• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:

    公开号:SU1805884A3
    申请号:SU904742818
    申请日:1990-01-09
    公开日:1993-03-30
    发明作者:Din Barns Rassel；Rodzher Shelar Gari；Pol Balvinkel Edvard；Frensis Kartrajt Uilyam；Yudzhin Chembers Ml Leon；Frensis Durocher Donald；Dzhilett Dzhir Robert；Dzhordzh Kasbo Lojd；Robert Radvanski Fred
    申请人:Reynolds Tobacco Co R；
    IPC主号:
    专利说明:

    SUBSTANCE: invention relates to a device for the manufacture of harnesses for use in the manufacture of smoking articles having a fuel cell, a separated physically generating aerosol means and an improved mouthpiece for delivering the resulting aerosol to a user. The mouthpiece consists of a non-woven fabric of fibers or threads of thermoplastic in the form of an ineffective thermodispersive mass of material in the form of a filter-plug. The mouthpiece may also include a spacer member located between the thermoplastic body and the aerosol generating means. It has been found that, unlike conventional mouthpieces such as cellulose acetate stopper, use (57) Use: for making tows in the manufacture of smoking articles having a fuel cell, a separated physically aerosol-generating means, and a mouthpiece that includes a segment of nonwoven fibers or thermoplastic filaments. The essence of the invention: the device contains means for feeding fibrous material into means for assembling and forming fibrous material into a cylindrical rod, means for wrapping it with the formation of an endless rope and means for its subsequent division into segments of a given length. The means for assembling and forming the fibrous material comprise two cones Λ installed coaxially with the formation of an annular space between them. 2 ill.
    improved mouthpiece according to the present invention reduces the temperature of the aerosol perceived by the consumer, but not. interferes with the delivery of the required quantities of aerosol.
    _ Preferably, smoking articles using the improved mouthpiece are in the form of a cigarette that uses a short fuel cell, preferably carbon, less than 30 mm in length. Preferably, the aerosol generating means is also in conductive heat exchange communication with the fuel cell. The mouthpiece portion according to the invention preferably comprises a cylindrical web segment of nonwoven thermoplastic rasrla
    SU ,,,, 1805884 AZ of water flow fibers that are collected or folded into a conventional filter plug with a length of 10-40 mm, preferably 15-35 mm, together with an assembled or folded tobacco paper spacer with a length of about 5-30 mm, preferably 5- 15 mm between the nonwoven segment and the aerosol generating agent.
    Conventional cigarette holders usually consist of moderate to high efficacy filter materials such as cellulose acetate wadding. Such materials usually have fibers that are oriented primarily in the direction of smoking, which can lead to air being channeled through a relatively small portion of the filter. It is not difficult to see, for example, when smoking filter cigarettes, that only a part of the filter is discolored, which indicates a smoke channeling in this part of the filter. This drainage effect is often felt by the consumer as a hot spot on the lips or tongue.
    It has been found that an improved mouthpiece in accordance with the present invention and. in particular, the nonwoven fabric component of thermoplastic acts as a heat sink and helps to reduce the perception of hot spots by distributing the generated aerosol over a large surface area, preferably substantially over the entire surface area of the mouthpiece component (s). Aerosol distribution over the large surface area appears to contribute to the perceived temperature reduction by increasing the residence time of the aerosol in the mouthpiece, and in particular in the nonwoven thermoplastic segment. In addition, unlike conventional mouthpieces, which are typically used to filter out significant amounts of various undesirable components of tobacco smoke, smoking articles using a thermoplastic nonwoven material as a mouthpiece in accordance with the present invention provide a similar perceived temperature reduction without significantly reducing the delivery of aerosol components. for example, glycerin, flavoring agents, and the like. In other words, the filtering effect. The efficacy of such materials is significantly lower than that of educational cigarette filter media such as cellulose acetate wadding, which is essential to maintain the required aerosol delivery of the smoking articles of the present invention, while allowing the use of longer material sections to provide increased residence time and aerosol cooling.
    The preferred spacer element, like the nonwoven thermoplastic segment, is a predominantly low efficiency filter material and also acts as a heat sink that not only helps to reduce the temperature of the aerosol perceived by the consumer, but helps to overcome unwanted decomposition or melting of the nonwoven thermoplastic material.
