Plant growth controller
专利摘要:
A PLANT GROWTH REGULATOR containing an active substance based on alkylammonium salts, a surfactant and a carrier, which also, in order to reduce the growth of plants, contains an alkyl: ammonium compound as a salt formulas x- (H2- (dHi) -dHz-B®2 i; if) where R is chlorine, bromine, methyl, methoxy, is trifluoromethyl, nitro; X - oxygen, sulfur; B - quinuclidine bicyclic, pyrrolizidinovy bicyclic, or group R - NY, where R - Cf-Cj alkyl, prpryl, unsubstituted or substituted by chlorine or methyl, propinyl, gschetonil, metoksidtil or benzyl, Y - group (CHzU, (CH) , (C) t or 7cH5t) i-0 (SNd) a, and the group TCH) j may be replaced by hydroxyl; Z is chloride, bromide or p-toluene. Sulfs "at; n - 2; 3-, m - O; 1, as yo-surfactant - sodium salt of dasisobuGO tilnaphthalene-a-sulfonic acid and sodium salt of ligninsulfonic acid, and c as a carrier - silica gel in the following ratio of xlonents, wt.% G. Compound of general formula (I) Sodium salt of diisobutylnaphthalene-ag-sulphonic acid Sodium salt ligning sulfoxpots Snlicagel. 公开号:SU1009268A3 申请号:SU802897805 申请日:1980-03-26 公开日:1983-03-30 发明作者:Заутер Губерт;Цее Бернд;Бушманн Эрнст;Юнг Иоганн 申请人:Басф Аг (Фирма); IPC主号:
专利说明:
The invention relates to chemical means of acting on plants, in particular to a plant growth regulator. A known plant growth regulator containing an active substance based on alkylammonium salts, for example chloride-2-chloroethyl-trimethylammonium, and additives from solid and liquid carriers .1. The disadvantage of the regulator is that its growth regulating activity is not satisfactory. A plant growth regulator containing an active substance based on alkylammonium salts, a surfactant and a carrier is also known. The active substance is represented by quaternary phenoxyalkylammonium salts 2. The known plant growth regulator is characterized by a lack of activity towards reducing plant growth. The purpose of the invention is to reduce the growth of plants. The goal is achieved by the fact that a plant growth regulator containing an active substance based on alkylammonium salts, a surfactant and a carrier, as an alkylamine salt contains a compound of the general formula (JS x-cJHz - () - (iHz-B®z ® where R is chlorine, bromine, methyl, methoxy, trifluoromethyl, nitro, X is oxygen, sulfur, B is a quinuclidine bicyclic, pyrrole 3, go to a new bicycle or group R -NY, where R is alkyl, propenyl, unsubstituted or substituted by chlorine or methyl , propinyl, acetonyl, methoxyethyl or benzyl; Y is the group (CH2.) 4, (CH2.) 5, (CH-j.) - or (CH) j-O- (CH), The group (CH / j) may be substituted by hydroxyl; Z is chloride, bromide or p-toluene sulfonate; n - 2; h; m - Oj 1, as the surfactant is the sodium salt of diisobutylnaphthyshin-a-sulfonic acid and sodium salt of ligninsulphonic acid and silica gel as a carrier in the following ratio of components, wt.%: Compound of general formula (I) Sodium salt of diisobutylnaphthalene-a-sulphonic acid Sodium salt of lignin sulphonic acid Silica gel Compounds of general formula (I) are presented in Table. 1, Experiencing plant growth regulators which, as an active substance, contain known compounds A or B ciHj A dHj-y ciHa-ciHi-ei cii (iKj (CCC commercial product) (quaternary phenoxyalkyl ammonium salt) or suggested compounds 1-44, summarized in Table 1. Example 1 (greenhouse experiments. Experimental plants are grown in plastic pots 12.5 cm in diameter on a peat culture substrate with a sufficient nutrient content. After the emergence, the plants are treated with an aqueous preparation of a regulator consisting of 20 weight . h. (20 wt.