• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    The method of the invention comprises steps of depositing a protective layer (3) on a support (1), of removing material consisting in making an opening (4) through the protective layer (3), for removing material consisting in forming a cavity (5) in said support (1), the cavity (5) being positioned in line with at least part of the opening (4) through the protective layer (3 ), depositing material (6) through said opening (4), and eliminating the protective layer (3). The material removal steps consisting in respectively making the opening (4) through the protective layer (3) and the cavity (5) are carried out simultaneously or directly one after the other using femtosecond pulses.
    公开号:CH708947B1
    申请号:CH01853/14
    申请日:2014-12-02
    公开日:2020-04-30
    发明作者:El Garrag Mourad；Saucy Clément；Oliveira Alexandre
    申请人:Rolex Sa；
    IPC主号:
    专利说明:

    The present invention relates to a method of manufacturing a timepiece component.
    The manufacture of a timepiece component intended to be integrated into a watch may include the production of decorative elements on said component, in particular in the case of a blank. These decorative elements can for example represent a name, a logo and / or a manufacturing motif, a caliber number, a number of stones, or any other distinctive element. They can be engraved by machining or by chemical engraving. Pre-masking of areas not to be etched is generally necessary. To this end, a layer of photosensitive resin is deposited on the surface to be etched, then the areas to be etched are released, by UV exposure and development of the resin. After having engraved the decorative elements, a metal or metallic alloy or other material is deposited in the engraving background, in order to achieve a color contrast between the blank and the engraving background. The resin is then removed. The blank is most often made of brass and coated with an aesthetic and / or functional coating, produced for example by rhodium plating or gilding.
    Document EP1070999 describes a method of surface shaping of a part of a timepiece movement. According to this method, the workpiece is first coated with a continuous coating, or covering, of photosensitive resin. Then, by UV exposure and development of the resin, predefined parts of the part are released, in particular for the formation of patterns. The exposed parts are then treated, for example, by etching by chemical means, or alternatively by galvanic, PVD (physical vapor deposition) and / or CVD (chemical vapor deposition) deposition on the non-etched surface. .
    Such methods prove ultimately relatively complex. The present invention improves the situation.
    To this end, the invention relates to a method of manufacturing a timepiece component, comprising the following steps:<tb> • <SEP> deposit of a protective layer on a support;<tb> • <SEP> removal of material consisting in making an opening through the protective layer,<tb> • <SEP> removal of material consisting in forming a cavity in said support, the cavity being positioned in line with at least part of the opening through the protective layer,<tb> • <SEP> deposit of material through said opening, and<tb> • <SEP> elimination of the protective layer, characterized in that the material removal steps consisting in respectively making the opening through the protective layer and the cavity are carried out simultaneously or directly one after the other using femtosecond pulses.
    Thanks to the invention, the ablation of resin and the production of a cavity in the support are carried out by the same means, namely femtosecond pulses, simultaneously or directly one after the other (it that is to say successively, without any intermediate operation except for a possible temporary stop of the femtosecond pulses to modify the emission parameters of these pulses). Thus, two separate operations are carried out by the same means and / or using the same equipment, at the same time or successively (directly one after the other). Thanks to this, the production of colored engravings on a watch component, for example, is greatly simplified.
    In addition, the method of the invention offers great flexibility of implementation.
    We also note that the treatment with femtosecond pulses offers great precision whatever the material treated. This is particularly advantageous for treating successive layers of different materials, and in particular forming an opening through the resin and a cavity in the support with constant precision.
    Advantageously, the femtosecond pulses are pulses of duration less than 1 picosecond produced by femtosecond laser equipment.
    In a particular embodiment, the femtosecond pulses acting to produce the opening through the protective layer and the femtosecond pulses acting to produce the cavity in the support are produced by the same femtosecond laser equipment. The use of the same laser equipment to deliver the femtosecond pulses impacting the protective layer and those impacting the support makes it possible to simplify the implementation of the method.
    Advantageously, the protective layer is a photosensitive resin.
    In this case, and advantageously still, the method comprises a step of polymerization of the resin by UV exposure.
    Once polymerized, the resin offers better adhesion to the support.
    The resin can be deposited by known deposition techniques, such as for example deposition by electrophoresis and deposition by centrifugal coating.
    As a non-limiting alternative, the protective layer is a metal layer, or a layer formed by an electrically insulating material, such as an oxide.
    The deposition of material in the cavity can be carried out in a known manner, such as by using one of the techniques of the group comprising a galvanic deposition, a chemical vapor deposition, a physical vapor deposition and a deposition of atomic layers.
