• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    Electroactive nanofluids based on graphene as liquid electrodes in flow cells. The invention relates to highly stable electroactive nanofluids comprising graphene-based compounds and their production processes. In addition, the present invention relates to the use of said electroactive nanofluids as liquid electrodes for energy storage in flow cells. (Machine-translation by Google Translate, not legally binding)
    公开号:ES2594508A1
    申请号:ES201530693
    申请日:2015-05-20
    公开日:2016-12-20
    发明作者:Pedro GÓMEZ ROMERO；Deepak DUBAI；Daniel GÓMEZ CASAÑ
    申请人:Consejo Superior de Investigaciones Cientificas CSIC；Institut Catala de Nanociencia i Nanotecnologia ICN2；
    IPC主号:
    专利说明:

    5
    10
    fifteen
    twenty
    25
    30
    GRAPHENE-BASED ELECTROACTIVE NANOFLUIDS AS LIQUID ELECTRODES IN FLOW CELLS
    DESCRIPTION
    The invention relates to very stable electroactive nanofluids comprising graphene-based compounds. In addition, the present invention relates to the use of said electroactive nanofluids as liquid electrodes for energy storage in flow cells.
    STATE OF THE TECHNIQUE
    Energy storage is in the midst of a revolutionary change that will make it a key factor in the emerging sustainable energy model. In fact, the electrochemical energy storage (ECES for its acronym in English) has evolved profoundly from acid, heavy and polluting lead batteries, introduced by Plante in 1859, to the latest generation of rechargeable lithium-ion batteries that dominate today. realm of consumer electronics, and the new generation of supercapacitors. But when it comes to high power applications, hydroelectric pumping, and to a lesser extent compressed air, are currently the only technologies with sufficient capacity to respond to our oversized collective power needs.
    Among ECES systems, redox flow batteries are considered the most adapted technology to address high power applications at low cost. This does not mean that they can already compete at the GW level but their design in the kW - MW range could make them good candidates for distributed storage and smart grid applications. [Dunn B. Kamath, H. Tarascon, J. M. Electrical Energy Storage for the Grid: A Battery of Choices. Science, 334, 928-935 (2011)]. In electrochemical flow cells, energy and power are disconnected thanks to the storage of electroactive compounds outside the electrochemical cell. However, the limited solubility of the electroactive species used in conventional flow battery solutions, for example vanadium salts 1-2 M in vanadium flow batteries, in turn limits their energy density. In addition, increasing energy density while maintaining low costs could make flow cells practical systems not only for storing intermittent renewable energies but also for powering electric vehicles (EV per
    5
    10
    fifteen
    twenty
    25
    30
    its acronym in English). [Leung P. et al. Progress in redox flow batteries, remaining challenges and their applications in energy storage. RSC Adv., 2, 10125-10156 (2012)].
    It should be noted that there are a few relevant publications in the bibliography that describe the use of consistent sludge or thick suspensions as electrodes for energy storage. For example, Gogotsi et al. [Presser, V. et al. The electrochemical flow capacitor: A new concept for rapid energy storage and recovery. Adv. Energy Mater. 2, 895-902 (2012)] described an electroqulmic flow condenser that employed a floating mud consisting of carbon that improved the concept introduced by Kastening et al. [Kastening B. Boinowitz, T. Heins, M. Design of a slurry electrode reactor system. J. Appl. Electrochem. 27, 147-152 (1997)]. However, consistent or thick suspension electrodes are not practical for application in flow cells due precisely to their poor flow properties. Indeed, several microparticle suspensions have been tested in various applications (including thermal) but do not measure up when it comes to an effective engineering design due to precipitation processes and / or system obstruction. SaidurR., Et al. (2011). "A review on applications and challenges of nanofluids." Renewable & Sustainable Energy Reviews 15 (3): 1646-1668
    DESCRIPTION OF THE INVENTION
    The present invention discloses electroactive nanofluids (ENF), specifically high stability graphene-based electro-nanofluids, which can be used as liquid electrodes for energy storage in flow cells.
    In the present invention, the term "nanofluid" describes a homogeneous dispersion of at least one nanomaterial with at least one dimension on a scale ranging from 100 to 102 nm in a conventional base fluid. In the present invention, said nanomaterial refers to compounds or composite materials based on graphene (GC).
    An electroactive material is a material, in the form of particles or liquid, solid or molecular, capable of accepting electrons and storing electrical energy through redox-type faradic mechanisms and / or through double-layer capacitive mechanisms and / or through pseudo-capacitive mechanisms. Thus, the term "electroactive nanofluid (ENF)" as used herein refers to a nanofluid comprising any type of electroactive material. In the ENF of the present invention, the compounds or
    5
    10
    fifteen
    twenty
    25
    30
    Graphene-based composite materials are nanomaterials and also act as electroactive materials.
    The ENFs of the present invention can be used as "fluid electrodes" in flow cells, since they behave as true liquid electrodes. Indeed, these graphene-based ENFs behave like authentic liquid electrodes with a very fast storage mechanism and announce the application of ENF in general for energy storage in a new generation of flow cells.
    The use of the ENFs of the invention as electrodes in flow cells constitutes an innovative concept within electrical energy storage systems that will attract a lot of attention for applications at the grid level due to a very attractive combination of electrochemical properties such as high capacities combined with good performance at high currents and long service life.
    The graphene-based electroactive nanofluid electrodes of the present invention have reached specific capacitance values around 170 F / g (C) with a high specific energy of 13.1 Wh / Kg (C) at a specific power of 450 W / Kg (C) and excellent coulombic efficiency of 97.6% after 1500 cycles.
