Method of obtaining furnace black

专利摘要:
This disclosure relates to an improved furnace process for producing carbon blacks by the incomplete combustion of hydrocarbonaceous feedstock wherein the resultant blacks have higher surface areas than the carbon blacks normally prepared from the feedstocks, as a result of which the blacks are particularly suitable for use in imparting conductivity properites to plastic materials and the like. This disclosure also relates to the production of a novel class of furnace blacks having excellent conductivity properites and which are characterized by high surface areas and low pH values.
公开号:SU1205775A3
申请号:SU802954176
申请日:1980-07-31
公开日:1986-01-15
发明作者:Дж.Етес Барри；С.Харст Рональд
申请人:Кабот Корпорейшн (Фирма)；
IPC主号:

专利说明:

f
The invention relates to an improved furnace method of semi-CNG. by incomplete combustion of hydrocarbon feedstock. The obtained data using the soot method have a higher specific surface area, which makes it possible to use gshastic materials, etc., to impart the conductive properties. The invention also relates to the preparation of a class of furnace blacks with wire properties and high specific surface area and low pH values used as fillers, ycujp vakshi; their agents, pigments, and so on.
The purpose of the invention is to increase
the specific surface of the stove saeki, 1
As a hydrocarbon feedstock
in the proposed method, volatile unsaturated hydrocarbons can be used under the reaction conditions, for example acetylene; olefins, such as ethylene, propylene butylene; aromatic hydrocarbons), such as benzene, toluene, xylene; some saturated hydrocarbons; volatile hydrocarbons such as kerosene, naphtha
containing aromatic cycles., and raw materials are injected, generally perpendicularly, from the odd or inside or both edges of the stream of hot gases formed during the end. Raw materials are injected as a set of small coherent jets3 that penetrate well into the inner region or core the flow of gases generated during combustion is not so deep as to collide with oncoming jets. In the implementation process of the invention, mossho hydrocarbon raw materials are easily introduced in the form of coherent liquid jets, pushing liquid e raw material through a nozzle with a lot of holes with a diameter (0.25 mm) - 0.15 (3.81 mm) inches, and better with a diameter of 0.02 (0.51 km) - 0.06 (1.52 mm inches, under an injection pressure sufficient to achieve the desired penetration. The amount of raw materials used and the amount of fuel and / or oxidizer is chosen so that the maximum percentage of combustion is approximately 46.5-57.0%. The limit combustion is expressed as the ratio of the total amount of oxygen, Using 10
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in the soot-forming process, to the amount of oxygen required for complete combustion to carbon dioxide and the total amount of water used in the soot-forming process, hydrocarbon (%). The implementation of the proposed method results in furnace soot with a high specific surface and excellent conductive properties, provided that the introduction of water in the form of water vapor is considered as an essential point of process control. This is simply the addition of water, and the method of its introduction, the amount of water and the manner in which it is introduced influence the production of soot with a high specific surface. Water, which at the time of introduction can be in any physical state, is inside a stream of combustion gases. should be in the form of water vapor prior to the introduction of liquid raw materials. In addition, the added water should be introduced so that it mixes well with the combustible gas stream before introducing the liquid feed. The effect of the process depends on the amount of water added in the form of water vapor, the concentration of which is 4.5-10.8% of the total gas volume of the fuel and oxidant used to obtain the combustion products.
The following evaluation methods were used to determine the analytical and | physical properties of the soot obtained by the proposed method. )
Determination of specific surface by iodine sorption.
The specific surface of carbon black by
20
25
thirty
35
40
.five
DU is determined according to the following procedure,. A soot sample placed of a zero-size porcelain crucible with a lid, with a gas outlet, is treated to remove volatile components or calcined at (927 ° C) for 7 minutes. Then the crucible with the contents of the ohl; they are eaten in a desiccator, the top layer of the burned carbon black) / 4 inches deep is removed and discarded. From the soot remaining in the crucible, a weighed portion (with an accuracy of 0.1 mg) is taken and placed in a 4-oz sample-5 sample bottle. It was found that for soot with the expected value of the specific surface area of 300–750 MVr, the weights are 0.1 g, and for
0