%) active in substances, 3 parts by weight (3% by weight) of the surfactant are sodium salt of diisobutylnaphthalene-a-sulfonic acid, 17 parts by weight (17% by weight) of the surfactant are sodium salt of ligninsulfonic acid and 60 parts by weight (60 wt.%) Of the carrier is powdered silica gel. The regulator is sprayed onto the plants with the help of nozzles. The growth regulating activity is determined by measuring the height of the plants after the experiment and comparing the obtained data with the results of measuring the height of untreated plants. The active substances of the regulator, their number, plants and the results of the experiments are given in Table. 2-5. Example 2 (vegetative experience). In the growing season, soybean varieties SRF are grown in neutral clay-sandy soil with a sufficient nutrient content in the climate chamber under optimal conditions. Treatment with an aqueous formulation of a regulator consisting of 20 weight parts (20 weight%) of the active substance, 3 weight parts. (3 wt.%) On the top of the active substance, sodium diisobutylnaphthalene-a-sulfonic acid, 17 re.h. (17 wt.%) Surfactant - sodium salt of ligninsulfonate and 60 wt.h. (60 wt.%) Of the carrier - powdered silicon to agel, lead after Active The structure of the active substance substance dl 5i vge shoots. The test was carried out for 69 days. The growth regulating activity is then determined by measuring the height of the plants and comparing the beam data with the results of measuring the height of the untreated plants. The active substances of the regulator, their number and the results of the experiment are shown in Table. 6 Table 1 I T. Go1., ( Bj 104-108 140-143 Os - (88-89 0 198-200 Br cii® 145-148 TTf HI PJ fi. ™ Tstoxx di B / 178-180 e Br 141-144 0 cii 75-77 Continued table. one about---- -/ i3r, x..ii ® / x ; ... .:.. about - H -io -xxfW 125 i -v -; :: s FROM% X 1N3 (1HF: H - hmm BG 131-134 Yg 188-189 V Vg 91-93 YNZ ® Br187-188 at Bg 122-127 OBG 146-1 & - x- HsdO 28 di x / O1 di 34 35 36 37 di Br 6l TgToIX) 38 ®r Bg 173-177 Br 115-117 4, x Br142-143 © Br120-125 df 126-130 di 85-89 W166-168 eleven 39 ; ( 1009268 Continuation of the table. one Ze 160-164 40 3 180-184 (1 Y / V ®1 (Jl And Yj Sv-dl PF a-iSl o-iBj x - ;: s. F. II Effect on the growth of dicotyledons (v. Varieties SRF 400; duration of the experiment 31 days.) 159-160, Bit vg 1180-184 Vg 90-95 Table 2 90-92 1009268, 14 13 Effect on the growth of dicotyledons (from variety SRF 4007 duration of the experiment 31 days) e processed 1.5 A 6.0 1.5 6.0 1.5 6.0 1.5 6.0 1.5 6.0 1.5 6.0 Continued table. 2 T a b l and c a 3 100 92.5 83.0 94.3 92.5 84.9 73.6 43.4 37.7 83.0 71.7 47.7 41.5 151Q09268W | Prodopheni & table. 3 17. 1009268, 18 Continued table. 3 The effect on the growth of dicots (summer rape of goat variety, experience 25 days) The effect on the growth of dicotyledons (sunflowers) duration of the experiment 21 days-). Table 4 I Table 5 Vegetation experience in the climate chamber (from the SRF 400 variety, experiment duration 69 days) Continued tabl; five Fabliceb
权利要求:
Claims (2) [1] (541 PLANT GROWTH REGULATOR, containing an active substance based on alkyl ammonium salts, a surfactant and a carrier, in that, in order to reduce the growth of plants, it contains an alkyl ammonium salt as a compound of general formula [CH, - (ene) m - dH, -v® e f g wherein R - chloro, bromo ,, methyl, methoxy, trifluoromethyl, nitro; X is oxygen, sulfur; ( B - quinuclidine bicycle, pyrrolisidine bicycle ^ or group R -'-NY, where - C, - (> alkyl, propenyl, unsubstituted or substituted with chloro or methyl, propynyl, acetonyl, methoxyethyl or 'benzyl, Y - group (CHe ^ ,. (CH 4 ) $, (CH ^) or (CH%) ^ - 0 (CH ^) a , and the group (CH 4 ) MAY be replaced by hydroxyl; [2] 2 - chloride, bromide or η-toluene. sulfonate; n '- 2, 3, m - o; ι, as the surface-active substance — diisobutylnaphthalene-a-sulfonic acid sodium salt and lignin sulfonic acid sodium salt, and silica gel as the carrier in the following ratio of components, wt.%: Compound common Formulas (I) 20 Sodium salt of daisobutylnaphthalene-a-sulfonic acid3 Sodium salt lignin sulfonic acid 17 " Silica gel .60
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同族专利:
公开号 | 公开日 DE2913523A1|1980-10-23| EP0017209A1|1980-10-15| DE3061398D1|1983-01-27| JPS55133358A|1980-10-17| AT2080T|1983-01-15| HU182685B|1984-02-28| JPS64947B2|1989-01-10| CA1144922A|1983-04-19| EP0017209B1|1982-12-22| US4350518A|1982-09-21| BR8001986A|1980-11-25|
引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题 US3255196A|1966-06-07|Phenoxyalkyl piperidine derivatives | FR558M|1959-03-13|1961-05-29| GB952736A|1959-06-16|1964-03-18|Wellcome Found|Quaternary ammonium compounds and their preparation| GB982572A|1960-06-10|1965-02-10|Wellcome Found|Improvements in and relating to quaternary ammonium compounds and the preparation thereof| US3142554A|1961-10-10|1964-07-28|Monsanto Co|Controlling vegetation with aryl thioalkylamines| US3275629A|1963-03-20|1966-09-27|Monsanto Co|Substituted aryloxyalkylene amines| CH502760A|1967-01-04|1971-02-15|Basf Ag|Preparations for the inhibition of plant growth and for changing the plant habit| CH518059A|1969-04-22|1972-01-31|Ciba Geigy Ag|Plant growth regulating agent| US3564046A|1969-05-16|1971-02-16|Amchem Prod|Quaternary ammonium derivatives of limonene| US3850611A|1970-03-25|1974-11-26|Fujisawa Pharmaceutical Co|Method for inhibiting plant growth with quaternary ammonium salts| BE795155A|1972-02-10|1973-08-08|Cassella Farbwerke Mainkur Ag|QUATERNARY AMMONIUM COMPOUNDS FOR USE AS ADDITIVES IN DYEING|DE3103069A1|1981-01-30|1982-08-26|Basf Ag, 6700 Ludwigshafen|DIBENZOFURANE DERIVATIVES, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE AS FUNGICIDES| DE3230087A1|1982-08-13|1984-02-16|Basf Ag, 6700 Ludwigshafen|CYCLOHEXAN-1,3-DION DERIVATIVES, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE FOR CONTROLLING UNWANTED PLANT GROWTH| JPS59106460A|1982-12-10|1984-06-20|Fujisawa Pharmaceut Co Ltd|N-containing heterocyclic compound derivative| AU5940186A|1985-07-05|1987-01-08|Institut Fur Pflanzenschutzforschung|2, 6 - dimethyl - morpholine quartenary compounds| JPS6225259A|1985-07-26|1987-02-03|Mitsubishi Electric Corp|Electromagnetic ultrasonic tranceducer| US5385912A|1991-03-08|1995-01-31|Rhone-Poulenc Rorer Pharmaceuticals Inc.|Multicyclic tertiary amine polyaromatic squalene synthase inhibitors|
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申请号 | 申请日 | 专利标题 DE19792913523|DE2913523A1|1979-04-04|1979-04-04|SUBSTITUTED ALKYLAMONIUM SALTS, THEIR PRODUCTION AND USE FOR REGULATING PLANT GROWTH| 相关专利
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