    In a first embodiment, the support comprises a surface of the timepiece component and the step of depositing material through the opening consists in depositing a decoration material in the cavity forming a recess.
    In this case, and advantageously, the opening through the protective layer releases a rim around the recess at the surface of the timepiece component, and in that, during the step of depositing the material of decoration, said decoration material is deposited on the rim.
    In a second embodiment, during the steps of removing material from the protective layer and from the support, a mold is produced having at least a first depth equal to the thickness of the protective layer and to the minus a second depth equal to the thickness of the protective layer increased by the depth of a cavity in the support.
    Advantageously, during the material deposition step, a metal or metal alloy forming the horological component is deposited in said mold, then the horological component is removed from the mold by eliminating the protective layer and detaching the support.
    Advantageously also, during the material deposition step, the mold is filled and an additional layer of metal or metal alloy of the timepiece component is deposited on the protective layer, and in that a step is provided subsequent upgrade consisting in eliminating said additional layer.
    In a third embodiment,<tb> • <SEP> during the steps of removing material from the protective layer and from the support, at least one cavity for receiving an insert is produced in the support, the mouth of which communicates with the opening through the protective layer, the latter releasing part of the support around said mouth;<tb> • <SEP> the insert is placed in said cavity, said insert projecting out of the cavity into the opening through the protective layer;<tb> • <SEP> during the material deposition step, a metal or metal alloy is deposited through said opening,<tb> • <SEP> then we unmold the timepiece component integrating the insert by eliminating the protective layer and detaching the support.
    In a fourth embodiment, the support comprising a substrate on which at least a first timepiece component element is deposited:<tb> • <SEP> during the deposition step, the protective layer is deposited on the support so as to completely cover the first element,<tb> • <SEP> during the steps of removing material from the protective layer and from the support, an opening is made through the protective layer and a recess in the first timepiece component, said opening releasing the recess, an edge of the recess and a portion of the substrate adjacent to the first timepiece component, and forming a mold comprising the recess, said edge and said portion of adjacent substrate;<tb> • <SEP> during the material deposition step, metal or a metal alloy is deposited in said mold in order to form a second element of the horological component;<tb> • <SEP> then the watch component comprising the first and the second element is removed from the mold by eliminating the resin and detaching the substrate.
    The invention will be better understood using the following description of several exemplary embodiments of the method for manufacturing a timepiece component according to the invention, with reference to the accompanying drawings in which:FIGS. 1A to 1E represent different steps of a first embodiment of the method of the invention;FIGS. 2A to 2E represent different stages of a second embodiment of the method of the invention;FIGS. 3A to 3G represent different steps of a third embodiment of the method of the invention;FIGS. 4A to 4G represent different steps of a fourth embodiment of the method of the invention;FIGS. 5A to 5E represent different stages of a fifth embodiment of the method of the invention;FIG. 6 represents a decorative element produced using a variant of the method shown in FIGS. 1A-1E.
    Each group of figures (1A-1E; 2A-2E; 3A-3G; 4A-4G; 5A-5E) is an example of implementation of an embodiment, showing a sectional view of the component at during different stages. Identical, analogous or corresponding elements shown in the different figures have the same references.
    According to a first embodiment, described with reference to Figures 1A to 1E, the method of manufacturing a timepiece component of the invention allows one or more patterns to be engraved on the timepiece component and to color this or these reasons. The horological component here comprises a part or substrate or support 1 of complex shape, intended for example for the production of a blank, such as a plate or a bridge, or even of a dial, or also of a clothing element. watchmaker, such as a bezel, a box, a crown, a flange, a case back, or a bracelet element.
    In a first preliminary step (Figure 1A), the workpiece or support 1 is prepared for subsequent processing. The external surface 2 of the part 1 is in particular cleaned and degreased in a known manner.
    A protective layer 3, for example made of resin, is then deposited, for example by electrophoresis, on the external surface 2 of the part 1, during a second step (FIG. 1B). The thickness of the resin layer is for example between 10 and 30 μm. The resin here is photosensitive. Instead, another suitable material could be used to form a protective layer covering the part 1. Thanks to the treatment applied during the first step, the adhesion of the protective layer 3 to the surface 2 of the support 1 is improved. As a variant, the deposition of the protective layer could also be carried out by dipping, by centrifugal coating or by any other suitable deposition technique.