carbon black with a specific surface area of more than 750 m / g, the corresponding weighting is 0.05 g. To the contents of the flask is added 40 ml of 0.0473N. iodine solution. The slides are closed and shaken for 10 minutes at a speed of 120-260 tilts per minute. The resulting solution is immediately centrifuged at a speed of 1200-2000 rpm until the solution is clear. Usually this stage takes 1-3 minutes. Immediately after centrifuging, 25 ml of the solution are titrated with 0.0394 n. sodium thiosulfate solution. As an indicator, add a few drops of 1% Kramal solution. The end point of the titrovars is determined by a drop of thiosulfate, which provides a blue solution. As a blank 40 ml 0,0473 n. the iodine solution is shaken, centrifuged and titrated in the manner described for the soot containing the solution. The specific surface area of iodine, expressed in, is calculated by the following formula:
n 10 (6-T) - 4.57 y, “,
where B is the titration of the blank sample T is the titration of the sample.
Dibutyl phthalate (DBF) oil number.
The DBP oil number of the granulated carbon black is determined by the method of ASTM D-2414-76.
Color intensity.
The intensity of the color of soot samples is determined relative to the industrial standard for soot staining in accordance with ASTM D-3265-76a.
Soot pH.
5 g of a sample of granulated carbon black and 50 MP of distilled water are placed in the corresponding Erlinmeyer flask. The water-soot mixture is brought to a boil on an electric stove and maintained for 10 minutes at low boiling so that water does not boil off. The resulting mixture is cooled to room temperature and then its pH is determined using a pH meter equipped with glass and calomel electrodes. The measurement is made with an accuracy of 0.05 pH units. Until the pH of the soot is determined, the pH meter is calibrated with two buffer values.
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solutions, one with and the other with a pH of 7.0.
In order to evaluate the properties of the soot that appear
5 in changing the moisture absorption and volume resistivity of the compounds when carbon is introduced into them, the latter are introduced into the appropriate resin, such as ethylene / ethyl acrylate 10 1 copolymer in this case. Pound testing is obtained by incorporating the desired weight of carbon black into the resin. For example, for such estimates the most approach is
15 compounds containing soot in the amount of 12, 20, 36 wt.%.
The process for the preparation of black compounds consists in the following. Half ethylene used /
20 ethyl acrylate resins are placed in a Benberry mixer, all soot is added thereto, and then the remaining amount of resin. The temperature in the mixer is up to 100 ° F (37.8 ° C) and begins
25 mixing.
The initial mixing was carried out for 30 seconds at a speed of 77 rpm under a pressure of 40 psi (0.276 MPa). After that speed
30 increase to 115 rpm for 45 s. During this cycle, the temperature reaches (37.8 ° C), after which the plunger is raised so that the soot can be brushed back into
,, bunker After the temperature reaches 250 ° (l21 ° CJ, water is circulated through the casing and the mixer rotor. During the mixing period at 115 rpm, the speed
“Increase to 230 rpm and mixing continues for another 105 s. After this time, the mixer is turned off and the black-filled compound is removed from the mixer. In that case,
j when the carbon black load is 12 or 20 wt.%, the temperature of the compound 260 i (127 ° C) is 290 ° F (143 C). For a 36% carbon black load, the temperature of the compound is 330 ° F () JQ (182 C). The resulting compound. twice passed through a cooled two-roll mill and formed into a film for subsequent tests,
55 Moisture absorption compound.
Films of various ethylene / euilacrylate compounds, prepared in a Benberry mixer, are cut into cubes and granulated to obtain samples suitable for measurement. 2 g of the sample of the granulated compound is weighed in a glass bottle of known weight, dried at 190 F (87) for overnight to remove moisture from the compound. After cooling in a desiccator, weigh to the accuracy of Q, mg. The sample is then kept at room temperature in a 79% humidity exicator. The sample is weighed again after an hour and then repeated periodically for 3 days, and, if necessary, more until the sample reaches a constant weight. Equal moisture absorption is defined as a weight percentage, the ratio of the compound.
Specific volume resistance. This test method is used to determine the specific volume resistivity of soot containing plastics. The following describes the process for obtaining test specimens from a film obtained in a Benberry mixer according to the indicated method. Samples of 7x7 inches (17.8x17.8) are cut out of the film. A 7x7 inch cell with a mold size (1758, 17.8 connector facilitations are covered with a layer of polyethylene terephthalate film on which the sample is placed. From above it is covered with PTFE film to facilitate The removable mold is placed under a press that works in compression at 320 F (l60 ° C, which is maintained, for example, by injecting steam under pressure of 100 psi to 0.689 MPa). When the temperature of the mold reaches 320 R. (160 ° C), the force of the piston of the press increases from 0 to 20 tons (181,144 kg and t Kim is maintained for 5 minutes. The pressure on the sample is approximately 816 psi (5.63 MPa b) Then the press (|) 0rmu is removed from the hot press and placed under a cold one, the piston force of which is also 20 tons (18144 kg), and the eye will remain there until it cools to room temperature. The pressed discs are 7x7 inches in size (17.8x17.8 cm) are removed from the mold and cleaned,
