Work recovery from process involving steam generation

专利摘要:
A method of treating a process comprising the generation of steam (24; 58; 104; 170; 198; 222; 259), wherein a high temperature process stream (16; "A"; 92; 152; 184; 204; 246) is generated. The way is to be presented. The hot process streams 16; " A "92;152;152;184;204; 246 can be generated in any manner and are burner sections of the steam methane reformer 2, integrated and combined cycle 3 of the gas turbine Compressing air in the combustion chamber, oxygen transfer membrane system 180, and gas turbine 202 or cryogenic air separation units 228; 240 used to preheat the incoming air and oxygen to the furnace 140. It may include a natural gas engine provided to.
公开号:KR20030090795A
申请号:KR10-2003-7014256
申请日:2002-04-08
公开日:2003-11-28
发明作者:아룬 아카리아；크리스찬 프리드리히 고츠맨；베이램 아르만；단테 패트릭 보나퀴스트；존 에이치. 로얄
申请人:프랙스에어 테크놀로지, 인코포레이티드；
IPC主号:

专利说明:

WORK RECOVERY FROM PROCESS INVOLVING STEAM GENERATION}
[2] There are a variety of industrial processes in which the hot process streams used to generate steam are generated. As will be described, steam can be used to generate additional energy that can be converted into electricity to be useful for the process or reintroduced into the power grid. Moreover, steam can itself constitute the necessary components of the process.
[3] For example, heat recovery steam generators, also known as waste heat boilers, recover energy from process streams produced by processes such as incineration systems, waste heat generation systems, and chemical process plants. Incineration systems typically operate at high temperatures between 1,650 and 2,400 ° F. In such a system, waste heat recovery from a process stream formed of hot exhaust gas may in turn be applied to generate a stream, which may be used to generate electricity. The thermal energy contained in the process stream formed from the gas turbine discharge in the waste heat generating plant can also be recovered in the form of steam and electricity. In chemical process plants, steam generators can be used to recover energy or can be used on their own in the process being treated.
[4] Specific embodiments of chemical processes involving steam generators can be found in steam-reforming operations where product streams from reformers and shift converters are frozen. The mixture of feed gas and steam is fed to the reaction furnace or reformer heated by the exhaust gas. The product stream is sent to the reactor where the exothermic shift conversion reaction takes place. The product stream from the shift transformation also needs to be frozen. As can be appreciated, during the freezing step, steam can be generated to recover energy and act as a reactant.
[5] The foregoing includes only a few examples of many processes that can generate a high temperature process stream where energy can be recovered by a steam generator. In any process where energy can be recovered at high temperatures through steam generation, thermodynamic inefficiencies can arise from heat discharge from the freezing end of the steam generator of actual size and cost.
[6] As will be described, the present invention includes the integration of a process in which steam is generated into a thermoacoustic engine. Processes may be of the type described below. In this regard, the operation of thermoacoustic organs is physics today, Gregory W. Fully described by Gregory W. Swift in "Thermoacoustic Engines and Refrigerators" (July 1995) pages 22-27. In brief, thermoacoustic engines are known devices that employ resonators that include hot and cold end heat exchangers thermally connected by a stack of parallel plates to convert thermal energy into acoustic energy. Work of acoustic energy can be converted to work, electricity or refrigeration. Examples of devices in which thermoacoustic work are converted to electricity can be found in US Pat. Nos. 5,996,345 and 4,559,551. An example of a device in which thermoacoustic work is used to generate refrigeration is shown in US Pat. No. 4,953,366, where a thermoacoustic engine is used in combination with an orifice pulse tube freezer. In the field of natural gas for liquefying natural gas, it is at least proposed to use a combination of an orifice pulse tube freezer and a thermoacoustic engine, known as TADOPTR. In this field, a portion of the liquefied natural gas is in turn combusted to power the TADOPTR which is used to liquefy the rest of the natural gas.
[7] In the present invention, a portion of the energy is usefully recovered from the high temperature process stream in the thermoacoustic engine prior to the generation of steam through indirect heat exchange with the intermediate temperature process stream at low temperatures. As a result, the overall thermodynamic efficiency of the overall process and thus the amount of energy that can be recovered is increased.
