuel cell. The fuel e1y element includes at least a channel I1I groove 84 extending longitudinally along the outer periphery of the burning portion towards the base portion, so. that 3 'from the channel and the hollow region 82 are connected. Thus, the drawn-in air passes through the channel 84, into the hollow region 82 and then through the aerosol forming means.
According to FIG. 9, the burning portion of the fuel cell 10 includes grooves 84, 85, and 86 extending along its outer longitudinal periphery. Other groove configurations (for example, 4 pairs of grooves offset at 90 ° intervals) can be used.
Referring again to FIG. 8, we see that the fuel element 10 is inserted through the rear of the fencing element 17 so that the portion of the base 32 abuts against the protruding shoulder or edge 88. Then the carrier 13 is placed inside the cartridge 80, and the ends of this cartridge are bent inward so as to enclose the carrier with maintaining the inlet 90, and the outlet 92 at each end of the chamber. The cartridge is then inserted into the rear of the fence element to abut against the rear of the base portion of the fuel cell. Preferably, the inner dimensions of the fencing element 17 and the outer dimensions of the cartridge 80 are such that the cartridge is securely fixed in place by friction fit. Essentially, the front of the cartridge 80 and collar 88 in the fencing element 17 provides a holding means for holding the fuel element 10 securely in place inside the cigarette.
In FIG. 10-16 illustrate exemplary configurations of heat sources or fuel cells that may be included in the composition of smoking articles according to the present invention, and in particular cigarettes, which are previously described with reference to FIGS. 1-7,
According to FIG. 10, the fuel cell 10 includes a combustion portion 30, an insulating portion 33, and a base portion 32. The insulating portion has external cross-sectional dimensions that are significantly smaller than those of the base portion. In addition, the fuel cell includes a plurality of discontinuities 92 spaced longitudinally along the length of the burning portion, and extending transversely through the fuel cell.
According to FIG. 11, the fuel cell 11 includes a hollow space 35 extending laterally through the fuel cell. The hollow space has a generally triangular shape, having a base almost parallel to the rear end of the fuel cell, and a tip that passes through the burning section of the fuel cell.
According to FIG. 12, the fuel cell 10 includes a burning section 30 and an insulating section 33 having identical external dimensions in cross section, and a section of the base 32 having a periphery in cross section that is larger than the periphery of the combustion and insulating sections. The fuel cell includes a hollow space 35 elongated transversely through the insulating section and a portion of the length of the base section.
According to FIG. 13, the fuel cell 10 includes a hollow space 35 elongated laterally through the insulating portion 33, and an additional hollow space 83 elongated through the lengths of the burning portion. Essentially, when the burning portion of the fuel cell burns during use, it forms longitudinally through the portion of the fuel cell elongated channel. Thus, after a certain period during use inside the smoking article, the drawn-in air can pass through the burning fuel cell (i.e., and therefore heat up), and then pass to the aerosol forming agent. The ability to allow drawn air to pass through the combustible portion of the fuel cell provides increased heat transfer to the aerosol forming agent for aerosol formation during subsequent stages of using the smoking article. As such, it is possible to provide a fuel cell capable of providing relatively consistent heat transfer to an aerosol forming agent over the life of the fuel cell.
According to FIG. 14, the fuel cell 10 includes a burning section 30, a base section 32, and an insulating section 33 including a hollow space 35 extending therethrough. The burning section and the base section have a similar shape to each other and essentially each end can be used as a burning section or a base section, depending on how the fuel cell is placed inside the smoking article. The fuel cell may also include ribbed grooves 37, 38 elongated across the front end of the burning section, and ribbed grooves 94, 95 elongated across the rear end of the base segment.
According to FIG. 15, the fuel cell 10 is similar to the fuel cell described with reference to FIG. 14, except that the two hollow spaces 35, 96 are elongated laterally through the insulating section 33.
According to FIG. 16, the fuel cell 10 is similar to the fuel cell described with reference to FIG. 14.
According to FIG. 17, an alternative embodiment of the present invention is in the form of a cigarette 8, which in many respects is similar to the cigarette shown in FIG. 1, 2, 6, and 7. The cigarette includes a fuel cell 10, a carrier 13 that carries an aerosol forming material, a material 70 that spans the entire longitudinal periphery of the fuel cell to hold the fuel cell in place, and a tubular mouthpiece 28.
The fuel cell 10 is longitudinally divided into segments and includes a base portion 32, a combustible portion 30 and an insulating portion 33 located between the combustible portion and the base portion. The fuel cell 10 is shaped so that the circumference of the base portion 32 is larger than the circumference of the portion (for example, insulating portion 33) adjacent to the base portion. Preferably, the fuel cell 10 includes at least one passage for air flow 98 extending in the form of a slit or groove along the entire length of the fuel cell.
The material 70 that surrounds the fuel cell 10 may vary. Material 70 may be material that tends to not burn, or ma-. A material that burns lightly to provide easy ignition of the smoking article. More preferably, material 70 is non-metallic in nature. Examples of suitable materials include fiberglass and other materials of the type of European Patent Application No. 336. 690 and pp. 48-52 of the publication of R.J. Reynolds Tabakou Co., Chemical and biological studies of new experimental Cigarette Samples that generate heat instead of tobacco burning (1988) Examples of other suitable materials are mixtures of fiberglass and tobacco, such as those described in US Pat. No. 4,756,318 to Klierman et al. Examples of other suitable materials are materials such as tightly packed paper. ennoy paper and paper-type materials which are spirally wrapped or otherwise wound around the fuel element. Suitable paper-type materials include treated paper, carbon-containing paper, tobacco-containing paper, wood pulp paper, sulphate paper, wood pulp paper (calcium carbonate paper, carbon-containing paper, wood pulp, and fillers such as agglomerated materials. 17 Paper type materials can be layered or corrugated and assembled around the fuel cell, assembled into a roll using a roll making machine sold on the market under the brand name CU-10 or CU-20 from Decoufle sarb, or the apparatus described in US Pat. No. 4,807,809 to Pryor et al., wrap around a fuel cell around a longitudinal axis of the fuel cell , or presented in the form of longitudinally elongated strands of a paper type sheet using apparatus types described in US Pat. No. 4,889,143 to Pryor et al, which is hereby incorporated by reference. Examples of sheet materials such as paper are available in carbon form. (copy) paper P-2540-136-E and pack paper cigarette weighers R-2674-157 from Kimberly-Clark 20 Corp., and preferably longitudinally elongated strips of such materials (for example, strands with a width of about 1/32 inch) are elongated along the length of the fuel cell. The fuel cell may also be limited to cut tobacco filler (eg, cut filler with pipe-dried tobacco treated with about 2 weight percent potassium carbonate). The number and location of 30 strands or a pattern of assembled-tight paper is dense enough to hold, support or otherwise preserve the fuel cell inside the cigarette. 35
The material 70 that surrounds the fuel cell. It is covered by a paper wrapper 101. This bamaga covers the entire length of the material70. An example of a suitable Zumura Wrapper that can be purchased is 40, P-850-63-5 from Kimmersley-Clark Corn. Part of the length of the paper 1 wrapper 101 is, in turn, covered by a second or outer paper wrapper 03. An example of a suitable outer paper wrapper that is sold is P-850-61-2 from Kimberly-Clark Orn.