    The inventors of the present invention were able to perform clinical voltamperograms with potential scans on electrodes comprising the aforementioned ENFs at scanning rates of up to 10-20 V / s.
    A first aspect of the present invention relates to an electroactive nanofluid (herein "nanofluid of the invention") characterized in that it comprises
    a) A liquid medium selected from an organic solvent or an aqueous solution of acidic, neutral or basic compounds and said liquid medium optionally comprising a surfactant, and
    b) A graphene-based compound or composite homogeneously dispersed in the liquid medium and said graphene-based compound or composite optionally comprising an electroactive material associated with graphene-based compounds.
    The term "liquid medium" or "base fluid" refers herein to a dielectric liquid medium used as a conventional liquid medium to form an electroactive nanofluid. Examples of liquid medium in the present invention are organic solvents.
    5
    10
    fifteen
    twenty
    25
    30
    such as acetonitrile, dimethylformamide and dimethylacetamide or aqueous solutions of acidic compounds, ie H2SO4, neutral, i.e. Na2SO4 or basic, i.e. KOH.
    If necessary, said liquid medium also comprises a surfactant. The term "surfactant" refers herein to any compound known to one skilled in the art that can decrease surface tension (or interfacial tension) between two liquids or between a liquid and a solid. Examples of surfactant in the present invention they are either ionic surfactants such as sodium dodecylsulfonate and MORWET D42 ™, or non-ionic surfactants such as triton X-100. Preferably, the surfactant is in a weight percentage, between 0.01 and 5% based on weight Total liquid medium.
    The term "compound or composite material based on graphene" refers herein to graphene, graphene oxide, reduced graphene oxide or a combination thereof that forms compounds or composite materials with any other molecule, polymer or solid phase, in extended form or nanoparticles.
    In another preferred embodiment of the present invention, the graphene-based compound of the nanofluid of the invention is in a weight percentage between 0.01% and 10% based on the total weight of the electroactive nanofluid.
    The electroactive nanofluids were prepared by direct mixing of compound or composite material based on graphene and the liquid medium.
    The graphene-based compound or composite optionally comprises electroactive substances bound to the graphene compound or forming a mixture by dispersion in the base fluid. Electroactive substances are those known to a person skilled in the art.
    For example, polyoxomethalate clusters can be anchored on the surface of graphene-based compounds. Therefore, a further embodiment of the present invention relates to graphene-based compounds comprising polyoxomethalate clusters that are in a weight percentage between 0.01% and 10% based on the total weight of the electroactive nanofluid. In another preferred embodiment of the present invention, the nanofluid polyoxomethalate clusters of the invention were selected from the list consisting of phosphotungstate and phosphomolibdate.
    Examples of electroactive organic compounds are quinones such as benzoquinone, naphthoquinone, anthraquinone and their derivatives.
    Examples of solid electroactive phases are hexacyanoferrates, ie KCu [Fe (CN) 6], Fe2 [Fe (CN) 6], oxides, that is MnO2, NaXMnO2, LiMn2O4, Li (NiMnCo) O2, TiO2, Li4Ti5O12 and phosphates, ie LiFePO4, LiMnPO4, Li3V2 (PO4) 3.
    Examples of electroactive polymers are polypyrrole, polyaniline, PEDOT, polyvinylcarbazole and their derivatives.
    Another preferred embodiment of the present invention relates to the electroactive nanofluid of the invention which also comprises carbon materials such as Activated Carbon (AC) or Carbon Nanotubes (CNT) apart from graphene. Each of these presents specific advantages such as low cost (AC) or anisotropla (CNT) that expand the possible applications of the nanofluids of the invention.
    Another aspect of the invention relates to the use of the nanofluid of the invention as an electrode of an electrochemical flow cell. For example, an electrochemical flow cell comprising two compartments (positive and negative) with conductive current collectors in contact with the liquid electroactive nanofluids, both compartments separated by a membrane (cationic or anionic) or a separator.
    Unless defined otherwise, all the technical and scientific terms used in this document have the same meaning as those usually understood by an expert in the field to which this invention belongs. Methods and materials similar or equivalent to those described herein may be used in the practice of the present invention. Throughout the description and the claims, the word "understand" and its variations do not imply the exclusion of other technical aspects, additives, components or stages. Additional objects, advantages and features of the invention will be apparent to those skilled in the art upon examination of the description or 25 can be learned by practicing the invention. The following examples and drawings are presented by way of illustration and are not intended to be limiting of the present invention.
    BRIEF DESCRIPTION OF THE DRAWINGS FIG 1. Spectra of GO and rGO respectively
    5
    10
    fifteen
    twenty
    25
    30
    FIG 2. (a) Graphite diffractograms, graphene oxide (GO) and reduced graphene oxide (rGO), (b) XGO spectrum of rGO, the inserted table shows the spectrum of internal CIS levels
    FIG 3. (a, b) Scanning electron microscopy (SEM) micrographs and (c, d) Transmission electron microscopy (TEM) microphotographs at two different magnifications.
    FIG. 4. (a, b) Nitrogen absorption / desorption isotherms for a rGO sample with the corresponding pore size distribution graph BJH.
    FIG. 5. Schematic diagram of the disposition of the flow cell used in example 3 in which the ENFs loaded and unloaded are stored in separate containers. Two peristaltic pumps were used with automatic control of the flow direction and flow rate. 1 Deposits 2 Pump 3 Separator 4 Cell
    FIG. 6 Cyclic Voltammetric (CV) curves of rGO electroactive nanofluids of different concentrations at a scanning speed of 20 mV / s under static conditions.
    FIG. 7 (a, b) CV curves of a rGO electroactive nanofluid of concentration 0.025% by weight at different scanning speeds starting at the slowest speed of 1 mV / s at the fastest speed of 10,000 mV / s respectively.
