Resin composition and sheet for optical screen

专利摘要:
A rubbery copolymer having a styrene monomer and a diene monomer unit, and a copolymer having a styrene monomer unit and a (meth) acrylic acid ester monomer unit, and having a saturation absorption ratio at a temperature of 60 ° C. and a relative humidity of 90% The total light transmittance is 85% or more, the haze value is 5% or less, and the beaker when the sheet has a bending elastic modulus of 1800 MPa or more, a notched eye impact strength of 2 kJ / m 2 or more and a thickness of 2 mm The resin composition which satisfy | fills the conditions whose softening temperature is 90 degreeC or more. This resin composition is excellent in transparency, hardly induces deformation such as deflection and deflection, and can be suitably used as a substrate for a screen sheet that does not easily generate cracks and chips.
公开号:KR20030072602A
申请号:KR10-2003-7009620
申请日:2002-01-21
公开日:2003-09-15
发明作者:아까다가쯔미；오오따까노리히꼬
申请人:스미또모 가가꾸 고오교오 가부시끼가이샤；다이니폰 인사츠 가부시키가이샤；
IPC主号:

专利说明:

Resin composition and sheet for optical screen {RESIN COMPOSITION AND SHEET FOR OPTICAL SCREEN}
[2] An optical screen such as a transmissive screen of a projection television is usually composed of a lens sheet such as a Fresnel lens sheet or a lenticular lens sheet. Moreover, in order to protect this lens sheet in recent years, a front panel may be attached to the surface of this lens sheet.
[3] As a base material of these optical screen sheets, conventional acrylic resins are mainly adopted from the viewpoint of transparency. For example, Japanese Unexamined Patent Application Publication No. Hei 1-28085 proposes a lens sheet obtained by adding a methyl methacrylate-based multilayer rubber to an acrylic resin. In addition, Japanese Patent Laid-Open No. 9-302176 or Japanese Patent Laid-Open No. 9-302177 proposes a lens sheet made of methyl methacrylate-styrene copolymer resin. Japanese Unexamined Patent Application Publication No. 2000-66307 proposes a lens sheet obtained by adding butadiene-based graft rubber to a methyl methacrylate-styrene copolymer resin.
[4] However, the lens sheet proposed in Japanese Unexamined Patent Publication No. Hei 1-128059 and Japanese Unexamined Patent Application Publication No. 2000-66307 has a problem of easily causing deformation such as warp or deflection during use, storage, or transportation. have. In addition, the lens sheet proposed in Japanese Patent Laid-Open No. 9-302176 or Japanese Patent Laid-Open No. 9-302177 has a problem of easily causing cracks and chips during processing or installation.
[1] This invention relates to the resin composition and the sheet | seat for optical screens using this as a base material.
[5] An object of the present invention is to provide a resin material which is excellent in transparency, hardly induces deformation such as deflection and deflection, and which can be suitably used as a base material of a screen sheet that is hard to cause cracks or chips.
[6] That is, this invention consists of a rubber-like copolymer (A) which has a styrene monomer unit and a diene monomer unit, and a copolymer (B) which has a styrene monomer unit and a (meth) acrylic acid ester monomer unit, and the following conditions The resin composition which satisfy | fills (1)-(5) is provided:
[7] (1) Saturation absorption rate is 0.8% or less when the temperature is 60 ℃ and the relative humidity is 90%,
[8] (2) the flexural modulus is 1800 MPa or more,
[9] (3) Notch eye resort impact strength is not less than 2 kJ / ㎡,
[10] (4) When the sheet having a thickness of 2 mm, the total light transmittance is 85% or more, haze value is 5% or less,
[11] (5) Beaker softening temperature is 90 degreeC or more.
[12] Moreover, this invention provides the sheet for optical screens based on the said resin composition which concerns on this invention.
[13] Moreover, this invention provides the method of manufacturing the sheet for optical screens by cut | disconnecting the sheet | seat based on the resin composition which concerns on this invention on both surfaces with the shear blade.
[14] Embodiment of the invention
[15] Hereinafter, the present invention will be described in detail. In addition, in this specification, (meth) acrylic acid ester means ester of acrylic acid and / or ester of methacrylic acid.
[16] The resin composition of this invention consists of a rubbery copolymer (A) which has a styrene monomer unit and a diene monomer unit, and a copolymer (B) which has a styrene monomer unit and a (meth) acrylic acid ester monomer unit, Usually, the particle | grains of this rubbery copolymer (A) are disperse | distributed in the continuous phase of this copolymer (B).