The second wrapping paper 103, more preferably, is a paper that is prone to non-Combustion (i.e., due to very low mountaineousness and / or due to chemical treatment), and preferably does not cover the paper wrapper 101 for the length from about mm to about 8 mm, more preferably from about 3 mm to about 6 mm, at the extreme end of the cigarette lighting. The second paper wrapper 103 also covers at least a portion of the length of the tube 45 of that mouthpiece 28, and therefore acts as a tip material. The second wrapper acts to help prevent burning of the fuel cell to any significant extent outside its burning section. Essentially, the fuel cell tends to self-extinguish prior to combustion, to any significant degree, of the insulating portion.
The carrier 13 is located behind the fuel element 10 inside the tubular mouthpiece and is installed with a gap relative to the rear end of the fuel element so as to have an air space 104 between them. For example, the rear end of the fuel element and the front end of the carrier are located at a distance of about 1 mm to about 10 mm preferably from about 2 mm to about 5 mm. The carrier preferably includes a tube of assembled or puff paper 105, a short piece of assembled paper 106 placed inside the tube 105 at the end of the tube near the rear end of the fuel cell, and air space 107 behind the assembled paper 106. The assembled paper provides a plurality of longitudinally elongated channels for air passage. The partition wall of the assembled paper is usually covered by a paper cover 55. The inner surface of the tubular mouthpiece is preferably coated, especially in it. the area adjacent to the carrier to a material that seeks to limit the amount of aerosol forming material that is transported from the carrier 13. Examples of suitable materials are ethyl cellulose (for example, which is applied as a dilute solution in ethanol) or a material that is commercially available under the name Negsop 70 from Hercules, Inc. the mouthpiece region adjacent to the fuel cell and / or the paper wrapper region 101, 103 that are outside the length of the base of the fuel cell may be coated with aqueous solutions of calcium chloride or ammonium acid phosphate, followed by drying.
According to FIG. 18, the fuel cell 10 includes grooves 98, 108 extending along its outer longitudinal periphery. Other groove or channel configurations to allow air to flow through the fuel cell may be used.
According to FIG. 19, an alternative embodiment of the present invention is in the form of a cigarette 8. which is in many ways similar to the cigarette shown in FIG. 17. The cigarette includes a fuel cell having a hollow space 35 extending completely through it in a direction transverse to the longitudinal axis of the cigarette and extending over a considerable length fuel cell. Part of the length of the portion of the base 32 of the fuel cell 10 extends beyond the bounding material 70, and thus provides a channel for the passage of air flow through the fuel cell, in particular after the fuel cell has been ignited. Material 70 covers the combustible portion and the fuel cell insulation portion. However, if necessary, part of the length of the burning portion may extend beyond the bounding material 70. The rear end of the fuel cell is positioned with a gap relative to the carrier 15. The carrier may have certain fairly wide, longitudinally elongated channels or grooves 110, 112 for the passage of air flow.
According to FIG. 20, an alternative embodiment of the present invention is in the form of a cigarette 8, which is similar in many ways to the cigarette shown in FIG. 17. The base portion 32 of the fuel cell 10 has a significantly larger circumference than the circumference of both the burning and insulating portions 30, 33, and includes a channel for passing an air stream (not shown) extending in the form of a groove along the entire length of the fuel cell. The carrier 13 is made almost in the shape of a cup inside the tubular mouthpiece 28 with the introduction of a round piece of paper having a diameter of about 2.5-4 times the inner diameter of the mouthpiece, through the extreme mouth end of the mouthpiece and bending or changing the shape of this paper otherwise to the desired shape inside the mouthpiece.
According to FIG. 21, the fuel cell 10 includes a hollow space 35 elongated laterally through the insulating portion 33, and channels for the passage of air flow 98, 108, 1 16, 1 17 extending in the form of grooves along the longitudinal periphery of the fuel cell. Such a fuel cell may be made by machining an extruded fuel cell or using direct compression technology. Such a fuel cell is particularly suitable for use in the types of cigarettes described with reference to FIG. 17 and 19.
The smoking articles of the present invention include some form of tobacco. The shape of the tobacco may vary, and more than one form of tobacco may be incorporated into a particular smoking article. Tobacco can be introduced into the fuel cell, into an aerosol converting agent, and / or placed inside the mouthpiece so that various odor-containing tobacco components are transferred to the retractable aerosol passing through the mouthpiece. The type of tobacco can vary and includes pipe-dried tobacco, burley, Maryland and oriental type tobacco, rare and delicate tobaccos, as well as mixtures thereof,
One form of tobacco is shredded tobacco (for example, tows or filler fibers having a width of about 1/15 inch to 1/40 inch and a length of about 1/4 inch to about 3 inches). Beveled tobacco can be presented in the form of layered tobacco, layered tobacco with a swollen volume or with an exploded volume, processed tobacco waste from medium veins, including cut into noodles or rugged expanded expanded veins, or reconstituted tobacco material. Processed tobaccos can also be used, such as those described in European Patent Application No. 412,768. Reconstituted tobacco material can be represented using casting technology, paper making techniques such as described in US Pat. No. 4,962,774 to Tomasson et al. and No. 4,987,906 to Yang et al. or extrusion technology, as described in US Pat. No. 4,821,749 to Tofta et al. Crumpled tobacco is typically introduced into a cigarette in the form of a cylindrical roll or filled with tobacco material that is wrapped tsya circumscribing paper wrapper. Crumpled tobacco can be presented in the form of a roll in a paper wrapper using the technology of manufacturing the core of a cigarette and apparatus, which are well known to a competent specialist in this field. Crushed tobacco can also be incorporated into an aerosol forming agent, if necessary.
Another form of tobacco is tobacco paper. For example, a roll of tobacco paper available on the market as P144-GNA from Kimberly-Clark Corp. can be folded into a cylindrical section as described in Example 2 of US Pat. No. 4,807,809 Priora. et al. Cylindrical sections of pleated tobacco paper may be included (I) in an aerosol forming agent for use as a carrier for aerosol forming material and / or (II) inside a cigarette mouthpiece. If necessary, the tobacco paper may form the inner liner of the tubular mouthpiece of the smoking article.
Another form of tobacco is finely ground tobacco material. This form of tobacco includes tobacco dust and finely ground tobacco sheets. Usually finely ground tobacco material is placed on a carrier that is placed inside an aerosol forming agent. However, finely ground tobacco material may also be included in the fuel cell.