To prepare the required samples to determine the specific volume resistivity, a 2x6 inch (5.1x15.2 cm) plate is cut from a pressed 7x7 inch disc. It is coated at both ends with silver paint (silver conductive coating in ethanol) to produce a silver electrode about half an inch wide. After drying, the uncoated portion of the sample is measured to accurately determine the distance between the electrodes, as well as the average width and thickness sample. The sample is then placed between two 8x6 inch (20.3 x X15.2 cm) glass plates arranged crosswise with each other so that the edge of the top plate is aligned with the edge of the sample. Then, on both sides, copper strips are placed on the coated ends of the sample, which are connected to a Digitac Model H102I20 universal instrument for measuring resistance.
First, the resistance of the sample is measured in an oven at 90 ° C, then after 3 minutes with a subsequent determination of the readings at a 2-minute interval for 30 minutes. After 30 minutes, readings are taken for the next 30 minutes every 5 minutes at 90 ° C in an oven. The resistance value of the sample is determined from an independent part of the curve. The specific volume resistance of the sample is calculated by the following formula:
Oud, voluminous, resist, Om-cm P “A
Where
(L
P resistance of the sample. Ohm
And - the area of the uncovered part of the sample,
oC is the distance between two silver electrodes — two coated ends of the specimen, see
Sunray Dx-fuel with the following elemental composition is used as a liquid hydrocarbon-foot raw material in the examples: carbon content 90.4 wt.%; hydrogen 7.56 wt.%; sulfur 1.5 wt.% | asphaltenes 4.4 wt.%; ash 0.049 wt.%; hydrogen to carbon ratio is 0.995; The sodium content is 2.8 parts per thousand, potassium is 0.73 parts per thousand, the index of dependence on the specific weight and boiling point is 135, the specific viscosity measured in accordance with AS TMD is 287, 1.10;
/
viscosity according to the method of the American Petroleum Institute 3.1; viscosity according to the Sei Bolt universal viscometer (AS TMD - 88} at 130,542.9 s, and at 210 ° F 63.3 s. The natural gas used in all examples, as a fuel, basically has the following composition, mol.% nitrogen 9.85, carbon dioxide gas 0.18, methane 86.68, ethane 3.07, propane 0.19 isobutane 0.01, n-butane 0.02.
Example 1 (control, without the introduction of water vapor), For carrying out the process, a reactor is used that provides the primary combustion zone with reactants, i.e. combustible and oxidant, in the form of separate FLOWS. E or in the form of pre-ignited gaseous reaction products, as well as providing soot-forming hydrocarbon feedstock, a method of introducing gases resulting from combustion downstream, methods of introducing additional quantities of water, etc.
The reactor can be made of any suitable material, such as metal. In the manufacture of equipment, it is envisaged to make it a shell with a refractory lbo to create a casing through which cooling, circulation, predominantly of its kind, circulates.
In addition, the reactor is equipped with instruments for recording temperature and pressure, means for quenching soot-forming reactions, such as jet nozzles, npH6opaNtti for cooling the soot product, and means for separating and separating soot from other unnecessary by-products. A reaction vessel with a diameter of 8.75 inches (0.22 m) was used at a length of 40.75 inches (1.035 m), then conically narrowed at a distance of 12 inches (0.305 m) with a diameter of 5.3 inches (0.135 m). . A first or transition zone with a diameter of 5.3 inches (0.135 m) and a length of 9 inches is associated with the first zone. It is in this zone that liquid raw materials are injected in the form of coherent jets through the required number of holes. Liquid raw materials are injected under conditions that ensure its full penetration into the stream of gases, which form during combustion, thereby eliminating the problem of formation
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HHfi coke in the reactor. The resulting hot gas stream then enters a third reaction zone in which soot is formed. Reactionary
5 zone consists of a section with a diameter
36 inches (0.914 m) and 24 feet long (7.32 m), behind which is a section with a diameter of 27 inches (0.69 MJ and a length of 1 feet (3.35 m)).
50 In the implementation of this example, 140% of the combustion in the first stage was obtained by injecting air into the combustion zone, preheated to 750 (399 ° C), at a rate of
15 60100 cubic feet / h (0.447) and natural gas at a speed of 4930 cubic feet / h (0.0367 M Vc) under an overpressure of 15 psi (0.103 MPa). The reported pressure20 in this zone is 2.6 inches Hg. (8.8 kPa). All this leads to the fact that the flow of hot gases generated during combustion moves downstream with a high linear velocity into the transition zone. In the transition zone, the raw material, preheated to 400 ° (), is injected mainly perpendicularly into the stream of gases generated during combustion of the scientific research institute at a rate of 54 gallons per hour.