[17] The styrene monomer used as the structural unit of the rubbery copolymer (A) means styrene or a styrene derivative, and examples thereof include styrene and alkyl substituted styrenes (for example, o-methyl styrene, p-methyl styrene, m-methyl styrene, 2). , 4-dimethylstyrene, p-ethylstyrene, pt-butylstyrene, α-methylstyrene, α-methyl-p-methylstyrene, etc.), halogen substituted styrenes (e.g., o-chlorostyrene, p-chlorostyrene, etc.) Can be mentioned. Among them, styrene is preferable. These styrene-based monomers can also use 2 or more types of these as needed.
[18] As an example of the diene type monomer used as a structural unit of a rubbery copolymer (A), butadiene, 2-methyl butadiene, 2, 3- dimethyl butadiene, etc. are mentioned. Especially, butadiene is preferable. These diene monomers can also use these 2 or more types as needed.
[19] In addition, the rubbery copolymer (A) may have monomer units other than a styrene monomer unit and a diene monomer unit as needed. As an example of such arbitrary monomers, (meth) acrylic acid esters (for example, methyl acrylate, ethyl acrylate, butyl acrylate, cyclohexyl acrylate, phenyl acrylate, benzyl acrylate, 2-ethylhexyl acrylate, 2-hydroxyethyl acrylate, methacrylate Methyl acid, ethyl methacrylate, butyl methacrylate, cyclohexyl methacrylate, phenyl methacrylate, benzyl methacrylate, 2-ethylhexyl methacrylate and 2-hydroxyethyl methacrylate); Unsaturated nitriles (such as acrylonitrile, methacrylonitrile, etc.); Unsaturated amides (eg acrylamide, diacetone acrylamide, etc.); Unsaturated acids (such as acrylic acid, methacrylic acid, etc.); Unsaturated imides (such as phenylmaleimide, cyclohexyl maleimide, etc.); Unsaturated acid anhydrides (such as maleic anhydride); and the like.
[20] As a styrene monomer used as a structural unit of a copolymer (B), the thing similar to the styrene monomer which comprises the said rubbery copolymer (A) can be illustrated, Especially, styrene is preferable.
[21] Moreover, the thing similar to the said (meth) acrylic acid ester can also be illustrated also as a (meth) acrylic acid ester monomer which is a structural unit of a copolymer (B), Especially, methyl methacrylate is preferable.
[22] In addition, the copolymer (B) may have monomer units other than a styrene-based monomeric unit and a (meth) acrylic acid ester-type monomeric unit as needed. The above-mentioned unsaturated nitriles, unsaturated amides, unsaturated acids, unsaturated imides, unsaturated acid anhydrides, etc. are mentioned as such arbitrary monomers.
[23] The resin composition of this invention needs to be 0.8% or less of saturation absorption rates at the temperature of 60 degreeC, and 90% of a relative humidity. When the saturation absorption rate exceeds 0.8%, the resulting screen is liable to be greatly bent due to the dimensional change due to absorption, and it is easy to cause deterioration of the image due to the focus shift or the like. This saturation absorption is preferably 0.7% or less.
[24] The resin composition of this invention needs to have bending elastic modulus 1800 Mpa or more. If this bending elastic modulus is less than 1800 Mpa, the screen obtained may be easy to bend, and independence may not be enough. This bending elastic modulus becomes like this. Preferably it is 1900 Mpa or more.
[25] In addition, the resin composition of the present invention needs to have a notch isolation impact strength of 2 kJ / m 2 or more. When the notch eye impact strength is less than 2 kJ / m 2, cracks are likely to occur or chips are generated when processing into a screen or when installing a screen obtained. The notch eye impact strength is preferably at least 2.5 kJ / m 2.
[26] Moreover, when the resin composition of this invention is set as the sheet of thickness 2mm, it is necessary that the total light transmittance of the thickness direction is 85% or more, and the noise value is 5% or less. When this total light transmittance is less than 85%, the luminance of the screen screen obtained may not be enough. On the other hand, when this haze value exceeds 5%, the clear feeling of the screen screen obtained may be impaired.
[27] And as for the resin composition of this invention, it is necessary that beaker softening temperature is 90 degreeC or more. If this beaker softening temperature is less than 90 ° C, the screen is likely to cause thermal deformation when it is brought to a relatively high temperature during storage or transportation of the resulting screen. This beaker softening temperature becomes like this. Preferably it is 95 degreeC or more.