Another form of tobacco is tobacco extract. Typically, tobacco extracts are obtained by extraction of tobacco material using a solvent such as water, carbon dioxide, sulfur hexafluoride, a hydrocarbon such as hexane or ethanol, a halocarbon such as commercially available Freon, and other organic and mineral solvents. Tobacco extracts may include tobacco extracts obtained in a spray dryer, lyophilized tobacco extracts, tobacco flavor oils and tobacco essences. Methods for preparing suitable tobacco extracts are described in US Pat. Nos. 4,506,682 Muller and 4,986,286 Roberts et al. And European Patent Applications Nos. 326,370 and 338,831. Flavored tobacco formulations such as those described in European Patent Application are also useful. 374 779. Another tobacco extract is obtained by extracting I part by weight of crushed tobacco with about 6 parts by weight of water in a stainless steel column at ambient temperature in order to obtain an aqueous tobacco extract having a solid content at About 15 cent percent, by freezing the water extract to a frozen block, curing about half the weight of the bewitched block, collecting the resulting melted water and extract, freezing the water and extract collected in this way to a frozen block, placing about half the weight of the frozen ylok, and collecting the obtained melted yuda and extract. Typically, at least one tobacco extract is contained on an aerosol forming agent carrier, junk tobacco, tobacco paper and filter media are located elsewhere inside the cigarette. In addition, tobacco extract may be included in the fuel cell.
A smoking article according to the present invention includes an aerosol forming agent that is physically separated from the fuel cell. Essentially, the aerosol forming agent is not miscible with the fuel cell and is not part of it. The aerosol forming agent is in a heat exchange relationship with the fuel cell so that the heat generated by the burning fuel cell is transferred to the aerosol forming agent for heating and vaporizing the aerosol forming material, in particular during periods of smoker's puffs.
A preferred aerosol forming agent includes a carrier for placing aerosol forming material thereon. Preferred carriers retain aerosol forming material when not in use and release aerosol forming material during the smoking period.
One type of carrier is in the form of a non-woven sheet-like material or cellulosic material such as paper, carbon paper or tobacco paper. Such a carrier is usually presented in the form of a cylindrical segment, including a pleated, pleated or corrugated roll of paper-type material enclosed in a wrapping outer wrapper. The bounding outer wrapper is preferably paper material and may be paper material. processed so that the limiter moves the aerosol forming material to other parts of the smoking article. If necessary, the bounding outer wrapper may be a metal (e.g., aluminum) foil. Such cylindrical segments can be made of rods that are manufactured using the equipment and technology described in US Pat. No. 4,807,809 to Pryora et al. Paper, as an example, which is folded to form carriers, is available on the market as MS2408 / S538 from the company Filtron Ltd., as well as in the form of P-1976-29-5, P-1976-29-7, P1976-29-1, P-1976-29-8 and P-1976-29-11 from Kimberly Clark Corp. You can use combinations of two or more papers or paper type materials. As an example, tobacco paper, which is folded to form carriers.
the market has the P144-GNA brand from Kimberly-Clark Corp., as well as carbon-filled tobacco sheet materials. described in the application for European patent No. 342 538. which is included in this case by reference. Another carrier may be in the form of a porous, breathable pad, which receives liquid aerosol forming material from the container according to the wick principle. The sheet-like material used as a carrier may have fillers having certain porous structures physically mixed with and / or incorporated therein in order to control the transfer of aerosol forming material from the carrier. However, media made from metallic materials and not containing metallic materials are often preferred.
Another type of carrier material is a heat-resistant material (for example, a material capable of withstanding temperatures from about 400 ° C to about 600 ° C without decomposition or burning). Examples of such materials include porous calibrated carbon, graphite, carbon yarn, activated and non-activated carbon, and ceramics. Suitable carbon carrier materials include PC-25 and PC-60, offered by Union Carbide Corp., SGL, offered by Calgon Carbon Corp., and catalog numbers CFY0204-1, CN-157 (HC), CN-210 (HC), ACN- 21110 and ACN- * 157-10 from American Kinol Inc., Other suitable carrier materials include alpha-alumina balls, commercially available as sintered alpha-alumina D-2- from U. R. Grace & Co., and carrier materials described in US Pat. No. 5,827,950 Banerjee et al. If necessary, the carrier material may be porous, airborne oncible extruded material. Another type of carrier is in the form of compacted granules formed from coal, tobacco, mixtures of coal and tobacco, mixtures of alumina and tobacco, or mixtures of paper and tobacco. The compacted granules can be made using the Marumerator supplied by Furzhi Powal KK, Japan. See German Patent No. 1,294,351, US Patent No. Re 27.714 and Japanese Patent No. 8684/1967.
More than one type of carrier material can be used to create an aerosol forming agent. For example, alumina balls that carry aerosol forming material on them may be placed behind the fuel cell, and a cylindrical segment of pleated paper carrying the aerosol forming material may be placed behind alumina balls.
Aerosol forming agents include aerosol forming material, and the aerosol forming material is in relation to heat exchange with the fuel cell. The aerosol forming material may have a liquid, semi-solid or solid form, and is usually located on a carrier. Examples of preferred aerosol forming materials include polyhydric alcohols (e.g. glycerol, propylene glycol, triethylene glycol and tetraethylene glycol), aliphatic esters, mono-, di- or poly-carboxylic acids (e.g. methyl stearate, dimethyl dodencandioate and dimethyl tetradecandioate, H, F), Inc., and the like, as well as mixtures thereof. For example, glycerol, triethylene glycol and Hystar TPF can be mixed together to form an aerosol forming material. Examples of other aerosol forming materials include volatile flavoring agents and tobacco odor modifiers. Volatile flavors include menthol, vanillin, cocoa, licorice, organic acids, high syrup corn syrup, and the like. Various other flavoring agents for smoking articles are defined in the publication Flavoring Tobacco for Smoking Products (1972) by Leffingwell et al. And European Patent Application No. 407 792. Tobacco flavor modifiers include levulinic acid, metallic (for example, sodium, potassium, calcium and magnesium) salts of levulinic acid, and the like.
The amount of aerosol forming material that is used for each smoking article may vary and depends on factors such as the components of the aerosol forming material and the composition of the particular carrier that carries the aerosol forming material. Usually the amount of aerosol forming material. used for each smoking article is in the range of about 20 mg to about 200 mg, preferably about 35 mg to about 125 mg. When using paper or paper type media, it is preferred that all of the aerosol forming material that is on this carrier is about 2 to about 4 times the dry weight of the carrier material.
A smoking article according to the present invention includes a heat source that generates heat sufficient to vaporize the aerosol-forming material in the aerosol forming agents. A preferred heat source or fuel cell is made of combustible material so that the density of the fuel cell is greater than about 0.5 g / cm ³ , often about 0.7 g / cm ³ or more, often about 1 g / cm ³ or more sometimes
1.5 g / cm ³ or more, but usually less than about 2 g / cm ³ . In addition, the fuel cell typically has a length, before burning, of less than about 20 mm, often less than about 15 mm, and often less, a meme of about 10 mm.