    The second deposition step is here followed by a third light exposure step, during which the deposited resin layer is exposed to UV rays which have the effect of polymerizing the resin. The polymerization ensures better adhesion of the resin to the support (part 1), better resistance during any subsequent treatments such as for example galvanic deposition or cleaning with the use of ultrasound. The resin used is for example a negative type resin, for example the product sold under the name Eagle 2100 ED. This third stage of UV exposure is however optional. Alternatively, the resin could be polymerized by heat treatment.
    The method then comprises a fourth step of removing material by femtosecond laser treatment (Figure 1C).
    By "femtosecond laser treatment", which could also be called "treatment by femtosecond pulses", is meant a treatment consisting in applying a beam of femtosecond pulses produced by a femtosecond laser on an area to be treated. A "femtosecond" pulse, also known as an "ultra-brief" pulse, is a propagating sinusoidal oscillation of the electromagnetic field (of frequency possibly variable in time), amplitude modulated by an envelope whose characteristic duration is small compared to 1 picosecond ( 1 picosecond = 1 ps = 10 <-12> second), typically between a few femtoseconds and a few hundred femtoseconds (1 femtosecond = 1 fs = 10 <-15> second).
    The femtosecond laser treatment carried out during the fourth step consists in emitting, using femtosecond laser emission equipment, femtosecond pulses impacting in a targeted manner the resin 3 and the part 1. It makes it possible to remove a predefined, localized part of the resin 3 and engrave the part 1.
    More specifically, the fourth step comprises:a first substep, during which an opening 4 is made through the protective layer 3 by femtosecond laser treatment,a second sub-step, during which a cavity 5, forming a recess, or etching, and positioned in line with the opening 4, is produced in the part 1, by femtosecond laser treatment.
    The through opening 4 and the cavity 5 in the part 1 are produced successively, directly one after the other, by the same femtosecond laser emission equipment. By the term "directly" one after the other, it is meant to mean that the two sub-steps indicated above are implemented successively and without an intermediate step, apart from a possible temporary stop of the femtosecond pulses to modify the parameters of laser emission adjustment such as the number of passes of the laser beam, the scanning speed, the emission power, or even the diameter of the laser beam.
    As an illustrative example, the femtosecond laser treatment used has the following characteristics:the wavelength of the laser is of the order of 1030 nm;the duration of the pulses is of the order of 320 fs (femtosecond, or 10 <-15> of a second);the repetition frequency is typically between 1 and 600 kHz, for example of the order of 100 kHz or of the order of 500 kHz;the power on target is typically in the range from 1 to 20W, for example of the order of 2W or of the order of 16W;the average fluence per pulse is typically greater than 1 10 <13> W / cm <2>, for example of the order of 1.3 10 <13> W / cm <2> or 2.5 10 <13> W / cm <2>;the recovery rate between two successive impacts of the laser beam is around 95%.
    Alternatively, the two substeps of making the opening 4 through the resin layer 3 and etching the part 1 to form the cavity 5 could be implemented simultaneously. In this case, the same laser beam could be used to remove material both from the resin layer 3 and from the part 1.
    Note that the femtosecond pulses acting to etch the resin 3 and the femtosecond pulses acting to etch the support 1 are here produced by the same femtosecond laser equipment. One could possibly consider using two femtosecond laser equipment or the same equipment emitting two distinct laser beams of femtosecond pulses, such as for example the same equipment with a beam splitter and a frequency doubler or tripler to change the wavelength from one of the beams.
    The fourth material removal step can be repeated several times, the relative position between the part 1 and the laser equipment can be modified between successive iterations, in order to produce a plurality of cavities, or recesses, in the part 1. In the illustrative embodiment shown in FIG. 1C, four cavities have been made in part 1.
    Each recess 5 includes vertical side walls and a horizontal bottom. One could however consider engraving other forms of recess, such as in particular hollows with a non-rectangular profile, for example hollows of concave shape.
    The different recesses can have different respective depths, the desired depth of each recess being obtained by adapting the operating parameters of the laser emission equipment (in particular the number of passages of the laser beam over the area to be etched and scanning speed). The depth of the recesses is for example between 80 and 120 μm.
    The material removal step is followed by a fifth step of adding or depositing material (Figure 1D). In the particular example described here, a galvanic treatment is implemented to deposit a decorative coating 6 of metal or metal alloy, at the bottom of each recess 5. Another material could be used, such as an oxide, a carbide and / or a nitride. We could also use another deposition technique such as a physical vapor deposition called "PVD" (from the English "Physical Vapor Deposition"), a chemical vapor deposition called "CVD" (from the English " Chemical Vapor Deposition “) or an atomic deposit called“ ALD “(from the English“ Atomic Layer Deposition “). Another technique could also be used, such as a conversion technique such as anodization. We could also use other materials, such as a paint, or even a lacquer. The thickness of the coating 6 deposited in each recess 5 may be equal to, less than or greater than the depth of the recess 5, depending on the desired aesthetic appearance.