[28] The resin composition of this invention which consists of a rubbery copolymer (A) and a copolymer (B) and has various desired physical properties is a rubbery copolymer (A), a styrene monomer, and a (meth) acrylic acid ester monomer as a raw material. And other monomers, if necessary, by appropriately adjusting the types and amounts of the respective raw materials, the conditions of polymerization, and mixing and polymerizing these monomers. In addition, by this polymerization, a styrene monomer, a (meth) acrylic acid ester monomer, and other monomers used as necessary copolymerize to produce a copolymer (B), and usually to a rubbery copolymer (A) A part of system type monomer, a (meth) acrylic acid ester type monomer, and the other monomer used as needed may be graft copolymerized.
[29] The rubbery copolymer (A) of the raw material preferably has 5 to 50% by weight of styrene monomer units and 50 to 95% by weight of diene monomer units, and more preferably 10 to 45% by weight of styrene monomer units. And 55 to 90% by weight of diene monomer units, particularly preferably 15 to 40% by weight of styrene monomer units and 60 to 85% by weight diene monomer units. Usually, the higher the ratio of the diene monomer unit in the rubbery copolymer (A) is, the higher the notch isolation impact strength of the resin composition can be.
[30] Although the random copolymer may be sufficient as the rubbery copolymer (A) of the said raw material, A random copolymer is preferable from a viewpoint of the balance of the total light transmittance of the resin composition and the color of transmitted light. Moreover, although the rubbery copolymer of the said raw material may be obtained by solution polymerization, for example, or may be obtained by emulsion polymerization, it is preferable that it is obtained by solution polymerization from a viewpoint of lowering the saturated water absorption of a resin composition.
[31] About the ratio of the quantity of each monomer of the said raw material, based on the sum total of all the monomers, ie, the styrene monomer, the (meth) acrylic acid ester monomer, and the other monomer used as needed, Preferably the styrene monomer is 25 ~ 65% by weight, (meth) acrylic acid ester monomers 35 to 75% by weight, other monomers 0 to 40% by weight, more preferably 30 to 60% by weight styrene monomer and (meth) acrylic acid ester monomer Is 40 to 70% by weight, other monomers are 0 to 30% by weight, particularly preferably 35 to 55% by weight of styrene monomer, 45 to 65% by weight of (meth) acrylic acid ester monomer and 0 to other monomers. 20 wt%. Usually, the higher the ratio of the styrene monomer to the total monomers, the lower the saturation absorption rate of the resin composition, while the higher the ratio of the (meth) acrylic acid ester monomer, the higher the beaker softening temperature of the resin composition. . In addition, from the viewpoint of increasing the total light transmittance of the resin composition and lowering the haze value, the ratio of the amount of each monomer of the raw material so that the difference in refractive index between the resulting copolymer (B) and the rubbery copolymer (A) is small. It is desirable to control the.
[32] Moreover, about the ratio of the quantity of the rubbery copolymer (A) of the said raw material and all the monomers of the said raw material, Preferably the former is 1-20 weight% and the latter 80-99 weight% based on the sum total of both. More preferably 2 to 18% by weight of the former, 82 to 98% by weight of the latter, particularly preferably 3 to 15% by weight of the former and 85 to 97% by weight of the latter. Usually, the higher the ratio of the former, the lower the saturation absorption rate of the resin composition can be, the higher the notch isolation layer strength can be. .
[33] As a method of superposing | polymerizing what mixed each said raw material, for example, after partial-polymerization by the bulk polymerization method of US Pat. No. 4,373,17 (corresponding to Japanese Patent Publication No. 62-13968), the partial polymer obtained is cast-polymerized or The method of superposing | polymerizing by suspension polymerization method or the method of removing and recovering unreacted monomer after superposing | polymerizing by a continuous block polymerization method is preferable.
[34] In each polymerization method, an azo compound, an organic peroxide, etc. are used as a radical polymerization initiator, and a chain transfer agent can also be added for the purpose of control of a polymerization rate, molecular weight adjustment, adjustment of a rubber dispersion state. In addition, mixing of each said raw material may be performed collectively, it may divide, and when it performs, when dividing is carried out, for example, the rubbery copolymer (A) of the said raw material and a part of monomer are mixed, and it is obtained after partial polymerization. You may mix and polymerize the remainder of a partial polymer and a monomer.