(o., 062 kg / s) under an overpressure of 197 psi (1.36 MPa).
Raw material: injected through four free nozzles, the size of each is equal to 0.029 inch (0.74 mm). The nozzles are located along the edges of the stream of gases formed during combustion. The gaseous stream then enters the reaction zone, in which, after 1.3 seconds, the stream is quenched with water to 1370 ° F (743 s). The limit of the percentage of combustion of 46.8%, Analytical and physical properties of carbon black are shown in table 1. This carbon black is used as a reference standard for examples 2 and 3.
35
45
i
EXAMPLE 2 A method similar to that of Example 1. In particular, combustion air, preheated to 750 ° F (., Is introduced into the chamber
50 burns at a speed of 60,100 cubic feet "/ h (0.067) with an overpressure of 16 psi (O, MPa MP) In this example, with combustion air to the zone
55 burns inject water at a rate of 20 gal / h (3510 cubic feet / h or 0.0261 liters), which corresponds to 5.4% of the total volume of gases — air and gas used in. obtaining primary combustion. As a result of the combined introduction of water and air into the combustion zone, the water is well mixed with the flow of gases formed during combustion prior to the injection of the raw material. Under these conditions, the primary combustion is 138.3% and the pressure in the combustion chamber is 2.8 inches Hg (9.4 kPa). Liquid feed, preheated to 395 ° F (at a rate of 55 gallons per hour (0.063 kg / cj) and under excess pressure to 195 psi, is introduced into a gaseous stream containing mixed water vapor as coherent jets. (1.35 MPa). The residence time in the reactor zone is 1.3 s, the reaction gases are quenched with water to (727 ° C), the limiting burning percentage in the experiment is 46.5%. Soot Ezhtsel, its analytical and physical properties are given in table. In which the characteristics of the obtained carbon black and polymer compositions based on it are presented.
Example 3. It differs from Examples 1 and 2. Here 1 az is introduced at a speed of 4920 cubic feet / h.
. (0.0366 at an overpressure of 15 psi (0.103: aaj 5 whereas combustion air, preheated to 740 F (), is injected into the combustion zone at a speed of 60100 cubic pounds (0.447), Previously water was introduced into the combustion air at a rate of 40 gallons per hour.
(7020 cubic feet / h), which is 10.8% of the total gaseous volume of air and gas. These changes cause the pressure in the combustion chamber to become 2.5 inches of mercury. (9.8 KPa), and the primary combustion of 139.5%. Raw materials heated to 387 ° F (injected through four free nozzles at a rate of 55 gallons / hour (0.063 kg / cj and under an overpressure of 191 psi (1.32 MPa). The residence time in the reactor is 1.3 s, thereafter, the sa; ke-gas products are quenched with water up to 1,450 F. (. The limiting burn percent is 46.6%; the analytical and physical properties of this carbon black are listed in that one liter. 1.
PRI me R 4. Technologists and equipment of example 4 are mainly
12057.7510
Examples are 1-3, with the exception of the to-go that the combustion air, preheated to 760 F (404 ° Cj, is introduced into the combustion zone at a speed of 5 BOOO cubic feet / h (0.447 and gas is introduced at a rate of 4910 cube / ft / h ; (0.0365) under pressure 15 psi (0.103 MPa), the amount of water introduced together
10 with combustion air, 40 gal / h (7020 cubic feet / h O, .0522) or 10.8 vol.%. Under these conditions, the pressure in the combustion zone or chamber is 2.5 inches Hg, ( 8.8 kpa) and primary
15th burning 138.8%. Liquid raw materials, preheated to 390 F (99 ° C), are then injected through four free jet of size 0.029 inch (0.74 mm each as
20 continuous jets at a speed of 49 ff / h (0.057 kg / s) and under an overpressure of 162 psi (1.12 MPa). The residence time in the reactor 1.3 s before quenching (quenching
25 hot gases with water to
(760 ° CJ. The limiting burning percentage is 49.9%. Soot is recovered in the usual way. Analytical and physical properties are given in
3Q Ta6. which also shows the characteristics of carbon black and polymer compositions based on them.
Ir and mep 5, Carried out analogously to examples 1-4, but the natural
- 5 gas is introduced into the combustion zone at a rate of 4930 cubic feet / h (0.0367 at an excess pressure of 16 psig: inch (j3,110 Sh. Combustion air containing the same amount of water, 40 gal / h (7020 cubic feet / h or 0.0522) or 0.0522 mUs or 10.8 vol.%, preheated to 750 F (399 ° CJ5 is injected at a rate of
 60100 cubic feet / h (0.447 m Vcj. The pressure in the combustion chamber is 2.5 inches Hg (8j4 kEA) and the primary combustion is 138.4% "In the gas flow, which forms 1 xs during combustion, then injects liquid feedstock preheated to 340T (7i ° cj, at a speed of 40 gal / h (0.046 kg / s) and under an overpressure of 152 psi (, 05 W1a. The reaction is quenched
