• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    A process is described for the production of high grade carbonaceous binders, wherein an aromatic high grade carbonaceous material is produced from 5-40% by weight of reduced or low ash coal or similar carbon containing raw materials by treatment with 20-80% by weight of high-boiling aromatic solvents, derived from coal, and 15-50% by weight of high-boiling aromatic solvents, derived from mineral oil, at temperatures of 300 DEG -420 DEG C. and for a reaction period of 1-4 hours, at a reaction pressure of up to 50 bar, and is optionally freed from low-boiling components.
    公开号:SU1055337A3
    申请号:SU813329301
    申请日:1981-09-02
    公开日:1983-11-15
    发明作者:Штадельхофер Юрген；Герхард Франк Хейнц；Келер Хельмут；Луис Хейнрих
    申请人:Рютгерсверке Аг (Фирма)；
    IPC主号:
    专利说明:

    This invention relates to a process for the release of a perverse binder from a upp by treating a disintegrated upp at elevated temperature and pressure using aromatic; taken from TPs and mineral oils, solvents, and can be used in the geological and coking industry. A known method for producing a carbon-organic binder by mixing 1 part by weight of powdered cpp with 1 part by weight. and a larger masp followed by stirring and heating at 30–30 ° C for 30–24 ° min. The obtained pitch for desalting is treated with a polar organic solvent or an aromatic solvent l |. There is also known a method for producing a perodic binder from a gopp and residual masp by attaching finely ground powdered carbohydrate with petroleum residues, and then dissolving the mixture at 4OO-45 ° C, according to which 30pa contained in the coal coagulates together with insoluble microspheres contained in the crude oil the rest. The latter is specially pretreated and thus removed from the mixture 21. The closest to the invention is a method for preparing a permeable binder by mixing carbon with an aromatic solvent to form a suspension and treating it at elevated temperature and pressure. The disadvantages of the method are the necessity to use the stages of separation of the insoluble solids from the extract and the presence in the separated extract of an increased amount of ash ash, which affects the quality of the binder. The purpose of the invention is to obtain a high quality, permeable binder in the production of electrodes. The goal is achieved by combining a binder with an aromatic solvent with the formation of a slurry binder and processing it at II (with a high temperature, as carbon and joining, it mixes with dissolving the mixture, and mixes with a dissolvable matte, which is mixed with a mixture of matrices and mixes with an aromatized solvent, which is mixed with solvent and matrices. , boiled coal, with a SOJcr-Horo temperature of boil-off of 416-4651 and a cracking residue “Yeukin with a temperature of 50% boil-off of 350-435С, with the following ratio of components in suspension, wt.%: Desiccated coal 5-4 O Aromatic m Spa with a temperature of 5O% boiling out 416-4b5s 20-80 residue, cracking of oil fractions with a temperature of 5O% boiling out of 350-435 ° C 15-50 and processing the suspension is carried out at ZOO-42Os, pressure 5-50 bar within 1-4 hours with the removal of low-boiling fractions and, if necessary, followed by mixing the resulting mixture with 30-60% by weight of pitch with a softening temperature of 115-160 °, obtained from carbonic or mineral oils. According to the proposed method, coal is used and in the disintegration circuits of the latter, residues from the splitting of naphtha or gas oil in the vapor phase, the residue and from catkracking, delayed coking, as well as high-boiling aromatic diethyls obtained as a result of raffiating of coal-tar nesa, with a mean boiling point above 350 ° C. In addition, up to 60% is used to finalize the flow of coking residue, taking into account the product obtained by disintegrating ugg, for example, residues from the distillation of coal tar pitch or, preferably, from distillation of pyrolgas oil with a softening point of 115-160 0 (Cremer’s and Sarnova), and the variety of CCP is only of secondary importance. However, preference is given to carbon seals with a high carbon content, and this in its own way. nature must be such that it is possible to separate it in a known way. In order to ensure the wide applicability of the proposed method, a desalting method is chosen, according to which the ash content of the coal is reduced by intensive chemical treatment with acids and bases. Other methods of sanitizing are also suitable, and when using ultrapure coals with ash content below 1.