    FIG. 8 Cyclic voltammetric (CV) curves of (a, b) electroactive nanofluid of 0.1% rGO by weight and (c, d) electroactive nanofluid of rGO 0.4% by weight at different scanning speeds starting at slower than 1mV / s (0.001 V / s) at 10000 mV / s (10V / s). It is very remarkable that the flow electrodes based on these rGO electroactive nanofluids showed a rectangular shaped CV (typical of capacitive behavior) at the very high scanning speed of 10 V / s which confirms an excellent power density for the capacitors flow electrochemicals based on rGO electroactive nanofluids. This is the highest scan speed used to measure CV curves in flow cells.
    FIG. 9 Variation of the specific capacitance with the scanning speed for ENF of rGO of different concentrations
    FIG. 10 (a) Nyquist diagrams for rGO ENFs of different concentrations in the frequency range between 10 mHz and 10 kHz.
    FIG. 11 Galvanostatic discharge charge curves for 0.025% rGO electroactive nanofluids at different current densities under static conditions.
    FIG. 12 Power density versus energy density for rGO electroactive nanofluids in a Ragone diagram.
    5 FIG. 13 Variation of the coulombic efficiency of ENF of rGO over 1500 cycles of loading and unloading.
    FIG. 14 Chronoamperometrla for an electroactive nanofluid of rGO (0.025% by weight) at different applied voltages such as 0.2, 0.4, 0.6, 0.8 V, which shows a high coulombic efficiency of 98.2% when Charge at a potential of 0.8 V and then discharge 10 at 0 V.
    FIG. 15 Self-discharge, that is, it shows the time-dependent loss of the potential of the open circuit cell for ENF of rGO (0.025% by weight).
    FIG. 16 Clinical voltamperograms (20 mV / s) of ENF of rGO at 0.025% by weight for different flow rates.
    15 FIG. 17 Variation of the specific capacitance of RGO ENFs with the flow rate.
    FIG. 18 Nyquist diagrams for 0.025% rGO electroactive nanofluid by weight for different flow rates (10 mHz to 10 kHz frequency range).
    FIG. 19 Chronoamperometer for an electroactive nanofluid of rGO (0.025% by weight) during flow conditions at 10 ml / min showing high coulombic efficiency of 20 96.8% when charged to a 0.9 V cell potential and download later to 0
    V.
    FIG. 20 (a, b, c) Scanning electron microscope (SEM) microphotographs and (d, e, f) Transmission scanning electron microscope (TEM) microphotographs for rGO, rGO -PMo12, rGO-PW12, respectively.
    25 FIG. 21 CV curves of electrode of electroactive nanofluids (0.025% by weight) a) rGO-PW12 and b) rGO-PMo12 at different scan speeds (from 5 mV / s at the highest scan speed of 200 mV / s)
    FIG. 22 Variation of the electrode specific capacitance of electroactive nanofluids (0.025% by weight) rGO-PW12 and rGO-PMo12 with the scanning speed.
    5
    10
    fifteen
    twenty
    25
    30
    FIG. 23 Galvanostatic discharge charge curves for 0.025% by weight of electroactive nanofluids (a) rGO-PW12 and (b) rGO-PMo12 at different current densities under static conditions.
    FIG. 24 Power density versus energy density of the electroactive nanofluids rGO-PW12 and rGO-PMo12 (0.025% by weight) in a Ragone diagram.
    FIG. 25 Chronoamperometers for electroactive nanofluids (a) rGO-PW12 and (b) rGO-PMo12 at different applied voltages, such as 0.4, 0.6, 0.8, and 1.0 V showing high coulombic efficiency of 95 , 2% when charged to a cell potential of 1.0 V and subsequently discharged at 0 V
    FIG. 26 Test of electroplating and loading cycles for rGO-POM electroactive nanofluids (rGO-PW12 and rGO-PMo12) at different current densities, from 4 A / g to 16 A / g for 200 cycles.
    FIG. 27 CV curves (at 100 mV / s scanning speed) of 0.025% rGO-POM electroactive nanofluid by weight, (a) rGO-PW12 and b) rGO-PMo12) for different flow rates.
    EXAMPLES
    Example 1: reduced graphene oxide synthesis (rGO).
    Graphene oxide (GO) was synthesized from natural graphite using the modified Hummers method. In summary, 5 g of NaNO3 and 225 ml of H2SO4 were added to 5 g of graphite and stirred for 30 min in an ice bath. 25 g of KMnO4 were added to the resulting solution and then the solution was stirred for 2 h at 50 ° C. 500 ml of deionized water and 30 ml of H2O2 (35%) were added slowly to the solution, and the solution was washed with dilute HCl. In addition, the GO product was washed again with 500 ml of concentrated HCl (37%). Reduced graphene oxide (rGO) was prepared by high temperature treatment of the GO sample at 800 ° C under nitrogen atmosphere.
    The results of the Raman spectroscopy analysis are shown in Figure 1. The ratio of intensities of the D band (at 1348 cm-1) and the G band (a1591 cm-1) of Raman was D / G = 1.02 , thereby confirming the formation of reduced graphene oxide.
    The crystallographic study was carried out using a Panalytical X’pert Pro-MRD instrument (CuKalpha radiation and PIXel detector). X-ray analyzes were carried out by
    5
    10
    fifteen
    twenty
    25
    30
    X-ray photoelectronic spectroscopy (XPS, SPECS Germany, PHOIBOS 150). Figures 2a) and b) refer to (a) graphite diffractograms, graphene oxide (GO) and reduced graphene oxide (rGO), (b) XGO spectrum of rGO, the inserted box shows the spectrum of C1s at the level of core. The oxygen content in this rGO, determined by XPS was 5.8%.