[1] The present invention relates to a process for treating a process comprising the generation of steam, from which the steam is generated from a high temperature process stream passing through the steam generator. More specifically, the present invention allows the hot process stream to enter a thermoacoustic engine to recover work before the hot process stream enters the steam generator.
[18] 1 is a schematic diagram of the invention generally applied to a high temperature process system for carrying out a method according to the invention,
[19] 2 is a schematic diagram of a steam methane reforming system incorporating the method of the present invention,
[20] 3 is a schematic diagram of an integrated vaporization bond cycle incorporating the method of the present invention,
[21] 4 is a glass furnace in combination with the method according to the invention,
[22] 5 is a schematic representation of an oxygen transport membrane system in combination with the method according to the invention,
[23] 6 is a schematic diagram of a system combining a gas turbine and a gas separation unit combined with a method according to the invention,
[24] 7 is a system using a natural gas engine and an air separation unit incorporating the method according to the invention.
[8] The present invention relates to a method for treating a process involving the generation of steam. According to the invention, a high temperature process stream is generated. Heat is transferred from the hot process stream to the thermoacoustic engine to recover energy from the hot process stream as a thermoacoustic work and generate an intermediate temperature process stream. The intermediate temperature process stream enters the steam generator to generate steam.
[9] Considering the carono cycle efficiency alone, as can be seen, to recover the largest possible energy from the hot process stream through steam generation, as can be seen, if it is quite large, but not expensive, heat from the process at the lowest possible temperature, normal ambient temperature In order to discharge the heat, a heat exchanger is required. By first recovering the energy in the thermoacoustic engine and then through the steam generator, a more ideal efficiency is approached, which is two stages: high temperature in the thermoacoustic engine and then low temperature in the steam generator, the low temperature intermediate process stream This is because energy is recovered through heat exchange with. After heat exchange in the steam generator, the intermediate process stream may be discharged to a temperature that is actually lower than the temperature at which it would be possible to obtain a high temperature process stream entering the steam generator directly. In contrast, while thermoacoustic engines require high temperatures for operation, synergism occurs because the steam generator can function properly at low temperatures.
[10] Hot process streams may be generated by combustion of fuel in the presence of oxidants. As described below, carbon dioxide can be usefully recovered as a result. For various applications of the present invention, usefully, acoustic work produced in thermoacoustic engines can drive an acoustic refrigerator.
[11] The above useful applications can be used in industrial processes such as steam methane reforming. For example, the steam can be combined with feed containing methane which is steam methane reformed to produce a hydrogen containing gas. Hydrogen can be separated from the hydrogen containing gas to produce a hydrogen product stream and fuel. As described below, the hydrogen product stream may be liquefied in an acoustic refrigerator driven by a thermoacoustic engine.
[12] Another potential application is in coal gasification. In such applications, additional energy may be recovered from the high temperature process stream in the turbine prior to heat transfer with the thermoacoustic engine. The steam then enters a coal gasifier to generate a portion of the fuel for the production of hot process streams. As discussed below, the additional work is to power the air compressor to produce a compressed air stream that can use at least a portion from the oxidant. Preferably the coal vaporizer produces an untreated fuel stream and an additional compressed air stream is combined with the compressed air stream to form an oxidant. The untreated fuel stream can be introduced into the further thermoacoustic engines in order to produce thermoacoustic work and into the exhaust gas refrigeration unit, purge unit to produce fuel. Other thermoacoustic work may be extracted from thermoacoustic organs.