[35] The resin composition of the present invention has excellent physical properties and can be suitably used as a material for various resin molded bodies. When producing various resin moldings using the resin composition of the present invention, the resin composition includes, as necessary, ordinary heat stabilizers, antioxidants, light stabilizers, ultraviolet absorbers, colorants, plasticizers, mold release agents, lubricants, and light diffusing agents. You may add 1 type (s) or 2 or more types of additives. Moreover, these may be added at the time of superposition | polymerization which prepares a resin composition, and may be added after pelletizing, for example, when pelletizing a resin composition.
[36] The resin composition of this invention can be used suitably as a base material of the sheet | seat for optical screens, such as the material of an optical member, especially the transmission type screen of a projection television. As this optical screen sheet, the lens sheet like a Fresnel lens sheet, a lenticular lens sheet, a front panel, etc. are mentioned, for example.
[37] The Fresnel lens sheet may be produced by, for example, cast molding, or may be manufactured by applying a Fresnel lens shape to a sheet to be a so-called disk obtained by cast molding, extrusion molding, or the like, by press molding, and the surface of the sheet to be disk. The ultraviolet curable resin may be cured so as to form a Fresnel lens shape.
[38] The lenticular lens sheet may be produced by, for example, extrusion molding, or may be manufactured by cast molding, or may be manufactured by applying a lenticular lens shape to a sheet to be a disc by press molding, and by using a UV curable resin on the surface thereof. You may bond and manufacture the film in which the lens shape was formed to the sheet used as a disc.
[39] In addition, the front panel may be produced by, for example, extrusion molding, or may be produced by cast molding, or may be manufactured by subjecting the surface treatment such as hard coating or low reflection coating to a surface.
[40] In the production of optical screen sheets such as Fresnel lens sheet, lenticular lens sheet and front panel, it is usually necessary to finally cut the sheet to a desired size. In this case, both sides of the sheet in terms of productivity and cost It is preferable to adopt a method (so-called press cutting method) in which the shear blade is inserted and cut from the almost vertical direction. At this time, if the impact resistance of the sheet is not sufficient, cracks and chips of the sheet are likely to occur, but such a crack is a sheet based on the resin composition of the present invention having a high notch isolation impact strength of 2 kJ / m 2 or more. Or chips are difficult to occur. From this point of view, the notched eye impact strength is preferably 3 kJ / m 2 or more, more preferably 4 kJ / m 2 or more, particularly preferably 5 kJ / m 2 or more.
[41] When manufacturing Fresnel lens sheet especially, among the said methods, the method of hardening UV curable resin so that a Fresnel lens shape may be formed in the surface of the sheet used as a disk from a viewpoint of productivity or cost is preferable. At this time, the thickness of the Fresnel lens-shaped cured resin layer is usually in the range of 100 to 300 µm. In this method, the cured resin layer which protrudes in a burr shape around the Fresnel lens-shaped cured resin layer formed on the surface of the sheet used as a disk is usually formed in thickness about several millimeters, It is preferable to remove unnecessary peripheral parts by the said press cutting. In this press cutting, the shear blade enters the surface having the cured resin layer and the opposite surface, and since the former surface is usually harder than the latter surface, the cutting is substantially performed so that the notch formed on the latter surface is propagated. Therefore, although this press cutting is cut | disconnected on the conditions which a crack and a chip | tip are very likely to generate | occur | produce, if a sheet used as a disc is based on the resin composition of this invention, this crack and a chip | tip will hardly arise.
[42] In an optical screen composed of a plurality of sheets, such as a Fresnel lens sheet, a lenticular stove sheet and a front panel, at least one of these sheets, preferably all sheets, is based on the resin composition of the present invention. I can adopt the sheet to say.
[43] Examples of the present invention are shown below, but the present invention is not limited thereto. In addition, the physical property of the obtained resin sheet was measured with the following method.
[44] (1) Saturation Absorption Rate (%)
