• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    Device and procedure for obtaining a dried product from blood or derivatives. The device comprises a multiple effect evaporation system (2) under vacuum, a vertical plate vacuum dryer (3), with the presence of agitators (3a3) extending the exchange surface, an ozonator (4); and where the evaporator system (2) and/or dryer (3) use as an energy source the residual effluents of an industry. The process comprises the steps of introducing the blood into the multiple effect evaporator system that concentrates it, and sending the concentrated blood to a dryer. In the dryer the blood is removed by the action of some agitators and is subjected to the action of ozone injected by an ozonator. (Machine-translation by Google Translate, not legally binding)
    公开号:ES2601932A1
    申请号:ES201730019
    申请日:2017-01-11
    公开日:2017-02-16
    发明作者:José Manuel MAGIDE AMEIJIDE；Hiram VARELA RODRÍGUEZ
    申请人:Universidade de Santiago de Compostela；
    IPC主号:
    专利说明:

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    low temperatures, as is the case with the present invention. On the other hand, the alloys must give the agitator adequate elasticity, so that it undergoes a certain deformation when pressed against the plate, in order to increase the contact surface between both elements and therefore accelerate the heat transfer. Examples of alloys that satisfy all properties of conductivity, mechanical strength, elasticity, and also offer good corrosion resistance are the following:
    -aluminium with 2% iron and 0.6% copper.
    -aluminium with 13.5% silicon, 4% manganese and 3% nickel.
    Preferably, the dryer is entirely made of stainless steel, for example of the AISI 316L type, except the agitators, which are preferably made of aluminum alloy. Stainless steel gives a superior mechanical resistance to that of aluminum alloy, which makes it an ideal material to support the equipment's own weight, dynamic stresses and pressure differences between chambers. However, this invention makes use of the particularity that the agitators are subjected to mechanical loads lower than those of the rest of the dryer, to construct them from another material, which sacrifices mechanical resistance in favor of thermal conductivity and elasticity. The agitators are not subject to pressure differences, and the weight they have to bear is low.
    In the first chamber of the dryer circulates a fluid that provides heat for drying, and in the second chamber the blood to dry and, if necessary, a gaseous mixture that provides heat to the blood by direct contact. Each camera is divided into a set of sub-cameras connected to each other, forming a single volume. Between each two adjacent plates, there is a sub-chamber belonging to one of both cameras. As an example, considering a dryer with 10 plates, correspondingly numbered 1, 2, 3, ..., 10, between pairs 1-2, 3-4, 5-6, 7-8 and 9-10 circulates the blood to desiccant and the aforementioned gaseous mixture, and a heating fluid circulates exclusively between the complementary pairs: 2-3, 4-5, 6-7 and 8-9. These types of configurations and their operation are known in the state of the art, and no further clarification is necessary. The contemplated separation between each pair of adjacent plates is preferably of the order of several centimeters.
    In one embodiment of the invention, the adjacent plates are separated 66 mm, and eight agitators are arranged in each sub chamber, thus achieving a ratio of approximately 32m2 of exchange surface for each cubic meter of dryer, a value that approximates twice the corresponding to the same embodiment but without stirrers. An advantage
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    Drying must take place avoiding the problems of blood clotting, microbial proliferation and the emission of bad odors:
    a) Blood coagulation can occur in liquid blood. It decreases its fluidity, increases viscosity and increases the ability of blood to adhere to heat exchange surfaces, soiling them. Likewise, coagulation requires a subsequent shredding treatment, for example by means of a hammer mill.
    b) Microbial proliferations in the blood can be a public health problem. Drying is carried out under vacuum and therefore at temperatures below those usual in the industry; by way of guidance between 40 and 70ºC. In this range some microorganisms may be active, which requires biocidal measures.
    c) A common problem in the dried blood production industry is the emission of bad odors. The volatile particles resulting from the drying of the blood are usually of an unpleasant odor, requiring treatment in this regard.
    The inventors have found in ozone a chemical agent capable of solving the three previous problems very effectively. It was observed that when ozone is bubbled in liquid blood, it stops its coagulation. On the other hand, ozone is a very potent bactericidal agent, on the order of several hundred times stronger than chlorine, and its use is compatible with the food industry. In addition, ozone is very effective in destroying the volatile substances that cause odors.
