FUNGICIDE, INSECTICIDE, NEMATICIDE OR BACTERICIDE COMPOSITION AND METHOD FOR CONTROLLING PESTS, HARM

专利摘要:
fungicidal or bactericidal composition, and method for controlling diseases. a new pesticide composition and particularly a composition for a fungicide. a fungicidal or bactericidal composition comprising one or more compounds selected from oxime-substituted amide compounds represented by formula (i), or their n-oxides or salts, and one or more compounds selected from known fungicidal or bactericidal compounds (i) in which g1 represents a structure of g1-1, g1-27, and the like, g2 represents a structure of g2-2, and the like, w represents an oxygen atom, and the like, x1 represents difluoromethyl, trifluoromethyl, and the like, x2, x3 , x4 and x5 each independently represent a hydrogen atom, and the like, y1 represents a halogen atom, and the like, y2 represents a hydrogen atom, a halogen atom, and the like, y3 represents a halogen atom, trifluoromethyl, c2-c6 alkynyl, and the like. y4 represents a hydrogen atom, and the like, r1 represents c1-c6 alkyl, c1-c4 haloalkyl, and the like, r2 and r3 each independently represent an atom of hydrogen, methyl, and the like, r4 represents a hydrogen atom, and the like, and r5 represents a methyl group, or the like.
公开号:BR112016017430B1
申请号:R112016017430-5
申请日:2015-02-06
公开日:2021-07-13
发明作者:Hidehito Kuwahara；Nakako HASUNUMA；Yasuhiro FUKAMI
申请人:Nissan Chemical Industries Ltd；
IPC主号:

专利说明:

Technical Field
[001] The present invention relates to a composition for controlling plant diseases, which comprises a specific amide compound substituted by oxime, or its N-oxide or salt, and a compound as an active ingredient of a fungicidal or bactericidal agent specific, and a method of controlling plant diseases. Previous Technique
[002] An oxime-substituted amide compound represented by the formula (I), or its N-oxide or salt, as the first compound as the active ingredient in the fungicidal or bactericidal composition of the present invention, is a known compound, and its activities as a pesticidal agent is known (see Patent Document 1).
[003] In addition, a compound being the active ingredient B as the second active ingredient in the fungicidal or bactericidal composition of the present invention, is a known compound having fungicidal activities or bactericidal activities (see Non-Patent Document 1). PRIOR TECHNIQUE DOCUMENTS PATENT DOCUMENT
[004] Patent Document 1: WO2014/010737 NON-PATENT DOCUMENT
[005] Non-Patent Document 1: The Pesticide Manual, 16th edition, The British Crop Protection Council, 2012 Description of the Invention TECHNICAL PROBLEM
[006] Plant diseases caused by infection of various pathogens in plants such as cereals, fruits, vegetables, ornamental plants, etc., will cause deterioration in the quality of agricultural crops, significant reduction in yield and in some cases , even serious damage such as plant death, and therefore represent a significant economic loss not only for producers but also for consumers. Therefore, effective control of such plant diseases is a very important issue in order to obtain efficient and stable production of agricultural crops. From this point of view, by now, developments of pest control agents for the purpose of controlling plant diseases have already been made, and many effective pesticides have been put into practical use so far.
[007] However, due to years of use of these pesticides, in recent years there has been an increasing number of cases where pathogens have acquired resistance to such pesticides, and pest control by existing plant disease controlling agents that have been used so far it tends to get difficult. In addition, the problem has become evident that some of the existing plant disease controlling agents are highly toxic, or that some remain too long in the environment to create some ecosystem disruption problem. Under these circumstances, it is now coherently desired to develop a new plant disease controlling agent that not only has excellent control activities against pathogenic bacteria, but also has a high level of control characteristics such as low toxicity and low residual properties, and a effective control method.
[008] It is an object of the present invention to provide a new plant disease controlling agent that exhibits excellent control activities against pathogenic bacteria, and has features such as low toxicity and low residual properties, and a method of controlling plant disease . SOLUTION TO THE PROBLEM
[009] As a result of extensive research aimed at solving the above problem, the present inventors have found that a composition comprising, in combination, a specific oxime-substituted amide compound represented by the formula (I) below, or its N -oxide or salt (active ingredient A), and a specific compound having fungicidal or bactericidal activities (active ingredient BA), exhibits excellent synergistic fungicidal or bactericidal effects, which cannot be predicted from a case using each of the compounds alone. That is, the above composition has been found to be extremely useful in the sense that it shows excellent plant disease controlling activities and does not have substantially any adverse effects against non-target organisms such as plants, mammals, fish, useful insects and natural enemies and , therefore, the present invention has been completed.
[0010] That is, the present invention offers, in essence, a composition defined in items [1] to [19] below (hereinafter also called the composition of the present invention), and a method of disease control defined in item [20] below (hereinafter also called the method of the present invention).
[0011] [1] A composition for a fungicide, an insecticide, a nematicide or a bactericide, characterized by comprising one or more compounds selected from active ingredients A below, and one or more compounds selected from active ingredients B below , respectively, in synergistically effective amounts:
[0012] (1) Active ingredient A: an oxime-substituted amide compound represented by the formula (I) below, or its N-oxide or its salt,

[0013] In the formula, G1 represents a structure of G1-1, G1-2, G1-3, G1-7, G1-8, G1-9, G1-11, G1-12, G1-13, G1-16 , G1-27, G1-32, G1-33 or G1-50,

[0014] G2 represents a structure of G2-1, G2-2, G2-6 or G2-9,

[0015] W represents an oxygen atom or a sulfur atom,
[0016] X1 represents a halogen, nitro, methyl, difluoromethyl or trifluoromethyl atom,
[0017] X2 represents a hydrogen atom, and even when G1 represents a structure of G1-27, and X1 represents trifluoromethyl, X2 can represent a halogen atom,
[0018] X3 represents a hydrogen or methyl atom,
[0019] X4 represents a hydrogen atom or a halogen atom,
[0020] X5 represents a hydrogen atom,
[0021] Y1 represents a hydrogen atom, a halogen atom, methyl, trifluoromethyl or methoxy,
[0022] Y2 represents a hydrogen atom, a halogen atom, cyano, methoxy, methylthio, methylsulfinyl or methylsulfonyl,
[0023] Y3 represents a hydrogen atom, a halogen atom, cyano, C1-C4 alkyl, trifluoromethyl, C2-C4 alkenyl, C2-C6 alkynyl, (C2-C6) alkynyl optionally substituted with R6, - OR7, C1C4 alkylthio, -C(R8)=NOR9, phenyl, D-3 or D-7,
[0024] Y4 represents a hydrogen atom or a halogen atom,
[0025] Y5 represents a hydrogen atom,
[0026] R1 represents C1-C6 alkyl, C1-C4 haloalkyl, (C1-C4)alkyl substituted with R10, C3-C6 cycloalkyl, C3-C6 alkenyl, C3-C4 halo-alkenyl, C3-C6 alkynyl or phenyl,
[0027] R2 represents a hydrogen, methyl or ethyl atom, provided that R2 represents methyl or ethyl when G1 represents a structure of G1-1, X1 represents a chlorine atom, X2, X3 and X5 each represent a hydrogen atom, X4 represents a hydrogen atom or a chlorine atom, and G2 represents a G2-1 structure, Y3 represents a chlorine atom, Y1, Y2, Y4 and Y5 each represent an atom of hydrogen,
[0028] R3 represents a hydrogen or methyl atom, or R2 and R3 together can form a cyclopropyl ring,
[0029] R4 represents a hydrogen atom, C1-C4 haloalkylthio, C1-C4 alkylcarbonyl or C1-C4 alkoxycarbonyl,
[0030] R5 represents methyl,
[0031] R6 represents a halogen atom, C3-C6 cycloalkyl, hydroxy(C3-C6)cycloalkyl, C5-C6 cycloalkenyl, -OH, -OR7, C1-C4 alkylcarbonyloxy, C1-C4 alkylsulfonyloxy, C1-C4 alkylthio , trimethylsilyl, - C(R8)=NOR9, phenyl, phenyl substituted with (Z)m or D-32,
[0032] Z represents a halogen atom, cyano, nitro, C1-C4 alkyl, trifluoromethyl, methoxy, trifluoromethoxy, trifluoromethylthio or phenyl, and when m or n represents 2 or more, the respective Zs may be identical or different from each other , and when there are two neighboring Zs, the two Zs can form -CH=CH-CH=CH- to form a 6-membered ring along with the carbon atoms attached to the two Zs,
[0033] R7 represents C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy(C1-C2)alkyl, E-14, C3-C4 alkynyl or phenyl substituted with (Z)m,
[0034] R8 represents a hydrogen or methyl atom,
[0035] R9 represents methyl or ethyl,
[0036] R10 represents cyano, C3-C6 cycloalkyl, E-5, E-9, C1-C4 alkoxy, C1-C4 alkylthio, trimethylsilyl, -C(R11)=NOR12, phenyl, phenyl substituted with (Z)m, D-10 or D-32,
[0037] D-3, D-7, D-10 and D-32, respectively, represent aromatic heterocyclic rings of the following structural formulas,

[0038] E-5, E-9 and E-14, respectively, represent saturated heterocyclic rings of the following structural formulas,

[0039] R11 represents methyl,
[0040] R12 represents methyl or ethyl,
[0041] m represents an integer of 1, 2 or 3,
[0042] n represents an integer of 0, 1 or 2,
[0043] (2) active ingredient B:
[0044] group B-I: benalaxyl, benalaxyl-M, furalaxyl, metalaxyl, metalaxyl-M, ofurace, oxadixyl, bupirimate, etirimol, hymexazol, octilinone and oxolinic acid,
[0045] group B-II: benomyl, carbendazim, fuberidazole, thiabendazole, thiophanate-methyl, diethofencarb, ethaboxam, zoxamide, pencycuron, fluopicolide, diflumethorim and benodanil,
[0046] group B-III: benzovindiflupyr, bixafen, boscalid, carboxin, fenfuram, fluopyram, flutolanil, fluxapyroxad, furametpyr, isofetamid, isopyrazam, mepronil, oxycarboxin, penflufen, penthiopyrad, sedaxane, tidioxystrobin, coumoxystrobin, coumoxystrobin, azaxane enestrobin, enoxastrobin, famoxadone, fenamidone, phenaminstrobin, fluphenoxystrobin, fluoxastrobin, kresoxim-methyl, mandestrobin, metaminostrobin, orysastrobin, picoxystrobin, pyraclostrobin, pyramythos-throbin, pyraoxyben- thyrombin, pyraoxyben- carbin trifloxystrobin, amisulbrom, cyazofamid, dinocap, fluazinam, meptyldinocap, fentin, tributyltin oxide, siltiofam and ametoctradin,
[0047] group B-IV: cyprodinil, mepanipyrim, pyrimethanil, mangraicidin-S, kasugamycin, streptomycin and oxytetracycline,
[0048] group B-V: proquinazid, quinoxyfen, fenpiclonil, fludioxonil and clozolinate,
[0049] group B-V: iprodione, procymidone and vinclozoline,
[0050] group B-VI: edifenphos, iprobenfos, isoprothiolane, pyrazophos, biphenyl, chloroneb, dichloran, etridiazole, quintazene, tecnazene, tolclophos-methyl, propamocarb hydrochloride and Bacillus subtilis (Cepa, GBA,0447 , MBI600, QST713, Y1336, etc.),
[0051] group B-VII: azaconazole, bitertanol, bromuconazole, climbazole, cyproconazole, diclobutrazol, difenoconazole, diniconazole, diniconazole-M, epoxiconazole, etaconazole, fenarimol, fenbuconazole, fluotriazole, fluquinconazole, fluquinconazole, hexaconazole, imazalil, imibenconazole, ipconazole, metconazole, myclobutanil, nuarimol, oxpoconazole fumarate, pefurazoate, penconazole, prochloraz, propiconazole, prothioconazole, pyrifenox, pyrisoxazole, simeconazole, tebuconazole, tetraformadiol, trimenadiol, trimenadiol triticonazole, aldimorph, dodemorph acetate, fenpropidin, fenpropimorph, piperaline, spiroxamine, tridemorph, fenhexamid and fenpyrazamine,
[0052] group B-VIII: validamycin, polyoxins, polyoxorim, benthia-valicarb-isopropyl, dimethomorph, flumorph, iprovalicarb, mandipropamid, pyrimorph and valifenalate,
[0053] group B-IX: phthalide, pyroquilon, tricyclazole, carpropamid, di-clocymet and fenoxanil,
[0054] BX group: acibenzolar-S-methyl, probenazol, isothianil and thiadinil, B-XI group: laminarin, bordeaux mixture, Cheshunt mixture, basic copper carbonate, copper hydroxide, copper naphthenate, copper oleate , copper oxychloride, copper sulfate, basic copper sulfate, copper oxine, calcium polysulfide, sulfur, amobam, ferbam, mancozeb, maneb, metiram, polycarbamate, propineb, thiram, ziram, captan, folpet, chlorothalonil, dichlofluanid, tolylfluanid , guazatine, iminoctadine albesylate, iminoctadine triacetate, anilazine, dithianon, chinometionat and fluoroimide,
[0055] group B-XII: cyflufenamid, cymoxanil, diclomezine, dodine, ferimzone, flusulfamide, flutianil, fosetyl-aluminium, metrafenone, oxathi-apiprolin, pyriophenone, tebufloquin, tolprocarb, triazoxide, sodium hydrogencarbonate, potassium hydrogen carbonate, shiitake mycelium extract, shiitake fruiting body extract, BCF-082 (test name) and NNF-0721 (test name).
[0056] [2] The composition for a fungicide, an insecticide, a nematicide or a bactericide according to item [1] above, where
[0057] G1 represents a structure of G1-1, G1-2, G1-3, G1-7, G1-11, G1-12, G1-16, G1-27 or G1-33,
[0058] G2 represents a structure of G2-1, G2-2 or G2-9,
[0059] W represents an oxygen atom,
[0060] X1 represents a halogen, methyl, difluoromethyl or trifluoromethyl atom,
[0061] X2 represents a hydrogen atom,
[0062] X3 represents a hydrogen or methyl atom,
[0063] X4 represents a hydrogen atom,
[0064] X5 represents a hydrogen atom,
[0065] Y1 represents a halogen atom,
[0066] Y2 represents a hydrogen atom, a halogen atom, a methoxy, methylthio or methylsulfonyl atom,
[0067] Y3 represents a halogen atom, trifluoromethyl, C2-C4 alkenyl, C2-C6 alkynyl, (C2-C6) alkynyl optionally substituted with R6, C1-C4 haloalkoxy or -C(R8)=NOR9,
[0068] Y4 represents a hydrogen atom or a halogen atom,
[0069] Y5 represents a hydrogen atom,
[0070] R1 represents C1-C6 alkyl, C1-C4 haloalkyl, (C1-C4)alkyl substituted with R10, C3-C6 cycloalkyl, C3-C6 alkenyl, C3-C4 halo-alkenyl or C3-C6 alkynyl,
[0071] R2 represents a hydrogen or methyl atom, provided that when G2 is a structure represented by G2-1, R2 represents methyl,
[0072] R3 represents a hydrogen atom,
[0073] R4 represents a hydrogen atom,
[0074] R5 represents methyl,
[0075] R6 represents a halogen atom, C3-C6 cycloalkyl, -OR7, trimethylsilyl, -C(R8)=NOR9 or phenyl,
[0076] R7 represents C1-C4 alkyl or C1-C4 alkoxymethyl,
[0077] R10 represents C3-C6 cycloalkyl, trimethylsilyl, phenyl, phenyl substituted with (Z)m, or D-32,
[0078] Z represents a halogen or cyan atom, and when m represents 2 or more, the respective Zs may be identical or different from each other,
[0079] n represents an integer of 1.
[0080] [3] The composition for a fungicide, an insecticide, a nematicide or a bactericide according to item [1] or [2] above, where
[0081] G1 represents a structure of G1-1, G1-3, G1-27 or G1-33,
[0082] G2 represents a structure of G2-2,
[0083] X1 represents a chlorine atom, an iodine, difluoromethyl or trifluoromethyl atom,
[0084] X2 represents a hydrogen atom,
[0085] X3 represents a hydrogen or methyl atom,
[0086] X4 represents a hydrogen atom,
[0087] X5 represents a hydrogen atom,
[0088] Y1 represents a chlorine atom or a bromine atom,
[0089] Y2 represents a hydrogen atom, a chlorine or methoxy atom,
[0090] Y3 represents a chlorine atom, a bromine atom, trifluoromethyl, C2-C6 alkynyl, or (C2-C6) alkynyl optionally substituted with R6,
[0091] Y4 represents a hydrogen atom,
[0092] R1 represents C1-C4 alkyl, C1-C4 haloalkyl or cyclopropylmethyl,
[0093] R2 represents a hydrogen or methyl atom,
[0094] R3 represents a hydrogen atom,
[0095] R4 represents a hydrogen atom,
[0096] R5 represents methyl,
[0097] R6 represents a halogen atom, cyclopropyl or C1-C4 alkoxy.
[0098] [4] The composition for a fungicide, an insecticide, a nematicide or a bactericide according to any of the items [1] to [3] above, where
[0099] G1 represents a structure of G1-1,
[00100] X1 represents an iodine or trifluoromethyl atom,
[00101] X2, X3, X4 and X5 each represent a hydrogen atom.
[00102] [5] The composition for a fungicide, an insecticide, a nematicide or a bactericide according to any of the items [1] to [3] above, where
[00103] G1 represents a structure of G1-3,
[00104] X1 represents a chlorine or difluoromethyl atom,
[00105] X2, X3 and X4 each represent a hydrogen atom.
[00106] [6] The composition for a fungicide, an insecticide, a nematicide or a bactericide according to any of [1] to [3] above, where
[00107] G1 represents a structure of G1-27,
[00108] X1 represents difluoromethyl,
[00109] X2 represents a hydrogen atom,
[00110] R5 represents methyl.
[00111] [7] The composition for a fungicide, an insecticide, a nematicide or a bactericide according to any of [1] to [3] above, where
[00112] G1 represents a structure of G1-33,
[00113] X1 represents difluoromethyl,
[00114] X3 represents methyl.
[00115] [8] The composition for a fungicide, an insecticide, a nematicide or a bactericide according to any of the items [1] to [7] above, which contains, as active ingredient B, a compound selected from the active ingredients of the BI group.
[00116] [9] The composition for a fungicide, an insecticide, a nematicide or a bactericide according to any of the items [1] to [7] above, which contains, as active ingredient B, a compound selected from the active ingredients of group B-II.
[00117] [10] The composition for a fungicide, an insecticide, a nematicide or a bactericide according to any one of items [1] to [7] above, which contains, as active ingredient B, a compound selected from among the ingredients assets of group B-III.
[00118] [11] The composition for a fungicide, an insecticide, a nematicide or a bactericide according to any one of items [1] to [7] above, which contains, as active ingredient B, a compound selected from among the ingredients assets of group B-IV.
[00119] [12] The composition for a fungicide, an insecticide, a nematicide or a bactericide according to any one of items [1] to [7] above, which contains, as active ingredient B, a compound selected from among the ingredients assets of the BV group.
[00120] [13] The composition for a fungicide, an insecticide, a nematicide or a bactericide according to any one of items [1] to [7] above, which contains, as active ingredient B, a compound selected from among the ingredients assets of the B-VI group.
[00121] [14] The composition for a fungicide, an insecticide, a nematicide or a bactericide according to any one of items [1] to [7] above, which contains, as active ingredient B, a compound selected from among the ingredients assets of group B-VII.
[00122] [15] The composition for a fungicide, an insecticide, a nematicide or a bactericide according to any one of items [1] to [7] above, which contains, as active ingredient B, a compound selected from among the ingredients assets of group B-VIII.
[00123] [16] The composition for a fungicide, an insecticide, a nematicide or a bactericide according to any one of items [1] to [7] above, which contains, as active ingredient B, a compound selected from among the ingredients assets of the B-IX group.
[00124] [17] The composition for a fungicide, an insecticide, a nematicide or a bactericide according to any one of items [1] to [7] above, which contains, as active ingredient B, a compound selected from among the ingredients assets of the BX group.
[00125] [18] The composition for a fungicide, an insecticide, a nematicide or a bactericide according to any one of items [1] to [7] above, which contains, as active ingredient B, a compound selected from among the ingredients assets of the B-XI group.
[00126] [19] The composition for a fungicide, an insecticide, a nematicide or a bactericide according to any one of items [1] to [7] above, which contains, as active ingredient B, a compound selected from among the ingredients assets of group B-XII.
[00127] [20] A method of controlling pests, harmful insects, nematodes or bacteria, by treatment at the same or in close temporal proximity with one or more compounds selected from the active ingredients A defined in item [1] above and one or more selected compounds from group BI to group B-XII of active ingredients B defined in item [1] above.
[00128] [21] The method to control pests, harmful insects, nematodes or bacteria according to item [20] above, where the application rate of each of active ingredient A and active ingredient B varies from 0, 1 to 1,000 g ai/ha.
[00129] [22] The method to control pests, harmful insects, nematodes or bacteria according to item [20] or [21] above, where the application dosage, such as the amount of active ingredients, varies from 0.005 at 50 kg/ha. ADVANTAGEOUS EFFECTS OF THE INVENTION
[00130] The fungicidal or bactericidal composition of the present invention and the disease control method using the composition of the present invention exhibit excellent synergistic control effects against plant diseases caused by various pathogens, and also exhibit sufficient synergistic control effects even against pa - Togens that have acquired resistance to certain conventional disease controlling agents. DESCRIPTION OF MODALITIES
[00131] The oxime-substituted amide compound represented by the formula (I) to be used as the active ingredient A of the present invention has geometric shapes of shape E- and shape Z-, and the compound to be used as the active ingredient A of the present invention is a compound encompassing such E-form, Z-form or a mixture comprising E-form and Z-form in optional proportions.
[00132] Furthermore, the compound represented by the formula (I) to be used as the active ingredient A of the present invention, may, depending on its substituents, sometimes have optically active isomers due to the presence of one or more asymmetric carbon atoms , and the compound to be used as active ingredient A of the present invention includes all such optically active isomers or racemic forms.
[00133] The halogen atom in this specification includes a fluorine atom, a chlorine atom, a bromine atom and an iodine atom. In addition, the notation "halo" in this specification also represents these halogen atoms.
[00134] The notation "Ca-Cb alkyl" represents a linear or branched hydrocarbon group having from a to b carbon atoms, and, for example, a methyl group, an ethyl group, a propyl group, an isopropyl group, a group butyl, an isobutyl group, an s-butyl group, a tert-butyl group, a pentyl group, a 1-ethylpropyl group, a 2,2-dimethylpropyl group, a hexyl group, etc. can be mentioned as specific examples, and is selected within the specified range of carbon numbers.
[00135] Here, sec- means secondary, ter- means tertiary, respectively, and the same applies hereafter.
[00136] The notation "Ca-Cb haloalkyl" represents a linear or branched hydrocarbon group having from a to b carbon atoms, where hydrogen atoms bonded to carbon atoms are optionally substituted with halogen atoms, and then, if substituted with two or more halogen atoms, such halogen atoms can be the same or different from each other. For example, a fluoromethyl group, a chloromethyl group, a bromomethyl group, an iodomethyl group, a difluoromethyl group, a dichloromethyl group, a trifluoromethyl group, a chlorodifluoromethyl group, a trichloromethyl group, a bromodifluoromethyl group, a group 1 -fluoroethyl, a 2-fluoroethyl group, a 2-chloroethyl group, a 2-bromoethyl group, a 2,2-difluoroethyl group, a 2,2,2-trifluoroethyl group, a 2-chloro-2,2-difluoroethyl group , a 2,2,2-trichloroethyl group, a 2-bromo-2,2-difluoroethyl group, a 1,1,2,2-tetrafluoroethyl group, a 2-chloro-1,1,2-trifluoroethyl group, a pentafluoroethyl group, a 2,2-difluoropropyl group, a 3,3,3-trifluoropropyl group, a 3-bromo-3,3-difluoropropyl group, a 2,2,3,3-tetrafluoropropyl group, a 2,2 group ,3,3,3-pentafluoropropyl, a 1,1,2,3,3,3-hexafluoropropyl group, a heptafluoropropyl group, a 2,2,2-trifluoro-1-(methyl)ethyl group, a 2 group, 2,2-trifluoro-1-(trifluoromethyl)ethyl, a 1,2,2,2-tetrafluoro-1-(trif) group fluoromethyl)ethyl, a 2,2,3,4,4,4-hexafluorobutyl group, a 2,2,3,3,4,4,4-heptafluorobutyl group, a nonafluorobutyl group, etc. can be mentioned as specific examples, and is selected within the specified range of carbon numbers.
[00137] The notation "Ca-Cb cycloalkyl" represents a cyclic hydrocarbon group having a to b carbon atoms, which can form a monocyclic or composite ring structure from a three-membered to a 10-membered ring. Furthermore, each ring can be optionally substituted with an alkyl group within a specified range of carbon numbers. For example, a cyclopropyl group, a cyclobutyl group, a 1-methylcyclopropyl group, a 2-methylcyclopropyl group, a cyclopentyl group, a 2,2-dimethylcyclopropyl group, a 1-methylcyclobutyl group, a cyclohexyl group, etc. can be mentioned as specific examples, and is selected within the specified range of carbon numbers.
[00138] The notation "Ca-Cb alkenyl" represents a linear or branched unsaturated hydrocarbon having from a to b carbon atoms and having one or more double bonds in its molecule, and, for example, a vinyl group, a 1-propenyl group, a 2-propenyl group, a 1-methylethenyl group, a 1-butenyl group, a 2-butenyl group, a 1-methyl-1-propenyl group, a 2-methyl-1-propenyl group, a 2-methyl-group 2-propenyl, a 3-methyl-3-butenyl group, etc. can be mentioned as specific examples, and is selected within the specified range of carbon numbers.
[00139] The notation "Ca-Cb haloalkenyl" represents a linear or branched unsaturated hydrocarbon group having from a to b carbon atoms and having one or more double bonds in its molecule, where hydrogen atoms bonded to carbon atoms are optionally substituted with halogen atoms. So, if substituted with two or more halogen atoms, those halogen atoms can be the same or different from each other. For example, a 2-fluoro-vinyl group, a 2-chloro-vinyl group, a 1,2-dichloro-vinyl group, a 2,2-dichloro-vinyl group, a 2,2-dibromo-vinyl group, a 2-fluoro-2-propenyl group, a 2-chloro-2-propenyl group, a 3-chloro-2-propenyl group, a 3,3-difluoro-2-propenyl group, a 2,3-dichloro-2 group -propenyl, a 3,3-dichloro-2-propenyl group, a 2,3,3-trifluoro-2-propenyl group, a 2,3,3-trichloro-2-propenyl group, a 1-(trifluoromethyl) group ethenyl, a 4,4-difluoro-3-butenyl group, a 3,4,4-trifluoro-3-butenyl group, a 2,4,4,4-tetrafluoro-2-butenyl group, a 3-chloro- 4,4,4- trifluoro-2-butenyl, etc. can be mentioned as specific examples, and is selected within the specified range of carbon numbers.
[00140] The notation "Ca-Cb alkynyl" represents a linear or branched unsaturated hydrocarbon group having from a to b carbon atoms and having one or more triple bonds in its molecule, and, for example, an ethynyl group, a group 1 -propynyl, a 2-propynyl group, a 1-butynyl group, a 2-butynyl group, a 3-butynyl group, a 1-methyl-2-propynyl group, a 1-pentynyl group, a 2-pentynyl group, a 1-hexynyl group, a 3-hexynyl group, a 3-methyl-1-pentynyl group, a 4-methyl-1-pentynyl group, a 3,3-dimethyl-1-butynyl group, etc. can be mentioned as specific examples, and is selected within the specified range of carbon numbers.
[00141] The notation "Ca-Cb haloalkynyl" represents a linear or branched unsaturated hydrocarbon group having from a to b carbon atoms and having one or more triple bonds in its molecule, where where hydrogen atoms bonded to carbon atoms are optionally substituted with halogen atoms. So, if substituted with two or more halogen atoms, those halogen atoms can be the same or different from each other. For example, a 2-chloroethynyl group, a 2-bromoethynyl group, a 2-iodoethynyl group, a 3-fluoro-1-propynyl group, a 3-chloro-1-propynyl group, a 3-chloro-2-propynyl group , a 3-bromo-1-propynyl group, a 3-bromo-2-propynyl group, a 3-iodo-2-propynyl group, a 3,3-difluoro-1-propynyl group, a 3,3,3 group -trifluoro-1-propynyl, a 3-bromo-1-butynyl group, a 3-fluoro-3-methyl-1-butynyl group, a 3-chloro-3-methyl-1-butynyl group, a 3-bromo group -3-methyl-1-butynyl, etc. can be mentioned as specific examples, and is selected within the specified range of carbon numbers.
[00142] The notation "Ca-Cb alkoxy" represents an alkyl-O- group having from a to b carbon atoms, as defined above, and, for example, a methoxy group, an ethoxy group, a propyloxy group, an iso- group. propyloxy, a butyloxy group, an iso-butyloxy group, an s-butyloxy group, a tert-butyloxy group, a pentyloxy group, a hexyloxy group, etc. can be mentioned as specific examples, and is selected within the specified range of carbon numbers.
[00143] The notation "Ca-Cb haloalkoxy" represents a haloalkyl-O- group having from a group ab carbon atoms, as defined above, and, for example, a difluoromethoxy group, a trifluoromethoxy group, a chlorodifluoromethoxy group, a bromodifluoromethoxy group, a 2-fluoroethoxy group, a 2-chloroethoxy group, a 2,2,2-trifluoroethoxy group, a 1,1,2,2-tetrafluoroethoxy group, a 2-chloro-1,1,2- trifluoroethoxy, a 1,1,2,3,3,3-hexafluoro-propyloxy group, etc. can be mentioned as specific examples, and is selected within the specified range of carbon numbers.
[00144] The notation "Ca-Cb alkylthio" represents an alkyl-S- group having from a tob carbon atoms, as defined above, and, for example, a methylthio group, an ethylthio group, a propylthio group, an isopropylthio group, a butylthio group, an isobutylthio group, an s-butylthio group, a tert-butylthio group, etc. can be mentioned as specific examples, and is selected within the specified range of carbon numbers.
[00145] The notation "Ca-Cb haloalkylthio" represents a haloalkyl-S- group having from a to b carbon atoms, as defined above, and, for example, a difluoromethylthio group, a trifluoromethylthio group, a chlorodifluoromethylthio group, a group trichloromethylthio, a bromodifluoromethylthio group, a 2,2,2-trifluoroethylthio group, a 1,1,2,2-tetrafluoroethylthio group, a 2-chloro-1,1,2-trifluoroethylthio group, a pentafluoroethylthio group, a 1,1,2,3,3,3-hexafluoropropylthio group, a heptafluoropropylthio group, a 1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethylthio group, a nonafluorobutylthio group, etc. can be mentioned as specific examples, and is selected within the specified range of carbon numbers.
The notation "Ca-Cb alkylsulfinyl" represents an alkyl-S(O) group having from a to b carbon atoms, as defined above, and, for example, a methylsulfinyl group, an ethylsulfinyl group, a propylsulfinyl group, an isopropylsulfinyl group, a butylsulfinyl group, an iso-butylsulfinyl group, an s-butylsulfinyl group, a tert-butylsulfinyl group, etc. can be mentioned as specific examples, and is selected within the specified range of carbon numbers.
[00147] The notation "Ca-Cb alkylsulfonyl" represents an alkyl-S(O)2 group having from a to b carbon atoms, as defined above, and, for example, a methylsulfonyl group, an ethylsulfonyl group, a propylsulfonyl group , an isopropylsulfonyl group, a butylsulfonyl group, an iso-butylsulfonyl group, a s-butylsulfonyl group, a tert-butylsulfonyl group, etc. can be mentioned as specific examples, and is selected within the specified range of carbon numbers.
[00148] The notation "tri(Ca-Cb alkyl)silyl" represents a silyl group substituted with alkyl groups each having from a to b carbon atoms, as defined above, which may be the same or different from one another, and , for example, a trimethylsilyl group, a triethylsilyl group, a tri(propyl)silyl group, an ethyldimethylsilyl group, a propyldimethylsilyl group, a butyldimethylsilyl group, an isobutyldimethylsilyl group, a tert-butyldimethylsilyl group, etc. can be mentioned as specific examples, and is selected within the specified range of carbon numbers.
[00149] The notation "Ca-Cb alkylcarbonyl" represents an alkyl-C(O)- group having from a to b carbon atoms, as defined above, and, for example, an acetyl group, a propionyl group, a butyryl group , an isobutyryl group, a valeryl group, an isovaleryl group, a 2-methyl butanoyl group, a pivaloyl group, etc. can be mentioned as specific examples, and is selected within the specified range of carbon numbers.
[00150] The notation "Ca-Cb alkoxycarbonyl" represents an alkyl-OC(O)- group having from a to b carbon atoms, as defined above, and, for example, a methoxycarbonyl group, an ethoxycarbonyl group, a propyloxycarbonyl group , an isopropyloxycarbonyl group, a butoxycarbonyl group, an isobutoxycarbonyl group, a tert-butoxycarbonyl group, etc. can be mentioned as specific examples, and is selected within the specified range of carbon numbers.
[00151] The notation "(Ca-Cb) alkyl substituted with R10" represents an alkyl group having from a to b carbon atoms, as defined above, where a hydrogen atom bonded to a carbon atom is replaced with optional R10, and is selected within the specified range of number of carbon atoms.
[00152] The notation "hydroxy(Cd-Ce)cycloalkyl" or "Ca-Cb alkoxy(Cd-Ce)cycloalkyl" represents a cycloalkyl group as defined above, having d and carbon atoms, where a hydrogen atom bonded to a carbon atom is optionally substituted with a hydroxy group or with an optional Ca-Cb alkoxy group as defined above, respectively, and is selected within the specified range of number of carbon atoms.
[00153] The notation "(Ca-Cb) alkynyl substituted with R6" represents an alkynyl group as defined above, having from a to b carbon atoms, where a hydrogen atom bonded to a carbon atom is replaced with optional R6, and is selected within the specified range of number of carbon atoms.
[00154] Preferred ranges of the respective substituents in the oxime-substituted amide compound represented by the formula (I) to be used as the active ingredient A of the present invention may be optionally combined, they respectively represent the preferred ranges of the compounds to be used as the active ingredient A of the present invention.
[00155] The oxime-substituted amide compound represented by the formula (I) to be used as the active ingredient A in the pesticide composition of the present invention is a known compound disclosed in International Patent Application Publication (WO2014/010737), and specifically , the compounds listed in Table 1 can be mentioned. However, the compounds in Table 1 are exemplary, and the oxime-substituted amide compound to be used as the active ingredient A of the present invention is not limited thereto.