[45] The test piece was cut out from the resin sheet of thickness 2mm, it vacuum-dried overnight at 80 degreeC, and the weight of the test piece was measured. This weight is called "dry test piece weight." Subsequently, the dry test piece was put into the thermo-hygrostat adjusted to the temperature of 60 degreeC, and 90% of the relative humidity, and it left to stand until the weight became fixed. This constant weight is called "a saturation test piece weight." Saturation absorption was calculated | required by the following formula from the obtained dry test piece weight and the water saturation test piece weight.
[46] Saturation Absorption Rate (%) = 100 × (Saturated Test Weight-Dry Test Weight) / Dry Test Weight
[47] (2) Flexural modulus (MPa)
[48] The test piece was cut out from the resin sheet of thickness 2mm, and the bending elastic modulus was measured according to JIS K 7203 (1995).
[49] (3) Notch Ijot Impact Strength (kJ / ㎡)
[50] The test piece was cut out of resin of thickness 2mm, and the notched eye impact strength was measured according to JIS K 7110 (1999).
[51] (4) Total light transmittance (%) and haze value (%)
[52] The test piece was cut out from the resin sheet of thickness 2mm, and the total light transmittance and haze value were measured according to JISK7105 (1981).
[53] (5) Vicat softening temperature (℃)
[54] The test piece was cut out from the resin sheet of thickness 2mm, and the beaker softening temperature was measured according to JISK7206 (1991).
[55] In addition, evaluation of the obtained resin sheet was performed with the following method.
[56] (Ⅰ) 웝
[57] The 20 cm x 30 cm sample was cut out from the 2 mm-thick resin sheet, and it adhere | attached on one side using aluminum foil as an adhesive. The sample with aluminium foil was put into the thermo-hygrostat adjusted to the temperature of 60 degreeC, and 90% of the relative humidity, and the magnitude of the magnitude | size after 24 hours was visually determined.
[58] (Π) deflection
[59] The 20 cm x 30 cm sample was cut out from the resin sheet of thickness 1mm, the 20 cm side was made into the base side, and it stood vertically, and fixed the bottom side, and the magnitude of the deflection was visually determined.
[60] (Ⅲ) cracks, chips
[61] The 20 cm x 30 cm sample was cut out from the resin sheet of thickness 2mm, the sheath was cut in the 20 cm direction with the acryl cutter, it cut by hand along the sheath, and the presence or absence of the crack of a cross section and the presence or absence of a chip | tip were visually determined.
[62] (IV) Clear feeling of the image
[63] The 20 cm x 30 cm sample was cut out from the resin sheet of thickness 2mm, and it installed in the front surface of the projection television screen, and visually judged the good or bad of the clear feeling of an image.
[64] (Ⅴ) Thermal deformation
[65] The 20 cm x 30 cm sample was cut out from the resin sheet of thickness 2mm, it hold | maintained at 80 degreeC for 1 week, and the presence or absence of deformation was visually determined.
[66] As the rubbery polymer of the starting material, the followings were used.
[67] (a): Random copolymer of styrene / butadiene = 25/75 (weight ratio) [Nippon Elastomer Co., Ltd. product, Tafden L208A]
[68] (b): Block copolymer of styrene / butadiene = 40/60 (weight ratio) [made by Nippon Xeon Co., Ltd., NS312S]
[69] (c): Butadiene rubber [manufactured by Nippon Elastomer Co., Ltd., Asaplen 730AS]
[70] (d): random copolymer of styrene / butadiene = 20/80 (weight ratio) [manufactured by Nippon Zeon Co., Ltd., NS218S]
[71] Examples 1 to 3, Comparative Examples 1 to 4
[72] Rubber type copolymers, monomers and polymerization initiators of the kind and amount shown in Table 1 were mixed, and predetermined residence time was carried out at 150 DEG C using a two-stage stirred continuous reactor (Examples 1 to 3 and Comparative Examples 1 and 4). 360 seconds, and 225 seconds in Comparative Examples 2 and 3).
[73] To 85 parts by weight of the obtained partial polymer, 0.1 parts by weight of monomers of the kind and amount shown in Table 2 and 2,2'-azobis (2,4-dimethylvaleronitrile) (polymerization initiator), t-amylperoxy2- 0.3 parts by weight of ethylhexanoate (polymerization initiator) and 0.1 parts by weight of t-dodecyl mercaptan (chain transfer agent) were added, and this was added to two cells having a pore thickness of 1 mm and 2 mm composed of two glass plates and a gasket. The polymerization was completed by heat treatment for 3 hours in an 80 degreeC water bath and then for 1 hour in an air oven at 120 ° C to obtain a resin sheet having a thickness of 1 mm and 2 mm.
[74] The weight ratio of the rubbery copolymer and monomer (styrene and methyl methacrylate) used as the raw material and the weight ratio of styrene and methyl methacrylate are usually shown in Table 2.
[75] The physical property values of the obtained resin sheet of thickness 2mm are shown in Table 3, and the evaluation result of the resin sheet of thickness 1mm or thickness 2mm is shown in Table 4.