55 with water up to 1400 F (760 ° CJ after a dwelling time of 1, 2 s. Soot is extracted in the usual way. Analytical and physical properties are shown in Table 2.
eleven
II e rme r 6. In this example, the equipment, as in examples 1-5, the size of the transition zone is the same, but the size of the four free nozzles is. 0.037 inches (0.97 mm) instead of 0.029 inches (0.74 mm). In addition, the dimensions are characterized in that the diameter of the closed reaction vessel is 8.4 inches. (0.213 m) on proto -. 26.6 inches {0.676 m) before conically tapering to a diameter of 5.3 inches (0.0135 m) over a 5.3 inches (0.0135). The third zone or zone in which soot formation is completed is 36 inches (0.914 n) in size and has a length of:
well 16 feet (4.88 m).
, -; - .- ..
Combustion air, preheated to 710 (), is introduced into the combustion zone at a rate of
70 7000 cubic feet / h (0.326), and natural gas at a speed of 6540 cubic feet / h (0.0487) with an overpressure of 26 psi (0.179 Mlla). Water is introduced into the reactor along with combustion air in an amount of 35 gal / h (0.0457 or 7.3 vol.%. In addition, oxygen is added to the combustion chamber at a rate of 7000 cubic feet / h (0.0520) Such conditions lead to the fact that the first burning increases to 180%, and the pressure in the chamber to 5.1 inches of mercury (17.2 Kllaj. The resultant stream of hot gases generated during combustion) a transition zone in which liquid SF in the form of coherent jets is injected from the edges into the flow through four free nozzles, the size of each is 0.038 inches (0.97 mm). 400 g / h (0.117 kg / s) at an overpressure of 216 psi of 41.49 mlla.). The residence time is 0.7 s, after which the gas stream is extinguished with water (760 ° C). The maximum percentage of combustion is 48.1%. Soot is collected in the usual way, granulated and dried under oxidative conditions of a suitable nature. The result is soot with a specific surface area of iodine 740, pH 3.2, DBP number, equal to 197 cm V100 g, color intensity 132%, other characteristics are given in table.3.
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Example 7. The process in the apparatus is similar to Example 6, with some exceptions. Combustion air, preheated to 7 ° C
5 (3777 s), are introduced into the combustion zone with
speed of 71100 cubic feet / h (0.529). This air contains mixed water introduced at a rate of 35 gal / h (6140 cubic feet / h or 0.0457),
10: which is 7.5% of the total reagents used to produce primary combustion. Natural gas is injected into the first zone at a rate of 3340 cubic feet / h (0.0248)
15 at an overpressure of 10 psi (0.069 MPa). Oxygen is also added to the combustion zone at a rate of 3500 cubic feet / hour (0.0260). Under these conditions, primary combustion is equal to
20 but 298.7%, and the pressure in the combustion chamber is 3.2 inches Hg. (0.8 KEaj. Liquid raw materials, preheated to 405 ° F (), then injected into a hot high-speed flow
25 gases generated during combustion.
The injection is carried out in the form of coherent jets through four free nozzles, the size of each is 0.036 inches (0.91 mm). Liquid raw materials
30 are injected at a rate of 99 gallons / hour (0.115 kg / s) and at an overpressure of 245 psi (1.69 MPa). The reaction zone consists of a section of 24 feet long (7.31 m in diameter of 36 inches Jmov (0.92 m), followed by
a section 9 feet long C2.74 m) and a diameter of 27 inches (0.686 m). After the residence time in the reactor reaches 1 s, the reaction is quenched by 4Q to 1400 ° (), The maximum burning percentage is 47.7%. Analytical and physical properties of carbon black are given in table 3.
 EXAMPLE 8 The apparatus of Example 6 with minimal modifications is used. Combustion air, preheated to (), is introduced into the first zone at a speed of 71,000 cubic feet per hour (0.528). 50 This air contains added water, which is introduced at a rate of 35 gallons / hour (6140 cubic feet / h or 0.0457, which is 7.7% of the volume of gaseous reactants involved in the production of primary combustion. B natural gas is introduced into the combustion chamber at a rate of 5540 cubic feet / h (0.0412) at an overpressure of 13
SRI 21 psi iO, J45 Mia / and oxygen at a speed of 3500 cubic feet / (0.0260). This leads to the fact that primary combustion is 179.6%, and the pressure in the combustion chamber is 4.1 inches Hg. (13.8 kPa), the gas flow of the combustion products enters the transition zone (9 inches (0.229 m long and 5.3 inches (0.134 m) in diameter) where liquid feed is injected into it in the form of continuous jets through four 0.040 inch free jet (1.02 mm) each. Liquid raw materials, preheated to 405 P (207 s /, are injected at a rate of 86 gallons / hour (100 kg / s) at an overpressure of 140 psig (0.97 Mlla, the most obtaining necessary penetration, ensuring good dispersion and dispersion of the raw material. The gas flow enters the reaction chamber, which consists of t of two sections, one section having a length of 24 feet (7.32 m) and a diameter of 36 ddoyms (0.9 m), and the next length of 8 feet (2.44 m) and a diameter of 27 inches (0.686 m), there, after staying for 1 s, the coke; is quenched with water to 1,400 ° F (760 CJ. Then the soot is collected, granulated and dried under oxidizing conditions. The limit of combustion is 47.9%. The analytical and physical properties of this soot are given in table.3.