    The morphological analysis of the surface of a rGO sample was carried out by scanning electron microscopy (FEI Quanta 650F Environmental SEM). TEM images were obtained with a field emission transmission electron microscope (Tecnai G2 F20 S-TWIN HR (S) TEM, FEI). See figure 3 a) - d). HRTEM revealed that rGO sheets are close to a monolayer with a very transparent appearance, while FESEM and TEM images of a sample of the material thickness showed perfectly extended layers to form a highly porous laminar structure.
    The adsorption / desorption of N2 was determined by Brunauer-Emmett-Teller (BET) measurements using a Micromeritics instrument (Data Master V4.00Q, Serial No.: 2000/2400). The results are shown in Figure 4. A clear cycle of hysteresis is observed, which is associated with the presence of a mesoporous structure related to interleaved nanolamines. In addition, rGO nanolamines exhibit pores in both the mesopore and macropore regions.
    Example 2: synthesis of rGO electroactive nanofluid.
    The electroactive nanofluids of rGO were prepared by direct mixing of the rGO with the liquid medium also called base fluid. In this analysis, the base fluid was 1 M H2SO4 in deionized water. Electroactive nanofluids with different concentrations were prepared by mixing 0.025, 0.1 and 0.4% by weight of rGO in 1 M H2SO4 aqueous solution. To obtain stable suspensions, 0.5% by weight of surfactant (triton X-) was added. 100) and the mixture was kept in an ultrasonic bath for 2 h. The resulting soles were used directly as flow electrodes in a flow cell manufactured in our laboratory and described in the text.
    The electroactive nanofluids of rGO were prepared with different concentrations (0.025, 0.05, 0.1, 0.2 and 0.4% by weight) after different time intervals. The electroactive nanofluid of rGO prepared in this way has a dark black appearance indicating a stable and uniform dispersion of the rGO in 1 M H2SO4 aqueous solution. The dispersions of rGO began to precipitate after standing for almost 10 h. and only after
    5
    10
    fifteen
    twenty
    25
    30
    from 40 h. The rainfall was complete. In addition, it is interesting to note that rGO electroactive nanofluids with low concentrations (0.025 and 0.05% by weight) remain stable for even longer. Finally all rGO electroactive nanofluids can be easily redispersed by gentle agitation, again looking similar to products prepared in this way and remaining stable for more than 5 h, which suggests a high stability of electroactive nanofluids from RGO
    Example 3: flow cell design
    The electrochemical characterization of these rGO electroactive nanofluids of example 2 was carried out both in static conditions and in continuous flow conditions using a specially designed flow cell. See Figure 5. The cell body (7 cm x 6 cm x 1 cm) was manufactured with two stainless steel plates that act as current collectors, with a 5 mm wide and 5 serpentine shaped flow channel. mm deep The two compartments of the cell were separated by a polyvinylidene fluoride (PVDF) membrane (Durapore®; Merck Millipore, Germany) and oiled paper was used as a gasket that provides a tight seal. The contact area between the ion permeable membrane and the flow electrode was 12.7 cm2. Finally, the cell was designed with the level of flow control required for testing a prototype to meet expectations for a larger-scale operating device (Effective Function Code (EFC)). In this way, peristaltic pumps were implemented for each of the positive and negative compartments, with automatic dual flow control (direct and reverse flow).
    Example 4: characterization of electrode nanofluid electrodes of rGO.
    The electrochemical performance of electrodes of electroactive nanofluids of rGO of different concentrations was investigated under static conditions by cyclic Voltammetry (CV) using the flow cell design of example 3.
    FIG 6. Shows the CV curves of symmetric cells with electroactive nanofluid of rGO with different concentrations (from 0.025% by weight to 0.4% by weight of rGO) at a scanning speed of 20 mV / s. current currents under curves increase and specific capacitances decrease as the concentration of electroactive nanofluids increases, thus showing a behavior similar to that of conventional supercapacitors with solid electrodes. The shape of the CV curves is
    5
    10
    fifteen
    twenty
    25
    30
    quasi-rectangular which indicates a dominant mechanism of capacitive type of energy storage.
    FIG 7 (a, b) shows the CV curves of electroactive nanofluid of rGO (0.025% by weight) at different scanning speeds (from 1 mV / s at the maximum speed of 10 V / s). The rectangular form of CV is maintained even at the very high speed of 10,000 mV / s; indicating that rGO electroactive nanofluids have excellent high speed performance, as required for high power supercapacitors.
    Similar results were observed even for high concentration electroactive nanofluids. FIG 8 shows curves of cyclic Voltammeters (CV) of (a, b) electroactive nanofluid of 0.1% rGO by weight and (c, d) electroactive nanofluid of rGO 0.4% by weight at different scanning rates from the lowest scan speed of 1 mV / s (0.001 V / s) to 10,000 mV / s (10 V / s). Extraordinarily, the electrode of flow based on electroactive nanofluid of rGO showed a CV of rectangular form, typical of capacitive behavior at the very high scanning speed of 10 V / s confirming an excellent power density of the electroqulmic flow condenser (EFC) based in rGO electroactive nanofluid. It should be noted that the shape of the CV curves becomes more and more rectangular as the scanning speed increases. This indicates an increasingly important relative contribution of capacitive storage (double layer) versus pseudo-capacitive (faradaic) at high speeds.
    The behavior observed for electroactive nanofluids implies that the entire volume of the liquid can be polarized, which in turn implies a percolative electronic conduction through the electroactive nanofluid, which could thus be considered as a true liquid electrode.
