• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    A device for generating high intensity ultraviolet radiation thermoemissively in a discharge tube filled with a mercury vapor and at least one rare gas, the discharge tube having two ends joined to two tubular envelopes housing anode and cathode electrodes, wherein the rare gas is either argon, krypton or xenon maintained at an operating pressure of between 0.01 and 0.5 Torr, and the discharge tube and the tubular envelopes consist of doped quartz glass doped such that radiation lines at 185 and 194 mm are almost completely absorbed and a radiation line at 254 nm is transmitted almost without loss, and wherein is provided on the discharge tube an appendix-like piece of tube, which is to receive condensed mercury and the temperature of which is adjustable between 48 DEG and 65 DEG C.
    公开号:SU1055347A3
    申请号:SU782683752
    申请日:1978-10-27
    公开日:1983-11-15
    发明作者:Брэндли Герольд；Нотц Ханс
    申请人:Ббц Аг Браун,Бовери Унд Ко (Фирма)；
    IPC主号:
    专利说明:

    This invention relates to devices for producing high intensity ultraviolet radiation. Devices known as multi-amperage sources of UV radiation or low pressure are known. In order to achieve a high radiation intensity, the lamps operate at a constant current. To do this, two electrodes are needed, namely, a thermionic cathode, for example, made from barium oxide and bombarded with high-energy 1-D electrons and therefore heat-resistant. an anode, for example, from graphite. Since during the operation of the radiation source at low pressure drops from the anode cavity to the cathode cavity, an intensive flow of mercury vapor can move, besides, the pressure compensation chamber (cavity) is required. However, the electrophoresis processes in the discharge cannot be eliminated; therefore, unequal irradiation of the entire surface of the discharge chamber is carried out and premature aging of the radiation source l and 2j occurs. The closest to the invention in its technical essence is a device for generating high-intensity ultraviolet radiation, which contains a discharge tube from a material that transmits ultraviolet radiation. The tube on opposite ends is connected by a stubby flasks in which thermionic electrodes are placed, and the mixture of mercury is filled under a pressure of 5-10 510 torr and an inert gas under a pressure of 0.010.5 torr. The known devices do not generate 254 mm of pure radiation. The purpose of the invention is to provide the generation of pure radiation with a wave of 254 nm with high efficiency and uniform intensity. The goal is achieved by the fact that in a device for generating high-intensity ultraviolet radiation, containing a discharge tube of a material that transmits ultraviolet radiation, connected at opposite ends with tubular flasks, in which thermal emission electrodes are not suitable, and filled with a mixture of mercury under pressure of 510–5 ° Chorr and an inert gas with a pressure of 0.01–0.5 Torr 72; the tube and flasks are made of doped quartz glass, absorbing lines 185 and 194 nm and allowing line 25 to pass through almost without loss 4 nm, the discharge tube has an area for receiving condensed mercury, made in the form of an appendix with means for temperature control from 48 to 65 ° C, the inner diameter of the tube lies within 815 mm, the diameter of the appendix is 0.3-1 of the diameter of the tube The diameter of each flask is 1-4 tube diameters, the length of which lies in the range of 0.8-2 m, the appendix length is 0.005-0.1 of the length of the discharge tube, and the volume of flasks is 0.5-4 volumes of the tube. Inert gas-xenon pressure values are within 0.04-0.1 Torr. FIG. Figure 1 shows the proposed device for operating on alternating current for producing UV radiation with an I-shaped discharge tube; in fig. 2 is a circuit diagram of a device power supply unit; in FIG. 3 shows the relative output of UV radiation in the device, depending on the pressure of the inert gas; in fig. 4 shows a pressure compensated DC device with a detailed image of the flasks; in fig. 5 - the same general view. A U-shaped gas discharge tube I at each end is connected to tubular bulbs 2 and 3, in which electrodes 4 and 5, respectively, which are led 6 and 7, are led outside. In the middle of the curved section of the gas discharge tube 1 there is an appendix section 8, which serves to receive condensed mercury. The gas discharge tube 1, including both flasks 2 and 3, as well as the appendix section 8, consists of quartz glass doped in such a way that the ozone-generating mercury lines 185 and 194 nm are absorbed, and the sterilization line 254 nm is passed through with almost no loss. Electrical leads 6 and 7. These are molybdenum plates that are pressed into the quartz glass of flasks 2 and 3. Wire 9, which touches the gas discharge tube 1, when loaded with pulses of about 20 kV, promotes ignition of the gas discharge tube 1 prepared for operation. At the same time, this wire can serve as an attachment for a gas discharge tube. The discharge tube 1 has a approximately circular cross-section and an inner diameter of mostly 8, 15 mm and a length of 0.8-2 m. Both flasks 2 and 3 have an internal diameter of 1-4 times more than that of the discharge tube. and the volume is 0.5. The volume of its appendix section 8 is preferably 10-50 mm in length, and the internal diameter is 0.3-1 internal diameter of the discharge tube. The shape and design of the electrodes 4 and 5 essentially correspond to the shape and design of the thermionic cathode {phage. 