A highly preferred fuel cell has a segmented structure. Such a fuel cell is designed so that when using a smoking article into which the fuel cell is inserted, (I) a portion of the length of the fuel cell is capable of 1 combustion, and (II) the remaining longitudinal portion of the fuel cell does not burn. The part of the fuel cell that is intended to remain unburned may have such a characteristic as a result of factors such as (I) the choice of the composition of this part of the fuel cell, (II) the general configuration of the fuel element. (Ill) placing the fuel cell inside the smoking article; and (IV) the method by which the fuel cell is secured inside the smoking article. A preferred segmented fuel cell includes in the cell i (I) a combustion section for generating heat, (II) a non-burning section including a base or support section, and (111) an insulating section located between the burning section and the base section. A preferred segmented fuel cell is also designed and configured so that this heat is not easily transferred from the burning portion of the fuel cell to • Ml
D sections of the product for smoking are regulated, and the element did not show a tendency to gravity
The combustible portion of the fuel cell is about 2 mm to about the non-combustible portion of the fuel cell. Essentially heat transfer through the conductivity from the fuel cell to other
I is preferably minimized, with the aim of ensuring that burning fuel fuels during normal periods of smokeless burning. Usually a length of mm, preferably from about 4 mm to about 8 mm, before combustion. Typically, the length of the base portion of the fuel cell is about 1 mm to about 5 mm. Typically, the length of the insulating portion of the fuel cell reaches about 10 mm, preferably about 8 mm.
The preferred fuel cell 10 has a radial or cross section so that its two opposite sides are substantially parallel to one another. Preferred segmented fuel cells are also such that the cross-sectional shape of each element, and in particular the base element, is usually square, rectangular or parallelepiped-shaped (i.e. each segment of the fuel element 20 has four sides elongated along the length of the fuel element , and each pair of opposite sides is almost parallel to each other),
The maximum dimensions of the cross section 25 of the fuel cell may vary, but they are such that the burning portion of the fuel cell does not come into contact with the fencing element that covers this part of the fuel cell. Typically, the burning portion of the fuel cell is located at a distance of about 0.2 to about 2 mm. but preferably not less than 1 mm from the enclosure element, A typical burning portion of the fuel cell 35 has a cross-sectional area of about 10 mm ² to about 25 mm ² . A typical base portion of a fuel cell has a cross-sectional area of about 15 mm ² to 40 about 30 mm ² . Although it is desirable that the cross-sectional dimensions of the insulating portion of the fuel cell are as small as possible, a conventional insulating portion has a cross-sectional area of from about 5 mm ² to about 10 mm ² .
The composition of the combustible material of the fuel cell may vary. Preferred fuel cells contain carbon, 50 and highly preferred fuel cells consist of carbon-containing materials. Preferred carbonaceous materials have a carbon content above about 60 weight percent, more preferably above about 75 weight percent. Flavors, tobacco extracts, fillers (e.g., clays or calcium carbonate), flammable additives (e.g., sodium chloride to improve decay burning and acting as a decay inhibitor), flame retardants (e.g., potassium carbonate to control flammability). binders and the like can be included in the composition of the fuel cell. Exemplary compositions of preferred carbon-containing fuel cells are described in US Pat. Nos. 4,714,08 to Banerjee et al., 4,756,318 Klierman et al. and 4,881,556 Klierman et al., as well as in applications for European patent No. 236 992 and 407 792, which are incorporated herein by reference. Other fuel cells may be provided from ground tobacco material, homogenized tobacco material, heat-treated or pyrolyzed tobacco materials, cellulosic materials, modified cellulosic materials, and the like. Examples of materials are given in US Pat. Nos. 4,347,855 to Lensilotti et al., 3,931,824 Miano et al., 3,885,574 Borswick et al. And 4,008,723 Borswick et al. Data Corp. (1976) Examples of carbon-containing materials are nutshell coals, such as RCS carbons, available on the market as PCBs, and experimental carbons, available as B-11030-CAC-5, B-11250-CAC115, and 089 -A12-CAC-45 from Calgon Carbon Corp.
The fuel cells for smoking articles according to the present invention are desirably molded, machined, injection molded or extruded to the desired shape. Molding fuel cells may have channels, or grooves or hollow areas. Preferred extruded carbon-containing fuel cells can be prepared by mixing up to 95 parts of carbon-containing material, up to 20 parts of a binder and up to 20 parts of tobacco (e.g., tobacco dust and / or tobacco extract) with enough water to produce a paste having a tough, pasty consistency. The paste can then be extruded using a piston, screw or plunger extruder to obtain the extrudate of the desired shape, having the required number of through channels or hollow cavities. The extrudate can be passed through a pair of gear or grooved rollers to print grooves (transversely or longitudinally with respect to the extrudate extrudate axis) at regular intervals so as to create a special surface appearance on selected surfaces of the last fuel cell. The extrudate can then be dried to a low moisture content, usually in the range of about 2 to about 7 weight percent. Then, the continuous length of the extruder is cut or otherwise subdivided at regular intervals to produce multiple individual fuel cells.
In essence, it is possible to obtain a fuel cell having an extrusion axis that is perpendicular (i.e., rather than parallel) to the longitudinal axis of the smoking article into which the fuel cell is finally inserted. If desired, various types of materials can be extruded together to produce fuel cells having combustible sections and base sections that have different compositions. For example, (I) the sections of the base and the insulating fuel cell may be composed of a material that is less prone to combustion. what is the case with the material that is used to obtain the burning section of the fuel cell, or (II) the extreme end for igniting the fuel cell may consist of a material having an extremely high tendency to burn in order to enhance the ease of ignition of the fuel cell.
The fencing element is made of heat-resistant material. The fence element is preferably a heat-conducting element, and usually consists of a strip or foil of a metal sheet. Typically, the thickness of the conductive element is in the range of about 0.01 mm to about 0.2 mm. The thickness, shape and / or type of the Material used for the manufacture of the heat-conducting element may vary in order to obtain the desired degree of heat transfer to the aerosol-forming material. A preferred heat-conducting element is made of a thin aluminum sheet. The heat-conducting element (I) may be constructed in the form of a single part or made of two or more segments, or (II) made of one or more heat-conducting materials.
The heat-conducting element preferably extends over at least a portion of the long burning portion of the fuel cell and forms a container that encloses an aerosol-forming ma
18 tier. The heat-conducting element is radially spaced relative to a significant portion of the length of the burning part of the fuel element and can extend beyond the front burning end of the fuel element. In most most preferred embodiments, the heat-conducting element is positioned with a gap with respect to the burning portion of the fuel element, as well as from the insulating part and the base part of the fuel element (i.e., the fuel element is physically isolated from the heat-conducting element). As such, heat transfer by thermal conductivity from the fuel cell to the heat-conducting element (and therefore to aerosol forming means) is controlled and preferably minimized.