[00156] In the Table, a substituent identified by Et represents an ethyl group, and hereinafter, n-Pr and Pr-n represent an n-propyl group, i-Pr and Pr-i represent an isopropyl group, c-Pr and Pr -c represent a cyclopropyl group, n-Bu and Bu-n represent a normal butyl group, s-Bu and Bu-s represent a secondary butyl group, t-Bu and Bu-t represent a tertiary butyl group, Pen- c represents a cyclopentyl group, and Ph represents a phenyl group.
[00157] In the Table, the notation "-" in the column for the Y5 substituent indicates that the corresponding substituent is not present.
[00158] In the Table, the notation (R) or (S) in the column for the substituent R2 indicates that the mixing ratio of the optical isomers of the carbon atom to which R2 is attached, form (R)- or form ( S)- is at least 90%, respectively.
[00159] In addition, the notation (E) or (Z) in the column for the R1 substituent indicates that the mixing ratio of the oxime geometric isomers to which the R1 substituent is attached, form (E)- or form ( Z)- is at least 90%, respectively.
[00160] These definitions also apply to the Tables given below. [Table 1]


[00161] In the structural formulas above, the G2 substituent represents the following G2-1 or G2-2.





[00162] Now, specific Synthesis Examples for the oxime substituted amide compounds represented by the formula (I) will be described as the active ingredient A of the present invention, but it should be understood that the synthetic methods are not limited to these examples .
[00163] Here, the chemical shift value of the proton nuclear magnetic resonance (1HRMN) used for the identification of the compounds was measured using Me4Si (tetramethylsilane) as the reference substance, at 300 MHz (model: ECX300 or ECP300, produced by JEOL Ltd.).
[00164] Symbols in the proton nuclear magnetic resonance chemical shift values have the following meanings.
[00165] s: singlet, d: doublet, t: triplet, q: quartet, m: multiplet, br: broad.
[00166] Here, the name of the solvent used in the NMR measurements is shown in parentheses ( ) in the chemical shift value data. Synthesis Example 1 (Z)-N-[2-[3-chloro-5-(cyclopropylethynyl)pyridin-2-yl]-2-(isopropoxy-imino)ethyl]-3-difluoromethyl-1-methyl-1H- pyrazole-4-carboxamide (Compound No. 25). Step 1: Production of 3-chloro-5-(cyclopropylethynyl)pyridine-2-carbonitrile
To a 200 ml solution of 17.37 g of 3,5-dichloropyridine-2-carbonitrile in N,N-dimethylformamide, 50.60 g of triethylamine, 7.90 g of cyclopropyl acetylene, 2.20 g of copper(I) iodide and 2.10 g of dichlorobis(triphenylphosphine)palladium(II) were added. After the addition was complete, the mixture was stirred under a nitrogen atmosphere overnight at room temperature. After completion of the reaction, 500 ml of water was added to the reaction mixture, followed by extraction with ethyl acetate (250 ml x 2). The obtained organic layers were combined and washed with water (500 ml x 1). Thereafter, using in order saturated aqueous sodium chloride and then anhydrous sodium sulfate, dehydration and drying were carried out, and the solvent was removed by distillation under reduced pressure. The obtained residue was purified by column chromatography on silica gel eluting it with ethyl acetate-hexane [1:9 (volume ratio, the same applies hereafter)], to obtain 18.40 g of the desired product as a brown solid.
[00168] 1H NMR (CDCl3, Me4Si, 300 MHz) δ 8.50 (d, J = 1.7 Hz, 1H), 7.77 (d, J = 1.7 Hz, 1H), 1.45- 1.55 (m, 1H), 0.8-1.05 (m, 4H). Step 2: Production of 1-[3-chloro-5-(cyclopropylethynyl)pyridin-2-yl]ethanone
To a solution of 90 ml of 9.0 g of 3-chloro-5-(cyclopropylethynyl)pyridine-2-carbonitrile in tetrahydrofuran, 22 ml of a 3M solution of methylmagnesium bromide in diethyl ether was added in drops with stirring under refrigeration with ice. After completion of dropwise addition, the reaction mixture was stirred at the same temperature for 40 minutes. After completion of the reaction, the reaction mixture was added dropwise to 200 ml of a 1N aqueous hydrochloric acid solution, and the mixture was extracted with ethyl acetate (125 ml x 2). The obtained organic layers were combined and washed with water (100 ml x 1). Then, using in order saturated aqueous sodium chloride and then anhydrous sodium sulfate, dehydration and drying were carried out, and the solvent was removed by distillation under reduced pressure. The obtained residue was purified by column chromatography on silica gel eluting it with ethyl acetate-hexane (1:9), to obtain 9.6 g of the desired product as a brown solid.
[00170] 1H NMR (CDCl3, Me4Si, 300 MHz) δ 8.45 (d, J = 1.7 Hz, 1H), 7.72 (d, J = 1.7 Hz, 1H), 2.67 ( s, 3H), 1.4-1.6 (m, 1H), 0.8-1.05 (m, 4H). Step 3: Production of 2-bromo-1-[3-chloro-5-(cyclopropylethynyl)pyridin-2-yl]ethanone
To a 145 ml solution of 9.6 g of 1-[3-chloro-5-(cyclopropylethynyl)pyridin-2-yl]ethanone in tetrahydrofuran, 16.3 g of trimethylphenylammonium tribromide were added. After the addition was complete, the reaction mixture was stirred at room temperature for 2 hours. After completion of the reaction, the precipitated solid was removed by filtration through Celite. The filtrate obtained was washed with 100 ml of ethyl acetate, and the filtrates were combined, and the solvent was distilled off under reduced pressure. The obtained residue was purified by column chromatography on silica gel eluting it with ethyl acetate-hexane (1:9), to obtain 12.0 g of the desired compound as a pale brown solid.
[00172] 1H NMR (CDCl3, Me4Si, 300 MHz) δ 8.46 (d, J = 1.7 Hz, 1H), 7.76 (d, J = 1.7 Hz, 1H), 4.71 ( s, 2H), 1.4-1.6 (m, 1H), 0.8-1.05 (m, 4H). Step 4: Production of 2-bromo-1-[3-chloro-5-(cyclopropylethynyl)pyridin-2-yl]ethanone-O-isopropyl oxime
To a solution of 10 ml of 1.50 g of 2-bromo-1-[3-chloro-5-(cyclopropylethynyl)pyridin-2-yl]ethanone and 2.28 g of trifluoroacetic acid in dichloromethane, a A 3 ml solution of 1.44 g of N-(isopropoxy)carbamide tert-butyl acid in dichloromethane was added dropwise with stirring under ice-cooling. After completion of dropwise addition, the reaction mixture was stirred at room temperature overnight. After completion of the reaction, the solvent was removed by distillation under reduced pressure. Thereafter, 20 ml of water were added to the obtained residue, and the mixture was extracted with ethyl acetate (15 ml x 2). The obtained organic layers were combined and washed with water (20 ml x 1). Then, using in order saturated aqueous sodium chloride and then anhydrous sodium sulfate, dehydration and drying were carried out, and the solvent was removed by distillation under reduced pressure. The obtained residue was purified by column chromatography on silica gel eluting it with ethyl acetate-hexane (1:4), to obtain 1.57 g of the desired product as a pale yellow oily substance (E/Z = 3/1).
[00174] 1H NMR (CDCl3, Me4Si, 300 MHz) δ 8.49 and 8.47 (d, J = 1.7 Hz, 1H), 7.73 and 7.71 (d, J = 1.7 Hz , 1H), 4.53 and 4.41 (s, 2H), 4.55 and 4.39 (sep, J = 6.1 Hz, 1H), 1.4-1.55 (m, 1H), 1.36 and 1.21 (d, J = 6.1 Hz, 6H), 0.8-1.0 (m, 4H). Step 5: Production of N-[2-[3-chloro-5-(cyclopropylethynyl)pyridin-2-yl]-2-(isopropoxyimino)ethyl]phthalimide
To a solution of 20 ml of 1.57 g of 2-bromo-1-[3-chloro-5-(cyclopropylethynyl)pyridin-2-yl]ethanone-O-isopropyl oxime in N,N-dimethylformamide, 0.88 g of potassium phthalimide was added. After the addition was complete, the reaction mixture was stirred at room temperature overnight. After completion of the reaction, 30 ml of water was added to the reaction mixture, followed by extraction with ethyl acetate (30 ml x 2). The obtained organic layer was washed with water (30 ml x 1), then dehydrated and dried using saturated aqueous sodium chloride and then anhydrous sodium sulfate, and the solvent was distilled off under reduced pressure. The obtained residue was purified by column chromatography on silica gel eluting it with ethyl acetate-hexane (3:7), to obtain 1.50 g of the desired product as a pale yellow solid (E/Z = 3/1) .
[00176] 1H NMR (CDCl3, Me4Si, 300 MHz) δ 8.44 and 8.31 (d, J = 1.8 Hz, 1H), 7.55-7.9 (m, 5H), 4.99 and 4.77 (s, 2H), 4.47 and 4.33 (sep, J = 6.3 Hz, 1H), 1.35-1.55 (m, 1H), 1.26 and 1.13 (d, J = 6.3 Hz, 6H), 0.75-1.0 (m, 4H). Step 6: Production of 2-amino-1-[3-chloro-5-(cyclopropylethynyl)pyridin-2-yl]ethanone-O-isopropyl oxime
To a solution of 20 ml of 1.50 g of N-[2-[3-chloro-5-(cyclopropylethynyl)pyridin-2-yl]-2-(isopropoxyimino)ethyl]phthalimide in ethanol, 533 mg of hydrazine monohydrate was added. After the addition was complete, the reaction mixture was stirred for 2 hours with heating and reflux. After completion of the reaction, the reaction mixture was allowed to cool to room temperature, and the solvent was removed by distillation under reduced pressure. Then 30 ml of water was added, and the mixture was extracted with dichloromethane (20 ml x 2). The obtained organic layers were combined, washed with water (20 ml x 1), then dehydrated and dried using saturated aqueous sodium chloride and then anhydrous sodium sulfate, and the solvent was removed by distillation under reduced pressure to obtain 1.04 g of a desired crude product as a pale yellow oily substance (E/Z = 2/1). This product was used, without further purification, directly in the next step.
[00178] 1H NMR (CDCl3, Me4Si, 300 MHz) δ 8.49 and 8.47 (d, J = 1.7 Hz, 1H), 7.71 and 7.68 (d, J = 1.7 Hz) , 1H), 4.48 and 4.34 (sep, J = 6.3 Hz, 1H), 3.87 and 3.73 (s, 2H), 1.55 (bs, 2H), 1.4- 1.55 (m, 1H), 1.33 and 1.18 (d, J = 6.3 Hz, 6H), 0.8-1.0 (m, 4H). Step 7: Production of N-[2-[3-chloro-5-(cyclopropylethynyl)pyridin-2-yl]-2-(isopropoxyimino)ethyl]-3-difluoromethyl-1-methyl-1H-pyrazol-4 -carboxamide
To a solution of 1 ml of 68 mg of 3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxylic acid in dichloromethane, 10 mg of N,N-dimethylformamide and 66 mg of oxalyl chloride were added. After the addition was complete, the reaction mixture was stirred at room temperature for 1 hour. After completion of the reaction, the solvent was distilled off from the reaction mixture under reduced pressure. The residue obtained was dissolved in 1 ml of dichloromethane and, with stirring under ice-cooling, was added dropwise to a mixed solution of 100 mg of 2-amino-1-[3-chloro-5-(cyclopropylethynyl)pyridin-2 - yl]ethanone-O-isopropyl oxime and 200 mg of potassium carbonate in 2 ml of dichloromethane and 2 ml of water. After completion of dropwise addition, stirring was continued for a further 1 hour at room temperature. After completion of the reaction, 10 ml of water was added to the reaction mixture, followed by extraction with dichloromethane (10 ml x 1). The obtained organic layer was washed with water (10 ml x 1), then dehydrated and dried using saturated aqueous sodium chloride and then anhydrous sodium sulfate, and the solvent was removed by distillation under reduced pressure. The obtained residue was purified by column chromatography on silica gel eluting it with ethyl acetate-hexane (2:3), to obtain 150 mg of the desired product as a pale yellow resinous substance (E/Z = 2/1).
[00180] 1H NMR (CDCl3, Me4Si, 300 MHz) δ 8.45 and 8.43 (d, J = 1.8 Hz, 1H), 7.88 and 7.82 (s, 1H), 7.68 and 7.66 (d, J = 1.8 Hz, 1H), 7.12 (bs, 1H), 6.85 and 6.75 (t, J = 54.2 Hz, 1H), 4.70 and 4.46 (d, J = 6.1, 4.9 Hz, 2H), 4.47 and 4.36 (sep, J = 6.3 Hz, 1H), 3.90 and 3.87 (s, 3H), 1.4-1.55 (m, 1H), 1.32 and 1.18 (d, J = 6.3 Hz, 6H), 0.8-1.0 (m, 4H). Step 8: Production of (Z)-N-[2-[3-chloro-5-(cyclopropylethynyl)pyridin-2-yl]-2-(isopropoxy-imino)ethyl]-3-difluoromethyl-1-methyl-1H -pyrazole-4-carboxamide
[00181] 150 mg of N-[2-[3-chloro-5-(cyclopropylethynyl)pyridin-2-yl]-2-(isopropoxy-imino)ethyl]-3-difluoromethyl-1-methyl-1H-pyrazol- 4-carboxamide (E/Z = 2/1) were dissolved in 4 ml of ethyl acetate and irradiated with light for 8 hours using a high pressure mercury lamp (produced by USHIO INC., lamp UM-102, device illumination lamp UM-103B-B) in a quartz cell (produced by Fine, fully transparent for spectroscopic analysis). After completion of the reaction, the solvent was distilled off from the reaction mixture under reduced pressure. The obtained residue was purified by column chromatography on silica gel eluting it with ethyl acetate-hexane (2:3), to obtain 53 mg of the desired product as white crystals.
[00182] Melting point: 105.0 to 107.0°C
[00183] 1H NMR (CDCl3, Me4Si, 300 MHz) δ 8.45 (d, J = 1.8 Hz, 1H), 7.88 (s, 1H), 7.66 (d, J = 1.8 Hz, 1H), 7.12 (bs, 1H), 6.85 (t, J = 54.2 Hz, 1H), 4.46 (d, J = 4.9 Hz, 2H), 4.35 ( sep, J = 6.3 Hz, 1H), 3.90 (s, 3H), 1.4-1.5 (m, 1H), 1.17 (d, J = 6.3 Hz, 6H), 0.85-0.95 (m, 2H), 0.8-0.85 (m, 2H). Synthesis Example 2 (Z)-N-[2-[3-chloro-5-(1-propynyl)pyridin-2-yl]-2-(isopropoxy-imino)ethyl]-3-difluoromethyl-1-methyl- 1H-pyrazole-4-carboxamide (Compound No. 20). Step 1: Production of 3-chloro-5-(1-propynyl)pyridine-2-carbonitrile
[00184] In a nitrogen atmosphere, 92 ml of a solution of 1-propynyl magnesium bromide in 0.5 M tetrahydrofuran were added dropwise to a 120 ml solution of 10.87 g of zinc (II) bromide ) in tetrahydrofuran, with stirring under ice-cooling. After completion of dropwise addition, the reaction mixture was stirred at the same temperature for 10 minutes. After the stirring had ended, 5.00 g of 3,5-dichloropyridine-2-carbonitrile and 0.94 g of dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II) were added to the reaction mixture. . After the addition was complete, the reaction mixture was continuously stirred at 50°C for 2 hours. After completion of the reaction, the reaction mixture was allowed to cool to room temperature, and then 40 ml of water was added, followed by extraction with ethyl acetate (20 ml x 2). The obtained organic layers were combined, washed with water (40 ml x 1) and then dehydrated and dried using saturated aqueous sodium chloride and then anhydrous sodium sulfate, and the solvent was removed by distillation under reduced pressure. The obtained residue was purified by column chromatography on silica gel eluting it with hexane, to obtain 5.50 g of the desired product as a pale yellow solid.
[00185] 1H NMR (CDCl3, Me4Si, 300 MHz) δ 8.54 (d, J = 1.8 Hz, 1H), 7.80 (d, J = 1.8 Hz, 1H), 2.13 ( s, 3H). Step 2: Production of 1-[3-chloro-5-(1-propynyl)pyridin-2-yl]ethanone
[00186] To a solution of 40 ml of 4.58 g of 3-chloro-5-(1-propynyl)pyridine-2-carbonitrile in tetrahydrofuran, 17 ml of a solution of methylmagnesium bromide in diethyl ether 3M were added dropwise with stirring under ice-cooling. After completion of dropwise addition, the reaction mixture was stirred at the same temperature for 2 hours. After completion of the reaction, the reaction mixture was added dropwise to 30 ml of water, and the mixture was extracted with ethyl acetate (15 ml x 2). The obtained organic layers were combined, washed with water (30 ml x 1) and then dehydrated and dried using saturated aqueous sodium chloride and then anhydrous sodium sulfate, and the solvent was removed by distillation under reduced pressure to obtain 4.76 g of a crude desired product as a black solid. This product was used, without further purification, directly in the next step.
[00187] 1H NMR (CDCl3, Me4Si, 300 MHz) δ 8.49 (d, J = 1.7 Hz, 1H), 7.75 (d, J = 1.7 Hz, 1H), 2.69 ( s, 3H), 2.12 (s, 3H). Step 3: Production of 2-bromo-1-[3-chloro-5-(1-propynyl)pyridin-2-yl]ethanone
[00188] To a solution of 30 ml of 4.76 g of 1-[3-chloro-5-(1-propynyl)pyridin-2-yl]ethanone in acetonitrile, 9.27 g of trimethylphenylammonium tribromide was added. After the addition was complete, the reaction mixture was stirred at 50°C for 1 hour. After completion of the reaction, the reaction mixture was allowed to cool to room temperature, then 50 ml of water was added, and the mixture was extracted with ethyl acetate (30 ml x 2). The obtained organic layers were combined, washed with water (30 ml x1) and then dehydrated and dried using saturated aqueous sodium chloride and then anhydrous sodium sulfate, and the solvent was removed by distillation under reduced pressure. The obtained residue was purified by column chromatography on silica gel eluting it with hexane, to obtain 3.20 g of the desired product as a black solid.
[00189] 1H NMR (CDCl3, Me4Si, 300 MHz) δ 8.50 (d, J = 1.7 Hz, 1H), 7.80 (d, J = 1.7 Hz, 1H), 4.73 ( s, 2H), 2.14 (s, 3H). Step 4: Production of 2-bromo-1-[3-chloro-5-(1-propynyl)pyridin-2-yl]ethanone-O-isopropyl oxime
To a solution of 10 ml of 2.00 g of 2-bromo-1-[3-chloro-5-(1-propynyl)pyridin-2-yl]ethanone and 3.35 g of trifluoroacetic acid in di - chloromethane, a solution of 3 ml of 1.41 g of N-(isopropoxy)carbamide ter-butyl acid in dichloromethane were added dropwise with stirring under ice-cooling. After completion of dropwise addition, the reaction mixture was stirred at room temperature overnight. After completion of the reaction, the solvent was distilled off from the reaction mixture under reduced pressure. To the obtained residue, 30 ml of water were added, and the mixture was extracted with ethyl acetate (15 ml x 2). The obtained organic layers were combined, washed with water (30 ml x 1) and then dehydrated and dried using saturated aqueous sodium chloride and then anhydrous sodium sulfate, and the solvent was removed by distillation under reduced pressure. The obtained residue was purified by column chromatography on silica gel eluting it with ethyl acetate-hexane (1:9), to obtain 1.90 g of the desired product as a pale yellow oily substance (E/Z = 3/1 ).
[00191] 1H NMR (CDCl3, Me4Si, 300 MHz) δ 8.51 and 8.49 (d, J = 1.7 Hz, 1H), 7.75 and 7.72 (d, J = 1.7 Hz , 1H), 4.54 and 4.41 (s, 2H), 4.56 and 4.40 (sep, J = 6.5 Hz, 1H), 2.10 (s, 3H), 1.37 and 1.22 (d, J = 6.5 Hz, 6H). Step 5: Production of N-[2-[3-chloro-5-(1-propynyl)pyridin-2-yl]-2-(isopropoxyimino)ethyl]phthalimide
To a solution of 20 ml of 1.90 g of 2-bromo-1-[3-chloro-5-(1-propynyl)pyridin-2-yl]ethanone-O-isopropyl oxime in N,N- dimethylformamide, 0.96 g of potassium phthalimide was added. After the addition was complete, the reaction mixture was stirred at room temperature overnight. After completion of the reaction, 30 ml of water was added to the reaction mixture, followed by extraction with ethyl acetate (20 ml *2). The obtained organic layer was washed with water (30 ml *1) and then dehydrated and dried using saturated aqueous sodium chloride and then anhydrous sodium sulfate, and the solvent was distilled off under reduced pressure. The obtained residue was purified by column chromatography on silica gel eluting it with ethyl acetate-hexane (3:7), to obtain 1.49 g of the desired product as a pale yellow solid (E/Z = 3/1) .
[00193] Melting point: 110.0 to 113.0°C
[00194] 1H NMR (CDCl3, Me4Si, 300 MHz) δ 8.44 and 8.31 (d, J = 1.8 Hz, 1H), 7.6-7.9 (m, 5H), 4.98 and 4.77 (s, 2H), 4.46 and 4.32 (sep, J = 6.4 Hz, 1H), 2.07 and 2.05 (s, 3H), 1.25 and 1.12 (d, J = 6.4 Hz, 6H). Step 6: Production of 2-amino-1-[3-chloro-5-(1-propynyl)pyridin-2-yl]ethanone-O-isopropyl oxime
[00195] To a solution of 20 ml of 1.49 g of N-[2-[3-chloro-5-(1-propynyl)pyridin-2-yl]-2-(isopropoxy-imino)ethyl]phthalimide in ethanol, 565 mg of hydrazine monohydrate was added. After the addition was complete, the reaction mixture was stirred for 3 hours with heating and reflux. After completion of the reaction, the reaction mixture was allowed to cool to room temperature, and the solvent was distilled off under reduced pressure. Then 20 ml of water was added, and the mixture was extracted with chloroform (20 ml *2). The obtained organic layers were combined, washed with water (20 ml *1) and then dehydrated and dried using saturated aqueous sodium chloride and then anhydrous sodium sulfate, and the solvent was removed by distillation under reduced pressure to obtain 1.04 g of a desired crude product as a pale yellow oily substance (E/Z = 5/2). This product was used, without further purification, directly in the next step.
[00196] 1H NMR (CDCl3, Me4Si, 300 MHz) δ 8.51 and 8.49 (d, J = 2.0 Hz, 1H), 7.73 and 7.70 (d, J = 2.0 Hz , 1H), 4.48 and 4.35 (sep, J = 6.3 Hz, 1H), 3.88 and 3.73 (s, 2H), 2.10 (s, 3H), 1.56 ( bs, 2H), 1.33 and 1.19 (d, J = 6.3 Hz, 6H). Step 7: Production of N-[2-[3-chloro-5-(1-propynyl)pyridin-2-yl]-2-(isopropoxyimino)ethyl]-3-difluoromethyl-1-methyl-1H-pyrazole -4-carboxamide
To a solution of 1 ml of 88 mg of 3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxylic acid in dichloromethane, 10 mg of N,N-dimethylformamide and 57 mg of oxalyl chloride were added. After the addition was complete, the reaction mixture was stirred at room temperature for 1 hour. After completion of the reaction, the solvent was removed by distillation under reduced pressure. Thereafter, the residue obtained was dissolved in 1 ml of dichloromethane and added dropwise, with stirring under ice-cooling, to a mixed solution of 80 mg of 2-amino-1-[3-chloro-5-(1-propynyl )pyridin-2-yl]ethanone-O-isopropyl oxime and 124 mg of potassium carbonate in 2 ml of dichloromethane and 2 ml of water. After completion of dropwise addition, the reaction mixture was further stirred at room temperature for 1 hour. After completion of the reaction, 10 ml of water was added to the reaction mixture, followed by extraction with dichloromethane (10 ml x 1). The organic layer was washed with water (10 ml x 1) and then dehydrated and dried using saturated aqueous sodium chloride and then anhydrous sodium sulfate, and the solvent was distilled off under reduced pressure. The obtained residue was purified by column chromatography on silica gel eluting it with ethyl acetate-hexane (3:5), to obtain 185 mg of the desired product as a pale yellow resinous substance (E/Z = 2/1).
[00198] 1H NMR (CDCl3, Me4Si, 300 MHz) δ 8.51 and 8.47 (d, J = 1.7 Hz, 1H), 7.91 and 7.85 (s, 1H), 7.71 and 7.70 (d, J = 1.7 Hz, 1H), 7.14 (bs, 1H), 6.88 and 6.77 (t, J = 54.0 Hz, 1H), 4.73 and 4.49 (d, J = 5.8, 4.9 Hz, 2H), 4.50 and 4.39 (sep, J = 6.3 Hz, 1H), 3.93 and 3.89 (s, 3H), 2.09 and 2.05 (s, 3H), 1.35 and 1.21 (d, J = 6.3 Hz, 6H). Step 8: Production of (Z)-N-[2-[3-chloro-5-(1-propynyl)pyridin-2-yl]-2-(isopropoxy-imino)ethyl]-3-difluoromethyl-1-methyl -1H-pyrazole-4-carboxamide
[00199] 185 mg of N-[2-[3-chloro-5-(1-propynyl)pyridin-2-yl]-2-(isopropoxy-imino)ethyl]-3-difluoromethyl-1-methyl-1H- pyrazole-4-carboxamide (E/Z = 2/1) were dissolved in 4 ml of ethyl acetate and irradiated with light for 8 hours using a 100 W high pressure mercury lamp (produced by USHIO INC., lamp UM-102, illumination device UM-103B-B) in a quartz cell (produced by Fine, fully transparent for spectroscopic analysis). After completion of the reaction, the solvent was removed by distillation under reduced pressure, and then, the residue obtained was purified by column chromatography on silica gel, eluting it with ethyl acetate-hexane (3:5), to obtain 71 mg of the desired product as white crystals.
[00200] Melting point: 102.0 to 103.0°C
[00201] 1H NMR (CDCl3, Me4Si, 300 MHz) δ 8.51 (d, J = 1.7 Hz, 1H), 7.91 (s, 1H), 7.70 (d, J = 1.7 Hz, 1H), 7.14 (bs, 1H), 6.88 (t, J = 54.0 Hz, 1H), 4.49 (d, J = 4.9 Hz, 2H), 4.39 ( sep, J = 6.3 Hz, 1H), 3.93 (s, 3H), 2.09 (s, 3H), 1.21 (d, J = 6.3 Hz, 6H). Synthesis Example 3 (Z)-N-[2-[3,5-dichloro-4-(methoxy)pyridin-2-yl]-2-(methoxyimino)ethyl]-2-(trifluoromethyl)benzamide (Compound No. 8). Step 1: Production of N-[2-[3,5-dichloro-4-(methoxy)pyridin-2-yl]-2-oxoethyl]carbamide ter-butyl acid
[00202] To 52.7 ml of a solution of a 2,2,6,6-tetramethylpiperidinyl magnesium chloride-lithium chloride complex in 1.0 M tetrahydrofuran-toluene in a nitrogen atmosphere, a solution of 15 ml of 8.9 g of 3,5-dichloro-4-(methoxy)pyridine in tetrahydrofuran was added dropwise with stirring at -20°C. After completion of dropwise addition, the reaction mixture was stirred at -15°C for 45 minutes. After cessation of stirring, a solution of 15 ml of 5.0 g of N-methoxy-N-methyl-2-(tert-butoxycarbonylamino)acetamide in tetrahydrofuran was added dropwise. After completion of dropwise addition, the reaction mixture was further stirred at 0°C for 2.5 hours. After completion of the reaction, 30 ml of a saturated aqueous solution of ammonium chloride and 20 ml of water were added to the reaction mixture, followed by extraction with ethyl acetate (100 ml x 2). The obtained organic layers were combined, washed with water (50 ml x 1) and then dehydrated and dried using saturated aqueous sodium chloride and then anhydrous sodium sulfate, and the solvent was removed by distillation under reduced pressure. The obtained residue was purified by column chromatography on silica gel eluting it with ethyl acetate-hexane (gradient from 5:95 to 50:50) to obtain 2.8 g of the desired product as pale yellow crystals.
[00203] Melting point: 59.0 to 60.0°C
[00204] 1H NMR (CDCl3, Me4Si, 300 MHz) δ 8.48 (s, 1H), 5.30 (bs, 1H), 4.73 (d, J = 4.8 Hz, 2H), 4, 04 (s, 3H), 1.47 (s, 9H). Step 2: Production of tert-butyl N-[2-[3,5-dichloro-4-(methoxy)pyridin-2-yl]-2-(methoxyimino)ethyl]carbamate
To a solution of 10.4 ml of 1.4 g of tert-butyl N-[2-[3,5-dichloro-4-(methoxy)pyridin-2-yl]-2-oxoethyl]carbamate and 698 mg of methoxyamine hydrochloride in ethanol, 825 mg of pyridine was added. After the addition was complete, the reaction mixture was stirred at room temperature for 18 hours. After completion of the reaction, the solvent was distilled off from the reaction mixture under reduced pressure. After that, to the obtained residue, 5 ml of water were added, followed by extraction with ethyl acetate (5 ml x 2). The obtained organic layers were combined, dehydrated and dried using saturated aqueous sodium chloride and then anhydrous sodium sulfate, and the solvent was removed by distillation under reduced pressure. The obtained residue was purified by column chromatography on silica gel eluting it with ethyl acetate-hexane (gradient from 5:95 to 50:50) to obtain 1.4 g of the desired product as a pale yellow oily substance.
1H NMR (CDCl3, Me4Si, 300 MHz) δ 8.46 and 8.44 (s, 1H), 5.04 and 4.97 (bs, 1H), 3.8-4.45 (m, 8H), 1.38 and 1.33 (s, 9H). Step 3: Production of 2-amino-1-[3,5-dichloro-4-(methoxy)pyridin-2-yl]ethanone-O-methyloxime trifluoroacetate
To 1.4 g of tert-butyl N-[2-[3,5-dichloro-4-(methoxy)pyridin-2-yl]-2-(methoxyimino)ethyl]carbamate, 15 were added. ml of trifluoroacetic acid. After the addition was complete, the reaction mixture was stirred at room temperature for 1 hour. After completion of the reaction, the solvent was distilled off from the reaction mixture under reduced pressure, to obtain 2.8 g of a desired crude product (approximately 40% trifluoroacetic acid solution) as a brown oily substance.
1H NMR (CDCl3, Me4Si, 300 MHz) δ 8.48 and 8.45 (s, 1H), 7.86 (bs, 2H), 3.9-4.35 (m, 8H). Step 4: Production of N-[2-[3,5-dichloro-4-(methoxy)pyridin-2-yl]-2-(methoxyimino)ethyl]-2-(trifluoromethyl)benzamide
To a solution of 330 mg of 2-amino-1-[3,5-dichloro-4-(methoxy)pyridin-2-yl]ethanone-O-methyloxime trifluoroacetate in 1 ml of water and 1 ml of dichloromethane With stirring at room temperature, 125 mg of 2-(trifluoromethyl)benzoyl chloride and 276 mg of potassium carbonate were added. After the addition was complete, the reaction mixture was stirred at room temperature for 1 hour. After completion of the reaction, the organic layer was separated and dried over anhydrous sodium sulfate, and the solvent was distilled off under reduced pressure. The obtained residue was purified by column chromatography on silica gel eluting it with ethyl acetate-hexane (gradient from 5:95 to 50:50) to obtain 140 mg of the desired product as a colorless resinous substance.
[00210] 1H NMR (CDCl3, Me4Si, 300 MHz) δ 8.47 and 8.43 (s, 1H), 7.35-7.75 (m, 4H), 6.49 and 6.41 (bs, 1H), 4.74 and 4.53 (d, J = 5.4 Hz, 2H), 3.85-4.1 (m, 6H). Step 5: Production of (Z)-N-[2-[3,5-dichloro-4-(methoxy)pyridin-2-yl]-2-(methoxyimino)ethyl]-2-(trifluoromethyl)benzamide
140 mg of N-[2-[3,5-dichloro-4-(methoxy)pyridin-2-yl]-2-(methoxyimino)ethyl]-2-(trifluoromethyl)benzamide was dissolved in 3 .5 ml of ethyl acetate and irradiated with light for 18 hours using a 100 W high pressure mercury lamp (produced by USHIO INC., lamp UM-102, lighting device UM-103B-B) in a cell of quartz (produced by Fine, fully transparent for spectroscopic analysis). After completion of the reaction, the solvent was distilled off under reduced pressure to obtain 140 mg of the desired product as white crystals.
[00212] Melting point: 74.0 to 76.0°C
1H NMR (CDCl3, Me4Si, 300 MHz) δ 8.47 (s, 1H), 7.5-7.75 (m, 4H), 6.47 (bs, 1H), 4.53 (d , J = 5.1 Hz, 2H), 4.06 (s, 3H), 3.88 (s, 3H).
[00214] In Table 2, more specific examples of the oxime substituted amide compound represented by the formula (I) to be used as the active ingredient A of the present invention will be shown, which can be prepared in the same manner as in Synthetic Examples 1 to 3, but the oxime substituted amide compound to be used as the active ingredient A of the present invention is not limited thereto.
[00215] In the Table, "*1" in the column for melting point means that the compound property was oily or resinous. [Table 2]

The G1 substituent represents the following G1-1a, G1-3a, G1-3b, G1-27a or G1-33a.


[00217] Among the oxime-substituted amide compounds of formula (I) shown in Table 2, the 1H NMR data of the compounds, whose properties were resinous, are shown in Table 3. [Table 3]




[00218] As the fungicidal or bactericidal active compound known to be used as the active ingredient B of the present invention, for example, compounds selected from each of the following groups can be mentioned.









[00219] Now, examples of the combination of [active ingredient A] selected from oxime substituted amide compounds represented by formula (I) and [active ingredient B] selected from known fungicidal or bactericidal compounds, which exhibit a synergistic effect of disease control, will be given below.
[00220] In the notations below, for example, the notation "1+(A01)" represents a combination of active ingredient A being the compound of No. 1 in Table 2, and active ingredient B being benalaxyl of No. A01 in the Table 4.