    Cell specific capacitance values for rGO electroactive fluids were calculated from the CV curves and are shown in FIG. 9 for the different concentrations and scan speeds tested.
    As expected, specific capacitances gradually decrease as the scan speed increases. For the electroactive nanofluid of rGO 0.025% by weight, a specific capacitance value of 169 F / g (rGO) was obtained at a scanning speed of 1 mV / s. Note that, to store that amount of charge in the rGO of the flow cell, the rGO sheets must be electrically connected to the external load through a conductive path. Unlike conventional supercapacitors in
    5
    10
    fifteen
    twenty
    25
    30
    which solid-film electrodes benefit from fixed and well-defined conduction paths, this cell uses a "liquid electrode" in which the charge must be percolated through a dynamic network of conductive particles.
    The specific capacitance values represented in FIG. 9 are comparable or even higher than the values reported for consistent sludge or thick carbon suspension.
    For example, Presser et al. [The electrochemical flow capacitor: A new concept for rapid energy storage and recovery. Adv. Energy Mater. 2, 895-902 (2012)] prepared a carbon sludge consisting of carbide powder derived from titanium carbide (TiC: CDC) and 1 M Na2SO4 with electroactive nanofluids 3: 1 and 4: 1 (electrolyte: mass carbon ). The highest specific capacitance reported for a consistent sludge of TiC: CDC with toothpaste texture (3: 1 electrolyte: carbon) was 109 F / g at a scanning speed of 2 mV / s.
    On the other hand, Zhang et al. [Zhang, C. et al. Highly porous carbon spheres for electrochemical capacitors and capacitive flowable suspension electrodes. Carbon, 77, 155164 (2014)] described a specific capacitance of 154 F / g at 2 mV / s in 1 M H2SO4 for a mud consisting of porous carbon spheres with concentrations varying between 16% and 23% by weight.
    Finally, electrochulmic impedance spectroscopy data showed a low ohmic resistance, in the range of -0.23-0.28 Q that suggests a fast ionic transport and a highly conductive network that facilitates the percolation of charge and ions, see FIG 10. These values are even lower than those described for electrodes of spherical carbon particle suspensions in the documents:
    - Hatzell, K. B. et al. A high performance pseudocapacitive suspension electrode for the electrochemical flow capacitor. Electrochim. Acta, 111, 888-897 (2013).
    - Hatzell, K. B. et al. Composite manganese oxide percolating networks as a suspension electrode for an asymmetric flow capacitor. ACS Appl. Mater. Interfaces, 6, 8886-8893 (2014).
    'Hatzell, K. B. et al. Capacitive deionization concept based on suspension electrodes without ion exchange membranes. Electrochem. Commun. 43, 18-21 (2014).
    5
    10
    fifteen
    twenty
    25
    30
    In addition, the impedance curves show a distorted semicircle in the high frequency region due to the porosity of rGO and an almost vertical linear increase in the low frequency region. The high frequency intersection of the semicircle on the real axis gives the dissolution resistance (electrolyte) (Rsol), and the diameter gives the charge transfer resistance (Rct) at the interface of the rGO electrode and the electrolyte.
    The electrochemical performance of the rGO electroactive nanofluids of Examples 2 was further studied by galvanic static charge / discharge cycles under static conditions, as shown in FIG 11. The shapes of the charge and discharge curves are symmetrical, triangular and linear for the electroactive nanofluids of rGO at all the different current densities used. For the 0.025% rGO electroactive nanofluid by weight, the specific capacitance values were 117 and 50 F / g (rGO) at current densities of 1 A / g and 2.5 A / g respectively. This corresponds to specific energy values of 5.7-13.1 Wh / kg (rGO) and specific power of 0.45-1.13 kW / kg (rGO), as shown in FIG 12.
    The specific energy values are significantly higher than those previously described for consistent sludge, for example 5.6-8.2 Wh / kg for a mud consisting of carbon beads [Campos, J. W. et al. Investigation of carbon materials for use as a flowable electrode in electrochemical flow capacitors. Electrochim. Minutes 98, 123-130 (2013)]. In addition, the electroplating cycles were stable, with cycle efficiencies greater than 97.6% after 1500 charge / discharge cycles (FIG 13).
    FIG 14 shows a series of chronoamperometric experiments carried out for electroactive nanofluids of rGO under static conditions. Initially, the cell was completely discharged over a period of 15 min and then charged to different potentials such as 0.2, 0.4, 0.6 and 0.8 V. The specific capacitances for the electroactive nanofluids of rGO were calculated. at different potentials and are in the range of 36-156 F / g (rGO), which are comparable to the values derived from the CV. The coulombic efficiency of the rGO electroactive nanofluid cell was 98.2% (FIG 14), a high value considering that the leakage current was included, a value that matches very well with the coulombic efficiency derived from the experiments static charge / discharge electroplating (98.9%).
    FIG 15 shows the time-dependent loss of potential of the open circuit cell (self-discharge) for rGO electroactive nanofluids. After 30 min of
    5
    10
    fifteen
    twenty
    25
    30
    charge to the maximum cell potential of 0.9 V the open circuit voltage dropped to 34% of the initial voltage (0.9 V) after 24 h.
    This remains comparable or even better than commercial supercapacitor cells with solid electrodes [Kaus, M. Kowal, J. Sauer, D. U. Modeling the effects of charge redistribution during self-discharge of supercapacitors. Electrochim. Minutes 55, 75167523 (2010)].
