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    • 专利摘要:
    The present invention relates to the use of a combination of succinic acid and ethylene carbonate in a bleaching agent to reduce the damage to keratinous fibers by oxidative capillary lightening.
    公开号:FR3076450A1
    申请号:FR1872371
    申请日:2018-12-05
    公开日:2019-07-12
    发明作者:Jing Hodes；Daniela Keßler-Becker
    申请人:Henkel AG and Co KGaA；
    IPC主号:
    专利说明:

    Description
    Title of the invention: Bleaching agent and method of hair lightening by gentle oxidation The present invention relates to bleaching agents used as agents for lightening keratin fibers, in particular the hair. Furthermore, the present invention relates to the use of the agents for gently bleaching or lightening the hair by gentle oxidation, a multicomponent conditioning unit (“kit”) containing several components separated from each other, which together form an agent for bleaching for lightening by gentle oxidation of keratinous fibers, as well as a method of lightening by oxidizing keratinous fibers by means of said bleaching agent and of this kit containing the bleaching agent.
    Historically, many consumers have wanted to lighten their own hair color because a blonde hair color is considered attractive and desirable from a fashion point of view. To this end, different bleaching agents offering various bleaching performance are available on the market. The oxidants contained in these products make it possible to lighten the hair fiber by destroying by oxidation the pigment which determines the color of the hair, called melanin. For a moderate bleaching effect, the use of hydrogen peroxide - possibly combined with ammonia or other alkalinizing agents - is sufficient on its own as an oxidant. To obtain a more pronounced bleaching effect, a mixture of hydrogen peroxide and at least one compound chosen from percarbonates and persalts, in particular the peroxodisulfate salts and / or the peroxymonosulfate salts, is usually used. To enhance the bleaching effect, the agents contain higher use concentrations of hydrogen peroxide and percarbonates or persalts, especially persulfates. Dark hair, dark brown or black in color, can be lightened with 4 to 6 shades in one step. Hydrogen peroxide and percarbonates or persalts are stored separately from each other until used, so as not to prematurely deactivate percarbonates or persalts. The hydrogen peroxide component, which contains an aqueous solution of hydrogen peroxide, has an acidic pH to stabilize the hydrogen peroxide.
    However, it is advantageous for the effect of hydrogen peroxide on the degradation of melanin and its bleaching effect on the keratin fiber that the mixture to be applied based on a solution of hydrogen peroxide and persalt presents an alkaline pH.
    The fixing of an alkaline pH for the lightening mixture to be applied can be carried out in different ways: [0005] the bleaching agent contains at least one powdery alkalizing agent, in a total amount such as the mixture to be applied has the desired alkaline pH; Or [0007] the hydrogen peroxide solution is also combined with a preparation of alkalizing agent to obtain the mixture to be applied.
    However, this lightening also results in damage to the hair, since oxidation damages not only the hair pigments, but also the structural constituents of the hair. Depending on the degree of damage, it can range from rough, brittle and difficult to comb hair to brittle hair, through a reduction in the strength and resistance to tearing of the hair. The more hydrogen peroxide - and persalts or percarbonates, if any - is used, the greater the damage to the keratin fibers.
    [0009] In order to minimize hair damage and to compensate for the harmful effects of oxidants, different approaches have been adopted.
    Patent EP 1022014 A1 describes an acid hair dye which contains an alkylene carbonate and is optionally acidified with organic dicarboxylic acids.
    The patents DE 102010063370 and DE 102005013488 describe the use of solubilizers based on acylpyridinium derivatives to improve the lightening effect of bleaching agents, which makes it possible to reduce the quantity of harmful substances to be used. Patent DE 10008640 describes a bleaching process under acid conditions, which also makes it possible to reduce the damage caused to the hair. However, this has the consequence that the oxidant is generally less reactive than under alkaline conditions, which can limit the effectiveness of the bleaching process. Patent WO 2017/085117 discloses bleaching agents in which the addition of certain amino acids to the dicarboxylic acids makes it possible to lighten the hair gently. Although the methods described already allow good results to be obtained, these can still be greatly improved.
    The objective of the present invention was therefore to provide agents which make it possible to lighten or bleach keratin fibers, in particular human hair, while minimally damaging the keratin fibers and being easy to prepare and to manipulate.
    Surprisingly, the above objectives are achieved by adding a combination of succinic acid and ethylene carbonate to an alkaline bleaching agent. The addition of succinic acid and ethylene carbonate to an oxidative lightening agent for keratinous fibers has enabled the inventors to reduce the damage caused to the fibers during their oxidative thinning, without, however, having to renounce the alkaline and the quality of the lightening results obtained. Combinations of ethylene carbonate with other acids, as well as combinations of propylene carbonate with succinic acid or other acids, have induced, in comparison with the formulation according to the invention, either more damage important to keratin fibers, a significantly weakening lightening effect.
    A first object of the invention is therefore a bleaching agent for lightening keratin fibers, in particular human hair, containing a. a composition (A) containing at least one alkalizing agent and, optionally, at least one parsley; and B. a composition (B) having a pH in the range from 2.5 to 5.5, preferably 3 to 5, particularly preferably 3.2 to 4, and containing hydrogen peroxide; and c. optionally, a composition (C) containing at least one parsley; Wherein the mixture of all the constituents of the bleaching agent produces an alkaline pH, preferably in the range from 8 to 12, preferably from 8.5 to 11.5, and particularly preferred from 9 to 10.5, characterized in that the bleaching agent contains succinic acid and ethylene carbonate.
    The bleaching agents according to the invention offer good bleaching performance, while effectively preserving the keratin fibers. They are also easy to prepare and handle.
    For the purposes of the invention, the term "keratin fibers" or "keratin fibers" means furs, wool, feathers and in particular the hair. Although the agents according to the invention are primarily suitable for the lightening by oxidation of keratin-based fibers, there is in principle nothing to prevent their use in other contexts.
    An appropriate indicator for quantifying the damage caused to the fibers, in particular to the hair, is the measurement of the cysteic acid content of the keratin fibers, which increases under the effect of the oxidation of the cysteine groups contained in the keratin fibers.
    For the purposes of the invention, the term "powder" or "pulverulent" means a solid composition consisting of individual particles and capable of flowing at 20 ° C and 1013 mbar, in which the size of the individual particles is is in the range from 0.1 µm to 1.6 mm maximum. The determination of the size of the particles can preferably be carried out by means of a measurement by laser diffraction according to standard ISO 13320-1 (2009). The particle size can optionally be adjusted by physical treatment such as sieving, pressing, granulation or tableting, or by the addition of certain excipients, to meet the requirements linked to the bleaching agent, for example for obtain better miscibility of the various constituents of the powder or the miscibility of the bleaching agent with a preparation of hydrogen peroxide.
    The preferred pulverulent compositions according to the invention have an apparent density situated in the range from 500 to 1000 g / 1 (grams per liter), preferably from 550 to 900 g / 1, and particularly preferably from 600 at 820 g / 1. The determination of the apparent density is preferably carried out according to standard EN ISO 60 (version 01/2000) or DIN ISO 697 (version 01/1984).
    Unless otherwise indicated, all temperature indications are given on the basis of a pressure of 1013 mbar.
    For the purposes of the invention, the term "paste" or "pasty" a composition having a viscosity at 20 ° C and 1013 mbar in the range from 200,000 to 1,600,000 mPas, preferably 250,000 at 1,400,000 mPas, particularly preferably from 300,000 to 1,000,000 mPas, and most preferably from 400,000 to 750,000 mPas.
    The viscosity of the dough is preferably determined using a Brookfield type viscometer; RVDV 11+ device; spindle N ° 96, 4 revolutions per minute, at 20 ° C.
    For the purposes of the invention, the term "cream" or "creamy" means a composition consisting mainly of an oil-in-water emulsion or a water-in-oil emulsion, in which ingredients are dissolved or suspended.
    For the purposes of the invention, the term "gel" or "in the form of a gel" means a composition consisting mainly of an aqueous solution or an oil-in-water emulsion treated with a gelling agent, in which ingredients are dissolved or suspended.
    Unless otherwise indicated, all the pH values are measured at 20 ° C. Unless otherwise indicated, percentage indications relate to weight.
    For the purposes of the present application, the term “bleaching” designates the lightening by oxidation of keratin fibers, in particular of the hair.
    The bleaching agents according to the invention do not contain oxidation dyes, nor precursors thereof. Direct dyes may optionally be present to mask unwanted color tones, but not to generate full color.
    The bleaching agents according to the invention preferably do not contain any acylpyridinium derivative.
    The bleaching agent according to the invention contains a composition (A), a composition (B), optionally a composition (C) and optionally a composition (D), the compositions (A), (B ), (C) and (D) being separated from each other; and A. containing at least one alkalizing agent and optionally at least one persalt, preferably a percarbonate or a persulfate, particularly preferably a persulfate; B. containing hydrogen peroxide and having a pH in the range 2.5 to 5.5, preferably 3 to 5, particularly preferably 3.2 to 4; and, C. containing, when present, at least one parsley, preferably a percarbonate or a persulfate, particularly preferably a persulfate; At least one of the compositions (A) or (B), or optionally (C) or optionally (D) containing succinic acid and at least one of the compositions (A) or (B), or optionally (C ) or optionally (D) containing ethylene carbonate; and the mixture of compositions (A), (B), (C) and (D) producing an alkaline pH, preferably located in the range from 8 to 12, particularly preferably from 8.5 to 11 , 5, and most preferably from 9.0 to 10.5, the pH being measured in each case at 20 ° C.
    In one embodiment, (A) is a cream or gel having a high content of alkalinizing agent, preferably ammonia or monoetha-nolamine; (B) is an aqueous solution or emulsion of hydrogen peroxide having a pH in the range of 2.5 to 5.5, preferably 3 to 5, and particularly preferably 3.2 to 4 ; (D) is an aqueous solution of succinic acid and ethylene carbonate; and C) is not present.
    In a second embodiment, (A) is a cream or gel having a high content of alkalizing agent, preferably ammonia or mono-ethanolamine; (B) is an aqueous solution or emulsion of hydrogen peroxide having a pH in the range of 2.5 to 5.5, preferably 3 to 5, and particularly preferably 3.2 to 4 ; and (C) and (D) are not present, (A) or (B) containing both succinic acid and ethylene carbonate.