    The method finally includes a sixth step of removing the resin 3 (Figure 1E). Resin 3 is removed in the usual way, according to the recommendations of the resin manufacturer.
    The method could also include a leveling step by polishing the surface 2.
    As an illustrative example, the part 1 is made of brass and the metal deposits in the recesses 5 are made of gold. After complete removal of the resin 3, a timepiece component 10 having a two-tone appearance is obtained.
    The femtosecond laser offers high engraving precision, both in terms of lateral definition and depth. It also makes it possible to engrave the desired area adequately, without affecting the surrounding areas, in particular without affecting the resin. It also allows the part to be engraved without modifying the material around the engraved area, in particular without thermally affecting the surroundings of the engraved area, without producing a machining burr or even without forming a bead of molten and solidified material again. These multiple advantages are specific to the femtosecond laser and cannot be obtained with other types of laser commonly used in the watch industry, such as nanosecond or picosecond pulse lasers. In particular, the use of nanosecond or picosecond pulse lasers to burn components produces results that are aesthetically unacceptable.
    In an alternative embodiment, the opening 4 formed through the resin layer 3 is wider than the opening of the recess 5 in the plane of the surface 2, which gives off a rim around the recess 5 on the surface 2 of the part 1. During the subsequent step of depositing a decorative material, this is deposited not only at the bottom of the recess 5 but also on the edge thereof. A pattern is thus obtained having a clipped aesthetic appearance, as shown in FIG. 6.
    One could consider making a decoration at the end of the preparation step, by machining and / or depositing thin layers.
    In the event of removal of deep material (typically greater than 100 μm) by femtosecond laser treatment, a deposit of black color is likely to appear in the etching. This deposit can be removed by washing with a detergent or using a chemical solution capable of dissolving the deposit or using a femtosecond laser beam having suitable characteristics. We could of course combine these different techniques.
    After removal of the resin and possibly upgraded, the timepiece component 10 is ready to be assembled.
    The following exemplary embodiments differ from the first exemplary embodiment described above by the elements and characteristics which will now be described.
    In a second embodiment, described with reference to Figures 2A to 2E, the manufacturing method of the invention is implemented to etch and deposit a coating on a timepiece component comprising a silicon substrate, such as for example a wheel, an anchor, or a hairspring. One could consider using another substrate material, in particular a semiconductor or insulating material such as diamond, ceramic, or even quartz.
    In a first step, components 1, shown in FIG. 2A, are produced from a silicon wafer by standard photolithography and deep etching techniques, for example by a reactive ion etching technique deep "DRIE" (from the English "Deep Reactive Ion Etching").
    During a second deposition step, a protective layer 3, for example made of photosensitive resin, is deposited on the surface 2 of the components, as shown in FIG. 2B. Optionally, the resin can be polymerized after deposition, either by exposure to UV rays, or by heat treatment, in particular in order to improve its adhesion to the substrate.
    During a third step of removing material, by a femtosecond laser treatment, an opening 4 is made through the protective layer 3, by removing resin, then the component 1 is etched through the opening 4, in order to produce a cavity 5. The opening 4 and the etching, or cavity, 5 are carried out using the same femtosecond laser emission equipment, directly one after the other, without intermediate stage, apart from a possible temporary shutdown of the laser equipment to modify the emission parameters. As a variant, the opening 4 and the cavity 5 could be produced simultaneously. Several cavities 5 can thus be produced in each substrate 1.
    In a fourth step (FIG. 2D), a coating of the metallic, oxide, carbide and / or nitride type is deposited either over the entire surface, for example by an ALD deposit, or in a targeted manner in the bottom of the etched cavities 5 by an ALD deposition or by a directional deposition technique such as the PVD or CVD deposition.
    In a fifth step (Figure 2E), the resin 3 is removed in a known manner, according to the recommendations of the manufacturer. The component can then be assembled.
    Alternatively, one could make the recesses and the coating before the deep etching, the cavities and coating then being protected by the layer of resin deposited to achieve the deep etching.
    A third embodiment of the manufacturing method of the invention will now be described with reference to Figures 3A to 3G. In this case, the method of the invention is used for molding a timepiece component.
    In a first step (Figure 3A), we provide a silicon substrate 1. Alternatively, we could use a metal substrate 1.