[00221] Examples of the combination of compounds: "1+(A01)", "1+(A02)", "1+(A03)", "1+(A04)", "1+(A05)", " 1+(A06)", "1+(A07)", "1+(A08)", "1+(A09)", "1+(A10)", "1+(A11)", "1+ (A12)", "1+(B01)", "1+(B02)", "1+(B03)", "1+(B04)", "1+(B05)", "1+(B06) )", "1+(B07)", 1+(B08)", "1+(B09)", "1+(B10)", "1+(B11)", "1+(B12)", "1+(C01) 1+(C02)", "1+(C03)", "1+(C04)", "1+(C05)", "1+(C06)", "1+(C07) ) 1+(C08)", "1+(C09)", "1+(C10)", "1+(C11)", "1+(C12)", "1+(C13) 1+(C14 )", "1+(C15)", "1+(C16)", "1+(C17)", "1+(C18)", "1+(C19) 1+(C20)", "1 +(C21)", "1+(C22)", "1+(C23)", "1+(C24)", "1+(C25) 1+(C26)", "1+(C27)" , "1+(C28)", "1+(C29)", "1+(C30)", "1+(C31) 1+(C32)", "1+(C33)", "1+( C34)", "1+(C35)", "1+(C36)", "1+(C37) 1+(C38)", "1+(C39)", "1+(C40)", " 1+(C41)", "1+(C42)", "1+(C43) 1+(C44)", "1+(C45)", "1+(C46)", "1+(C47) ", "1+(C48)", "1+(D01) 1+(D02)", "1+(D03)", "1+(D04)", "1+(D05)", "1+ (E01)", "1+(E02) 1+(E03)", "1+(E04)", "1+(E05)", "1+(F01)", "1+(F02)", "1+(F03) 1+(G01)", "1+(G02)", "1+(G03)", "1+(G04)", "1+(G05)", "1+(G06) 1+(G07)", "1+(G08)", "1+(G09)", "1+(G10)", "1+(G11)", "1+(G12) ) 1+(G13)", "1+(H01)", "1+(H02)", "1+(H03)", "1+(H04)", "1+(H05) 1+(H06 )", "1+(H07)", "1+(H08)", "1+(H09)", "1+(H10)", "1+(H11) 1+(H12)", "1 +(H13)", "1+(H14)", "1+(H15)", "1+(H16)", "1+(H17) 1+(H18)", "1+(H19)" , "1+(H20)", "1+(H21)", "1+(H22)", "1+(H23) 1+(H24)", "1+(H25)", "1+( H26)", "1+(H27)", "1+(H28)", "1+(H29) 1+(H30)", "1+(H31)", "1+(H32)", " 1+(H33)", "1+(H34)", "1+(H35) 1+(H36)", "1+(H37)", "1+(H38)", "1+(H39) ", "1+(H40)", "1+(H41) 1+(H42)", "1+(H43)", "1+(H44)", "1+(H45)", "1+ (H46)", "1+(H47) 1+(H48)", "1+(H49)", "1+(H50)", "1+(I01)", "1+(I02)", "1+(I03) 1+(I04)", "1+(I05)", "1+(I06)", "1+(I07)", "1+(I08)", "1+(I09) )" , "1+(I10) 1+(J01)", "1+(J02)", "1+(J03)", "1+(J04)", "1+(J05)", "1 +(J06) 1+(K01)", "1+(K02)", "1+(K03)", "1+(K04)", "1+(K05)", "1+(K06) 1 +(K07)", "1+(K08)", "1+(K09)", "1+(K10)", "1+(K11)", "1+(K12) 1+(K13)" , "1+(K14)", "1+(L01)", "1+(L02)", "1+(L03)", "1+(L04) 1+(L05)", "1+( L06)", "1+(L07)", " 1+(L08)", "1+(L09)", "1+(L10) 1+(L11)", "1+(L12)", "1+(L13)", "1+(L14) ", "1+(L15)", "1+(L16) 1+(L17)", "1+(L18)", "1+(L19)", "1+(L20)", "1+ (L21)", "1+(L22) "1+(L23)", "1+(L24)", "1+(L25)", "1+(L26)", "1+(L27)" , "1+(L28)", "1+(L29)", "1+(L30)", "1+(L31)", "1+(L32)", "1+(L33)", " 1+(L34)", "1+(M01)", "1+(M02)", "1+(M03)", "1+(M04)", "1+(M05)", "1+ (M06)", "1+(M07)", "1+(M08)", "1+(M09)", "1+(M10)", "1+(M11)", "1+(M12) )", "1+(M13)", "1+(M14)", "1+(M19)", "1+(M20)", "1+(M15)", "1+(M16)" , "1+(M17)", "1+(M21)", "1+(M22)", "1+(M23)" "1+(M18)",
[00222] "2+(A01)", "2+(A02)", "2+(A03)", "2+(A04)", "2+(A05)", "2+(A06)" , "2+(A07)", "2+(A08)", "2+(A09)", "2+(A10)", "2+(A11)", "2+(A12)", " 2+(B01)", "2+(B02)", "2+(B03)", "2+(B04)", "2+(B05)", "2+(B06)", "2+ (B07)", "2+(B08)", "2+(B09)", "2+(B10)", "2+(B11)", "2+(B12)", "2+(C01) )", "2+(C02)", "2+(C03)", "2+(C04)", "2+(C05)", "2+(C06)", "2+(C07)" , "2+(C08)", "2+(C09)", "2+(C10)", "2+(C11)", "2+(C12)", "2+(C13)", " 2+(C14)", "2+(C15)", "2+(C16)", "2+(C17)", "2+(C18)", "2+(C19)", "2+ (C20)", "2+(C21)", "2+(C22)", "2+(C23)", "2+(C24)", "2+(C25)", "2+(C26) )", "2+(C27)", "2+(C28)", "2+(C29)", "2+(C30)", "2+(C31)", "2+(C32)" , "2+(C33)", "2+(C34)", "2+(C35)", "2+(C36)", "2+(C37)", "2+(C38)", " 2+(C39)", "2+(C40)", "2+(C41)", "2+(C42)", "2+(C43)", "2+(C44)", "2+ (C45)", "2+(C46)", "2+(C47)", "2+(C48)", "2+(D01)", "2+(D02)", "2+(D03) )", "2+(D04)", "2+(D05)", "2+(E01)", "2+(E02)", "2+(E03)", "2+(E04)" , "2+(E05)", "2+(F01)", "2+(F02)", "2+(F03)", "2+(G01)", "2+(G02)", " 2+(G03)", "2+(G04)", "2+(G05)", "2 +(G06)", "2+(G07)", "2+(G08)", "2+(G09)", "2+(G10)", "2+(G11)", "2+( G12)", "2+(G13)", "2+(H01)", "2+(H02)", "2+(H03)", "2+(H04)", "2+(H05) ", "2+(H06)", "2+(H07)", "2+(H08)", "2+(H09)", "2+(H10)", "2+(H11)", "2+(H12)", "2+(H13)", "2+(H14)", "2+(H15)", "2+(H16)", "2+(H17)", "2 +(H18)", "2+(H19)", "2+(H20)", "2+(H21)", "2+(H22)", "2+(H23)", "2+( H24)", "2+(H25)", "2+(H26)", "2+(H27)", "2+(H28)", "2+(H29)", "2+(H30) ", "2+(H31)", "2+(H32)", "2+(H33)", "2+(H34)", "2+(H35)", "2+(H36)", "2+(H37)", "2+(H38)", "2+(H39)", "2+(H40)", "2+(H41)", "2+(H42)", "2 +(H43)", "2+(H44)", "2+(H45)", "2+(H46)", "2+(H47)", "2+(H48)", "2+( H49)", "2+(H50)", "2+(I01) "2+(I02)", "2+(I03)", "2+(I04)", "2+(I05)", "2+(I06)", "2+(I07) , "2+(I08) "2+(I09)", "2+(I10)", "2+(J01)", "2+(J02) )", "2+(J03)", "2+(J04) "2+(J05)", "2+(J06)", "2+(K01)", "2+(K02)", " 2+(K03)", "2+(K04) "2+(K05)", "2+(K06)", "2+(K07)", "2+(K08)", "2+(K09) )", "2+(K10) "2+(K11)", "2+(K12)", "2+(K13)", "2+(K14)", "2+(L01)", " 2+(L02) "2+(L03)", "2+(L04)", " 2+(L05)", "2+(L06)", "2+(L07)", "2+(L08) "2+(L09)", "2+(L10)", "2+(L11) )", "2+(L12)", "2+(L13)", "2+(L14) "2+(L15)", "2+(L16)", "2+(L17)", " 2+(L18)", "2+(L19)", "2+(L20) "2+(L21)", "2+(L22)", "2+(L23)", "2+(L24) )", "2+(L25)", "2+(L26) "2+(L27)", "2+(L28)", "2+(L29)", "2+(L30)", " 2+(L31)", "2+(L32) "2+(L33)", "2+(L34)", "2+(M01)", "2+(M02)", "2+(M03) )", "2+(M04) "2+(M05)", "2+(M06)", "2+(M07)", "2+(M08)", "2+(M09)", " 2+(M10) "2+(M11)", "2+(M12)", "2+(M13)", "2+(M14)", "2+(M15)", "2+(M16) ) "2+(M17)", "2+(M18)", "2+(M19)", "2+(M20)", "2+(M21)", "2+(M22) "2+ (M23)"
[00223] "3+(A01)", "3+(A02)", "3+(A03)", "3+(A04)", "3+(A05) "3+(A06)", " 3+(A07)", "3+(A08)", "3+(A09)", "3+(A10)", "3+(A11) "3+(A12)", "3+(B01) )", "3+(B02)", "3+(B03)", "3+(B04)", "3+(B05) "3+(B06)", "3+(B07)", " 3+(B08)", "3+(B09)", "3+(B10)", "3+(B11) "3+(B12)", "3+(C01)", "3+(C02) )", "3+(C03)", "3+(C04)", "3+(C05) "3+(C06)", "3+(C07)", "3+(C08)", " 3+(C09)", "3+(C10)", "3+(C11) "3+(C12)", "3+(C13)", "3+(C14)", "3+(C15) )", "3+(C16)", "3+(C17) "3+(C18)", "3+(C19)", "3+(C20)", "3+(C21)", " 3+(C22)", "3+(C23) "3+(C24)", "3+(C25)", "3+(C26)", "3+(C27)", "3+(C28) )", "3+(C29) "3+(C30)", "3+(C31)", "3+(C32)", "3+(C33)", "3+(C34)", " 3+(C35) "3+(C36)", "3+(C37)", "3+(C38)", "3+(C39)", "3+(C40)", "3+(C41) ) "3+(C42)", "3+(C43)", "3+(C44)", "3+(C45)", "3+(C46)", "3+(C47) "3+ (C48)", "3+(D01)", "3+(D02)", "3+(D03)", "3+(D04)", "3+(D05) "3+(E01)" , "3+(E02)", "3+(E03)", "3+(E04)", "3+(E05)", "3+(F01) "3+(F02)", "3+ (F03)", "3+(G01)", "3+(G02)", "3+(G03)", "3+(G04)", "3+(G05)", "3+(G06) )", "3+(G07)", "3+(G08) )", "3+(G09)", "3+(G10)", "3+(G11)", "3+(G12)", "3+(G13)", "3+(H01)" , "3+(H02)", "3+(H03)", "3+(H04)", "3+(H05)", "3+(H06)", "3+(H07)", " 3+(H08)", "3+(H09)", "3+(H10)", "3+(H11)", "3+(H12)", "3+(H13)", "3+ (H14)", "3+(H15)", "3+(H16)", "3+(H17)", "3+(H18)", "3+(H19)", "3+(H20) )", "3+(H21)", "3+(H22)", "3+(H23)", "3+(H24)", "3+(H25)", "3+(H26)" , "3+(H27)", "3+(H28)", "3+(H29)", "3+(H30)", "3+(H31)", "3+(H32)", " 3+(H33)", "3+(H34)", "3+(H35)", "3+(H36)", "3+(H37)", "3+(H38)", "3+ (H39)", "3+(H40)", "3+(H41)", "3+(H42)", "3+(H43)", "3+(H44)", "3+(H45) )", "3+(H46)", "3+(H47)", "3+(H48)", "3+(H49)", "3+(H50)", "3+(I01)" , "3+(I02)", "3+(I03)", "3+(I04)", "3+(I05)", "3+(I06)", "3+(I07) , "3 +(I08)", "3+(I09)", "3+(I10)", "3+(J01)", "3+(J02)", "3+(J03)", "3+( J04)", "3+(J05)", "3+(J06)", "3+(K01)", "3+(K02)", "3+(K03)", "3+(K04) ", "3+(K05)", "3+(K06)", "3+(K07)", "3+(K08)", "3+(K09)", "3+(K10)", "3+(K11)", "3+(K12)", "3+(K13)", "3+(K14)", "3+(L01)", "3+(L02)", "3 +(L03)", "3+(L04)", "3+(L05)", "3+(L0) 6)", "3+(L07)", "3+(L08)", "3+(L09)", "3+(L10)", "3+(L11)", "3+(L12) ", "3+(L13)", "3+(L14)", "3+(L15)", "3+(L16)", "3+(L17)", "3+(L18)", "3+(L19)", "3+(L20)", "3+(L21)", "3+(L22)", "3+(L23)", "3+(L24)", "3 +(L25)", "3+(L26)", "3+(L27)", "3+(L28)", "3+(L29)", "3+(L30)", "3+( L31)", "3+(L32)", "3+(L33)", "3+(L34)", "3+(M01)", "3+(M02)", "3+(M03) ", "3+(M04)", "3+(M05)", "3+(M06)", "3+(M07)", "3+(M08)", "3+(M09)", "3+(M10)", "3+(M11)", "3+(M12)", "3+(M13)", "3+(M14)", "3+(M15)", "3 +(M16)", "3+(M17)", "3+(M18)", "3+(M19)", "3+(M20)", "3+(M21)", "3+( M22)", "3+(M23)",
[00224] "4+(A01)", "4+(A02)", "4+(A03)", "4+(A04)", "4+(A05)", "4+(A06)" , "4+(A07)", "4+(A08)", "4+(A09)", "4+(A10)", "4+(A11)", "4+(A12)", " 4+(B01)", "4+(B02)", "4+(B03)", "4+(B04)", "4+(B05)", "4+(B06)", "4+ (B07)", "4+(B08)", "4+(B09)", "4+(B10)", "4+(B11)", "4+(B12)", "4+(C01) )", "4+(C02)", "4+(C03)", "4+(C04)", "4+(C05)", "4+(C06)", "4+(C07)" , "4+(C08)", "4+(C09)", "4+(C10)", "4+(C11)", "4+(C12)", "4+(C13)", " 4+(C14)", "4+(C15)", "4+(C16)", "4+(C17)", "4+(C18)", "4+(C19)", "4+ (C20)", "4+(C21)", "4+(C22)", "4+(C23)", "4+(C24)", "4+(C25)", "4+(C26) )", "4+(C27)", "4+(C28)", "4+(C29)", "4+(C30)", "4+(C31)", "4+(C32)" , "4+(C33)", "4+(C34)", "4+(C35)", "4+(C36)", "4+(C37)", "4+(C38)", " 4+(C39)", "4+(C40)", "4+(C41)", "4+(C42)", "4+(C43)", "4+(C44)", "4+ (C45)", "4+(C46)", "4+(C47)", "4+(C48)", "4+(D01)", "4+(D02)", "4+(D03) )", "4+(D04)", "4+(D05)", "4+(E01)", "4+(E02)", "4+(E03)", "4+(E04)" , "4+(E05)", "4+(F01)", "4+(F02)", "4+(F03)", "4+(G01)", "4+(G02)", " 4+(G03)", "4+(G04)", "4+(G05)", " 4+(G06)", "4+(G07)", "4+(G08)", "4+(G09)", "4+(G10)", "4+(G11)", "4+ (G12)", "4+(G13)", "4+(H01)", "4+(H02)", "4+(H03)", "4+(H04)", "4+(H05) )", "4+(H06)", "4+(H07)", "4+(H08)", "4+(H09)", "4+(H10)", "4+(H11)" , "4+(H12)", "4+(H13)", "4+(H14)", "4+(H15)", "4+(H16)", "4+(H17)", " 4+(H18)", "4+(H19)", "4+(H20)", "4+(H21)", "4+(H22)", "4+(H23)", "4+ (H24)", "4+(H25)", "4+(H26)", "4+(H27)", "4+(H28)", "4+(H29)", "4+(H30) )", "4+(H31)", "4+(H32)", "4+(H33)", "4+(H34)", "4+(H35)", "4+(H36)" , "4+(H37)", "4+(H38)", "4+(H39)", "4+(H40)", "4+(H41)", "4+(H42)", " 4+(H43)", "4+(H44)", "4+(H45)", "4+(H46)", "4+(H47)", "4+(H48)", "4+ (H49)", "4+(H50)", "4+(I01)", "4+(I02)", "4+(I03)", "4+(I04)", "4+(I05) )", "4+(I06)", "4+(I07)" , "4+(I08)", "4+(I09)", "4+(I10)", "4+(J01)" , "4+(J02)", "4+(J03)", "4+(J04)", "4+(J05)", "4+(J06)", "4+(K01)", " 4+(K02)", "4+(K03)", "4+(K04)", "4+(K05)", "4+(K06)", "4+(K07)", "4+ (K08)", "4+(K09)", "4+(K10)", "4+(K11)", "4+(K12)", "4+(K13)", "4+(K14) )", "4+(L01)", "4+(L02)", "4+(L03)", "4+(L04)", "4+(L05)", "4+(L06)", "4+(L07)", "4+(L08)", "4+(L09)", "4 +(L10)", "4+(L11)", "4+(L12)", "4+(L13)", "4+(L14)", "4+(L15)", "4+( L16)", "4+(L17)", "4+(L18)", "4+(L19)", "4+(L20)", "4+(L21)", "4+(L22) ", "4+(L23)", "4+(L24)", "4+(L25)", "4+(L26)", "4+(L27)", "4+(L28)", "4+(L29)", "4+(L30)", "4+(L31)", "4+(L32) "4+(L33)", "4+(L34)", "4+( M01)", "4+(M02)", "4+(M03)", "4+(M04) "4+(M05)", "4+(M06)", "4+(M07)", "4+(M08)", "4+(M09)", "4+(M10) "4+(M11)", "4+(M12)", "4+(M13)", "4+( M14)", "4+(M15)", "4+(M16) "4+(M17)", "4+(M18)", "4+(M19)", "4+(M20)", "4+(M21)", "4+(M22) "4+(M23)",
[00225] "5+(A01)", "5+(A02)", "5+(A03)", "5+(A04)", "5+(A05) "5+(A06)", " 5+(A07)", "5+(A08)", "5+(A09)", "5+(A10)", "5+(A11) "5+(A12)", "5+(B01) )", "5+(B02)", "5+(B03)", "5+(B04)", "5+(B05) "5+(B06)", "5+(B07)", " 5+(B08)", "5+(B09)", "5+(B10)", "5+(B11) "5+(B12)", "5+(C01)", "5+(C02) )", "5+(C03)", "5+(C04)", "5+(C05) "5+(C06)", "5+(C07)", "5+(C08)", " 5+(C09)", "5+(C10)", "5+(C11) "5+(C12)", "5+(C13)", "5+(C14)", "5+(C15) )", "5+(C16)", "5+(C17) "5+(C18)", "5+(C19)", "5+(C20)", "5+(C21)", " 5+(C22)", "5+(C23) "5+(C24)", "5+(C25)", "5+(C26)", "5+(C27)", "5+(C28) )", "5+(C29) "5+(C30)", "5+(C31)", "5+(C32)", "5+(C33)", "5+(C34)", " 5+(C35) "5+(C36)", "5+(C37)", "5+(C38)", "5+(C39)", "5+(C40)", "5+(C41) ) "5+(C42)", "5+(C43)", "5+(C44)", "5+(C45)", "5+(C46)", "5+(C47) "5+ (C48)", "5+(D01)", "5+(D02)", "5+(D03)", "5+(D04)", "5+(D05) "5+(E01)" , "5+(E02)", "5+(E03)", "5+(E04)", "5+(E05)", "5+(F01) "5+(F02)", "5+ (F03)", "5+(G01)", "5+(G02)", "5+(G03)", "5+(G04) "5+(G05)", "5+(G06)" , "5+(G07)", "5+(G08)", "5+(G09)", "5+(G10) "5+(G11)", "5+(G12)", "5+(G13)", "5+(H01)", "5+( H02)", "5+(H03) "5+(H04)", "5+(H05)", "5+(H06)", "5+(H07)", "5+(H08)", "5+(H09) "5+(H10)", "5+(H11)", "5+(H12)", "5+(H13)", "5+(H14)", "5+( H15) "5+(H16)", "5+(H17)", "5+(H18)", "5+(H19)", "5+(H20)", "5+(H21) "5 +(H22)", "5+(H23)", "5+(H24)", "5+(H25)", "5+(H26)", "5+(H27) "5+(H28) ", "5+(H29)", "5+(H30)", "5+(H31)", "5+(H32)", "5+(H33) "5+(H34)", "5 +(H35)", "5+(H36)", "5+(H37)", "5+(H38)", "5+(H39) "5+(H40)", "5+(H41) ", "5+(H42)", "5+(H43)", "5+(H44)", "5+(H45) "5+(H46)", "5+(H47)", "5 +(H48)", "5+(H49)", "5+(H50)", "5+(I01) "5+(I02)", "5+(I03)", "5+(I04) ", "5+(I05)", "5+(I06)", "5+(I07) , "5+(I08) "5+(I09)", "5+(I10)", "5+ (J01)", "5+(J02)", "5+(J03)", "5+(J04) "5+(J05)", "5+(J06)", "5+(K01)" , "5+(K02)", "5+(K03)", "5+(K04) "5+(K05)", "5+(K06)", "5+(K07)", "5+ (K08)", "5+(K09)", "5+(K10) "5+(K11)", "5+(K12)", "5+(K13)", "5+(K14)" , "5+(L01)", "5+(L02) "5+(L03)", "5+(L04)", "5+(L05)", "5+(L06)", "5+ (L07)", "5+(L08) "5+(L09 )", "5+(L10)", "5+(L11)", "5+(L12)", "5+(L13)", "5+(L14) "5+(L15)", " 5+(L16)", "5+(L17)", "5+(L18)", "5+(L19)", "5+(L20) "5+(L21)", "5+(L22) )", "5+(L23)", "5+(L24)", "5+(L25)", "5+(L26) "5+(L27)", "5+(L28)", " 5+(L29)", "5+(L30)", "5+(L31)", "5+(L32) "5+(L33)", "5+(L34)", "5+(M01) )", "5+(M02)", "5+(M03)", "5+(M04) "5+(M05)", "5+(M06)", "5+(M07)", " 5+(M08)", "5+(M09)", "5+(M10) "5+(M11)", "5+(M12)", "5+(M13)", "5+(M14) )", "5+(M15)", "5+(M16) "5+(M17)", "5+(M18)", "5+(M19)", "5+(M20)", " 5+(M21)", "5+(M22) "5+(M23)",
[00226] "6+(A01)", "6+(A02)", "6+(A03)", "6+(A04)", "6+(A05) "6+(A06)", " 6+(A07)", "6+(A08)", "6+(A09)", "6+(A10)", "6+(A11) "6+(A12)", "6+(B01) )", "6+(B02)", "6+(B03)", "6+(B04)", "6+(B05) "6+(B06)", "6+(B07)", " 6+(B08)", "6+(B09)", "6+(B10)", "6+(B11) "6+(B12)", "6+(C01)", "6+(C02) )", "6+(C03)", "6+(C04)", "6+(C05) "6+(C06)", "6+(C07)", "6+(C08)", " 6+(C09)", "6+(C10)", "6+(C11) "6+(C12)", "6+(C13)", "6+(C14)", "6+(C15) )", "6+(C16)", "6+(C17) "6+(C18)", "6+(C19)", "6+(C20)", "6+(C21)", " 6+(C22)", "6+(C23) "6+(C24)", "6+(C25)", "6+(C26)", "6+(C27)", "6+(C28) )", "6+(C29) "6+(C30)", "6+(C31)", "6+(C32)", "6+(C33)", "6+(C34)", " 6+(C35) "6+(C36)", "6+(C37)", "6+(C38)", "6+(C39)", "6+(C40)", "6+(C41) ) "6+(C42)", "6+(C43)", "6+(C44)", "6+(C45)", "6+(C46)", "6+(C47) "6+ (C48)", "6+(D01)", "6+(D02)", "6+(D03)", "6+(D04)", "6+(D05) "6+(E01)" , "6+(E02)", "6+(E03)", "6+(E04)", "6+(E05)", "6+(F01) "6+(F02)", "6+ (F03)", "6+(G01)", "6+(G02)", "6+(G03)", "6+(G04)", "6+(G05)", "6+(G06) )", "6+(G07)", "6+(G08) )", "6+(G09)", "6+(G10)", "6+(G11)", "6+(G12)", "6+(G13)", "6+(H01)" , "6+(H02)", "6+(H03)", "6+(H04)", "6+(H05)", "6+(H06)", "6+(H07)", " 6+(H08)", "6+(H09)", "6+(H10)", "6+(H11)", "6+(H12)", "6+(H13)", "6+ (H14)", "6+(H15)", "6+(H16)", "6+(H17)", "6+(H18)", "6+(H19)", "6+(H20) )", "6+(H21)", "6+(H22)", "6+(H23)", "6+(H24)", "6+(H25)", "6+(H26)" , "6+(H27)", "6+(H28)", "6+(H29)", "6+(H30)", "6+(H31)", "6+(H32)", " 6+(H33)", "6+(H34)", "6+(H35)", "6+(H36)", "6+(H37)", "6+(H38)", "6+ (H39)", "6+(H40)", "6+(H41)", "6+(H42)", "6+(H43)", "6+(H44)", "6+(H45) )", "6+(H46)", "6+(H47)", "6+(H48)", "6+(H49)", "6+(H50)", "6+(I01)" , "6+(I02)", "6+(I03)", "6+(I04)", "6+(I05)", "6+(I06)", "6+(I07) , "6 +(I08)", "6+(I09)", "6+(I10)", "6+(J01)", "6+(J02)", "6+(J03)", "6+( J04)", "6+(J05)", "6+(J06)", "6+(K01)", "6+(K02)", "6+(K03)", "6+(K04) ", "6+(K05)", "6+(K06)", "6+(K07)", "6+(K08)", "6+(K09)", "6+(K10)", "6+(K11)", "6+(K12)", "6+(K13)", "6+(K14)", "6+(L01)", "6+(L02)", "6 +(L03)", "6+(L04)", "6+(L05)", "6+(L0 6)", "6+(L07)", "6+(L08)", "6+(L09)", "6+(L10)", "6+(L11)", "6+(L12) ", "6+(L13)", "6+(L14)", "6+(L15)", "6+(L16)", "6+(L17)", "6+(L18)", "6+(L19)", "6+(L20)", "6+(L21)", "6+(L22)", "6+(L23)", "6+(L24)", "6 +(L25)", "6+(L26)", "6+(L27)", "6+(L28)", "6+(L29)", "6+(L30)", "6+( L31)", "6+(L32)", "6+(L33)", "6+(L34)", "6+(M01)", "6+(M02)", "6+(M03) ", "6+(M04)", "6+(M05)", "6+(M06)", "6+(M07)", "6+(M08)", "6+(M09)", "6+(M10)", "6+(M11)", "6+(M12)", "6+(M13)", "6+(M14)", "6+(M15)", "6 +(M16)", "6+(M17)", "6+(M18)", "6+(M19)", "6+(M20)", "6+(M21)", "6+( M22)", "6+(M23)",
[00227] "7+(A01)", "7+(A02)", "7+(A03)", "7+(A04)", "7+(A05)", "7+(A06)" , "7+(A07)", "7+(A08)", "7+(A09)", "7+(A10)", "7+(A11)", "7+(A12)", " 7+(B01)", "7+(B02)", "7+(B03)", "7+(B04)", "7+(B05)", "7+(B06)", "7+ (B07)", "7+(B08)", "7+(B09)", "7+(B10)", "7+(B11)", "7+(B12)", "7+(C01) )", "7+(C02)", "7+(C03)", "7+(C04)", "7+(C05)", "7+(C06)", "7+(C07)" , "7+(C08)", "7+(C09)", "7+(C10)", "7+(C11)", "7+(C12)", "7+(C13)", " 7+(C14)", "7+(C15)", "7+(C16)", "7+(C17)", "7+(C18)", "7+(C19)", "7+ (C20)", "7+(C21)", "7+(C22)", "7+(C23)", "7+(C24)", "7+(C25)", "7+(C26) )", "7+(C27)", "7+(C28)", "7+(C29)", "7+(C30)", "7+(C31)", "7+(C32)" , "7+(C33)", "7+(C34)", "7+(C35)", "7+(C36)", "7+(C37)", "7+(C38)", " 7+(C39)", "7+(C40)", "7+(C41)", "7+(C42)", "7+(C43)", "7+(C44)", "7+ (C45)", "7+(C46)", "7+(C47)", "7+(C48)", "7+(D01)", "7+(D02)", "7+(D03) )", "7+(D04)", "7+(D05)", "7+(E01)", "7+(E02)", "7+(E03)", "7+(E04)" , "7+(E05)", "7+(F01)", "7+(F02)", "7+(F03)", "7+(G01)", "7+(G02)", " 7+(G03)", "7+(G04)", "7+(G05)", " 7+(G06)", "7+(G07)", "7+(G08)", "7+(G09)", "7+(G10)", "7+(G11)", "7+ (G12)", "7+(G13)", "7+(H01)", "7+(H02)", "7+(H03)", "7+(H04)", "7+(H05) )", "7+(H06)", "7+(H07)", "7+(H08)", "7+(H09)", "7+(H10)", "7+(H11)" , "7+(H12)", "7+(H13)", "7+(H14)", "7+(H15)", "7+(H16)", "7+(H17)", " 7+(H18)", "7+(H19)", "7+(H20)", "7+(H21)", "7+(H22)", "7+(H23)", "7+ (H24)", "7+(H25)", "7+(H26)", "7+(H27)", "7+(H28)", "7+(H29)", "7+(H30) )", "7+(H31)", "7+(H32)", "7+(H33)", "7+(H34)", "7+(H35)", "7+(H36)" , "7+(H37)", "7+(H38)", "7+(H39)", "7+(H40)", "7+(H41)", "7+(H42)", " 7+(H43)", "7+(H44)", "7+(H45)", "7+(H46)", "7+(H47)", "7+(H48)", "7+ (H49)", "7+(H50)", "7+(I01)", "7+(I02)", "7+(I03)", "7+(I04)", "7+(I05) )", "7+(I06)", "7+(I07)" , "7+(I08)", "7+(I09)", "7+(I10)", "7+(J01)" , "7+(J02)", "7+(J03)", "7+(J04)", "7+(J05)", "7+(J06)", "7+(K01)", " 7+(K02)", "7+(K03)", "7+(K04)", "7+(K05)", "7+(K06)", "7+(K07)", "7+ (K08)", "7+(K09)", "7+(K10)", "7+(K11)", "7+(K12)", "7+(K13)", "7+(K14) )", "7+(L01)", "7+(L02)", "7+(L03)", "7+(L04)", "7+(L05)", "7+(L06)", "7+(L07)", "7+(L08)", "7+(L09)", "7 +(L10)", "7+(L11)", "7+(L12)", "7+(L13)", "7+(L14)", "7+(L15)", "7+( L16)", "7+(L17)", "7+(L18)", "7+(L19)", "7+(L20)", "7+(L21)", "7+(L22) ", "7+(L23)", "7+(L24)", "7+(L25)", "7+(L26)", 7+(L27)", "7+(L28)", " 7+(L29)", "7+(L30)", "7+(L31)", "7+(L32) 7+(L33)", "7+(L34)", "7+(M01) ", "7+(M02)", "7+(M03)", "7+(M04) 7+(M05)", "7+(M06)", "7+(M07)", "7+ (M08)", "7+(M09)", "7+(M10) 7+(M11)", "7+(M12)", "7+(M13)", "7+(M14)", "7+(M15)", "7+(M16) 7+(M17)", "7+(M18)", "7+(M19)", "7+(M20)", "7+(M21) )", "7+(M22) 7+(M23)",
[00228] "8+(A01)", "8+(A02)", "8+(A03)", "8+(A04)", "8+(A05) "8+(A06)", " 8+(A07)", "8+(A08)", "8+(A09)", "8+(A10)", "8+(A11) "8+(A12)", "8+(B01) )", "8+(B02)", "8+(B03)", "8+(B04)", "8+(B05) "8+(B06)", "8+(B07)", " 8+(B08)", "8+(B09)", "8+(B10)", "8+(B11) "8+(B12)", "8+(C01)", "8+(C02) )", "8+(C03)", "8+(C04)", "8+(C05) "8+(C06)", "8+(C07)", "8+(C08)", " 8+(C09)", "8+(C10)", "8+(C11) "8+(C12)", "8+(C13)", "8+(C14)", "8+(C15) )", "8+(C16)", "8+(C17) "8+(C18)", "8+(C19)", "8+(C20)", "8+(C21)", " 8+(C22)", "8+(C23) "8+(C24)", "8+(C25)", "8+(C26)", "8+(C27)", "8+(C28) )", "8+(C29) "8+(C30)", "8+(C31)", "8+(C32)", "8+(C33)", "8+(C34)", " 8+(C35) "8+(C36)", "8+(C37)", "8+(C38)", "8+(C39)", "8+(C40)", "8+(C41) ) "8+(C42)", "8+(C43)", "8+(C44)", "8+(C45)", "8+(C46)", "8+(C47) "8+ (C48)", "8+(D01)", "8+(D02)", "8+(D03)", "8+(D04)", "8+(D05) "8+(E01)" , "8+(E02)", "8+(E03)", "8+(E04)", "8+(E05)", "8+(F01) "8+(F02)", "8+ (F03)", "8+(G01)", "8+(G02)", "8+(G03)", "8+(G04) "8+(G05)", "8+(G06)" , "8+(G07)", "8+(G08)", "8+(G09)", "8+(G10) "8+(G11)", "8+(G12)", "8+(G13)", "8+(H01)", "8+( H02)", "8+(H03) "8+(H04)", "8+(H05)", "8+(H06)", "8+(H07)", "8+(H08)", "8+(H09) "8+(H10)", "8+(H11)", "8+(H12)", "8+(H13)", "8+(H14)", "8+( H15) "8+(H16)", "8+(H17)", "8+(H18)", "8+(H19)", "8+(H20)", "8+(H21) "8 +(H22)", "8+(H23)", "8+(H24)", "8+(H25)", "8+(H26)", "8+(H27) "8+(H28) ", "8+(H29)", "8+(H30)", "8+(H31)", "8+(H32)", "8+(H33) "8+(H34)", "8 +(H35)", "8+(H36)", "8+(H37)", "8+(H38)", "8+(H39) "8+(H40)", "8+(H41) ", "8+(H42)", "8+(H43)", "8+(H44)", "8+(H45) "8+(H46)", "8+(H47)", "8 +(H48)", "8+(H49)", "8+(H50)", "8+(I01) "8+(I02)", "8+(I03)", "8+(I04) ", "8+(I05)", "8+(I06)", "8+(I07) , "8+(I08) "8+(I09)", "8+(I10)", "8+ (J01)", "8+(J02)", "8+(J03)", "8+(J04) "8+(J05)", "8+(J06)", "8+(K01)" , "8+(K02)", "8+(K03)", "8+(K04) "8+(K05)", "8+(K06)", "8+(K07)", "8+ (K08)", "8+(K09)", "8+(K10) "8+(K11)", "8+(K12)", "8+(K13)", "8+(K14)" , "8+(L01)", "8+(L02) "8+(L03)", "8+(L04)", "8+(L05)", "8+(L06)", "8+ (L07)", "8+(L08) "8+(L09 )", "8+(L10)", "8+(L11)", "8+(L12)", "8+(L13)", "8+(L14) "8+(L15)", " 8+(L16)", "8+(L17)", "8+(L18)", "8+(L19)", "8+(L20) "8+(L21)", "8+(L22) )", "8+(L23)", "8+(L24)", "8+(L25)", "8+(L26) "8+(L27)", "8+(L28)", " 8+(L29)", "8+(L30)", "8+(L31)", "8+(L32) "8+(L33)", "8+(L34)", "8+(M01) )", "8+(M02)", "8+(M03)", "8+(M04) "8+(M05)", "8+(M06)", "8+(M07)", " 8+(M08)", "8+(M09)", "8+(M10) "8+(M11)", "8+(M12)", "8+(M13)", "8+(M14) )", "8+(M15)", "8+(M16) "8+(M17)", "8+(M18)", "8+(M19)", "8+(M20)", " 8+(M21)", "8+(M22) "8+(M23)",