    In a third embodiment, (A) is a cream or gel having a high content of alkalinizing agent, preferably ammonia or mono-ethanolamine; (B) is an aqueous solution or emulsion of hydrogen peroxide having a pH in the range of 2.5 to 5.5, preferably 3 to 5, and particularly preferably 3.2 to 4 ; and (C) and (D) are not present, (A) containing a constituent chosen from succinic acid and ethylene carbonate, and (B) containing the constituent chosen from succinic acid and carbonate ethylene which is not present in (A).
    In a fourth embodiment, (A) is a cream or gel having a high content of alkalizing agent, preferably ammonia or mono-ethanolamine; (B) is an aqueous solution or emulsion of hydrogen peroxide having a pH in the range of 2.5 to 5.5, preferably 3 to 5, and particularly preferably 3.2 to 4 ; (C) is a powder containing a persalt, preferably a powder containing a persulfate or a percarbonate, particularly preferably a powder containing a persulfate, optionally containing a filler, preferably silica, optionally containing an oil, and optionally containing a powdery alkalizing agent; and (D) is an aqueous solution of succinic acid and ethylene carbonate.
    In a fifth embodiment, (A) is a cream or gel having a high content of alkalizing agent, preferably ammonia or mono-ethanolamine; (B) is an aqueous solution or emulsion of hydrogen peroxide having a pH in the range of 2.5 to 5.5, preferably 3 to 5, and particularly preferably 3.2 to 4 ; (C) is a powder containing a persalt, preferably a powder containing a persulfate or a percarbonate, particularly preferably a powder containing a persulfate, optionally containing a filler, preferably silica, optionally containing an oil, and optionally containing a powdery alkalizing agent; and (D) is not present, (A) or (B) or (C) containing both succinic acid and ethylene carbonate.
    In a sixth embodiment, (A) is a cream or gel having a high content of alkalizing agent, preferably ammonia or mono-ethanolamine; (B) is an aqueous solution or emulsion of hydrogen peroxide having a pH in the range of 2.5 to 5.5, preferably 3 to 5, and particularly preferably 3.2 to 4 ; (C) is a powder containing a persalt, preferably a powder containing a persulfate or a percarbonate, particularly preferably a powder containing a persulfate, optionally containing a filler, preferably silica, optionally containing an oil, and optionally containing a powdery alkalizing agent; and (D) is not present, (A) or (C) containing a constituent chosen from succinic acid and ethylene carbonate, and (B) containing the constituent chosen from succinic acid and carbonate d ethylene which is not present in (A) or (C).
    In a seventh embodiment, (A) is a cream or gel having a high content of alkalizing agent, preferably ammonia or mono-ethanolamine; (B) is an aqueous solution or emulsion of hydrogen peroxide having a pH in the range of 2.5 to 5.5, preferably 3 to 5, and particularly preferably 3.2 to 4 ; (C) is a powder containing a persalt, preferably a powder containing a persulfate or a percarbonate, particularly preferably a powder containing a persulfate, optionally containing a filler, preferably silica, optionally containing an oil, and optionally containing a powdery alkalizing agent; and (D) is not present, (A) containing a constituent chosen from succinic acid and ethylene carbonate, and (C) containing the constituent chosen from succinic acid and ethylene carbonate which n is not present in (A).
    In an eighth embodiment, (A) is an anhydrous oily powder or paste having a high content of alkalizing agent, preferably alkali silicate, further containing at least one persalt, preferably a persulfate or a percarbonate, and particularly preferably a persulfate; (B) is an aqueous solution or emulsion of hydrogen peroxide having a pH in the range of 2.5 to 5.5, preferably 3 to 5, and particularly preferably 3.2 to 4 ; (D) is an aqueous solution of succinic acid and ethylene carbonate; and C) is not present.
    In a ninth embodiment, (A) is an anhydrous oily powder or paste having a high content of alkalizing agent, preferably of alkali silicate, further containing at least one persalt, preferably a persulfate or a percarbonate, and particularly preferably a persulfate; (B) is an aqueous solution or emulsion of hydrogen peroxide having a pH in the range of 2.5 to 5.5, preferably 3 to 5, and particularly preferably 3.2 to 4 ; and (C) and (D) are not present, (A) or (B) containing both succinic acid and ethylene carbonate.
    In a tenth embodiment, (A) is an anhydrous oily powder or paste having a high content of alkalizing agent, preferably alkaline silicate, further containing at least one persalt, preferably a persulfate or a percarbonate, and particularly preferably a persulfate; (B) is an aqueous solution or emulsion of hydrogen peroxide having a pH in the range of 2.5 to 5.5, preferably 3 to 5, and particularly preferably 3.2 to 4 ; and (C) and (D) are not present, (A) containing a constituent chosen from succinic acid and ethylene carbonate and (B) containing the constituent chosen from succinic acid and ethylene carbonate which is not present in (A).
    The term "high content of alkalizing agent" means a content with which a mixture of the compositions (A), (B), optionally (C) and optionally (D) generates an alkaline pH, preferably located in the range from 8 to 12, particularly preferably from 8.5 to 11.5, and most preferably from 9.0 to 10.5.
    The above embodiments are only given by way of examples and the invention is not limited thereto.
    The following paragraphs describe in more detail each of the constituents and each of the compositions (A), (B), (C) and (D).
    [0048] Succinic acid and ethylene carbonate The bleaching agents according to the invention contain both succinic acid and ethylene carbonate, the latter being distributed as desired between the compositions (A), (B), possibly (C) and possibly (D).
    The preferred bleaching agents according to the invention contain succinic acid in a single composition chosen from (A), (B), optionally (C) and optionally (D), and ethylene carbonate in a only composition chosen from (A), (B), possibly (C) and possibly (D). In this case, the succinic acid can be contained either in the same composition as that containing ethylene carbonate, or in another composition.
    In a preferred embodiment, the succinic acid and the ethylene carbonate form a separate composition (D).
    In another preferred embodiment, the succinic acid and the ethylene carbonate are present in the composition (A).
    In another preferred embodiment, the succinic acid is present in the composition (A) and the ethylene carbonate is present in the composition (B).
    In another preferred embodiment, the ethylene carbonate is present in the composition (A) and the succinic acid is present in the composition (B).
    In another preferred embodiment, the bleaching agent according to the invention contains a composition (C), the succinic acid is present in the composition (C) and the ethylene carbonate is present in the composition (B).
    In another preferred embodiment, the bleaching agent according to the invention contains a composition (C), the succinic acid is present in the composition (C) and the ethylene carbonate is present in the composition (AT).
    In another preferred embodiment, the bleaching agent according to the invention contains a composition (C), the succinic acid is present in the composition (B) and the ethylene carbonate is present in the composition (VS).
    In another preferred embodiment, the bleaching agent according to the invention contains a composition (C), the succinic acid is present in the composition (A) and the ethylene carbonate is present in the composition (VS).
    The preferred bleaching agents according to the invention contain between 0.01% by weight and 1% by weight, preferably between 0.1% by weight and 0.8% by weight, particularly preferably between 0, 2% by weight and 0.5% by weight, and most preferably between 0.3% by weight and 0.4% by weight of succinic acid, and between 0.01% by weight and 1% by weight , preferably between 0.1% by weight and 0.8% by weight, particularly preferably between 0.2% by weight and 0.5% by weight, and most preferably between 0.3% by weight and 0.4% by weight of ethylene carbonate, in each case relative to the weight of the total bleaching agent.
    The particularly preferred bleaching agents according to the invention contain succinic acid and ethylene carbonate, generally in a weight ratio of succinic acid: ethylene carbonate situated in the range from 3: 1 to 1 : 3, preferably from 2: 1 to 1: 2, particularly preferably from 1.5: 1 to 1: 1.5, and most preferably from 1: 1.
    The present invention also relates to the use of a combination of succinic acid and ethylene carbonate in an alkaline bleaching agent to reduce the damage caused to keratin fibers, in particular to the hair, by lightening by oxidation of these fibers, the bleaching agent preferably being a bleaching agent according to the invention.
    Composition f A) The bleaching agents according to the invention contain in composition (A) at least one alkalizing agent. If composition (A) is in the form of a cream or lotion, the alkalizing agent is preferably chosen from ammonia and amines, the amine preferably being an alkanolamine, particularly preferably monoethanolamine, 2-amino-2-methylpropanol and triethanolamine, and very particularly preferably monoethanolamine.
    In the preferred bleaching agents according to the invention, which contain in the composition (A) ammonia or an amine, preferably ammonia or monoethanolamine, particularly preferably ammonia in as an alkalizing agent, composition (A) contains water and has a pH in the range from 8 to 12, preferably from 9 to 11, particularly preferably from 9.5 to 10, 5, the pH measurement being carried out in each case at 20 ° C. Generally, ammonia (NH3) is used as an aqueous solution. Aqueous ammonia solutions often contain ammonia (NH3) in concentrations in the range of 10 to 32% by weight. As such, an aqueous ammonia solution containing 25% by weight of ammonia (NH3) is preferably used.
    The ammonia and / or monoethanolamine present in the alkalinization compositions preferably used according to the invention are preferably present in amounts ranging from 0.01 to 10% by weight, preferably 0.1 to 7.5% by weight, more preferably 0.5 to 5.5% by weight and particularly preferably 1.5 to 4.5% by weight - in each case, relative by weight of the composition (A).
    In addition to ammonia and alkanolamines, at least one other alkalinizing agent may be present, which is chosen from alkali metal silicates, alkaline earth metal silicates, alkali metal hydroxide carbonates. earthy, alkaline earth carbonates, alkali metal metasilicates, alkaline earth metasilicates, alkali metal hydroxides and alkaline earth metal hydroxides, as well as mixtures of these substances.
    The bleaching agents according to the invention in which the composition (A) is in the form of an anhydrous oily powder or paste preferably contains exclusively solid alkalinizing agents (at 20 ° C. and 1013 mbar), preferably chosen from those mentioned above.
    In a preferred embodiment, the bleaching agents according to the invention optionally contain at least one parsley as an oxidant in the composition (A).