    In a second step (Figure 3B), a protective layer is deposited on the substrate, for example by centrifugal coating (in English "spin coating"). The protective layer can be a photosensitive resin, of positive or negative type, such as for example a resin of type "SU-8".
    Optionally, after deposition, the resin can be polymerized, either by exposure to UV rays, or by heat treatment, in particular to improve its adhesion to the substrate.
    In a third step (FIG. 3C), material is removed from the resin layer 3 and from the substrate 1, by femtosecond laser treatment, in order to produce a mold 8.
    During this third step, an opening 4 is made through the resin layer 3 and then directly (that is to say without an intermediate step apart from a possible temporary stop of the laser emission to adjust the parameters d 'emission), the substrate 1 is etched, in line with the opening 4, in order to produce one or more cavities 5, using the same laser emission equipment. In the example shown in FIG. 3C, two cavities 5A and 5B have been dug.
    The cavities 5A, 5B have vertical side walls and a horizontal bottom and here have different respective depths. The desired depth of each cavity 5A (5B) is obtained by adjusting the application parameters of the femtosecond laser beam, in particular the number of passes of the laser beam over the area to be treated, the scanning speed, the transmission power, or again the diameter of the laser beam.
    During the femtosecond laser treatment step, an opening 4 is made in the resin layer 3 and, in line with this opening 4, two cavities 5A, 5B are separated in the substrate 1 separated by a cleared part 7 from the surface 2 of the substrate 1, on which only the resin 3 has been removed. The assembly comprising the cavities 5A, 5B, the exposed part of the substrate 7 and the internal edges (or vertical sides) of the opening 4 forms the mold 8.
    Of course, one could consider other mold configurations having one or more cavities in the substrate 1 and one or more exposed parts of the substrate. The shape and depth of each cavity can be adapted according to the desired component. One could also consider cavities with a profile different from a rectangular profile, such as for example a profile of concave shape, trapezoidal shape, or the like.
    In a fourth step (Figure 3D), implemented in the case of a non-conductive substrate, a conductive layer is deposited on the interior walls of the mold 8. This conductive layer can cover the horizontal surfaces forming the bottom of the mold and possibly the vertical side walls of the mold 8 formed by the vertical sides of the substrate 1 and of the resin 3.
    In a fifth step (FIG. 3E), a metal or metal alloy 9 is deposited by electroforming in the mold 8 and on a layer covering the resin layer 3.
    Optionally, following this step, recovery, machining, polishing, leveling or surface modification operations can be carried out on the metal or the metal alloy deposited. These operation (s) could be carried out later, at the end of manufacture (after detachment of the substrate 1).
    In the example described here, during a sixth step, an upgrade is carried out in order to remove the upper metal layer 9, as shown in FIG. 3F. The fact of depositing the upper layer 9 over the entire surface makes it possible to improve the uniformity and the quality of the deposit at the end of the leveling step.
    In a seventh step (Figure 3G), the substrate 1 is detached and the resin 3 is removed, chemically or by plasma treatment. The resin can be removed before or after detachment from the substrate 1.
    One obtains a metallic timepiece component 10 having the shape of the mold 8.
    Referring to Figures 4A to 4G, we will describe a fourth embodiment of the method of the invention for the manufacture by molding of a timepiece component incorporating an insert.
    The first three steps are analogous to the steps of the previous example of a method described with reference to FIGS. 3A to 3C and allow a mold 8 to be produced, comprising here�:two cavities 5A and 5B of different respective depths,a first portion of exposed substrate 7A connecting the two cavities 5A, 5B, anda second part of exposed substrate 7B produced near the cavity 5B, the opening of the cavity 5B being surrounded by a rim devoid of resin.
    In a fourth step (Figure 4D), an insert 11 is placed in one of the cavities, here the cavity 5B. The insert 11 can be of conductive or insulating material. It projects here from the cavity 5B, in the opening 4 made through the resin layer 3, by a projecting part whose height is here less than the thickness of the resin layer 3.
    In an optional fifth step (Figure 4E), implemented according to the nature of the substrate and the insert, a conductive layer 15 is deposited inside the mold. This conductive layer can cover the surfaces at the bottom of the mold 8, including the projecting part of the insert 11, and, optionally, the vertical side walls of the mold 8 and of the insert 11.
    In a sixth step (Figure 4F), is deposited by electroforming a metal or metal alloy 14 in the mold 8, completely covering the protruding part of the insert 11. The latter is thus embedded in the metal or deposited metal alloy 14.