4, item 5). In addition, oxide cathodes made using powdered nickel and (Ba, Ca, Sr) carbonate, or dispersed cathodes containing tungsten, molybdenum or tantalum in powder, and barium or a rare-earth metal are suitable. Dp power supply of the proposed device is the circuit (Fig. 2). In this block, the transformer 10 by heating the electrodes by the primary winding is connected to an alternating voltage source of 220 V. A part of the secondary winding is used to heat the electrode 4, another part is to heat the electrode 5. Parallel to two current leads of both electrodes 4 and 5, an ignition circuit 11 is mounted The supply electrode 4 by the current of the secondary winding of the heating transformer 10 is connected through a current-limiting choke 12 and the switch 13 to one of the poles of the voltage source, and the current supplying the electrode 4 of the secondary heating winding Shaper 10 is shorted to the other pole of the voltage source. Thanks to this unit, this device can be operated with the simplest means, without using rectifiers. As filling gases, argon, krypton and / or xenon are used, as well as mercury, which is in excess in liquid form is disposed in apen dixo 8 tube section. The temperature and, therefore, the pressure of mercury are regulated by heating the appendix-like area to 48-65 ° C. From FIG. 3, where the UV output of this device is shown in the wavelength range of 254 nm, depending on the pressure used to fill the inert gas, it follows that the UV emission output of this pump is in the pressure range of 0.01-0.5 Torr of argon, krypton or xenon is greater than 50% of the maximum yield, and therefore, in this pressure range, high radiation intensity is easily reached at a wavelength of 254 nm. In addition, it is advisable to set the pressure of xenon to 0.040, 1 torr, since xenon in this pressure range with respect to, in particular, the ionization voltage during electrical discharge has properties similar to 1 mercury at 55 ° C. Curves (Fig. 3) dp gas discharge tubes with an internal diameter of about 10 mm were constructed at a mercury pressure corresponding to a condensation temperature of 55 ° C and a current density of 5 A / cm. Instead of limiting the current density to only 5 A / cm, depending on the shape and size of the lamp proposed, it is advisable to set the current density within 3-10 A / cm, and the arc voltage 0.3-1.2 V / cm2. In the flask 2 (Fig. 4), both electrodes cathode 5 and anode 4 are located next to each other from heat-resistant refractory glass. 5 Along with its own heating coil, it has a cylindrical radiation screen 14, which should delay the radiation of heat to the sides. The discharge gap of tube 1 consists of two bends, which are closed at one end to alba 2. At the same time, a starter. In flask 2, the knee enters coaxially into flask 3, penetrates the annular anode 4 and, with a corresponding expansion in region I5, encloses cathode 5. Pressure compensation cavity 16. between the walls of the flasks 2 and 3 in the entire area forms a stable and protected from the sample area, which provides sufficient gas / vapor flow, if the distance D is not less than 0.5 mm. With distances D greater than 4 mm, arbitrary ignition (breakdown) can be carried out on its own. In these cases, the cathode 5 should be placed further inside the bulb 3, since then the path from the anode to the cathode through the pressure compensation cavity is extended, which also prevents the possibility of breakdown. Radiation sources with a distance of 0 mm are appropriate. In order to ensure flawless operation of the source of treatment, the length L of flask 3 in flask 3 from the bottom edge of the anode 4 to the bottom edge of flask 3 should be 7 approximately 1 / 5-1 / 20, mainly 1/10, and length L located outside the flask 2 of the gas discharge (tube. The design of the proposed device is simple to manufacture. Preferred. Working characteristics: inert gas pressure (2-5) 10 Torr, current density 48 A / cm, temperature of mercury in the appendix-shaped ZO-BO C, voltage drop across the discharge gap 1 V / cm ± 0.2, length and the appendix-shaped area 3-6 cm with an internal diameter of 10 mm.
    V
    13
    t.0.
    t
    g
    If
    11 6
    five
    Ar
     Yu
     Mr. S
    PCJffrrJ
    FIG.