[00229] "9+(A01)", "9+(A02)", "9+(A03)", "9+(A04)", "9+(A05) "9+(A06)", " 9+(A07)", "9+(A08)", "9+(A09)", "9+(A10)", "9+(A11) "9+(A12)", "9+(B01) )", "9+(B02)", "9+(B03)", "9+(B04)", "9+(B05) "9+(B06)", "9+(B07)", " 9+(B08)", "9+(B09)", "9+(B10)", "9+(B11) "9+(B12)", "9+(C01)", "9+(C02) )", "9+(C03)", "9+(C04)", "9+(C05) "9+(C06)", "9+(C07)", "9+(C08)", " 9+(C09)", "9+(C10)", "9+(C11) "9+(C12)", "9+(C13)", "9+(C14)", "9+(C15) )", "9+(C16)", "9+(C17) "9+(C18)", "9+(C19)", "9+(C20)", "9+(C21)", " 9+(C22)", "9+(C23) "9+(C24)", "9+(C25)", "9+(C26)", "9+(C27)", "9+(C28) )", "9+(C29) "9+(C30)", "9+(C31)", "9+(C32)", "9+(C33)", "9+(C34)", " 9+(C35) "9+(C36)", "9+(C37)", "9+(C38)", "9+(C39)", "9+(C40)", "9+(C41) ) "9+(C42)", "9+(C43)", "9+(C44)", "9+(C45)", "9+(C46)", "9+(C47) "9+ (C48)", "9+(D01)", "9+(D02)", "9+(D03)", "9+(D04)", "9+(D05) "9+(E01)" , "9+(E02)", "9+(E03)", "9+(E04)", "9+(E05)", "9+(F01) "9+(F02)", "9+ (F03)", "9+(G01)", "9+(G02)", "9+(G03)", "9+(G04)", "9+(G05)", "9+(G06) )", "9+(G07)", "9+(G08) )", "9+(G09)", "9+(G10)", "9+(G11)", "9+(G12)", "9+(G13)", "9+(H01)" , "9+(H02)", "9+(H03)", "9+(H04)", "9+(H05)", "9+(H06)", "9+(H07)", " 9+(H08)", "9+(H09)", "9+(H10)", "9+(H11)", "9+(H12)", "9+(H13)", "9+ (H14)", "9+(H15)", "9+(H16)", "9+(H17)", "9+(H18)", "9+(H19)", "9+(H20) )", "9+(H21)", "9+(H22)", "9+(H23)", "9+(H24)", "9+(H25)", "9+(H26)" , "9+(H27)", "9+(H28)", "9+(H29)", "9+(H30)", "9+(H31)", "9+(H32)", " 9+(H33)", "9+(H34)", "9+(H35)", "9+(H36)", "9+(H37)", "9+(H38)", "9+ (H39)", "9+(H40)", "9+(H41)", "9+(H42)", "9+(H43)", "9+(H44)", "9+(H45) )", "9+(H46)", "9+(H47)", "9+(H48)", "9+(H49)", "9+(H50)", "9+(I01)" , "9+(I02)", "9+(I03)", "9+(I04)", "9+(I05)", "9+(I06)", "9+(I07) , "9 +(I08)", "9+(I09)", "9+(I10)", "9+(J01)", "9+(J02)", "9+(J03)", "9+( J04)", "9+(J05)", "9+(J06)", "9+(K01)", "9+(K02)", "9+(K03)", "9+(K04) ", "9+(K05)", "9+(K06)", "9+(K07)", "9+(K08)", "9+(K09)", "9+(K10)", "9+(K11)", "9+(K12)", "9+(K13)", "9+(K14)", "9+(L01)", "9+(L02)", "9 +(L03)", "9+(L04)", "9+(L05)", "9+(L0) 6)", "9+(L07)", "9+(L08)", "9+(L09)", "9+(L10)", "9+(L11)", "9+(L12) ", "9+(L13)", "9+(L14)", "9+(L15)", "9+(L16)", "9+(L17)", "9+(L18)", "9+(L19)", "9+(L20)", "9+(L21)", "9+(L22)", "9+(L23)", "9+(L24)", "9 +(L25)", "9+(L26)", "9+(L27)", "9+(L28)", "9+(L29)", "9+(L30)", "9+( L31)", "9+(L32)", "9+(L33)", "9+(L34)", "9+(M01)", "9+(M02)", "9+(M03) ", "9+(M04)", "9+(M05)", "9+(M06)", "9+(M07)", "9+(M08)", "9+(M09)", "9+(M10)", "9+(M11)", "9+(M12)", "9+(M13)", "9+(M14)", "9+(M15)", "9 +(M16)", "9+(M17)", "9+(M18)", "9+(M19)", "9+(M20)", "9+(M21)", "9+( M22)", "9+(M23)",
[00230] "10+(A01)", "10+(A02)", "10+(A03)", "10+(A04) "10+(A05)", "10+(A06)", " 10+(A07)", "10+(A08)", "10+(A09) "10+(A10)", "10+(A11)", "10+(A12)", "10+(B01) )", "10+(B02) "10+(B03)", "10+(B04)", "10+(B05)", "10+(B06)", "10+(B07) "10+ (B08)", "10+(B09)", "10+(B10)", "10+(B11)", "10+(B12) "10+(C01)", "10+(C02)" , "10+(C03)", "10+(C04)", "10+(C05) "10+(C06)", "10+(C07)", "10+(C08)", "10+ (C09)", "10+(C10)", "10+(C11)", "10+(C12)", "10+(C13)", "10+(C14)", "10+(C15)" 10+(C16)", "10+(C17)", "10+(C18)", "10+(C19)", "10+(C20) "10+(C21)", "10+(C22) )", "10+(C23)", "10+(C24)", "10+(C25) "10+(C26)", "10+(C27)", "10+(C28)", " 10+(C29)", "10+(C30) "10+(C31)", "10+(C32)", "10+(C33)", "10+(C34)", "10+(C35) ) "10+(C36)", "10+(C37)", "10+(C38)", "10+(C39)", "10+(C40) "10+(C41)", "10+ (C42)", "10+(C43)", "10+(C44)", "10+(C45) "10+(C46)", "10+(C47)", "10+(C48)" , "10+(D01)", "10+(D02) "10+(D03)", "10+(D04)", "10+(D05)", "10+(E01)", "10+ (E02) "10+(E03)", "10+(E04)", "10+(E05)", "10+(F01)", "10+(F02) "10+(F03)", " 1 0+(G01)", "10+(G02)", "10+(G03)", "10+(G04) "10+(G05)", "10+(G06)", "10+(G07) )", "10+(G08)", "10+(G09) "10+(G10)", "10+(G11)", "10+(G12)", "10+(G13)", " 10+(H01) "10+(H02)", "10+(H03)", "10+(H04)", "10+(H05)", "10+(H06) "10+(H07)" , "10+(H08)", "10+(H09)", "10+(H10)", "10+(H11) "10+(H12)", "10+(H13)", "10+ (H14)", "10+(H15)", "10+(H16) "10+(H17)", "10+(H18)", "10+(H19)", "10+(H20)" , "10+(H21)"10+(H22)", "10+(H23)", "10+(H24)", "10+(H25)", "10+(H26) "10+(H27) )", "10+(H28)", "10+(H29)", "10+(H30)", "10+(H31) "10+(H32)", "10+(H33)", " 10+(H34)", "10+(H35)", "10+(H36) "10+(H37)", "10+(H38)", "10+(H39)", "10+(H40) )", "10+(H41) "10+(H42)", "10+(H43)", "10+(H44)", "10+(H45)", "10+(H46) "10+ (H47)", "10+(H48)", "10+(H49)", "10+(H50)", "10+(I01)", "10+(I02)" "10+(I03) ", "10+(I04)", "10+(I05)", "10+(I06)", "10+(I07)", "10+(I08)" "10+(I09)", " 10+(I10)", "10+(J01)", "10+(J02)", "10+(J03)", "10+(J04)" "10+(J05)", "10+( J06)", "10+(K01)", "10+(K02)", "10+(K03)" "10+(K04)", "10+(K05)", "10+(K06)" , "10+(K07)" , "10+(K08)" "10+(K09)", "10+(K10)", "10+(K11)", "10+(K12)", "10+(K13)" "10+ (K14)", "10+(L01)", "10+(L02)", "10+(L03)", "10+(L04)", "10+(L05)" "10+(L06) ", "10+(L07)", "10+(L08)", "10+(L09)", "10+(L10)", "10+(L11)" "10+(L12)", " 10+(L13)", "10+(L14)", "10+(L15)", "10+(L16)", "10+(L17)" "10+(L18)", "10+( L19)", "10+(L20)", "10+(L21)", "10+(L22)", "10+(L23)" "10+(L24)", "10+(L25)" , "10+(L26)", "10+(L27)", "10+(L28)", "10+(L29)" "10+(L30)", "10+(L31)", "10 +(L32)", "10+(L33)", "10+(L34)", "10+(M01)", "10+(M02)", "10+(M03)", "10+( M04)", "10+(M05)", "10+(M06)", "10+(M07)", "10+(M08)", "10+(M09)", "10+(M10) ", "10+(M11)", "10+(M12)", "10+(M13)", "10+(M14)", "10+(M15)", "10+(M16)", "10+(M17)", "10+(M18)", "10+(M19)", "10+(M20)", "10+(M21)", "10+(M22)", " 0 +(M23)",
[00231] "11+(A01)", "11+(A02)", "11+(A03)", "11+(A04)", "11+(A05)", "11+(A06)" , "11+(A07)", "11+(A08)", "11+(A09)", "11+(A10)", "11+(A11)", "11+(A12)", " 11+(B01)", "11+(B02)", "11+(B03)", "11+(B04)", "11+(B05)", "11+(B06)", "11+ (B07)", "11+(B08)", "11+(B09)", "11+(B10)", "11+(B11)", "11+(B12)", "11+(C01) )", "11+(C02)", "11+(C03)", "11+(C04)", "11+(C05)", "11+(C06)", "11+(C07)" , "11+(C08)", "11+(C09)", "11+(C10)", "11+(C11)", "11+(C12)", "11+(C13)", " 11+(C14)", "11+(C15)", "11+(C16)", "11+(C17)", "11+(C18)", "11+(C19)", "11+ (C20)", "11+(C21)", "11+(C22)", "11+(C23)", "11+(C24)", "11+(C25)", "11+(C26) )", "11+(C27)", "11+(C28)", "11+(C29)", "11+(C30)", "11+(C31)", "11+(C32)" , "11+(C33)", "11+(C34)", "11+(C35)", "11+(C36)", "11+(C37)", "11+(C38)", " 11+(C39)", "11+(C40)", "11+(C41)", "11+(C42)", "11+(C43)", "11+(C44)", "11+ (C45)", "11+(C46)", "11+(C47)", "11+(C48)", "11+(D01)", "11+(D02)", "11+(D03) )", "11+(D04)", "11+(D05)", "11+(E01)", "11+(E02)", "11+(E03)", "11+(E04)" , "11+(E05)", "11+(F0) 1)", "11+(F02)", "11+(F03)", "11+(G01)", "11+(G02)", "11+(G03)", "11+(G04) ", "11+(G05)", "11+(G06)", "11+(G07)", "11+(G08)", "11+(G09)", "11+(G10)", "11+(G11)", "11+(G12)", "11+(G13)", "11+(H01)", "11+(H02)", "11+(H03)", "11 +(H04)", "11+(H05)", "11+(H06)", "11+(H07)", "11+(H08)", "11+(H09)", "11+( H10)", "11+(H11)", "11+(H12)", "11+(H13)", "11+(H14)", "11+(H15)", "11+(H16) ", "11+(H17)", "11+(H18)", "11+(H19)", "11+(H20)", "11+(H21)", "11+(H22)", "11+(H23)", "11+(H24)", "11+(H25)", "11+(H26)", "11+(H27)", "11+(H28)", "11 +(H29)", "11+(H30)", "11+(H31)", "11+(H32)", "11+(H33)", "11+(H34)", "11+( H35)", "11+(H36)", "11+(H37)", "11+(H38)", "11+(H39)", "11+(H40)", "11+(H41) ", "11+(H42)", "11+(H43)", "11+(H44)", "11+(H45)", "11+(H46)", "11+(H47)", "11+(H48)", "11+(H49)", "11+(H50)", "11+(I01)", "11+(I02)" "11+(I03)", "11+ (I04)", "11+(I05)", "11+(I06)", "11+(I07)", "11+(I08)" "11+(I09)", "11+(I10) ", "11+(J01)", "11+(J02)", "11+(J03)", "11+(J04)" "11+(J05)", "11+(J06)", " 11+(K01)", "11+(K02)", " 11+(K03)" "11+(K04)", "11+(K05)", "11+(K06)", "11+(K07)", "11+(K08)" "11+(K09) )", "11+(K10)", "11+(K11)", "11+(K12)", "11+(K13)" "11+(K14)", "11+(L01)", "11+(L02)", "11+(L03)", "11+(L04)", "11+(L05)" "11+(L06)", "11+(L07)", "11+ (L08)", "11+(L09)", "11+(L10)", "11+(L11)" "11+(L12)", "11+(L13)", "11+(L14) ", "11+(L15)", "11+(L16)", "11+(L17)" "11+(L18)", "11+(L19)", "11+(L20)", " 11+(L21)", "11+(L22)", "11+(L23)" "11+(L24)", "11+(L25)", "11+(L26)", "11+( L27)", "11+(L28)", "11+(L29)" "11+(L30)", "11+(L31)", "11+(L32)", "11+(L33)" , "11+(L34)", "11+(M01)", "11+(M02)", "11+(M03)", "11+(M04)", "11+(M05)", " 11+(M06)", "11+(M07)", "11+(M08)", "11+(M09)", "11+(M10)", "11+(M11)", "11+ (M12)", "11+(M13)", "11+(M14)", "11+(M15)", "11+(M16)", "11+(M17)", "11+(M18) )", "11+(M19)", "11+(M20)", "11+(M21)", "11+(M22)", "11+(M23)",
[00232] "12+(A01)", "12+(A02)", "12+(A03)", "12+(A04)", "12+(A05)", "12+(A06)" , "12+(A07)", "12+(A08)", "12+(A09)", 12+(A10)", "12+(A11)", "12+(A12)", "12 +(B01)", "12+(B02) 12+(B03)", "12+(B04)", "12+(B05)", "12+(B06)", "12+(B07) 12 +(B08)", "12+(B09)", "12+(B10)", "12+(B11)", "12+(B12) 12+(C01)", "12+(C02)" , "12+(C03)", "12+(C04)", "12+(C05) 12+(C06)", "12+(C07)", "12+(C08)", "12+( C09)", "12+(C10) 12+(C11)", "12+(C12)", "12+(C13)", "12+(C14)", "12+(C15) 12+( C16)", "12+(C17)", "12+(C18)", "12+(C19)", "12+(C20) 12+(C21)", "12+(C22)", " 12+(C23)", "12+(C24)", "12+(C25) 12+(C26)", "12+(C27)", "12+(C28)", "12+(C29) ", "12+(C30) 12+(C31)", "12+(C32)", "12+(C33)", "12+(C34)", "12+(C35) 12+(C36) ", "12+(C37)", "12+(C38)", "12+(C39)", "12+(C40) 12+(C41)", "12+(C42)", "12+ (C43)", "12+(C44)", "12+(C45) 12+(C46)", "12+(C47)", "12+(C48)", "12+(D01)", "12+(D02) 12+(D03)", "12+(D04)", "12+(D05)", "12+(E01)", "12+(E02) 12+(E03)", "12+(E04)", "12+(E05)", "12+(F01)", "12+(F02) 12+(F03)", "12+(G01)", "12+ (G02)", "12+(G03)", "12+(G04) 12+(G05)", "12+(G06)", "12+(G07)", "12+(G08)", "12+(G09) 12+(G10)", "12+(G11)", "12+(G12)", "12+(G13)", "12+(H01) 12+(H02)", "12+(H03)", "12+(H04)", "12+(H05)", "12+(H06) 12+(H07)", "12+(H08)", "12+(H09) )", "12+(H10)", "12+(H11) 12+(H12)", "12+(H13)", "12+(H14)", "12+(H15)", "12 +(H16) 12+(H17)", "12+(H18)", "12+(H19)", "12+(H20)", "12+(H21) 12+(H22)", "12 +(H23)", "12+(H24)", "12+(H25)", "12+(H26) 12+(H27)", "12+(H28)", "12+(H29)" , "12+(H30)", "12+(H31) 12+(H32)", "12+(H33)", "12+(H34)", "12+(H35)", "12+( H36) 12+(H37)", "12+(H38)", "12+(H39)", "12+(H40)", "12+(H41) 12+(H42)", "12+( H43)", "12+(H44)", "12+(H45)", "12+(H46) "12+(H47)", "12+(H48)", "12+(H49)", "12+(H50)", "12+(I01)", "12+(I02)" "12+(I03)", "12+(I04)", "12+(I05)", "12+ (I06)", "12+(I07)", "12+(I08)" "12+(I09)", "12+(I10)", "12+(J01)", "12+(J02) ", "12+(J03)", "12+(J04)" "12+(J05)", "12+(J06)", "12+(K01)", "12+(K02)", " 12+(K03)" "12+(K04)", "12+(K05)", "12+(K06)", "12+(K07)", "12+(K08)" "12+(K09) )", "12+(K10)", "12+(K11)", "12+(K12)", "12+(K13)" "12+(K14)", "12+(L01)", "12+ (L02)", "12+(L03)", "12+(L04)", "12+(L05)" "12+(L06)", "12+(L07)", "12+(L08) ", "12+(L09)", "12+(L10)", "12+(L11)" "12+(L12)", "12+(L13)", "12+(L14)", " 12+(L15)", "12+(L16)", "12+(L17)" "12+(L18)", "12+(L19)", "12+(L20)", "12+( L21)", "12+(L22)", "12+(L23)" "12+(L24)", "12+(L25)", "12+(L26)", "12+(L27)" , "12+(L28)", "12+(L29)" "12+(L30)", "12+(L31)", "12+(L32)", "12+(L33)", "12 +(L34) "12+(M01)", "12+(M02)", "12+(M03)", "12+(M04)", "12+(M05) "12+(M06)", "12+(M07)", "12+(M08)", "12+(M09)", "12+(M10) "12+(M11)", "12+(M12)", "12+( M13)", "12+(M14)", "12+(M15) "12+(M16)", "12+(M17)", "12+(M18)", "12+(M19)", "12+(M20) "12+(M23)",
[00233] "13+(A01)", "13+(A02)", "13+(A03)", "13+(A04) "13+(A05)", "13+(A06)", " 13+(A07)", "13+(A08)", "13+(A09) "13+(A10)", "13+(A11)", "13+(A12)", "13+(B01) )", "13+(B02) "13+(B03)", "13+(B04)", "13+(B05)", "13+(B06)", "13+(B07) "13+ (B08)", "13+(B09)", "13+(B10)", "13+(B11)", "13+(B12) "13+(C01)", "13+(C02)" , "13+(C03)", "13+(C04)", "13+(C05) "13+(C06)", "13+(C07)", "13+(C08)", "13+ (C09)", "13+(C10) "13+(C11)", "13+(C12)", "13+(C13)", "13+(C14)", "13+(C15)" 13+(C16)", "13+(C17)", "13+(C18)", "13+(C19)", "13+(C20) "13+(C21)", "13+(C22) )", "13+(C23)", "13+(C24)", "13+(C25) "13+(C26)", "13+(C27)", "13+(C28)", " 13+(C29)", "13+(C30) "13+(C31)", "13+(C32)", "13+(C33)", "13+(C34)", "13+(C35) ) "13+(C36)", "13+(C37)", "13+(C38)", "13+(C39)", "13+(C40) "13+(C41)", "13+ (C42)", "13+(C43)", "13+(C44)", "13+(C45) "13+(C46)", "13+(C47)", "13+(C48)" , "13+(D01)", "13+(D02) "13+(D03)", "13+(D04)", "13+(D05)", "13+(E01)", "13+ (E02) "13+(E03)", "13+(E04)", "13+(E05)", "13+(F01)", "13+(F02)", "13+(F03)" , "1 3+(G01)", "13+(G02)", "13+(G03)", "13+(G04)", "13+(G05)", "13+(G06)", "13+ (G07)", "13+(G08)", "13+(G09)", "13+(G10)", "13+(G11)", "13+(G12)", "13+(G13) )", "13+(H01)", "13+(H02)", "13+(H03)", "13+(H04)", "13+(H05)", "13+(H06)" , "13+(H07)", "13+(H08)", "13+(H09)", "13+(H10)", "13+(H11)", "13+(H12)", " 13+(H13)", "13+(H14)", "13+(H15)", "13+(H16)", "13+(H17)", "13+(H18)", "13+ (H19)", "13+(H20)", "13+(H21)", "13+(H22)", "13+(H23)", "13+(H24)", "13+(H25) )", "13+(H26)", "13+(H27)", "13+(H28)", "13+(H29)", "13+(H30)", "13+(H31)" , "13+(H32)", "13+(H33)", "13+(H34)", "13+(H35)", "13+(H36)", "13+(H37)", " 13+(H38)", "13+(H39)", "13+(H40)", "13+(H41)", "13+(H42)", "13+(H43)", "13+ (H44)", "13+(H45)", "13+(H46)", "13+(H47)", "13+(H48)", "13+(H49)", "13+(H50) )", "13+(I01)", "13+(I02)" "13+(I03)", "13+(I04)", "13+(I05)", "13+(I06)", "13+(I07)", "13+(I08)" "13+(I09)", "13+(I10)", "13+(J01)", "13+(J02)", "13+ (J03)", "13+(J04)" 13+(J05)", "13+(J06)", "13+(K01)", "13+(K02)", "13+(K03) 13 +(K04)", "13+(K05)", " 13+(K06)", "13+(K07)", "13+(K08) 13+(K09)", "13+(K10)", "13+(K11)", "13+(K12) ", "13+(K13) "13+(K14)", "13+(L01)", "13+(L02)", "13+(L03)", "13+(L04)", "13 +(L05)" "13+(L06)", "13+(L07)", "13+(L08)", "13+(L09)", "13+(L10)", "13+(L11) )" "13+(L12)", "13+(L13)", "13+(L14)", "13+(L15)", "13+(L16)", "13+(L17)" " 13+(L18)", "13+(L19)", "13+(L20)", "13+(L21)", "13+(L22)", "13+(L23)" "13+( L24)", "13+(L25)", "13+(L26)", "13+(L27)", "13+(L28)", "13+(L29)" 13+(L30)", "13+(L31)", "13+(L32)", "13+(L33)", "13+(L34) 13+(M01)", "13+(M02)", "13+(M03) )", "13+(M04)", "13+(M05) 13+(M06)", "13+(M07)", "13+(M08)", "13+(M09)", "13 +(M10) 13+(M11)", "13+(M12)", "13+(M13)", "13+(M14)", "13+(M15) 13+(M16)", "13 +(M17)", "13+(M18)", "13+(M19)", "13+(M20) 13+(M21)", "13+(M22)", "13+(M23)" ,
[00234] "14+(A01)", "14+(A02)", "14+(A03)", "14+(A04) "14+(A05)", "14+(A06)", " 14+(A07)", "14+(A08)", "14+(A09) "14+(A10)", "14+(A11)", "14+(A12)", "14+(B01) )", "14+(B02) "14+(B03)", "14+(B04)", "14+(B05)", "14+(B06)", "14+(B07) "14+ (B08)", "14+(B09)", "14+(B10)", "14+(B11)", "14+(B12) "14+(C01)", "14+(C02)" , "14+(C03)", "14+(C04)", "14+(C05) "14+(C06)", "14+(C07)", "14+(C08)", "14+ (C09)", "14+(C10) "14+(C11)", "14+(C12)", "14+(C13)", "14+(C14)", "14+(C15)" 14+(C16)", "14+(C17)", "14+(C18)", "14+(C19)", "14+(C20) "14+(C21)", "14+(C22) )", "14+(C23)", "14+(C24)", "14+(C25) "14+(C26)", "14+(C27)", "14+(C28)", " 14+(C29)", "14+(C30) "14+(C31)", "14+(C32)", "14+(C33)", "14+(C34)", "14+(C35) ) "14+(C36)", "14+(C37)", "14+(C38)", "14+(C39)", "14+(C40) "14+(C41)", "14+ (C42)", "14+(C43)", "14+(C44)", "14+(C45) "14+(C46)", "14+(C47)", "14+(C48)" , "14+(D01)", "14+(D02) "14+(D03)", "14+(D04)", "14+(D05)", "14+(E01)", "14+ (E02) "14+(E03)", "14+(E04)", "14+(E05)", "14+(F01)", "14+(F02) "14+(F03)", " 14+( G01)", "14+(G02)", "14+(G03)", "14+(G04) "14+(G05)", "14+(G06)", "14+(G07)", "14+(G08)", "14+(G09) "14+(G10)", "14+(G11)", "14+(G12)", "14+(G13)", "14+( H01) "14+(H02)", "14+(H03)", "14+(H04)", "14+(H05)", "14+(H06) "14+(H07)", "14 +(H08)", "14+(H09)", "14+(H10)", "14+(H11) "14+(H12)", "14+(H13)", "14+(H14) ", "14+(H15)", "14+(H16) "14+(H17)", "14+(H18)", "14+(H19)", "14+(H20)", "14 +(H21) "14+(H22)", "14+(H23)", "14+(H24)", "14+(H25)", "14+(H26) "14+(H27)", "14+(H28)", "14+(H29)", "14+(H30)", "14+(H31) "14+(H32)", "14+(H33)", "14+( H34)", "14+(H35)", "14+(H36) "14+(H37)", "14+(H38)", "14+(H39)", "14+(H40)", "14+(H41) "14+(H42)", "14+(H43)", "14+(H44)", "14+(H45)", "14+(H46) "14+(H47) ", "14+(H48)", "14+(H49)", "14+(H50)", "14+(I01)", "14+(I02) "14+(I03)", "14 +(I04)", "14+(I05)", "14+(I06)", "14+(I07)", "14+(I08)" "14+(I09)", "14+(I10) )", "14+(J01)", "14+(J02)", "14+(J03)", "14+(J04)" "14+(J05)", "14+(J06)", "14+(K01)", "14+(K02)", "14+(K03)" "14+(K04)", "14+(K05)", "14+(K06)", "14+ (K07)", "14+(K08)" "14+(K09)", "14+(K10)", "14+(K11)", "14+(K12)", "14+(K13)" "14+( K14)", "14+(L01)", "14+(L02)", "14+(L03)", "14+(L04)", "14+(L05)" "14+(L06)" , "14+(L07)", "14+(L08)", "14+(L09)", "14+(L10)", "14+(L11)" "14+(L12)", "14 +(L13)", "14+(L14)", "14+(L15)", "14+(L16)", "14+(L17)" "14+(L18)", "14+(L19) )", "14+(L20)", "14+(L21)", "14+(L22)", "14+(L23)" "14+(L24)", "14+(L25)", "14+(L26)", "14+(L27)", "14+(L28)", "14+(L29)" "14+(L30)", "14+(L31)", "14+ (L32)", "14+(L33)", "14+(L34) "14+(M01)", "14+(M02)", "14+(M03)", "14+(M04)" , "14+(M05) "14+(M06)", "14+(M07)", "14+(M08)", "14+(M09)", "14+(M10) "14+(M11) )", "14+(M12)", "14+(M13)", "14+(M14)", "14+(M15) "14+(M16)", "14+(M17)", " 14+(M18)", "14+(M19)", "14+(M20) "14+(M21)", "14+(M22)", "14+(M23)",
[00235] "15+(A01)", "15+(A02)", "15+(A03)", "15+(A04) "15+(A05)", "15+(A06)", " 15+(A07)", "15+(A08)", "15+(A09) "15+(A10)", "15+(A11)", "15+(A12)", "15+(B01) )", "15+(B02) "15+(B03)", "15+(B04)", "15+(B05)", "15+(B06)", "15+(B07) "15+ (B08)", "15+(B09)", "15+(B10)", "15+(B11)", "15+(B12) "15+(C01)", "15+(C02)" , "15+(C03)", "15+(C04)", "15+(C05) "15+(C06)", "15+(C07)", "15+(C08)", "15+ (C09)", "15+(C10)", "15+(C11)", "15+(C12)", "15+(C13)", "15+(C14)", "15+(C15)" 15+(C16)", "15+(C17)", "15+(C18)", "15+(C19)", "15+(C20) "15+(C21)", "15+(C22) )", "15+(C23)", "15+(C24)", "15+(C25) "15+(C26)", "15+(C27)", "15+(C28)", " 15+(C29)", "15+(C30) "15+(C31)", "15+(C32)", "15+(C33)", "15+(C34)", "15+(C35) ) "15+(C36)", "15+(C37)", "15+(C38)", "15+(C39)", "15+(C40) "15+(C41)", "15+ (C42)", "15+(C43)", "15+(C44)", "15+(C45) "15+(C46)", "15+(C47)", "15+(C48)" , "15+(D01)", "15+(D02)", "15+(D03)", "15+(D04)", "15+(D05)", "15+(E01)", " 15+(E02)", "15+(E03)", "15+(E04)", "15+(E05)", "15+(F01)", "15+(F02)", "15+ (F03)" , "15+(G01)", "15+(G02)", "15+(G03)", "15+(G04)", "15+(G05)", "15+(G06)", " 15+(G07)", "15+(G08)", "15+(G09)", "15+(G10)", "15+(G11)", "15+(G12)", "15+ (G13)", "15+(H01)", "15+(H02)", "15+(H03)", "15+(H04)", "15+(H05)", "15+(H06) )", "15+(H07)", "15+(H08)", "15+(H09)", "15+(H10)", "15+(H11)", "15+(H12)" , "15+(H13)", "15+(H14)", "15+(H15)", "15+(H16)", "15+(H17)", "15+(H18)", " 15+(H19)", "15+(H20)", "15+(H21)", "15+(H22)", "15+(H23)", "15+(H24)", "15+ (H25)", "15+(H26)", "15+(H27)", "15+(H28)", "15+(H29)", "15+(H30)", "15+(H31) )", "15+(H32)", "15+(H33)", "15+(H34)", "15+(H35)", "15+(H36)", "15+(H37)" , "15+(H38)", "15+(H39)", "15+(H40)", "15+(H41)", "15+(H42)", "15+(H43)", " 15+(H44)", "15+(H45)", "15+(H46)", "15+(H47)", "15+(H48)", "15+(H49)", "15+ (H50)", "15+(I01)", "15+(I02)" "15+(I03)", "15+(I04)", "15+(I05)", "15+(I06) ", "15+(I07)", "15+(I08)" "15+(I09)", "15+(I10)", "15+(J01)", "15+(J02)", " 15+(J03)", "15+(J04)" "15+(J05)", "15+(J06)", "15+(K01)", "15+(K02)", "15+( K03)" "15+(K04)", "15+(K 05)", "15+(K06)", "15+(K07)", "15+(K08)" "15+(K09)", "15+(K10)", "15+(K11)" , "15+(K12)", "15+(K13)" "15+(K14)", "15+(L01)", "15+(L02)", "15+(L03)", "15 +(L04)", "15+(L05)" "15+(L06)", "15+(L07)", "15+(L08)", "15+(L09)", "15+(L10) )", "15+(L11)" "15+(L12)", "15+(L13)", "15+(L14)", "15+(L15)", "15+(L16)", "15+(L17)" "15+(L18)", "15+(L19)", "15+(L20)", "15+(L21)", "15+(L22)", "15+ (L23)" "15+(L24)", "15+(L25)", "15+(L26)", "15+(L27)", "15+(L28)", "15+(L29) "15+(L30)", "15+(L31)", "15+(L32)", "15+(L33)", "15+(L34) 15+(M01)", "15+(M02) )", "15+(M03)", "15+(M04)", "15+(M05) 15+(M06)", "15+(M07)", "15+(M08)", "15 +(M09)", "15+(M10) 15+(M11)", "15+(M12)", "15+(M13)", "15+(M14)", "15+(M15)" 15+(M16)", "15+(M17)", "15+(M18)", "15+(M19)", "15+(M20)", "15+(M21)", "15+ (M22)", "5+(M23)",
[00236] "16+(A01)", "16+(A02)", "16+(A03)", "16+(A04)", "16+(A05)", "16+(A06)" , "16+(A07)", "16+(A08)", "16+(A09)", "16+(A10)", "16+(A11)", "16+(A12)", " 16+(B01)", "16+(B02)", "16+(B03)", "16+(B04)", "16+(B05)", "16+(B06)", "16+ (B07)", "16+(B08)", "16+(B09)", "16+(B10)", "16+(B11)", "16+(B12)", "16+(C01) )", "16+(C02)", "16+(C03)", "16+(C04)", "16+(C05)", "16+(C06)", "16+(C07)" , "16+(C08)", "16+(C09)", "16+(C10)", "16+(C11)", "16+(C12)", "16+(C13)", " 16+(C14)", "16+(C15)", "16+(C16)", "16+(C17)", "16+(C18)", "16+(C19)", "16+ (C20)", "16+(C21)", "16+(C22)", "16+(C23)", "16+(C24)", "16+(C25)", "16+(C26) )", "16+(C27)", "16+(C28)", "16+(C29)", "16+(C30)", "16+(C31)", "16+(C32)" , "16+(C33)", "16+(C34)", "16+(C35)", "16+(C36)", "16+(C37)", "16+(C38)", " 16+(C39)", "16+(C40)", "16+(C41)", "16+(C42)", "16+(C43)", "16+(C44)", "16+ (C45)", "16+(C46)", "16+(C47)", "16+(C48)", "16+(D01)", "16+(D02)", "16+(D03) )", "16+(D04)", "16+(D05)", "16+(E01)", "16+(E02)", "16+(E03)", "16+(E04)" , "16+(E05)", "16+(F0) 1)", "16+(F02)", "16+(F03)", "16+(G01)", "16+(G02)", "16+(G03)", "16+(G04) ", "16+(G05)", "16+(G06)", "16+(G07)", "16+(G08)", "16+(G09)", "16+(G10)", "16+(G11)", "16+(G12)", "16+(G13)", "16+(H01)", "16+(H02)", "16+(H03)", "16 +(H04)", "16+(H05)", "16+(H06)", "16+(H07)", "16+(H08)", "16+(H09)", "16+( H10)", "16+(H11)", "16+(H12)", "16+(H13)", "16+(H14)", "16+(H15)", "16+(H16) ", "16+(H17)", "16+(H18)", "16+(H19)", "16+(H20)", "16+(H21)", "16+(H22)", "16+(H23)", "16+(H24)", "16+(H25)", "16+(H26)", "16+(H27)", "16+(H28)", "16 +(H29)", "16+(H30)", "16+(H31)", "16+(H32)", "16+(H33)", "16+(H34)", "16+( H35)", "16+(H36)", "16+(H37)", "16+(H38)", "16+(H39)", "16+(H40)", "16+(H41) ", "16+(H42)", "16+(H43)", "16+(H44)", "16+(H45)", "16+(H46)" "16+(H47)", " 16+(H48)", "16+(H49)", "16+(H50)", "16+(I01)", "16+(I02)" "16+(I03)", "16+( I04)", "16+(I05)", "16+(I06)", "16+(I07)", "16+(I08)" "16+(I09)", "16+(I10)" , "16+(J01)", "16+(J02)", "16+(J03)", "16+(J04)" "16+(J05)", "16+(J06)", "16 +(K01)", "16+(K02)", "1 6+(K03)" "16+(K04)", "16+(K05)", "16+(K06)", "16+(K07)", "16+(K08)" "16+(K09) )", "16+(K10)", "16+(K11)", "16+(K12)", "16+(K13)" "16+(K14)", "16+(L01)", "16+(L02)", "16+(L03)", "16+(L04)", "16+(L05)" "16+(L06)", "16+(L07)", "16+ (L08)", "16+(L09)", "16+(L10)", "16+(L11)" "16+(L12)", "16+(L13)", "16+(L14) ", "16+(L15)", "16+(L16)", "16+(L17)" "16+(L18)", "16+(L19)", "16+(L20)", " 16+(L21)", "16+(L22)", "16+(L23)" "16+(L24)", "16+(L25)", "16+(L26)", "16+( L27)", "16+(L28)", "16+(L29)" "16+(L30)", "16+(L31)", "16+(L32)", "16+(L33)" , "16+(L34)", "16+(M01)", "16+(M02)", "16+(M03)", "16+(M04)", "16+(M05)", " 16+(M06)", "16+(M07)", "16+(M08)", "16+(M09)", "16+(M10)", "16+(M11)", "16+ (M12)", "16+(M13)", "16+(M14)", "16+(M15)", "16+(M16)", "16+(M17)", "16+(M18) )", "16+(M19)", "16+(M20)", "16+(M21)", "16+(M22)", "16+(M23)",
