![]() Herbicide composition
专利摘要:
A herbicidal composition containing as an active ingredient the compound of the formula wherein Ro represents a hydrogen atom or a lower alkyl group, and R1, R2 and R3 each represent a hydrogen or halogen atom, or a lower alkyl, lower alkoxy or lower alkenyloxy group, which is especially useful for application to aquatic rice paddies, and novel compounds of formula (I) wherein Ro, R1, R2 and R3 have the same meanings as defined above, provided that R1, R2 and R3 do not represent hydrogen atom at the same time. 公开号:SU1209017A3 申请号:SU823404162 申请日:1982-03-02 公开日:1986-01-30 发明作者:Такематсу Петсуо;Сузуки Акинори;Тода Казуя 申请人:Ясима Кемикал Индастриал Ко.,Лтд (Фирма); IPC主号:
专利说明:
the purpose of enhancing the herbicidal activity, it contains as an active substance a phenyl acetate-nilide derivative of the general formula / 3 (oVc-C - T4; cps where R is hydrogen or C, gC (-alkyl; 3 R is hydrogen, chlorine, bromine, fluorine, C, C-alkyl, C, -Cj-anKOKCH or allyloxy; R is hydrogen, chlorine, methyl, ethyl or methoxy; xylene is used as a solvent, and polyoxyethyl alkyl aryl ether as a surfactant at a mass ratio of 30:60: jlO, respectively. The invention relates to hickshackles for controlling weeds and undesirable vegetation, namely, herbicidal compositions for killing weeds in rice crops. Herbicidal compositions recommended for controlling weeds during rice cultivation are known, for example, the herbicidal composition based on molinata, i.e. N-hexamethylene-8-ethylthiocarbamate 1. However, this herbicide is used in relatively high doses of the active substance, which often causes significant damage to rice plants. In addition, it is used only by embedding in the soil. Herbicides recommended for rice cultivation containing c. as active substances annpida carboxylic acids. Such herbicides include, for example, substituted meta-trifluoro methylphenipucetic acid anilides 2. However, in optimal doses, they are not sufficiently effective for some types of weeds grown in rice crops. The purpose of the invention is to increase the herbicidal activity of the composition based on feil-acetanilide derivatives. This goal is achieved by using the following as a herbal composition. A wettable powder containing the active substance is a phenylacetanilide derivative of the general formula R is hydrogen or C, -C-alksh1; R is hydrogen, chlorine, bromine, fluorine, C, -C4-alkyl, C-C-alkoxy or allyloxy; R ® ° DOR ° D chlorine, methyl, ethyl or methoxy; as a filler, diatomaceous earth; and surfactants, polyvinyl alcohol and sodium dodecylbenzenesulfonate at a weight ratio of 50: 45: 2: 3, respectively. The granules containing the active substance is a phenylacetanilide derivative of the indicated general formula, the fillers are bentonite and talc, the surfactants are sodium ligninsulfonate, sodium alkyl benzene sulfonate and sodium bicarbonate with mass 5: 23.75: 68.11: 1.9:: O, 475: 0.765, respectively. An emulsifiable concentrate containing the active substance - a phenylacetanilide derivative of the indicated general formula, / solvent - xylene and surfactant - polyoxyethylalkyl ether and a weight ratio of 30:60:10, respectively. The herbaceous composition according to the invention differs from the known irrigates by intraspecific selectivity. This makes it possible to successfully fight against various grassland sorinas in rice crops, not damaging the latter. (molinat) These formulations of the germicidal composition (wettable powder, emulsifiable concentrate) are prepared by known methods — by thoroughly grinding and mixing all the ingredients In tab. 1 shows the active substances of the indicated general formula and examples showing the effectiveness of the herbicidal