    In a seventh step, the substrate 1 is detached and the resin 3 is removed, in known manner, for example by plasma treatment or chemically. The resin can be removed before or after stain removal from the substrate.
    This produces a timepiece component 10, as shown in Figure 4G, comprising the molded portion 14 and the insert 11 nested one inside the other, ready to be assembled.
    Optionally, one or more of the following operations can be carried out, before or after stain removal from the substrate: recovery, machining, polishing, leveling and surface modification.
    Instead of an insert projecting from its receiving cavity, one could install a non-protruding insert (in other words a height equal to the depth of the receiving cavity) and providing a recess in its upper surface. In this case, during the sixth step, the metal or metal alloy is also deposited by electroforming in the recess of the insert, which makes it possible to secure the insert to the rest of the component. The digging can be carried out before placing the insert in the cavity or after, for example by etching using the femtosecond laser equipment.
    A fifth embodiment of the method of the invention will now be described with reference to FIGS. 5A to 5E. In this exemplary embodiment, the method of the invention is used for the manufacture of various watch components.
    In a first step (Figure 5A), it is provided with a substrate 1 secured on its upper face 2, one or more metal elements (here two elements 12A, 12B) forming a first level. These metal elements 12A, 12B constitute elements of the timepiece component.
    In a second step, a protective layer 3, for example made of resin, is deposited on the substrate 1 so as to completely cover the first elements of the timepiece component 12A, 12B of the first level and to extend to the - above the first level by forming a second upper level.
    In a third step (Figure 5B), we proceed to a material removal by femtosecond laser treatment. One or more of the following elements are produced during this step:opening (s) through the resin layer 3;recess (s) made in a metallic element of the first level in line with an opening through the resin;cavity (ies) formed in the substrate at the level of an opening through the resin.
    These elements can be combined (that is to say associated to form the same mold) or separate (that is to say dissociated to form separate molds). They are made using the same femtosecond laser emission equipment.
    For making a hollow in a metallic element of a timepiece component or a cavity in the substrate, part of the resin is first removed and then in stride, that is to say directly, without an intermediate operation apart from a possible temporary stop of the laser emission, either the metal element 12A, 12B (to make the recess) or the substrate 1 (to make the cavity) are etched. As a variant, the ablation of the resin and the etching (of a hollow in the timepiece component or of a cavity in the substrate) could be carried out simultaneously.
    In the particular illustrative example, described with reference to FIG. 5B, we have achieved:on the left in the figure, an opening 4A through the resin layer 3 and a recess 13A in the metal element 12A, the opening 4A clearing the recess 13A, a rim of the recess 13A and part of the surface 2 of the substrate 1 adjacent to the metallic element 12A, the whole combined forming a mold or a mold part 8A comprising the recess, the recess rim, and the adjacent part released from the substrate;in the center in the figure, an opening 4B through the resin 3, freeing a part here central from the upper surface of the second metal element, and forming a mold or a mold part 8B;on the right in the figure, an opening 4C through the resin 3 and a cavity 5C, the opening 4C being positioned in line with the cavity 5C and releasing part of the surface 2 of the substrate adjoining the cavity 5C, the whole forming a mold or part of mold 8C.
    In an optional fourth step (Figure 5C), implemented according to the nature of the substrate (that is to say if the substrate is non-metallic, for example made of silicon), a conductive layer 15A-15C , is deposited inside each mold 8A, 8B, 8C. This conductive layer can cover the horizontal surfaces at the bottom of the molds or mold parts 8A-8C and possibly the vertical side walls of the molds or mold parts 8A-8C.
    In a fifth step (Figure 5D), is deposited by electroforming a metal or metal alloy 14A-14C in each mold or a mold part 8A, 8B, 8C.
    In a sixth step (Figure 5E), the substrate 1 is detached and the resin 3 is removed, in known manner, for example by plasma treatment or chemically. The resin can be removed before or after stain removal from the substrate.
    Optionally, one or more of the following operations can be carried out, before or after detaching the substrate: recovery, machining, polishing, leveling and surface modification.
    At the end of the steps described above, three components or parts of timepiece components 10A, 10B, 10C are obtained, represented in FIG. 5E. The component or component part 10A comprises two metallic elements (12A, 14A) inserted one inside the other. The component or component part 10B comprises two metallic elements (12B, 14B) joined to one another. The component or component part 10C is in one piece (14C).