[13] Heat may be transferred from the hot process stream to the thermoacoustic engine by the heated hot transfer fluid through indirect heat exchange with the hot process stream produced as exhaust gas in the furnace. The furnace can be a furnace and steam can be used to drive the steam turbine to create shaft work. Shafts can be applied to two air compressors to compress the air. One of the two air compressors is coupled to a vacuum pressure swing adsorption unit to produce an oxygen stream. Compressed air streams and oxygen streams can enter the furnace to help burn the coke to produce a reduced gas.
[14] In another application, the oxygen containing gas can pass through an oxygen transfer membrane reactor to produce a heated retentate stream and an oxygen product stream. The hot process stream then forms at least a portion from the heated retentate stream. As described below, the oxygen product stream may be liquefied in an acoustic refrigerator driven by a thermoacoustic engine.
[15] Another application includes cryogenic air separation. Hot process streams can be produced from the discharge of gas turbines. The shaft work produced by the gas turbine can be applied to the compressor to compress the air in the cryogenic air separation unit. The cryogenic air separation unit produces one or more product streams consisting predominantly of nitrogen or oxygen and the one or more product streams can be liquefied in an acoustic refrigerator driven by a thermoacoustic engine. In such applications, the steam is usefully introduced into the steam turbine to create additional shaft work. Then additional shafting can be applied to further compress the air.
[16] In another application of the invention, the fuel and the oxidant are combusted in a natural gas engine producing a shaft work. A portion of the shaft work is used to drive the air compressor to compress the air in the cryogenic air separation unit. Cryogenic air separation units produce product streams rich in either oxygen or nitrogen. This product stream enters the vapor compression freezer driven by an additional part of the shaft work and then into the acoustic freezer driven by the acoustic work produced in the thermoacoustic engine.
[17] While the specification includes claims that distinctly designate key elements of the application to the invention, the invention may be more readily understood in connection with the accompanying drawings.
[25] Referring to FIG. 1, an apparatus 1 is shown. Apparatus 1 represents a process involving the generation of steam as a whole. Such a process includes a process system 10 operating at high temperature through the combustion of fuel present in the oxygen containing gas entering the process system 10 via the fuel and air streams 12 and 14 respectively. Depending on the process, another feed stream 13 may be required.
[26] Process system 10 generates hot process stream 16. The high temperature process stream 16 may be a waste stream, a product stream or perhaps an intermediate product stream. Another example of a process system 10 will be described with reference to the following figures included herein.
[27] The calorific value of the high temperature process 16 is recovered to a steam generator 18 that generates steam that can be used for various purposes. The high temperature process stream 16 is at a temperature of 600 to 1000 ° C. and in practice it is impossible to efficiently recover the thermal energy of the high temperature process stream 16 alone in the steam generator 18. In accordance with the present invention, in order to recover useful work from the hot process stream 16, the hot process stream 16 may first recover the energy of the hot process stream 16 at a high temperature, as described above and in accordance with the electrical work and As the sound work that can be applied to the generation of refrigeration as it flows into the thermoacoustic engine (20).
[28] As will be described later, the thermoacoustic engine 20 is a device consisting of a resonator tube comprising hot and cold end heat exchangers connected by a stack of parallel plates. A gas, typically helium, is located in the resonator tube. When a sufficiently large temperature difference is maintained by the hot and cold end heat exchangers, the gas in the stack operates because the gas in the stack expands at high pressure and thermally contracts at low pressure. Work produced by such expansion and contraction can be used for a variety of purposes. However, the invention is not to be considered as limiting as used in the description and claims, and "thermoacoustic engine" means any device specifically designed to convert thermal energy into acoustic energy. In this regard, the present invention has the same applicability as known toroidal devices such as thermoacoustic stirling heat engines or Buillerumier engines.
