• 专利附录
  • 专利说明
  • 权利要求
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  • 优先权
    • 专利摘要:
    Procedure to recycle olive mill products, preparation thus obtained and uses given to it. The present invention relates to a method for recycling mill products to the preparation thus obtained and to the uses given thereto. The object of the invention is to take advantage of the residues that are formed in the mills in the production of olive oil. The present invention recycles both the liquid effluents and part of the sludge formed in the mills and the leaves of the olive tree and limestone lands of the olive farms themselves, giving rise to a composition rich in active ingredients but free of hormones, parabens, heavy metals and harmful pesticides for people, animals and the environment. The composition of the present invention will have uses in agriculture, cosmetics, pharmacy and cleaning. (Machine-translation by Google Translate, not legally binding)
    公开号:ES2609994A1
    申请号:ES201531513
    申请日:2015-10-22
    公开日:2017-04-25
    发明作者:Juan Luis Fernández De Mesa Coca；Mercedes FERNÁNDEZ DE MESA MOYANA
    申请人:Juan Luis Fernández De Mesa Coca；
    IPC主号:
    专利说明:

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    DESCRIPTION
    Procedure to recycle oil mill products, preparation thus obtained and uses given to it
    The present invention relates to a process for recycling mill products to the preparation thus obtained and to the uses given thereto.
    The object of the invention is to take advantage of the residues that are formed in the oil mills in the production of olive oil. The present invention recycles both liquid effluents and part of the sludges formed in olive oil mills and leaves and limestone lands of the olive farms themselves, giving rise to a composition rich in active ingredients but free of hormones, parabens, heavy metals and pesticides harmful to animals and the environment.
    The composition of the present invention will have uses in agriculture, cosmetics, pharmacy and cleaning.
    Background of the invention
    Various compositions obtained through processes of elimination of contaminating residues are known (especially the alperujo and sludges from evaporation rafts), which are generated in the elaboration of olive oil.
    The Spanish patent with publication number ES2116923 entitled, "Procedure for obtaining recyclable waste derived from olives" describes a procedure for recycling alpeichm residue. The procedure consists of drying the sludge from the alpeichm residue. This residue can be used as fertilizer in agriculture. It is this patent as it has been said the only treatment that is done to the sludge before being used as fertilizer is the drying and therefore the pollutants that could be presented are not eliminated.
    The international application WO2014155141 refers to a process of water recycling that comes from the production of oil by the addition of a salt and by an electrolysis process. After a complex process, recycled water is obtained.
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    From what is known in the state of the art, it follows that the use of preparations free of contaminating residues obtained by simple procedures that come from the recycling of products obtained in obtaining oil can be of great interest for agriculture.
    Description of the invention
    The inventors have developed a recycling process and a preparation obtained by said procedure that includes recycled products from the production of olive oil that has excellent properties for agriculture and regenerative properties that make it suitable for use in the areas of Cosmetics or pharmacy.
    The preparation of the invention has proved to be more effective than other preparations comprising recycled mill liquids and also has the advantage of its natural origin. The preparation is free of hormones, parabens, heavy metals and pesticides harmful to people, animals and the environment due to their zero or low percentage of these pollutants. Products have been analyzed and no presence of parabens or hormones has been found and the amount of heavy metals is less than 0.01pmm and the possible presence of pesticides is also less than 0.01 ppm.
    There is nothing described in the state of the art that suggests that the preparation of the invention may present the effects it shows.
    The procedure for obtaining the aforementioned preparation mixes the liquids and sludges that come from the evaporation rafts of the oil mills with the olive leaves and the limestone earth, after the mixing there is a basification phase and again a mixture, with This treatment facilitates the homogenization of the preparation and the oxidation-reduction reactions are favored, finally the preparation is acidified.
    Therefore, a first aspect of the invention relates to a process for recycling mill products comprising the steps of:
    a) mix liquids and sludge from the evaporation rafts of the oil mills, with olive leaves from the crushed oil mills with granulometry of 0.01cm and 0.5cm, and limestone lands in the proportion: between 70% and 90 % by weight of liquids,
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    between 1% and 10% by weight of sludge, between 0.5% and 15% of olive leaves, between 0.5% and 5% of limestone lands;
    b) fill with the mixture of stage a) a basification tank;
    c) add a base until reaching a pH between 11 and 13;
    d) homogenize by recirculation in the basification tank;
    e) add an acid until a pH between 4 to 9 is reached.