    In the first embodiment, the deposited protective layer preferably has a thickness of at least 1 μm, more preferably a thickness of at least 10 μm, and advantageously a thickness of, for example, between 10 and 30 μm. The etchings produced in the substrate 1 preferably have a depth of at least 10 μm, more preferably a depth of at least 50 μm, more preferably a depth of between 50 μm and 500 μm, and advantageously a depth of between 80 and 120 μm.
    In the other embodiments, the protective layer deposited preferably has a thickness of at least 100 μm, more preferably a thickness of at least 200 μm, and advantageously a thickness of for example between 200 and 1000 μm. The etchings produced in the substrate 1 preferably have a depth of at least 100 μm, more preferably a depth of at least 200 μm, more preferably a depth of between 200 μm and 1000 μm.
    In the various embodiments, the coating or deposited material is formed from a single material. As a variant, the deposit can obviously be formed from several materials and / or several layers. As nonlimiting examples, there may be mentioned a deposit formed by a first bonding layer to improve adhesion and a second functional and / or decorative layer, or else a deposit formed by successive layers of two materials deposited alternately.
    The component itself can be formed from a block of a material, or be composed of several materials, which can preferably be metallic alloys, for example and in a nonlimiting manner, copper metallic alloys such as brass, ferrous metal alloys, amorphous metal alloys, or even precious metal alloys. Alternatively, the component can be formed of ceramic materials such as zirconia or alumina, or of semiconductor or insulating materials such as silicon, diamond or quartz.
    The cavities made in the component can have vertical side walls and a horizontal bottom. They may also have different respective depths, the desired depth of each cavity being obtained by adjusting the application parameters of the femtosecond laser beam, in particular the number of passages of the laser beam over the area to be treated, the scanning speed, the emission power, or the diameter of the laser beam. The shape and depth of each cavity can thus be adapted according to the desired component. One could also consider cavities with a profile different from a rectangular profile, such as for example a profile of concave shape, trapezoidal shape, or the like.
    In combination with the production of cavities, it is also possible to remove only the resin on certain parts of the surface, in order to form a free part of the surface of the substrate on which only the resin 3 has been removed.
    权利要求:
    Claims (15)
    [1]
    1. Method for manufacturing a timepiece component, comprising the following steps:• depositing a protective layer (3) on a support (1) forming part of said timepiece component;Removal of material consisting in making an opening (4; 4A, 4B, 4C) through the protective layer (3),• removal of material consisting of forming a cavity (5; 5A, 5B, 5C) in said support (1), the cavity (5; 5A, 5B, 5C) being positioned in line with at least part of the opening (4; 4A, 4B, 4C) through the protective layer (3),• deposit of material (6; 9; 14) through said opening (4; 4A, 4B, 4C), and• elimination of the protective layer (3),characterized in that the material removal steps consisting in respectively making the opening (4; 4A, 4B, 4C) through the protective layer (3) and the cavity (5; 5A, 5B, 5C) are carried out simultaneously or directly one after the other using femtosecond pulses.
    [2]
    2. Method for manufacturing a watch component, comprising the following steps:• deposit of a protective layer (3) on a support (1);Removal of material consisting in making an opening (4; 4A, 4B, 4C) through the protective layer (3),• removal of material consisting of forming a cavity (5; 5A, 5B, 5C) in said support (1), the cavity (5; 5A, 5B, 5C) being positioned in line with at least part of the opening (4; 4A, 4B, 4C) through the protective layer (3),• deposit of material (6; 9; 14) through said opening (4; 4A, 4B, 4C), and• release of the watch component by eliminating the protective layer (3) and detaching it from the support,characterized in that the material removal steps consisting in respectively making the opening (4; 4A, 4B, 4C) through the protective layer (3) and the cavity (5; 5A, 5B, 5C) are carried out simultaneously or directly one after the other using femtosecond pulses and in that during the material removal steps in the protective layer and in the support, a mold is produced having at least a first depth equal to the thickness of the protective layer and at least a second depth equal to the thickness of the protective layer increased by the depth of a cavity in the support.
    [3]
    3. Method according to one of the preceding claims, characterized in that the femtosecond pulses acting to produce the opening through the protective layer and the femtosecond pulses acting to produce the cavity in the support are produced by the same femtosecond laser equipment. .
    [4]
    4. Method according to one of the preceding claims, characterized in that it comprises a momentary stop of the femtosecond pulses to modify the emission parameters of said pulses between the step of removal of material consisting in making said opening through the protective layer and the material removal step of forming said cavity in the support.
    [5]
    5. Method according to one of the preceding claims, characterized in that the protective layer is a photosensitive resin.