[29] As described below, one object is to drive an acoustic chiller, such as a pulsed tube chiller. In a pulse tube freezer, the pulse tube is in communication with the resonator tube through a regenerator material such as a steel microsphere or screen. The aftercooler in heat communication with one end of the regenerator material removes compressed heat. The working fluid in the pulse tube is frozen in the regenerator and then expanded in the pulse tube to produce refrigeration in the cold end heat exchanger to release heat from the warm end heat exchanger. The reservoir, in communication with the pulse tube by the orifice, improves performance by adjusting the flow and pressure changes of the pulse. The thermoacoustic engine described above has applicability to other known acoustic refrigerators such as acoustic sterling hybrid refrigerators.
[30] Recovery of energy from the hot process stream 16 in the thermoacoustic engine 20 produces an intermediate temperature process stream 22 which is fed to the steam generator 18 to generate a stream 24 of steam. In this regard, the water stream 26 is divided into auxiliary water streams 28 and 30. Auxiliary water stream 30 enters steam generator 18 to produce stream 24. Stream 24 produces a shaft work that can be applied to various devices, such as compressors and generators, that can enter steam turbine 32. Depending on the temperature and pressure, turbine discharge stream 34 may be further used in a two stage steam turbine or other process. The same is true for the cold intermediate process stream 36 exiting the steam generator 18.
[31] Where the high temperature process stream 16 is produced by fuel combustion of the oxidant, carbon dioxide is produced. Carbon dioxide can be recovered from the low temperature medium temperature process by various known processes. The advantage is that carbon dioxide can be sequestered to prevent the formation of greenhouse gases and later sold or used for other industrial processes. Preferably, the water stream is heated during the recovery of the working fluid in the thermoacoustic engine, carbon dioxide and in the low temperature medium temperature process stream 36 in the steam generator 18 and in direct heat exchange as described above. Work may also be recovered by introducing steam into the steam turbine. The recovered stream of carbon dioxide can be liquefied in an acoustic refrigerator driven by a thermoacoustic engine.
[32] Referring to FIG. 2, an apparatus 2 is shown that is designed to produce gaseous hydrogen products through steam methane reforming. According to the apparatus 2, a high temperature process stream is produced in the form of exhaust gas indicated by the arrow "A". The process system of the apparatus 2 is a furnace 40 into which air and fuel streams 42 and 44 respectively enter. Methane containing preheat feed stream 46 and steam containing stream 48 enter the known steam methane reformer 40. In the presence of a catalyst not shown, the mixture of fuel (methane) and steam produces an intermediate product stream 50 containing hydrogen, carbon monoxide, carbon dioxide and unreacted methane.
[33] As a result, the exhaust gas stream "A" indirectly heat exchanges with the hot end heat exchanger of thermoacoustic engine 52 to produce an intermediate temperature exhaust gas stream, denoted "B". Water enters the cold end heat exchanger located in thermoacoustic engine 52 as water stream 54. Additional water stream 58 may be combined with water stream 54 to generate steam in heat exchanger 56 located in the stack of steam methane reformer 40. The stack gas is discharged as a stream indicated by arrow "C". The combined streams 54, 58 may be combined with additional stream 60 (or steam) generated in the steam generator 62 which, after vaporized with steam, serves to recover heat in the intermediate product stream 50. have. The heat exchanger 63 contained in the steam methane reformer 40 superheats the combined stream. Stream 64 may be divided into an exhaust stream 66 which may be used for additional processes and stream 48.
[34] The intermediate product stream 50 enters a known PSA separation unit 68 as described in US Pat. No. 6,007,606 to obtain a gaseous hydrogen and fuel stream 44 which can be obtained as a gaseous hydrogen product stream 70. And a portion of product stream 72 that is liquefied in an acoustic freezer, such as pulsed tube freezer 74, to produce liquid product stream 76. The orifice pulse tube freezer 74 is connected to a thermoacoustic engine 52 and driven by a high temperature extraction from the exhaust gas.