[76] Comparative Example 5
[77] A copolymer of styrene / methyl methacrylate = 40/60 (weight ratio) [manufactured by Shin-Nitetsu Chemical Co., Ltd., MS600] was molded using an extrusion molding machine to obtain a resin sheet having a thickness of 1 mm and 2 mm. The physical property values of the obtained resin sheet of thickness 2mm are shown in Table 3, and the evaluation result of the resin sheet of thickness 1mm or thickness 2mm is shown in Table 4.
[78] YesRubbery copolymerMonomerPolymerization initiator KindsParts by weightStyrene (part by weight)Methyl methacrylate (parts by weight)Benzyl peroxide (parts by weight)Lauryl peroxide (parts by weight) Example 1(a)5.036.158.90.0160.131 Example 2(a)5.036.158.90.0160.131 Example 3(b)5.052.242.8-0.362 Comparative Example 1(a)5.036.158.90.0160.131 Comparative Example 2(c)5.011.483.6-0.302 Comparative Example 3(d)8.027.664.4-0.302 Comparative Example 4(b)5.052.242.8-0.362
[79] YesPartial Polymer (parts by weight)MonomerRaw material cost Styrene (part by weight)Methyl methacrylate (parts by weight)Rubber copolymer / monomer ratio (weight)Styrene / methyl methacrylate ratio (weight) Example 18510.010.04.0 / 96.040.4 / 59.6 Example 28513.07.04.0 / 96.043.4 / 56.6 Example 3855.015.04.0 / 96.049.0 / 51.0 Comparative Example 18515.05.04.0 / 96.045.3 / 54.7 Comparative Example 28513.56.54.0 / 96.023.0 / 77.0 Comparative Example 38516.04.06.5 / 93.540.2 / 59.8 Comparative Example 48511.09.04.0 / 96.055.0 / 45.0
[80] YesSaturation Absorption Rate (%)Flexural Modulus (MPa)I-joint impact strength (kJ / ㎡)Total light transmittance (%)Haze value (%)Beaker Softening Temperature (℃) Example 10.6728703.391.00.8102.0 Example 20.6327905.791.21.5103.7 Example 30.4528504.090.72.394.0 Comparative Example 10.6227603.190.57.097.1 Comparative Example 20.9320807.491.43.5106.6 3 in comparison0.6717909.291.14.2103.3 Comparative Example 40.4231204.189.820.289.0 Comparative Example 50.7733001.692.00.3103.0
[81] Yes웝DeflectionCrack / ChipClear feeling of the imageHeat deformation Example 1smallsmallradishGoodradish Example 2smallsmallradishGoodradish Example 3smallsmallradishGoodradish Comparative Example 1smallsmallradishBadradish Comparative Example 2versussmallradishGoodradish Comparative Example 3smallversusradishGoodradish Comparative Example 4smallsmallradishBadU Comparative Example 5smallsmallUGoodradish
[82] Example 4
[83] 85 parts by weight of the partial polymer obtained in the same manner as in Example 1, 10 parts by weight of styrene, 10 parts by weight of methyl methacrylate, 0.1 part by weight of 70% by weight of t-butylperoxy pivalate (polymerization initiator), t-amylper 0.3 parts by weight of oxy2-ethylhexanoate (polymerization initiator) and 0.1 parts by weight of t-dodecyl mercaptan (chain transfer agent) were added, and these were two kinds of pore thicknesses of 1.8 mm and 2 mm composed of two glass plates and gaskets. Into a cell of, the polymerization was completed by heat treatment in an air oven at 70 ° C. for 8 hours, at 75 ° C. for 2 hours, and at 120 ° C. for 1 hour to obtain a resin sheet having a thickness of 1.8 mm and 2 mm.
[84] As a result of measuring the physical properties of the obtained resin sheet having a thickness of 2 mm, the saturation absorption rate was 0.6%, the bending elastic modulus was 2770 MPa, the notch eye impact strength was 7.0 kJ / m2, the total light transmittance was 91%, the haze value was 0.3%, The beaker softening temperature was 104 ° C.
[85] The Fresnel lens layer of thickness 100-300 micrometers was formed in the surface of this resin sheet by hardening by ultraviolet irradiation between the obtained resin sheet of thickness 1.8mm and the metal mold | die which has Fresnel lens shape. No cracks or chips were observed as a result of cutting the shear blades on both sides of the sheet from a substantially perpendicular direction.
[86] Comparative Example 6
[87] A copolymer of styrene / methyl methacrylate = 40/60 (weight ratio) [Shin-Nitdetsu Chemical Co., Ltd. product, MS600] was shape | molded using the extrusion molding machine, and the resin sheet of thickness 1.8mm was obtained. A 100-300 micrometer-thick Fresnel lens layer was formed on the surface of this resin sheet by hardening by ultraviolet irradiation between the obtained resin sheet and the metal mold | die which has Fresnel lens shape. As a result of cutting the shear blades on both sides of the sheet from a substantially perpendicular direction, many cracks and chips were observed.
[88] The resin composition of this invention is excellent in transparency, can be used suitably as a base material of the sheet | seat for screens which is hard to produce deformation | transformation, such as shock and deflection, and is hard to produce a crack and a chip | tip.