    For the purposes of the invention, the persalts are percarbonates and persulfates. The term “percarbonates” is understood to mean in particular the sodium carbonate-hydrogen peroxide complexes. Commercially available sodium percarbonate has an average composition of 2 Na2CO3.3 H2O2. Sodium percarbonate is in the form of a white water-soluble powder, which decomposes easily into sodium carbonate and "active" oxygen with a whitening and oxidizing action.
    The term "persulfates" means the inorganic salts of peroxysulfuric acids.
    The term “peroxisulfuric acids” means peroxydisulfuric acid and peroxyoxy mono sulfuric acid (Caro acid). Preferably, the persulfates are chosen from ammonium peroxydisulfate, alkali metal peroxydisulfates, ammonium peroxymonosulfate, alkali metal peroxymonosulfates and alkali metal hydrogen peroxymonosulfates. Particular preference is given to ammonium peroxydisulfate, potassium peroxydisulfate, sodium peroxydisulfate and potassium hydrogenoperoxymonosulfate. In a preferred embodiment, the bleaching agent according to the invention contains at least two different peroxydisulfates. The preferred peroxydisulfate salts are combinations of ammonium peroxydisulfate and potassium peroxydisulfate and / or sodium peroxydisulfate.
    Preferably, the at least one persalt is chosen from sodium percarbonates and inorganic salts of a peroxysulfuric acid as well as the mixtures thereof, in a total amount ranging from 5 to 85 % by weight, preferably from 10 to 75% by weight, particularly preferably from 15 to 65% by weight, and most preferably from 20 to 55% by weight, in each case relative to the weight of the composition (AT).
    The bleaching agents according to the invention, which exclusively contain solid alkalinizing agents, preferably at least one alkaline silicate, in composition (A), preferably also contain an oxidant chosen from percarbonates of sodium and the inorganic salts of a peroxysulfuric acid, and mixtures thereof, in a total amount in the range of 5 to 85% by weight, preferably 10 to 75% by weight, particularly preferred from 15 to 65% by weight, and most preferably from 20 to 55% by weight, in each case relative to the weight of the composition (A).
    The preferred bleaching agents according to the invention, which contain in composition (A) an oxidant chosen from sodium percarbonates and the inorganic salts of a peroxy sulfuric acid, as well as mixtures thereof, contain in in addition in composition (A) at least one solid inorganic alkalizing agent at 20 ° C. and 1013 mbar, in particular at least one sodium silicate or sodium metasilicate having a molar ratio SiO2 / Na2O greater than or equal to 2, and preferably located in the range of 2.5 to 3.5, in a total amount in the range of 0.1 to 50% by weight, preferably 5 to 40% by weight, in each case by relative to the weight of the composition (A). The solid alkalizing agent at 20 ° C. and 1013 mbar is preferably present in a total amount ranging from 1 to 60% by weight, preferably from 5 to 55% by weight, particularly preferably from 10 to 50% by weight, and most preferably 15 to 45% by weight, relative to the weight of the composition (A). In addition to at least one sodium silicate or sodium metasilicate having a SiO2 / Na2O molar ratio greater than or equal to 2, and preferably situated in the range from 2.5 to 3.5, in a total amount situated in the range from 0.1 to 50% by weight, preferably from 5 to 40% by weight, in each case relative to the weight of the composition (A) as an optional alkalizing agent, other agents particularly preferred alkalinizing agents according to the invention are the inorganic alkalizing agents which are solid at 20 ° C. and 1013 mbar chosen from alkali earth metal silicates, alkaline earth metal hydroxide carbonates, metal carbonates alkaline earth, metasilicates of alkaline earth metals, hydroxides of alkali metals, hydroxides of alkaline earth metals, phosphates of alkali metals (or alkaline earth metals) and hydro-genophosphates of alkali metals (or alkaline earth metals) them), as well as mixtures thereof. The preferred inorganic solidifying alkalinizing agents at 20 ° C. and 1013 mbar according to the invention are, in addition to at least one mandatory sodium silicate or sodium metasilicate, in each case having a greater or equal ratio of moles SiO2 / Na2O to 2, and preferably situated in the range from 2.5 to 3.5, chosen from magnesium hydroxycarbonates and mixtures of these alkalinizing agents. The magnesium hydroxycarbonates preferred according to the invention are those corresponding to the formula MgCO3 Mg (OH) 2 2 H2O and those corresponding to the formula MgCO3 Mg (OH) 2. Particularly preferred according to the invention is magnesium hydroxycarbonate of formula MgCO3 Mg (OH) 2.
    The particularly preferred bleaching agents according to the invention, which contain in composition (A) an oxidant chosen from sodium percarbonates and the inorganic salts of a peroxy sulfuric acid, as well as mixtures thereof, contain in composition (A), relative to their total weight, from 0.1 to 50% by weight, preferably from 5 to 40% by weight, of sodium silicates having a molar ratio SiO2 / Na2O greater than or equal to 2, and preferably situated in the range from 2.5 to 3.5, and from 2 to 20% by weight, preferably from 5 to 15% by weight, particularly preferably from 8 to 25% by weight. magnesium hydroxycarbonate as a solid inorganic alkalizing agent at 20 ° C and 1013 mbar.
    The most preferred bleaching agents according to the invention contain in composition (A), in the absence of composition (C), when the latter is present, each time relative to their total weight, of 0 , 1 to 50% by weight, preferably 5 to 40% by weight, of sodium silicates having a molar ratio SiO2 / Na2O greater than or equal to 2, and preferably situated in the range from 2.5 to 3 , 5, and from 2 to 20% by weight, preferably from 5 to 15% by weight, and particularly preferably from 10 to 13% by weight of magnesium hydroxycarbonate of formula MgCO3 Mg (OH) 2 as solid inorganic alkalizing agent at 20 ° C and 1013 mbar.
    If the bleaching agent according to the invention or preferred according to the invention contains in composition (A) one or more inorganic carbonate (s), either as agent (s) d alkalization or as oxidant (s) in the form of sodium carbonate-hydrogen peroxide complex (s), their content is preferably chosen so that, in the mixture to be applied, the total concentration in moles of CO32 or, with composition (B), optionally composition (C) and optionally composition (D), of at least 0.015 moles / 100 grams of mixture to be applied.
    If the bleaching agent according to the invention or preferred according to the invention contains in composition (A) one or more inorganic carbonate (s), either as agent (s) d alkalization or as oxidant (s) in the form of sodium carbonate-hydrogen peroxide complexes, their content is particularly preferably chosen so that, in the mixture to be applied, the total concentration in moles of CO32 is , with composition (B) and optionally composition (D), numerically at least four times greater than the total concentration of proton donors.
    If the bleaching agent according to the invention or preferred according to the invention in composition (A) contains one or more inorganic carbonate (s), either as basifying agent (s) ), either as oxidizing agent (s) in the form of sodium carbonate-hydrogen peroxide complex (s), their content is chosen most preferably so that in the mixture to be applied, with the composition (B), optionally the composition (C) and possibly the composition (D), the total concentration in moles of CO32- either at least 0.015 moles / 100 grams of the application mixture and either arithmetically at least four times the total concentration of proton donors.
    The bleaching agents according to the invention preferably have a water content in the range from 0 to 8% by weight, preferably from 0.1 to 5% by weight, particularly preferably from 0, 5 to 3% by weight of water in the composition (A), relative to the weight of the composition (A), when the latter contains alkali silicates, and not ammonia or an amine, as alkalinizing agents.
    These indications relate to the free water content. This does not take into account the water content linked to the molecular level or the water of crystallization, potentially associated with individual pulverulent constituents. The water content can be determined, for example, by referring to ISO standard 4317 (version 2011-12) by Karl Fischer titration.
    To extract the dust of the composition (A), if the latter contains alkali silicates, and not ammonia or an amine, as alkalizing agents, it is possible to add at least one dusting agent , chosen in particular from at least one oil, chosen in particular from paraffin oil, silicone oil or ester oil as well as mixtures of these oils. Preferably, the at least one oil is present in a total amount ranging from 0.1 to 15% by weight, preferably from 0.5 to 10% by weight, particularly preferably from 1 to 8 % by weight, and most preferably from 2 to 6% by weight, in each case, relative to the weight of the composition (A).
    The preferred oils according to the invention are chosen from natural and synthetic hydrocarbons, particularly preferably from paraffin oils, C [8 to C30 isoparaffins, in particular isoéicosane, polyisobutenes and po- lydecenes, also chosen from C8 to C16 isoparaffins, in particular from isodecane, isododecane, isotetradecane and isohexadecane, as well as mixtures thereof, and l, 3-di- ( 2-ethylhexyl) -cyclohexane.
    Other preferred oils according to the invention are chosen from benzoic acid esters of linear or branched C8 to C22 alkanols. Particularly preferred are C12 to C π alkyl esters of benzoic acid.
    Other preferred oils according to the invention are chosen from fatty alcohols having from 6 to 30 carbon atoms, which are unsaturated or branched and saturated or branched and unsaturated. The preferred alcohol oils are 2-hexyldecanol, 2-octyldodecanol, 2-ethylhexyl alcohol and isostearyl alcohol.
    Other preferred cosmetic oils according to the invention are chosen from triglycerides (= triple esters of glycerol) of linear or branched, saturated or unsaturated, optionally hydroxylated C8 to C30 fatty acids. Particular preference can be given to using natural oils, such as, for example. amaranth seed oil, apricot kernel oil, argan oil, avocado oil, babassu oil, cottonseed oil, borage seed, camelina oil, safflower oil, peanut oil, pomegranate seed oil, hemp oil, hazelnut oil, elderflower seed oil , blackberry oil, jojoba oil, linseed oil, macadamia nut oil, corn germ oil, almond oil, marula oil, evening primrose oil, olive oil, palm oil, palm kernel oil, Brazil nut oil, pecan oil, peach kernel oil, rapeseed oil, castor oil, sea buckthorn pulp oil, sea buckthorn kernel oil, sesame oil, soybean oil, sunflower oil, grape seed oil, walnut oil, wild rose oil, wheat germ oil, and the liquid fraction of coconut oil. However, oils of synthetic triglycerides, in particular capric / caprylic triglycerides, are also preferred.