Preferably, the fuel cell is installed inside the smoking article so that the burning portion of the fuel cell is thermally isolated from the heat sink components of the smoking article. In addition, the fuel cell is located inside the smoking article so that the fuel cell experiences a limited or controlled supply of oxygen during the combustion process. In essence, it is highly preferable to use small fuel cells with low weight, which quickly heat up, burn enough to maintain the operating temperature (and therefore do not self-extinguish), and emit enough heat to produce aerosol during the period when the product is inhaled for drift. The radial clearance between the burning section of the fuel cell and the heat-conducting element is close enough, as a result of which the heat generated by the burning fuel element is transmitted by radiation to the heat-conducting element. However, the radial gap between the burning section of the fuel cell and the heat-conducting element is such that the burning section receives a sufficient supply of oxygen for the fuel cell to maintain smoldering during the normal period of use of the smoking article. In addition, the fuel cell and the heat-conducting element are preferably arranged so that the drawn-in air passing through the air flow passage between the fuel cell and the heat-conducting element is heated, thereby providing convection heating of the aerosol forming means.
'· (’
An arrangement with a clearance of i-ή ’κοη <{· ηι of the fuel cell and heat-conducting element can be selected as follows. to provide the required amount of heat transfer by convection. Alternatively, the drawn-in air may pass through an air passage passage formed inside the heat-conducting element so that the drawn-in air is heated as it passes through the passage to the aerosol forming agent. If necessary, the heat-conducting element may be configured such that the drawn-in air passes along a winding path before and / or during contact with the aerosol forming material.
Retention aids may vary in shape and composition. However, the holding means is most preferably made of a thin metal sheet which can easily be deformed in this way. in order to (I) hold the fuel cell securely in place, and (II) stay in position within the smoking article. In preferred embodiments, the holding element acts as a physical barrier between the fuel element and the aerosol forming material within the aerosol forming means. In most preferred embodiments, the holding means provides an airtight barrier between the rear surface of the fuel cell and the aerosol forming means. As such, the movement of the aerosol forming material into the fuel cell is minimized. In preferred embodiments, an adjustable gap between one or more regions between the retaining element and the heat-conducting element allows the air to be drawn in through the fuel and into the aerosol forming means (i.e., at least one air passage is provided). If necessary, through channels or slots may be formed in the rear surface of the retaining means for the passage of air flow, or the retaining element may be deformed or cut along to ensure reliable retention of the fuel element, as well as for the corresponding channel of the air passage.
Although less preferred, the restraining means may be made of a series of wires or of wire mesh. The wire can be shaped to hold the base of the fuel cell in place, as well as to hold the fuel cell in place inside the smoking article. The choice of a particular wire, as well as the selected wire configuration, so that the fuel cell is held firmly in place within the smoking article, will be apparent to one skilled in the art. One end of the wire can be formed into a fuel cell, and the opposite end of the wire can be used to secure the fuel cell in place inside the product. If desired, several wires can be drawn through and / or around the fuel cell to secure the fuel cell in place. Alternatively, several wires may pass through the combustion-resistant portion of the co-extruded fuel cell in order to hold the fuel cell securely in place. Such co-extruded fuel cells include a combustion section for generating heat and a combustion resistant portion elongated laterally or longitudinally through the fuel cell through which the wire holding means passes. In essence, it is possible to hold the fuel cell inside the smoking article, both prior to use and during combustion of the fuel cell during use. Typically, fuel cells are extruded with through passages passing through them so that wires that form the retaining member properly can pass through the fuel cell in order to hold the fuel cell in place. Holding elements made of thin metal wires or wire mesh provide good thermal insulation of the fuel element, since thin wires tend not to conduct large amounts of heat with high efficiency to other components of the product for smoking. A smoking article having a holding member of wire or wire mesh may optionally comprise a perforated end cup that extends beyond the protruding burning end of the smoking article.
In most embodiments of the present invention, a heat-conducting cartridge that contains a carrier and aerosol forming material is attached to the mouthpiece, although the ejected fuel cell and cartridge can be used with a separate mouthpiece, such as a reusable mouthpiece. The part inserted into the mouth provides a channel that serves to move the evaporated aerosol forming material into the smoker's mouth, and can also impart additional flavor to the evaporated aerosol forming material. Typically, the length of the part inserted into the mouth ranges from 40 mm to about 85 mm. Typically, the length of the part inserted into the mouth is such that (I) the burning portion of the fuel cell and the hot heat-conducting element are kept away from the smoker's mouth and fingers, and (II) the hot escaping aerosol forming materials have enough time to cool until the smoker's mouth reaches. Often it is highly desirable to create a hollow space inside the part inserted into the mouth directly behind the aerosol forming agent. For example, a hollow space extending at least about 10 mm along the length of the smoking article is provided directly behind the aerosol forming agent and in front of any crumpled tobacco, tobacco paper or filter segments.
Suitable parts for insertion into the mouth are usually inert with respect to the aerosol forming material, create minimal loss of aerosol as a result of condensation or filtration, and are able to withstand temperatures that occur during use of the smoking article. Exemplary mouth-inserted parts include plasticized cellulose acetate tubes, such as those available under the SCS-1 brand from American Filtron Corp., polyimide tubes available as Kapton from E.I. DuPont de Nemours, cardboard or heavy tubes paper, and paper tubes with a layer of aluminum foil.
The total length of the smoking article, or any part thereof, can be wrapped in cigarette paper. Preferred types of paper that cover the heat-conducting portion are paper treated with lip-free materials, and such types of paper will be apparent to those skilled in the art. The element must not burn freely while smoking a smoking article, must have controlled smoldering properties and must form gray ash. Known cigarette paper is described in US patent No. 4779.631 in the name of Durocher and others and in European patent application No. 304.766. Suitable wrapping paper is classified as P1961-152. P1961
124 and P1224-63, manufactured by Kimerli-Clark Corp.
Binding paper may limit the end of the smoking article that is inserted into the smoker's mouth. Corresponding paper types are non-poetic envelope types.
A section of the creased tobacco | umaga may be inserted into the inserted part of the mouth. Such a segment can be placed directly behind the heat-conducting element, which contains an erosol-forming material. A piece of charcoal paper folded into the folds can be included in the part inserted into the mouth, in order to introduce the menthol aroma into the aerosol. Suitable pieces of gum paper are described in European Patent Application No. 342.538. If necessary, a segment including a folded core made of non-woven polypropylene or polyester in close contact with a water-soluble tobacco extract can be inserted into the inserted mouth.
The mouth end of the smoking article preferably includes an iltrating element or tip, in particular for aesthetic reasons. Preferred filter elements pre-absorb the filter elements from the aerosol. Suitable filter media of low efficiency, which do not significantly interfere with the yield, are small, including ineffective cellulose acetate or polypromene acetate, cloisonne or fabricated in one-piece form polypropylene materials, or folded cores made of ethylene polypropylene materials. Suitable filter elements can be obtained by folding the non-woven polypropylene core, commercially available as PP-1OO-F from Kimberly-Clark Corp. using an apparatus for preparing a filter core in Example 1 of US Pat. No. 4,807,809 Prior and others.
The smoking articles of the present invention are capable of providing at least about 6 to about 10 puffs when smoking under FTC conditions. FTC smoking conditions are of 35 mm puff for 2 seconds, with an interval of 58 seconds of smoldering. A typical fuel cell of a preferred smoking article of the present invention produces less than about 300 calories, preferably in the range of about 200 to about 250 calories, when
I yes the product is smoked under FTC smoking conditions. During the period when a preferred smoking article is smoked, at least 40 percent.
preferably at least about 65 percent, more preferably at least about 75 percent of the heat produced by the combustible fuel cell is used to heat aerosol forming agents and to sequentially generate aerosol to dispense the aerosol in the main stream.