[35] Referring to FIG. 3, there is shown an integrated vaporization apparatus 3 incorporating a cycle designed to generate electricity through vaporization of coal. In the apparatus 3, the process system consists of a combustion chamber 80 coupled to a gas turbine generator 81. Each of the fuel and air streams 82 and 84 enters the combustion chamber 80. The fuel is combusted to produce a hot exhaust gas stream 85 that enters the turbine 86 of the gas turbine generator 81. A portion of the shaft work of the turbine 86 is delivered to an air compressor 88 which produces a compressor air stream 90 which partially forms an air stream 84 to assist combustion in the combustion chamber 80. Other work is recovered from turbine 86 as electricity.
[36] The discharge of the turbine 86 forms a high temperature process stream 92 which enters the thermoacoustic engine 94 to generate an intermediate temperature process stream 96 which is fed to the steam generator 98. The incoming water stream 100 is divided into auxiliary water streams 102 and 103. Auxiliary water stream 102 removes heat from the cold end heat exchanger of thermoacoustic engine 94. Auxiliary water stream 103 enters steam generator 98 to produce stream 104 of steam. Stream 104 may enter steam turbine generator 105 to generate additional electricity. The discharge of the steam turbine generator 105 as stream 106 enters the known coal gasifier-desulfurizer system 108 along the compressed air stream 110 where a portion is formed from the compressed air stream 90. Coal and limestone 112 are also fed to the coal vaporizer-desulfurizer system 108.
[37] The vaporizer-desulfurizer system 108 produces an untreated fuel stream 114 that can act as a hot process stream to the additional thermoacoustic engine 116 to produce thermoacoustic work. As a result, an intermediate temperature process stream 118 is produced, which is frozen in the freezer 120 after generating steam from the incoming water streams 122 and 124. As a result, the frozen stream 126 then enters a known washing unit 128 to produce a purified exhaust stream 130 which is combusted in the combustion chamber 80 of the gas turbine. It can be combined with natural gas stream 132 to produce a fuel stream 82.
[38] Referring to FIG. 4, there is shown an apparatus 4 utilizing the present invention in connection with a furnace 140. According to an application of the invention, the furnace discharges iron, coke and limestone. The heated air and oxygen streams 141 and 142 enter the base of the furnace to combust the coke and produce a reducing gas containing carbon monoxide, hydrogen and carbon dioxide. When the reducing gas is raised in the furnace 140, the iron oxide is reduced to iron and the remaining gas at the top of the furnace exothermic to melt the iron supplied to the top of the furnace 140. As a result, a significant amount of combustible hydrogen containing exhaust gas and carbon monoxide are discharged from the top of the furnace 140 as gas stream 144. Molten iron and slag are extracted from the bottom of the furnace 140.
[39] After separation of the dust in the separation unit 146, the exhaust gas stream 148 combusted in the combustion chamber 150 to heat the incoming air and oxygen streams 141 and 142, respectively, and produce a high temperature process stream 152. ) Is generated.
[40] Heat is transferred from the high temperature process stream 152 to the thermoacoustic engine 154 by a heat transfer loop having a heat exchanger 156 and a pump 158 through the hot end heat exchanger of the thermoacoustic engine 154, helium Or a heat transfer fluid consisting of other gases / liquids. Instead of a heat transfer loop, heat pipes can be used to transfer heat to the thermoacoustic engine. Water stream 160 enters the refrigeration end heat exchanger of thermoacoustic engine 154 to provide the necessary refrigeration of the laminate contained therebetween. Thermoacoustic work is generally indicated by arrow 164 and extracted to apply to the generation of electricity, refrigeration, or other necessary processes.
[41] As a result, the intermediate temperature process stream 166 then enters the steam generator 168 and is heated to generate steam from a water stream 170 consisting of water vapor 160. As a result, steam enters the steam turbine 172. Steam turbine 172 generates shaft work that is applied to a compressor having stages 174 and 176. Stage 176 is indicated at 178 to produce an oxygen stream 142 and compresses air for use in any of a number of published vacuum pressure swing absorption processes. Stage 174 compresses the air to produce a compressed air stream 141.