    With this procedure a preparation is obtained that in addition to taking advantage of the liquids and sludge from the mills after the recycling process, it also has olive leaves that provide all its nutrients and limestone soils that help stabilize the pH of the preparation and that They also undergo the same recycling procedure.
    Therefore, according to a second aspect of the invention this refers to a preparation obtained by the process described above.
    The preparation obtained by the process of the invention is used as a fertilizer since it has a high fertilizing, phyto-fortifying and biostimulant power. It can be used in multiple crops and for gardening and indoor plants, with the added advantages of being rich in nutrients both by recycled waters and by the addition of leaves. The preparation of the invention is a nutrient assimilation enhancer, prepared exclusively from vegetables, with presence of limestone, with vegetable components from the olive grove with high antioxidant power, rich in tocopherols and polyphenols from which excesses have been eliminated of organic matter through the process of the invention.
    The agricultural use can be as fertilizer irrigation water and useful in phytosanitary treatments such as biostimulant or if it has more presence of leaves, limestone and mud can be a semi-solid or solid fertilizer for gardening and indoor plants.
    Therefore a third aspect of the invention is the use of the preparation as defined in the claims as fertilizer.
    In the field of agriculture the administration of the preparation of the invention is possible without any additive, excipient or vehicle. It can also be applied in combination with other fertilizers. It can be used in broad types of crops in greenhouses, fruit trees
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    of bone and pipita, vineyards, olive groves.
    With the fertilizers of the invention, an increase in production is achieved, rapid rooting and broad pollination are achieved even in low-attractive flower crops.
    Another aspect of the invention is a pharmaceutical, veterinary or cosmetic composition comprising an effective amount of the preparation as defined above together with one or more pharmaceutical, veterinary or cosmetic excipients or carriers respectively.
    Finally, another aspect of the invention is the use of the preparation of the invention in cleaning.
    Detailed description of the invention
    As indicated the procedure for recycling mill products of the present invention comprises the steps of:
    a) Mix liquids and sludge from the evaporation rafts of the oil mills, with olive leaves from the crushed oil mills with granulometry of 0.01cm and 0.5cm, and limestone soils in proportion:
    between 70% and 90% by weight of liquids, between 1% and 10% by weight of sludge, between 0.5% and 15% of olive leaves, between 0.5% and 5 % of limestone lands;
    b) fill with the mixture of stage a) a basification tank;
    c) add a base until reaching a pH between 11 and 13;
    d) homogenize by recirculation in the basification tank;
    e) add an acid until a pH between 4 to 9 is reached.
    In a particular materialization the basis of step c) of the process is potassium hydroxide.
    In a preferred embodiment the homogenization of step d) is carried out for a time between 4 hours and 6 hours.
    In a preferred embodiment, the acid in e) is selected from metric acid, acetic acid, dic acid, boric acid, or ferrous sulfate heptahydrate or mixtures thereof. More
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    preferably it is selected from acetic acid or dric acid or a combination of both. In an even more preferred materialization the acid is boric acid or ferrous sulfate heptahydrate.
    In a preferred materialization the range of the Kquidos and sludge presented is between 80% and 85% by weight, and the olive leaves are between 0.5% and 2% by weight. In a preferred materialization the limestone lands are between 1% and 3%.
    In a preferred embodiment the pH of step e) is between 4 and 8. More preferably between 5 and 7.
    In a particular materialization after stage d) and before stage e) the content of the basification tank is transferred to an acidification tank.
    In a preferred materialization after step e) it is allowed to stand.
    A second aspect of the invention relates to the preparation obtained by the process and the materializations of the process of the invention described above.
    As mentioned above, the present invention relates to pharmaceutical, veterinary or cosmetic compositions comprising an effective amount of the preparation as defined above together with one or more pharmaceutical, veterinary or cosmetic excipients or carriers respectively.
    For the purpose of the present invention the term effective amount "means an amount that is sufficient to obtain the expected effect. In the case of pharmaceutical and veterinary compositions in the effective amount is" the therapeutically effective amount "and refers to the amount of the compound that when administered is sufficient to prevent the development or alleviate, one or more of the symptoms of the disease to be treated.
    The term "pharmaceutically or veterinarily acceptable excipient or vehicle - refers to acceptable veterinary or pharmaceutical materials, compositions or vehicles used in the veterinary or pharmaceutical field. They must be suitable for use in contact with human or animal tissues or organs without causing toxicity. , irritation or other problems or complications with a reasonable benefit / risk ratio.