composition according to the invention. . Known compounds used for comparison. (CH2) b C8C2H5 O ; O) cis-usa- O -os2H5 {. compound A) CF3OHN3 Uusint, -s - mn (o) I connection B1 - Example 1. The soil from rice fields is laid in special pots. Seeds of chicken millet and long sows are sown on the surface layer and tubers of water sowing round are planted. The pots are filled with water to ensure a depth of 3 cm. Before these weeds germinate, the moistened soil is treated with pre- ; minor damage medium damage strong damage The results of the experiment are presented in. . tab. 3 Example 3. The soil, taken from paddy rice plantation, is placed in special pots and seedlings or tubers of chicken millet, corn, dpinna, corn round and kamppa are planted. Then, the emulsifiable concentrate prepared according to embodiment 3 is diluted with water and the soil with seeds and tubers is treated with it. Two days after treatment, young rice plants are placed in pots at the two-leaf stage. the amount of wettable powder obtained in accordance with option 1. Herbicidal efficacy is observed 3 weeks after treatment. Herbicidal effect is assessed on a scale from 0 to 5 points. The results of the experiment are presented in table. 2 Index five 43 2 one ABOUT Herbicidal effect Uv danie 80-99% destruction 60-79% destruction 40-59% destruction 20-39% destruction Without damage Example 2. Special pots fill the soil from the paddy rice fields and sow the seeds of chicken millet, and grow long and lake reeds. Water round tubers are planted at the same time. The pots are filled with water to ensure a depth of 3 cm. 5 days after emergence, the weeds are moistened with a pre-determined amount of granules obtained in accordance with option 2. 3 weeks after the treatment, the degree of phytotoxicity is observed with respect to rice plants transplanted into the soil and herbicidal effect (assessed according to the scale given in example 1). The degree of phytotoxicity in relation to rice is estimated by following standards:,, : slight damage Each active ingredient is tested in two, areas at different concentrations. Three weeks after treatment, the herbicidal effect and phytotoxicity of OTHomeHtno for rice are determined according to the standard method. The results of the experiment are presented in table. four. Presented in table. 2-4 data indicate a high germicidal activity of the composition COI- Laspo invented -1ha. It allows you to successfully wrestle with malignant sprint; -z when you raise rice. J 1209017 " Table Active compounds of general formula. SNS about : oya-yo . cn 23 „ 3-Methoxy - Continued table. 2 Continuation of table 2 Table 3 17 12090P18 Continuation of table 3 nineteen 13 14 15 6 7 eight 9 0 2.5 1.25 5.0- 2.5 1.25 5.0 2.5 1.25 5.0 2.5 1.25 5.0 2.5 1.25 5.0 2.5 1.25 5.0 2.5 1.25 5.0 2.5 1.25 5.0 2.0 120901720 Continuation of table 3 5 5 5 5 5 5 5 4 5 5 5 5 5 4 5 5 5 5 A 4 5 5 4 5 5 5 4 .5 5 4 4 3 3 5 5 4 4 4 3 5 5 4 3 3 3 4 4 3 3 3 five four five four four four four 3 four four four four 3 3 five four four ; four four 3 five four 3 3 3 four 3 five four 3 four 3 3 four 3 3 2 I ABOUT four 3 3 3 2 one five four 3 3 3 21 120901722 Continuation of table 3 1.25 5.0 2.5 1.25 5.0 2.5 1.25 5.0 2.5 1.25 5.0 2.5 1.25 5.0 2.5 1.25 5.0 2.5 1.25 5.0 2.5 1.25 5.0 2.5 1.25 t - I 2 four 43 four 3 3 five five five five five five five five four five four 3 five four BUT 3 3 2 2 four 3 3 five 3 one five five four five four four BUT four four four four 3 five five four BUT 3 2 one 3 3 2 3 2 ABOUT five five BUT five four 3 four 3 3 four four 2 five five 3 one ABOUT ABOUT 25 1209017 6 Continuation 27 1209017 28 Continuation of table 3 29 120901730 Continuation of tab. . 