    Other particularly preferred cosmetic oils according to the invention are chosen from dicarboxylic acid esters of linear or branched C2 to C10 alkanols, in particular diisopropyl adipate, di-n- adipate butyl, di- (2-ethylhexyl) adipate, di-octyl adipate, diethyl sebacate / di-n-butyl / dioctyl, diisopropyl sebacate, dioctyl malate, dioctyl maleate, dicaprylyl maleate, diisooctyl succinate, di-2-ethylhexyl succinate and di- (2-hexyldecyl) succinate.
    Other particularly preferred cosmetic oils according to the invention are chosen from esters of saturated or unsaturated, linear or branched fatty alcohols, having from 2 to 30 carbon atoms with saturated or unsaturated, linear or branched fatty acids , having 2 to 30 carbon atoms, which can be hydroxylated. These include 2-hexyldecyl stearate, 2-hexyldecyl laurate, isodecyl neo-pentanoate, isononyl isononanoate, 2-ethylhexyl palmitate and 2-ethylhexyl stearate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, iso-octyl stearate, isononyl stearate, stearate d isocetyl, isononyl isononanoate, isotridecyl isononanoate, cetaryl isononanoate, 2-ethylhexyl laurate, 2-ethylhexyl isostearate, 2-ethylhexyl cocoate, 2-octyldodecyl palmitate, butyloc-tanoic acid 2-butyloctanoate, di-isotridecyl acetate, n-butyl stearate, n-hexyl laurate, n-decyl oleate, oleyl oleate, oleyl erucate, erucyl oleate, erucyl erucate, dioleate d ethylene glycol dipalmitate and ethylene glycol.
    Other preferred cosmetic oils according to the invention are chosen from additives of 1 to 5 units of propylene oxide with mono- or multivalent C8 to C22 alkanols such as octanol, decanol , decanediol, lauryl alcohol, myristyl alcohol and stearyl alcohol, for example myristyl ether PPG-2 and myristyl ether PPG-3. Other preferred cosmetic oils according to the invention are chosen from additives of at least 6 units of ethylene oxide and / or propylene oxide with mono- or multivalent C3 to C22 alkanols such as as glycerol, butanol, butanediol, myristyl alcohol and stearyl alcohol, which can be esterified if desired, for example butyl ether PPG-14, butyl ether PPG-9, butanediol PPG -10, stearyl ether PPG-15 and glycereth-7-diisononanoate.
    Other preferred cosmetic oils according to the invention are chosen from C8 to C22 fatty alcohol esters of mono- or multivalent C2 to C7 hydroxycarboxylic acids, in particular esters of glycolic acid, lactic acid, malic acid, tartaric acid, citric acid and salicylic acid, for example C [2 to C 15 alkyl lactate.
    Other preferred cosmetic oils according to the invention are chosen from symmetrical, asymmetrical or cyclic esters of the carboxylic acid with C 3 to C22 alkanols, C3 to C22 alkanediols or C3 to C22 alkanetriols , such as dicaprylyl carbonate, or esters according to patent DE 19756454 A1, in particular glycerol carbonate.
    Other cosmetic oils which are suitable according to the invention are chosen from silicone oils, which include dialkyl- and alkylarylsiloxanes such as decamé-thylcyclopentasiloxane, dodecamethylcyclohexasiloxane, dimethylpolysiloxane and methylphenylpolysiloxane, but also l ' hexamethyldisiloxane, octamethyltrisiloxane and decamethyltetrasiloxane.
    For the purposes of the invention, the use of mixtures of the oils mentioned above may be preferred among all.
    The preferred bleaching agents according to the invention are characterized in that the cosmetic oil is chosen from natural and synthetic hydrocarbons, particularly preferably from paraffin oils, C [8 to C30 isoparaffins, in in particular isoéicosane, polyisobutenes and polydecenes, C8 to C16 isoparaffins, as well as 1,3-di- (2-ethylhexyl) -cyclohexane; benzoic acid esters of linear or branched C8 to C22 alkanols; fatty alcohols having from 6 to 30 carbon atoms, unsaturated or branched and saturated or branched and unsaturated; triglycerides of linear or branched, saturated or unsaturated, optionally hydroxylated C8 to C30 fatty acids, in particular of natural oils; dicarboxylic acid esters of linear or branched C2 to C10 alkanols; esters of saturated or unsaturated, linear or branched fatty alcohols having from 2 to 30 carbon atoms with saturated or unsaturated, linear or branched fatty acids having from 2 to 30 carbon atoms, which may be hydroxylated; adducts of 1 to 5 units of propylene oxide with C8 to C22mono- or multivalent alkanols; additives of at least 6 units of ethylene oxide and / or propylene oxide with mono- or multivalent C3 to C22 alkanols; C8 to C22 fatty alcohol esters of C2 to C7 hydroxycarboxylic acids, monovalent or multivalent; symmetrical, asymmetric or cyclic esters of carboxylic acid with C3 to C22 alkanols, C3 to C22 al-canediols or C3 to C22 alkanetriols; esters of dimers of unsaturated C [2 to C22 fatty acids (dimer fatty acids) with linear, branched or cyclic monovalent C2 to C [8 alkanols or with linear or branched multivalent C2 to C16 alkanols; silicone oils and mixtures of the substances mentioned above, and preferably in a total amount in the range from 0.1 to 15% by weight, preferably from 0.5 to 10% by weight, so particularly preferred from 1 to 8% by weight, and most preferably from 2 to 6% by weight, in each case relative to the weight of the bleaching agent.
    The preferred bleaching agents according to the invention optionally contain at least one polymer chosen from homopolymers and copolymers of acrylic acid, homopolymers and copolymers of methacrylic acid, homopolymers and copolymers of itaconic acid, modifiable polysaccharides chemically and / or physically, and mixtures of these polymers, one or more of the polymers mentioned above being present, in a particularly preferred manner, in a total amount ranging from 0.1 to 6% by weight, preferably from 0.5 to 4% by weight, particularly preferably from 1 to 3.5% by weight, and most preferably from 2 to 3% by weight, in each case relative to the weight of the agent discoloration.
    Optionally, the composition (A) may also contain, in a preferred embodiment, ether chloride of 2- [2-hydroxy-3- (trimethylammomo) propoxy] ethylcellulose. Preferably, 2- [2-hydroxy-3- (trimethylammomo) propoxy] ethylcellulose ether chloride is present in a total amount in the range of 0.01 to 1.00% by weight, particularly preferred from 0.10 to 0.60% by weight, more particularly preferably from 0.20 to 0.48% by weight, and most preferably from 0.30 to 0.47% by weight, in each case relative to the weight of the bleaching powder.
    In a preferred embodiment, the composition (A) also contains at least one amino acid chosen from arginine, lysine, histidine or at least one of the salts of these amino acids. Arginine is preferred among all. Mixtures of arginine and lysine may be particularly preferred according to the invention. Among the arginine, lysine or histidine salts which are preferably suitable according to the invention, mention may be made of ammonium salts, alkali metal salts and alkaline earth metal salts, in particular the salts of lithium, sodium, potassium, magnesium and calcium, as well as hydrohalides, in particular hydrochlorides, and mixtures of these salts. A particularly preferred amino acid salt according to the invention is lysine hydrochloride. The amino acids suitable according to the invention, chosen from arginine, lysine, histidine and the salts thereof, can also contain water of crystallization.
    The preferred compositions (A) according to the invention may contain at least one amino acid chosen from arginine, lysine, histidine or at least one salt of these amino acids, in a total amount, converted into mass free amino acid, in the range from 0.1 to 7% by weight, preferably from 0.2 to 5% by weight, particularly preferably from 0.5 to 2.5% by weight, and most preferably from 1 to 2% by weight, in each case relative to the weight of the composition (A).
    Composition (B) Composition (B) in the bleaching agent according to the invention contains from 50 to 96% by weight, preferably from 70 to 93% by weight, particularly preferably from 80 to 90% by weight of water and from 0.5 to 20% by weight of hydrogen peroxide, in each case relative to the weight of the composition (B), and in addition at least one pH regulator in an amount such that the composition (B) has a pH measured at 20 ° C. situated in the range going from 2.5 to 5.5, in particular from 3 to 5.
    Composition (B) in the bleaching agent according to the invention essentially contains water and hydrogen peroxide. The concentration of hydrogen peroxide is determined on the one hand by legal requirements and on the other hand by the desired effect. It comprises from 0.5 to 20% by weight, preferably from 3 to 12% by weight, in a particularly preferred manner from 6 to 9% by weight of hydrogen peroxide (calculated as H2O2 at 100%), in each case relative to the weight of the composition (B).
    The composition (B) in the bleaching agent according to the invention preferably has an acidic pH to stabilize the hydrogen peroxide, in particular a pH measured at 20 ° C. situated in the range from 2.5 to 5.5, in particular from 3 to 5. To stabilize the hydrogen peroxide, the composition (B) preferably also contains chelating agents, preservatives and / or buffers.
    The particularly preferred bleaching agents according to the invention also contain, in composition (B), at least one oil and / or at least one fatty substance having a melting point situated in the range from 23 to 110 ° C, preferably in a total amount in the range of 0.1 to 60% by weight, particularly preferably 0.5 to 40% by weight, and most preferably 2 to 24% by weight , in each case relative to the weight of the composition (B). The oils present in composition (B) which are suitable for the preferred bleaching agent according to the invention are the same oils as those described above as suitable dedusting agents.
    The fatty substances preferably used according to the invention in composition (B), and whose melting point is in the range from 23 to 110 ° C., are chosen from linear saturated 1-alkanols having 12 to 30 carbon atoms, preferably in a total amount in the range of 0.1 to 8% by weight, particularly preferably 3.0 to 6.0% by weight, in each case relative to the weight of the composition (B).
    Preferably, the at least one linear saturated 1-alkanol having from 12 to 30 carbon atoms is chosen from lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, alcohol arachidyl and behenyl alcohol, as well as mixtures of these 1-alkanols, particularly preferably from mixtures of cetyl alcohol, stearyl alcohol and cetyl alcohol / stearyl alcohol.
    The preferred bleaching agents according to the invention present in composition (B) further contain, in each case with respect to their weight, at least one linear saturated 1-alkanol having from 12 to 30 carbon atoms in one total amount in the range from 0.1 to 8% by weight, preferably in a total amount in the range from 2 to 6% by weight, the at least one 1-alkanol present being chosen from mixtures cetyl alcohol, stearyl alcohol and cetyl alcohol / stearyl alcohol.