    Preferred smoking articles using the improved mouthpiece of the present invention are capable of delivering at least 0.6 mg aerosol, as measured by the Wet Total Particulate Matter (TOTM) Index, during the first three puffs when smoked under FCC Regulations ( FKT), which consist of 35 ml puffs of 2 s duration, separated by 58 s smoldering. More preferably, embodiments of the invention are capable of delivering 1.5 mg or more aerosol during the first 3 puffs. Most preferably, embodiments of the invention are capable of delivering 3 mg or more aerosol during the first 3 puffs when smoking according to FCT norms. In addition, preferred embodiments of the invention deliver, on average, a minimum of 0.8 mg of WODI per puff during the first 6 puffs, preferably at least 10 puffs, in a smoking environment according to the FCT guidelines.
    In addition to these advantages, preferred smoking articles according to the present invention are capable of producing an aerosol that is chemically simple and consists essentially of air, carbon monoxide, water, an aerosol former, possibly desired flavors or other desirable volatile materials, and traces of other materials. The aerosol preferably does not exhibit significant mutagenic activity as measured by the Ames test. In addition, preferred articles can be made substantially ash-free so that the consumer does not have to shake off the ash during use.
    As used herein, and for the purposes of this application only, the term aerosol is defined to encompass vapors, gases, particles, etc., both visible and invisible, and especially those components that are perceived by the consumer as smoke-like, emitted under the effect of the heat from the combustion of the fuel cell on the substances contained in the aerosol-generating means, or elsewhere in the article. As defined in this way, the term aerosol also includes volatile fragrances and / or pharmacologically or physiologically active substances, regardless of whether they produce a visible aerosol.
    As used herein, the phrase conductive heat exchange coupling is defined as the physical arrangement of the aerosol generating means and the fuel cell by which heat is transferred by conduction from the burning fuel cell to the aerosol generating means during substantially the entire burning period of the fuel cell. Conductive heat exchange connection can be achieved by placing an aerosol generating means in contact with the fuel cell and thus in close proximity to the burning part of the fuel cell, and / or by using a conductive element to transfer heat from the burning fuel to the generating fuel. aerosol to the agent. Preferably, both methods of providing conductive heat transfer are used.
    As used herein, the term carbonaceous means substances containing mainly carbon. ...
    As used herein, the term "insulating element" applies to all materials that act primarily as insulators. Predpochty- 40: Tel'nykh, such materials do not burn during use, but they may include slow burning carbons and like materials, as well as materials that are melted when used; for example 45 low temperature fiberglass grades. Suitable insulators have a thermal conductivity (in g-cal / s (cm 2 ) (° C / cm) less than 0.05, preferably less than 0.02, most preferably less than 0.005 ... 50
    Smoking articles that use the filter material of the present invention are discussed in more detail in the accompanying drawings and in the detailed description of the invention 55 below.
    1 is a schematic illustration of a method for forming a strip of meltblown thermoplastic in the form of a cylindrical segment in the shape of a filter plug; Figure 2 is a double conical system used to collect or fold material in the shape of a filter plug.
    In accordance with the invention, an improved mouthpiece for use in smoking articles is provided. The mouthpiece is particularly suitable for smoking articles having a burnable fuel cell and a separated physically aerosol generating means.
    In general, the improved mouthpiece includes a segment formed from a nonwoven web of thermoplastic fibers or filaments and may also include a spacer member located between the segment of thermoplastic fibers and the aerosol generating means.
    Preferred means for making such thermoplastic webs are based on melt blowing.
    The thermoplastic web can be formed into a cylindrical or other shaped element using traditional filter plug technology, such as the conventional tow-makers used to make cellulose acetate filter inserts.
    Figure 1 illustrates means for forming a filter plug web. As shown schematically in FIG. 1, a roll 1 of thermoplastic fiber web 2 is wound and pulled and a preforming cone 3 which collects or folds a flat web in the form of a cylinder suitable for passing through filter plugs. A paper web 5 (the so-called filter wrapper) is wrapped on the cylinder 4 formed in this way, and this combination is cut into the required lengths 6 using a knife 7. Before entering the set, a continuous bead of glue is applied to one edge of the wrapper using a applicator. During the passage of these components through the garment, the formed strip of web is additionally crimped in the form of a rod with a cylindrical section while being wrapped with a filter wrapper 5. When the bead of adhesive touches the overlapping section of the wrapped rod, the sealing bar is sealed. This endless filter rod is then cut into lengths 6 using a cutter 7.
