![]() USE OF LECITHINS AS A BIOCIDE AGAINST ARTHROPODS (Machine-translation by Google Translate, not legal
专利摘要:
Use of lecithins as a biocide against arthropods. The present invention relates to the use of a lecithin as a biocide against arthropod species; in which lecithin is applied in the form of a liquid composition; also refers to said liquid composition comprising a solid formulation of lecithin powder and water; as well as said formula. (Machine-translation by Google Translate, not legally binding) 公开号:ES2754717A1 申请号:ES201830996 申请日:2018-10-16 公开日:2020-04-20 发明作者:Bretones German Martin;Aguilera Juan Antonio Fernandez 申请人:Bretones German Martin;Ortega Carrasco Javier Carlos;Aguilera Juan Antonio Fernandez; IPC主号:
专利说明:
[0001] [0002] [0003] [0004] Field of the Invention [0005] [0006] The present invention is framed within the agri-food sector. It refers to the use of lecithins as substances with the capacity to negatively affect the integrity of arthropod species, more specifically capable of acting as insecticides or acaricides. [0007] [0008] Background of the Invention [0009] [0010] To date, although it is true that there are abundant written references to the use of soy lecithin as a fungicidal or fungistatic agent, in no case has any description of lecithins been found, as they are chemically or physically extracted from their original matrices, such as substances capable of acting or negatively affecting the development of insects or mites. [0011] [0012] In the market there are formulated concentrates of emulsified lecithins (EUROPEAN COMMISSION, DIRECTORATE-GENERAL FOR HEALTH AND FOOD SAFETY, Safety of the Food Chain, Pesticides and Biocides, SANCO / 12798/2014-rev. 2; 30 March 2015)), are suspensions of lecithin in oils with maximum riches of 49% w / V. The use of these commercial concentrated lecithin suspensions is indicated as a fungicide or as an adjuvant. [0013] [0014] However, it is very difficult, if not impossible, to reach high concentrations of lecithin with these emulsifiers. The liquid becomes very viscous and commercially useless. [0015] [0016] Furthermore, the soluble powder format - which is standardized in the agricultural environment - or the wettable powder of lecithin has never been described in the agricultural sector. In this sense, it has not been possible so far to be able to obtain lecithin powder among agricultural supplies. [0017] On the other hand, until now it has not been economically feasible to reach an optimal concentration for acaricide / insecticide use based on concentrated suspensions of lecithins. It is not economically feasible to reach liquid compositions, application broths, with a concentration of 30 g / l (30 grams of lecithin per liter of composition) starting from these suspensions. [0018] [0019] In order to have a lecithin concentration sufficient for use against arthropods in a liquid composition, ready for application, starting from concentrated emulsifiers, an amount of emulsifier would be necessary such that it makes the use of lecithins not economically viable . [0020] [0021] Therefore, there are several needs in the state of the art, on the one hand, the development of new biocides with insecticidal and acaricidal capacities, which are environmentally friendly, harmless to humans, economically sustainable and respectful of the mechanisms of Biological control fully integrated in agricultural development, and on the other hand, compositions that contain lecithin in the desired effective and effective concentration and that are economically viable for use in phytosanitary or nutritional applications in the environment of the agricultural sector. [0022] [0023] Surprisingly it has been found that lecithins have biocidal properties against arthropods, in particular they have insecticidal and acaricidal properties. It has further been found that it is possible to achieve necessary concentrations of lecithin in a composition that can be used against arthropods, such as insects and mites. Furthermore, it has been found that it is not necessary to use a lecithin emulsion as the starting raw material, which is precisely one of the reasons why it was not hitherto economically viable to prepare compositions effective against arthropods. The present invention also solves this problem by having been able to prepare liquid compositions using lecithin powder - for example, soluble powder or wettable powder - as a starting product, this point being an innovative aspect and an advantage over the state of the art, since that to date, there was no lecithin powder format in the agricultural sector for