[00237] "17+(A01)", "17+(A02)", "17+(A03)", "17+(A04)", "17+(A05)", "17+(A06)" , "17+(A07)", "17+(A08)", "17+(A09)", "17+(A10)", "17+(A11)", "17+(A12)", " 17+(B01)", "17+(B02)", "17+(B03)", "17+(B04)", "17+(B05)", "17+(B06)", "17+ (B07)", "17+(B08)", "17+(B09)", "17+(B10)", "17+(B11)", "17+(B12)", "17+(C01) )", "17+(C02)", "17+(C03)", "17+(C04)", "17+(C05)", "17+(C06)", "17+(C07)" , "17+(C08)", "17+(C09)", "17+(C10)", "17+(C11)", "17+(C12)", "17+(C13)", " 17+(C14)", "17+(C15)", "17+(C16)", "17+(C17)", "17+(C18)", "17+(C19)", "17+ (C20)", "17+(C21)", "17+(C22)", "17+(C23)", "17+(C24)", "17+(C25)", "17+(C26) )", "17+(C27)", "17+(C28)", "17+(C29)", "17+(C30)", "17+(C31)", "17+(C32)" , "17+(C33)", "17+(C34)", "17+(C35)", "17+(C36)", "17+(C37)", "17+(C38)", " 17+(C39)", "17+(C40)", "17+(C41)", "17+(C42)", "17+(C43)", "17+(C44)", "17+ (C45)", "17+(C46)", "17+(C47)", "17+(C48)", "17+(D01)", "17+(D02)", "17+(D03) )", "17+(D04)", "17+(D05)", "17+(E01)", "17+(E02)", "17+(E03)", "17+(E04)" , "17+(E05)", "17+(F 01)", "17+(F02)", "17+(F03)", "17+(G01)", "17+(G02)", "17+(G03)", "17+(G04) ", "17+(G05)", "17+(G06)", "17+(G07)", "17+(G08)", "17+(G09)", "17+(G10)", "17+(G11)", "17+(G12)", "17+(G13)", "17+(H01)", "17+(H02)", "17+(H03)", "17 +(H04)", "17+(H05)", "17+(H06)", "17+(H07)", "17+(H08)", "17+(H09)", "17+( H10)", "17+(H11)", "17+(H12)", "17+(H13)", "17+(H14)", "17+(H15)", "17+(H16) ", "17+(H17)", "17+(H18)", "17+(H19)", "17+(H20)", "17+(H21)", "17+(H22)", "17+(H23)", "17+(H24)", "17+(H25)", "17+(H26)", "17+(H27)", "17+(H28)", "17 +(H29)", "17+(H30)", "17+(H31)", "17+(H32)", "17+(H33)", "17+(H34)", "17+( H35)", "17+(H36)", "17+(H37)", "17+(H38)", "17+(H39)", "17+(H40)", "17+(H41) ", "17+(H42)", "17+(H43)", "17+(H44)", "17+(H45)", "17+(H46)", "17+(H47)", "17+(H48)", "17+(H49)", "17+(H50)", "17+(I01)", "17+(I02)" "17+(I03)", "17+ (I04)", "17+(I05)", "17+(I06)", "17+(I07)", "17+(I08)" "17+(I09)", "17+(I10) ", "17+(J01)", "17+(J02)", "17+(J03)", "17+(J04)" "17+(J05)", "17+(J06)", " 17+(K01)", "17+(K02)", " 17+(K03)" "17+(K04)", "17+(K05)", "17+(K06)", "17+(K07)", "17+(K08)" "17+(K09) )", "17+(K10)", "17+(K11)", "17+(K12)", "17+(K13)" "17+(K14)", "17+(L01)", "17+(L02)", "17+(L03)", "17+(L04)", "17+(L05)" "17+(L06)", "17+(L07)", "17+ (L08)", "17+(L09)", "17+(L10)", "17+(L11)" "17+(L12)", "17+(L13)", "17+(L14) ", "17+(L15)", "17+(L16)", "17+(L17)" "17+(L18)", "17+(L19)", "17+(L20)", " 17+(L21)", "17+(L22)", "17+(L23)" "17+(L24)", "17+(L25)", "17+(L26)", "17+( L27)", "17+(L28)", "17+(L29)" "17+(L30)", "17+(L31)", "17+(L32)", "17+(L33)" , "17+(L34)" "17+(M01)", "17+(M02)", "17+(M03)", "17+(M04)", "17+(M05)" "17+ (M06)", "17+(M07)", "17+(M08)", "17+(M09)", "17+(M10) "17+(M11)", "17+(M12)" , "17+(M13)", "17+(M14)", "17+(M15) "17+(M16)", "17+(M17)", "17+(M18)", "17+ (M19)", "17+(M20) "17+(M21)", "17+(M22)", "1 7+(M23)",
[00238] "18+(A01)", "18+(A02)", "18+(A03)", "18+(A04) "18+(A05)", "18+(A06)", " 18+(A07)", "18+(A08)", "18+(A09) "18+(A10)", "18+(A11)", "18+(A12)", "18+(B01) )", "18+(B02) "18+(B03)", "18+(B04)", "18+(B05)", "18+(B06)", "18+(B07) "18+ (B08)", "18+(B09)", "18+(B10)", "18+(B11)", "18+(B12) "18+(C01)", "18+(C02)" , "18+(C03)", "18+(C04)", "18+(C05) "18+(C06)", "18+(C07)", "18+(C08)", "18+ (C09)", "18+(C10) "18+(C11)", "18+(C12)", "18+(C13)", "18+(C14)", "18+(C15)" 18+(C16)", "18+(C17)", "18+(C18)", "18+(C19)", "18+(C20) "18+(C21)", "18+(C22) )", "18+(C23)", "18+(C24)", "18+(C25) "18+(C26)", "18+(C27)", "18+(C28)", " 18+(C29)", "18+(C30) "18+(C31)", "18+(C32)", "18+(C33)", "18+(C34)", "18+(C35) ) "18+(C36)", "18+(C37)", "18+(C38)", "18+(C39)", "18+(C40) "18+(C41)", "18+ (C42)", "18+(C43)", "18+(C44)", "18+(C45) "18+(C46)", "18+(C47)", "18+(C48)" , "18+(D01)", "18+(D02) "18+(D03)", "18+(D04)", "18+(D05)", "18+(E01)", "18+ (E02) "18+(E03)", "18+(E04)", "18+(E05)", "18+(F01)", "18+(F02) "18+(F03)", " 18+( G01)", "18+(G02)", "18+(G03)", "18+(G04) "18+(G05)", "18+(G06)", "18+(G07)", "18+(G08)", "18+(G09) "18+(G10)", "18+(G11)", "18+(G12)", "18+(G13)", "18+( H01) "18+(H02)", "18+(H03)", "18+(H04)", "18+(H05)", "18+(H06) "18+(H07)", "18 +(H08)", "18+(H09)", "18+(H10)", "18+(H11) "18+(H12)", "18+(H13)", "18+(H14) ", "18+(H15)", "18+(H16) "18+(H17)", "18+(H18)", "18+(H19)", "18+(H20)", "18 +(H21) "18+(H22)", "18+(H23)", "18+(H24)", "18+(H25)", "18+(H26) "18+(H27)", "18+(H28)", "18+(H29)", "18+(H30)", "18+(H31) "18+(H32)", "18+(H33)", "18+( H34)", "18+(H35)", "18+(H36)" "18+(H37)", "18+(H38)", "18+(H39)", "18+(H40)" , "18+(H41)" "18+(H42)", "18+(H43)", "18+(H44)", "18+(H45)", "18+(H46)" "18+ (H47)", "18+(H48)", "18+(H49)", "18+(H50)", "18+(I01)", "18+(I02)" "18+(I03) ", "18+(I04)", "18+(I05)", "18+(I06)", "18+(I07)", "18+(I08)" "18+(I09)", " 18+(I10)", "18+(J01)", "18+(J02)", "18+(J03)", "18+(J04)" "18+(J05)", "18+( J06)", "18+(K01)", "18+(K02)", "18+(K03)" "18+(K04)", "18+(K05)", "18+(K06)" , "18+(K07) ", "18+(K08)" "18+(K09)", "18+(K10)", "18+(K11)", "18+(K12)", "18+(K13)" "18 +(K14)", "18+(L01)", "18+(L02)", "18+(L03)", "18+(L04)", "18+(L05)" "18+(L06) )", "18+(L07)", "18+(L08)", "18+(L09)", "18+(L10)", "18+(L11)" "18+(L12)", "18+(L13)", "18+(L14)", "18+(L15)", "18+(L16)", "18+(L17)" "18+(L18)", "18+ (L19)", "18+(L20)", "18+(L21)", "18+(L22)", "18+(L23)" "18+(L24)", "18+(L25) ", "18+(L26)", "18+(L27)", "18+(L28)", "18+(L29)" "18+(L30)", "18+(L31)", " 18+(L32)", "18+(L33)", "18+(L34)", "18+(M01)", "18+(M02)", "18+(M03)", "18+ (M04)", "18+(M05)", "18+(M06)", "18+(M07)", "18+(M08)", "18+(M09)", "18+(M10) )", "18+(M11)", "18+(M12)" , "18+(M13)", "18+(M14)", "18+(M15)", "18+(M16)" , "18+(M17)", "18+(M18)", "18+(M19)", "18+(M20)", "18+(M21)", "18+(M22)", " 18+(M23)",
[00239] "19+(A01)", "19+(A02)", "19+(A03)", "19+(A04)", "19+(A05)", "19+(A06)" , "19+(A07)", "19+(A08)", "19+(A09)", "19+(A10)", "19+(A11)", "19+(A12)", " 19+(B01)", "19+(B02)", "19+(B03)", "19+(B04)", "19+(B05)", "19+(B06)", "19+ (B07)", "19+(B08)", "19+(B09)", "19+(B10)", "19+(B11)", "19+(B12)", "19+(C01) )", "19+(C02)", "19+(C03)", "19+(C04)", "19+(C05)", "19+(C06)", "19+(C07)" , "19+(C08)", "19+(C09)", "19+(C10)", "19+(C11)", "19+(C12)", "19+(C13)", " 19+(C14)", "19+(C15)", "19+(C16)", "19+(C17)", "19+(C18)", "19+(C19)", "19+ (C20)", "19+(C21)", "19+(C22)", "19+(C23)", "19+(C24)", "19+(C25)", 19+(C26) ", "19+(C27)", "19+(C28)", "19+(C29)", "19+(C30) 19+(C31)", "19+(C32)", "19+ (C33)", "19+(C34)", "19+(C35) 19+(C36)", "19+(C37)", "19+(C38)", "19+(C39)", "19+(C40) 19+(C41)", "19+(C42)", "19+(C43)", "19+(C44)", "19+(C45) 19+(C46)", "19+(C47)", "19+(C48)", "19+(D01)", "19+(D02) 19+(D03)", "19+(D04)", "19+(D05) )", "19+(E01)", "19+(E02) 19+(E03)", "19+(E04)", "19+(E05)", "19+(F01)", "19 +(F02) 19+ (F03)", "19+(G01)", "19+(G02)", "19+(G03)", "19+(G04) 19+(G05)", "19+(G06)", "19+(G07)", "19+(G08)", "19+(G09) 19+(G10)", "19+(G11)", "19+(G12)", "19+(G13) )", "19+(H01) 19+(H02)", "19+(H03)", "19+(H04)", "19+(H05)", "19+(H06) 19+(H07 )", "19+(H08)", "19+(H09)", "19+(H10)", "19+(H11) 19+(H12)", "19+(H13)", "19 +(H14)", "19+(H15)", "19+(H16) 19+(H17)", "19+(H18)", "19+(H19)", "19+(H20)" , "19+(H21) 19+(H22)", "19+(H23)", "19+(H24)", "19+(H25)", "19+(H26) 19+(H27)" , "19+(H28)", "19+(H29)", "19+(H30)", "19+(H31) 19+(H32)", "19+(H33)", "19+( H34)", "19+(H35)", "19+(H36) 19+(H37)", "19+(H38)", "19+(H39)", "19+(H40)", " 19+(H41) 19+(H42)", "19+(H43)", "19+(H44)", "19+(H45)", "19+(H46) "19+(H47)", "19+(H48)", "19+(H49)", "19+(H50)", "19+(I01)", "19+(I02)" "19+(I03)", "19+ (I04)", "19+(I05)", "19+(I06)", "19+(I07)", "19+(I08)" "19+(I09)", "19+(I10) ", "19+(J01)", "19+(J02)", "19+(J03)", "19+(J04)" "19+(J05)", "19+(J06)", " 19+(K01)", "19+(K02)", "19+(K03)" "19+(K04)", "19+(K05)", "19+(K06)", "19+( K07)", "19+(K08)" "19+(K09)", "19+(K10)", "19+(K11)", "19+(K12)", "19+(K13)" "19+( K14)", "19+(L01)", "19+(L02)", "19+(L03)", "19+(L04)", "19+(L05)" "19+(L06)" , "19+(L07)", "19+(L08)", "19+(L09)", "19+(L10)", "19+(L11)" "19+(L12)", "19 +(L13)", "19+(L14)", "19+(L15)", "19+(L16)", "19+(L17)" "19+(L18)", "19+(L19) )", "19+(L20)", "19+(L21)", "19+(L22)", "19+(L23)" "19+(L24)", "19+(L25)", "19+(L26)", "19+(L27)", "19+(L28)", "19+(L29)" "19+(L30)", "19+(L31)", "19+ (L32)", "19+(L33)", "19+(L34) "19+(M01)", "19+(M02)", "19+(M03)", "19+(M04)" , "19+(M05) "19+(M06)", "19+(M07)", "19+(M08)", "19+(M09)", "19+(M10) "19+(M11) )", "19+(M12)", "19+(M13)", "19+(M14)", "19+(M15) "19+(M16)", "19+(M17)", " 19+(M18)", "19+(M19)", "19+(M20) "19+(M21)", "19+(M22)", "19+(M23)",
[00240] "20+(A01)", "20+(A02)", "20+(A03)", "20+(A04) "20+(A05)", "20+(A06)", " 20+(A07)", "20+(A08)", "20+(A09) "20+(A10)", "20+(A11)", "20+(A12)", "20+(B01) )", "20+(B02) "20+(B03)", "20+(B04)", "20+(B05)", "20+(B06)", "20+(B07) "20+ (B08)", "20+(B09)", "20+(B10)", "20+(B11)", "20+(B12) "20+(C01)", "20+(C02)" , "20+(C03)", "20+(C04)", "20+(C05) "20+(C06)", "20+(C07)", "20+(C08)", "20+ (C09)", "20+(C10)", "20+(C11)", "20+(C12)", "20+(C13)", "20+(C14)", "20+(C15)" 20+(C16)", "20+(C17)", "20+(C18)", "20+(C19)", "20+(C20) "20+(C21)", "20+(C22) )", "20+(C23)", "20+(C24)", "20+(C25) "20+(C26)", "20+(C27)", "20+(C28)", " 20+(C29)", "20+(C30) "20+(C31)", "20+(C32)", "20+(C33)", "20+(C34)", "20+(C35) ) "20+(C36)", "20+(C37)", "20+(C38)", "20+(C39)", "20+(C40) "20+(C41)", "20+ (C42)", "20+(C43)", "20+(C44)", "20+(C45) "20+(C46)", "20+(C47)", "20+(C48)" , "20+(D01)", "20+(D02) "20+(D03)", "20+(D04)", "20+(D05)", "20+(E01)", "20+ (E02) "20+(E03)", "20+(E04)", "20+(E05)", "20+(F01)", "20+(F02) "20+(F03)", " 20+( G01)", "20+(G02)", "20+(G03)", "20+(G04) "20+(G05)", "20+(G06)", "20+(G07)", "20+(G08)", "20+(G09) "20+(G10)", "20+(G11)", "20+(G12)", "20+(G13)", "20+( H01) "20+(H02)", "20+(H03)", "20+(H04)", "20+(H05)", "20+(H06) "20+(H07)", "20 +(H08)", "20+(H09)", "20+(H10)", "20+(H11) "20+(H12)", "20+(H13)", "20+(H14) ", "20+(H15)", "20+(H16) "20+(H17)", "20+(H18)", "20+(H19)", "20+(H20)", "20 +(H21) "20+(H22)", "20+(H23)", "20+(H24)", "20+(H25)", "20+(H26) "20+(H27)", "20+(H28)", "20+(H29)", "20+(H30)", "20+(H31) "20+(H32)", "20+(H33)", "20+( H34)", "20+(H35)", "20+(H36) "20+(H37)", "20+(H38)", "20+(H39)", "20+(H40)", "20+(H41) "20+(H42)", "20+(H43)", "20+(H44)", "20+(H45)", "20+(H46) "20+(H47) ", "20+(H48)", "20+(H49)", "20+(H50)", "20+(I01)", "20+(I02)" "20+(I03)", " 20+(I04)", "20+(I05)", "20+(I06)", "20+(I07)", "20+(I08)" "20+(I09)", "20+( I10)", "20+(J01)", "20+(J02)", "20+(J03)", "20+(J04)" "20+(J05)", "20+(J06)" , "20+(K01)", "20+(K02)", "20+(K03)", "20+(K04)", "20+(K05)", "20+(K06)", " 20+(K07)", "20+(K08)", "20+(K09)", "20+(K10)", "20+(K11)", "20+(K12)", "20+(K13)", "20 +(K14)", "20+(L01)", "20+(L02)", "20+(L03)", "20+(L04)", "20+(L05)" "20+(L06) )", "20+(L07)", "20+(L08)", "20+(L09)", "20+(L10)", "20+(L11)" "20+(L12)", "20+(L13)", "20+(L14)", "20+(L15)", "20+(L16)", "20+(L17)" "20+(L18)", "20+ (L19)", "20+(L20)", "20+(L21)", "20+(L22)", "20+(L23)" "20+(L24)", "20+(L25) ", "20+(L26)", "20+(L27)", "20+(L28)", "20+(L29)" "20+(L30)", "20+(L31)", " 20+(L32)", "20+(L33)", "20+(L34) "20+(M01)", "20+(M02)", "20+(M03)", "20+(M04) )", "20+(M05) "20+(M06)", "20+(M07)", "20+(M08)", "20+(M09)", "20+(M10) "20+ (M11)", "20+(M12)", "20+(M13)", "20+(M14)", "20+(M15) "20+(M16)", "20+(M17)" , "20+(M18)", "20+(M19)", "20+(M20) "20+(M21)", "20+(M22)", "20+(M23)",
[00241] "21+(A01)", "21+(A02)", "21+(A03)", "21+(A04) "21+(A05)", "21+(A06)", " 21+(A07)", "21+(A08)", "21+(A09) "21+(A10)", "21+(A11)", "21+(A12)", "21+(B01) )", "21+(B02) "21+(B03)", "21+(B04)", "21+(B05)", "21+(B06)", "21+(B07) "21+ (B08)", "21+(B09)", "21+(B10)", "21+(B11)", "21+(B12) "21+(C01)", "21+(C02)" , "21+(C03)", "21+(C04)", "21+(C05) "21+(C06)", "21+(C07)", "21+(C08)", "21+ (C09)", "21+(C10) "21+(C11)", "21+(C12)", "21+(C13)", "21+(C14)", "21+(C15) 21 +(C16)", "21+(C17)", "21+(C18)", "21+(C19)", "21+(C20) 21+(C21)", "21+(C22)" , "21+(C23)", "21+(C24)", "21+(C25) 21+(C26)", "21+(C27)", "21+(C28)", "21+( C29)", "21+(C30) 21+(C31)", "21+(C32)", "21+(C33)", "21+(C34)", "21+(C35) 21+( C36)", "21+(C37)", "21+(C38)", "21+(C39)", "21+(C40) 21+(C41)", "21+(C42)", " 21+(C43)", "21+(C44)", "21+(C45) 21+(C46)", "21+(C47)", "21+(C48)", "21+(D01) ", "21+(D02) 21+(D03)", "21+(D04)", "21+(D05)", "21+(E01)", "21+(E02) 21+(E03) ", "21+(E04)", "21+(E05)", "21+(F01)", "21+(F02) 21+(F03)", "21+(G01)", "2 1+(G02)", "21+(G03)", "21+(G04) 21+(G05)", "21+(G06)", "21+(G07)", "21+(G08) ", "21+(G09) 21+(G10)", "21+(G11)", "21+(G12)", "21+(G13)", "21+(H01) 21+(H02) ", "21+(H03)", "21+(H04)", "21+(H05)", "21+(H06) 21+(H07)", "21+(H08)", "21+ (H09)", "21+(H10)", "21+(H11) 21+(H12)", "21+(H13)", "21+(H14)", "21+(H15)", "21+(H16) 21+(H17)", "21+(H18)", "21+(H19)", "21+(H20)", "21+(H21) 21+(H22)", "21+(H23)", "21+(H24)", "21+(H25)", "21+(H26) 21+(H27)", "21+(H28)", "21+(H29) )", "21+(H30)", "21+(H31) 21+(H32)", "21+(H33)", "21+(H34)", "21+(H35)", "21 +(H36) 21+(H37)", "21+(H38)", "21+(H39)", "21+(H40)", "21+(H41) 21+(H42)", "21 +(H43)", "21+(H44)", "21+(H45)", "21+(H46) "21+(H47)", "21+(H48)", "21+(H49) ", "21+(H50)", "21+(I01)", "21+(I02)" "21+(I03)", "21+(I04)", "21+(I05)", " 21+(I06)", "21+(I07)", "21+(I08)" "21+(I09)", "21+(I10)", "21+(J01)", "21+( J02)", "21+(J03)", "21+(J04)" "21+(J05)", "21+(J06)", "21+(K01)", "21+(K02)" , "21+(K03)" "21+(K04)", "21+(K05)", "21+(K06)", "21+(K07)", "21+(K08)" "21+ (K09)" , "21+(K10)", "21+(K11)", "21+(K12)", "21+(K13)" "21+(K14)", "21+(L01)", "21 +(L02)", "21+(L03)", "21+(L04)", "21+(L05)" "21+(L06)", "21+(L07)", "21+(L08) )", "21+(L09)", "21+(L10)", "21+(L11)" "21+(L12)", "21+(L13)", "21+(L14)", "21+(L15)", "21+(L16)", "21+(L17)" "21+(L18)", "21+(L19)", "21+(L20)", "21+ (L21)", "21+(L22)", "21+(L23)", "21+(L24)", "21+(L25)", "21+(L26)", "21+(L27) )", "21+(L28)", "21+(L29)", "21+(L30)", "21+(L31)", "21+(L32)", "21+(L33)" , "21+(L34)", "21+(M01)", "21+(M02)", "21+(M03)", "21+(M04)", "21+(M05)", " 21+(M06)", "21+(M07)", "21+(M08)", "21+(M09)", "21+(M10)", "21+(M11)", "21+ (M12)", "21+(M13)", "21+(M14)", "21+(M15)", "21+(M16)", "21+(M17)", "21+(M18) )", "21+(M19)", "21+(M20)", "21+(M21)", "21+(M22)", "3+(M23)",
[00242] "22+(A01)", "22+(A02)", "22+(A03)", "22+(A04)", "22+(A05)", "22+(A06)" , "22+(A07)", "22+(A08)", "22+(A09)", "22+(A10)", "22+(A11)", "22+(A12)", " 22+(B01)", "22+(B02)", "22+(B03)", "22+(B04)", "22+(B05)", "22+(B06)", "22+ (B07)", "22+(B08)", "22+(B09)", "22+(B10)", "22+(B11)", "22+(B12)", "22+(C01) )", "22+(C02)", "22+(C03)", "22+(C04)", "22+(C05)", "22+(C06)", "22+(C07)" , "22+(C08)", "22+(C09)", "22+(C10)", "22+(C11)", "22+(C12)", "22+(C13)", " 22+(C14)", "22+(C15)", "22+(C16)", "22+(C17)", "22+(C18)", "22+(C19)", "22+ (C20)", "22+(C21)", "22+(C22)", "22+(C23)", "22+(C24)", "22+(C25)", "22+(C26) )", "22+(C27)", "22+(C28)", "22+(C29)", "22+(C30)", "22+(C31)", "22+(C32)" , "22+(C33)", "22+(C34)", "22+(C35)", "22+(C36)", "22+(C37)", "22+(C38)", " 22+(C39)", "22+(C40)", "22+(C41)", "22+(C42)", "22+(C43)", "22+(C44)", "22+ (C45)", "22+(C46)", "22+(C47)", "22+(C48)", "22+(D01)", "22+(D02)", "22+(D03) )", "22+(D04)", "22+(D05)", "22+(E01)", "22+(E02)", "22+(E03)", "22+(E04)" , "22+(E05)", "22+(F0) 1)", "22+(F02)", "22+(F03)", "22+(G01)", "22+(G02)", "22+(G03)", "22+(G04) ", "22+(G05)", "22+(G06)", "22+(G07)", "22+(G08)", "22+(G09)", "22+(G10)", "22+(G11)", "22+(G12)", "22+(G13)", "22+(H01)", "22+(H02)", "22+(H03)", "22 +(H04)", "22+(H05)", "22+(H06)", "22+(H07)", "22+(H08)", "22+(H09)", "22+( H10)", "22+(H11)", "22+(H12)", "22+(H13)", "22+(H14)", "22+(H15)", "22+(H16) "22+(H17)", "22+(H18)", "22+(H19)", "22+(H20)", "22+(H21) "22+(H22)", "22+( H23)", "22+(H24)", "22+(H25)", "22+(H26) "22+(H27)", "22+(H28)", "22+(H29)", "22+(H30)", "22+(H31) "22+(H32)", "22+(H33)", "22+(H34)", "22+(H35)", "22+( H36) "22+(H37)", "22+(H38)", "22+(H39)", "22+(H40)", "22+(H41) "22+(H42)", "22 +(H43)", "22+(H44)", "22+(H45)", "22+(H46) "22+(H47)", "22+(H48)", "22+(H49) ", "22+(H50)", "22+(I01)", "22+(I02)" "22+(I03)", "22+(I04)", "22+(I05)", " 22+(I06)", "22+(I07)", "22+(I08)" "22+(I09)", "22+(I10)", "22+(J01)", "22+( J02)", "22+(J03)", "22+(J04)" "22+(J05)", "22+(J06)", "22+(K01)", "22+(K02)" , "22+(K03)", "22 +(K04)", "22+(K05)", "22+(K06)", "22+(K07)", "22+(K08)", "22+(K09)", "22+( K10)", "22+(K11)", "22+(K12)", "22+(K13)", "22+(K14)", "22+(L01)", "22+(L02) ", "22+(L03)", "22+(L04)", "22+(L05)" "22+(L06)", "22+(L07)", "22+(L08)", " 22+(L09)", "22+(L10)", "22+(L11)" "22+(L12)", "22+(L13)", "22+(L14)", "22+( L15)", "22+(L16)", "22+(L17)" "22+(L18)", "22+(L19)", "22+(L20)", "22+(L21)" , "22+(L22)", "22+(L23)" "22+(L24)", "22+(L25)", "22+(L26)", "22+(L27)", "22 +(L28)", "22+(L29)" "22+(L30)", "22+(L31)", "22+(L32)", "22+(L33)", "22+(L34) )", "22+(M01)", "22+(M02)", "22+(M03)", "22+(M04)", "22+(M05)", "22+(M06)" , "22+(M07)", "22+(M08)", "22+(M09)", "22+(M10)", "22+(M11)", "22+(M12)", " 22+(M13)", "22+(M14)", "22+(M15)", "22+(M16)", "22+(M17)", "22+(M18)", "22+ (M19)", "22+(M20)", "22+(M21)", "22+(M22)", "22+(M23)",
[00243] "23+(A01)", "23+(A02)", "23+(A03)", "23+(A04)", "23+(A05)", "23+(A06)" , "23+(A07)", "23+(A08)", "23+(A09)", "23+(A10)", "23+(A11)", "23+(A12)", " 23+(B01)", "23+(B02)", "23+(B03)", "23+(B04)", "23+(B05)", "23+(B06)", "23+ (B07)", "23+(B08)", "23+(B09)", "23+(B10)", "23+(B11)", "23+(B12)", "23+(C01) )", "23+(C02)", "23+(C03)", "23+(C04)", "23+(C05)", "23+(C06)", "23+(C07)" , "23+(C08)", "23+(C09)", "23+(C10) "23+(C11)", "23+(C12)", "23+(C13)", "23+ (C14)", "23+(C15) "23+(C16)", "23+(C17)", "23+(C18)", "23+(C19)", "23+(C20)" 23+(C21)", "23+(C22)", "23+(C23)", "23+(C24)", "23+(C25) "23+(C26)", "23+(C27) )", "23+(C28)", "23+(C29)", "23+(C30) "23+(C31)", "23+(C32)", "23+(C33)", " 23+(C34)", "23+(C35) "23+(C36)", "23+(C37)", "23+(C38)", "23+(C39)", "23+(C40) ) "23+(C41)", "23+(C42)", "23+(C43)", "23+(C44)", "23+(C45) "23+(C46)", "23+ (C47)", "23+(C48)", "23+(D01)", "23+(D02) "23+(D03)", "23+(D04)", "23+(D05)" , "23+(E01)", "23+(E02) "23+(E03)", "23+(E04)", "23+(E05)", "23+(F01)", "23+ (F02) "23+ (F03)", "23+(G01)", "23+(G02)", "23+(G03)", "23+(G04) "23+(G05)", "23+(G06)" , "23+(G07)", "23+(G08)", "23+(G09) "23+(G10)", "23+(G11)", "23+(G12)", "23+ (G13)", "23+(H01) "23+(H02)", "23+(H03)", "23+(H04)", "23+(H05)", "23+(H06)" 23+(H07)", "23+(H08)", "23+(H09)", "23+(H10)", "23+(H11) "23+(H12)", "23+(H13) )", "23+(H14)", "23+(H15)", "23+(H16) "23+(H17)", "23+(H18)", "23+(H19)", " 23+(H20)", "23+(H21) "23+(H22)", "23+(H23)", "23+(H24)", "23+(H25)", "23+(H26) ) "23+(H27)", "23+(H28)", "23+(H29)", "23+(H30)", "23+(H31) "23+(H32)", "23+ (H33)", "23+(H34)", "23+(H35)", "23+(H36) "23+(H37)", "23+(H38)", "23+(H39)" , "23+(H40)", "23+(H41) "23+(H42)", "23+(H43)", "23+(H44)", "23+(H45)", "23+ (H46) "23+(H47)", "23+(H48)", "23+(H49)", "23+(H50)", "23+(I01)", "23+(I02)" "23+(I03)", "23+(I04)", "23+(I05)", "23+(I06)", "23+(I07)", "23+(I08)" "23+ (I09)", "23+(I10)", "23+(J01)", "23+(J02)", "23+(J03)", "23+(J04)" "23+(J05) ", "23+(J06)", "23+(K01)", "23+(K02)", "23+(K03)" "23+(K04)", "23+(K05)", " 23+(K06)", "23+(K07)", "23+(K08)" "23+(K09)", "23+(K10)", "23+(K11)", "23+(K12)", "23+ (K13)" "23+(K14)", "23+(L01)", "23+(L02)", "23+(L03)", "23+(L04)", "23+(L05) ""23+(L06)", "23+(L07)", "23+(L08)", "23+(L09)", "23+(L10)", "23+(L11)" "23 +(L12)", "23+(L13)", "23+(L14)", "23+(L15)", "23+(L16)", "23+(L17)" "23+(L18) )", "23+(L19)", "23+(L20)", "23+(L21)", "23+(L22)", "23+(L23)" "23+(L24)", "23+(L25)", "23+(L26)", "23+(L27)", "23+(L28)", "23+(L29)" "23+(L30)", "23+ (L31)", "23+(L32)", "23+(L33)", "23+(L34)", "23+(M01)", "23+(M02)", "23+(M03) )", "23+(M04)", "23+(M05)", "23+(M06)", "23+(M07)", "23+(M08)", "23+(M09)" , "23+(M10)", "23+(M11)", "23+(M12)", "23+(M13)", "23+(M14)", "23+(M15)", " 23+(M16)", "23+(M17)", "23+(M18)", "23+(M19)", "23+(M20)", "23+(M21)", "23 +(M22)", "23+(M23)",