    Although not essential for making acceptable filter plugs, the thermoplastic fabric is self-sufficient.
    1805884 8 is pretreated before being formed into a core. Two such treatments, illustrated in FIG. 1, may involve the use of a pair of grooved rollers 8 used for corrugation 5 and a nanoCarrier fluid 9 used for surface treatment of the material with, for example, glycerin or other humectants.
    In an alternative 10, the double cone system shown in FIG. 2 is preferably used instead of a single cone 3. Such a system comprises a cone within a cone as a preforming apparatus. The thermoplastic web is threaded into the annular space between the cones in a substantially unstressed state, for example at the point of entry, and the web material is wrapped around the radial portion of the inner cone. The cones can be moved relative to each other to achieve the required uniformity and density of the notch filter.
    While most thermoplastic polymers can be used to prepare the web material for the segment of thermoplastic fibers 25, polyolefins such as isotactic polypropylene and polyesters such as poly (butylene terephthalate) 30 are preferred. Due to the nature of the melt blown thermoforming process, various additives (e.g. , calcium carbonate) can be easily introduced into the polymer melt or blown onto the surface of the molten polymer during extrusion to change the structure of the meltblown web and thus its characteristics in the filter element. 40 In addition, the webs obtained by blowing. After being molded, they can be easily subjected to known subsequent treatments with auxiliary agents in dry or liquid form in order to impart certain organoleptic and / or medical properties.
    The basis weight of such a web can vary depending on a number of factors, including the process used to form the web material as well as the particular thermoplastic polymer used. For preferred polypropylene meltblown materials, the basis weight is preferably 55 0.5-1.0 oz / yd. '
    The tensile strength of such webs when attached to the grippers can also fluctuate, but generally it is 0.1 to 3.0 pounds in the CD direction, and at least 0.1 pounds in the processing direction ( MD). Preferred ranges are 0.7-2.4 pounds in the technology direction and 0.5-2.3 pounds in the cross direction. Preferred webs also have a grip tensile strength providing an MD / CD ratio in the range of 1: 1-4: 1, preferably 1: 1-2: 1. test standard No. 191A by the Instron Corporation Model 1122 Testing Machine. This strength is usually determined by a number of factors, including fiber orientation with respect to processing direction and transverse direction, the degree of fiber fusion and distribution of fiber width.
    Fraser porosity for such webs can also range from 1001000 cfm / sqft / min, preferably in the range 150-1000 cfm / sqft / min (for a 5-layer sample). Fraser porosity tests for such materials are performed using the Fraser Air Permeability Tester, available from Fraser Presision Instrument Company. These porosity measurements reflect the breathability of the web. The procedure meets the requirements of Method 5450, Federal Standard No. 191A for testing, except that the sample size is 8 "* 8" and a 5-layer sample is used for measurements at a 20 mm air nozzle. Fraser units are expressed in. cubic feet of air per square foot of samples in 1 min.
    The percentage of open area for such webs is typically 10-60%, with a preferred range of 14-52%. The percentage of open area is a measure of openness and can be measured using an image analyzer type Kvantymet model 970, manufactured by Cambridge Instruments. This indicator is very significant in determining the filtration characteristics of cylinders made from webs in accordance with the present invention.
    A particularly preferred web suitable for forming the improved plug filter of the invention is an experimental meltblown polypropylene material marketed by Kimberly-Clark Corporation under the brand name PP-100-F. This particular material has a Fraser permeability of about 600, tensile strength in grips of about 1.3 lb (MD) and 0.7 lb (CD), and a basis weight of 0.75 oz / yd. This material also contains 2 wt. .% to facilitate the formation of the material in the form of a cylinder. The amount of glycerin or other humectant can range from 0.5-8%, preferably 1-4%, most preferably 1.5-2.5%. Such materials are described in more detail in US patent application No. 003980, filed January 16, 1987, which is incorporated herein for reference purposes.