the preparation of liquid compositions ready to be applied in the field. [0024] In addition to the aforementioned advantages, the use of inert substances in formulations of lecithin powder, soluble powder, or wettable powder, provide improvements over lecithin alone in terms of preservation and manageability. [0025] [0026] Description of the Invention [0027] [0028] In the present invention, the term "lecithins" refers to a family of emulsifying and saponifiable lipids that occur naturally in animal and plant tissues, the general formula of which is as follows: [0029] [0030] [0031] [0032] [0033] The term "arthropods" refers to invertebrate animals that form the most diverse phylum in the animal kingdom. These animals have their bodies covered by an exoskeleton known as a cuticle and forming a linear series of ostensible segments, with appendages of articulated pieces. Arachnids, insects, and crustaceans are arthropods. [0034] [0035] The term "insects" refers to a class of invertebrate animals of the arthropod's edge, characterized by presenting a pair of antennas, three pairs of legs and two pairs of wings. [0036] [0037] The term "mites" refers to a subclass of arachnids encompassed by the arthropod edge. [0038] [0039] The term "formulated" refers to a solid product that comprises lecithin powder - soluble powder or wettable powder - and that optionally can comprise one or more inert substances. This term is used because it is commonly used in agriculture-related technology and in products that are applied as biocides or biopesticides. [0040] [0041] The present invention relates firstly to the use of a lecithin as a biocide against arthropod species, and in particular as an acaricide or insecticide. [0042] [0043] Lecithin is applied in the form of a liquid composition, and is normally applied in the form of a spray. [0044] [0045] The liquid composition, or in liquid form, is also called an application broth. The liquid composition comprises at least lecithin and water and the composition is now complete for field application. [0046] [0047] Said liquid composition is prepared from a solid formulation of lecithin powder - soluble powder or wettable powder -. This solid formulation comprises lecithin powder either pure or mixed with at least one inert substance. [0048] [0049] This formulation comprises lecithin powder in an amount of at least 50% by weight with respect to the total weight of the formulated, preferably, at least 80% by weight with respect to the total weight of the formulated. [0050] [0051] The inert substances that can be used can be any as long as they do not negatively affect the environment, and preferably they are those approved for organic cultivation. [0052] [0053] For example, among these inert substances can be used: monopotassium phosphate, monoammonium phosphate, clay, talc, potassium nitrate, ammonium sulfate, amino acids, glutamates, acetates, humates, citric acid, ascorbic acid, potassium carbonate, potassium sorbate, potassium malate, citrulline malate, urea, potassium chloride, silica gel, oxalate, zeolite, algae extracts, alginates, diatomaceous earth, xanthan gum, arabic gum, methylcellulose, agarose, acrylamide, gels, lignin, pectin, lignosulfonates, molybdates, phosphates biamonic, mica, kaolin, fructose, sucrose, chitosan, calcium hydroxide, quartz sand, sodium bicarbonate, serum or mixtures of them. [0054] [0055] These substances are preferably selected from mica, kaolin, fructose, sucrose, chitosan, calcium hydroxide, quartz sand, sodium bicarbonate, serum and mixtures thereof. [0056] [0057] The inert substance or substances fulfill an essential function, such as improving the formulation in aspects such as solubility, stability, exerting an anti-caking, anti-wetting and / or coloring effect. Some of these properties are also essential to be able to commercialize the product in good conservation conditions, and in good conditions for its use. [0058] [0059] The liquid composition for field application comprises at least lecithin and water. [0060] [0061] According to particular embodiments, said composition comprises only lecithin and water, and lecithin is present in a concentration equal to or greater than 0.5 grams of lecithin per liter of water. [0062] [0063] According to further particular embodiments, said composition comprises lecithin in a concentration equal to or greater than 0.5 grams of lecithin per liter of water, preferably greater than 1.1 grams of lecithin per liter of water. [0064] [0065] For example, the composition may comprise lecithin in a concentration between 0.5 grams of lecithin per liter of