Preferred combustible fuel cells create temperatures from about 15 ° C to about 400 ° C to about 850 ° C, more preferably from about 400 ° C to about 700 ° C. Due to the relatively low temperatures and relatively small amounts of heat generated by the preferred fuel cells, typical smoking articles including such fuel cells emit less than about 10 mg, preferably less than about 5 mg, 25 and more preferably less. less than about 2 mg of carbon monoxide when smoked under FTC smoking conditions.
Preferred smoking articles according to the present invention are capable of dispensing at least about 0.6 mg of aerosol measured as wet particulate matter (VHPF) for the first 3 puffs when smoking under FTC smoking conditions. In addition, preferred smoking articles release an average of at least about 0.2 mg of HMSC per puff for at least 6 puffs. preferably at least about 10 puffs when smoking under 40 FTC smoking conditions. Highly preferred smoking articles emit at least about 5 mg of HMSC for at least 10 puffs when smoking under FTC smoking conditions.
The aerosol produced by the preferred smoking articles according to the present invention is chemically simple, consisting mainly of air, water, carbon oxides, aerosol forming agent, any flavorings or other volatile materials required, and trace amounts of other materials.
The HPMP produced by certain 55 preferred smoking articles according to the present invention has little or no measurable mutagenic activity when measured using the Ames test (i.e. there is a small or negligible dose response relationship between the HPMP obtained from the preferred cigarettes according to the present invention , and the number of revertants found in standard test microorganisms exposed to such products). According to those who offer the Ames test, a significant dose-dependent reaction indicates the presence of mutagenic materials in the test products. See Ames, et al. Mut.Res.31: 347-364 (1975) Nagao etal, Mut.Res. 42: 335 (1977).
The following examples are intended to further illustrate various embodiments of the present invention, but should not be construed as limiting its scope. Unless otherwise indicated, all parts and percentages are by weight.
Example 1. The cigarette shown in FIG. Type 1 is made as follows.
Fuel cell fabrication. The segmented fuel cell has a base, insulating and burning sections, and a total length of about 7 mm. The longitudinal length of the base portion is approximately 2 mm, the longitudinal length of the insulating portion is approximately 2 mm and the longitudinal length of the burning portion is approximately 3 mm. The cross-sectional shape of the base portion is rectangular, and the base portion is approximately 4 mm wide and approximately 5.4 mm in height. The cross-sectional shape of the insulating portion is square, and the insulating portion is about 4 mm wide and about 4 mm high. The cross-sectional shape of the burning portion is square, and the burning portion is about 4 mm high and about 4 mm wide. The fuel cell includes a hollow space having a rectangular shape, elongated approximately 2.5 mm longitudinally and 2.2 mm in the transverse direction. The hollow space is located 3 mm from the front end of the fuel cell and extends toward the end of the base of the fuel cell. Two grooves 0.4 mm wide and 1 mm deep pass through the front end of the fuel cell. The fuel cell weighs about 117 mg and has a density of about 1.8 g / cm ³ as determined using a helium pycnometer. There are no longitudinally extending channels for air to pass completely through the burning section or the base section of the fuel cell.
A fuel cell is obtained by extruding a paste from tobacco dust, coal from a hardwood core and a carboxymethyl cellulose binder, commercially available under the Hercules brand
7HFSCMC from Hernules Inc.
Coal from the core of hardwood is prepared by carbonizing talc-free varieties of hardwood kraft paper from the Canadian Canadian Prairies under a nitrogen protective layer, increasing the temperature stepwise enough to minimize paper oxidation to a final carbonization temperature of at least 750 ° C. The resulting carbon material is cooled under nitrogen to lower than 35 ° C and then ground to a fine powder having an average particle size of about 4 to about 8 microns in diameter.
About 74 parts of finely powdered hardwood coal are mixed with about 20 parts of fine tobacco dust and with about 6 parts of a sodium carboxymethyl cellulose binder and with enough water to produce a mixture in the form of a tough pasty paste,
Fuel cells are extruded from the paste using a piston extruder. The resulting extruder is air dried. Then the extrudate is cut into segments of 4 mm length, thus obtaining a plurality of fuel cells.
The holding element for the fuel cell.
The small cup is made of deep drawn aluminum sheet having a thickness of about 0.004 inches. The cup has sealed sides and a bottom and has open up. The height of the cup is approximately 2.9 mm. The two sides of the cup are parallel to one another, with the result that the cup is approximately 6.5 mm wide. The two sides of the cup are round, resulting in a maximum cup width of approximately 7.5 mm.
The fuel element is placed in the cup so that the end surface of the base of the fuel element remains on the inner bottom surface of the cup. The surface of the base of the fuel cell is parallel to the extruding axis of the fuel cell (i.e., the extruding axis of the fuel cell is perpendicular to the longitudinal axis of the main cigarette). The parallel sides of the cup are then bent over the portions of the front surface of the corresponding segments of the base of the fuel cell in order to hold the fuel cell securely in place inside the cup.
Thermally conductive cartridge and aerosol forming agent.
A cylindrical cartridge is made of 5 deep drawn aluminum sheet having a thickness of about 0.004 inches. The cartridge has a circular cross-sectional shape having an inner diameter of about 7.2 mm. One end of the chamber is open, and the other end is sealed, and the hole is approximately
1.5 mm pierced through the bottom surface of the gatronchik. The cartridge has a length of approximately 14 mm.
The cartridge contains 325 mg of aerosol-bracing material and a carrier for it. Carrier and aerosol converting material includes about 3.7 percent Fructose, about 11 percent spray-dried aqueous extract of tobacco in powder form, about 20 percent glycerin, about 0.1 percent chocolate-flavored oil and is generally api v, ¢: n πι method calling BET, and have a size of
65.2 percent of the bulbs from ilf-alumina. available on the market for sintered alpha-alumina D-2 from Irma U.R. Grace & Co. Balls have a surface area of approximately 4 m ² / g, approximately 8 m ² / g, as determined using 30 to +20 mesh (USA).
A holding element is introduced into the cartridge, so that the fuel element held in place by the holding element is elongated about 1 mm beyond the harmful portion of the cartridge. Holding 35
D | P
and, the element is held firmly in place in the cartridge chamber by means of a friction fit.
Mouthpiece and prefabricated cigarettes. A D1oy tube of approximately 78 mm and a diameter of approximately 7.7 mm is prepared from a roll of paper approximately 27 mm wide. The paper is 76 lb. mouthpiece paper having a thickness of about 0.012 ohm and supplied by Simpson Pzipe Co. The paper is formed into a tube by lapping the paper using ethylene vinyl acetate or an aqueous base.
A cartridge is inserted at one end of the paper tube so that the front surface of the fuel cell is on the same yf as the front end of the paper tube. As a result, the axis of extrusion of the fuel element is perpendicular to the longitudinal axis of the cigarette. The cartridge is held in place securely inside the paper tube by means of a friction fit.