    Other preferred compositions (B) according to the invention contain at least one fatty substance having a melting point situated in the range from 23 to 110 ° C., and chosen from the esters of a C1 to 6 alkanol. Saturated and monovalent C60 and of a saturated C8 to C36 monocarboxylic acid, in particular cetyl behenate, stearyl behenate and C2 to C40 alkyl stearate, glycerol triesters of carboxylic acids in C [2 to C30 saturated linear can be hydroxylated, candelilla wax, carnauba wax, beeswax, saturated linear C14 to C36 carboxylic acids and mixtures of the substances mentioned above.
    Other preferred bleaching agents according to the invention contain in composition (B) at least one surfactant or at least one emulsifier, preferably in a total amount lying in the range from 0.5 to 10% by weight, preferably from 1 to 5% by weight, in each case relative to the weight of the composition (B).
    The surfactants and emulsifiers within the meaning of the present application are amphiphilic (bifunctional) compounds consisting of at least one hydrophobic molecular fragment and at least one hydrophilic molecular fragment. The hydrophobic moiety is preferably a hydrocarbon chain of 8 to 28 carbon atoms, which can be saturated or unsaturated, linear or branched. In a particularly preferred manner, this C8 to C28 alkyl chain is linear. The basic properties of surfactants and emulsifiers are directed absorption at interfaces, aggregation into micelles and the formation of lyotropic phases.
    According to the invention, the anionic, nonionic and cationic surfactants are particularly suitable. But even zwitterionic and amphoteric surfactants are well suited according to the invention.
    As suitable anionic surfactants in the compositions according to the invention, all the anionic surfactants suitable for use on the human body are suitable. These are characterized by an anionic group with a water-solubilizing effect such as a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group having from 8 to 30 carbon atoms. Glycolether or polyglycolether groups, ester, ether and amide groups and hydroxyl groups may also be present. Examples of suitable anionic surfactants are linear and branched fatty acids having 8 to 30 carbon atoms (soaps), alkyl ethercarboxylic acids, acylsarcosides, acyltaurides, acylisethionates, mono- and dialkylesters of sulfosuccinic acid and mono -alkylpolyoxethylesters of sulfosuccinic acid, linear alkanesulfonates, linear alpha-olefinsulfonates, alkyl sulfates and alkyl ether sulfates, as well as alkyl and / or alkenyl phosphates. Preferred anionic surfactants are alkyl sulfates, alkyl ether sulfates and alkyl ethercarboxylic acids each having 10 to 18 carbon atoms, preferably 12 to 14 carbon atoms in the alkyl group and up to 12 ether glycol groups, preferably 2 to 6 ether glycol groups in the molecule. Examples of these surfactants are the compounds identified by the names INCI Sodium Laureth Sulfate, Sodium Lauryl Sulfate, Sodium Myreth Sulfate or Sodium Laureth Carboxylate.
    Zwitterionic surfactants denote surfactant compounds which comprise at least one quaternary ammonium group and at least one carboxylate, sulfonate or sulfate group in the molecule. Particularly suitable zwitterionic surfactants are those which are called betaines, such as N-alkyl-N, N-dimethylammonium glycinates, for example cocoalkyldimethylammonium glycinate, N-acylaminopropyl-N, N- glycinates dimethylammonium, for example cocoacylaminopropyl-dimethylammonium glycinate, and the 2-alkyl-3-carboxymethyl-3-hydroxyethyl-imidazolines having, in each case, from 8 to 18 carbon atoms in the alkyl or acyl group, as well as the glycinate cocoa-cylaminoethylhydroxyethylcarboxymethyl. A preferred zwitterionic surfactant is the fatty acid amide derivative known under the name INCI Cocamidopropyl Betaine.
    By amphoteric surfactants is meant the surfactant compounds which contain in the molecule, in addition to a C8 to C24 alkyl or acyl group, at least one free amino group and at least one -COOH or -SO3H group and are capable of forming internal salts. Examples of suitable amphoteric surfactants are N-alkylglycols, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycol, N-alkyltaurines, N-alkylsarcosines, 2-alkylaminopropionic acids and alkylaminoacetic acids having, in each case, from 8 to 24 carbon atoms in the alkyl group. Particularly preferred amphoteric surfactants are N-cocoalkylaminopropionate, cocoacylaminoethylammopropionate and C12 to C18 acylsarcosine.
    The nonionic surfactants contain, as hydrophilic group, for example a polyol group, a polyalkylene glycol ether group or a combination of polyol ether and polyglycol groups. These compounds are, for example, adducts of 4 to 50 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide with linear and branched fatty alcohols, with fatty acids and with alkylphenols , having in each case from 8 to 20 carbon atoms in the alkyl group, ethoxylated mono-, di- and triglycerides, such as for example glycerol monolaurate + 20 ethylene oxide and glycerol monostearate + 20 oxide of ethylene, sorbitan fatty acid esters and ethylene oxide adducts with sorbitan fatty acid esters such as polysorbates (Tween 20, Tween 21, Tween 60, Tween 61, Tween 81 ), adducts of ethylene oxide with alkanolamides of fatty acids, as well as alkylpolyglycosides. Particularly suitable nonionic surfactants are the C8 to C22 alkylmono- and oligoglycosides and their ethoxylated analogs, as well as the adducts of ethylene oxide with saturated or unsaturated linear fatty alcohols having, in each case, 2 to 30 moles of ethylene oxide per mole of fatty alcohol.
    Other preferred bleaching agents according to the invention are characterized in that the at least one anionic surfactant present in composition (B) is chosen from alkyl sulfates, alkyl ether sulfates and acids alkyl ethercarboxyliques having in each case from 10 to 18 carbon atoms, preferably from 12 to 14 carbon atoms in the alkyl group and up to 12, preferably from 2 to 6 ether glycol groups in the molecule.
    Other preferred bleaching agents according to the invention are characterized in that composition (B) contains in the molecule at least one nonionic surfactant chosen from ethylene oxide adducts with alcohols saturated or unsaturated linear fats with, in each case, from 2 to 30 moles of ethylene oxide per mole of fatty alcohol, and at least one anionic surfactant chosen from alkyl sulfates, alkyl ether sulfate and alkyl ethercarboxylic acids having, in each case, from 10 to 18 carbon atoms, preferably from 12 to 14 carbon atoms in the alkyl group and up to 12, preferably from 2 to 6 glycol ether groups, the ratio in weight of the totality of all the anionic surfactants to the totality of all the nonionic surfactants being particularly preferably in the range from 5 to 50, preferably from 10 to 30.
    The suitable cationic surfactants present in the composition (B) of the preferred bleaching agents according to the invention are in principle all the cationic surfactants suitable for use on the human body. These are characterized by at least one cationic group with water-solubilizing effect such as a quaternary ammonium group, or by at least one cationizable group with water-solubilizing effect such as an amine group, and in addition at least one alkyl group ( with lipophilic action) having from 6 to 30 carbon atoms or at least one imidazole group (with lipophilic action) or at least one imidazylalkyl group (with lipophilic action).
    The particularly preferred bleaching agents according to the invention contain in composition (B) at least one cationic surfactant, preferably chosen from quaternary ammonium compounds having at least one C8 to C24 alkyl radical, the esterquats and amidoamines having, in each case, at least one C8 to C24 acyl radical, as well as mixtures thereof. Preferred quaternary ammonium compounds with at least one C8 to C24 alkyl radical are ammonium halides, in particular chlorides, and ammonium alkyl sulfates, such as methosulfates or ethosulfates, such as chlorides of C8 to C24 alkyltrimethylammonium, C8 to C24 dialkyldimethylammonium chlorides and C8 to C24 trialkylmethylammonium chlorides, e.g. cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, distearyldimethylammonium chloride, lauryldimethylammonium chloride, lauryldimethylbenzylammonium chloride and tricetylmethylammonium chloride, as well as the imidazolium compounds identified by the names INCI Quatemium-27, Quatemium-27, Quatemium-27 Quatemium-87 and Quatemium-91. The alkyl chains of the above-mentioned surfactants preferably have from 8 to 24 carbon atoms.
    Esterquats are cationic surfactants which contain both at least one ester function and at least one quaternary ammonium group as a structural element, as well as at least one C8 to C24 alkyl or C8 to acyl radical. C24. Preferred esterquats are quaternized fatty acid ester salts with triethanolamine, quaternized fatty acid ester salts with diethanolalkylamines and quaternized fatty acid ester salts with 1,2 -dihydroxypropyldialkylamines. These products are marketed, for example, under the trade names Stepantex®, Dehyquart® and Armocare®. N, N-bis (2-palmitoyloxyethyl) dimethylammonium chloride, distearoylethyl dimonium methosulfate and distearoylethylhydroxyethylmonium methosulfate are preferred examples of these esterquats.
    The alkylamidoamines are usually prepared by amidation of natural or synthetic C8 to C24 fatty acids and of fatty acid sections with di (Ci-C3) alkylaminoamines. A compound of this group of substances which is particularly suitable according to the invention is stearamidopropyldimethylamine.
    The particularly preferred bleaching agents according to the invention contain in composition (B) at least one cationic surfactant in a total amount ranging from 0.01 to 5% by weight, preferably 0.1 to 3% by weight, and particularly preferably from 0.3 to 2% by weight, in each case relative to the weight of the composition (B).
    Composition (C) [0123] The bleaching agents according to the invention optionally contain a composition (C) containing at least one parsley, the latter being defined as indicated above.
    The bleaching agents according to the invention preferably contain a composition (C) only if the composition (A) does not contain an oxidant chosen from sodium percarbonates and the inorganic salts of a peroxy sulfuric acid, as well as mixtures thereof.
    The ingredients of composition (C) are thus chosen from the ingredients which may be present in a composition (A) containing an oxidant chosen from sodium percarbonates and the inorganic salts of a peroxy sulfuric acid, as well as mixtures of these.
    The particularly preferred bleaching agents according to the invention which contain a composition (C), contain in the composition (A) as an alkalizing agent for ammonia or an amine, preferably ammonia or monoethanolamine, and particularly preferably ammonia.