water and 30 grams of lecithin per liter of water. Preferred compositions comprise lecithin at a concentration between 1.1 grams of lecithin per liter of water and 10 grams of lecithin per liter of water, and more preferably still comprise lecithin at a concentration of between 2 grams of lecithin per liter of water and 5 grams of lecithin per liter of water. grams of lecithin per liter of water. [0066] [0067] The lecithin for use as a biocide against arthropods can be any one, and according to particular embodiments is selected from soy lecithin, sunflower lecithin, rape lecithin, cotton lecithin, egg lecithin and mixtures thereof. [0068] According to particular embodiments of the present invention, arthropods are selected from insects and arachnids. [0069] [0070] In particular, arthropods are arachnids, and preferably are mites. [0071] [0072] Among the arthropods, a particular selection is made of Red Spider ( Tetranychus urticae), Red Spider ( Tetranychus evansii), Vasates ( Aculops lycopersici), White Spider ( Polyphagotarsonemus latus), Trips ( Frankliniella occidentalis), Whitefly ( Bemisia tabaci), Mosquito green ( Empoasca spp), Aphid ( Macrosyphum euphorbiae), Aphid ( Myzus persicae), Aphid ( Aphis gossypii), Aphid ( Aphis fabae), Aulacartun solani and Creontiades pallidus. [0073] [0074] Other arthropod species against which lecithins can be used include, for example: Bemisia tabaci (whitefly), Trialeurodes vaporariorum (whitefly), Ceratitis capitata (fruitfly), Tuta absolu (tomato moth), Icerya purchasi (grooved mealybug), Phenacoccus solani (pepper mealybug), Nezara viridula (green stinkbug), Liriomyza huidobrensis (leaf miner fly). [0075] [0076] The present invention also relates to a lecithin solid formulation comprising lecithin powder in pure form or accompanied by one or more inert substances. Said inert substances can be any substance that does not negatively affect the environment, and are preferably those approved for organic cultivation. [0077] [0078] Among these inert substances can be used: monopotassium phosphate, monoammonium phosphate, clay, talc, potassium nitrate, ammonium sulfate, amino acids, glutamates, acetates, humates, citric acid, ascorbic acid, potassium carbonate, potassium sorbate, potassium malate, citrulline malate , urea, potassium chloride, silica gel, oxalate, zeolite, algae extracts, alginates, diatomaceous earth, xanthan gum, gum arabic, methylcellulose, agarose, acrylamide, gels, lignin, pectin, lignosulfonates, molybdates, biammonium phosphate, mica , kaolin, fructose, sucrose, chitosan, calcium hydroxide, quartz sand, sodium bicarbonate, serum or mixtures thereof. [0079] According to preferred embodiments, they are selected from mica, kaolin, fructose, sucrose, chitosan, calcium hydroxide, quartz sand, sodium bicarbonate, serum and mixtures thereof. [0080] [0081] In the solid formulation according to the invention, the lecithin can be present in an amount of between 50% and 100% by weight with respect to the total weight of the formulated, preferably, between 70% and 100%, and more preferably between 90% and 100% by weight with respect to the total weight of the formulated. [0082] [0083] In the solid formulation according to the invention, the lecithin can be any lecithin or mixture of lecithins. In particular, it is selected from soy lecithin, sunflower lecithin, rapeseed lecithin, cotton lecithin, egg lecithin and mixtures thereof. [0084] [0085] In particular, the solid formulation is used to prepare a liquid composition comprising lecithin in a concentration comprised between 0.05% and 1.5% by total weight of the liquid composition. [0086] [0087] Furthermore, the present invention relates to a liquid composition comprising: - a solid lecithin formulation as defined above, [0088] - and water, [0089] in which lecithin is present in a concentration comprised between 0.5 grams of lecithin per liter of water and 30 grams of lecithin per liter of water, preferably between 1.1 grams of lecithin per liter of water and 30 grams of lecithin per liter of water. [0090] [0091] Particular embodiments of the composition comprise lecithin at a concentration between 1.1 grams of lecithin per liter of water and 10 grams of lecithin per liter of water, and more preferably still comprise lecithin at a concentration of between 2 grams of lecithin per liter of water and 5 grams of lecithin per liter of water. [0092] [0093] In the liquid composition defined above, said formulation is a solid formulation comprising pure lecithin powder or lecithin powder mixed with one or more inert substances. Said inert substances can