    权利要求:
    Claims (2)
    [1]
    1. DEVICE FOR GENERATION OF HIGH-PERFORMANCE UV RADIATION, containing a discharge tube made of a material that transmits ultraviolet radiation, connected at the opposite ends with tubular flasks, in which thermionic electrodes are placed, and filled with mercury * mixture under a pressure of 5 × 10 5 torr and inert gas under a pressure of 0.01-0.5 torr, characterized in that, in order to generate pure radiation with a wave of 254 nm at high efficiency and uniform intensity, the tube and flask are made of doped qua A glass, absorbing the lines of 185 and 194 nm and transmitting the line of 254 nm almost without loss, the discharge tube has a section for. receiving condensed mercury, made in the form of an appendix with means for controlling the temperature from 48 to 65 ° C, the inner diameter of the tube is in the range of 8-15 mm, the diameter of the appendix is 0.3-1 the diameter of the tube, the diameter of each of the flasks is 1-4 * the diameter of the tube, the length of which lies within 0.82 m, the length of the appendix is 0.005-0.1 the length of the discharge tube, and the volume of the flasks is 0.5-4 volumes g of the tube.
    [2]
    2. The device according to p. I, with the exception that the values (inert gas-xenon pressures are 0.04-0.1 torr.
    Priority on points:
    10.31.77 by π. 04.10.77 p. 2
    类似技术:
    公开号 | 公开日 | 专利标题
    SU1055347A3|1983-11-15|Device for generating high-intensity ultraviolet radiation
    US3778662A|1973-12-11|High intensity fluorescent lamp radiating ionic radiation within the range of 1,600{14 2,300 a.u.
    US3900753A|1975-08-19|High pressure sodium vapor lamp having low starting voltage
    US4636692A|1987-01-13|Mercury-free discharge lamp
    EP0054959A1|1982-06-30|Beam mode fluorescent lamp
    US3484640A|1969-12-16|Metal halide vapor photochemical light sources
    EP0115653A1|1984-08-15|Discharge lamp
    US4445073A|1984-04-24|Intimate contact starting aid for arc lamps
    US3828214A|1974-08-06|Plasma enshrouded electric discharge device
    US2774013A|1956-12-11|Electric discharge lamp
    US3657590A|1972-04-18|High intensity far u.v. radiation source
    US3757159A|1973-09-04|Sodium vapor lamp having improved starting means
    US2492619A|1949-12-27|Electrical discharge tube
    US2001501A|1935-05-14|Gaseous electric discharge device
    US3721845A|1973-03-20|Sodium vapor lamp having improved starting means
    KR100687946B1|2007-02-27|A flash discharge lamp and a light energy irradiation apparatus
    US2404002A|1946-07-16|Electrical gaseous discharge lamp
    US3558964A|1971-01-26|High current thermionic hollow cathode lamp
    US1908649A|1933-05-09|Electrical discharge device
    US3450925A|1969-06-17|Mercury bismuth halide photochemical arc lamp light sources
    US3444415A|1969-05-13|Fluorescent discharge lamp
    US3590306A|1971-06-29|Convective arc stabilization by lamp rotation
    US1965127A|1934-07-03|Electrical discharge lamp
    US3657591A|1972-04-18|High intensity far u.v. radiation source
    US3771007A|1973-11-06|High intensity lamp apparatus and method of operation thereof
    同族专利:
    公开号 | 公开日
    JPS63127065U|1988-08-19|
    AU537569B2|1984-07-05|
    BR7807109A|1979-07-17|
    IN149856B|1982-05-15|
    AT362018B|1981-04-27|
    FR2407569B1|1983-12-16|
    AU4116178A|1980-05-08|
    DK481378A|1979-05-01|
    JPS5471887A|1979-06-08|
    GB2009493B|1982-07-28|
    DK151599B|1987-12-14|
    FR2407569A1|1979-05-25|
    SE7811150L|1979-05-01|
    JPH0122219Y2|1989-06-30|
    GB2009493A|1979-06-13|
    NL7810715A|1979-05-02|
    ES474610A1|1979-03-16|
    NL185374C|1990-03-16|
    SE430836B|1983-12-12|
    JPS6292561U|1987-06-13|
    NL185374B|1989-10-16|
    US4349765A|1982-09-14|
    DK151599C|1988-05-24|
    ATA770878A|1980-09-15|