A cylindrical filter element is inserted at the opposite end of the paper tube. The filter element has a length of about 10 mm and a circumference of about 24 mm. The filter element is obtained using well-known manufacturing techniques for filters from tow from cellulose acetate (8.0 denier per thread, 40,000 denier in total). and from the surrounding wrapper for paper cork.
The cigarette is lit and it emits visible aerosol and tobacco flavor (i.e., volatilized tobacco components) for all puffs, which are approximately
10.
PRI me R 2. Cigarettes of the type depicted in FIG. 1, manufactured mainly as. described in example 1, except that the following fuel cells are used:
The fuel cell, divided into segments, has a base section, insulating and burning sections; and a total length of about 7 mm. The fuel cell has the form generally shown in FIG. 11. The longitudinal length of the base portion is approximately 2 mm, the longitudinal length of the insulating portion is approximately 2 mm, and the longitudinal portion of the combustible portion is approximately 3 mm. The cross sectional shape of the base portion is rectangular, and the base portion is approximately 5.6 mm in height and approximately 4 mm in width. The outer cross-sectional dimensions of the insulating section increase from the burning section to the base section. The cross-sectional shape of the burning section is square, and the burning section has about 4 mm of height and about 4 mm of width. The fuel cell includes a hollow space having a triangular shape, elongated longitudinally 2.5 mm and 2.2 mm transversely. The tip of the triangular hollow space is located 3 mm from the front surface of the fuel cell and is extended toward the end of the base of the fuel cell. A fuel cell weighs about 109 mg and has a density of about 1.8 g / cm ³ as determined using a helium pycnometer. There are no longitudinally extending air passage channels passing through the burning section or the base section of the fuel cell.
A fuel cell is obtained by extruding a paste of tobacco dust, charcoal from a hardwood core, and a sodium salt binder carboxymethyl cellulose commercially available as Hercules 7HFSCMC from Hercules Inc.
Hardwood core charcoal is prepared as described in Example 1.
About 90 parts of finely powdered hardwood coal are mixed with about 10 parts of a sodium carboxymethyl cellulose binder and with enough water to form a mixture in the form of a tough pasty paste.
Fuel cells are extracted from this paste using a piston extruder. The resulting extrudate is dried in air. The extrudate is then cut into pieces of about 4 mm length, resulting in a plurality of fuel cells.
A cigarette is smoked while smoking FTC. A cigarette emits about 0.7 mg of glycerol during the first 3 puffs and about 0.8 mg of glycerol during the second 3 puffs. The cigarette emits visible aerosol and tobacco flavor for all puffs for approximately 13 puffs. The cigarette exhibits a pressure drop of approximately 65 mm H 2 O at 17.5 cm ³ / s airflow, which is measured using a filter filter test setup (CTS model), supplied by Filterron Instrument & Automation Ltd.,
Example 3. Cigarettes are made as described in Example 2, except that the following carrier materials and aerosol forming material are used:
The cartridge contains two segments of carrier materials. One segment, located directly behind the retaining element, consists of approximately 140 mg of balls of alumina and aerosol-forming material described in Example 1. The second segment, located behind balls of alumina, consists of glycerol contained in collected folds of paper wrapped in paper wrapper. The creased paper has a common cylindrical shape and has a length of about 3.3 mm and a circumference of about 23.2 mm. The longitudinal axis of the cylindrical paper carrier is parallel to the longitudinal axis of the cigarette. The creased paper is supplied as MS2408 / S538 from Filtron Ltd. and is folded into a segment weighing approximately 25 mg. Approximately 45 mg of glycerol is added to the collected 8 folds of paper.
The cigarette is lit and it emits visible aerosol and tobacco flavor (i.e., volatilized tobacco components) for all puffs for about 13 puffs.
The cigarette shows a pressure drop of approximately 90 mm water column at
17.5 cm ³ / s using the device described in Example 2.
Example 4. Cigarettes of the type depicted in FIG. 17 are manufactured as follows.
Fuel cell fabrication. The fuel cell 10, divided into sections, has a base section, insulating and burning sections, and a total length of about 14 mm. The longitudinal length of the base portion is approximately 3 mm, the longitudinal length of the insulating portion is approximately 15 but 8 mm and the longitudinal length of the burning portion is approximately 3 mm. The cross-sectional shape of the base portion is circular, and the base portion is approximately 4.5 mm in diameter. The insulating portion 20 is typically rectangular in cross-sectional shape, and the insulating portion has a width of about 4.5 mm and a thickness of about 2 mm. The cross-sectional shape of the burning section is round, and the burning section 25 is approximately 4.5 mm in diameter.
The fuel cell includes 2 grooves made along the entire length of the fuel cell, which are approximately 180 ° apart on each side of the fuel cell. Each groove is approximately 0.75 mm wide and approximately 1.5 mm deep. A fuel cell weighs about 163 mg and has a density of about 163 mg and a density of about 1.8 g / cm ³ , as determined using a helium picnometer.
A fuel cell is obtained by extruding a paste from tobacco dust, coal from a hardwood core, and 40 binder from disodium salt of carboxymethyl cellulose, supplied in the form of Nehe le 7NHGMSC from Hercules Inc.
Coal from the core of hardwood is usually obtained as described in Example 45-1, and ground to a fine powder having an average particle size of about 10 to about 14 microns in diameter.
About 72 parts of finely powdered hardwood coal 50 are mixed with about 20 parts of fine tobacco dust and about 8 parts of a disodium binder of carboxymethyl cellulose and with enough water to produce a mixture having the form of a 55 tough, pasty paste. Tobacco dust is prepared by grinding crumbled tobacco of the American mixture type on a ball mill to a particle size of about 12 microns in diameter,
Fuel cells are extruded from the mouthpaste using a piston extruder. The extrudate extrusion axis is such that the extrusion axis of the obtained fuel element is parallel to the longitudinal axis of the cigarette into which the fuel element is inserted. The extrudate is extruded so that 2 grooves extend along its length. The resulting extrudate is air dried. Then, the dried extrudate is cut into 14 mm lengths, whereby many fuel cells are obtained, the fuel elements are mechanically processed using a diamond cutting disc to obtain an insulating segment. ] Getting the front end. The fuel cell is covered with fiberglass of the type described on pages 48-52 Chemical and Biological Studies of Nav Cigarette Prototypes Phat Heat Instead of Born Tobacco (Chemical and biological studies of new prototypes of cigarettes that are heated instead of burning tobacco), publication by R.J. Reynolds Tobacco Co., (1988) Fiberglass, in turn, is covered by a paper wrapper available on the market in the form of P-850-63-5 from Kimberly-Clark Corp. in order to obtain a cylinder having open ends for passage through them of air, length 30 approximately 14 m and with a circumference of about 7, 5 mm.