    To deepen the potential of the electroactive nanofluids described in example 2 for application in flow cells, the electrochemical properties of electroactive nanofluids of rGO under continuous flow conditions were also investigated. FIG 16 shows CV curves of a 0.025% rGO electroactive nanofluid by weight (at a scan rate of 20 mV / s) for different flow rates. It is interesting to appreciate that the shape of the CV curves remains identical for the different flow rates used, which confirms the uniform and stable nature of the electroactive nanofluid. However, the current under the curves increases as the flow rate increases between 0 and 10 ml / min, but then begins to decrease for flow rates> 10 ml / min.
    The variation of the specific capacitance values with the flow rate is presented in FIG 17. It can be seen how those values increase from 31 to 48 F / g (rGO) as the flow rate increases from 0 to 10 ml / min, but then decrease for higher flow rates. This initial increase in specific capacitance can be attributed to the flow of new rGO nanoparticles that take part in charge storage. However, at high flow rates and in the experimental conditions used, the residence time of the rGO nanoparticles in the flow channels will eventually be insufficient to allow full loading of all dispersed material, consequently causing a decrease in capacitance. specific. It should be noted, however, that this derivation effect ("bypassing") could take place at much higher flow rates, through an optimized design of the electrochemical cell, for example with current collectors with greater surface area.
    In addition to this, high flow rates can also cause a detrimental increase in resistance (contact resistance, friction resistances, and between particles). This is confirmed by potentiodynamic electrochemical measurements (PEIS) measurements shown in FIG 18. It was found that the resistance
    5
    10
    fifteen
    twenty
    25
    30
    interfacial associated with the interface of the current collector and the electroactive nanofluid of rGO constitutes a large part of the total resistance of the cell.
    In addition, when compared with static charge-discharge experiments, there is a slight decrease in coulombic efficiency in cycles under flow conditions (96.8%) (FIG 19). This can also be attributed to the increase in interfacial resistance under flow conditions. However, these preliminary experiments with flow confirmed that EGO cells based on rGO electroactive nanofluids work very promisingly during flow conditions.
    Example 5: synthesis of rGO electroactive nanofluids with polyoxometalate (POM).
    Two different hybrid materials based on rGO and polyoxomethalates (POM) i) rG O-phosphotu ng stato (H3PW12O40) (abbreviated, rGO-PW12) and ii) rGO-phosphomolibdate (H3PMo12O40) (abbreviated, rGO-PMo12) were prepared. In summary, two samples of 0.25 g each of rGO were dispersed in 100 ml of deionized water in two different beakers with an ultrasonic sonic probe (1500 W of power) for 2 h. Then, 10 mM of each of phosphotungstic acid (H3PW12O403H2O, (PW12) and phosphomollbodic acid (H3PMo12O40.3H2O, (PMo12)) were added to the beakers of the preset rGO solutions. These suspensions were additionally sonicated for an additional 5 h and were maintained at room temperature for the next 24 h. Subsequently, these products were filtered off separately and dried in a vacuum oven at 80 ° C overnight. The resulting products were labeled as rGO-PW12 and rGO-PMo12, for the synthesis of phosphotungstic and phosphomollbodic acids, respectively.
    Hybrid electroactive nanofluids of rGO-POM were prepared by direct dispersion of rGO-PW12 and rGO-PMo12 solids in water. In particular, for application as a flow electrode, the solids were dispersed in an aqueous H2SO4 electrolyte. Thus, hybrid electroactive nanofluids were prepared by mixing 0.025% by weight of rGO-PW12 and rGO-PMo12 separately in a 1 M aqueous solution of H2SO4. In order to obtain a stable suspension, 0.5% by weight of surfactant (triton X-100) was added and the mixture was kept in ultrasonic bath for up to 2 h.
    FIG 20 (a, b and c) shows SEM images of samples of rGO, rGO-PMo12 and rGO-PW12 respectively, while FIG 20 d), e) and f) show high resolution images of scanning TEM (STEM) , which show complete and homogeneous coverage
    5
    10
    fifteen
    twenty
    25
    30
    of the POM clusters on rGO (FIG 20 e) and f)) that are perceived as tiny minuscule nuggets (1 nm in size) on graphene sheets.
    Example 6: characterization of electrode electrode nanofluids from POMRGO.
    The electrochemical characterization of the electro-active nanofluids of POM-rGO of Example 5 was carried out both under static and continuous flow conditions using the flow cell described in Example 4.
    FIG 21 shows the CV curves of an electrode based on electroactive nanofluid of a) rGO-PW12 and b) rGO-PMo12 (0.025% by weight) at different scanning speeds (between 5 mV / s and 200 mV / s). It should be noted that the forms of these CVs are not rectangular, which confirms the contribution of the redox activities of the POM clusters. In addition, the shape of the CV curves remains unchanged even at the high scanning speed of 200 mV / s, which indicates that rGO-POM electroactive nanofluids have excellent performance at high speeds, as needed for supercapacitors of High power.
    The cell specific capacitance values for electroactive nanofluids based on rGO-POM (example 5) were calculated from the CV curves and are shown in FIG 22 for nanofluid of rGO-PW12 and rGO-PMo12 of constant concentration (0.025 % by weight) at different scan speeds.
    The specific capacitances gradually decrease as the scanning speed increases. Interestingly, specific capacitance values of 273 F / g (rGO-PW12) and 305 F / g (rGO-PMo12) were obtained for electroactive nanofluids of 0.025% rGO-POM by weight at scanning speeds of 5 mV / s. The specific capacitance values shown in FIG 22 are comparable or even considerably higher than the values described for solid carbon-POM nanocomposite solid electrodes in conventional supercapacitors.