    Composition (D) [0128] The bleaching agents according to the invention optionally contain a composition (D) containing succinic acid and / or ethylene carbonate and optionally water. Preferably, a composition (D) is present only if none of the compositions (A), (B) or (C) contains succinic acid or ethylene carbonate.
    In order to mask the undesirable shades of color resulting from discoloration, the bleaching agent according to the invention optionally contains, preferably in composition (A) or (C), at least one direct dye. These are dyes that are applied directly to the hair and do not require any oxidative process to form the color. To matify the undesirable residual color impressions caused by the degradation products of melanin, in particular in the range of reddish or bluish colors, direct dyes of complementary colors are particularly preferred. The direct dyes are generally nitro-phenylenediamines, nitroaminophenols, azo dyes, anthraquinones or indophenols. The direct dyes can be anionic, cationic or nonionic. The direct dyes are, in each case, preferably present in an amount ranging from 0.001 to 2% by weight, relative to the weight of the composition (A) or (C).
    The preferred anionic direct dyes are the compounds designated by the international names or trade names: Acid Yellow 1, Yellow 10, Acid Yellow 23, Acid Yellow 36, Acid Orange 7, Acid Red 33, Acid Red 52, Pigment Red 57 : 1, Acid Blue 7, Acid Green 50, Acid Violet 43, Acid Black 1, Acid Black 52, bromophenol blue and tetrabromphenol blue. Preferred cationic direct dyes are cationic triphenylmethane dyes, for example, Basic Blue 7, Basic Blue 26, Basic Violet 2 and Basic Violet 14; aromatic systems substituted by a quaternary nitrogen group, for example Basic Yellow 57, Basic Red 76, Basic Blue 99 and Basic Brown 16 and Basic Brown 17; cationic anthraquinone dyes such as HC Blue 16 (Bluequat B); as well as direct dyes containing a heterocycle having at least one quaternary nitrogen atom, in particular Basic Yellow 87, Basic Orange 31 and Basic Red 51. The cationic direct dyes sold under the brand Arianor are also preferred cationic direct dyes according to the invention. 'invention. Suitable nonionic direct dyes are in particular nonionic dyes of the nitro and quinone type and neutral dyes of the azo type. The preferred nonionic direct dyes are the compounds known under the international names or trade names HC Yellow 2, HC Yellow 4, HC Yellow 5, HC Yellow 6, HC Yellow 12, HC Orange 1, Disperse Orange 3, HC Red 1, HC Red 3, HC Red 10, HC Red 11, HC Red 13, HC Red BN, HC Blue 2, HC Blue 11, HC Blue 12, Disperse Blue 3, HC Violet 1, Disperse Violet 1, Disperse Violet 4 and Disperse Black 9 , as well as 1,4-diamino-2-mtrobenzol, 2- amino-4-nitrophenol, 1,4-bis- (2-hydroxyethyl) -amino-2-mtrobenzol, 3-nitro-4- ( 2-hydroxyethyl) aminophenol, 2- (2-hydroxyethyl) amino-4,6-dimtrophenol, 4- [(2-hydroxyethyl) ammo] -3-nitro-1-methylbenzol, 1- amino-4- ( 2-hydroxyethyl) amino-5-chloro-2-nitrobenzol, 4-amino-3-mtrophenol, l- (2'-ureidoethyl) amino-4-nitrobenzol, acid 2- [(4-amino-2 -mtrophenyl) amino] -benzoic, 6-metro-1,2,3,4-tetrahydroquinoxalme, 2-hydroxy-1,4-naphthoquinone, picramic acid and its salts, 2-amino-6-chloro -4- nitrophenol, 4-ethylamino-3-nitrobenzoic acid and 2-chloro-6-ethylamino-4-mtrophenol. A combination of tetrabromophenol blue and Acid Red 92 is particularly preferred according to the invention.
    The bleaching agents and means for dyeing keratin-based fibers according to the invention may also contain, in composition (A) or possibly composition (C), pigments for coloring the bleaching agent, which are not used to color fibers based on keratin. The pigments are preferably chosen from commercially available pigments and are present in a total amount ranging from 0.1 to 1% by weight, preferably from 0.2 to 0.7% by weight, from particularly preferably from 0.3 to 0.5% by weight, relative to the weight of the composition (A) or optionally of the composition (C).
    Mixture to be applied [0133] Preferably according to the invention, the bleaching agent is composed such that the mixture of composition (A) with (B) and optionally (C) and optionally (D) has a pH in the range of 8 to 12, preferably 8.5 to 11.5, particularly preferably 9 to 10.5, and most preferably a pH in the range of 9 , 5 to 10.2, the pH being measured in each case at 20 ° C.
    The bleaching agent according to the invention is usually present before application in the form of a multi-component packaging unit ("kit").
    Another object of the present invention is therefore a multi-component conditioning unit (“kit”) for the lightening of keratin fibers, which contains at least two components conditioned separately from one another and which is characterized in that [0136] the first component (I) consists of the composition (A), [0137] the second component (II) consists of the composition (B), [0138] optionally iii) another component (III) consists of composition (C), [0139] and optionally iv) another component (IV) consists of composition (D), [0140] the components (I) and (II) occurring, in the absence of a component (III), preferably in a weight ratio (1) :( 11) of 0.2-1, particularly preferably of 0.3-0.8, more preferably of 0.4- 0.7, and most preferably 0.5-0.6 and, components (I), (II) and (III) occurring, in the presence of component (III), in a ratio by weight (1) :( 11) :( III) of (2-3) :( 2-3) :( 0.7-1.3), particularly preferably of (2.3-2.7) : (2.3-2.7) :( 0.8-1.2), and most preferably 2: 2: 1. In the particularly preferred multi-component packaging units (“kits”) according to the invention, a component (IV) is present, the weight ratio (II) :( IV) being 20-2, preferably 15- 5, and particularly preferably 12-8.
    A multi-component packaging unit comprises several individual components packaged separately from each other, and common packaging for these components, for example a folding box. In this document, the components are in each case supplied separately in different containers.
    For the purposes of the present invention, the term "container" means a package which is in the form of a bottle, a tube, a can, a sachet, or any other possibly resealable package. According to the invention, there are no restrictions as to the material of this packaging. However, these are preferably glass or plastic packaging.
    In addition, the packaging unit may include application assistance devices such as combs, brushes or paintbrushes, personal protective clothing, in particular disposable gloves, as well as instructions for use. 'use.
    Another object of the present invention is the use of a bleaching agent according to the invention for the lightening by oxidation of keratin-based fibers, in particular human hair.
    Another object of the present invention is a process for lightening by oxidation of fibers based on keratin, in particular human hair, characterized in that the compositions (A) and (B) and optionally (C) and optionally (D) are mixed with each other, applied immediately afterwards to the keratin fibers, left to stand for 5 to 60 minutes on the keratin fibers, before the fibers are rinsed with water and optionally washed with a washing agent containing a surfactant, the composition (A) and the composition (B) being, in the absence of composition (C), preferably mixed with each other in a weight ratio ( A) :( B) 0.2-1, particularly preferably 0.3-0.8, more preferably 0.4-0.7, and most preferably 0.5 -0.6, and the compositions (A), (B) and (C) being, in the presence of the composition (C), mixed l preferably with each other in a weight ratio (A) :( B) :( C) of (2-3) :( 2-3) :( 0.7-1.3), particularly preferably from (2.3-2.7) :( 2.3-2.7) :( 0.8-1.2), and most preferably from 2: 2: 1.
    In the particularly preferred method according to the invention, the composition (D) is present in the bleaching agent, the weight ratio (B) :( D) being 20-2, preferably 15-5 , and particularly preferably 12-8.
    The present invention also relates to fiber coloring agents based on keratin, in particular hair. These agents are composed essentially of the same constituents as the bleaching agents according to the invention, but also contain in one of the constituents (A) or (B) or optionally (C) or optionally (D), preferably in ( A) or (C), and particularly preferably in (A), at least one dye precursor by oxidation modifying the color of the hair or at least one direct dye.
    Another object of the present invention is therefore a process for dyeing keratin fibers, in particular hair, in which the compositions (A), (B), (C) and optionally (D) of an agent for coloring of keratin-based fibers, in particular hair, according to the invention or preferred according to the invention are mixed with each other, applied immediately afterwards to the keratin-based fibers, left to stand for 5 to 60 minutes on the fibers, before the fibers are rinsed with water and optionally washed with a washing agent containing a surfactant, the compositions (A), (B), and (C) being mixed with each other preferably in a weight ratio (A) :( B) :( C) of (2-3) :( 2-3) :( 0.7-1.3), particularly preferably of (2.3-2, 7) :( 2.3-2.7) :( 0.8-1.2), and most preferably 2: 2: 1.
    Preferably according to the invention, the coloring agent is composed such that the mixture of compositions (A), (B), (C) and optionally (D), is the ready coloring agent on application, has an alkaline pH, preferably a pH in the range from 8 to 12, particularly preferably a pH in the range from 8.5 to 11.5, and most preferably a pH in the range from 9.0 to 10.5, the pH being measured in each case at 20 ° C.
    The coloring agents for keratin-based fibers, in particular hair, ready for application preferably have a viscosity in the range from 15,000 to 100,000 mPas, particularly preferably from 20,000 to 85,000 mPas, measured in each case at 20 ° C with a Brookfield viscometer of DV-11 + type, spindle 5, at a speed of 4 revolutions per minute. A viscosity in this range allows the agent ready for application to be easy to apply on the one hand, and to have a flow behavior capable of guaranteeing a sufficiently long exposure time on the other hand. the agent at the site of action on keratin fibers.
    To facilitate the miscibility of the compositions (A), (B), (C) and optionally (D), and to improve the application properties of the mixture to be applied thus obtained, the composition (A) preferably contains, in each case with respect to its weight, at least one surfactant in a total amount lying in the range from 0.5 to 10% by weight, preferably from 2 to 8% by weight.
    The suitable surfactants are chosen from the same anionic, cationic, nonionic, amphoteric and zwitterionic and emulsifying surfactants as those described above as surfactants and emulsifiers suitable for composition (B).
    The coloring agents for keratin-based fibers, in particular hair, used in a particularly preferred manner according to the invention, also contain, in composition (A), at least one oil and / or at least one body. fatty having a melting point in the range from 23 to 110 ° C, preferably in a total amount in the range from 0.1 to 60% by weight, particularly preferably from 0.5 to 40 % by weight, and most preferably from 2 to 24% by weight, in each case relative to the weight of the composition (A).