[00244] "24+(A01)", "24+(A02)", "24+(A03)", "24+(A04)", "24+(A05)", "24+(A06)" , "24+(A07)", "24+(A08)", "24+(A09)", "24+(A10)", "24+(A11)", "24+(A12)", " 24+(B01)", "24+(B02)", "24+(B03)", "24+(B04)", "24+(B05)", "24+(B06)", "24+ (B07)", "24+(B08)", "24+(B09)", "24+(B10)", "24+(B11)", "24+(B12)", "24+(C01) )", "24+(C02)", "24+(C03)", "24+(C04)", "24+(C05)", "24+(C06)", "24+(C07)" , "24+(C08)", "24+(C09)", "24+(C10)", "24+(C11)", "24+(C12)", "24+(C13)", " 24+(C14)", "24+(C15)", "24+(C16)", "24+(C17)", "24+(C18)", "24+(C19)", "24+ (C20)", "24+(C21)", "24+(C22)", "24+(C23)", "24+(C24)", "24+(C25)", "24+(C26) )", "24+(C27)", "24+(C28)", "24+(C29)", "24+(C30)", "24+(C31)", "24+(C32)" , "24+(C33)", "24+(C34)", "24+(C35)", "24+(C36)", "24+(C37)", "24+(C38)", " 24+(C39)", "24+(C40)", "24+(C41)", "24+(C42)", "24+(C43)", "24+(C44)", "24+ (C45)", "24+(C46)", "24+(C47)", "24+(C48)", "24+(D01)", "24+(D02)", "24+(D03) )", "24+(D04)", "24+(D05)", "24+(E01)", "24+(E02)", "24+(E03)", "24+(E04)" , "24+(E05)", "24+(F0) 1)", "24+(F02)", "24+(F03)", "24+(G01)", "24+(G02)", "24+(G03)", "24+(G04) ", "24+(G05)", "24+(G06)", "24+(G07)", "24+(G08)", "24+(G09)", "24+(G10)", "24+(G11)", "24+(G12)", "24+(G13)", "24+(H01)", "24+(H02)", "24+(H03)", "24 +(H04)", "24+(H05)", "24+(H06)" "24+(H07)", "24+(H08)", "24+(H09)", "24+(H10) )", "24+(H11)" "24+(H12)", "24+(H13)", "24+(H14)", "24+(H15)", "24+(H16)" " 24+(H17)", "24+(H18)", "24+(H19)", "24+(H20)", "24+(H21)" "24+(H22)", "24+( H23)", "24+(H24)", "24+(H25)", "24+(H26)" "24+(H27)", "24+(H28)", "24+(H29)" , "24+(H30)", "24+(H31)" "24+(H32)", "24+(H33)", "24+(H34)", "24+(H35)", "24 +(H36)" "24+(H37)", "24+(H38)", "24+(H39)", "24+(H40)", "24+(H41)" "24+(H42) ", "24+(H43)", "24+(H44)", "24+(H45)", "24+(H46)" "24+(H47)", "24+(H48)", " 24+(H49)", "24+(H50)", "24+(I01)", "24+(I02)" "24+(I03)", "24+(I04)", "24+( I05)", "24+(I06)", "24+(I07)", "24+(I08)" "24+(I09)", "24+(I10)", "24+(J01)" , "24+(J02)", "24+(J03)", "24+(J04)" "24+(J05)", "24+(J06)", "24+(K01)", "24 +(K02)", "24+(K03)" "24+(K04)", "24+(K05)", "24+(K06)", "24+(K07)", "24+(K08)" "24+(K09)", "24+ (K10)", "24+(K11)", "24+(K12)", "24+(K13)" "24+(K14)", "24+(L01)", "24+(L02) ", "24+(L03)", "24+(L04)", "24+(L05)" "24+(L06)", "24+(L07)", "24+(L08)", " 24+(L09)", "24+(L10)", "24+(L11)" "24+(L12)", "24+(L13)", "24+(L14)", "24+( L15)", "24+(L16)", "24+(L17)" "24+(L18)", "24+(L19)", "24+(L20)", "24+(L21)" , "24+(L22)", "24+(L23)" "24+(L24)", "24+(L25)", "24+(L26)", "24+(L27)", "24 +(L28)", "24+(L29)" "24+(L30)", "24+(L31)", "24+(L32)", "24+(L33)", "24+(L34) )", "24+(M01)", "24+(M02)", "24+(M03)", "24+(M04)", "24+(M05)", "24+(M06)" , "24+(M07)", "24+(M08)", "24+(M09)", "24+(M10)", "24+(M11)", "24+(M12)", " 24+(M13)", "24+(M14)", "24+(M15)", "24+(M16)", "24+(M17)", "24+(M18)", "24+ (M19)", "24+(M20)", "24+(M21)", "24+(M22)", "24+(M23)",
[00245] "25+(A01)", "25+(A02)", "25+(A03)", "25+(A04)", "25+(A05)", "25+(A06)" , "25+(A07)", "25+(A08)", "25+(A09)", "25+(A10)", "25+(A11)", "25+(A12)", " 25+(B01)", "25+(B02)", "25+(B03)", "25+(B04)", "25+(B05)", "25+(B06)", "25+ (B07)", "25+(B08)", "25+(B09)", "25+(B10)", "25+(B11)", "25+(B12) "25+(C01)" , "25+(C02)", "25+(C03)", "25+(C04)", "25+(C05) "25+(C06)", "25+(C07)", "25+ (C08)", "25+(C09)", "25+(C10) "25+(C11)", "25+(C12)", "25+(C13)", "25+(C14)" , "25+(C15) "25+(C16)", "25+(C17)", "25+(C18)", "25+(C19)", "25+(C20) "25+(C21) )", "25+(C22)", "25+(C23)", "25+(C24)", "25+(C25) "25+(C26)", "25+(C27)", " 25+(C28)", "25+(C29)", "25+(C30) "25+(C31)", "25+(C32)", "25+(C33)", "25+(C34) )", "25+(C35) "25+(C36)", "25+(C37)", "25+(C38)", "25+(C39)", "25+(C40) "25+ (C41)", "25+(C42)", "25+(C43)", "25+(C44)", "25+(C45) "25+(C46)", "25+(C47)" , "25+(C48)", "25+(D01)", "25+(D02) "25+(D03)", "25+(D04)", "25+(D05)", "25+ (E01)", "25+(E02) "25+(E03)", "25+(E04)", "25+(E05)", "25+(F01)", "25+(F02)" 25+(F03 )", "25+(G01)", "25+(G02)", "25+(G03)", "25+(G04) "25+(G05)", "25+(G06)", " 25+(G07)", "25+(G08)", "25+(G09) "25+(G10)", "25+(G11)", "25+(G12)", "25+(G13) )", "25+(H01) "25+(H02)", "25+(H03)", "25+(H04)", "25+(H05)", "25+(H06) "25+ (H07)", "25+(H08)", "25+(H09)", "25+(H10)", "25+(H11) "25+(H12)", "25+(H13)" , "25+(H14)", "25+(H15)", "25+(H16) "25+(H17)", "25+(H18)", "25+(H19)", "25+ (H20)", "25+(H21) "25+(H22)", "25+(H23)", "25+(H24)", "25+(H25)", "25+(H26)" 25+(H27)", "25+(H28)", "25+(H29)", "25+(H30)", "25+(H31) "25+(H32)", "25+(H33) )", "25+(H34)", "25+(H35)", "25+(H36) "25+(H37)", "25+(H38)", "25+(H39)", " 25+(H40)", "25+(H41) "25+(H42)", "25+(H43)", "25+(H44)", "25+(H45)", "25+(H46) ) "25+(H47)", "25+(H48)", "25+(H49)", "25+(H50)", "25+(I01)", "25+(I02)" "25 +(I03)", "25+(I04)", "25+(I05)", "25+(I06)", "25+(I07)", "25+(I08)" "25+(I09) )", "25+(I10)", "25+(J01)", "25+(J02)", "25+(J03)", "25+(J04)" "25+(J05)", "25+(J06)", "25+(K01)", "25+(K02)", "25+(K03)" "25+(K04)", "25+(K05)", "25+ (K06)", "25+ (K07)", "25+(K08)" "25+(K09)", "25+(K10)", "25+(K11)", "25+(K12)", "25+(K13) ""25+(K14)", "25+(L01)", "25+(L02)", "25+(L03)", "25+(L04)", "25+(L05)" "25 +(L06)", "25+(L07)", "25+(L08)", "25+(L09)", "25+(L10)", "25+(L11)" "25+(L12) )", "25+(L13)", "25+(L14)", "25+(L15)", "25+(L16)", "25+(L17)" "25+(L18)", "25+(L19)", "25+(L20)", "25+(L21)", "25+(L22)", "25+(L23)" "25+(L24)", "25+ (L25)", "25+(L26)", "25+(L27)", "25+(L28)", "25+(L29)" "25+(L30)", "25+(L31) ", "25+(L32)", "25+(L33)", "25+(L34) "25+(M01)", "25+(M02)", "25+(M03)", "25 +(M04)", "25+(M05) "25+(M06)", "25+(M07)", "25+(M08)", "25+(M09)", "25+(M10) "25+(M11)", "25+(M12)", "25+(M13)", "25+(M14)", "25+(M15) "25+(M16)", "25+( M17)", "25+(M18)", "25+(M19)", "25+(M20) "25+(M21)", "25+(M22)", "25+(M23)",
[00246] "26+(A01)", "26+(A02)", "26+(A03)", "26+(A04) "26+(A05)", "26+(A06)", " 26+(A07)", "26+(A08)", "26+(A09) "26+(A10)", "26+(A11)", "26+(A12)", "26+(B01) )", "26+(B02) "26+(B03)", "26+(B04)", "26+(B05)", "26+(B06)", "26+(B07) "26+ (B08)", "26+(B09)", "26+(B10)", "26+(B11)", "26+(B12) "26+(C01)", "26+(C02)" , "26+(C03)", "26+(C04)", "26+(C05) "26+(C06)", "26+(C07)", "26+(C08)", "26+ (C09)", "26+(C10) "26+(C11)", "26+(C12)", "26+(C13)", "26+(C14)", "26+(C15)" 26+(C16)", "26+(C17)", "26+(C18)", "26+(C19)", "26+(C20) "26+(C21)", "26+(C22) )", "26+(C23)", "26+(C24)", "26+(C25) "26+(C26)", "26+(C27)", "26+(C28)", " 26+(C29)", "26+(C30) "26+(C31)", "26+(C32)", "26+(C33)", "26+(C34)", "26+(C35) ) "26+(C36)", "26+(C37)", "26+(C38)", "26+(C39)", "26+(C40) "26+(C41)", "26+ (C42)", "26+(C43)", "26+(C44)", "26+(C45) "26+(C46)", "26+(C47)", "26+(C48)" , "26+(D01)", "26+(D02) "26+(D03)", "26+(D04)", "26+(D05)", "26+(E01)", "26+ (E02) "26+(E03)", "26+(E04)", "26+(E05)", "26+(F01)", "26+(F02) "26+(F03)", " 26+( G01)", "26+(G02)", "26+(G03)", "26+(G04) "26+(G05)", "26+(G06)", "26+(G07)", "26+(G08)", "26+(G09)", "26+(G10)", "26+(G11)", "26+(G12)", "26+(G13)", "26 +(H01)", "26+(H02)", "26+(H03)", "26+(H04)", "26+(H05)", "26+(H06)", "26+( H07)", "26+(H08)", "26+(H09)", "26+(H10)", "26+(H11)", "26+(H12)", "26+(H13) ", "26+(H14)", "26+(H15)", "26+(H16)", "26+(H17)", "26+(H18)", "26+(H19)", "26+(H20)", "26+(H21)", "26+(H22)", "26+(H23)", "26+(H24)", "26+(H25)", "26 +(H26)", "26+(H27)", "26+(H28)", "26+(H29)", "26+(H30)", "26+(H31)", "26+( H32)", "26+(H33)", "26+(H34)", "26+(H35)", "26+(H36)", "26+(H37)", "26+(H38) ", "26+(H39)", "26+(H40)", "26+(H41)", "26+(H42)", "26+(H43)", "26+(H44)", "26+(H45)", "26+(H46)", "26+(H47)", "26+(H48)", "26+(H49)", "26+(H50)", "26 +(I01)", "26+(I02)" "26+(I03)", "26+(I04)", "26+(I05)", "26+(I06)", "26+(I07) )", "26+(I08)" "26+(I09)", "26+(I10)", "26+(J01)", "26+(J02)", "26+(J03)", "26+(J04)" "26+(J05)", "26+(J06)", "26+(K01)", "26+(K02)", "26+(K03)" "26+( K04)", "26+(K05)", "2 6+(K06)", "26+(K07)", "26+(K08)" "26+(K09)", "26+(K10)", "26+(K11)", "26+( K12)", "26+(K13)" "26+(K14)", "26+(L01)", "26+(L02)", "26+(L03)", "26+(L04)" , "26+(L05)" "26+(L06)", "26+(L07)", "26+(L08)", "26+(L09)", "26+(L10)", "26 +(L11)" "26+(L12)", "26+(L13)", "26+(L14)", "26+(L15)", "26+(L16)", "26+(L17) )" "26+(L18)", "26+(L19)", "26+(L20)", "26+(L21)", "26+(L22)", "26+(L23)" " 26+(L24)", "26+(L25)", "26+(L26)", "26+(L27)", "26+(L28)", "26+(L29)" "26+( L30)", "26+(L31)", "26+(L32)", "26+(L33)", "26+(L34) "26+(M01)", "26+(M02)", "26+(M03)", "26+(M04)", "26+(M05) "26+(M06)", "26+(M07)", "26+(M08)", "26+( M09)", "26+(M10) "26+(M11)", "26+(M12)", "26+(M13)", "26+(M14)", "26+(M15) "26 +(M16)", "26+(M17)", "26+(M18)", "26+(M19)", "26+(M20) "26+(M21)",
[00247] ""26+(M22)", "26+(M23)", 27+(A01)", "27+(A02)", "27+(A03)", "27+(A04)" 27+(A05)", "27+(A06)", "27+(A07)", "27+(A08)", "27+(A09) 27+(A10)", "27+(A11) ", "27+(A12)", "27+(B01)", "27+(B02) 27+(B03)", "27+(B04)", "27+(B05)", "27+ (B06)", "27+(B07) 27+(B08)", "27+(B09)", "27+(B10)", "27+(B11)", "27+(B12) 27+ (C01)", "27+(C02)", "27+(C03)", "27+(C04)", "27+(C05) 27+(C06)", "27+(C07)", "27+(C08)", "27+(C09)", "27+(C10) 27+(C11)", "27+(C12)", "27+(C13)", "27+(C14) )", "27+(C15) 27+(C16)", "27+(C17)", "27+(C18)", "27+(C19)", "27+(C20) 27+(C21) )", "27+(C22)", "27+(C23)", "27+(C24)", "27+(C25) 27+(C26)", "27+(C27)", "27 +(C28)", "27+(C29)", "27+(C30) 27+(C31)", "27+(C32)", "27+(C33)", "27+(C34)" , "27+(C35) 27+(C36)", "27+(C37)", "27+(C38)", "27+(C39)", "27+(C40) 27+(C41)" , "27+(C42)", "27+(C43)", "27+(C44)", "27+(C45) 27+(C46)", "27+(C47)", "27+( C48)", "27+(D01)", "27+(D02) 27+(D03)", "27+(D04)", "27+(D05)", "27+(E01)", " 27+(E02) 27+(E03)", "27+(E04)", "27+(E05)", "27+(F01)", "27+(F02) 27+(F03) )", "27+(G01)", "27+(G02)", "27+(G03)", "27+(G04) 27+(G05)", "27+(G06)", "27 +(G07)", "27+(G08)", "27+(G09) 27+(G10)", "27+(G11)", "27+(G12)", "27+(G13)" , "27+(H01) 27+(H02)", "27+(H03)", "27+(H04)", "27+(H05)", "27+(H06) 27+(H07)" , "27+(H08)", "27+(H09)", "27+(H10)", "27+(H11) 27+(H12)", "27+(H13)", "27+( H14)", "27+(H15)", "27+(H16) 27+(H17)", "27+(H18)", "27+(H19)", "27+(H20)", " 27+(H21) 27+(H22)", "27+(H23)", "27+(H24)", "27+(H25)", "27+(H26) 27+(H27)", " 27+(H28)", "27+(H29)", "27+(H30)", "27+(H31) 27+(H32)", "27+(H33)", "27+(H34) ", "27+(H35)", "27+(H36) 27+(H37)", "27+(H38)", "27+(H39)", "27+(H40)", "27+ (H41) 27+(H42)", "27+(H43)", "27+(H44)", "27+(H45)", "27+(H46) "27+(H47)", "27 +(H48)", "27+(H49)", "27+(H50)", "27+(I01)", "27+(I02)" "27+(I03)", "27+(I04) )", "27+(I05)", "27+(I06)", "27+(I07)", "27+(I08)" "27+(I09)", "27+(I10)", "27+(J01)", "27+(J02)", "27+(J03)", "27+(J04)" 27+(J05)", "27+(J06)", "27+( K01)", "27+(K02)", "27+(K03) 27+(K04)", "27+(K05)", "27+(K06)", "27+(K07)", " 27+(K 08) 27+(K09)", "27+(K10)", "27+(K11)", "27+(K12)", "27+(K13) "27+(K14)", "27+ (L01)", "27+(L02)", "27+(L03)", "27+(L04)", "27+(L05)" "27+(L06)", "27+(L07) ", "27+(L08)", "27+(L09)", "27+(L10)", "27+(L11)" "27+(L12)", "27+(L13)", " 27+(L14)", "27+(L15)", "27+(L16)", "27+(L17)" "27+(L18)", "27+(L19)", "27+( L20)", "27+(L21)", "27+(L22)", "27+(L23)" "27+(L24)", "27+(L25)", "27+(L26)" , "27+(L27)", "27+(L28)", "27+(L29)" "27+(L30)", "27+(L31)", "27+(L32)", "27 +(L33)", "27+(L34) "27+(M01)", "27+(M02)", "27+(M03)", "27+(M04)", "27+(M05) "27+(M06)", "27+(M07)", "27+(M08)", "27+(M09)", "27+(M10) "27+(M11)", "27+( M12)", "27+(M13)", "27+(M14)", "27+(M15) "27+(M16)", "27+(M17)", "27+(M18)", "27+(M19)", "27+(M20) "27+(M21)", "27+(M22)", "27+(M23)",
[00248] "28+(A01)", "28+(A02)", "28+(A03)", "28+(A04) "28+(A05)", "28+(A06)", " 28+(A07)", "28+(A08)", "28+(A09) "28+(A10)", "28+(A11)", "28+(A12)", "28+(B01) )", "28+(B02) "28+(B03)", "28+(B04)", "28+(B05)", "28+(B06)", "28+(B07) "28+ (B08)", "28+(B09)", "28+(B10)", "28+(B11)", "28+(B12) "28+(C01)", "28+(C02)" , "28+(C03)", "28+(C04)", "28+(C05) "28+(C06)", "28+(C07)", "28+(C08)", "28+ (C09)", "28+(C10)", "28+(C11)", "28+(C12)", "28+(C13)", "28+(C14)", "28+(C15)" 28+(C16)", "28+(C17)", "28+(C18)", "28+(C19)", "28+(C20) "28+(C21)", "28+(C22) )", "28+(C23)", "28+(C24)", "28+(C25) "28+(C26)", "28+(C27)", "28+(C28)", " 28+(C29)", "28+(C30) "28+(C31)", "28+(C32)", "28+(C33)", "28+(C34)", "28+(C35) ) "28+(C36)", "28+(C37)", "28+(C38)", "28+(C39)", "28+(C40) "28+(C41)", "28+ (C42)", "28+(C43)", "28+(C44)", "28+(C45) "28+(C46)", "28+(C47)", "28+(C48)" , "28+(D01)", "28+(D02) "28+(D03)", "28+(D04)", "28+(D05)", "28+(E01)", "28+ (E02) "28+(E03)", "28+(E04)", "28+(E05)", "28+(F01)", "28+(F02)", "28+(F03)" , "two 8+(G01)", "28+(G02)", "28+(G03)", "28+(G04)", "28+(G05)", "28+(G06)", "28+ (G07)", "28+(G08)", "28+(G09)", "28+(G10)", "28+(G11)", "28+(G12)", "28+(G13) )", "28+(H01)", "28+(H02)", "28+(H03)", "28+(H04)", "28+(H05)", "28+(H06)" , "28+(H07)", "28+(H08)", "28+(H09)", "28+(H10)", "28+(H11)", "28+(H12)", " 28+(H13)", "28+(H14)", "28+(H15)", "28+(H16)", "28+(H17)", "28+(H18)", "28+ (H19)", "28+(H20)", "28+(H21)", "28+(H22)", "28+(H23)", "28+(H24)", "28+(H25) )", "28+(H26)", "28+(H27)", "28+(H28)", "28+(H29)", "28+(H30)", "28+(H31)" , "28+(H32)", "28+(H33)", "28+(H34)", "28+(H35)", "28+(H36)", "28+(H37)", " 28+(H38)", "28+(H39)", "28+(H40)", "28+(H41)", "28+(H42)", "28+(H43)", "28+ (H44)", "28+(H45)", "28+(H46)", "28+(H47)", "28+(H48)", "28+(H49)", "28+(H50) )", "28+(I01)", "28+(I02)" "28+(I03)", "28+(I04)", "28+(I05)", "28+(I06)", "28+(I07)", "28+(I08)" "28+(I09)", "28+(I10)", "28+(J01)", "28+(J02)", "28+ (J03)", "28+(J04)" 28+(J05)", "28+(J06)", "28+(K01)", "28+(K02)", "28+(K03) 28 +(K04)", "28+(K05)", " 28+(K06)", "28+(K07)", "28+(K08) 28+(K09)", "28+(K10)", "28+(K11)", "28+(K12) ", "28+(K13) "28+(K14)", "28+(L01)", "28+(L02)", "28+(L03)", "28+(L04)", "28 +(L05)" "28+(L06)", "28+(L07)", "28+(L08)", "28+(L09)", "28+(L10)", "28+(L11) )" "28+(L12)", "28+(L13)", "28+(L14)", "28+(L15)", "28+(L16)", "28+(L17)" " 28+(L18)", "28+(L19)", "28+(L20)", "28+(L21)", "28+(L22)", "28+(L23)" "28+( L24)", "28+(L25)", "28+(L26)", "28+(L27)", "28+(L28)", "28+(L29)" 28+(L30)", "28+(L31)", "28+(L32)", "28+(L33)", "28+(L34) 28+(M01)", "28+(M02)", "28+(M03) )", "28+(M04)", "28+(M05) 28+(M06)", "28+(M07)", "28+(M08)", "28+(M09)", "28 +(M10) 28+(M11)", "28+(M12)", "28+(M13)", "28+(M14)", "28+(M15) 28+(M16)", "28 +(M17)", "28+(M18)", "28+(M19)", "28+(M20) "28+(M21)", "28+(M22)", "28+(M23) ",
[00249] "29+(A01)", "29+(A02)", "29+(A03)", "29+(A04) "29+(A05)", "29+(A06)", " 29+(A07)", "29+(A08)", "29+(A09) "29+(A10)", "29+(A11)", "29+(A12)", "29+(B01) )", "29+(B02) "29+(B03)", "29+(B04)", "29+(B05)", "29+(B06)", "29+(B07) "29+ (B08)", "29+(B09)", "29+(B10)", "29+(B11)", "29+(B12) "29+(C01)", "29+(C02)" , "29+(C03)", "29+(C04)", "29+(C05) "29+(C06)", "29+(C07)", "29+(C08)", "29+ (C09)", "29+(C10) "29+(C11)", "29+(C12)", "29+(C13)", "29+(C14)", "29+(C15)" 29+(C16)", "29+(C17)", "29+(C18)", "29+(C19)", "29+(C20) "29+(C21)", "29+(C22) )", "29+(C23)", "29+(C24)", "29+(C25) "29+(C26)", "29+(C27)", "29+(C28)", " 29+(C29)", "29+(C30) "29+(C31)", "29+(C32)", "29+(C33)", "29+(C34)", "29+(C35) ) "29+(C36)", "29+(C37)", "29+(C38)", "29+(C39)", "29+(C40) "29+(C41)", "29+ (C42)", "29+(C43)", "29+(C44)", "29+(C45) "29+(C46)", "29+(C47)", "29+(C48)" , "29+(D01)", "29+(D02) "29+(D03)", "29+(D04)", "29+(D05)", "29+(E01)", "29+ (E02) "29+(E03)", "29+(E04)", "29+(E05)", "29+(F01)", "29+(F02) "29+(F03)", " 29+( G01)", "29+(G02)", "29+(G03)", "29+(G04) "29+(G05)", "29+(G06)", "29+(G07)", "29+(G08)", "29+(G09) "29+(G10)", "29+(G11)", "29+(G12)", "29+(G13)", "29+( H01) "29+(H02)", "29+(H03)", "29+(H04)", "29+(H05)", "29+(H06) "29+(H07)", "29 +(H08)", "29+(H09)", "29+(H10)", "29+(H11) "29+(H12)", "29+(H13)", "29+(H14) ", "29+(H15)", "29+(H16) "29+(H17)", "29+(H18)", "29+(H19)", "29+(H20)", "29 +(H21) "29+(H22)", "29+(H23)", "29+(H24)", "29+(H25)", "29+(H26) "29+(H27)", "29+(H28)", "29+(H29)", "29+(H30)", "29+(H31) "29+(H32)", "29+(H33)", "29+( H34)", "29+(H35)", "29+(H36) "29+(H37)", "29+(H38)", "29+(H39)", "29+(H40)", "29+(H41) "29+(H42)", "29+(H43)", "29+(H44)", "29+(H45)", "29+(H46) "29+(H47) ", "29+(H48)", "29+(H49)", "29+(H50)", "29+(I01)", "29+(I02) "29+(I03)", "29 +(I04)", "29+(I05)", "29+(I06)", "29+(I07)", "29+(I08)" "29+(I09)", "29+(I10) )", "29+(J01)", "29+(J02)", "29+(J03)", "29+(J04)" "29+(J05)", "29+(J06)", "29+(K01)", "29+(K02)", "29+(K03)" "29+(K04)", "29+(K05)", "29+(K06)", "29+ (K07)", "29+(K08)" "29+(K09)", "29+(K10)", "29+(K11)", "29+(K12)", "29+(K13)" "29+( K14)", "29+(L01)", "29+(L02)", "29+(L03)", "29+(L04)", "29+(L05)" "29+(L06)" , "29+(L07)", "29+(L08)", "29+(L09)", "29+(L10)", "29+(L11)" "29+(L12)", "29 +(L13)", "29+(L14)", "29+(L15)", "29+(L16)", "29+(L17)" "29+(L18)", "29+(L19) )", "29+(L20)", "29+(L21)", "29+(L22)", "29+(L23)" "29+(L24)", "29+(L25)", "29+(L26)", "29+(L27)", "29+(L28)", "29+(L29)" "29+(L30)", "29+(L31)", "29+ (L32)", "29+(L33)", "29+(L34) "29+(M01)", "29+(M02)", "29+(M03)", "29+(M04)" , "29+(M05) "29+(M06)", "29+(M07)", "29+(M08)", "29+(M09)", "29+(M10) "29+(M11) )", "29+(M12)", "29+(M13)", "29+(M14)", "29+(M15) "29+(M16)", "29+(M17)", " 29+(M18)", "29+(M19)", "29+(M20) "29+(M21)", "29+(M22)", "29+(M23)",
[00250] "30+(A01)", "30+(A02)", "30+(A03)", "30+(A04) "30+(A05)", "30+(A06)", " 30+(A07)", "30+(A08)", "30+(A09) "30+(A10)", "30+(A11)", "30+(A12)", "30+(B01) )", "30+(B02) "30+(B03)", "30+(B04)", "30+(B05)", "30+(B06)", "30+(B07) "30+ (B08)", "30+(B09)", "30+(B10)", "30+(B11)", "30+(B12) "30+(C01)", "30+(C02)" , "30+(C03)", "30+(C04)", "30+(C05) "30+(C06)", "30+(C07)", "30+(C08)", "30+ (C09)", "30+(C10)", "30+(C11)", "30+(C12)", "30+(C13)", "30+(C14)", "30+(C15)" 30+(C16)", "30+(C17)", "30+(C18)", "30+(C19)", "30+(C20) "30+(C21)", "30+(C22) )", "30+(C23)", "30+(C24)", "30+(C25) "30+(C26)", "30+(C27)", "30+(C28)", " 30+(C29)", "30+(C30) "30+(C31)", "30+(C32)", "30+(C33)", "30+(C34)", "30+(C35) ) "30+(C36)", "30+(C37)", "30+(C38)", "30+(C39)", "30+(C40) "30+(C41)", "30+ (C42)", "30+(C43)", "30+(C44)", "30+(C45) 30+(C46)", "30+(C47)", "30+(C48)", "30+(D01)", "30+(D02)", 30+(D03)", "30+(D04)", "30+(D05)", "30+(E01)", "30+ (E02)", 30+(E03)", "30+(E04)", "30+(E05)", "30+(F01)", "30+(F02)", 30+(F03)" , "3 0+(G01)", "30+(G02)", "30+(G03)", "30+(G04)", 30+(G05)", "30+(G06)", "30+( G07)", "30+(G08)", "30+(G09)", 30+(G10)", "30+(G11)", "30+(G12)", "30+(G13)" , "30+(H01)", 30+(H02)", "30+(H03)", "30+(H04)", "30+(H05)", "30+(H06)", 30+ (H07)", "30+(H08)", "30+(H09)", "30+(H10)", "30+(H11)", 30+(H12)", "30+(H13) ", "30+(H14)", "30+(H15)", "30+(H16)", 30+(H17)", "30+(H18)", "30+(H19)", " 30+(H20)", "30+(H21)", 30+(H22)", "30+(H23)", "30+(H24)", "30+(H25)", "30+( H26)", 30+(H27)", "30+(H28)", "30+(H29)", "30+(H30)", "30+(H31)", 30+(H32)", "30+(H33)", "30+(H34)", "30+(H35)", "30+(H36)", 30+(H37)", "30+(H38)", "30+ (H39)", "30+(H40)", "30+(H41)", 30+(H42)", "30+(H43)", "30+(H44)", "30+(H45) ", "30+(H46)", "30+(H47)", "30+(H48)", "30+(H49)", "30+(H50)", "30+(I01)", "30+(I02)" "30+(I03)", "30+(I04)", "30+(I05)", "30+(I06)", "30+(I07)", "30+ (I08)" "30+(I09)", "30+(I10)", "30+(J01)", "30+(J02)", "30+(J03)", "30+(J04) ""30+(J05)", "30+(J06)", "30+(K01)", "30+(K02)", "30+(K03)" "30+(K04)", "30 +(K05)", "30+(K06) ", "30+(K07)", "30+(K08)" "30+(K09)", "30+(K10)", "30+(K11)", "30+(K12)", " 30+(K13)" "30+(K14)", "30+(L01)", "30+(L02)", "30+(L03)", "30+(L04)", "30+( L05)" "30+(L06)", "30+(L07)", "30+(L08)", "30+(L09)", "30+(L10)", "30+(L11)" "30+(L12)", "30+(L13)", "30+(L14)", "30+(L15)", "30+(L16)", "30+(L17)" "30+ (L18)", "30+(L19)", "30+(L20)", "30+(L21)", "30+(L22)", "30+(L23)" "30+(L24) ", "30+(L25)", "30+(L26)", "30+(L27)", "30+(L28)", "30+(L29)" "30+(L30)", " 30+(L31)", "30+(L32)", "30+(L33)", "30+(L34)", "30+(M01)", "30+(M02)", "30+ (M03)", "30+(M04)", "30+(M05)", "30+(M06)", "30+(M07)", "30+(M08)", "30+(M09) )", "30+(M10)", "30+(M11)", "30+(M12)", "30+(M13)", "30+(M14)", "30+(M15)" , "30+(M16)", "30+(M17)", "30+(M18)", "30+(M19)", "30+(M20)", "30+(M21)", " 30+(M22)", "30+(M23)",
[00251] "31+(A01)", "31+(A02)", "31+(A03)", "31+(A04)", "31+(A05)", "31+(A06)" , "31+(A07)", "31+(A08)", "31+(A09)", "31+(A10)", "31+(A11)", "31+(A12)", " 31+(B01)", "31+(B02)", "31+(B03)", "31+(B04)", "31+(B05)", "31+(B06)", "31+ (B07)", "31+(B08)", "31+(B09)", "31+(B10)", "31+(B11)", "31+(B12)", "31+(C01) )", "31+(C02)", "31+(C03)", "31+(C04)", "31+(C05)", "31+(C06)", "31+(C07)" , "31+(C08)", "31+(C09)", "31+(C10)", "31+(C11)", "31+(C12)", "31+(C13)", " 31+(C14)", "31+(C15)", "31+(C16)", "31+(C17)", "31+(C18)", "31+(C19)", "31+ (C20)", "31+(C21)", "31+(C22)", "31+(C23)", "31+(C24)", "31+(C25)", "31+(C26) )", "31+(C27)", "31+(C28)", "31+(C29)", "31+(C30)", "31+(C31)", "31+(C32)" , "31+(C33)", "31+(C34)", "31+(C35)", "31+(C36)", "31+(C37)", "31+(C38)", " 31+(C39)", "31+(C40)", "31+(C41)", "31+(C42)", "31+(C43)", "31+(C44)", "31+ (C45)", "31+(C46)", "31+(C47)", "31+(C48)", "31+(D01)", "31+(D02)", "31+(D03) )", "31+(D04)", "31+(D05)", "31+(E01)", "31+(E02)", "31+(E03)", "31+(E04)" , "31+(E05)", "31+(F0) 1)", "31+(F02)", "31+(F03)", "31+(G01)", "31+(G02)", "31+(G03)", "31+(G04) ", "31+(G05)", "31+(G06)", "31+(G07)", "31+(G08)", "31+(G09)", "31+(G10)", "31+(G11)", "31+(G12)", "31+(G13)", "31+(H01)", "31+(H02)", "31+(H03)", "31 +(H04)", "31+(H05)", "31+(H06)", "31+(H07)", "31+(H08)", "31+(H09)", "31+( H10)", "31+(H11)", "31+(H12)", "31+(H13)", "31+(H14)", "31+(H15)", "31+(H16) ", "31+(H17)", "31+(H18)", "31+(H19)", "31+(H20)", "31+(H21)", "31+(H22)", "31+(H23)", "31+(H24)", "31+(H25)", "31+(H26)", "31+(H27)", "31+(H28)", "31 +(H29)", "31+(H30)", "31+(H31)", "31+(H32)", "31+(H33)", "31+(H34)", "31+( H35)", "31+(H36)", "31+(H37)", "31+(H38)", "31+(H39)", "31+(H40)", "31+(H41) ", "31+(H42)", "31+(H43)", "31+(H44)", "31+(H45)", "31+(H46)" "31+(H47)", " 31+(H48)", "31+(H49)", "31+(H50)", "31+(I01)", "31+(I02)" "31+(I03)", "31+( I04)", "31+(I05)", "31+(I06)", "31+(I07)", "31+(I08)" "31+(I09)", "31+(I10)" , "31+(J01)", "31+(J02)", "31+(J03)", "31+(J04)" "31+(J05)", "31+(J06)", "31 +(K01)", "31+(K02)", "3 1+(K03)" "31+(K04)", "31+(K05)", "31+(K06)", "31+(K07)", "31+(K08)" "31+(K09) )", "31+(K10)", "31+(K11)", "31+(K12)", "31+(K13)" "31+(K14)", "31+(L01)", "31+(L02)", "31+(L03)", "31+(L04)", "31+(L05)" "31+(L06)", "31+(L07)", "31+ (L08)", "31+(L09)", "31+(L10)", "31+(L11)" "31+(L12)", "31+(L13)", "31+(L14) ", "31+(L15)", "31+(L16)", "31+(L17)" "31+(L18)", "31+(L19)", "31+(L20)", " 31+(L21)", "31+(L22)", "31+(L23)" "31+(L24)", "31+(L25)", "31+(L26)", "31+( L27)", "31+(L28)", "31+(L29)" "31+(L30)", "31+(L31)", "31+(L32)", "31+(L33)" , "31+(L34) "31+(M01)", "31+(M02)", "31+(M03)", "31+(M04)", "31+(M05) "31+(M06) )", "31+(M07)", "31+(M08)", "31+(M09)", "31+(M10) "31+(M11)", "31+(M12)", " 31+(M13)", "31+(M14)", "31+(M15) "31+(M16)", "31+(M17)", "31+(M18)", "31+(M19) )", "31+(M20) "31+(M21)", "31+(M22)", "31+(M23)",