PRI me R 9. Use the apparatus, a tour similar to that specified in case 8, with the exception of the following. Combustion air, preheated to 750 ° F (399 ° C), containing water introduced into it at a rate of,. 20 gal / h (3510 cubic feet / h (0.0261, which is 4.5% of the volume of the reactants of the first zone) are introduced into the combustion zone at a rate of 70700 cubic feet / h (0.526). Natural gas is injected into the first zone at a speed of 6,700 cubic feet / h (0.05) with an overpressure of 26 pounds per square inch (0.179 MPa). Under such conditions, primary combustion is 119.8% and the pressure in the combustion ratio is 3 6 inches. (12.2 KPa). The hot stream of gas products formed during the burning of the scientific research institute then enters the transition zone and with liquid raw materials injected into it from the edges.
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heated to ZZO {l66 c}, with an overpressure of 320 psi inch (2.20 MPa). Liquid raw materials are injected through four free
5 jet size 0.0225 inch (0.57 mm) each with. speed of 44 gallons / hour (0.05 kg / s). After being in the reactor for 1.0 s, the black-and-gas products are quenched with water to
 About 1400 ° F (760 ° C). The maximum burning percentage is 55.5%. The carbon black is collected and granulated, dried under α-oxidizing conditions to obtain a product with a low pH value.
 5 Analytical and physical properties are given in table 3.
Example 10. The equipment is similar to that used in example 3, except that the air
20 for burning S is pre-heated to 710 F (3f7 C), together with water introduced at a rate of 31 gallons per hour (5440 cubic feet per hour) or 0.0405, which represents 8.3% of the volume of
25 spirit and natural gas used to prepare the primary combustion were injected at a speed of 60,500 cubic feet / h (0.450 into the burning zone. Natural gas was injected into the first zone at a rate of 4910 cubic feet / h (Oj0365.) At overpressure - SRI 17 psig (o, 117 MPa, Primary combustion is 139.7% and pressure in the combustion chamber is 2.7 inches
35 ma mouth, art. (9.1 IQIa). Then the hot JTOTOK of the gaseous products passes into the transition zone, equipping from the edges with four free jets of size 0.025 inch.
40 (0.64 mm) each. Liquid raw materials, preheated to 330 (16b C, are injected into a gaseous stream through four nozzles at a speed of 41 gallons / hour (0.048 kg / s) at
45 overpressure 167 psi an inch (1.15 MPa), the residence time in the reaction zone is 1.2 s before quenching with water up to 1400. The limit burning percentage is 55.9%. The carbon black is collected, granulated and dried under oxidizing conditions so that carbon black with a low pH is obtained. Analytical and physical properties of carbon black
are given in table 3. I
PRI me R 11. For example 10
combustion air, preheated to (), containing 46 g / h
55
15
8070 cubic feet / hr (0.060 m3 / s water, which corresponds to 10.5% of the volume of air and gas used to produce primary combustion, entered at the rate of 70100 cubic feet / h (0.522) to the combustion zone. Natural gas is injected into the first zone at a rate of 6750 cubic feet / h (0.050 m / s at an excess pressure of 18 psi (0.124 MPa). As a result, primary combustion is 119.9% and the pressure in the combustion chamber 3, 1 inch Hg j (lO, 4 KPa). The resulting hot stream, enriched with water, from the gases generated during combustion, enters the transition zone, into which it is injected through four free x 0,825 in. (0.57 mm) each liquid feed, preheated to 310 ° F (154 C), the feed is injected from the edges at a speed of 41 gallons / hour (0.048 kg / s) and with excess indicators. soot
Amount of water vapor,% of the volume of fuel and oxidizer
Surface area by iodine, MVr
PH
DBP, g
Color intensity,%
Compounds based on ethylene / ethylamine resin, content of 12 wt.% Carbon black
Specific volume -1-scarlet resistance, Ohm-cm room temperature623
Specific volume resistance. Ohm cm, 90 ° C
Moisture absorption,%
,
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a pressure of 170 psig (1.17 MPa), ensuring proper penetration into the stream of gases generated during combustion. The time of stay of 5 vanities in the reactor is 1 s, followed by quenching of the carbon-gas products with water up to 1345 F (729 C). The maximum burning percentage is 57%. The carbon black is collected, granulated and dried under oxidizing conditions. The properties of carbon black are given in the table
From the data presented in Table 1-3, it is obvious that the method according to the invention
results in furnace furnaces with an extremely high specific surface area. In addition, these data indicate that the conductive properties of furnace soot are
compare with properties high line 0; their soot, which is a by-product of gasification.
Table 1
Examples