    From a performance and aesthetic standpoint, the stiffness of the thermoplastic segment filter used in accordance with the present invention can vary widely without significantly interfering with the delivery of the aerosol to the consumer. However, it is desirable for the segment to provide the feel and harshness of a cigarette using conventional cellulose acetate filters. Although there are many ways to assess the stiffness of the filter material, the stiffness values for segments of thermoplastic fibers obtained from the Kimberly-Clark Corporation, brand PP-100-F; was determined by placing a filter plug under a plate with a diameter of 19 mm. The plate was brought into contact with the filter and an initial diameter reading was taken without compression. In this property, an actual force of the order of 27 g was created on the filter. Then the plate was loaded with an additional force of 100 g. After 10 under this load, a second reading was taken. This stiffness indicator was indicated as a percentage and was calculated by multiplying by 100 the ratio of the second indicator to the first. In general, the hardness of the filter is 94-99%, preferably 96-98%.
    The total pressure drop for articles using the improved mouthpiece according to the invention is preferably similar to or lower than that of conventional cigarettes. The pressure drop across the mouthpiece itself fluctuates depending on the pressure drop at the front end of the smoking article. For preferred smoking articles, such as those described below in Example 1, the pressure drop is generally lower than that of conventional mouthpieces, 'being, v,'. '.
    water column / cm of filter length, preferably 0.5-4.5 cm / cm, and most preferably 0.7-1.5 cm / cm. Drop in pressure. represents the pressure drop in • centimeters of the water column when 1050 cm ^ / min of air passes through the filter. These pressure drops can be normalized to the unit of filter slug length by dividing by the actual filter length.
    The filter efficiency per unit length of the nonwoven fiber segment of the thermoplastic prepared according to the present invention is generally lower than that of a conventional cellulose acetate filter. Preferably, the effectiveness of such materials is lower than that of low performance cellulose acetate tow filters made from 8.0 / 40K material obtained from Salanis Corporation. As noted above, the mouthpiece of the invention helps to reduce the temperature of the aerosol as perceived by the consumer, for example by distributing the aerosol generated during smoking over a larger surface area. The use of low performance materials according to the invention, however, also allows the use of longer segments of nonwoven thermoplastic fibers without interfering with the desired aerosol delivery. This increases the residence time of the aerosol in the mouthpiece, which also helps to reduce the temperature of the aerosol as perceived by the consumer.
    The length of the segment of nonwoven fibers of thermoplastic used in the mouthpiece can vary widely depending on a number of factors, including the desired reduction in the temperature of the aerosol perceived by the consumer. For preferred smoking articles using a mouthpiece according to the invention, the thermoplastic segment is typically 10-40 mm long, preferably 15-35 mm, most preferably about 30 mm.
    The spacer element preferably used in the practice of 45 of the invention can be made from a variety of materials such as cellulose acetate tow and materials such as pipe containing tobacco.
    The preferred material for constructing the spacer is tobacco-containing paper. A preferred tobacco-containing paper is a regenerated tobacco web.... .... note of the material obtained from the company is usually 0.1-6.0 cm 55 Kimberly-Clark Corporation under the brand name '! P144-185-CAPF Reconstituted Tobacco Sheet
    The material comprises about 60% tobacco, mainly in the form of burgundy tobacco stalks, and 35% softwood pulp (dry weight basis 35
    40.
    su material). The moisture content in the sheet material is preferably 1114%. The material has a dry tensile strength of 1600-3300 g / in and a dry weight of 38-44 g / m 2 . The material is manufactured using a conventional papermaking process, with the addition of 2% glycerin or other humectant, 1.8% potassium carbonate, 0.1% flavors and 1% commercial sizing agent available under the brand name Aquaped 360jcc Reactive Size from Hercules Corporation.
    Tobacco paper can be cork shaped using cork learning techniques. However, for smoking articles using a mouthpiece according to the invention, it is preferred to be molded with a double cone system to form a segment of nonwoven thermoplastic fibers.
    The length of the spacer is generally inversely proportional to the length of the nonwoven thermoplastic fiber segment. For preferred smoking articles using the mouthpiece of the present invention, it is typically 5-30 mm, preferably 5-15 mm, most preferably about 10 mm.
    The combination fuel cell - capsule in the shell was inserted into the channel of the tobacco rod until the fiberglass shell was in contact with the tobacco. The fiberglass and tobacco sections were combined together under a single outer wrap that encloses both the fuel cell, insulating jacket and outer wrap combination and the wrapped tobacco rod. The outer wrapper was Kimberly-Clark P1768-65-2. "
    The mouthpiece was formed by joining two sections: 1) a separating element 10 mm long and 7.5 mm in diameter, near the cap of Sula, made of tabular sheet material obtained from the Kimberly-Clark corporation and having the P mark, 144-185-CAPF. wrapped with Kimberly-Clark P850-186-2 paper, and 2) a cylindrical segment of nonwoven fabric of thermoplastic meltblown polypropylene fabric manufactured by Kimberly Clark Corporation and PP-100-F, and wrapped with P1487-184-2 paper manufactured by the Kimberly-Clark Corporation. Both sections were prepared by passing tobacco paper and thermoplastic fiber webs with the double cone system described above. The two sections were joined with P850-186-2 wrapping paper from the Kimberly Clark Corporation.