    The appropriate oils are the same oils as those described above as suitable dusting agents.
    The fatty substances preferably used according to the invention in the composition (A) and having a melting point situated in the range going from 23 to 110 ° C are chosen from linear saturated 1-alkanols having from 12 to 30 carbon atoms, preferably in a total amount in the range of 0.1 to 20% by weight, particularly preferably 3 to 15% by weight, and most preferably 5 to 10% by weight , in each case relative to the weight of the composition (A).
    Preferably, the at least one linear saturated 1-alkanol having from 12 to 30 carbon atoms is chosen from lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, alcohol arachidyl and behenyl alcohol, as well as mixtures of these 1-alkanols, particularly preferably from mixtures of cetyl alcohol, stearyl alcohol and cetyl alcohol / stearyl alcohol.
    The agents for coloring fibers based on keratin, in particular hair, preferably used according to the invention, contain in composition (A), in each case relative to their weight, at least one 1 linear saturated alkanol having 12 to 30 carbon atoms in a total amount in the range of 0.1 to 20% by weight, preferably in a total amount in the range of 3 to 15% by weight , and most preferably from 5 to 10% by weight, at least one 1-alkanol chosen from cetyl alcohol, stearyl alcohol and cetyl alcohol / stearyl alcohol mixtures being present.
    Other agents for coloring fibers based on keratin, in particular hair, preferably used according to the invention contain in composition (A) at least one fatty substance having a melting point in the range from from 23 to 110 ° C, and chosen from the esters of a saturated and monovalent C1 to C60 alkanol and of a saturated C8 to C36 monocarboxylic acid, in particular cetyl behenate, stearyl behenate and stearate d C2 to C40 alkyl, glycerol triesters of saturated linear C [2 to C30 carboxylic acids which can be hydroxylated, candelilla wax, carnauba wax, beeswax, C carboxylic acids [4 to C36 saturated linear and mixtures of the substances mentioned above.
    In addition, the coloring agents for keratin-based fibers, in particular hair, according to the invention or preferred according to the invention, contain at least one dye precursor by oxidation and / or a direct dye in the composition (A) or (C).
    The at least one dye precursor by oxidation preferably consists of one or more revealing constituents and optionally one or more coupler constituents.
    It is particularly preferred that at least one dye precursor by oxidation is present in a total amount situated in the range from 0.0001 to 10.0% by weight, preferably from 0.001 to 8% by weight, in each case relative to the weight of the composition (A) or (C).
    According to the invention, it may be preferable to choose as revealing constituent at least one compound from the group consisting of p-phenylenediamine, p-toluylenediamine, 2- (2-hydroxyethyl) -p-phenylenediamine, 2- ( 1,2-dihydroxyethyl) -p-phenylenediamine, N, N-bis- (2-hydroxyethyl) -p-phenylenediamme, N- (4-amino-3-methylphenyl) -N- [3- (1H-imidazol -l-yl) propyl] amine, N, N '-bis- (2-hydroxyethyl) -N, N' -bis- (4-aminophenyl) -1,3-diamino-propan-2-ol, bis - (2-hydroxy-5-aminophenyl) methane, 1,3-bis- (2,5-diaminophenoxy) -propan-2-ol, N, N '-bis- (4-aminophenyl) -1,4 -diazacycloheptane, 1,10-bis- (2,5-diaminophenyl) -1,4,7,10-tetraoxadecane, p-aminophenol, 4-amino-3-methylphenol, 4-ammo-2-aminomethylphenol , 4-amino-2- (1,2-dihydroxyethyl) phenol, 4-ammo-2- (diethylammomethyl) phenol, 4.5- diamino-l- (2-hydroxyethyl) -pyrazole, 2,4,5 , 6-tetraaminopyrimidine, 4-hydroxy-2,5,6-triaminopyrimidine, 2-hydroxy-4,5,6-triamino pyrimidme as well as their physiologically acceptable salts.
    Preferably, at least one revealing constituent is present in a total amount lying in the range from 0.0001 to 10.0% by weight, preferably from 0.001 to 8% by weight, in each case relative to the weight of the composition (A).
    The coupler constituents alone do not form significant coloration during oxidation coloration, but always require the presence of revealing constituents. Consequently, it is preferred according to the invention to additionally use at least one coupler component when using at least one developer component.
    The preferred coupler constituents according to the invention are chosen from 3-aminophenol, 5-amino-2-methylphenol, N-cyclopentyl-3-aminophenol, 3-amino-2-chloro-6-methylphenol, 2-hydroxy-4-amino-phenoxyethanol, 2.6-dimethyl-3-ammophenol, 3-trifluoroacetylammo-2-chloro-6-methylphenol, 5-amino-4-chloro-2-methylphenol, 5-ammo -4-methoxy-2-methylphenol, 5- (2-hydroxyethyl) amino-2-methylphenol, 3- (diethylamino) phenol, N-cyclopentyl-3-aminophenol, l, 3-dihydroxy-5- ( methylamino) benzene, 3-ethylamino-4-methylphenol, 2,4-dichloro-3-aminophenol, 2- (2,4-diaminophenoxy) ethanol, 1,3-bis- (2,4-diaminophenoxy) propane, l-methoxy-2-ammo-4- (2-hydroxyethylammo) benzene, 1.3- bis- (2,4-diaminophenyl) propane, 2.6- bis- (2 '-hydroxyethylamino) -1 -methylbenzene, 2 - ({3 - [(2-hydroxyethyl) amino] -4-methoxy-5-methylphenyl} amino) ethanol, 2 - ({3 - [(2-hydroxyethyl) amino] -2-methoxy-5- methylphenyl} am ino) ethanol, 2 - ({3 - [(2-hydroxyethyl) amino] -4,5-dimethylphenyl} amino) ethanol, 2- [3-morpholin-4-ylphenyl) -amino] -ethanol, 3 - amino-4- (2-methoxyethoxy) -5-methylphenylamine, 1- amino-3-bis- (2-hydroxyethyl) aminobenzene, resorcinol, resorcinol monomethylether, 2-methylresorcinol, 5-methylresorcinol, 2,5-dimethylresorcin, 2-chlororesorcin, 4-chlororesorcin, pyrogallol, 1,2,4-trihydroxybenzene, 2,6-dihydroxypyridine, 2-amino-3-hydroxypyridine, 2-amino-5-chloro -3-hydroxypyridine, 3-amino-2-methylamino-6-methoxypyridine, 2,6-dihydroxy-3,4-dimethylpyridine, 2,6-dihydroxy-4-methylpyridine, 2.6-diaminopyridine, 2, 3-diamino-6-methoxypyridine, 3,5-diamino-2,6-dimethoxypyridine, 2,6-dihydroxy-3,4-dimethylpyridine, 3.4- diaminopyridine, 2- (2-methoxyethyl) amino-3 -amino-6-methoxypyridine, 2- (4'-methoxyphenyl) amino-3-aminopyridine, 1-naphthol, 2-methyl-l-naphthol, 2-hydroxym ethyl-1-naphthol, 2-hydroxyethyl-1-naphthol, 1,3-dihydroxynaphthalene, 1,5-dihydroxynaphthalene, 1,6-dihydroxynaphthalene, 1,7-dihydroxynaphthalene, 1,8-dihydroxynaphthalene, 2,7-dihydroxynaphthalene, 2,3-dihydroxynaphthalene, 4-hydroxyindole, 6-hydroxyindole, 7-hydroxyindole, 4-hydroxyindoline, 6-hydroxyindoline, 7-hydroxyindoline, 4,6-diaminopyrimidine , 4-amino-2,6-dihydroxypyrimidine, 2,4-diamino-6-hydroxypyrimidine, 2.4.6-trihydroxypyrimidine, 2-amino-4-methylpyrimidine, 2-amino-4-hydroxy-6- methylpyrimidine and 4,6-dihydroxy-2-methylpyrimidine or mixtures of these compounds or their physiologically acceptable salts.
    Preferably, at least one coupler component is present in a total amount in the range from 0.0001 to 10.0% by weight, preferably from 0.001 to 8% by weight, in each case relative to the weight of the composition (A) or (C).
    The revealing constituents and the coupler constituents are generally used in approximately equimolar amounts relative to each other. Although equimolar use has been found to be practical, a certain excess of individual oxidative dye precursors is not disadvantageous, so that the developer and coupler components may be present in a mole ratio of 0.2-2 , and in particular 0.5-1.
    The direct dyes are preferably those already described above.
    The exposure time is preferably in the range from 5 to 60 minutes, in particular from 5 to 50 minutes, and in a particularly preferred manner from 10 to 45 minutes. During the time that agents are applied to the fiber, it may be advantageous to support the lightening or color modification process by providing heat. A laying phase at room temperature is also in accordance with the invention. The temperature during the exposure time is in particular between 20 ° C and 40 ° C, and in particular between 25 ° C and 38 ° C. The agents give good treatment results even at physiologically tolerable temperatures, ie below 45 ° C.
    After the color modification process, all the constituents present on the keratin fibers are rinsed with water or with a washing agent containing a surfactant. A commercially available shampoo can be used as the washing agent, the washing agent then being able in particular to be omitted and the rinsing process being able to be carried out under running water when the color modification agent has a content high in surfactant.
    The present invention also relates to the use of a combination of succinic acid and ethylene carbonate in an agent for modifying the color of keratin fibers, in particular the hair, containing at least one oxidant chosen from sodium percarbonates and inorganic salts of a peroxy-sulfuric acid, as well as mixtures thereof, and additionally containing at least one chelating agent chosen from the acids listed below and / or their alkali metal salts : ethylenediaminetetraacetic acid (EDTA); N-hydroxyethylethylenediaminetriacetic acid; aminotrimethylenephosphonic acid; diethylenetriaminepentaacetic acid; lauroylethylenediaminetriacetic acid; nitrilotriacetic acid; iminodisuccinic acid; N-2-hydroxyethyliminodiacetic acid; ethylene glycol-bis- (beta-ammoethyl ether) -N, N-tetraacetic acid; aminotrimethylenephosphonic acid; Pentasodium taminotrimethylenephosphonate, and mixtures thereof, in a total amount in the range of 0.1 to 1.4% by weight, preferably 0.2 to 1.4% by weight, so particularly preferred from 0.5 to 1.4% by weight, in each case relative to the weight of the bleaching agent, to reduce the damage caused to the keratin fibers, in particular to the hair, by the treatment of these fibers with a oxidizing agent for modifying the color of fibers based on keratin, in particular the hair.