Cooking media. The core of pleated filter paper, available on the market in the form of MS2408 / S538 og from Filtron Ltd., is expanded to a length of approximately 5 mm, a length of approximately 3 mm and a diameter of approximately 3 mm piercing through the center of the cut . This stretch has a dry weight of about 55 mg, and about 125 mg of glycerol D is added to the carrier.
Cigarette holder A tube with a length of peimerno 63 mm and a diameter of about 7.5 | M is prepared from a paper tape with a width of winterly 27 mm. The paper is 76 pound mouthpiece paper having a thickness of about 0.012 inches and is inserted from Simpson Paper Co. ha paper is formed in the form of a tube pu35
1О | 1 п This volume of lap compound of this paper using ethylene vinyl acetate adhesive <1 based on water. The inner surface of the tube is covered with Nehsop 70 from Hercules Inc., about 10 mm into the tube, and allowed to dry. Then the inner surface of the coated tube is coated with an aqueous solution of calcium chloride and allowed to dry.
A carrier is inserted at the end of the coated paper tube at the end so that the front surface of the carrier is about 3 mm from the front end of the paper tube. The media is held securely in a paper tube by friction adjustment.
A cut of 10 mm length of crushed tobacco wrapped in a paper wrapper is introduced into the opposite end of the tube. This segment is introduced into the tube so that the posterior end of this segment is approximately 10 mm from the extreme end of the tube facing the mouth.
At the end of the paper tube, opposite the carrier, a cylindrical filter element is inserted so as to abut against a length of crushed tobacco. The filter element has a length of about 10 mm and a circumference of about 24 mm. The filter element is prepared using the well-known manufacturing technology of a filter from tow from cellulose acetate (0.8 denier per filament, 40,000 denier total), plasticized using triacetin, and covering a paper wrapper.
Assembly of cigarettes. The part inserted into the mouth and the front end are installed end-to-end, abutting against each other, so. that the front surface of the carrier is approximately 3 mm from the rear surface of the fuel cell. The front end and the parts inserted into the mouth are held together by a wrapping paper wrapper that acts as a tip paper. The paper wrapper is a non-porous paper and is commercially available in the form of P-850-61-2 from Kimberly-Clark Corp. and covers the entire length of the front end part, with the exception of about 3 mm of the length of the front end part at its extreme end for lighting .
The cigarette does not contain a metal thermally conductive cartridge, does not contain metal holding means and does not contain metal components in the carrier. The fuel cell is held firmly in place inside the cigarette using insulating glass fibers that enclose the fuel cell.
The cigarette is lit and the visible aerosol and tobacco flavor (i.e., volatilized tobacco components) are emitted from all puffs for about 10 puffs. The fuel cell burns to about the area where the burning portion meets the insulating portion and the cigarette fades out on its own.
Example 5. Cigarettes are made as described in example 4, except that the following configuration and carrier materials are used:
The carrier has almost the same dimensions as described in example 4, except that the section having a length of about 5 mm is presented in the form of a tube of wound paper, available on the market in the form of P-1981-152 from Kimberly Clark Corp., and an inner section having a length of about 2 mm and a diameter of about 3 mm, are obtained by folding into folds of paper available on the market in the form of P-780-63-5 from Kimberly-Clark Corp.
A detail of the last end is obtained by covering the fuel cell and fiberglass with paper commercially available in the form of P-850-63-5 from Kimberly-Clark Corp., and then covering it with paper commercially available in the form of P-850-61-2 from Kimberly-Clark Corp., except for a length of approximately 3 mm at the front end at its extreme end for ignition.
A Simpson Pepe Co. mouthpiece paper tube having a length of approximately 74 mm is inserted over the front end part so as to leave the front 3 mm front end parts out and held in place by a friction fit. The inner surface of the tube is coated using the material and technology of Example 4. The carrier is positioned inside the tube so that the rear surface of the fuel cell and the front surface of the carrier are approximately 33 mm in the compartment.
The remaining components of the cigarette perform almost as described in example 4.
A cigarette is lit, and it emits a visible aerosol and tobacco flavor (i.e., volatilized tobacco components) for all puffs for about 10 puffs. The fuel cell burns to about its area where the burning section meets the insulating part and the cigarette goes out by itself.

权利要求:
Claims (15)
[1]
Claim
1. A smoking article containing a combustible fuel element: a means physically separated from it that creates an aerosol, a holding means, a mouthpiece and tobacco, characterized in that, in order to efficiently use the heat generated by the fuel element, the latter is divided longitudinally into a burning section , the base portion and the insulating portion located between them, and the holding means is arranged to contact the base portion of the fuel cell to fix it in a predetermined position and inside the product.
[2]
2. Product pop. 1, characterized in that the aerosol generating means is disposed longitudinally to the fuel cell.
[3]
3. Product pop. 1, characterized in that it has a fence radially located with a gap relative to the longitudinal outer periphery of the burning section of the fuel cell.
[4]
4. The product according to paragraphs. 1-3, characterized in that the fuel cell is at least 20 mm long.
[5]
5. The product according to paragraphs. 1-3, characterized in that the fuel cell includes at least one transverse cavity.
[6]
6. Product pop. 1, characterized in that the length of the burning section is 4-15 mm, the length of the base section is 1-3 mm, and the length of the insulating section is not more than 5 mm. ^:
[7]
7. The product according to claim 1, characterized in that the aerosol generating agent includes a substrate carrying an aerosol forming material, tobacco is a tobacco extract located on a substrate.
[8]
8. A smoking article containing a mouthpiece, tobacco, a fuel cell and an aerosol forming means physically separated from it, characterized in that the fuel cell is extruded and located inside the product so that the extrusion axis is perpendicular to the longitudinal axis of the product, the last one holding means for securing the fuel element in a predetermined position.
[9]
9. The product according to claim 8, with the proviso that the extruded fuel element is longitudinally divided into a burning section and a base section.
[10]
10. The product according to claim 9, characterized in that the fuel cell includes an insulating section located between the burning section and the base section.
[11]
11. The product according to claim 8, as follows, in that the aerosol generating agent is positioned longitudinally to the fuel cell.
[12]
12. The product according to paragraphs. 9 and 10, characterized in that it has a guard radially located with a clearance relative to
18378'15 along the longitudinal outer periphery of the burning portion of the fuel cell.
[13]
13. The product according to paragraphs. 8-10, characterized in that the length of the fuel cell is not more than 20 mm
[14]
14. The product according to paragraphs. 8-10, characterized in that the fuel cell includes at least one transverse cavity.
[15]
15. The product according to claim 8, characterized in that the aerosol generating medium includes a substrate carrying the aerosol forming material, tobacco is a tobacco extract and is located on the substrate.
5B 44 23 13 17 52 60 61 28 68
Fig-2. ^θ
FIG. fifteen
FIG.5
FIG. 9
F IG. 10
FIG. II
Pei duct
Order 2876
FI G. 12 FIG. thirteen

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同族专利:

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公开号 | 公开日

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US5027837A|1991-07-02|

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法律状态:

优先权:

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申请号 | 申请日 | 专利标题

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US07/488,516|US5027837A|1990-02-27|1990-02-27|Cigarette|

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