[42] Referring to FIG. 5, an apparatus 5 is shown illustrating the application of the present invention to an oxygen generator 5 coupled with an oxygen transfer membrane system 180. Oxygen transport membrane system 180 is one that functions to allow the transport of oxygen ions produced by oxygen in the oxygen-containing gas introduced at high temperature to the cathode side of one or more oxygen transport membranes of oxygen transport membrane system 180. It has the above ceramic film. Depending on the type of membrane, oxygen ions through pressure differentials or currents are transferred to the anode side of the membrane.
[43] In oxygen transfer membrane system 180, the pressure differential is used to effect the transfer of oxygen ions, and thus, compressed air stream 182 enters oxygen transfer membrane system 180. It is heated by methane which burns in the presence of the desired oxygen contained in the compressed air stream 182. Oxygen is separated from the air to produce a high temperature process stream 184 consisting of the remaining components of the compressed air stream 182 after separation of the oxygen. Oxygen product stream 186 is extracted from oxygen delivery membrane system 180. Hot process stream 184 enters thermoacoustic engine 188 along water stream 190. The hot process stream 184 is frozen to produce an intermediate process stream 189 that enters the steam generator 188. Water contained in stream 190 and water stream 196 enters steam generator 197 to produce steam containing stream 198. The work of thermoacoustic engine 188 is applied to an acoustic chiller, such as pulsed tube chiller 199, used to liquefy oxygen product stream 186. Water stream 200 enters the low temperature heat exchanger in contact with the regenerator material contained in orifice pulse tube freezer 199.
[44] 6 shows one application of the invention to an air separation unit. In accordance with this embodiment of the present invention, gas turbine 202 produces hot process stream 204 as exhaust. The gas turbine unit 202 is provided with an air compressor 205 and a combustor 206 to burn fuel in the presence of oxygen contained in the air to heat the air and introduce this air into the turbine 208. Hot process stream 204 enters thermoacoustic engine 210 to produce intermediate process stream 212. The water stream 214 enters the thermoacoustic engine 210 for use in the cold heat exchanger and then combines with the water stream 218. Streams 214 and 218 produce a combined stream that enters steam generator 220 after combustion and raises steam as stream 222 that can enter steam turbine 224. The shaft work of the steam turbine 224 can be used for electricity generation or other purposes.
[45] The air compressor 226 is coupled to the gas turbine 202 to compress air and introduce compressed air into the air separation unit 228. Although not shown, air separation unit 228 has one or more distillation columns that function to separate nitrogen and oxygen to produce one or more product streams that may be rich in nitrogen or oxygen. This product stream, indicated by reference numeral 229, causes the liquefied pulse tube freezer 231 to flow into the same acoustic freezer to produce a liquid product stream 232. One output of thermoacoustic engine 220 drives pulsed tube chiller 230 that includes a cold end heat exchanger frozen by stream 234.
[46] FIG. 7 shows an application of the invention to an apparatus 7 using an air separation unit 240 having a compressor 242 powered by a natural gas engine 244. Natural gas engine 244 produces an exhaust that functions as hot process stream 246 that enters thermoacoustic engine 248 that burns fuel in the presence of oxygen or oxygen-rich air to produce an intermediate temperature process stream. The intermediate temperature process stream 250 heats the water in the steam generator 252 to raise the steam. Thermoacoustic engine 248 is frozen by the incoming water as stream 254 combined with stream 258. As a result, the combined stream 259 enters the steam generator 252.
[47] As described above, the natural gas engine 244 powers the compressor 242, which compresses the air to be separated from the air separation unit 240. The air separation unit 240 produces a stream 260 which is also rich in nitrogen or oxygen enters the vapor compression freezer 261 which is also powered by the natural gas engine 244. As shown, any axis can be used for other purposes. As a result, product stream 262 enters orifice pulse tube freezer 264, which is then powered by thermoacoustic engine 248 to liquefy product stream 262. The water stream 266 enters the aftercooler of the pulse tube freezer 264.
[48] While the invention has been described with reference to the preferred embodiments, those skilled in the art may make various changes, additions, and omissions without departing from the spirit and scope of the invention.