    Additionally, the level of vacuum in the dryer allows to exert a bacteriostatic effect on the blood to be dried, especially against aerobic bacteria. This phenomenon is known in the food industry, for example with the product preservation technique by vacuum packaging.
    The ozone treatment is divided into two phases. The first phase is that in which the blood is liquid, and ozone is bubbled in its breast, in order to dissolve in it. In the second phase the blood has ceased to be liquid, and the ozone introduced is part of the surrounding gas atmosphere. The biocidal and anticoagulant effects of ozone are mostly concentrated in the first phase, while the deodorizing effects are concentrated in the second phase.
    In the second phase, low blood moisture is itself a biocidal factor. This phenomenon is known through any of the methods of food preservation


    by dehydration And as in the second phase, ozone has hardly any water to dissolve in, it remains in the atmosphere that envelops the blood in a pasty and / or dusty state. This atmosphere also contains volatile substances that cause odor, hence ozone acts primarily as a deodorizer in this phase.
    It is known to the person skilled in the art that the solubility of ozone in water depends, among other factors, on the concentration of ozone in the gas mixture injected into the dryer and the pressure inside. The higher concentration and pressure, the greater the solubility. For reasons of food safety, it is necessary to provide significant microbial concentrations in liquid blood. Since most of the biocidal effect of ozone will be concentrated in the first phase of drying (liquid blood), higher ozone needs are contemplated than in the second phase. For these purposes, to dissolve in the blood the desired amount of ozone, it is contemplated that in the first phase the concentration of ozone and the pressure in the dryer are greater than in the second phase. As an illustrative and non-limiting example, it is contemplated that the first phase runs under vacuum with an absolute pressure of 350 mbar and the injected gas mixture contains 400g / Nm3 of ozone; and the second phase at 150 mbar and mixed with 150 g / Nm3 of ozone.
    Depending on the needs, the source of ozone can be atmospheric air or a bottle of oxygen. The second option is considered particularly interesting during the first phase of drying, because it allows the gaseous mixture to be injected into the dryer to have ozone concentrations higher than those corresponding to the case of air.
    An additional novelty of great relevance disclosed by the present invention is the inclusion of an ozone heater. Said heater preferably acts in the second phase, to contribute to the completion of the drying process. In addition, the injection of hot ozone in the second phase helps keep the drying rate constant. In the first phase, the blood has a large amount of water, which generates a convection that accelerates heat transfer and evaporation. However, in the second phase the amount of water is less, and the blood acquires a doughy and / or powdery texture of lower density than in the first phase, because it accumulates pores of air inside. This feature reduces the heat transfer coefficient and therefore the drying rate in the second phase. One way to compensate for this and contribute to a constant speed is to accelerate drying in the second phase with the addition of hot ozonized gas.
    The heater raises the temperature of the gaseous mixture with ozone injected into the dryer, so that this heat cedes to the blood and thus contribute to its dehydration. As an example
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    Illustrative, if in the second phase of drying there is a vacuum of 150 mbar, corresponding to a boiling temperature of around 53 ° C, the ozonized mixture can be heated to 70 ° C and subsequently injected into the dryer. In this way the mixture contributes, with its contribution of thermal energy, to drying. This phenomenon is of special relevance because it allows combining in the same dryer, the technique of indirect drying, through metallic surfaces of thermal transfer (plates and stirrers), and that of direct drying (hot gas). As is known by the person skilled in the art, direct drying with hot gas significantly increases the thermal transfer surface, especially when the gas passes through the sine of a powdery product, as is the case with spray dryers. In this sense, the disclosed dryer combines both indirect and direct drying, benefiting from the advantages of spray dryers, which are direct contact.