    The composite mouthpiece section was connected to the fuel cell - capsule in the shell section by final wrapping them with bonding paper of 30637-801-12001 brand from Ekusta.
    The smoking articles thus produced produced aerosol-like tobacco smoke without any undesirable aftertaste due to the burning off or thermal decomposition of the aerosol-forming material. The manufacture of the article in this manner was smoked under conditions simulating human smoking, in which puffs of 50 ml of 2 seconds duration were made, separated by 28 seconds of smoldering. There were at least 6 puffs. The temperature of the heat at the lips, measured with a portable thermometer for measuring heat radiation Cyclops! '' At an area located approximately 4 mm from the end of the mouthpiece, was less than or equal to body temperature. In other words, such products created an aerosol without the unwanted hotness felt by those who use similar products without an improved mouthpiece.
    权利要求:
    Claims (1)
    [1]
    Claim
    A device for making tows in the manufacture of smoking articles, comprising means for feeding fibrous material into means for assembling and forming fibrous material into a cylindrical rod, means for wrapping it to form an endless tow and means for subsequently dividing it into a plurality of lengths of predetermined length, differing in that, in order to improve the quality of the manufactured tows for their use as ineffective filters, the means for assembling and forming the fibrous material contain two cones installed coaxially with the formation of an annular space between them.
    "
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    EP0304759A2|1989-03-01|
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    FI84550C|1991-12-27|
    CS274474B2|1991-04-11|
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    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    RU2633855C2|2012-02-08|2017-10-18|Эссентра Филтер Продактс Девелопмент Ко. Пти. Лтд|Tobacco smoke filter|
    RU2732956C2|2015-10-08|2020-09-25|Филип Моррис Продактс С.А.|Method of adjusting diameter of elongated rod|US2001709A|1932-02-27|1935-05-21|Davidson Glenn|Cigarette mouthpiece or the like|
    US2039298A|1932-12-03|1936-05-05|Davidson Glenn|Cigarette mouthpiece|
    US2164702A|1936-02-29|1939-07-04|Davidson Glenn|Method and apparatus for making cigarette mouthpieces|
    US2202839A|1936-05-04|1940-06-04|Davidson Glenn|Cigarette mouthpiece|
    BE535871A|1954-02-23|
    US2907686A|1954-12-23|1959-10-06|Henry I Siegel|Cigarette substitute and method|
    US2900989A|1955-01-26|1959-08-25|Davidson Glenn|Cigarette filter tip|
    US3226795A|1959-08-12|1966-01-04|Celanese Corp|Method for producing a high bulk filamentary material|
    US3110642A|1960-09-09|1963-11-12|Eastman Kodak Co|Method of producing a fibrous product from extruded organic thermoplastic filaments|
    US3329544A|1961-05-11|1967-07-04|Cigarette Components Ltd|Method of producing filter cores|
    US3119396A|1961-05-24|1964-01-28|Minnesota Mining & Mfg|Tobacco smoke filter|
    US3258015A|1964-02-04|1966-06-28|Battelle Memorial Institute|Smoking device|
    US3396061A|1964-06-01|1968-08-06|Celanese Corp|Smoke filters|
    US3353543A|1964-12-02|1967-11-21|American Filtrona Corp|Smoke filter|
    US3356094A|1965-09-22|1967-12-05|Battelle Memorial Institute|Smoking devices|
    US3393685A|1965-10-24|1968-07-23|Eastman Kodak Co|Self-crimping, self-bonding fibrous polyolefin tobacco smoke filter|
    US3407822A|1966-02-07|1968-10-29|Eastman Kodak Co|Tobacco smoke filters containing polyethylene encapsulated cellulose particles|