be any substance that does not negatively affect the environment, and are preferably those approved for organic farming. According to particular embodiments, they are selected from mica, kaolin, fructose, sucrose, chitosan, calcium hydroxide, quartz sand, sodium bicarbonate, serum and mixtures thereof. [0094] [0095] In the composition according to the invention, the lecithin can be any or they can be mixtures of lecithins, and is preferably selected from soy lecithin, sunflower lecithin, rapeseed lecithin, cotton lecithin and egg lecithin, or mixtures thereof. . The present invention also relates to the use of the solid formulation to prepare a liquid composition such as that defined above. [0096] [0097] The present invention also relates to the use of the composition defined above, or of the formulation defined above, in agriculture. [0098] [0099] In particular, the solid formulation of the invention or the composition of the invention are directed to use as biocides, and more specifically against arthropod species, and preferably against insects and arachnids. Arthropods are preferably arachnids, and more preferably mites. [0100] [0101] According to preferred embodiments, the use of the solid formulation, or of the liquid composition of the invention, refers to the use in which the arthropods are selected from Red spider ( Tetranychus urticae), Red spider ( Tetranychus evansii), Vasates ( Aculops lycopersici), White spider ( Polyphagotarsonemus latus), Trips ( Frankliniella occidentalis), White fly ( Bemisia tabaci), Green mosquito ( Empoasca spp), Aphid ( Macrosyphum euphorbiae), Aphid ( Myzus persicae), Aphid ( Aphis gossypii), Aphid ( Aphis fabae) , Aulacartun solani and Creontiades pallidus. [0102] [0103] Other arthropod species against which the solid formulation or the liquid composition of lecithins can be used are, for example: Bemisia tabaci (whitefly), Trialeurodes vaporariorum (whitefly), Ceratitis capitata (fruitfly), Tuta absolute (tomato moth), Icerya purchasi (grooved mealybug), Phenacoccus solani (pepper mealybug), Nezara viridula (green stink bug), Liriomyza huidobrensis (leaf miner fly). [0104] The use of a solid formulation of lecithin is essential in the invention, and one of the main advantages, since otherwise lecithin would not be effective as an acaricide / insecticide, since the maximum biocidal efficacy concentrations that are necessary could not be reached. against all the uses and studies that have been made with it so far in the agricultural sector. [0105] [0106] Examples: [0107] [0108] Example 1 [0109] [0110] Tests have been carried out with soy lecithin and sunflower lecithin. For this, 100% rich lecithin powder, that is, pure lecithin powder, was used as the starting product. [0111] [0112] Each formulation of each class of lecithin was tested at different concentrations, expressed in grams of lecithin for each liter of water: 0.5 g / l, 1 g / l, 2 g / l, 4 g / l, 8 g / l 16 g / l. [0113] [0114] The acaricidal or insecticidal activity of lecithins in their different concentrations were evaluated against one mite and two insects, considered a pest in horticultural crops globally: [0115] [0116] - Tetranychus urticae, plague mite commonly called "red spider" [0117] - Frankliniella occidentalis, phytophagous insect commonly called "trips". [0118] - Aphis fabae, aphid. [0119] [0120] The acaricidal and / or insecticidal activity of the lecithin formulations (100% lecithin) of the example was evaluated in both the adult and immature stages of the three pests used. [0121] [0122] The acaricidal or insecticidal activity was determined in terms of percentage of mortality or mortality efficiency of red spider, thrips and aphids. Negative controls, that is, populations of spider, thrips or of healthy aphids to which only treatments with distilled water were applied. [0123] [0124] The mortality efficiencies obtained from each treatment, from each composition and at each concentration in each pest tested were subjected to the Henderson-Tilton correction, with the following formula: [0125] [0126] % Henderson-Tilton efficiency = [1- (Td / Cd) x (Ca / Ta)] x 100 [0127] Where: [0128] [0129] Ta = n ° live individuals in the treatment before application. [0130] Td = n ° individuals alive in the treatment after the application. [0131] Ca = n ° live individuals in the control before application. [0132] Cd = n ° live individuals in the control after application. [0133] [0134] The corrected mortality efficacy results obtained were subjected to statistical tests in order to verify the statistical significance of the results. [0135] [0136] Table 