%, the separation of ash can be avoided. De-coaling coal & 1 will prescribe chemical reactions under severe conditions with the use of KEYPOT, bases and will oxidize them, affecting the dissolution of carbon, particularly in the case of oxidizing treatment of coal, pre-decay of pac-t in aromatic compounds. When used for disinfection, UGF solvents should be as low as possible. This requirement is satisfied in particular by pyrolysis oils obtained by splitting mineral oil fractions in the vapor phase, distillates obtained by refining coal tar, and residual oils obtained by delayed coking and selected coal tarry. For dry ash, cracking residues can also be used as additional solvents. ; It is preferable to use pyrolysis oils obtained as a result of the splitting of mineral oil fractions in the vapor phase, since these oils have a pronounced tendency to poly. merization, which is beneficial for obtaining large residues from coking. Among the coal tar oils, preference is given to distillates obtained by treating the coal tar pitch with heat and pressure with a midpoint of a higher boiling point or similar distillates obtained from the processing of coal tar by distillation. Example 1. Getting degraded Shago coal in accordance with US patent No. 4134737: G; weight.h. nysocodis4 persistent gas flame of coal of the Veotherholt type (MVestet-hoEt) with ash content of 7.8% and a volatile content of water components without ash and ash 38% for 3 hours at 25 ° C o & g. work 4 weight.h. 1O% solution of caustic soda. Washed - the reaction product for 30 min when treated, 2 weight.h. 5% sulfuric acid and then another 1 hour at 75 ° C 1.5 parts by weight 18% nitric acid. The ash content of the coal thus treated is 0.9%. The output is quantitative. In order to obtain a binder for the electrodes, a mixture is prepared: 30% of the weight of the depoped Vesterkolt; 30 weight.h. pyrolysis of 1H) of the residue of the split & nine naphtha in the vapor phase (initial boiling point 220 ° C, 50% at 360 ° C) and 40 parts by weight pitch distillate obtained by treating coal tar pitch with heat and pressure (boiling start temperature 305 ° C, 50% at 416 ° C, 8.0% at 455 ° C), and with good stirring, 1,374 are homogenized for 2 hours at 375 ° C. reaction pressure 24 bar. After separation of 3% of the light-boiling components, a pitch-like coal processing product is obtained with a yield of 95%. This product is mixed to homogeneity with 30% solid pitch, obtained as a result of the processing of coal pitch and ordinary pitch. The softening point of this solid pitch is 160 C (according to Kremer and Sarnov). Indicators of the obtained binder are shown in the table. Example 2. ZO weight.h. de-ashes gas flame Westerholt type is treated for 3 hours at 4OO ° С with a mixture of 20 parts by weight pitch distillate obtained as a result of treatment of carbonate pitch with heat and pressure, 4O weight.h. pyrolysis residue obtained according to example 1 after splitting the caffe, and 1O weight.h. residues of cracking (initial boiling point, 50% to 435 C). Maximum reaction pressure 40 bar. . After separation of 3% of light-boiling components, a coal processing product is obtained with a yield of 95% with a measuring point of 60 ° C (according to Kremer and Sarnow). This preduct mixed to homogeneity with 50 weight.h. solid pitch obtained by distilling crude gasoline pyrolysis residues. The softening point of solid pitch 135C (according to Kremer and Sarnov). Indicators of the obtained binder are given in the table. Example 3: Carried out analogously to example 1. As coal, gas fired coal with a content of volatiles of 26.5% and ash content, 9% is used. Desalting is carried out as in Example 1. The residual ash content of coal is 0.8%. 30 weight.h. dispersed gas flame coal with good stirring for 2 h at 400 ° C is subjected to reaction with 40 weight. including pitch distillate, obtained as a result of processing coal tar pitch with heat and pressure, as in 1, and 300 weight.h. shpdannogo oil, resulting from the cleavage of raw gasoline in the vapor phase (temperature of chickens 220 ° C, 50% to 350 ° C). Maximum reaction pressure 18 bar. A product is obtained: recycled ugp with a yield of 97% with a softening point of 80 ° C (according to Kremer and Sarno woo). Easy-to-use components (3%) are separated from this product, after which it is
    they are mixed to homogeneity with 30% of the total pitch of the pitch with a softening point (according to Kremer and Sarnov), resulting from the distillation of the pyropweave masoia.
    The indicators of the resulting binder 5 are shown in the table.
    Example 4. 5 wt. 4, gas-flame Westerpopt type carbon coal is treated for 1 hour at 420 ° C in a weight of about. pitch distillate obtained as a result of processing coal tar pitch with heat “pressure as in example 1” and 15 wt. including the residue of pyrolysis of naphtha, as in example 1. The maximum pressure IN bar.
    After otyutuni ZO% light boilers (5 components receive the product of coal processing with yields of 67% with a ramification point of 89 ° C.