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    The expression "excipient or cosmetically acceptable vehicle" refers to the excipient or vehicle for use in contact with the skin that does not produce toxicity, incompatibility, instability, allergies or others. Examples of these excipients or vehicles are: aloe vera juice, acid Doric, boric acid, cypress essence, rosemary essence, eucalyptus essence, linden essence, nettle essence, fennel essence, chamomile essence, chicory essence, birch essence, bardena root essence. Particularly preferred are boric acid and dric acid.
    The cosmetic compositions of the invention can be formulated in several ways that include but are not limited to: solutions, aerosols, face masks, creams, lotions, shampoos, hair conditioners, or face and body soaps.
    These cosmetic compositions of the invention can be prepared by methods well known in the state of the art. Appropriate excipients and / or vegetables and their amounts can be determined by the person skilled in the art according to the formulation that he wishes to prepare.
    As mentioned, the preparation of the invention can be used for a cosmetic purpose.
    Therefore the present invention relates to a cosmetic use of the preparation as a skin or hair care agent. The hair can improve in its structure, shine. In the same way it prevents hair loss. The cosmetic uses of the cosmetic composition of the invention can be selected among others: hair regenerator, cuticle control, calluses and cell exfoliation, facial cleansing, head and soap removal soap, lice and dandruff, hand soap, severe hand cleaning Operators, shower or bath soap, deodorant. It also removes lice and hair dandruff. It can also be used as a protector for the spread of lice by applying once a week.
    The cosmetic composition has a high degree of efficacy due to its emollient and exfoliating power since it eliminates dead cells, cracks and calluses, moisturizes the cutaneous cells and improves the appearance providing elasticity, freshness and shine. Therefore the preparation of the invention is used in moisturizers for body use of hands and skin.
    It can also be used as shower soap, bath, hands and severe cleaning of
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    Operators' hands because the antioxidants and tissue regenerators present in the preparation achieve a regeneration of the skin, sweat control and the elimination of odors.
    The pharmaceutical composition of the invention can be used as an anti-inflammatory healing, treatment of psoriasis, acne, treatment and wound healing including burns, relief of blows, bruises, sprains, preferably hospital scoriations, chafing.
    A final aspect of the invention is the use of the preparation of the invention in cleaning. It is especially indicated the preparation in cleaning of cars in dry, interior and exterior including aluminum wheels eliminated odors and insects, cleaning of motor vehicles of all kinds by hand or machine, general cleaning of buildings eliminating dirt, odors and insects, cleaning of glassware and catavinos especially in competition eliminating odors, cleaning places of public concurrence where odors, fungi, insects or mites are prevented or eliminated.
    Example 1
    The liquids were transported from the evaporation rafts of the oil mills, mixed with crushed olive leaves with granulometry of 0.4 cm, and 2% limestone soils to a basified tank.
    Deposits of basified were in a closed ship. The deposits were vertical, cylindrical with base inclined at 45 °.
    The aforementioned tanks have an outlet in the lower area and which was also used for pumping to the top, which is not completely closed. The deposits have an exit at about 15 cm high, with respect to the lowest point on the side, by the end of this phase of the process (basified), in order to transfer to the acidification tanks that will have similar characteristics to those of basified
    Once the basification tanks were filled, potassium hydroxide was added until a pH of 8 was reached. The mixture was homogenized. Sodium hydroxide was added again until the pH reached 12. It was recirculated for 5 hours.
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    The content of the basification tank was transferred to an acidification tank.
    Nordic acid was added to the neutralization tank until the pH was below 7.
    Example 2. Use as fertilizer
    The product obtained in Example 1 was used to irrigate a crop such as the olive grove that has veceria (production alternates every two years). Applying the product in the olive trees achieved the elimination of the trice and increased bi-annual production by 60%.
    Example 3. Use as semi-solid fertilizer
    The product of example 1 was mixed with sand to obtain a more solid fertilizer. In this way it served as a support in a pot of lemon tree where its fertilizing capacity was tested, giving rise to the flowering of the same that never bloomed hatia.
    This same test was repeated in different pots, 50, always obtaining very good results.
    Example 4. Hair regenerator
    With the product of Example 1 a hair regenerator was formulated by adding aloe vera juice, dric acid, boric acid, cypress essence, rosemary essence, eucalyptus essence.
    This hair regenerator is respectful with the environment, hair and scalp, parasite repellent.