权利要求:
Claims (11)
[1" claim-type="Currently amended] A method of treating a process involving the generation of steam,
Generating a high temperature process stream 16 (" A ";92;152;184;204; 246),
As a thermoacoustic one, energy is recovered from the hot process stream 16 (" A ";92;152;184;204; 246) and the intermediate temperature process streams 22; " B ";96;166; Transferring heat from the hot process stream 16 (“A”; 92; 152; 184; 204; 246) to a thermoacoustic engine (20; 52; 94; 154; 188; 210; 248) , And
Introducing said intermediate temperature process stream into a stream generator (18; 63; 56; 98; 168; 188; 220; 252) to generate steam (24; 58; 104; 170; 198; 222; 259). And a process comprising the generation of steam.
[2" claim-type="Currently amended] The method of claim 1,
Steam generated by burning the fuel 12; 44; 82; 148 in the presence of the oxidant 14; 42; 84; and the hot process stream 16; "A"; 92; 152; 184; 204; 246 How to handle a process involving the occurrence of.
[3" claim-type="Currently amended] The method of claim 1,
And further work is recovered by introducing the steam (104) into the steam turbine (105).
[4" claim-type="Currently amended] The method of claim 2,
The vapor 58 is combined with a methane containing feed 46 which is steam methane reformed to produce a hydrogen containing gas 50,
Wherein the hydrogen is separated from the oxygen containing gas (50) to produce a hydrogen product stream (70, 72) and a portion of the fuel (44).
[5" claim-type="Currently amended] The method of claim 2,
Recovering additional energy from the hot process stream 85 in the turbine 81 before transferring heat from the hot process stream 85 to the thermoacoustic engine 94, and
Introducing the steam (104) into a coal vaporizer (108) such that a portion of the fuel (82) is generated.
[6" claim-type="Currently amended] The method of claim 1,
Steam is transferred from the hot process stream to the thermoacoustic engine 154 by a heat transfer fluid heated through indirect heat exchange with the hot process stream produced as exhaust gas in the furnace 140. How to handle a process that involves an occurrence.
[7" claim-type="Currently amended] The method of claim 7, wherein
The furnace is a furnace 140,
The steam drives steam turbine 172 to produce shaft work,
The shaft work enters two air compressors (174) 176 to compress the air,
One of the two air compressors 176 is coupled to a vacuum pressure swing absorption unit 178 to produce an oxygen stream 142 and the other of the two air compressors 174 is a compressed air stream. (141),
The compressed air stream 141 and the oxygen stream 142 are heated,
The compressed air stream 141 and the oxygen stream 142 are heated and then flowed into the furnace 140 to assist in the combustion of the coke to produce a reducing gas, the process comprising a process comprising the generation of steam. .
[8" claim-type="Currently amended] The method of claim 1,
Oxygen containing gas 182 passes to oxygen transfer membrane reactor 180 to produce heated retentate stream 184 and oxygen product stream 184,
Wherein the hot process stream is formed at least partially from the heated retentate stream (184).
[9" claim-type="Currently amended] The method of claim 1,
The hot process stream 204 is generated from the discharge of the gas turbine 202,
The shaft work produced by the gas turbine 202 is applied to compress the air in the cryogenic air separation unit 228,
The cryogenic air separation unit 228 produces one or more product streams 229 consisting primarily of oxygen or nitrogen,
Wherein the one or more product streams (229) are liquefied in an acoustic refrigerator (231) driven by the thermoacoustic engine (210).
[10" claim-type="Currently amended] The method of claim 2,
The fuel and oxidant are combusted in a natural gas engine 244 where
A portion of the shaft work is used to drive the air compressor 242 to compress the air in the cryogenic air separation unit 240,
The cryogenic air separation unit 240 produces a product stream 260 rich in one of oxygen and nitrogen,
The product stream 260 enters a vapor compression freezer 261 driven by an additional portion of the shaft work and then into an acoustic freezer 264 driven by the acoustic work generated in the thermoacoustic engine 248. A method of treating a process comprising the generation of steam, which is introduced.
[11" claim-type="Currently amended] The method of claim 1,
The acoustic work generated in the thermoacoustic engine (20; 52; 154; 188; 210; 248) drives an acoustic refrigerator (74; 199; 231; 264). .

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同族专利:

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公开号 | 公开日

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CA2446057A1|2002-11-14|

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EP1525374A2|2005-04-27|

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KR100722636B1|2007-05-28|

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CN1518635A|2004-08-04|

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EP1525374A4|2006-05-10|

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US6523348B1|2003-02-25|

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CN1283906C|2006-11-08|

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WO2002090726A3|2005-03-03|

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WO2002090726A2|2002-11-14|

引用文献:

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公开号 | 申请日 | 公开日 | 申请人 | 专利标题

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法律状态:
2001-05-02|Priority to US09/846,361

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2001-05-02|Priority to US09/846,361

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2002-04-08|Application filed by 프랙스에어 테크놀로지, 인코포레이티드

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2002-04-08|Priority to PCT/US2002/010846

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2003-11-28|Publication of KR20030090795A

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2007-05-28|Application granted

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2007-05-28|Publication of KR100722636B1

优先权:

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申请号 | 申请日 | 专利标题

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US09/846,361|2001-05-02|

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US09/846,361|US6523348B1|2001-05-02|2001-05-02|Work recovery from process involving steam generation|

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PCT/US2002/010846|WO2002090726A2|2001-05-02|2002-04-08|Work recovery from process involving steam generation|