    As for the energy sources of the evaporator system and the dryer, various possibilities are contemplated. On the one hand, conventional systems such as hot water, thermal oil or steam from a boiler can be used. But preferably, the thermal energy of those residual effluents produced in an industry that leave at a temperature higher than a certain minimum threshold is used, approximately 55 ° C. Particularly interesting, said industry will be the factory itself in which the invention that is recommended here is installed. In the case of a slaughterhouse, it is common to produce huge amounts of residual fluids at temperatures above 55 ° C. For example, the scalding waters of pigs can be found at temperatures between 60 and 80 ° C. Cleaning waters take a typical temperature of around 65ºC. Whatever their origin, the residual effluents are pollutants and have their destiny in a waste treatment plant, so their use as an energy source is of ecological relevance. Its low temperatures greatly limit its industrial applications, but vacuum processes, in the case of the present invention, allow its efficient use. As an illustrative example, if the absolute pressure in the dryer is 150 mbar, the boiling temperature of the water will be approximately 53.6 ° C. If the source of energy is the cleaning waters, which return at a temperature of 65ºC, there is a thermal differential of 65 - 53.6 = 11.4ºC, which will allow the effluent to transmit heat to the blood inside the dryer, to produce its drying empty If instead of the vacuum the dryer were at atmospheric pressure, with a boiling water temperature of around 99 ° C, the energy use of the effluent would be impossible; hence the importance of the vacuum operation of the processes of this invention.


    A more complicated case occurs when the temperatures of the residual effluents are below the aforementioned threshold of around 55 ° C. In order to continue taking advantage of thermal energy in this situation, the arrangement of a heat pump is contemplated. In it, a refrigerant fluid suitable for the food industry, such as R-134a, is circulated in a closed circuit comprising a compressor and a rolling valve. Said refrigerant fluid absorbs heat from the residual effluent, and delivers it to the evaporator system.
    or dryer, at a temperature higher than that of the effluent. To illustrate this property, the residual effluent could have a temperature of 42 ° C, and going through a heat exchanger yields thermal energy to the R-134a fluid, which passes through the same exchanger, in another chamber and at a lower temperature, for example 32 ° C. This temperature difference of 42-32 = 10 ° C allows the residual effluent to transmit thermal energy to R-134a, which will subsequently raise its temperature by compressor action, to a value above 42 ° C from the effluent, for example 65 ° C. Once at 65 ° C, the R-134a fluid travels to the dryer and yields to the blood the thermal energy that it absorbed from the effluent, which is
    15 is boiling at 53.6 ° C. Upon exiting the dryer, the R-134a fluid passes through the laminating valve, reduces its pressure and consequently lowers its temperature, up to 32 ° C already mentioned. The cycle is repeated in this way. No further explanations are deemed necessary, as this is a subject widely known to the person skilled in the art.
    In another aspect the present invention also relates to a process for the
    20 obtaining a dried product from blood or derivatives which is described below. The process for obtaining a dried product from blood or derivatives, characterized in that it comprises the following steps:
    25 a. introduction of blood into a multi-effect evaporator system, where it is concentrated;
    b. introduction of concentrated blood leaving the evaporator system in a vertical plate dryer;
    30
    C. continuous agitation of the blood in the dryer, by means of agitator mechanisms, which eliminate scale and extend the exchange surface;
    35 d. introduction of ozone inside the dryer; Y


    and. energy injection into the evaporator and / or dryer system by means of residual effluents from an industry.
    In another aspect of the process the residual effluents are circulated by a heat pump. In another aspect of the process, network water consumed by an industry is circulated as a cold fluid that condenses the vapors that leave the evaporator and / or dryer system.
    Blood drying by means of the process object of the present invention is carried out in two phases.
    to. a first phase, at a given pressure, ozone temperature and ozone concentration, which takes place at an absolute pressure of 350 mbar and in which the ozone concentration is 400g / Nm3 and the heater remains inactive; Y
    b. a second phase, after the first one, at a pressure, ozone temperature and ozone concentration with values different from those corresponding to the first phase. In a particular embodiment the second phase takes place at an absolute pressure of 150mbar, the ozone concentration is 150g / Nm3 and the heater is activated, heating the ozone to 67 ° C.
    In another aspect of the procedure the dried blood leaving the dryer is passed through a hammer mill. The raw blood is collected in an accumulation tank and then introduced into a multi-effect evaporator system. The evaporator system is optionally fed by the energy provided by residual effluents from an industry, with or without the mediation of a heat pump. The blood travels through the evaporator system, and at its exit it contains less water than at its entrance.
    In the case of batch operation, the blood that leaves the evaporator system concentrated is introduced into a tank, where it accumulates. Once the evaporator system has already processed the expected amount of blood, it stops its activity, and from the aforementioned tank begins to send blood to a dryer.


    The option is contemplated that the evaporator system condenser uses as a cold fluid the mains water consumed by an industry.