31 0.3125 0.625 0.3125 0.625 0.3125, 0.625 0.3125 0.625 0.3125 0.625 0.3125 0.625 0.3125 0.625 0.3125 0.625 0.3125 0.625 0.3125 0.625 0.3125 0.625 0.3125 0.625 0.3125 I2090I732 Continuation of table 3 2 2 1 2 2 3 3 3 2 .5 5 five five four four 3 3 four 3 2 one 2 I 3 2 2 3 2 2 one 3 3 one one four four four four four four 3 2 four 3 2 2 3 2 four 3 2 1 I I 1 2 2 ABOUT ABOUT four four 3 3 3 3 2 I 3 3 oh oh oh 2 one 33 (Zytotoxicity molinatv at a dose of 5.0 kg / ha to rice: for other connections: - (not damaged) 120901734 Continuation of table 3 about “di emy The number of active and that; kg / ha 120901738 Continuation of table 4 Herbishzdna lio effect on plants Chicken millet Syty is long Syt round Kaion Lake 0.625 1.25 0.625 1.25 0.625 0.625 1.25 0.625 1.25 0.625 1.25 0.625, 25 0.625 1.25 0.625 1.25 0.625 1.25 0.625 1.25 0.625 1.25 0.625 4 4 4 5 5 А 4 5 5 4 4 4 4 4 4 4 3 3 3 5 4 4 4 3 3 Syt round Kaion Lake 3 3 3 4 4 3 3 4 4 3 2 3 2 2 .2 3 2 2 2 3 2 3 2 1 About 3 3 2 3 3 1 About 3 2 : i i 3 3 2 .1 J O 2 2 1 1 2 I 1 .1 . 39 1.25 0.625 1.25 0.625 1.25 0.625 1.25 0.625 1.25 0.625 1.25 0.625 1.25 0.625 1.25 0.625 U25 0.625 1.25 0.625 1.25 0.625 l; 25 0.625 1.25 120901740 Continuation of table 4 A 3 3 3 3 3 A 3 A A 5 5 5. five BUT BUT BUT BUT BUT 3 2 2 3 3 3 3 2 3 2 2 one 3 2 one ABOUT BUT , BUT BUT BUT 3 3 3 2 BUT 3 2 one , 3 one 3 2 2 1 1 1 About 2 2 1 ABOUT BUT BUT 3 3 3 3 2 2 3 2 1 o I About 2 l ( NOTE: Phytotoxicity to rice for all connections - (not damaged) Editor. Kolesnikova Tehred m. Parotsay Corrector. Shekmar i Order 302/61 Circulation. 679 ° Subscription VNISH State Committee of the USSR for inventions and discoveries 113035, Moscow, Zh-35, Raushsk nab, 4/5 Branch ShSh Patent, Uzhgorod, st. Design, And 120901742 Continued tab. A
权利要求:
Claims (3) [1] 1. A HERBICIDAL COMPOSITION in the form of a wettable powder containing an active substance - a phenylacetanilide derivative, a filler and surfactants, characterized in that, in order to increase the herbicidal activity, it contains a phenylacetanilide derivative of the general formula “wherein R 1 is hydrogen or C, -C 4 ~ alkyl; • R 2 - hydrogen, chlorine, bromine, fluorine, C, -C 4 -alkyl, C, -C ^ -alkoxy or allyloxy; R 3 - hydrogen, chlorine, methyl, ethyl or methoxy as a filler - diatomaceous earth, and as surface-active substances - polyvinyl alcohol and sodium dodecylbenzenesulfonate in a mass ratio of 50:45:: 2: 3, respectively. [2] 2. A herbicidal composition in the form of granules containing an active substance - a phenylacetanilide derivative, a filler and surfactants, characterized in that, in order to increase the herbicidal activity, it contains a phenylacetanilide derivative of the general formula as an active substance Sk .. ·, 1209017 where is hydrogen or C f -C 4 -alkyl; R is hydrogen, chloro, bromo, fluoro, C ( -C4 -alkyl, C | -Cj-alkoxy "or allyloxy; R 3 is hydrogen, chlorine, methyl, ethyl or methoxy, bentonite and I talc as a filler, and sodium ligninsulfonateί, sodium alkylbenzenesulfonate I and sodium bicarbonate in a mass ratio of 5: 23.75: 68 as a surface-active substance; 11: 1.9: 9.475:: 0.765, respectively. [3] 3. A herbicidal composition in the form of an emulsifiable concentrate containing an active substance - a phenylacetanilide derivative, a solvent and a surfactant, characterized in that, with the aim of increasing herbicidal activity, it contains a phenylacetanilide derivative of the general formula as active substance where R * - hydrogen or C ( > -C ^ -alkyl; R * is hydrogen, chloro, bromo, fluoro, C ( -C 4 -alkyl, C ^ -C 5 -alkoxy or allyloxy; R is hydrogen, chloro, methyl ', ethyl or methoxy; xylene is used as a solvent, and polyoxyethylene alkyl aryl ether as a surfactant in a mass ratio of 30:60:: 10, respectively.
