• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    FUNGICIDE MEANS in the form of an emulsifiable concentrate, containing the active ingredient - derivatives of o1-azolyl-o1-phenylacetic acid and emulsifier - sodium ligninsulfonate or polyoxyethylene sorbitan monooleate, which is different from the fact that it is used as a component, as well as in the same package, as well as in the same package, as well as in the same package, it is also used as a component. ot-phenylacetic acid of a compound of the general formula xt (L where X is chlorine in position 2 and / or 4; m is O, 1 or 2; A is the -OR group, where R is tert-butyl, tert-amyl, or the NRR group 2, where R is isopropyl, butyl, sec-butynyl, cyclohexyl, phenyl, b enyl, p-chlorophenyl, 2 methyl, isopropyl, isobutyl, tert-butyl, or R and R together with the nitrogen atom form a 2,6-dimethylpiperidine ring, and 01 is 2; SP AZ - imidazol-1-yl, 1,2 , 4-triazol-1-yl, and, if C is O, then A means NR1R2, with the following ratio of components, wt.%: These derivatives of oL-azolyl-oC-phenylacetic acid80 Sodium ligninsulfonate or polyoxyethylene sorbitan monooleate 20 four
    公开号:SU1011034A3
    申请号:SU792836783
    申请日:1979-10-12
    公开日:1983-04-07
    发明作者:Саутер Хуберт；Цее Бернд；Ренцеа Костин；Поммер Эрнст-Хайнрих
    申请人:Басф Аг (Фирма)；
    IPC主号:
    专利说明:

    This invention relates to a chemical plant protection agent, specifically a fungicide agent based on o-azolyl-cA-pheny derivatives of uksu acid and an emulsifier. It is known fungicide, the active agent of which is derived from azole Cl J. The fungicide based on derivatives with α-phenyl- (1, 2, 4-triaol-1 or acetic acid and emulsifier sodium ligninsulfonate or polyoxyethylene sorbitan monoole is the closest to the one proposed. L 2 J. However, these fungicidal agents have insufficient activity at low concentrations. The purpose of the invention is to increase the fungicidal activity by finding new fungicidal agents. To achieve this goal the fungicide in the emulsifiable concentrate contains the active ingredient - derivatives d - azo lyl- {g-phenylacetic acid of the formula AZ - imidazol - 1-yl, 1,2,4-triazol-1-yl, moreover, if m is O, then A means NR1R2, a mulgator — ligninsulfonate, natoles, polyoxyethylene sorbitan monoate, in the following ratio,% by weight: Specified derivatives — azolyl-o — phenylacetic acid80 Sodium ligninsulfonate or polyoxyethylene sorbate monooleate 20 The proposed fungicide is used by the means of the means using the methods used by the means of the masses to use the tools by the means of the means of the means of the use of the means of the means of the use of the means of the means of the means of the means of the use of the means of the means of the means of the means of the means of the means of the use of methods, the polyoxyethylene sorbate monooleate20. Ator. The compounds of formula (I) are obtained by the action of compounds of formula
    tn
    -h.d :: op in position 2 and / or 4;
    e X
    —O, 1 or 2;
    -OR group, in which
    R is tert-butyl, tert-amyl, or the group NRR2, in which. H - isopropyl, butyl, sec-butynyl, cyclohexyl, phenyl, benzyl, p-chlorophenyl, R 2. methyl, isopropyl, -, tert-butyl, or R and R together with the nitrogen atom form a 2,6-dimethylpiperidine ring, and m is 2;
    where X, m and A have the above
    value;
    Z is a chlorine or bromine atom, with 0.5-2 equivalents of an alkali salt of the corresponding azole at 0–200 ° C, preferably 20–160 ° C, in presence of ccBHH {if necessary) bases, solvents and / or diluents. Methanol ethanol, ieopropanol, n-butanol, diethyl ether, tetrahydrofuran, dioxane, dimethyl sulfoxide, chloroform, methylene chloride, toluene and preferably acetone, acetonitrile or dimethylformamide are used as solvents or diluents. Organic amines or inorganic compounds are used as bases.
     The compounds obtained by this method are presented in Table. one.
    .Table 1
    2, - 4-С
    1,2,4-Triazol-1-yl
    Jl
    lo-j-io
    Mf
    41
    117-120
    BUT
    ..about
    157-161 16 N- 1011034
    I Continuation tabl, 1 X v.,. JL106
    -J
    1,2, 4-Triaol-1 IL
    Continuation of table 1
    J
    115
    Tya
    19 4-С
    20
    21
    Continued table. 2 dl ester of dL-phenyl -, - l, 2, 4-triazol-1-yl-acetic acid; B - tert-45-butylamide oC-phenyl-CI, 2, 4-triOZOL-1-IL-acetic acid.