权利要求:
Claims (7)
[1" claim-type="Currently amended] It consists of the rubbery copolymer (A) which has a styrene monomer unit and a diene monomer unit, and the copolymer (B) which has a styrene monomer unit and a (meth) acrylic acid ester monomer unit, The following conditions (1)-( 5) Resin composition characterized by satisfying:
(1) Saturation absorption rate is 0.8% or less when the temperature is 60 ℃ and the relative humidity is 90%,
(2) the flexural modulus is 1800 MPa or more,
(3) Notch eye resort impact strength is not less than 2 kJ / ㎡,
(4) When the sheet having a thickness of 2 mm, the total light transmittance is 85% or more, haze value is 5% or less,
(5) Beaker softening temperature is 90 degreeC or more.
[2" claim-type="Currently amended] The resin composition according to claim 1, wherein the saturated water absorption (1) is 0.7% or less.
[3" claim-type="Currently amended] The resin composition of Claim 1 whose bending elastic modulus (2) is 1900 Mpa or more.
[4" claim-type="Currently amended] The resin composition according to claim 1, wherein the notched eye impact strength (3) is 2.5 kJ / m 2 or more.
[5" claim-type="Currently amended] The resin composition of Claim 1 whose beaker softening temperature (5) is 95 degreeC or more.
[6" claim-type="Currently amended] The sheet for optical screens based on the resin composition in any one of Claims 1-5.
[7" claim-type="Currently amended] The manufacturing method of the sheet | seat for optical screens which cuts the sheet | seat based on the resin composition in any one of Claims 1-5 on both sides of the sheet | seat, and cut | disconnects.