5.4
566 8.1 186 131
10.8
630 8.4 198 139

537
3601 1.28
236
892 1.45
Compounds based on ethylene / ethyl acrylate resin, content of 12 wt.% Carbon black
Specific volume resistance, Ohm, cm, room temperature
Specific volume resistance
Oohahatel SJM
Surface area for iodine, wVr 740 630 772 865935
pH 3.2 3.6 3.4 3.03.3
DV ", cm / 100 g 197 196 .25 241264
On the other hand, the viscosity of coloring,% 1.32 121 i38 134142
Etnpe / ethylacpathic sopolinor, godskkkyy12 weight.Hsp
 The object of the OS was matched. Om-cm, yuptag temp- “T7P
Determine the bypass resistance of the KoBTpoiu – muyocapacitance of the sadi, bypassing the processes, using: the process for obtaining carbon dioxide to the hydroxy content of nx. glzagil mixtures, including gas and hydrocarbons with Sch1: gas content in the gas high temperatures: ..
VNIIPI Order 8551/62 j Circulation 644 Subscription Affiliate gash Patent, Uzhgorod, Proektna St., 4
Table 2
236
59
Table3
PR measures

678 9, 313 125
49
EO
22
18
N, 7

权利要求:
Claims (1)
[1]
METHOD FOR PRODUCING LIVER SOOT, including the introduction of water vapor into the combustion products of an oxidizing agent with fuel, radially injecting liquid coal and hydrogen raw materials into the flow of combustion products, thermal decomposition of the raw materials in the combustion products to form carbon black and gas products, their quenching, cooling and soot emission, characterized in that, in order to increase the specific surface area of soot, water vapor is introduced bi in the amount of 4.5-10.8% of the volume of fuel and oxidizer and the maximum percentage of combustion is 46.5-57.0%.
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类似技术:

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公开号 | 公开日 | 专利标题

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US4370308A|1983-01-25|Production of carbon black

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US3725103A|1973-04-03|Carbon black pigments

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US3952087A|1976-04-20|Production of high structure carbon blacks

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SU1205775A3|1986-01-15|Method of obtaining furnace black

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US4879104A|1989-11-07|Process for producing carbon black

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US6120594A|2000-09-19|Hydrogen peroxide oxidation of carbon black

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US6348181B1|2002-02-19|Process for producing carbon blacks

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US2914418A|1959-11-24|Manufacture of carbon black from liquid hydrocarbons

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US4105750A|1978-08-08|Production of carbon blacks

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US4751069A|1988-06-14|Automotive high color carbon

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US3207614A|1965-09-21|Cure indicator

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US4374113A|1983-02-15|Production of high surface area carbon blacks

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Hanson et al.1987|Novel applications of topological indices. 2. Prediction of the threshold soot index for hydrocarbon fuels

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DD114422B3|1986-10-29|OVEN GAS PRODUCT RUSS

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CA1081433A|1980-07-15|Production of carbon blacks

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KR800001355B1|1980-11-17|Production of carbon blacks

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US2066120A|1936-12-29|Manufacture of resins

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US2414465A|1947-01-21|Fuse powder compositions

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GB818823A|1959-08-26|Improvements in and relating to the production of hydrocarbons

同族专利:

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公开号 | 公开日

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DK317080A|1981-02-02|

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CS533480A2|1990-08-14|

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LU82671A1|1980-10-24|

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CA1156023A|1983-11-01|

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SE8700508D0|1987-02-10|

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SE463157B|1990-10-15|

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DK599683D0|1983-12-27|

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GB2094773A|1982-09-22|

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MY8500932A|1985-12-31|

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IT8068094D0|1980-07-10|

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DK599683A|1983-12-27|

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UA7201A1|1995-06-30|

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IE801605L|1981-02-01|

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JPH0210185B2|1990-03-07|

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RO80186A|1982-10-26|

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DE3026712A1|1981-03-26|

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JPS5624455A|1981-03-09|

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DE3026712C2|1994-01-27|

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BE884582A|1980-11-17|

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AU6091680A|1981-02-05|

---

NL183524C|1988-11-16|

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DK151386C|1988-05-16|

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SG70984G|1985-03-15|

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ZA803604B|1981-06-24|

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FR2465771B1|1984-10-19|

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PL126970B1|1983-09-30|

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SG70184G|1985-03-15|

---

NL8004048A|1981-02-03|

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IT1128926B|1986-06-04|

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GB2056957B|1983-01-12|

---

YU42674B|1988-10-31|

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DK151386B|1987-11-30|

---

SE8700508L|1987-02-10|

---

GB2056957A|1981-03-25|

---

ES493814A0|1981-08-01|

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NL183524B|1988-06-16|

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HK3185A|1985-01-18|

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IE50184B1|1986-03-05|

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GB2094773B|1983-09-14|

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SE8005237L|1981-02-02|

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YU177580A|1983-02-28|

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MY8500169A|1985-12-31|

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ES8106172A1|1981-08-01|

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HK92984A|1984-11-30|

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CS273305B2|1991-03-12|

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IL60340D0|1980-09-16|

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PL225834A1|1981-04-24|

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US4283378A|1981-08-11|

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SE450387B|1987-06-22|

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DD152571A5|1981-12-02|

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KR830000810B1|1983-04-19|

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EG14271A|1986-03-31|

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PT71560A|1980-08-01|

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AR242617A1|1993-04-30|

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FR2465771A1|1981-03-27|

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AU534358B2|1984-01-26|

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IN153979B|1984-09-08|

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DD152571B3|1986-06-25|

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BR8004740A|1981-02-10|

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AR231546A1|1984-12-28|

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NZ194441A|1982-03-30|

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IL60340A|1983-11-30|

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EP1310782B1|2001-11-09|2006-08-16|Trumpf Werkzeugmaschinen GmbH + Co. KG|Method and device for recording information for monitoring a laser device|

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JP4293831B2|2003-05-16|2009-07-08|三洋電機株式会社|Fuel cell|

法律状态:

优先权:

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申请号 | 申请日 | 专利标题

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US06/062,727|US4283378A|1979-08-01|1979-08-01|Production of high surface area carbon blacks|

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