    For example, in the recent investigation by P. Gomez-Romero et al. [Hybrid energy storage: high voltage aqueous supercapacitors based on activated carbon-phosphotungstate hybrid materials, Mater. Chem. A, 2014, 2, 1014] a specific capacitance of 254 F / g for solid compounds of activated carbon-PW12 was described, while in another publication [Hybrid electrodes based on polyoxometalates-
    5
    10
    fifteen
    twenty
    25
    30
    carbon for electrochemical supercapacitors] the specific capacitance value obtained for a solid activated carbon-PMo12 electrode was 183 F / g.
    The electrochemical performance of the electroactive nanofluids of rGO-POM described in example 5 was further studied by charge / discharge cycles under static conditions as shown in FIG 23 a) rGO-PW12 and b) rGO-PMo12. The shapes of the charge-discharge curves do not have the ideal triangular and linear appearance for the electroactive nanofluids of rGO-POM at all the different current densities used. For the 0.025% rGO-POM electroactive nanofluid by weight, the specific energy values obtained are in the range of 7-28.8 Wh / kg (rGO-PW12) and 9.3-30.9 Wh / kg ( rGO-PMo12), while the specific power for both electroactive nanofluids is 2-8 kW / kg (rGO-POM), as shown in FIG 24.
    FIG 25 shows a series of chronoamperometric experiments carried out for electroactive nanofluids of a) rGO-PW12 and b) rGO-PMo12 under static conditions. Initially, the cell was completely discharged for a period of 15 min and then charged to different potentials such as 0.4, 0.6, 0.8 and 1.0 V. The specific capacitances were calculated for both rGO electroactive nanofluids. -POM at different potentials and are in the range of 124-242 F / g (rGO-PW12 and 143-293 F / g (rGO-PMo12), which are comparable to the values derived from the CVs. It was discovered that efficiency The coulombic of the rGO-POM electroactive nanofluid cell was between 98.3 and 98.7% (FIG 25), a high value since the leakage current was included.
    In supercapacitors, clinical life is a very important parameter. FIG 26 shows the cyclic stability of rGO-POM electroactive nanofluids that was investigated by electroplating / loading tests at different current densities, from 4 A / g to 16 A / g for 200 cycles. It is interesting to note that both liquid electrodes based on rGO-POM have a stability in the range of 92-94% after 2000 cycles.
    In addition, the electroactive nanofluids described in Example 5 to be applied in flow cells, to investigate the electrochemical properties of electroactive nanofluids of rGO-POM under continuous flow conditions. FIG 27 a) rGO-PW12, b) rGO-PMo12 shows CV curves (at scanning speeds of 100 mV / s) of 0.025% rGO-POM electroactive nanofluid by weight for different flow rates. It is interesting to note that the shape of the CV curves remains identical for the different flow rates used,
    which confirms the stable and uniform nature of the electroactive nanofluid of rGO-POM. However, the current under the curve increases slightly with the increase in flow rate from 0 to 10 ml / min and then decreases slightly for flow rates> 10 ml / min.
    The slight variation of the current density can be attributed to the flow of new 5 rGO-POM nanoparticles that take part in the load storage. However, at higher flow rates and in the experimental conditions used, the residence time for rGO-POM particles in the flow channels will eventually be insufficient to allow a full load of all dispersed material, thereby causing a decrease of specific capacitance. In addition to this, during the high-flow process, the redox species in rGO-POM (example 5) may not have time to complete their oxidation or reduction, which would reduce the current under curves accordingly.
    权利要求:
    Claims (10)
    [1]
    5
    10
    fifteen
    twenty
    25
    30
    1. An electroactive nanofluid characterized in that it comprises
    a) a liquid medium selected from an organic solvent or an aqueous solution of acidic, neutral or basic compounds and said liquid medium optionally comprising a surfactant, and b) a compound or composite material based on graphene, homogeneously dispersed in the liquid medium, and said graphene-based compound or composite optionally comprising an electroactive substance associated with the graphene-based compound or composite.
    [2]
    2. The electroactive nanofluid according to the preceding claim, wherein the liquid medium is an organic solvent selected from the list consisting of acetonitrile, dimethylformamide and dimethylacetamide.
    [3]
    3. The electroactive nanofluid according to the preceding claim, wherein the surfactant is in a weight percentage between 0.01% and 5% based on the total weight of the liquid medium.
    [4]
    4. The electroactive nanofluid according to any one of claims 1 to 3, wherein the graphene-based compound is in a weight percentage between 0.01% and 10% based on the total weight of the electroactive nanofluid.
    [5]
    5. The electroactive nanofluid according to the preceding claim, wherein the graphene-based compound is in a weight percentage between 0.025% and 0.4% based on the total weight of the electroactive nanofluid.
    [6]
    6. The electroactive nanofluid according to any one of claims 1 to 5, wherein the graphene-based compound further comprises polyoxomethalate clusters as the electroactive material.
    [7]
    7. The electroactive nanofluid according to the previous claim in which the polyoxometalate clusters are in a weight percentage between 0.01% and 10% based on the total weight of the electroactive nanofluid.
    [8]
    8. The electroactive nanofluid according to any of claims 6 or 7, wherein the polyoxometalate clusters are selected from the list consisting of phosphotungstate and phosphomolibdate.
    [9]
    9. The electroactive nanofluid according to any one of claims 1 to 8, comprising activated carbons or carbon nanotubes.
    [10]
    10. The use of the electroactive nanofluid according to any one of claims 1 to 9 as an electrode of an electrochemical flow cell.