    The dryer receives liquid blood, which loses moisture until it becomes blood meal. The dryer optionally feeds on the energy provided by residual effluents from an industry, with or without the mediation of a heat pump. Throughout the process, stirring mechanisms act, which move in a rotational movement around an axis. These mechanisms remove scale, increase the thermal transfer coefficient and extend the heat exchange surface.
    A first phase of drying is distinguished, in which the blood remains in a liquid state and flows easily. In a second phase, after the first phase, the blood stops flowing easily and / or acquires greater viscosity. The possibility of a differentiated treatment for both phases is contemplated, where each phase passes to the most advantageous ozone pressure and concentration. The following differentiated treatment is particularly interesting:
    -During the first phase of drying, the biocidal and anticoagulant effects are concentrated. The vacuum pump keeps the dryer at a certain pressure and the ozonator introduces a gaseous mixture with a certain concentration of ozone.
    -In the second phase of drying the deodorizing effects are concentrated. The vacuum pump reduces the absolute pressure to a lower value than the first phase, and the ozonator reduces the ozone concentration.
    Additionally, ozone can be passed through a heater prior to entering the dryer. In this way the ozonated gas mixture contributes to the drying of the blood, in a manner similar to the operation of a spray dryer.
    It is contemplated as an option that the dryer condenser uses as a cold fluid the mains water consumed by an industry.
    Once the blood has been made flour, the possibility of passing it through a hammer mill that shreds its eventual agglomerations to obtain a powdery product is contemplated.
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    wet Evaporator systems are widely known to those skilled in the art, so that explanations about their constitution or operation are not considered appropriate. Furthermore, the present invention contemplates the possibility of installing any type of evaporator system, for example of natural or forced circulation, of long or short vertical tubes, of horizontal tubes, of falling film, etc. With a non-limiting nature of the scope, the basic features of a preferred type of exchanger system are described below.
    The evaporator system (2) consists of two evaporators in series, operating against the current. It is of natural circulation. The heat exchangers (2c and 2d) are vertical and of the type of casing and tubes. The exchangers (2c and 2d) are connected to separate steam separators (2a and 2b), which comprise de-foggers (2e and 2f). For transferring from one evaporator to another, the system (2) comprises a peristaltic pump (2g). No further explanations are necessary for being outside the essence of the invention and for being apparent to the person skilled in the art.
    The steam that leaves the evaporator system (2) passes through a condenser (8) and at its outlet is sucked by a vacuum pump (8c). The pump (8c) sucks those components that could not be condensed in the condenser (8). The operating vacuum level in the evaporator system (2) is maintained both by the action of the condenser (8) and the pump (8c). The condenser (8) is placed vertically, and the vacuum pump (8c) is conveniently located in the upper zone of the condenser (8), to avoid the suction of condensates, which accumulate by gravity in the lower zone of the condenser (8 ). The condensates are evacuated outwards by means of a centrifugal pump (8a). The cold fluid that absorbs heat from the vapor to condense is the network water consumed by an industry. This water comes at a usual temperature between 7 and 20º C, depending on the place and time of the year, and is used in large quantities by slaughterhouses, for tasks such as cleaning, sterilization, boiler feed, etc. At the outlet of the condenser (8), the mains water is at a higher temperature than the inlet. Taking into account that the meat or slaughterhouse industries need to heat a large part of the mains water they consume, this condenser (8) represents energy savings. As an example, it is typical that a slaughterhouse needs to heat 60% of the mains water it consumes at temperatures above 62 ° C, to be used as cleaning water. Mains water is driven through the condenser (8) by means of a centrifugal pump (8b).
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    centrifuge (9a), and the condensates, accumulated in the lower zone, are removed with a second centrifugal pump (9b).
    To ensure the asepsis of dried blood, the elimination of odors and prevent coagulation, an ozonator (4) is available, which introduces ozone into the dryer (3). The ozonator (4) is fed with a bottle of pure oxygen, not shown. In order to inject the ozone at the appropriate temperature for each phase of drying, it passes through a heater (5) prior to the dryer (3). The ozone that has not reacted in the dryer (3), leaves it through the vertical duct (3B2), crosses the condenser (9) and reaches an ozone destroyer (6), prior to the vacuum pump (9c) . Ozone destroyers are known to the person skilled in the art.