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JPWO2005105918A1|2008-03-13|Acrylic resin film and manufacturing method

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US7183001B1|2007-02-27|Transparent thermoplastic composition comprising hollow glass beads

---

US5449731A|1995-09-12|Resin for plastic lens

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DE10243062A1|2004-03-25|A sanitary material made from thermoplastic polymethyl methacrylate molding material useful for sanitary material resistant to hot water,which is crack resistant, cheap to produce, and can be recycled

---

US5583191A|1996-12-10|Plastic lens

同族专利:

---

公开号 | 公开日

---

WO2002057356A1|2002-07-25|

---

CN1223630C|2005-10-19|

---

US20040054087A1|2004-03-18|

---

US6927257B2|2005-08-09|

---

KR100828974B1|2008-05-13|

---

EP1375587A4|2005-03-02|

---

TW555805B|2003-10-01|

---

JP2002284946A|2002-10-03|

---

EP1375587A1|2004-01-02|

---

CN1487972A|2004-04-07|

引用文献:

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公开号 | 申请日 | 公开日 | 申请人 | 专利标题

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法律状态:
2001-01-22|Priority to JPJP-P-2001-00013452

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2001-01-22|Priority to JP2001013452

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2002-01-21|Application filed by 스미또모 가가꾸 고오교오 가부시끼가이샤, 다이니폰 인사츠 가부시키가이샤

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2002-01-21|Priority to PCT/JP2002/000367

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2003-09-15|Publication of KR20030072602A

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2008-05-13|Application granted

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2008-05-13|Publication of KR100828974B1

优先权:

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申请号 | 申请日 | 专利标题

---

JPJP-P-2001-00013452|2001-01-22|

---

JP2001013452|2001-01-22|

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PCT/JP2002/000367|WO2002057356A1|2001-01-22|2002-01-21|Resin composition and sheet for optical screen|