    Example 2. Leaves of a grapevine variety Mie IIeg-Thurgau grown in pots are sprayed with aqueous suspensions containing 80% by weight of compound (I) and 20% ligninsulfonate. Use 0.05 and
    0.025% spray solutions. After the leaves have dried, they are infected with a suspension of zoospores P1 hectares viticola. Then plants for 16 hours
    0 is placed in a chamber saturated with water vapor at 20 s, and then for 8 days in a greenhouse at 20–30 ° С. Thereafter, I, to speed up and enhance the development of the sporangiafor plant, are again placed in a humid chamber for 16 hours. Then the fungal damage is determined, and O means no damage to the bacteria, 5 is a complete damage (control). The data presented in Table. 3Table
    Leaf damage after
    Acting spray solution of the current beginning concentration,%
    0.025
    0.05 7 O 9 O 10 O Control (untreated) Thus, the tool has a significant activity in chi. fungicidal juice concentrate
    权利要求:
    Claims (1)
    [1]
    A FUNGICIDIC AGENT in the form of an emulsifiable concentrate containing the active ingredient - derivatives of C1-azolyl-C1-phenylacetic acid and an emulsifier - sodium lignin sulfonate or polyoxyethylene sorbitan monooleate, distinguished by the fact that, in order to increase fungicidal activity, it contains -azolyl-ct-phenylacetic acid of the compound of the general formula
    Xt where X is chlorine at position 2 and / or 4; m is 0.1 or 2;
    A is a —0R group, where R is tert-butyl, tert-amyl, or an NR ″ R2 group, where R 1 is isopropyl, butyl, sec-butynyl, cyclohexyl, phenyl, benzyl, p-chlorophenyl, r2 is methyl, isopropyl, isobutyl, tert-butyl or R 1 and R ^ together with the nitrogen atom form a 2,6-dimethylpiperidine ring, am is 2;
    Az is imidazol-1-yl, 1,2,4-triazol-1-yl, and if m is 0, then A means NR 1 r2, in the following ratio of components, wt.%:
    The indicated derivatives of c-azolyl-cC-phenylacetic acid 80
    Sodium ligninsulfonate or polyoxyethylene sorbitan monooleate 20
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    同族专利:
    公开号 | 公开日
    DK437779A|1980-04-19|
    DE2961271D1|1982-01-14|
    EP0010270A1|1980-04-30|
    DE2845293A1|1980-05-08|
    ZA795528B|1980-10-29|
    DD146538A5|1981-02-18|
    AT353T|1981-11-15|
    JPS5555166A|1980-04-22|
    PL218988A2|1980-08-11|
    PL119823B2|1982-01-30|
    IL58445D0|1980-01-31|
    EP0010270B1|1981-11-04|
    CA1127154A|1982-07-06|
    CS203039B2|1981-02-27|
    US4297364A|1981-10-27|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    CH531516A|1969-05-21|1972-12-15|Bayer Ag|Process for the production of new phenylimidazolyl fatty acid derivatives|
    GB1535777A|1975-08-26|1978-12-13|Ici Ltd|Imidazole and 1,2,4-triazole compounds and their use as pesticides|
    US4079143A|1975-08-26|1978-03-14|Imperial Chemical Industries Limited|Fungicidal 1H-1,2,4-triazoles|
    US4073923A|1975-09-10|1978-02-14|Imperial Chemical Industries Limited|Fungicidally effective imidazoles and use thereof against fungal pests|
    IE43731B1|1975-10-09|1981-05-26|Ici Ltd|A--acetophenones and their use as pesticides|
    US4073925A|1975-12-12|1978-02-14|Imperial Chemical Industries Limited|Fungicidally effective imidazoles and use thereof against fungal pests|DE3032326A1|1980-08-27|1982-04-08|Bayer Ag, 5090 Leverkusen|AZOLYLALKYL DERIVATIVES, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE AS FUNGICIDES|
    DE3041702A1|1980-11-05|1982-06-09|Basf Ag, 6700 Ludwigshafen|METHOD FOR CONTROLLING UNWANTED PLANT GROWTH WITH 2-ARYLOXY-2-AZOLYL ALKANICARBONIC ACID AMIDES, HERBICIDES CONTAINING THEM, AND METHOD FOR THE PRODUCTION THEREOF|
    US4515623A|1981-10-09|1985-05-07|Basf Aktiengesellschaft|Control of unwanted plant growth with 2-aryloxy-2-azolylalkanecarboxamides|
    EP0084236A3|1981-12-22|1983-08-03|Fbc Limited|Fungicidal heterocyclic compounds and compositions containing them|
    GB8330715D0|1983-11-17|1983-12-29|Ici Plc|Extraction of metal values|
    US5254695A|1983-11-17|1993-10-19|Imperial Chemical Industries Plc|Substituted triazoles|
    US5484802A|1995-03-29|1996-01-16|Patel; Bomi P.|Fungicidal α-acetanilide compounds|
    WO2005100325A1|2004-04-14|2005-10-27|Astrazeneca Ab|Aryl glycinamide derivatives and their use as nk1 antagonists and serotonin reuptake inhibithors|
    WO2013135674A1|2012-03-12|2013-09-19|Syngenta Participations Ag|Insecticidal 2-aryl-acetamide compounds|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    DE19782845293|DE2845293A1|1978-10-18|1978-10-18|ALPHA -AZOLYL- ALPHA -PHENYLESSIGAIC DERIVATIVES|
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