    Indicators of the obtained binder are given in table.20
    Example 5. 4O weight.h. gasoline coal coal according to example 3
    melted for 4 hours at 20 weight.h. soft coal tar pitch (softening point according to Kremer and Sarnov, initial boiling point 300, 5% to 465 ° C) and 40 parts by weight pyrolysis oil, obtained as a result of the uncoupled crude gasoline in the vapor phase (initial boiling point, 10% to 35 ° C),
    Max1 4 pressure is 5 bar.
    The resulting carbon processing product is obtained with a yield of 98% with a softening point. After separating 2% of the easily boiled components, the product is mixed to a level of solid with a% solid pitch with a softening point (according to Kremer and Sarvov), obtained as a result of distillation of pyrolysis oil).
    Indicators of the received general reduction in the table.
    9 105ВЗЭ710
    Example b (comparative), in terms of high-quality binding agents, in comparison with tabular prints, there are several types of binders, according to which, as a binder made from ka-components, you can use a gamble cupboard, which is well tolerated as materials, coal and mines remains a simple pop-up method.
    权利要求:
    Claims (1)
    [1]
    METHOD FOR PRODUCING CARBOHYDRATE OF A NATURAL BINDER by mixing coal with an aromatic solvent to form a suspension and treating it at elevated temperature and tsavpe ( characterized in that, with a chain for obtaining high-quality "
    5-40
    20-80 carbon binder for electrodes, desalted coal is used as coal, which is mixed with a solvent consisting of aromatic oils obtained from coal with a temperature of 50% boiling point 416-465 ° С and the residue of cracking of oil fractions with a temperature of 50% - boiling 350-435 ° C, with the following ratio of components in suspension, wt.%:
    Desalted coal Aromatic oils with a temperature of 50% boiling point 416-465 ° С
    The remainder of the cracking of oil fractions with a temperature of 50% boiling point of 350-435 ° C 15-50 and the processing of the suspension is carried out at 300-42O ° C, a pressure of 5-50 bar for 1-4 hours to remove low boiling fractions and, if necessary, subsequent mixing of the mixture with 30-60 wt.% yeka with a softening temperature of 115-160 ° C, obtained from coal or mineral oils.
    I>
    I ί
    类似技术:
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    同族专利:
    公开号 | 公开日
    AU7488581A|1982-03-11|
    FR2489357B1|1984-10-26|
    GB2083070A|1982-03-17|
    PL130835B1|1984-09-29|
    US4339328A|1982-07-13|
    ZA814803B|1982-07-28|
    GB2083070B|1984-01-25|
    CA1159787A|1984-01-03|
    FR2489357A1|1982-03-05|
    AU544658B2|1985-06-06|
    DE3033075C2|1982-11-18|
    PL232881A1|1982-04-26|
    JPS619269B2|1986-03-20|
    JPS5777017A|1982-05-14|
    CS223894B2|1983-11-25|
    DE3033075A1|1982-05-06|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    DE1105379B|1953-08-10|1961-04-27|Bergwerksverband Ges Mit Besch|Process for the production of shaped coke|
    US3849287A|1973-02-05|1974-11-19|Universal Oil Prod Co|Coal liquefaction process|
    GB1481799A|1973-11-30|1977-08-03|Coal Ind|Manufacture of coke|
    US4072599A|1975-08-28|1978-02-07|Reynolds Metals Company|Carbon electrodes having stabilized binders derived from the entire organic fraction of bituminous coal|
    US4040941A|1975-11-17|1977-08-09|Director-General Of The Agency Of Industrial Science And Technology|Process for liquefying coal|
    US4188235A|1976-07-09|1980-02-12|Mobil Oil Corporation|Electrode binder composition|
    DE2935039C2|1979-08-30|1982-11-25|Rütgerswerke AG, 6000 Frankfurt|Process for the production of a highly aromatic, pitch-like carbon material|DE3030723C2|1980-08-14|1984-09-20|Rütgerswerke AG, 6000 Frankfurt|Process for dissolving coal in hydrocarbon mixtures|
    DE3311552A1|1983-03-30|1984-10-04|Veba Oel Entwicklungsgesellschaft mbH, 4660 Gelsenkirchen-Buer|METHOD FOR HYDROGENATING COAL|
    JPS6335195B2|1983-04-22|1988-07-13|Kogyo Gijutsuin|
    US4806227A|1984-04-06|1989-02-21|The Dow Chemical Company|Carbon black inhibition of pitch polymerization|
    JPH01149270U|1988-04-06|1989-10-16|
    TWI657127B|2017-01-20|2019-04-21|台灣中油股份有限公司|Densifying agent|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    DE3033075A|DE3033075C2|1980-09-03|1980-09-03|Process for the production of high quality carbon binders|
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