    类似技术:
    公开号 | 公开日 | 专利标题
    Chen et al.2016|One-pot synthesis of hollow NiSe–CoSe nanoparticles with improved performance for hybrid supercapacitors
    Guan et al.2016|Capacitive and non-capacitive faradaic charge storage
    Xu et al.2018|Mesostructured CuCo2S4/CuCo2O4 nanoflowers as advanced electrodes for asymmetric supercapacitors
    He et al.2019|Construction of Longan–like hybrid structures by anchoring nickel hydroxide on yolk–shell polypyrrole for asymmetric supercapacitors
    Zhao et al.2017|Amorphous/crystalline hybrid MoO 2 nanosheets for high-energy lithium-ion capacitors
    Zhai et al.2013|3D MnO 2–graphene composites with large areal capacitance for high-performance asymmetric supercapacitors
    Huang et al.2014|Hierarchical NiO nanoflake coated CuO flower core–shell nanostructures for supercapacitor
    Su et al.2015|Asymmetric electrochemical supercapacitor, based on polypyrrole coated carbon nanotube electrodes
    Qu et al.2014|An asymmetric supercapacitor with highly dispersed nano-Bi2O3 and active carbon electrodes
    Zhu et al.2015|An electrochemical exploration of hollow NiCo2O4 submicrospheres and its capacitive performances
    Lei et al.2013|A high-energy-density supercapacitor with graphene–CMK-5 as the electrode and ionic liquid as the electrolyte
    Kim et al.2014|Development of high power and energy density microsphere silicon carbide–MnO 2 nanoneedles and thermally oxidized activated carbon asymmetric electrochemical supercapacitors
    Zhang et al.2013|A high-performance supercapacitor-battery hybrid energy storage device based on graphene-enhanced electrode materials with ultrahigh energy density
    Wan et al.2014|Effects of electrode mass-loading on the electrochemical properties of porous MnO2 for electrochemical supercapacitor
    Zhao et al.2015|Design and synthesis of three-dimensional hierarchical ordered porous carbons for supercapacitors
    Balasingam et al.2017|Freeze-dried MoS 2 sponge electrodes for enhanced electrochemical energy storage
    Patil et al.2016|Ag: BiVO 4 dendritic hybrid-architecture for high energy density symmetric supercapacitors
    Sun et al.2016|Rational design of uniformly embedded metal oxide nanoparticles into nitrogen-doped carbon aerogel for high-performance asymmetric supercapacitors with a high operating voltage window
    Tang et al.2017|Functionalized carbon nanotube based hybrid electrochemical capacitors using neutral bromide redox-active electrolyte for enhancing energy density
    Abbas et al.2016|Preparation of mesoporous microspheres of NiO with high surface area and analysis on their pseudocapacitive behavior
    Sun et al.2015|Hydrothermal synthesis of a MnOOH/three-dimensional reduced graphene oxide composite and its electrochemical properties for supercapacitors
    Tran et al.2017|Three-dimensionally assembled Graphene/α-MnO2 nanowire hybrid hydrogels for high performance supercapacitors
    Deshmukh et al.2013|Synthesis and electrochemical performance of a single walled carbon nanohorn–Fe 3 O 4 nanocomposite supercapacitor electrode
    Li et al.2016|Core–shell structured CeO 2@ MoS 2 nanocomposites for high performance symmetric supercapacitors
    Li et al.2018|Embedding hollow Co3O4 nanoboxes into a three-dimensional macroporous graphene framework for high-performance energy storage devices
    同族专利:
    公开号 | 公开日
    EP3299338A4|2019-05-01|
    EP3299338A1|2018-03-28|
    US20180158622A1|2018-06-07|
    ES2594508B1|2017-09-27|
    WO2016185071A1|2016-11-24|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    EP3865454A3|2009-05-26|2021-11-24|Belenos Clean Power Holding AG|Stable dispersions of single and multiple graphene layers in solution|
    WO2012006657A1|2010-07-14|2012-01-19|Monash University|Material and applications therefor|
    CN102942906B|2012-11-28|2015-04-01|上海第二工业大学|High thermal conductivity and low viscosity water base composite heat conductivity filler nanofluid and preparation method thereof|
    WO2014183028A2|2013-05-10|2014-11-13|Timofeeva Elena V|Rechargeable nanoelectrofuel electrodes and devices for high energy density flow batteries|
    CN104016337B|2014-06-13|2015-08-12|吉林大学|A kind of method adopting multi-metal oxygen cluster mixture to prepare graphene dispersing solution|CN111029164B|2019-12-16|2021-06-04|太原理工大学|Phosphomolybdic acid/polymer/carbon nanotube composite conductive hydrogel, preparation method and application in all-solid-state flexible supercapacitor|
    法律状态:
    2017-09-27| FG2A| Definitive protection|Ref document number: 2594508 Country of ref document: ES Kind code of ref document: B1 Effective date: 20170927 |
    2021-10-04| FD2A| Announcement of lapse in spain|Effective date: 20211004 |
    优先权:
    申请号 | 申请日 | 专利标题
    ES201530693A|ES2594508B1|2015-05-20|2015-05-20|GRAPHENE-BASED ELECTROACTIVE NANOFLUIDS AS LIQUID ELECTRODES IN FLOW CELLS|ES201530693A| ES2594508B1|2015-05-20|2015-05-20|GRAPHENE-BASED ELECTROACTIVE NANOFLUIDS AS LIQUID ELECTRODES IN FLOW CELLS|
    US15/575,622| US20180158622A1|2015-05-20|2016-05-18|Graphene-based electroactive nanofluids as liquid electrodes in flow cells|
    EP16795939.4A| EP3299338A4|2015-05-20|2016-05-18|Graphene-based electroactive nanofluids as liquid electrodes in flow cells|
    PCT/ES2016/070371| WO2016185071A1|2015-05-20|2016-05-18|Graphene-based electroactive nanofluids as liquid electrodes in flow cells|
    [返回顶部]