1 reflects the summary of Henderson-Tilton corrected efficacy results obtained in the different tests by the different lecithins, in their different formulations and at the different concentrations on the three pests used in the test: [0137] [0138] [0139] Table 1. Efficacy results for mortality corrected according to Henderson-Tilton in% obtained in the different tests. [0140] [0141] All the corrected mortality efficiencies obtained were found to be statistically significant with a significance level of 95%, therefore all the compositions tested were shown to have insecticidal and / or acaricidal activity at the doses tested. [0142] [0143] Both soybean and sunflower lecithin compositions have been shown to have insecticidal and / or acaricidal activity on the pests used in the test, in their different formulations and in different concentrations. This activity manifests itself in the different phases of the life cycle of the insects and mites tested and would allow, to a certain extent, to control the pests tested in field conditions. [0144] [0145] Example 2. [0146] [0147] Tests have been carried out with soy lecithin mixed with chitosan as an inert matter as a method of improving the solubility of the product in water. For this, solid lecithin powder was used as the starting product and it was mixed with chitosan powder in a ratio of 3: 1 w / w, that is, 3 parts of lecithin and 1 of chitosan, thus, lecithin powder tested against various insects and mites it had a final richness of 75% by weight of lecithin on the total and 25% by weight of chitosan on the total [0148] [0149] This 75% lecithin was tested at different concentrations, expressed in final grams of lecithin for each liter of water: 0.5 g / l, 1 g / l, 2 g / l, 4 g / l, 8 g / l and 16 g / l. [0150] The acaricidal or insecticidal activity of lecithin in its different concentrations was evaluated against a mite and two insects, considered pests in horticultural crops globally: [0151] [0152] - Tetranychus urticae, plague mite commonly called "red spider" [0153] - Frankliniella occidentalis, phytophagous insect commonly called "trips". - Aphis fabae, aphid [0154] The acaricidal and / or insecticidal activity of the lecithin formulations of this example was evaluated in both the adult and immature stages of the three pests used. [0155] [0156] The acaricidal or insecticidal activity was determined in terms of percentage of mortality or mortality efficiency of red spider, thrips and aphids. Negative controls were included in the trials, that is, healthy spider, thrips or aphid populations that were only treated with distilled water. [0157] [0158] The mortality efficiencies obtained at each concentration in each pest tested were subjected to the Henderson-Tilton correction, with the following formula: [0159] [0160] % Henderson-Tilton efficiency = [1- (Td / Cd) x (Ca / Ta)] x 100 Where: [0161] [0162] Ta = n ° live individuals in the treatment before application. [0163] Td = n ° individuals alive in the treatment after the application. [0164] Ca = n ° live individuals in the control before application. [0165] Cd = n ° live individuals in the control after application. [0166] [0167] The corrected mortality efficacy results obtained were subjected to statistical tests in order to verify the statistical significance of the results. [0168] [0169] Table 2 reflects the summary of Henderson-Tilton corrected efficacy results obtained in the different trials by lecithin of 75% richness at the different concentrations on the three pests used in the trial: [0170] [0171] [0172] [0173] [0174] [0175] a) final lecithin concentrations (grams of lecithin per liter of water) [0176] [0177] Table 2. [0178] [0179] All the corrected mortality efficiencies obtained were found to be statistically significant with a significance level of 95%, therefore all concentrations were shown to have insecticidal and / or acaricidal activity at the doses tested. [0180] [0181] Compositions of soy lecithin and chitosan as inert matter in the ratio 3: 1 have been shown to have insecticidal and / or acaricidal activity on the pests used in the test at different concentrations. This activity manifests itself in the different phases of the life cycle of the insects and mites tested and allows to exercise, to a certain degree, control of the pests tested in field conditions. On the other hand, these efficiencies have been found to be equivalent to those obtained with the use of pure soy lecithin and dissolved in water at the same final concentrations.
权利要求:
Claims (28) [1] 1. Use of a lecithin as a biocide against arthropod species. [2] 2. Use of a lecithin according to the preceding claim in which the lecithin is applied in the form of a liquid composition. [3] 3. Use of a lecithin according to claim 2, wherein the liquid composition is prepared from a powdered lecithin solid formulation. [4] 4. Use of a lecithin according to claim 3, wherein said formulation comprises lecithin powder either pure or mixed with at least one inert substance. [5] 5. Use of a lecithin according to claim 4, wherein said formulation comprises lecithin powder in an amount of at least 50% by weight with respect to the total weight of the formulation. [6] 6. Use of a lecithin according to claim 4, wherein said inert substance is selected from monopotassium phosphate, monoammonium phosphate, clay, talc, potassium nitrate, ammonium sulfate, amino acids, glutamates, acetates, humates, citric acid, ascorbic acid, potassium carbonate, potassium sorbate, potassium malate, citrulline malate, urea, potassium chloride, silica gel, oxalate, zeolite, algae extracts, alginates, diatomaceous earth, xanthan gum, gum arabic, methylcellulose, agarose, acrylamide, gels, lignin, pectin, lignosulfonates, molybdates, biammonium phosphate, mica, kaolin, fructose, sucrose, chitosan, calcium hydroxide, quartz sand, sodium bicarbonate, serum, and mixtures thereof. [7] 7. Use of a lecithin according to claim 2 wherein said liquid composition comprises at least lecithin and water. [8] 8. Use of a lecithin according to the preceding claim wherein said composition comprises only lecithin and water, and the lecithin is present in a concentration equal to or greater than 0.5 grams of lecithin per liter of water. [9] 9. Use of a lecithin according to claim 7, wherein said composition comprises lecithin in a concentration equal to or greater than 0.5 grams of lecithin per liter of water. [10] 10. Use of a lecithin according to claim 7, wherein said composition comprises lecithin in a concentration greater than 1.1 grams of lecithin per liter of water. [11] 11. Use according to claim 1, wherein the lecithin is selected from soy lecithin, sunflower lecithin, rapeseed lecithin, cotton lecithin, egg lecithin and mixtures thereof. [12] 12. Use according to claim 1, wherein the arthropods are selected from insects and arachnids. [13] 13. Use according to claim 12, wherein the arachnids are mites. [14] 14. Use according to claim 11, in which the arthropods are selected from Red spider ( Tetranychus urticae), Red spider ( Tetranychus evansii), Vasates ( Aculops lycopersici), White spider ( Polyphagotarsonemus latus), Trips ( Frankliniella occidentalis), Fly White ( Bemisia tabaci), Green mosquito ( Empoasca spp), Aphid ( Macrosyphum euphorbiae), Aphid ( Myzus persicae), Aphid ( Aphis gossypii), Aphid ( Aphis fabae), Aulacartun solani, Creontiades pallidus, Bemisia tabaci (mosca) Trialeurodes vaporariorum (whitefly), capitata Ceratitis (fruit fly), Tuta absoluta (moth tomato), Icerya purchasi (grooved mealybug), Phenacoccus solani (cochineal pepper), Nezara viridula (green stink bug) and Liriomyza huidobrensis (fly miner). [15] 15. A solid lecithin formulation comprising lecithin powder, either pure or accompanied by one or more inert substances. [16] 16. A solid lecithin formulation according to claim 15, in which the inert substances are selected from monopotassium phosphate, monoammonium phosphate, clay, talc, potassium nitrate, ammonium sulfate, amino acids, glutamates, acetates, humates, citric acid, ascorbic acid, potassium carbonate, potassium sorbate, potassium malate, citrulline malate, urea, potassium chloride, silica gel, oxalate, zeolite, algae extracts, alginates, diatomaceous earth, xanthan gum, gum arabic, methylcellulose, agarose, acrylamide, gels, lignin, pectin, lignosulfonates, molybdates, biammonium phosphate, mica, kaolin, fructose, sucrose, chitosan, calcium hydroxide, quartz sand, sodium bicarbonate, serum, and mixtures thereof. [17] 17. A solid lecithin formulation according to claim 18 or 19, wherein the lecithin is present in an amount of between 50% and 100% by weight with respect to the total weight of the formulation. [18] 18. A solid formulation according to any one of claims 15 to 17, wherein the lecithin is selected from soy lecithin, sunflower lecithin, rapeseed lecithin, cotton lecithin, egg lecithin, and mixtures thereof. [19] 19. A liquid composition comprising: - a solid lecithin formulation as defined in claim 15 - and water, in which lecithin is present in a concentration comprised between 0.5 grams of lecithin and 30 g / l of water. [20] 20. A composition according to claim 19, wherein the lecithin