    DE1560800A1|1966-02-10|1971-01-07|Lutravil Spinnvlies|Method and device for the production of mixed nonwovens by melt spinning|
    US3396733A|1966-03-23|1968-08-13|Lorillard Co P|Cigarette tip|
    US3461882A|1967-05-08|1969-08-19|Celanese Corp|Method of filtering tobacco smoke|
    US3538920A|1967-08-09|1970-11-10|Polymer Corp|Polyamide smoke filter|
    US3516417A|1968-04-05|1970-06-23|Clayton Small Moses|Method of smoking and means therefor|
    GB1234134A|1968-05-15|1971-06-03|
    US3595245A|1968-08-14|1971-07-27|Exxon Research Engineering Co|Cigarette filter from polypropylene fibers|
    US3978185A|1968-12-23|1976-08-31|Exxon Research And Engineering Company|Melt blowing process|
    US3849241A|1968-12-23|1974-11-19|Exxon Research Engineering Co|Non-woven mats by melt blowing|
    US3861404A|1970-03-23|1975-01-21|Monsanto Chemicals|Tobacco smoke filter|
    US3852007A|1970-05-13|1974-12-03|Celanese Corp|Apparatus for making filters|
    US3939849A|1970-11-18|1976-02-24|Monsanto Chemicals Limited|Filter elements|
    CA956537A|1970-11-18|1974-10-22|Monsanto Chemicals Limited|Filtering elements|
    US3749685A|1972-01-26|1973-07-31|Philip Morris Inc|Microporous vinyl chloride polymers and process for producing|
    JPS519039B2|1972-03-23|1976-03-23|
    US3930077A|1972-03-24|1975-12-30|Celanese Corp|Filters|
    US4044777A|1972-04-20|1977-08-30|Gallaher Limited|Synthetic smoking product|
    IE37524B1|1972-04-20|1977-08-17|Gallaher Ltd|Synthetic smoking product|
    GB1442593A|1972-04-20|1976-07-14|British Ropes Ltd|Filter material|
    GB1381800A|1972-04-26|1975-01-29|Rothmans Of Pall Mall|Filter for tobacco smoke|
    US4059121A|1973-04-20|1977-11-22|Rothmans Of Pall Mall Canada Limited|Filter for tobacco smoke|
    US3887730A|1972-08-21|1975-06-03|Philip Morris Inc|Microporous styrene polymers and method of making same|
    US3888610A|1973-08-24|1975-06-10|Rothmans Of Pall Mall|Formation of polymeric fibres|
    US3860011A|1973-08-27|1975-01-14|Liggett & Myers Inc|Hollow filter|
    GB1482216A|1974-04-11|1977-08-10|Monsanto Ltd|Cigarette filters|
    DE2623844A1|1976-05-28|1977-12-08|Hoechst Ag|CIGARETTE FILTER|
    US4286604A|1976-10-05|1981-09-01|Gallaher Limited|Smoking materials|
    US4079742A|1976-10-20|1978-03-21|Philip Morris Incorporated|Process for the manufacture of synthetic smoking materials|
    US4284089A|1978-10-02|1981-08-18|Ray Jon P|Simulated smoking device|
    WO1980001132A1|1978-12-11|1980-06-12|Gallaher Ltd|Smoking product and method for the preparation|
    US4355995A|1979-03-27|1982-10-26|American Filtrona Corporation|Tobacco smoke filter providing tobacco flavor enrichment, and method for producing same|
    US4291711A|1979-03-27|1981-09-29|American Filtrona Corporation|Tobacco smoke filter providing tobacco flavor enrichment, and method for producing same|
    FR2462111B1|1979-07-26|1988-08-12|Job Ets Bardou Job Pauilhac|PROCESS FOR THE PRODUCTION OF A FILTERING STRUCTURE, IN PARTICULAR FOR CIGARETTER FILTERS AND FILTERS OBTAINED|
    US4340072A|1979-11-16|1982-07-20|Imperial Group Limited|Smokeable device|
    US4391285A|1980-05-09|1983-07-05|Philip Morris, Incorporated|Smoking article|
    US4474191A|1982-09-30|1984-10-02|Steiner Pierre G|Tar-free smoking devices|
    US4549875A|1983-06-02|1985-10-29|R. J. Reynolds Tobacco Co.|Manufacture of tobacco smoke filters|
    CS237872B1|1983-06-09|1985-11-13|Rudolf Simo|Cigarette filtration stick filling and method of this filling making|
    IN166122B|1985-08-26|1990-03-17|Reynolds Tobacco Co R|