    [6]
    6. Method according to the preceding claim, characterized in that it comprises a step of polymerization of the resin (3) by UV exposure.
    [7]
    7. Method according to one of the preceding claims, characterized in that the protective layer is deposited by one of the deposition techniques comprising deposition by electrophoresis or deposition by centrifugal coating.
    [8]
    8. Method according to one of the preceding claims, characterized in that the deposition of material in the cavity is carried out using one of the techniques of the group comprising a galvanic deposition, a chemical vapor deposition CVD, a physical deposition in PVD vapor phase and an ALD atomic layer deposition.
    [9]
    9. Method according to claim 1 or according to claim 1 and one of claims 3 to 8, characterized in that the support comprises a surface of the timepiece component and the step of depositing material through the opening consists in depositing a decoration material in the cavity.
    [10]
    10. Method according to the preceding claim, characterized in that the opening through the protective layer releases a rim around the cavity at the surface of the timepiece component, and in that, during the deposition step of the decoration material, said decoration material is deposited on the rim.
    [11]
    11. Method according to claim 2, characterized in that, during the material deposition step, a metal or metal alloy forming the watch component is deposited in said mold, then the watch component is removed from the mold by removing the protective layer and by detaching it from the support.
    [12]
    12. Method according to claim 2 or 11, characterized in that, during the material deposition step, the mold is filled and an additional layer of metal or metal alloy of the horological component is deposited on the protective layer, and in that there is provided a subsequent leveling step consisting in eliminating said additional layer.
    [13]
    13. Method according to one of claims 2, 11 and 12, characterized in thatDuring the steps of removing material from the protective layer (3) and from the support (1), at least one cavity (5B) for receiving an insert (11) is produced in the support, the mouth of which communicates with the opening (4) through the protective layer (3), the latter releasing a part (7A) of the support around said mouth;• the insert (11) is placed in said cavity (5B), said insert (11) projecting out of the cavity (5B) into the opening (4) through the protective layer (3);During the material deposition step, a metal or metal alloy (14) is deposited through said opening (4),• then the watch component (10) is removed from the mold integrating the insert (11) by eliminating the protective layer (3) and detaching the support (1).
    [14]
    14. Method according to one of claims 2, 12 and 13, characterized in that it comprises a step consisting in providing a support (1) integral, on its upper face (2), with one or more timepiece component elements (12A, 12B), the support (1) comprising a substrate on which at least a first timepiece component element (12A, 12B) is then deposited in that it comprises:During the deposition step, the protective layer (3) is deposited on the support (1) so as to completely cover the first element (12A),• during the material removal steps in the protective layer (3) and in the support (1), an opening (4) is made through the protective layer and a recess (13A) in the first component element watchmaker (12A), said opening clearing the recess (13A), an edge of the recess and a part of the substrate adjacent to the first element of the watchmaking component, and forming a mold (8A) comprising the recess, said edge and said part of substrate adjacent;• during the material deposition step, metal or a metal alloy is deposited in said mold (8A) in order to form a second timepiece component element (14A);• then the watch component comprising the first and the second element (12A, 14A) is removed from the mold by removing the resin (3) and detaching the substrate (1).
    [15]
    15. Method according to one of the preceding claims, characterized in that the component comprises several materials, in particular several metal alloys.
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    同族专利:
    公开号 | 公开日
    EP2881808A2|2015-06-10|
    CH708947A2|2015-06-15|
    EP2881808B1|2020-08-19|
    EP2881808A3|2016-07-06|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    EP1071000A1|1999-07-23|2001-01-24|Damian Rickenbach|Method for shaping surfaces of parts of watch|
    DE102008061182A1|2008-12-04|2010-06-10|Konrad Damasko|Manufacturing a microcomponent for mechanical clockwork of a wristwatch, comprises providing layer sequence consisting of carrier-, intermediate- and wearing layer, and cutting-off the microcomponent made of wearing layer by laser cutting|
    US8790534B2|2010-04-30|2014-07-29|Corporation For National Research Initiatives|System and method for precision fabrication of micro- and nano-devices and structures|
    US8557683B2|2011-06-15|2013-10-15|Applied Materials, Inc.|Multi-step and asymmetrically shaped laser beam scribing|
    法律状态:
    2016-06-15| PK| Correction|Free format text: RECTIFICATION INVENTEUR |
    2018-12-14| PFA| Name/firm changed|Owner name: ROLEX SA, CH Free format text: FORMER OWNER: ROLEX SA, CH |
    优先权:
    申请号 | 申请日 | 专利标题
    EP13195421|2013-12-03|
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