is present in a concentration comprised between 1.1 grams of lecithin per liter of water and 10 grams of lecithin per liter of water. [21] 21. A liquid composition according to claim 19 or 20, wherein said formulation is a solid formulation comprising pure lecithin powder or lecithin powder mixed with one or more inert substances selected from monopotassium phosphate, monoammonium phosphate, clay, talc, potassium nitrate, ammonium sulfate, amino acids, glutamates, acetates, humates, citric acid, ascorbic acid, potassium carbonate, potassium sorbate, potassium malate, citrulline malate, urea, potassium chloride, silica gel, oxalate, zeolite, algae extracts, alginates, diatomaceous earth, xanthan gum, gum arabic, methylcellulose, agarose, acrylamide, gels, lignin, pectin, lignosulfonates, molybdates, biammonium phosphate, mica, kaolin, fructose, sucrose, chitosan, calcium hydroxide, quartz sand, sodium bicarbonate, serum and mixtures of them. [22] 22. A liquid composition according to any one of claims 19 to 21, wherein the lecithin is selected from soy lecithin, sunflower lecithin, rapeseed lecithin, cotton lecithin, egg lecithin, and mixtures thereof. [23] 23. Use of the solid formulation defined in one of claims 15 to 18 to prepare a liquid composition comprising lecithin in a concentration comprised between 0.05% and 1.5% by total weight of the liquid composition. [24] 24. Use of the composition defined in one of claims 15 to 18 or of the formulation defined in one of claims 19 to 22, in agriculture. [25] 25. Use according to claim 24, as biocides against arthropod species. [26] 26. Use according to claim 25 wherein the arthropods are selected from insects and arachnids. [27] 27. Use according to the preceding claim, wherein the arachnids are mites. [28] 28. Use according to claim 26, in which the arthropods are selected from Red spider ( Tetranychus urticae), Red spider ( Tetranychus evansii), Vasates ( Aculops lycopersici), White spider ( Polyphagotarsonemus latus), Trips ( Frankliniella occidentalis), Fly White ( Bemisia tabaci), Green mosquito ( Empoasca spp), Aphid ( Macrosyphum euphorbiae), Aphid ( Myzus persicae), Aphid ( Aphis gossypii), Aphid ( Aphis fabae), Aulacartun solani, Creontiades pallidus, Bemisia tabaci (mosca) Trialeurodes vaporariorum (whitefly), capitata Ceratitis (fruit fly), Tuta absoluta (moth tomato), Icerya purchasi (grooved mealybug), Phenacoccus solani (cochineal pepper), Nezara viridula (green stink bug) and Liriomyza huidobrensis (fly miner).
类似技术:
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同族专利:
公开号 | 公开日 WO2020079301A1|2020-04-23| PE20211864A1|2021-09-21| CL2021000937A1|2021-10-29| MA51607A|2020-11-25| CO2021006173A2|2021-08-09| ES2754717B2|2020-09-29| AR116708A1|2021-06-02| EP3639666A1|2020-04-22|
引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题 KR100780806B1|2006-11-18|2007-11-30|한국식품연구원|Foods with the enhanced performance of learning ability| US20080269177A1|2007-04-30|2008-10-30|Ecosmart Technologies, Inc.|Pesticidal compositions| CN107028194A|2016-11-18|2017-08-11|吉林大学|A kind of high lecithin corn peptide chewable tablets and preparation method| CN108157357A|2017-12-26|2018-06-15|陈显兵|Winged oil-proofing agent and its application containing botanical insecticidal activities| US20090285937A1|2008-05-15|2009-11-19|The Bug Company Of Minnesota|Combination water and food insect supplement| WO2016070091A1|2014-10-31|2016-05-06|Integrated Aquaculture International, Llc|Encapsulated aquaculture premix feed| CA3065143A1|2017-06-13|2018-12-20|Croda, Inc.|Agrochemical electrolyte compositions|
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申请号 | 申请日 | 专利标题 ES201830996A|ES2754717B2|2018-10-16|2018-10-16|USE OF LECITHINS AS A BIOCIDAL AGAINST ARTHROPODS|ES201830996A| ES2754717B2|2018-10-16|2018-10-16|USE OF LECITHINS AS A BIOCIDAL AGAINST ARTHROPODS| PE2021000511A| PE20211864A1|2018-10-16|2019-10-11|USE OF LECITHINS AS A BIOCIDE AGAINST ARTHROPODS| PCT/ES2019/070695| WO2020079301A1|2018-10-16|2019-10-11|Use of lecithins as a biocide against arthropods| MA051607A| MA51607A|2018-10-16|2019-10-11|USE OF LECITHINS AS A BIOCIDE AGAINST ARTHROPODS| EP19202718.3A| EP3639666A1|2018-10-16|2019-10-11|Use of lecithins as a biocide against arthropods| ARP190102930A| AR116708A1|2018-10-16|2019-10-15|USE OF LECITHINS AS A BIOCIDE AGAINST ARTHROPODS| CL2021000937A| CL2021000937A1|2018-10-16|2021-04-15|Use of lecithins as a biocide against arthropods| CONC2021/0006173A| CO2021006173A2|2018-10-16|2021-05-12|Use of lecithins as a biocide against arthropods| 相关专利
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