类似技术:
公开号 | 公开日 | 专利标题 SU668569A3|1979-06-15|Herbicide PL158086B1|1992-08-31|Weed killer CS212337B2|1982-03-26|Herbicide means and means for regulation of the plant growth and method of making the active substance CS203967B2|1981-03-31|Insecticide means RU2045512C1|1995-10-10|2-[2′,3′,4′-trisubstituted benzoyl]-1,3-cyclohexanediones or their salts, herbicide composition and a method of struggle against weeds SK281501B6|2001-04-09|Pesticidal fluoroolefins, process for their preparation, pesticidal and insecticidal compositions them containing, their use and method of treating insects SU882403A3|1981-11-15|Herbicide agent SU1209017A3|1986-01-30|Herbicide composition JP2901794B2|1999-06-07|Herbicidal composition HU185801B|1985-04-28|Process for preparing new benzamide derivatives and herbicide compositions containing benzamide derivatives as active suastances US3978228A|1976-08-31|Method for killing noxious fungi in plants using dihalo sulfonates US2981619A|1961-04-25|Method of inhibiting plant growth JP2996475B2|1999-12-27|Benzoxazinone derivatives and herbicides containing the same as an active ingredient US3390976A|1968-07-02|Method for modifying the growth characteristics of plants HU187757B|1986-02-28|Fungicide compositions containing new benzamine derivatives SU1440324A3|1988-11-23|Herbicide compound SU1222185A3|1986-03-30|Herbicide SU1701102A3|1991-12-23|Herbicidal composition JP2525625B2|1996-08-21|Weeding composition for paddy field EP0120480B1|1987-07-08|4h-3,1-benzoxazine derivatives, process for producing the same and agricultural or horticultural fungicide containing the same EP1124421A1|2001-08-22|Novel herbicide compositions based on glyphosates and isoxazoles US4017295A|1977-04-12|Herbicidal composition KR800000244B1|1980-04-02|Process for the preparation of oximeethers SU1327780A3|1987-07-30|Method of fighting weeds SU1152506A3|1985-04-23|Method of fighting weeds
同族专利:
公开号 | 公开日 KR860002107B1|1986-11-26| US4453975A|1984-06-12| JPS57144203A|1982-09-06| JPS599521B2|1984-03-03| BR8201093A|1983-01-11| EP0061583B1|1984-05-02| DE3260132D1|1984-06-07| KR830008484A|1983-12-10| EP0061583A1|1982-10-06|
引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题 US3022302A|1956-03-15|1962-02-20|Pharmacia Ab|Manufacture of nu, nu-disubstituted amides of aryl acetic acids| JPS6154017B2|1979-06-05|1986-11-20|Ihara Chemical Ind Co| JPS6058884B2|1979-06-15|1985-12-23|Idemitsu Kosan Co| JPS5761349B2|1980-01-28|1982-12-23|Sumitomo Chemical Co| JPS5842864B2|1980-02-06|1983-09-22|Idemitsu Kosan Co|JPS6154765B2|1983-12-02|1986-11-25|Yashima Kagaku Kogyo Kk| JPS6353184B2|1983-12-26|1988-10-21|Yashima Kagaku Kogyo Kk| JPH0565258A|1991-07-03|1993-03-19|Nippon Bayeragrochem Kk|Acetic acid anilide derivative and herbicide| NZ598271A|2009-07-21|2014-04-30|Marrone Bio Innovations Inc|Use of sarmentine and its analogs for controlling plant pests| WO2015050705A1|2013-10-01|2015-04-09|Marrone Bio Innovations, Inc.|Use of sarmentine and its analogues with an herbicide, and compositions thereof|
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申请号 | 申请日 | 专利标题 JP56029319A|JPS599521B2|1981-03-03|1981-03-03| 相关专利
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