    JPS6330108Y2|1988-08-12|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    WO2004059694A1|2002-12-25|2004-07-15|Zakrytoe Akzionernoe Obschestvo Nauchno-Proisvodstvenny Tsentr 'soliton-Ntt'|Ultraviolet vapour lamp|GB293682A|1927-07-09|1928-12-24|Rainbow Light Inc|Improvements in luminous electric discharge tubes of high candle power|
    US2272992A|1938-09-17|1942-02-10|Hebo Halfdan|Generator for ultraviolet energy|
    IN142576B|1974-03-04|1977-07-30|Bbc Brown Boveri & Cie|
    US3988628A|1974-06-13|1976-10-26|General Electric Company|Metal halide lamp with titania-silicate barrier zone in fused silica envelope|
    CH581903A5|1975-03-14|1976-11-15|Bbc Brown Boveri & Cie|
    US4056751A|1976-03-22|1977-11-01|Gte Sylvania Incorporated|Metal halide discharge lamp having optimum electrode location|
    NL180156C|1976-10-29|1987-01-02|Philips Nv|GAS AND / OR VAPOR DISCHARGE LAMP.|JPS59148256A|1983-02-10|1984-08-24|Oak Kk|Flash discharge tube|
    DE3422605C2|1984-06-18|1991-10-17|Friedrich 7800 Freiburg De Wolff|
    US4611661A|1985-04-15|1986-09-16|Vetco Offshore Industries, Inc.|Retrievable exploration guide base/completion guide base system|
    JPS63133444A|1986-11-25|1988-06-06|Semiconductor Energy Lab Co Ltd|Light source for photoprocessing equipment and its usage|
    US4835442A|1987-01-29|1989-05-30|Kabushiki Kaisha Toshiba|Lamp for generating ultraviolet radiation|
    KR920010058B1|1989-04-28|1992-11-13|도오시바 라이텍크 가부시기가이샤|Low pressure gas discharge lamp|
    DE4018792C2|1990-06-12|1994-03-10|Vector Related Physics Consult|Process for producing a gas discharge light source and gas discharge tube|
    US5170091A|1990-12-10|1992-12-08|Ultraviolet Energy Generators, Inc.|Linear ultraviolet flash lamp with self-replenishing cathode|
    KR940001248A|1992-06-27|1994-01-11|최승재|Fluorescent lamp|
    CN2378828Y|1999-05-26|2000-05-17|马士科技有限公司|Cold-end device for low-voltage mercury vapour discharge lamp|
    JP2001286543A|2000-01-31|2001-10-16|Tanita Corp|Shoe deodorizer|
    CN1267966C|2000-03-31|2006-08-02|皇家菲利浦电子有限公司|Discharge lamp|
    US20030051990A1|2001-08-15|2003-03-20|Crt Holdings, Inc.|System, method, and apparatus for an intense ultraviolet radiation source|
    US20050035711A1|2003-05-27|2005-02-17|Abq Ultraviolet Pollution Solutions, Inc.|Method and apparatus for a high efficiency ultraviolet radiation source|
    US7173254B2|2004-05-19|2007-02-06|Light Sources, Inc.|Compact germicidal lamp having multiple wavelengths|
    CN2829078Y|2005-09-28|2006-10-18|杨世光|Vitalight tube|
    US20110180423A1|2008-02-11|2011-07-28|Wisconsin Alumni Research Foundation|Methods for removing contaminants from aqueous solutions using photoelectrocatalytic oxidization|
    US20090314711A1|2008-02-11|2009-12-24|Barry Terence P|PHOTOELECTROCATALYTIC OXIDIZER DEVICE HAVING COMPOSITE NANOPOROUS TiO2 COATED Ti PHOTOANODE AND METHOD OF REMOVING AMMONIA FROM WATER IN AQUARIA AND RECIRCULATION AQUACULTURE SYSTEMS|
    CA2857147C|2011-12-02|2016-01-12|AquaMost, Inc.|Apparatus and method for treating aqueous solutions and contaminants therein|
    US8398828B1|2012-01-06|2013-03-19|AquaMost, Inc.|Apparatus and method for treating aqueous solutions and contaminants therein|
    US9045357B2|2012-01-06|2015-06-02|AquaMost, Inc.|System for reducing contaminants from a photoelectrocatalytic oxidization apparatus through polarity reversal and method of operation|
    CA2900722A1|2013-02-11|2014-08-14|AquaMost, Inc.|Apparatus and method for treating aqueous solutions and contaminants therein|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    CH1319877A|CH623957A5|1977-10-31|1977-10-31|Device for producing ultraviolet radiation, especially a low-pressure gas-discharge lamp|
    DE19782814683|DE2814683C2|1978-04-05|1978-04-05|
    [返回顶部]