    IE65679B1|1984-09-14|1995-11-15|Reynolds Tobacco Co R|Cigarette type smoking article|
    JPH0446205B2|1984-10-04|1992-07-29|Ngk Insulators Ltd|
    ES2047501T3|1988-03-01|1994-03-01|Kimberly Clark Co|FILTERING ELEMENT OF CONTROLLED SUCTION AND EFFICIENCY FOR SMOKING ITEMS.|
    IN172374B|1988-05-16|1993-07-10|Reynolds Tobacco Co R|US4819665A|1987-01-23|1989-04-11|R. J. Reynolds Tobacco Company|Aerosol delivery article|
    US5076295A|1989-09-29|1991-12-31|R. J. Reynolds Tobacco Company|Cigarette filter|
    US5056537A|1989-09-29|1991-10-15|R. J. Reynolds Tobacco Company|Cigarette|
    US4967774A|1989-10-11|1990-11-06|R. J. Reynolds Tobacco Company|Smoking article with improved means for retaining the fuel element|
    EP0434339A3|1989-12-18|1991-10-09|R.J. Reynolds Tobacco Company|Cigarette and cigarette filter element therefor|
    US5105834A|1989-12-18|1992-04-21|R.J. Reynolds Tobacco Company|Cigarette and cigarette filter element therefor|
    US5246017A|1990-11-06|1993-09-21|R. J. Reynolds Tobacco Company|Cigarette and cigarette filter element therefor|
    US5247947A|1990-02-27|1993-09-28|R. J. Reynolds Tobacco Company|Cigarette|
    US5183062A|1990-02-27|1993-02-02|R. J. Reynolds Tobacco Company|Cigarette|
    US5396911A|1990-08-15|1995-03-14|R. J. Reynolds Tobacco Company|Substrate material for smoking articles|
    US5415186A|1990-08-15|1995-05-16|R. J. Reynolds Tobacco Company|Substrates material for smoking articles|
    GB9018131D0|1990-08-17|1990-10-03|Rothmans International Ltd|Smoking article|
    US5105837A|1990-08-28|1992-04-21|R. J. Reynolds Tobacco Company|Smoking article with improved wrapper|
    US5348027A|1991-02-14|1994-09-20|R. J. Reynolds Tobacco Company|Cigarette with improved substrate|
    US5203355A|1991-02-14|1993-04-20|R. J. Reynolds Tobacco Company|Cigarette with cellulosic substrate|
    US5178167A|1991-06-28|1993-01-12|R. J. Reynolds Tobacco Company|Carbonaceous composition for fuel elements of smoking articles and method of modifying the burning characteristics thereof|
    US5345955A|1992-09-17|1994-09-13|R. J. Reynolds Tobacco Company|Composite fuel element for smoking articles|
    US5469871A|1992-09-17|1995-11-28|R. J. Reynolds Tobacco Company|Cigarette and method of making same|
    PH30299A|1993-04-07|1997-02-20|Reynolds Tobacco Co R|Fuel element composition|
    US5669900A|1993-11-03|1997-09-23|Kimberly-Clark Worldwide, Inc.|Spunbond loop material for hook and loop fastening systems|
    US5538019A|1993-11-03|1996-07-23|Schweitzer-Mauduit International, Inc.|Spunbond cigarette filter|
    US5592955A|1994-02-07|1997-01-14|Philip Morris Incorporated|Cigarette with insulating shell and method for making same|
    US5546965A|1994-06-22|1996-08-20|R. J. Reynolds Tobacco Company|Cigarette with improved fuel element insulator|
    US5533530A|1994-09-01|1996-07-09|R. J. Reynolds Tobacco Company|Tobacco reconstitution process|
    GB9712815D0|1997-06-19|1997-08-20|British American Tobacco Co|Smoking article and smoking material therefor|
    HU0101273A3|1998-01-06|2001-10-29|Philip Morris Products Inc Ric|Cigarette having reduced sidestream smoke|
    US5996589A|1998-03-03|1999-12-07|Brown & Williamson Tobacco Corporation|Aerosol-delivery smoking article|
    KR20030014068A|2001-08-10|2003-02-15|권현옥|Cigarette of spray or liquid|
    US10188140B2|2005-08-01|2019-01-29|R.J. Reynolds Tobacco Company|Smoking article|
    US7479098B2|2005-09-23|2009-01-20|R. J. Reynolds Tobacco Company|Equipment for insertion of objects into smoking articles|
    US20070137668A1|2005-12-15|2007-06-21|Borschke August J|Smoking articles and wrapping materials therefor|