[00252] "32+(A01)", "32+(A02)", "32+(A03)", "32+(A04) "32+(A05)", "32+(A06)", " 32+(A07)", "32+(A08)", "32+(A09) "32+(A10)", "32+(A11)", "32+(A12)", "32+(B01) )", "32+(B02) "32+(B03)", "32+(B04)", "32+(B05)", "32+(B06)", "32+(B07) "32+ (B08)", "32+(B09)", "32+(B10)", "32+(B11)", "32+(B12) "32+(C01)", "32+(C02)" , "32+(C03)", "32+(C04)", "32+(C05) "32+(C06)", "32+(C07)", "32+(C08)", "32+ (C09)", "32+(C10) "32+(C11)", "32+(C12)", "32+(C13)", "32+(C14)", "32+(C15)" 32+(C16)", "32+(C17)", "32+(C18)", "32+(C19)", "32+(C20) "32+(C21)", "32+(C22) )", "32+(C23)", "32+(C24)", "32+(C25) "32+(C26)", "32+(C27)", "32+(C28)", " 32+(C29)", "32+(C30) "32+(C31)", "32+(C32)", "32+(C33)", "32+(C34)", "32+(C35) ) 32+(C36)", "32+(C37)", "32+(C38)", "32+(C39)", "32+(C40) 32+(C41)", "32+(C42) )", "32+(C43)", "32+(C44)", "32+(C45) 32+(C46)", "32+(C47)", "32+(C48)", "32 +(D01)", "32+(D02) 32+(D03)", "32+(D04)", "32+(D05)", "32+(E01)", "32+(E02) 32 +(E03)", "32+(E04)", "32+(E05)", "32+(F01)", "32+(F02) 32+(F03)", "32+(G01)" , "32+(G02)", "32+(G03)", "32+(G04) 32+(G05)", "32+(G06)", "32+(G07)", "32+( G08)", "32+(G09) 32+(G10)", "32+(G11)", "32+(G12)", "32+(G13)", "32+(H01) 32+( H02)", "32+(H03)", "32+(H04)", "32+(H05)", "32+(H06) 32+(H07)", "32+(H08)", " 32+(H09)", "32+(H10)", "32+(H11) 32+(H12)", "32+(H13)", "32+(H14)", "32+(H15) ", "32+(H16) 32+(H17)", "32+(H18)", "32+(H19)", "32+(H20)", "32+(H21) 32+(H22) ", "32+(H23)", "32+(H24)", "32+(H25)", "32+(H26) 32+(H27)", "32+(H28)", "32+ (H29)", "32+(H30)", "32+(H31) 32+(H32)", "32+(H33)", "32+(H34)", "32+(H35)", "32+(H36) 32+(H37)", "32+(H38)", "32+(H39)", "32+(H40)", "32+(H41) 32+(H42)", "32+(H43)", "32+(H44)", "32+(H45)", "32+(H46) "32+(H47)", "32+(H48)", "32+( H49)", "32+(H50)", "32+(I01)", "32+(I02)" "32+(I03)", "32+(I04)", "32+(I05)" , "32+(I06)", "32+(I07)", "32+(I08)" "32+(I09)", "32+(I10)", "32+(J01)", "32 +(J02)", "32+(J03)", "32+(J04)" 32+(J05)", "32+(J06)", "32+(K01)", "32+(K02) ", "32+(K03)", 32+(K04)", "32+(K05)", "32+(K06)", "32+(K07)", "32+(K08)", 32 +(K0 9)", "32+(K10)", "32+(K11)", "32+(K12)", "32+(K13)", "32+(K14)", "32+(L01) ", "32+(L02)", "32+(L03)", "32+(L04)", "32+(L05)" "32+(L06)", "32+(L07)", " 32+(L08)", "32+(L09)", "32+(L10)", "32+(L11)" "32+(L12)", "32+(L13)", "32+( L14)", "32+(L15)", "32+(L16)", "32+(L17)" "32+(L18)", "32+(L19)", "32+(L20)" , "32+(L21)", "32+(L22)", "32+(L23)" "32+(L24)", "32+(L25)", "32+(L26)", "32 +(L27)", "32+(L28)", "32+(L29)" "32+(L30)", "32+(L31)", "32+(L32)", "32+(L33) )", "32+(L34)" "32+(M01)", "32+(M02)", "32+(M03)", "32+(M04)", "32+(M05)" " 32+(M06)", "32+(M07)", "32+(M08)", "32+(M09)", "32+(M10) "32+(M11)", "32+(M12) )", "32+(M13)", "32+(M14)", "32+(M15) "32+(M16)", "32+(M17)", "32+(M18)", " 32+(M19)", "32+(M20) "32+(M21)", "32+(M22)", "32+(M23)",
[00253] "33+(A01)", "33+(A02)", "33+(A03)", "33+(A04) "33+(A05)", "33+(A06)", " 33+(A07)", "33+(A08)", "33+(A09) "33+(A10)", "33+(A11)", "33+(A12)", "33+(B01) )", "33+(B02) "33+(B03)", "33+(B04)", "33+(B05)", "33+(B06)", "33+(B07) "33+ (B08)", "33+(B09)", "33+(B10)", "33+(B11)", "33+(B12) "33+(C01)", "33+(C02)" , "33+(C03)", "33+(C04)", "33+(C05) "33+(C06)", "33+(C07)", "33+(C08)", "33+ (C09)", "33+(C10)", "33+(C11)", "33+(C12)", "33+(C13)", "33+(C14)", "33+(C15)" 33+(C16)", "33+(C17)", "33+(C18)", "33+(C19)", "33+(C20) "33+(C21)", "33+(C22) )", "33+(C23)", "33+(C24)", "33+(C25) "33+(C26)", "33+(C27)", "33+(C28)", " 33+(C29)", "33+(C30) "33+(C31)", "33+(C32)", "33+(C33)", "33+(C34)", "33+(C35) ) "33+(C36)", "33+(C37)", "33+(C38)", "33+(C39)", "33+(C40) "33+(C41)", "33+ (C42)", "33+(C43)", "33+(C44)", "33+(C45) "33+(C46)", "33+(C47)", "33+(C48)" , "33+(D01)", "33+(D02) "33+(D03)", "33+(D04)", "33+(D05)", "33+(E01)", "33+ (E02) "33+(E03)", "33+(E04)", "33+(E05)", "33+(F01)", "33+(F02) "33+(F03)", " 33+( G01)", "33+(G02)", "33+(G03)", "33+(G04) "33+(G05)", "33+(G06)", "33+(G07)", "33+(G08)", "33+(G09) "33+(G10)", "33+(G11)", "33+(G12)", "33+(G13)", "33+( H01) "33+(H02)", "33+(H03)", "33+(H04)", "33+(H05)", "33+(H06) "33+(H07)", "33 +(H08)", "33+(H09)", "33+(H10)", "33+(H11) "33+(H12)", "33+(H13)", "33+(H14) ", "33+(H15)", "33+(H16) "33+(H17)", "33+(H18)", "33+(H19)", "33+(H20)", "33 +(H21) "33+(H22)", "33+(H23)", "33+(H24)", "33+(H25)", "33+(H26) "33+(H27)", "33+(H28)", "33+(H29)", "33+(H30)", "33+(H31) "33+(H32)", "33+(H33)", "33+( H34)", "33+(H35)", "33+(H36)" "33+(H37)", "33+(H38)", "33+(H39)", "33+(H40)" , "33+(H41)" "33+(H42)", "33+(H43)", "33+(H44)", "33+(H45)", "33+(H46)" "33+ (H47)", "33+(H48)", "33+(H49)", "33+(H50)", "33+(I01)", "33+(I02)" "33+(I03) ", "33+(I04)", "33+(I05)", "33+(I06)", "33+(I07)", "33+(I08)" "33+(I09)", " 33+(I10)", "33+(J01)", "33+(J02)", "33+(J03)", "33+(J04)" "33+(J05)", "33+( J06)", "33+(K01)", "33+(K02)", "33+(K03)" "33+(K04)", "33+(K05)", "33+(K06)" , "33+(K07) ", "33+(K08)" "33+(K09)", "33+(K10)", "33+(K11)", "33+(K12)", "33+(K13)" "33 +(K14)", "33+(L01)", "33+(L02)", "33+(L03)", "33+(L04)", "33+(L05)" "33+(L06) )", "33+(L07)", "33+(L08)", "33+(L09)", "33+(L10)", "33+(L11)" "33+(L12)", "33+(L13)", "33+(L14)", "33+(L15)", "33+(L16)", "33+(L17)" "33+(L18)", "33+ (L19)", "33+(L20)", "33+(L21)", "33+(L22)", "33+(L23)" "33+(L24)", "33+(L25) ", "33+(L26)", "33+(L27)", "33+(L28)", "33+(L29)" "33+(L30)", "33+(L31)", " 33+(L32)", "33+(L33)", "33+(L34)" "33+(M01)", "33+(M02)", "33+(M03)", "33+( M04)", "33+(M05)" "33+(M06)", "33+(M07)", "33+(M08)", "33+(M09)", "33+(M10)" "33+(M11)", "33+(M12)", "33+(M13)", "33+(M14)", "33+(M15)" "33+(M16)", "33+ (M17)", "33+(M18)", "33+(M19)", "33+(M20)" "33+(M21)", "33+(M22)", "33+(M23) ",
[00254] "34+(A01)", "34+(A02)", "34+(A03)", "34+(A04)" "34+(A05)", "34+(A06)", "34+(A07)", "34+(A08)", "34+(A09)" "34+(A10)", "34+(A11)", "34+(A12)", "34+ (B01)", "34+(B02)" "34+(B03)", "34+(B04)", "34+(B05)", "34+(B06)", "34+(B07) ""34+(B08)", "34+(B09)", "34+(B10)", "34+(B11)", "34+(B12)" "34+(C01)", "34 +(C02)", "34+(C03)", "34+(C04)", "34+(C05)" "34+(C06)", "34+(C07)", "34+(C08) )", "34+(C09)", "34+(C10)" "34+(C11)", "34+(C12)", "34+(C13)", "34+(C14)", "34+(C15)" "34+(C16)", "34+(C17)", "34+(C18)", "34+(C19)", "34+(C20)" "34+( C21)", "34+(C22)", "34+(C23)", "34+(C24)", "34+(C25)" 34+(C26)", "34+(C27)", "34+(C28)", "34+(C29)", "34+(C30) 34+(C31)", "34+(C32)", "34+(C33)", "34+(C34) )", "34+(C35) 34+(C36)", "34+(C37)", "34+(C38)", "34+(C39)", "34+(C40) 34+(C41) )", "34+(C42)", "34+(C43)", "34+(C44)", "34+(C45) 34+(C46)", "34+(C47)", "34 +(C48)", "34+(D01)", "34+(D02) 34+(D03)", "34+(D04)", "34+(D05)", "34+(E01)" , "34+(E02) 34+(E03)", "34+(E04)", "34+(E05)", "34+(F01)", "34+(F02) 34+(F03)" , "3 4+(G01)", "34+(G02)", "34+(G03)", "34+(G04) 34+(G05)", "34+(G06)", "34+(G07) ", "34+(G08)", "34+(G09) 34+(G10)", "34+(G11)", "34+(G12)", "34+(G13)", "34+ (H01) 34+(H02)", "34+(H03)", "34+(H04)", "34+(H05)", "34+(H06) 34+(H07)", "34+ (H08)", "34+(H09)", "34+(H10)", "34+(H11) 34+(H12)", "34+(H13)", "34+(H14)", "34+(H15)", "34+(H16) 34+(H17)", "34+(H18)", "34+(H19)", "34+(H20)", "34+(H21) ) 34+(H22)", "34+(H23)", "34+(H24)", "34+(H25)", "34+(H26) 34+(H27)", "34+(H28) )", "34+(H29)", "34+(H30)", "34+(H31) 34+(H32)", "34+(H33)", "34+(H34)", "34 +(H35)", "34+(H36) 34+(H37)", "34+(H38)", "34+(H39)", "34+(H40)", "34+(H41) 34 +(H42)", "34+(H43)", "34+(H44)", "34+(H45)", "34+(H46) "34+(H47)", "34+(H48) ", "34+(H49)", "34+(H50)", "34+(I01)", "34+(I02)" "34+(I03)", "34+(I04)", " 34+(I05)", "34+(I06)", "34+(I07)", "34+(I08)" "34+(I09)", "34+(I10)", "34+( J01)", "34+(J02)", "34+(J03)", "34+(J04)" "34+(J05)", "34+(J06)", "34+(K01)" , "34+(K02)", "34+(K03)" "34+(K04)", "34+(K05)", "34+(K06)", "34+(K07)", "34 +(K08) " "34+(K09)", "34+(K10)", "34+(K11)", "34+(K12)", "34+(K13)" "34+(K14)", "34 +(L01)", "34+(L02)", "34+(L03)", "34+(L04)", "34+(L05)" "34+(L06)", "34+(L07) )", "34+(L08)", "34+(L09)", "34+(L10)", "34+(L11)" "34+(L12)", "34+(L13)", "34+(L14)", "34+(L15)", "34+(L16)", "34+(L17)" "34+(L18)", "34+(L19)", "34+ (L20)", "34+(L21)", "34+(L22)", "34+(L23)" "34+(L24)", "34+(L25)", "34+(L26) ", "34+(L27)", "34+(L28)", "34+(L29)" "34+(L30)", "34+(L31)", "34+(L32)", " 34+(L33)", "34+(L34) "34+(M01)", "34+(M02)", "34+(M03)", "34+(M04)", "34+(M05) ) "34+(M06)", "34+(M07)" "34+(M08)", "34+(M09)", "34+(M10) "34+(M11)", "34+( M12)", "34+(M13)", "34+(M14)", "34+(M15) "34+(M16)", "34+(M17)", "34+(M18)", "34+(M19)", "34+(M20) "34+(M21)", "34+(M22)", "34+(M23)",
[00255] "35+(A01)", "35+(A02)", "35+(A03)", "35+(A04) "35+(A05)", "35+(A06)", " 35+(A07)", "35+(A08)", "35+(A09) "35+(A10)", "35+(A11)", "35+(A12)", "35+(B01) )", "35+(B02) "35+(B03)", "35+(B04)", "35+(B05)", "35+(B06)", "35+(B07) "35+ (B08)", "35+(B09)", "35+(B10)", "35+(B11)", "35+(B12) "35+(C01)", "35+(C02)" , "35+(C03)", "35+(C04)", "35+(C05) "35+(C06)", "35+(C07)", "35+(C08)", "35+ (C09)", "35+(C10)", "35+(C11)", "35+(C12)", "35+(C13)", "35+(C14)", "35+(C15)" 35+(C16)", "35+(C17)", "35+(C18)", "35+(C19)", "35+(C20) "35+(C21)", "35+(C22) )", "35+(C23)", "35+(C24)", "35+(C25) "35+(C26)", "35+(C27)", "35+(C28)", " 35+(C29)", "35+(C30) "35+(C31)", "35+(C32)", "35+(C33)", "35+(C34)", "35+(C35) ) "35+(C36)", "35+(C37)", "35+(C38)", "35+(C39)", "35+(C40) "35+(C41)", "35+ (C42)", "35+(C43)", "35+(C44)", "35+(C45) "35+(C46)", "35+(C47)", "35+(C48)" , "35+(D01)", "35+(D02) "35+(D03)", "35+(D04)", "35+(D05)", "35+(E01)", "35+ (E02) "35+(E03)", "35+(E04)", "35+(E05)", "35+(F01)", "35+(F02) "35+(F03)", " 35+( G01)", "35+(G02)", "35+(G03)", "35+(G04) "35+(G05)", "35+(G06)", "35+(G07)", "35+(G08)", "35+(G09) "35+(G10)", "35+(G11)", "35+(G12)", "35+(G13)", "35+( H01) "35+(H02)", "35+(H03)", "35+(H04)", "35+(H05)", "35+(H06) "35+(H07)", "35 +(H08)", "35+(H09)", "35+(H10)", "35+(H11) "35+(H12)", "35+(H13)", "35+(H14) ", "35+(H15)", "35+(H16) "35+(H17)", "35+(H18)", "35+(H19)", "35+(H20)", "35 +(H21) "35+(H22)", "35+(H23)", "35+(H24)", "35+(H25)", "35+(H26) "35+(H27)", "35+(H28)", "35+(H29)", "35+(H30)", "35+(H31) "35+(H32)", "35+(H33)", "35+( H34)", "35+(H35)", "35+(H36) "35+(H37)", "35+(H38)", "35+(H39)", "35+(H40)", "35+(H41) "35+(H42)", "35+(H43)", "35+(H44)", "35+(H45)", "35+(H46) "35+(H47) ", "35+(H48)", "35+(H49)", "35+(H50)", "35+(I01)", "35+(I02)" "35+(I03)", " 35+(I04)", "35+(I05)", "35+(I06)", "35+(I07)", "35+(I08)" "35+(I09)", "35+( I10)", "35+(J01)", "35+(J02)", "35+(J03)", "35+(J04)" "35+(J05)", "35+(J06)" , "35+(K01)", "35+(K02)", "35+(K03) "35+(K04)", "35+(K05)", "35+(K06)", "35+ (K07)", " 35+(K08) "35+(K09)", "35+(K10)", "35+(K11)", "35+(K12)", "35+(K13) "35+(K14)" , "35+(L01)", "35+(L02)", "35+(L03)", "35+(L04)", "35+(L05)" "35+(L06)", "35 +(L07)", "35+(L08)", "35+(L09)", "35+(L10)", "35+(L11)" "35+(L12)", "35+(L13) )", "35+(L14)", "35+(L15)", "35+(L16)", "35+(L17)" "35+(L18)", "35+(L19)", "35+(L20)", "35+(L21)", "35+(L22)", "35+(L23)" "35+(L24)", "35+(L25)", "35+ (L26)", "35+(L27)", "35+(L28)", "35+(L29)" "35+(L30)", "35+(L31)", "35+(L32) ", "35+(L33)", "35+(L34)", "35+(M01)", "35+(M02)", "35+(M03)", "35+(M04)", "35+(M05)", "35+(M06)", "35+(M07)", "35+(M08)", "35+(M09)", "35+(M10)", "35 +(M11)", "35+(M12)", "35+(M13)", "35+(M14)", "35+(M15)", "35+(M16)", "35+( M17)", "35+(M18)", "35+(M19)", "35+(M20)", "35+(M21)", "35+(M22)", "35+(M23) ",
[00256] "36+(A01)", "36+(A02)", "36+(A03)", "36+(A04)", "36+(A05)", "36+(A06)" , "36+(A07)", "36+(A08)", "36+(A09)", "36+(A10)", "36+(A11)", "36+(A12)", " 36+(B01)", "36+(B02)", "36+(B03)", "36+(B04)", "36+(B05)", "36+(B06)", "36+ (B07)", "36+(B08)", "36+(B09)", "36+(B10)", "36+(B11)", "36+(B12)", "36+(C01) )", "36+(C02)", "36+(C03)", "36+(C04)", "36+(C05)", "36+(C06)", "36+(C07)" , "36+(C08)", "36+(C09)", "36+(C10)", "36+(C11)", "36+(C12)", "36+(C13)", " 36+(C14)", "36+(C15)", 36+(C16)", "36+(C17)", "36+(C18)", "36+(C19)", "36+( C20) 36+(C21)", "36+(C22)", "36+(C23)", "36+(C24)", "36+(C25) 36+(C26)", "36+( C27)", "36+(C28)", "36+(C29)", "36+(C30) 36+(C31)", "36+(C32)", "36+(C33)", " 36+(C34)", "36+(C35) 36+(C36)", "36+(C37)", "36+(C38)", "36+(C39)", "36+(C40) 36+(C41)", "36+(C42)", "36+(C43)", "36+(C44)", "36+(C45) 36+(C46)", "36+(C47) ", "36+(C48)", "36+(D01)", "36+(D02) 36+(D03)", "36+(D04)", "36+(D05)", "36+ (E01)", "36+(E02) 36+(E03)", "36+(E04)", "36+(E05)", "36+(F01)", "36+(F02) 36+ (F03)" , "36+(G01)", "36+(G02)", "36+(G03)", "36+(G04) 36+(G05)", "36+(G06)", "36+( G07)", "36+(G08)", "36+(G09) 36+(G10)", "36+(G11)", "36+(G12)", "36+(G13)", " 36+(H01) 36+(H02)", "36+(H03)", "36+(H04)", "36+(H05)", "36+(H06) 36+(H07)", " 36+(H08)", "36+(H09)", "36+(H10)", "36+(H11) 36+(H12)", "36+(H13)", "36+(H14) ", "36+(H15)", "36+(H16) 36+(H17)", "36+(H18)", "36+(H19)", "36+(H20)", "36+ (H21) 36+(H22)", "36+(H23)", "36+(H24)", "36+(H25)", "36+(H26) 36+(H27)", "36+ (H28)", "36+(H29)", "36+(H30)", "36+(H31) 36+(H32)", "36+(H33)", "36+(H34)", "36+(H35)", "36+(H36) 36+(H37)", "36+(H38)", "36+(H39)", "36+(H40)", "36+(H41) ) 36+(H42)", "36+(H43)", "36+(H44)", "36+(H45)", "36+(H46) "36+(H47)", "36+( H48)", "36+(H49)", "36+(H50)", "36+(I01)", "36+(I02)" "36+(I03)", "36+(I04)" , "36+(I05)", "36+(I06)", "36+(I07)", "36+(I08)" "36+(I09)", "36+(I10)", "36 +(J01)", "36+(J02)", "36+(J03)", "36+(J04)" "36+(J05)", "36+(J06)", "36+(K01) )", "36+(K02)", "36+(K03)" "36+(K04)", "36+(K05)", "36+(K06)", "36+(K07)", "36+( K08)" "36+(K09)", "36+(K10)", "36+(K11)", "36+(K12)", "36+(K13)" "36+(K14)", "36+(L01)", "36+(L02)", "36+(L03)", "36+(L04)", "36+(L05)" "36+(L06)", "36+ (L07)", "36+(L08)", "36+(L09)", "36+(L10)", "36+(L11)" "36+(L12)", "36+(L13) ", "36+(L14)", "36+(L15)", "36+(L16)", "36+(L17)" "36+(L18)", "36+(L19)", " 36+(L20)", "36+(L21)", "36+(L22)", "36+(L23)", "36+(L24)", "36+(L25)", "36+ (L26)", "36+(L27)", "36+(L28)", "36+(L29)", "36+(L30)", "36+(L31)", "36+(L32) )", "36+(L33)", "36+(L34)", "36+(M01)", "36+(M02)", "36+(M03)", "36+(M04)" , "36+(M05)", "36+(M06)", "36+(M07)", "36+(M08)", "36+(M09)", "36+(M10)", " 36+(M11)", "36+(M12)", "36+(M13)", "36+(M14)", "36+(M15)", "36+(M16)", "36+ (M17)", "36+(M18)", "36+(M19)", "36+(M20)", "36+(M21)", "36+(M22)", "36+(M23) )",
[00257] "37+(A01)", "37+(A02)", "37+(A03)", "37+(A04)", "37+(A05)", "37+(A06)" , "37+(A07)", "37+(A08)", "37+(A09)", "37+(A10)", "37+(A11)", "37+(A12)", " 37+(B01)", "37+(B02)", "37+(B03)", "37+(B04)", "37+(B05)", "37+(B06)", "37+ (B07)", "37+(B08)", "37+(B09)", "37+(B10)", "37+(B11)", "37+(B12)", "37+(C01) )", "37+(C02)", "37+(C03)", "37+(C04)", "37+(C05)", "37+(C06)", "37+(C07)" , "37+(C08)", "37+(C09)", "37+(C10)", "37+(C11)", "37+(C12)", "37+(C13)", " 37+(C14)", "37+(C15)", "37+(C16)", "37+(C17)", "37+(C18)", "37+(C19)", "37+ (C20)", "37+(C21)", "37+(C22)", "37+(C23)", "37+(C24)", "37+(C25)", "37+(C26) )", "37+(C27)", "37+(C28)", "37+(C29)", "37+(C30)", "37+(C31)", "37+(C32)" , "37+(C33)", "37+(C34)", "37+(C35)", "37+(C36)", "37+(C37)", "37+(C38)", " 37+(C39)", "37+(C40)", "37+(C41)", "37+(C42)", "37+(C43)", "37+(C44)", "37+ (C45)", "37+(C46)", "37+(C47)", "37+(C48)", "37+(D01)", "37+(D02)", "37+(D03) )", "37+(D04)", "37+(D05)", "37+(E01)", "37+(E02)", "37+(E03)", "37+(E04)" , "37+(E05)", "37+(F0) 1)", "37+(F02)", "37+(F03)", "37+(G01)", "37+(G02)", "37+(G03)", "37+(G04) ", "37+(G05)", "37+(G06)", "37+(G07)", "37+(G08)", "37+(G09)", "37+(G10)", "37+(G11)", "37+(G12)", "37+(G13)", "37+(H01)", "37+(H02)", "37+(H03)", "37 +(H04)", "37+(H05)", "37+(H06)", "37+(H07)", "37+(H08)", "37+(H09)", "37+( H10)", "37+(H11)", "37+(H12)", "37+(H13)", "37+(H14)", "37+(H15)", "37+(H16) ", "37+(H17)", "37+(H18)", "37+(H19)", "37+(H20)", "37+(H21)", "37+(H22)", "37+(H23)", "37+(H24)", "37+(H25)", "37+(H26)", "37+(H27)", "37+(H28)", "37 +(H29)", "37+(H30)", "37+(H31)", "37+(H32)", "37+(H33)", "37+(H34)", "37+( H35)", "37+(H36)", "37+(H37)", "37+(H38)", "37+(H39)", "37+(H40)", "37+(H41) ", "37+(H42)", "37+(H43)", "37+(H44)", "37+(H45)", "37+(H46)", "37+(H47)", "37+(H48)", "37+(H49)", "37+(H50)", "37+(I01)", "37+(I02)" "37+(I03)", "37+ (I04)", "37+(I05)", "37+(I06)", "37+(I07)", "37+(I08)" "37+(I09)", "37+(I10) ", "37+(J01)", "37+(J02)", "37+(J03)", "37+(J04)" "37+(J05)", "37+(J06)", " 37+(K01)", "37+(K02)", " 37+(K03)" "37+(K04)", "37+(K05)", "37+(K06)", "37+(K07)", "37+(K08)" "37+(K09) )", "37+(K10)", "37+(K11)", "37+(K12)", "37+(K13)" "37+(K14)", "37+(L01)", "37+(L02)", "37+(L03)", "37+(L04)", "37+(L05)" "37+(L06)", "37+(L07)", "37+ (L08)", "37+(L09)", "37+(L10)", "37+(L11)" "37+(L12)", "37+(L13)", "37+(L14) ", "37+(L15)", "37+(L16)", "37+(L17)" "37+(L18)", "37+(L19)", "37+(L20)", " 37+(L21)", "37+(L22)", "37+(L23)" "37+(L24)", "37+(L25)", "37+(L26)", "37+( L27)", "37+(L28)", "37+(L29)" "37+(L30)", "37+(L31)", "37+(L32)", "37+(L33)" , "37+(L34)", "37+(M01)", "37+(M02)", "37+(M03)", "37+(M04)", "37+(M05)", " 37+(M06)", "37+(M07)", "37+(M08)", "37+(M09)", "37+(M10)", "37+(M11)", "37+ (M12)", "37+(M13)", "37+(M14)", "37+(M15)", "37+(M16)", "37+(M17)", "37+(M18) )", "37+(M19)", "37+(M20)", "37+(M21)", "37+(M22)", "37+(M23)".
[00258] In the composition of the present invention and the method of the present invention, a suitable mixing ratio of [active ingredient A] selected from oxime substituted amide compounds represented by formula (I) and [active ingredient B] selected from compounds Known fungicides or bactericides is such that, for 1 part by weight of active ingredient A, active ingredient B usually ranges from 0.001 to 1,000 parts by weight, preferably from 0.01 to 100 parts by weight, more preferably from 0.1 to 10 parts by weight.
[00259] In the composition of the present invention and the method of the present invention, a preferred amount of the compound as active ingredient to be applied may vary depending, for example, on the type of target disease to be controlled, but generally it is such that the active ingredient A ranges from 0.1 to 1000 g ai/ha, and active ingredient B ranges from 0.1 to 1000 g ai/ha, and preferably active ingredient A ranges from 1 to 300 g ai/ha, and the active ingredient B ranges from 1 to 300 g ai/ha.
[00260] In this report, a "plant disease controlling agent" means a fungicide or bactericide to control target harmful pathogenic bacteria that infect plants.
[00261] In this report, "plant" means cereals, fruits or vegetables that are cultivated as human food, fodder, for example, for cattle and birds, ornamental plants to enhance their appearance and shapes, or vascular plants (Tracheophyta) planted in parks or streets. Specifically, one can mention, for example, the following plants, but the plant is not limited to these.
[00262] Pinales belonging to the pine family (Pinaceae), such as Japanese red pine (Pinus densiflora), wild pine (Pinus sylvestris), Japanese black pine (Pinus thunbergii), etc.
[00263] Magnolia (magnoliids) belonging to the family of peppers (Piperaceae) such as black pepper (Piper nigrum), Lauraceae such as avocado (Persea americana), etc.,
Monocots belonging to the Araceae family such as Konjac (Amorphophallus konjac), Eddoe (Colocasia esculenta), etc., Dioscoreaceae such as Chinese yam (Dioscorea potatoes), Japanese yam (Dioscorea japonica), etc., green onions family ( Alliaceae) such as leeks (Allium ampeloprasum var. porrum), onions (Allium cepa), Rakkyo (Allium chinense), chives (Allium fistulosum), garlic (Allium sativum), chives (Allium schoenoprasum), chives -French (Allium schoenoprasum var. foli-osum), oriental garlic (Allium tuberosum), scallion (Allium x wakegi), etc., Asparagaceae such as asparagus (Asparagus officinalis), etc., palm family (Arecaceae) subfamily of Dypsis lutescens (Arecoideae) such as coconut (Cocos nucifera), oil palm (Elaeis guineensis), etc., palm family (Arecaceae) subfamily of talipot palm (Coryphoideae) such as date palm (Phoenix dactylifera), etc., family from pineapples (Bromeliaceae) such as pineapples. axi (Ananas comosus), etc., Graminaae (Poaceae) subfamily of Eruharuta (Ehrhartoideae) such as rice (Oryza sativa), etc., Gramineae (Poaceae) subfamily of grassland (Pooideae) such as grass (Agrostis spp.), grassland (Poa spp.), barley (Hordeum vulgare), wheat (Triticum aestivum, T. durum), rye (Secale cereale), etc., Gramine-ae (Poaceae) subfamily Higeshiba (Chloridoideae) such as Bermuda grass (Cynodon dactylon), grass (Zoysia spp.), etc., Gramineae (Poaceae) subfamily of millet (Panicoideae) such as sugarcane (Saccharum officinarum), sorghum (Sorghum bicolor) , corn (Zea mays), etc., Musaceae such as Banana (Musa spp.), etc., ginger family (Zingiberaceae) such as ginger mioga (Zingiber mioga), ginger (Zingiber officinale).