    A schematic drawing of the dryer (3) is shown in Figure 2, to illustrate the nomenclature used herein. The measures and proportions are exaggerated in order to increase clarity. A housing (12) can be seen, inside which a total of six heat exchange plates (13a, 13b, 13c, 13d, 13e and 13f) are housed. In this particular embodiment, an evaporation chamber (3B) is shown, through which blood circulates, and a heating chamber (3A), through which a residual effluent circulates, for example scalding water. The blood and effluent paths are indicated representatively by means of arrows; for the effluent the line thickness is thin, and for the thick blood. The separation between both chambers (3A and 3B) is watertight, so that at no time contact between the two fluids occurs. The heating chamber (3A) comprises in this particular embodiment a total of three sub-chambers (14a, 14b and 14c), which are all connected, via pipes (15), to two manifolds (3A1 and 3A2), so such that they form a single volume, said heating chamber (3A). The evaporation chamber (3B) comprises four subchambers (16a, 16b, 16c and 16d), which are also all in communication, also forming a single volume, said evaporation chamber (3B). Inside each of the subchambers (16a, 16b, 16c and 16d) of the evaporation chamber (3B), an agitator (3A3) is housed, driven by a shaft (17).
    The agitators (3A3) are welded on a rod (17a), which is fixed on the shaft (17). The rod (17a) and the axis are perpendicular, as shown in the figure. For reasons of simplicity in the drawing, in this schematic figure the agitators (3A3) do not make physical contact with the exchange plates (13a, 13b, 13c, 13d, 13e, 13f), since they have been drawn with insufficient length. In order to define the length of the stirrers (3A3),
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    权利要求:
    Claims (1)
    [1]
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    同族专利:
    公开号 | 公开日
    ES2601932B2|2017-05-25|
    EP3569296A4|2020-10-28|
    EP3569296A1|2019-11-20|
    WO2018130736A1|2018-07-19|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    EP0628331A1|1993-05-11|1994-12-14|Ultrasonic Dryer Ltd.|Spray drying system|
    WO2010097060A2|2009-02-26|2010-09-02|Svus Pharma A.S.|A method of biotechnological production of bovine hemoderivative and use of bovine hemoderivative|
    CN203985914U|2014-06-25|2014-12-10|索纳克（漯河）生物科技有限公司|The blood drying device that a kind of temperature is controlled automatically|
    DE181965C|
    US2351091A|1940-12-24|1944-06-13|Bar Peter Joachim|Apparatus for treating solids in fluids|
    US3764483A|1970-10-05|1973-10-09|B Tleimat|Rotating disk still with a hydrodynamically applied thin film|
    US4067119A|1976-10-20|1978-01-10|Glen Overton|Method of drying blood|
    DE2849862A1|1978-11-17|1980-05-29|Constantin Dipl Ing Sandu|Multistage liq. vaporising and drying system - removes water leaving dry powder using convection stages, followed by radiation drier|
    US4187617A|1978-12-18|1980-02-12|Becker James J Jr|Spray dryer|
    IT1135153B|1981-01-23|1986-08-20|Consiglio Nazionale Ricerche|PROCESS FOR MAKING BLOOD INCOAGULABLE BY PROTEOLITHIC ENZYMES AND USE OF INCOAGULABLE BLOOD TO PRODUCE A PROTEIN CONCENTRATE FROM WHOLE BLOOD|
    US5409576A|1993-07-16|1995-04-25|Tleimat; Badawi|Rotating evaporator device for the distillation or concentration of liquids|
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    ES201730019A|ES2601932B2|2017-01-11|2017-01-11|DEVICE AND PROCEDURE FOR OBTAINING A PRODUCTDESIRED FROM BLOOD OR DERIVATIVES|ES201730019A| ES2601932B2|2017-01-11|2017-01-11|DEVICE AND PROCEDURE FOR OBTAINING A PRODUCTDESIRED FROM BLOOD OR DERIVATIVES|
    EP18738496.1A| EP3569296A4|2017-01-11|2018-01-10|Device and method for obtaining a desiccated product from blood or derivatives|
    PCT/ES2018/070017| WO2018130736A1|2017-01-11|2018-01-10|Device and method for obtaining a desiccated product from blood or derivatives|
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