    What has been said about bleaching agents or agents for modifying the color of fibers based on keratin according to the invention or preferred according to the invention, also applies mutatis mutandis for multi-component packaging units ("Kits") according to the invention and preferred according to the invention.
    What has been said about bleaching agents or agents for modifying the color of fibers based on keratin according to the invention or preferred according to the invention, also applies mutatis mutandis for the lightening processes and / or modification of the color of the keratin fibers according to the invention and preferred according to the invention.
    What has been said about bleaching agents or agents for modifying the color of fibers based on keratin according to the invention or preferred according to the invention, also applies mutatis mutandis for the use according to the invention .
    EXAMPLES 1. Table 1: Composition (A) [Tables 1]
    * A 3% by weight solution of this copolymer in water has a viscosity at 20 ° C in the range from 7,700 to 11,000 mPas. 1. Table 2: Composition (B)
    [Tableaux2]
    1. Table 3: Composition (D) [Tables3]
    The compositions (A), (B) and (D) were mixed with each other in a weight ratio (A) :( B) :( D) of 5: 10: 1.
    2. Application [0178] Natural Kerling type hair strands (7-0) were washed and dried. The freshly prepared mixture of bleaching agent compositions was applied to locks of dry hair (at the rate of 5 g of mixture to be applied per gram of hair). After a reaction time of 45 minutes at 32 ° C, the locks were rinsed for two minutes with hot running water, then air dried. This discoloration process was repeated once, so that the strands were discolored a total of two times in succession.
    3. Measurement of the content of cysteic acid
    To measure the damage caused to the hair by bleaching, the cysteic acid value of each strand of hair treated was determined by quantitative near infrared (NIR) spectroscopy.
    The spectra were recorded with an MP A ™ FT-NIR spectrometer from the company Bruker Optik GmbH. The infrared range includes the range of wave numbers from 12,500 cm1 to 4,000 cm 1 and is characteristic of the higher and combined harmonic oscillations of the CH, OH and NH groups, for example.
    The measurement of the samples was carried out with the integration sphere module at six different points of the sample in diffuse reflection. For the analysis of the measured NIR spectra, the range of wave numbers from 7,300 cm 1 to 4,020 cm 1 was chosen. [0183] The NIR spectra of cystine show characteristic absorption bands in the range of wave numbers ranging from 6,200 cm1 to 5,500 cm1. If the hair changes due to greater damage (in other words, if the cysteic acid content of the hair increases), this will have an effect in the NIR spectrum on the characteristic bands of cysteic acid between 5020 cm1 and 4,020 cm1. The quantitative evaluation of the NIR spectrum was computer assisted.
    Eighteen strands of hair were treated and measured for each bleaching process, the average value being calculated from the eighteen measurements. Comparative examples VI to V7 include in composition (D) an acid different from succinic acid and / or propylene carbonate in place of ethylene carbonate. The example according to the invention E1 contains in composition (D) succinic acid and ethylene carbonate.
    Table 4: Measurement of the content of cysteic acid in keratin fibers after treatment with various bleaching agents by oxidation. El is an example according to the invention; VI to V7 are comparative examples.
    [Tableaux4]
    AS: succinic acid; AT: tartaric acid; AL: lactic acid; AC: citric acid; CE: ethylene carbonate; CP: propylene carbonate [0188] 4. Measurement of color differences [0189] All the locks of lightened hair were measured with a colorimeter of the type
    "Exact" from X-Right and the colors measured have been described using their coordinates in the CIELAB L * color space, a * and b *. The value L * describes the clarity, the value a * the green or red components, and the value b * the blue or yellow components of the colors.
    The difference in the color of the hair after bleaching in the presence of the combinations E1, V1-V7 relative to the color of the hair after bleaching without the addition of acids and alkylene carbonates was calculated on the distance ΔΕ in the color space L *, a *, b *. The distance ΔΕ is defined as ΔΕ = [(L * - L0) 2 + (a * - a0) 2 + (b * - b0) 2] 0'5, where L *, a * and b * are the coordinates of the shade of color after discoloration in the presence of a combination E1, V1-V7, and LO, a0 and b0 are the coordinates of the shade of color after discoloration without the addition of acids and alkylene carbonates. The color differences of ΔΕ <2 are not noticeable for untrained eyes.
    Table 5: Deviation of the shade of hair color after bleaching in the presence of combinations El, VI-V7 relative to the shade of hair color after bleaching without the addition of alkylene acids and carbonates (sample- witness).
    [Tableaux5]
    AS: succinic acid; AT: tartaric acid; AL: lactic acid; AC: citric acid; CE: ethylene carbonate; CP: propylene carbonate [0193] Only a particularly effective preservation of the keratin fibers is observed in El (example according to the invention) during lightening by oxidation, without observing any visible difference in color compared to the control sample. Although the combination V2 of lactic acid and ethylene carbonate preserves the hair slightly better than the combination according to the invention, the bleaching result visibly differs from the bleaching result obtained with T control sample (ΔΕ =
    3.15) and is much darker than this one (L * is much weaker).
    权利要求:
    Claims (1)
    [1" id="c-fr-0001]
    Claims [Claim 1] Bleaching agent for lightening by oxidation of keratin fibers, in particular hair, containing a) a composition (A) containing at least one alkalizing agent and, optionally, at least one persalt; and b) a composition (B) having a pH in the range from 2.5 to 5.5, preferably 3 to 5, particularly preferably 3.2 to 4, and containing hydrogen peroxide ; and c) optionally, a composition (C) containing at least one parsley; wherein the mixture of all the constituents of the bleaching agent produces an alkaline pH, preferably in the range from 8 to 12, particularly preferably from 8.5 to 11.5, and most particularly preferably from 9 to 10.5, characterized in that the bleaching agent contains succinic acid and ethylene carbonate. [Claim 2] A bleaching agent according to claim 1, characterized in that the composition (A) also contains a parsley, but no composition (C). [Claim 3] A bleaching agent according to claim 1, characterized in that the composition (C) is present and preferably contains another powdered alkalinizing agent. [Claim 4] A bleaching agent according to any one of claims 1 to 3, characterized in that the succinic acid is either in composition (A), or in composition (B), or in composition (C ) and the ethylene carbonate is either in composition (A), or in composition (B), or in composition (C), succinic acid and ethylene carbonate being either in the same composition , or in two different compositions. [Claim 5] A bleaching agent according to any one of claims 1 to 3, characterized in that the succinic acid and the ethylene carbonate are in an additional composition (D). [Claim 6] A bleaching agent according to any one of claims 1 to 5, characterized in that it contains 0% by weight of acylpyridinium derivatives. [Claim 7] Bleaching agent according to any one of Claims 1 to 6, characterized in that the composition (A) or, when it is present (C), contains a parsley and that this parsley is a persulfate or a percarbonate. [Claim 8] A bleaching agent according to any one of claims 1 to 7, characterized in that the weight ratio succinic acid: ethylene carbonate is in the range from 3: 1 to 1: 3. [Claim 9] Bleaching agent according to any one of claims 1 to 8, characterized in that it contains succinic acid in a total amount ranging from 0.01 to 1% by weight, per based on the weight of the bleaching agent, and ethylene carbonate in a total amount in the range of 0.01 to 1% by weight, based on the weight of the total bleaching agent. [Claim 10] Multicomponent conditioning unit (“kit”) for lightening keratin fibers, in particular hair, containing a bleaching agent according to any one of claims 1 to 9, in at least two compartments of separate packaging, characterized in that the composition (A) is packaged in the first compartment (I), the composition (B) is packaged in the second / second compartment (II), optionally, the composition (C) is packaged in a third compartment (III), and optionally, the composition (D) is packaged in a fourth compartment (IV). [Claim 11] Process for lightening by oxidation of keratin fibers, in particular of the hair, characterized in that all the constituents of a bleaching agent according to any one of Claims 1 to 9 are mixed with each other, applied immediately afterwards to the keratin fibers, left to stand on the fibers for 5 to 60 minutes, before the fibers are rinsed with water and optionally washed with a washing agent containing a surfactant. [Claim 12] Use of a combination of succinic acid and ethylene carbonate in an alkaline bleaching agent to reduce damage to keratin fibers, particularly hair, by oxidative lightening of these fibers, l bleaching agent preferably being a bleaching agent according to any one of Claims 1 to 9. [Claim 13] Use of a bleaching agent according to any one of Claims 1 to 9 for the lightening by oxidation of keratin fibers, especially hair. [Claim 14] Keratin fiber coloring agent, containing a bleaching agent according to any one of claims 1 to 9, and characterized in that it additionally contains at least one dye precursor by oxidation or at minus a direct dye. [Claim 15] Process for coloring keratin fibers, in particular hair, characterized in that all the constituents of a keratin fiber coloring agent according to claim 14 are mixed with each other, applied immediately after on the keratin fibers, left to lay on the fibers for 5 to 60 minutes, before the fibers are rinsed with water and optionally washed with a washing agent containing a surfactant.
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    同族专利:
    公开号 | 公开日
    DE102017222516A1|2019-06-13|
    US10632051B2|2020-04-28|
    GB2570782A|2019-08-07|
    FR3076450B1|2021-08-27|
    GB2570782B|2020-06-03|
    GB201820269D0|2019-01-30|
    US20190175462A1|2019-06-13|
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    法律状态:
    2019-12-19| PLFP| Fee payment|Year of fee payment: 2 |
    2020-12-23| PLFP| Fee payment|Year of fee payment: 3 |
    2021-01-22| PLSC| Publication of the preliminary search report|Effective date: 20210122 |
    2021-12-24| PLFP| Fee payment|Year of fee payment: 4 |
    优先权:
    申请号 | 申请日 | 专利标题
    DE102017222516.5A|DE102017222516A1|2017-12-12|2017-12-12|Bleaching agent and method for gentle oxidative hair whitening|
    DE102017222516.5|2017-12-12|
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