    The regenerator acted by strengthening the hair follicle, continuously regenerating its fall by attenuating it by modifying the fall cycle and its number gradually increased and its volume began to increase and the depopulated areas of hair diminished and giving body to it, favoring its growth by controlling the sebaceous segregation and eliminating the dandruff and damaged parts of the different hairs so that by decreasing their fall, they increase their volume, brightness, thickness, softness and number.
    Example 5. Use for the control of calluses and scoriations
    With the product of Example 1 a cream was formulated that was applied to a group of people, 20, in order to prove the elimination of calluses. In all cases the calluses
    They disappeared after the application of the cream.
    A person with scoriations of a hip operation was treated with the cream of the present example and was relieved in the first application and eliminated the scoriations at 5 to 5 days.
    Example 6. Pharmaceutical composition
    With the product of Example 1 a pharmaceutical composition in the form of cream 10 was formulated to treat psoriasis.
    This composition was used in 6 people with psoriasis and the symptoms of psoriasis disappeared.
    15 Example 7. Cleaning composition
    A cleaning composition that was used in car cleaning was formulated with the product of Example 1.
    20 Cleaning it was very effective. The goodness and difference in effectiveness is motivated by the substitution of water for the product from the oil mills being its
    non-aggressive behavior
    权利要求:
    Claims (9)
    [1]
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    1. Procedure to recycle oil mill products comprising the stages of:
    a) Mix Kquidos and sludge from the evaporation rafts of the oil mills, with olive leaves of the crushed oil mills with granulometry of 0.01cm and 0.5cm, and limestone lands in the proportion:
    between 70% and 90% by weight of Kquidos, between 1% and 10% by weight of sludge, between 0.5% and 15% of olive leaves, between 0.5% and 5 % of limestone lands;
    b) fill with the mixture of stage a) a basification tank;
    c) add a base until reaching a pH between 11 and 13;
    d) homogenize by recirculation in the basification tank;
    e) add an acid until a pH between 4 to 9 is reached.
    [2]
    2. The method according to claim 1 wherein the base is potassium hydroxide.
    [3]
    3. The method according to claim 1 wherein the acid is selected from nitric acid, acetic acid, dric acid, boric acid, or ferrous sulfate heptahydrate or mixtures thereof.
    [4]
    4. The method according to claim 2 wherein the acid is selected from acetic acid or citric acid or a combination of both.
    [5]
    5. Preparation obtained by the procedure of claims 1-4.
    [6]
    6. Use of the preparation as defined in claim 5 as fertilizer.
    [7]
    7. A pharmaceutical, veterinary or cosmetic composition comprising an effective amount of the preparation as defined in claim 5 together with one or more pharmaceutical, veterinary or cosmetic excipients or vegetables respectively.
    [8]
    8. Use of the cosmetic composition as defined in claim 7 as a skin care agent, or as a hair care agent.
    [9]
    9. Use of the preparation of the invention according to claim 5 in compositions of
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    同族专利:
    公开号 | 公开日
    ES2609994B2|2017-12-18|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    ES2005196A6|1986-04-28|1989-03-01|Consiglio Nazionale Ricerche|Purificn. of vegetable agricultural effluents|
    BE1016600A6|2005-05-25|2007-02-06|Debillemont Paul|Treatment of liquid effluents and/or sludge, useful to prepare a solid product, which is useful in agriculture, comprises electrolysis and biomethanation of the liquid effluents and/or the sludge|
    EP1810953A1|2006-01-17|2007-07-25|Unieco Societa' Cooperativa|A method and a plant for treating waste material from olive oil production|
    EP1849756A1|2006-04-28|2007-10-31|Universidade de Tras-os-Montes e Alto Douro|A process for the treatment and recovery of residues and effluents from olive oil production units through the utilisation and reprocessing of cork industry waste|
    WO2009101455A1|2008-02-11|2009-08-20|Pantelis Xynogalas|Physicochemical method of processing liquid and semisolid wastes of olive mills using ozone |WO2019243655A1|2018-06-21|2019-12-26|Universidad De Granada|Method for producing polyols and other compounds of interest from oil mill waste|
    法律状态:
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    ES201531513A|ES2609994B2|2015-10-22|2015-10-22|Procedure to recycle oil mill products, preparation thus obtained and uses given to it|ES201531513A| ES2609994B2|2015-10-22|2015-10-22|Procedure to recycle oil mill products, preparation thus obtained and uses given to it|
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