    US7987856B2|2005-12-29|2011-08-02|Philip Morris Usa Inc.|Smoking article with bypass channel|
    US8240315B2|2005-12-29|2012-08-14|Philip Morris Usa Inc.|Smoking article with improved delivery profile|
    US9220301B2|2006-03-16|2015-12-29|R.J. Reynolds Tobacco Company|Smoking article|
    US20070215167A1|2006-03-16|2007-09-20|Evon Llewellyn Crooks|Smoking article|
    EA015068B1|2006-03-28|2011-04-29|Филип Моррис Продактс С.А.|Smoking article with a restrictor|
    US8353298B2|2006-07-12|2013-01-15|Philip Morris Usa Inc.|Smoking article with impaction filter segment|
    US8424539B2|2006-08-08|2013-04-23|Philip Morris Usa Inc.|Smoking article with single piece restrictor and chamber|
    US8235056B2|2006-12-29|2012-08-07|Philip Morris Usa Inc.|Smoking article with concentric hollow core in tobacco rod and capsule containing flavorant and aerosol forming agents in the filter system|
    TW200911138A|2007-03-09|2009-03-16|Philip Morris Prod|Smoking articles with restrictor and aerosol former|
    TW200911141A|2007-03-09|2009-03-16|Philip Morris Prod|Super recessed filter cigarette restrictor|
    US8251072B1|2009-01-12|2012-08-28|Zepp Scott D|One shot cigarette system|
    ZA200901679B|2009-03-09|2015-08-26|Tobacco Res And Development InstituteLtd|Apparatus for introducing objects into filter rod material|
    AR080556A1|2009-10-09|2012-04-18|Philip Morris Prod|FILTER DESIGN TO IMPROVE THE SENSORY PROFILE OF ARTICLES FOR SMOKING WITH CARBON FILTER NOZZLE|
    US8424540B2|2009-10-09|2013-04-23|Philip Morris Usa Inc.|Smoking article with valved restrictor|
    US8905037B2|2009-10-15|2014-12-09|Philip Morris Inc.|Enhanced subjective activated carbon cigarette|
    US20110180084A1|2010-01-27|2011-07-28|R.J. Reynolds Tobacco Company|Apparatus and associated method for forming a filter component of a smoking article|
    US9034106B2|2010-03-26|2015-05-19|Philip Morris Usa Inc.|Smoking article including alkanoylated glycoside|
    TW201204272A|2010-03-26|2012-02-01|Philip Morris Prod|Smoking articles with significantly reduced gas vapor phase smoking constituents|
    ZA201008663B|2010-12-01|2014-08-27|Tobacco Res And Dev InstLtd|Feed mechanism|
    EP3033950B1|2011-05-31|2018-07-04|Philip Morris Products S.a.s.|Rods for use in smoking articles|
    MX369865B|2011-12-30|2019-11-25|Philip Morris Products Sa|Smoking article with front-plug and aerosol-forming substrate and method.|
    EP2625975A1|2012-02-13|2013-08-14|Philip Morris Products S.A.|Aerosol-generating article having an aerosol-cooling element|
    US9854833B2|2012-02-16|2018-01-02|R. J. Reynolds Tobacco Company|Apparatus and associated method for forming a filter component of a smoking article|
    SI3160275T1|2014-06-27|2018-10-30|Philip Morris Products S.A.|Smoking article comprising a combustible heat source and holder and method of manufacture thereof|
    WO2017032755A1|2015-08-24|2017-03-02|Philip Morris Products S.A.|Method for drying filter rods|
    US10897925B2|2018-07-27|2021-01-26|Joseph Pandolfino|Articles and formulations for smoking products and vaporizers|
    US20200035118A1|2018-07-27|2020-01-30|Joseph Pandolfino|Methods and products to facilitate smokers switching to a tobacco heating product or e-cigarettes|
    CN110664006A|2019-09-09|2020-01-10|河南中烟工业有限责任公司|Smoking article containing hot-melt atomizing agent|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    US07/089,692|US4903714A|1987-08-25|1987-08-25|Smoking article with improved mouthend piece|
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