[00265] Eudicotyledons belonging to the lotus family (Nelumbonaceae) such as lotus flower (Nelumbo nucifera), etc., legumes (Fabaceae) such as peanut (Arachis hypogaea), chickpea (Cicer arietinum) , lentil (Lens culinaris), pea (Pisum sativum), broad bean (Vicia faba), soybean (Glycine max), common bean (Phaseolus vulgaris), red bean (Vigna angularis), cowpea (Vigna unguiculata), etc. ., hemp family (Cannabaceae) such as hops (Humulus lupulus), etc., blackberry family (Moraceae) such as fig (Ficus carica), mulberry (Morus spp.), etc., bloodthirsty family (Rhamnaceae) such as common jujube (Ziziphus jujuba), etc., rose family (Rosaceae) rose subfamily (Rosoideae) such as strawberry (Fragaria), rose (Rosa spp.), etc., rose family ( Rosaceae) subfamily of pear (Maloideae) such as Japanese loquat (Eriobotrya japonica), apple (Malus pumila), European pear (Pyrus communis), nashi pear (Pyrus pyrifolia var. cultured), etc., family of roses (Rosaceae) amygdaloideae (Prunoideae) such as peach (Amygdalus persica), apricot (Prunus armeniaca), cherry (Prunus avium), plum (Prunus domestica), almond (Prunus dulcis), Japanese apricot (Prunus mume), Japanese plum (Prunus salicina), OOSHIMAZAKURA (Cerasus speciosa), Yoshino cherry (Cerasus x yedoensis 'Somei-yoshino'), etc., Cucurbitaceae such as winter melon (Benincasa hispida), watermelon (Citrullus lanatus), calabash (Lagenaria siceraria var. hispida), luffa (Luffa cylindrica), pumpkin (Cucurbita spp.), zucchini (Cucurbita pepo), bitter melon (Momordica charantia var. pavel), lace melon (Cucumis melo), melon - oriental bitter (Cucumis melo var. conomon), oriental melon melon (Cucumis melo var. makuwa), cucumber (Cucumis sativus), etc., beech family (Fagaceae) such as Japanese chestnut (Castanea crenata), etc. , nut family (Juglandaceae) such as walnuts (Juglans spp.), etc., Anacardiaceae such as cashew (Anacardi an occidentale), mango (Mangifera indica), pistachio (Pistacia vera), etc., family of mandarin oranges (Rutaceae) subfamily of rue (Rutoideae) such as Japanese pepper (Zanthoxilum piperitum), etc., family of mandarin oranges (Rutaceae) subfamily of mandarin oranges (Aurantioideae) such as bitter orange (Citrus aurantium), lime (Citrus aurantifolia), Hassaku orange (Citrus hassaku), Yuzu (Citrus junos), lemon (Citrus limon) , Natsumikan (Citrus natsudaidai), grapefruit (Citrus x paradisi), orange (Citrus sinensis), Kabo-su (Citrus sphaerocarpa), Sudachi (Citrus sudachi), mandarin orange (Citrus tangerine), Satsuma (Citrus unshiu), cumquat ( Fortunella spp.), etc., crucifers (Brassicaceae) such as horseradish (Armoracia rusticana), mustard (Brassica juncea), takana (Brassica juncea var. integrifolia), canola (Brassica napus), cauliflower (Brassica oleracea var. botrytis), cabbage (Brassica oleracea var. capitata), Brussels cabbage (Brassica oleracea var. gemmifera), broccoli (Brassica oleracea). var. italica), green pak choi (Brassica rapa var. chinensis), Nozawana (Brassica rapa var. hakabura), nappa cabbage (Brassica rapa var. nippo-oleifera), potherb mustard (Brassica rapa var. nipposinica), nappa cabbage ( Brassica rapa var. pekinensis), turnip leaf (Brassica rapa var. perviridis), turnip (Brassica rapa var. rapa), Persian mustard (Eruca vesicaria), daikon (Raphanus sativus var. longipinnatus), wasabi (Wasa- bia japonica), etc., family of papayas (Caricaceae) such as papaya (Carica papaya), etc., Malvaceae such as okra (Abelmoschus esculentus), cotton (Gossypium spp.), cocoa (Theobroma cacao), etc. , family of grapes (Vitaceae) such as grape (Vitis spp.), etc., Amaranthaceae such as red beet (Beta vulgaris ssp. vulgaris var. altissima), table beet (Beta vulgaris ssp. vulgaris var. vulgaris), spinach (Spinacia oleracea), etc., Polygonaceae such as buckwheat (Fagopyrum esculentum), etc., Ebenaceae such as persimmon (Diospyros kaki), etc., camellia family (Theaceae) such as tea. India (Camellia sinensis), etc., Actinidia family (Actinidiaceae) such as kiwi (Actinidia delicious, A. chinensis), etc., azalea family (Ericaceae) such as blueberry (Vaccinium spp.), blueberry blackberry ( Vaccinium spp.), etc., madder family (Rubiaceae) such as coffee (Coffea spp.), etc., Lamiaceae such as lemon balm (Melissa officinalis), mint (Mentha spp.), basil (Ocimum basilicum), shiso (Perilla frutescens var. crispa), perilla (Perilla frutescens var. frutescens), common sage (Salvia officinalis), thyme (Thymus spp.), etc., sesame family (Pedaliaceae) such as sesame (Sesamum indicum), etc., Oleaceae such as olive (Olea europaea), etc., family of Convolvulaceae (Convolvulaceae) such as sweet potato (Ipomoea b atatas), etc., Solanaceae such as tomato (Solanum lycopersicum), eggplant (Solanum melongena), potato (Solanum tuberosum), chili pepper (Capsicum annuum), pepper (Capsicum annuum var. 'grossum'), tobacco (Nicotiana tabacum), etc., Seri family (Apiaceae) such as celery (Apium graveolens var. dulce), coriander (Coriandrum sativum), wild Japanese parsley (Cryptotaenia Canadensis subsp. japonica), carrot (Daucus carota subsp. sativus), parsley (Petroselium crispum), Italian parsley (Petroselinum neapolitanum), etc., Araliaceae such as Udo (Aralia cordata), Aralia elata, etc., Asteracea and thistle (Carduoideae) subfamily such as artichoke (Cynara scolymus), etc., Asteraceae subfamily of dandelion (Asteraceae) such as chicory (Cichorium intybus), lettuce (Lactuca sativa), etc., Asteraceae subfamily Chrysanthemum (Asteraceae) such as florist chrysanthemum ( Dendranthema grandiflorum), chrysanthemum coronaria (Glebionis coronaria), sunflower (Helianthus annuus), fuki (Petasites japonicus), burdock (Arctium lappa), etc.
[00266] In addition, the "plant" in this report includes plants having resistance to HPPD inhibitors such as isoxaflutole, etc., ALS inhibitors such as imazethapyr, thifenenxofreon-methyl, etc., EPSP synthetase inhibitors such as glyphosate, etc. ., glutamine synthetase inhibitors such as glufosinate, etc., acetyl-CoA carboxylase inhibitors such as sethoxydim, PPO inhibitors such as flumioxazin, etc., or herbicides such as bromoxynil, dicamba and 2,4-D, conferred by a classical breeding method or by genetic recombination technology.
Examples of "agricultural/horticultural plants" having such resistance imparted by a classical breeding method are canola, wheat, sunflower, rice and corn which are resistant to imidazolinone-type ALS-inhibiting herbicides such as imazethapyr, etc., and they are already commercially available under the trade name "Clearfield" (trademark).
[00268] Similarly, there is soybean having resistance to ALS-inhibiting ALS-type ALS-inhibiting herbicides such as thifenenxophreon-methyl, conferred by a classical breeding method, which is already commercially available under the trade name "STS soybean". Similarly, SR corn, etc. are available as examples of agricultural/horticultural plants having resistance to acetyl CoA carboxylase inhibitors such as trione oxime type herbicides, aryloxy phenoxypropionic acid, imparted by a classical breeding method. Agricultural/horticultural plants having conferred resistance to acetyl CoA carboxylase inhibitors are disclosed, for example, in Proceedings of the National Academy of Sciences of the United States of America (Proc. Natl. Acad. Sci. USA), Vol. 87, p. . 7175-7179 (1990). Furthermore, mutant acetyl CoA carboxylase resistant to an acetyl CoA carboxylase inhibitor is reported in Weed Science, Vol. 53, p. 728-746 (2005), etc., and by introducing a mutant acetyl CoA carboxylase gene into a plant by a genetic recombination technique, or by introducing a mutation to confer resistance into a cultured acetyl CoA carboxylase, it is possible to produce a plant that is resistant to acetyl CoA carboxylase inhibitors. Furthermore, as represented by chimeric plasticine technology (Gura T. 1999. Repairing the Genome's Spelling Mistakes. Science 285: 316-318), a nucleic acid introducing base substitution mutation is introduced into plant cells to induce a substitution mutation site-specific amino acid in the crop gene (target of acetyl-CoA carboxylase/herbicide), so that it is possible to produce a plant that is resistant to acetyl-CoA carboxylase/herbicide inhibitors.
[00269] Examples of agricultural/horticultural plants having resistance conferred by genetic recombination technology include glyphosate resistant corn, soybean, cotton, canola and sugar beet varieties, and they are already commercially available under the trade names "Roundup Ready" (brand name trademark), "AgrisureGT" (trademark), etc. Similarly, there are varieties of corn, soybeans, cotton and canola having glufosinate resistance conferred by genetic recombination technology, and they are already commercially available under the trade name "LibertyLink" (trademark), etc. Similarly, cotton having bromoxynil resistance imparted by genetic engineering technology is already commercially available under the trade name "BXN".
[00270] The "agricultural/horticultural plants" above include plants that are now able to synthesize known selective toxins, for example, in the genus Bacillus, using a technique of genetic manipulation.
[00271] Insecticidal toxins to be expressed in such genetically modified plants may be, for example, an insecticidal parotein derived from Bacillus cereus or Bacillus popilliae; δ-endotoxin such as Cry1Ab, Cry1Ac, Cry1F, Cry1Fa2, Cry2Ab, Cry3A, Cry3Bb1 or Cry9C derived from Bacillus thuringiensis, or an insecticidal protein such as VIP1, VIP2, VIP3 or VIP3A; a nematode-derived insecticidal protein; a scorpion toxin, a spider toxin, a bee toxin, or an animal produced toxin, such as an insect-specific neurotoxin; a filamentous fungus toxin; vegetable lectin; agglutinin; a trypsin inhibitor, a serine protease inhibitor, patatin, cystatin, a protease inhibitor such as a papain inhibitor; a ribosome inactivating protein (RIP) such as lysine, corn RIP, abrin, saporin, briodin, etc.; a steroid metabolism enzyme such as 3-hydroxy steroid oxidase, ecdysteroid-UDP-glucosyltransferase, cholesterol oxidase, etc.; an ecdysone inhibitor; HMG-CoA reductase; an ion channel inhibitor such as a sodium channel inhibitor, a calcium channel inhibitor, etc.; juvenile hormone esterase; diuretic hormone receptor; stilbene synthase; bibenzyl synthase; chitinase; glucanase; etc.
[00272] In addition, the toxins to be expressed in genetically modified plants also include hybrid toxins, partially deficient toxins and modified δ-endotoxin protein toxins, such as Cry1Ab, Cry1Ac, Cry1F, Cry1Fa2, Cry2Ab, Cry3A, Cry3Bb1 or Cry9C, or an insecticidal protein such as VIP1, VIP2, VIP3 or VIP3A. Hybrid toxins are produced by a new combination of different domains of these proteins using recombinant techniques. As a partially deficient toxin, Cry1Ab is known to lack a portion of the amino acid sequence. In the modified toxin, one or more amino acids from a naturally occurring toxin are replaced.
Examples of such toxins and recombinant plants capable of synthesizing such toxins are disclosed, for example, in Patent documents such as EP-A-0374753, WO93/07278, WO95/34656, EP-A-0427529, EP-A- 451878, WO03/052073. The toxins contained in these genetically modified plants will give the plants resistance, in particular, against pests of the order Coleoptera, pests of the order Diptera or pests of the order Lepidoptera.
[00274] Furthermore, genetically modified plants that comprise one or more genes resistant to insecticide pests, and express one or several toxins, are already known, and some of them are commercially available. Examples of such genetically engineered plants can be, for example, YieldGard <trademark> (a corn variety expressing the Cry1Ab toxin), YieldGard Rootworm <trademark> (a corn variety expressing the Cry3Bb1 toxin), YieldGard Plus <trademark > (a variety of corn expressing the toxins Cry1Ab and Cry3Bb1), Herculex I <trademark> (a variety of corn expressing phosphinothricin N-acetyl transferase (PAT) to confer resistance to the toxin Cry1Fa2 and glufosinate), NuCOTN33B <trademark> ( a cotton variety expressing the Cry1Ac toxin), Bollgard I <trademark> (a cotton variety expressing the Cry1Ac toxin), Bollgard II <trademark> (a cotton variety expressing the Cry1Ac and Cry2Ab toxins), VIPCOT < trademark> (a cotton variety expressing the VIP toxin), NewLeaf <trademark> (a potato variety expressing the Cry3A toxin), NatureGuard Agrisure GT Advantage (NatureGard <marc a registered> Agrisure <trademark> GT Advantage) (trace resistant to GA21 glyphosate), Agrisure CB Advantage (Agrisure <trademark> CB Advantage) (trace of corn borer (CB) Bt11), Protecta <trademark>, etc. .
[00275] The plants mentioned above include those that are capable of generating antipathogenic substances having selective actions, conferred by the use of genetic recombination techniques.
[00276] Such anti-pathogenic substances can be, for example, PR proteins (PRPs, described in EP-A-0392225); ion channel inhibitors such as sodium channel inhibitors, calcium channel inhibitors (KP1, KP4, KP6 toxins produced by viruses, etc. are known), etc.; stilbene synthase; bibenzyl synthase; chitinase; glucanase; substances, etc. produced by microorganisms, such as peptide antibiotics, antibiotics having a heterocyclic ring, protein factors related to plant disease resistance (so-called plant disease resistance genes, described in WO03/000906); etc. Such anti-pathogenic substances and plants genetically manipulated to produce them are disclosed, for example, in EP-A-0392225, WO95/33818, EP-A-0353191, etc.
[00277] The plants mentioned above also include plants having useful traits such as traits to improve oily ingredients or to increase the amino acid content, imparted using genetic recombination technology. As an example, VISTIVE <trademark> (low linolenic soybean having reduced linolenic content) or high lysine corn (high oil content) (corn having an increased lysine or oil content) may be mentioned.
[00278] In addition, with respect to the herbicide traits or classical herbicide tolerance genes mentioned above, insecticide pest resistant genes, genes producing antipathogenic substances, and useful traits such as to improve oily ingredients or to increase the content in amino acids, varieties of cuttings plants having a plurality of them combined are also included.
[00279] The pathogen in this report means a micro-organism that is a plant disease pathogen and specifically the following micro-organisms may, for example, be mentioned, but the pathogen is not limited to these.
[00280] Ascomycota fungi, such as Taphrina spp. (e.g. Taphrina deformans, T. pruni, etc.), Pneumocystis spp., Geotrichum spp., Candida spp. (e.g. Candida albicans, C. sorbosa, etc.), Pichia spp. (for example, Pichia kluyveri, etc.), Capnodium spp., Fumago spp., Hypocapnodium spp., Cercospora spp. (eg Cercospora apii, C. asparagi, C. beticola, C. capsici, C. carotae, C. kaki, C. kikuchii, C. zonata, etc.), Cercosporidium spp., Cladosporium spp. (for example Cladosporium colocasiae, C. cucumerinum, C. variabile, etc.), Davidiella spp., Didymosporium spp., Heterosporium spp. (for example, Heterosporium allii, etc.), Mycosphaerella spp. (for example, Mycosphaerella arachidis, M. berkeleyi, M. cerasella, M. fijiensis, M. fragariae, M. graminicola, M. nawae, M. pinodes, M. pomi, M. zingiberis, etc.), Mycovellosiella, etc.), Mycovellosiella spp. (for example, Mycovellosiella fulva, M. nattrassii, etc.), Paracercospora spp. (for example, Paracercospora egenula, etc.), Phaeoisariopsis spp., Phaeoramularia spp., Pseudocercospora spp. (for example, Pseudocercospora abelmoschi, P. fuligena, P. vitis, etc.), Pseudocercosporella spp. (for example, Pseudocercosporella capsellae, etc.), Ramichloridium spp., Ramularia spp., Septogloeum spp., Septoria spp. (for example, Septoria albopunctata, S. apiicola, S. chrysanthemella, S. helianthi, S. obesa, etc.), Sphaerulina spp., Aureobasidium spp., Kabatiella spp., Plowrightia spp., Stigmina spp., Elsinoe. (e.g. Elsinoe ampelina, E. araliae, E. fawcettii, etc.), Sphaceloma spp. (for example, Sphaceloma caricae, etc.), Ascochyta spp. (eg Ascochyta pisi, etc.), Corynespora spp. (for example, Corynespora cassiicola, etc.), Leptosphaeria spp. (for example, Leptosphaeria coniothyrium, L. maculans, etc.), Saccharicola spp., Phaeosphaeria spp. (e.g. Phaeosphaeria nodorum, etc.), Ophiosphaerella spp., Setophoma spp., Helminthosporium spp., Alternaria spp. (eg Alternaria alternata, A. brassicae, A. brassicicola, A. citri, A. dauci, A. helianthi, A. japonica, A. kikuchiana, A. mali, A. panax, A. porri, A. radicina , A. solani, etc.), Bipolaris spp. (for example Bipolaris sorghicola, etc.), Cochliobolus spp. (eg Cochliobolus heterostrophus, C. lunatus, C. miyabeanus, etc.), Curvularia spp. (e.g. Curvularia geniculata, C. verruculosa, etc.), Drechslera spp., Pleospora spp. (for example, Pleospora herbarum, etc.), Pyrenophora spp. (for example, Pyrenophora graminaa, P. teres, etc.), Setosphaeria spp. (for example, Setosphaeria turcica, etc.), Stemphylium spp. (for example Stemphylium botryosum, S. lycopersici, S. solani, S. vesicarium, etc.), Fusicladium spp., Venturia spp. (e.g. Venturia carpophila, V. Inaequalis, V. nashicola, V. pirina, etc.), Didymella spp. (e.g. Didymella bryoniae, D. fabae, etc.), Hendersonia spp., Phoma spp. (e.g. Phoma erratica var. mikan, P. exigua var. exigua, P. wasabiae, etc.), Pyrenochaeta spp. (eg Pyrenochaeta lycopersici, etc.), Stagonospora spp. (for example, Stagonospora sacchari, etc.), Botryosphaeria spp. (for example Botryosphaeria berengeriana f. sp. piricola, B. dothidea, etc.), Dotiorella spp., Fusicoccum spp., Guignardia spp., Lasiodiplodia spp. (for example, Lasiodiplodia theobromae, etc.), Macrophoma spp., Macrophoma spp., Neofusicoccum spp., Phyllosticta spp. (for example, Phyllosticta zingiberis, etc.), Schizothyrium spp. (e.g. Schizothyrium pomi, etc.), Acrospermum spp., Leptosphaerulina spp., Aspergillus spp., Penicillium spp. (e.g. Penicillium digitatum, P. italicum, P. sclerotigenum, etc.), Microsporum spp., Trichophyton spp. (e.g. Trichophyton mentagrophytes, T. rubrum, etc.), Histoplasma spp., Blumeria spp. (for example Blumeria graminis f. sp. hordei, B. g. f. sp. tritici, etc.), Erysiphe spp. (e.g. Erysiphe betae, E. cichoracearum, E.c. var. cichoracearum, E. heraclei, E. pisi, etc.), Golovinomyces spp. (for example, Golovinomyces cichoracearum var. latisporus, etc.), Leveillula spp. (for example, Leveillula taurica, etc.), Microsphaera spp., Oidium spp. (for example, Oidium neolycopersici, etc.), Phyllactinia spp. (for example, Phyllactinia kakicola, P. mali, P. moricola, etc.), Podosphaera spp. (for example, Podosphaera fusca, P. leucotricha, P. pannosa, P. tridactyla var. tridactyla, P. xanthii, etc.), Sphaerotheca spp. (for example, Sphaerotheca aphanis var. aphanis, S. fuliginea, etc.), Uncinula spp. (for example, Uncinula necator, U.n. var. necator, etc.), Uncinuliella spp. (for example, Uncinuliella simulans var. simulans, U.s. var. tandae, etc.), Blumeriella spp. (for example Blumeriella jaapii, etc.), Cylindrosporium spp., Diplocarpon spp. (for example, Diplocarpon mali, D. mespili, D. rosae, etc.), Gloeosporium spp. (e.g. Gloeosporium minus, etc.), Marssonina spp., Tapesia spp. (e.g. Tapesia acuformis, T. yallundae, etc.), Lachnum spp., Scleromitrula spp., Botryotinia spp. (eg Botryotinia fuckeliana, etc.), Botrytis spp. (for example Botrytis allii, B. byssoidea, B. cinerea, B. elliptica, B. fabae, B. squamosa, etc.), Cyborinia spp., Grovesinia spp., Monilia mumecola, Monilinia spp. (for example Monilinia fructicola, M. fructigena, M. laxa, M. mali, M. vaccinii-corymbosi, etc.), Sclerotinia spp. (for example, Sclerotinia borealis, S. homoeocarpa, S. minor, S. sclerotiorum, etc.), Valdensia spp. (for example, heterodoxa Valdensia, etc.), Claviceps spp. (for example Claviceps sorghi, C. sorghicola, etc.), Epichloe spp., Ephelis japonica, Villosiclava virens, Hypomyces spp. (for example, Hypomyces solani f. sp. mori, H. s.f. sp. pisi, etc.), Trichoderma spp. (eg Trichoderma viride, etc.), Calonectria spp. (e.g. Calonectria ilicicola, etc.), Candelospora spp., Cylindrocarpon spp., Cylindrocladium spp., Fusarium spp. (eg Fusarium arthrosporioides, F. crookwellense, F. culmorum, F. cuneirostrum, F. oxisporum, F. of sp. adzukicola, F. of sp. allii, F. of sp. asparagi, F. of sp. potatoes , F. of sp. cepae, F. of sp. colocasiae, F. of sp. conglutinans, F. of sp. cubense, F. of sp. cucumerinum, F. of sp. fabae, F. of sp. fragariae, F. of sp. lactucae, F. of sp. lagenariae, F. of sp. lycopersici, F. of sp. melongenae, F. of sp. melonis, F. of sp. nelumbinicola, F. of sp. niveum, F. of sp. radicis-lycopersici, F. of sp. raphani, F. of sp. spinaciae, F. sporotrichioides, F. solani, F. sf. sf sp. glycines, F. sf sp. pisi, F. sf sp. Radicicola, F. virguliforme, etc.), Gibberella spp. (for example, Gibberella avenacea, G. baccata, G. fujikuroi, G. zeae, etc.), Haematonecria spp., Nectria spp., Ophionectria spp., Caldariomyces spp., Myrothecium spp., Trichothecium spp., Trichothecium spp. spp. (for example, Verticillium albo-atrum, V. dahliae, V. longisporum, etc.), Ceratocystis spp. (for example, Ceratocystis ficicola, C. fimbriata, etc.), Thielaviopsis spp. (e.g. Thielaviopsis basicola, etc.), Adisciso spp., Monochaetia spp., Pestalotia spp. (for example, Pestalotia eriobotrifolia, etc.), Pestalotiopsis spp. (for example Pestalotiopsis funerea, P. longiseta, P. neglecta, P. theae, etc.), Physalospora spp., Nemania spp., Nodulisporium spp., Rosellinia spp. (eg Rosellinia necatrix, etc.), Monographella spp. (for example, Monographella nivalis, etc.), Ophiostoma spp., Cryphonectria spp. (e.g. Cryphonectria parasitic, etc.), Diaporthe spp. (for example, Diaporthe citri, D. kyushuensis, D. nomurai, D. tanakae, etc.), Diaporthopsis spp., Pho-mopsis spp. (e.g. Phomopsis asparagi, P. fukushii, P. obscurans, P. vexans, etc.), Cryptosporella spp., Discula spp. (for example, Discula theae-sinensis, etc.), Gnomonia spp., Coniella spp., Coryneum spp., Greeneria spp., Melanconis spp., Cytospora spp., Leucostoma spp., Waltz spp. (e.g. Waltz ceratosperma, etc.), Tubakia spp., Monosporascus spp., Clasterosporium spp., Gaeumannomyces spp. (eg Gaeumannomyces graminis, etc.), Magnaporthe spp. (eg Magnaporthe grisea, etc.), Pyricularia spp. (eg Pyricularia zingiberis, etc.), Monilochaetes infuscans, Colletotrichum spp. (eg Colletotrichum acutatum, C. capsici, C. cereale, C. destructivum, C. fragariae, C. lindemuthianum, C. nigrum, C. orbiculare, C. spinaciae, etc.), Glomerella spp. (e.g. Glomerella cingulata, etc.), Khuskia oryzae, Phyllachora spp. (for example, Phyllachora pomigena, etc.), Ellisembia spp., Briosia spp., Cephalosporium spp. (e.g. Cephalosporium graminaum, etc.), Epicoccum spp., Gloeocercospora sorghi, Mycocentrospora spp., Peltaster spp. (for example, Peltaster fructicola, etc.), Phaeocytostroma spp., Phialophora spp. (e.g. Phialophora gregata, etc.), Pseudophloeosporella dioscoreae, Pseudoseptoria spp., Rhynchosporium spp. (e.g., Rhynchosporium sealis, etc.), Sarocladium spp., Coleophoma spp., Helicoceras oryzae, etc.
[00281] Basidiomycota fungi, such as Septobasidium spp. (for example, Septobasidium bogoriense, S. tanakae, etc.), Helicobasidium spp. (eg Helicobasidium longisporum, etc.), Coleosporium spp. (e.g. Coleosporium plectranthi, etc.), Cronartium spp., Phakopsora spp. (for example, Phakopsora artemisiae, P. nishidana, P. pachyrhizi, etc.), Physopella spp. (for example, Physopella ampelopsidis, etc.), Kuehneola spp. (e.g. Kuehneola japonica, etc.), Phragmidium spp. (for example, Phragmidium fusiforme, P. mucronatum, P. rosae-multiflorae, etc.), Gymnosporangium spp. (for example Gymnosporangium asiaticum, G. yamadae, etc.), Puccinia spp. (for example, Puccinia allii, P. brachypodii var. poae-nemoralis, P. coronata, P.c. var. coronata, P. cynodontis, P. graminis, P.g. subsp. graminicola, P.c. hordei, P. horiana, P. kuehnii, P. melanocephala, P. recondita, P. striiformis var. striiformis, P. tanaceti var. tanaceti, P. tokyensis, P. zoysiae, etc.), Uromyces spp. (for example, Uromyces phaseoli var. azukicola, U.p. var. phaseoli, Uromyces viciae-fabae var. viciae-fabae, etc.), Naohidemyces vaccinii, Nyssopsora spp., Leucotelium spp., Tranzschelia spp. (for example, Tranzschelia discolor, etc.), Aecidium spp., mangraospora spp. (e.g., mangraospora smilacis, etc.), Uredo spp., Sphacelotheca spp., Urocystis spp., Sporisorium spp. (for example, Sporisorium scitaminaum, etc.), Ustilago spp. (e.g. Ustilago maydis, U. nuda, etc.), Entyloma spp., Exobasidium spp. (e.g. Exobasidium reticulatum, E. vexans, etc.), Microstroma spp., Tilletia spp. (e.g. Tilletia caries, T. controversial, T. laevis, etc.), Itersonilia spp. (e.g. Itersonilia perplexans, etc.), Cryptococcus spp., Bovista spp. (eg Bovista dermoxantha, etc.), Lycoperdon spp. (eg Lycoperdon curtisii, L. perlatum, etc.), Conocybe spp. (eg Conocybe apala, etc.), Marasmius spp. (e.g., Marasmius oreades, etc.), Armillaria spp., Helotium spp., Lepiña spp. (eg, Lepista subnuda, etc.), Sclerotium spp. (for example, Sclerotium cepivorum, etc.), Typhula spp. (for example Typhula incarnata, T. ishikariensis var. ishikariensis, etc.), Athelia spp. (for example, Athelia rolfsii, etc.), Ceratobasidium spp. (e.g. Ceratobasidium cornigerum, etc.), Ceratorhiza spp., Rhizoctonia spp. (for example, Rhizoctonia solani, etc.), Thanatephorus spp. (for example, Thanatephorus cucumeris, etc.), Laetisaria spp., Waitea spp., Fomitiporia spp., Ganoderma spp., Chondrostereum purpureum, Phanerochaete spp., etc.
[00282] Chitridiomycota fungi, such as Olpidium spp., etc.
[00283] Mangraocladiomycota fungi, such as Physoderma spp., etc.
Mucoromycotina fungi such as Choanephora spp., Choanephoroidea cucurbitae, Mucor spp. (eg Mucor fragilis, etc.), Rhizopus spp. (for example, Rhizopus arrhizus, R. chinensis, R. oryzae, R. stolonifer var. stolonifer, etc.), etc.
[00285] Cercozoa protists, such as Plasmodiophora spp. (e.g. Plasmodiophora brassicae, etc.), Spongospora subterranea f. sp. underground, etc.
[00286] Oomycetes Heterokontophyta, such as Aphanomyces spp. (for example, Aphanomyces cochlioides, A. raphani, etc.), Albugo spp. (eg Albugo macrospora, A. wasabiae, etc.), Bremia spp. (for example, Bremia lactucae, etc.), Hyaloperonospora spp., Peronosclerospora spp., Peronospora spp. (for example, Peronospora alliariae-wasabi, P. chrysanthemi-coronarii, P. destructor, P. farinosa f. sp. spinaciae, P. manshurica, P. parasitica, P. sparsa, etc.), Plasmopara spp. (eg Plasmopara halstedii, P. nivea, P. viticola, etc.), Pseudoperonospora spp. (for example, Pseudoperonospora cubensis, etc.), Sclerophthora spp., Phytophthora spp. (eg Phytophthora cactorum, P. capsici, P. citricola, P. citrophthora, P. cryptogea, P. fragariae, P. infestans, P. melonis, P. nicotianae, P. palmivora, P. porri, P. soybeane, P. syringae, P. vignae f. sp. adzukicola, etc.), Pythium spp. (for example, Pythium afertile, P. aphanidermatum, P. apleroticum, P. aristosporum, P. arrhenomanes, P. buismaniae, P. debaryanum, P. graminicola, P. horinouchiense, P. irregulare, P. iwayamaimai , P. myriotylum, P. okanoganense, P. paddicum, P. paroecandrum, P. periplocum, P. spinosum, P. sulcatum, P. sylvaticum, P. ultimum var. ultimum, P. vanterpoolii, P. vexans, P. volutum, etc.), etc.
[00287] Gram-positive Actinobacteria fungi, such as Clavibacter spp. (for example Clavibacter michiganensis subsp. michiganensis, etc.), Curtobacterium spp., Leifsonia spp. (e.g. Leifsonia xyli subsp. xyli, etc.), Streptomyces spp. (e.g., Streptomyces ipomoeae, etc.), etc.
[00288] Gram-positive Firmicutes fungi, such as Clostridium sp., etc.
[00289] Tenericutes gram-positive fungi, such as Phytoplas ma, etc.
Proteobacteria gram-negative fungi, such as Rhizobium spp. (for example, Rhizobium radiobacter, etc.), Acetobacter spp., Burkholderia spp. (for example Burkholderia andropogonis, B. cepacia, B. gladioli, B. glumae, B. plantarii, etc.), Acidovorax spp. (for example, Acidovorax avenae subsp. avenae, A.a. subsp. citrulli, A. konjaci, etc.), Herbaspirillum spp., Ralstonia spp. (for example, Ralstonia solanacearum, etc.), Xanthomonas spp. (for example, Xanthomonas albilineans, X. arboricola pv. pruni, X. axonopodis pv. vitians, X. campestris pv. campestris, X. c. pv. cucurbitae, X. c. pv. glycines, X. c. pv. mangiferaeindicae, X.c.pv.nigromaculans, X.c.pv.vesicatoria, X.citri subsp.citri, X.oryzae pv.oryzae, etc.), Pseudomonas spp. (for example, Pseudomonas cichorii, P. fluorescens, P. marginalis, P. m. pv. marginalis, P. savastanoi pv. glycinea, P. syringae, P. s. pv. actinidiae, P. s. pv. eriobotryae, P.s.pv.helianthi, P.s.pv.lachrymans, P.s.pv.maculicola, P.s.pv.mori, P.s.pv.morsprunorum, P.s.pv.spi- naciae, P.s.pv.syringae, P.s.pv.theae, P.viridiflava, etc.), Rhizobacter spp., Brenneria spp. (e.g. Brenneria nigrifluens, etc.), Dickeya spp. (for example Dickeya dianthicola, D. zeae, etc.), Erwinia spp. (e.g. Erwinia amylovora, E. rhapontici, etc.), Pantoea spp., Pectobacterium spp. (for example, Pectobacterium atrosepticum, P. carotovorum, P. wasabiae, etc.), etc.
[00291] As specific examples of plant diseases caused by infection and proliferation of these pathogens, the following plant diseases can, for example, be mentioned, but plant diseases are not limited to these.
[00292] Leaf crunch (Taphrina deformans), plum leprosy (Taphrina pruni), leaf spot (Cercospora asparagi), leaf spot caused by Cercospora (Cercospora beticola), leaf spot caused by Frogeye (Cercospora capsici), spot leaf spot (Cercospora kaki), purple spot (Cercospora kikuchii), brown leaf spot (Mycosphaerella arachidis), leaf spot caused by Cylindrosporium (Mycosphaerella cerasella, Blumeriella jaapii), black sigatoka (Mycosphaerella fijiensis), speckled leaf pustule (Mycosphaerella graminicola), circular leaf spot (Mycosphaerella nawae), Mycosphaerella blight (Mycosphaerella pinodes), leaf spot (Mycosphaerella zingiberis), leaf mold (Mycovellosiella fulva), leaf mold (Mycovellosiella nattrasss) , leaf mold caused by Cercospora (Pseudocercospora fuligena), leaf spot caused by Isariopsis (Pseudocercospora vitis), leaf spot (Pse udocercosporella capsellae), leaf spot (Septoria chrysanthemella), leaf blight (Septoria obesa), anthracnose (Elsinoe ampelina), anthracnose ("spot anthracnose") (Elsinoe arali ae), scab (Elsinoe fawcettii), scabies leaves (Ascochyta pisi), leaf spot caused by Corynespora (Corynespora cassiicola), stem cancers (Leptosphaeria coniothyrium), gluma pustule (Leptosphaeria nodorum), leaf spot (Alternaria alternata), leaf spot caused by Alternaria ( Alternaria brassicae), leaf blight (Alternaria dauci), black spot (Alternaria kikuchiana), pustule caused by Alternaria (Alternaria mali), leaf blight caused by Alternaria (Alternaria porri), target spot (Bipolaris sorghicola) , southern leaf blight (Cochliobolus heterostrophus), brown spot (Cochliobolus miyabeanus), edge blight (Pleospora herbarum), streaks (Pyrenophora graminaa), reticular spot (Pyrenophora teres), blight leaf blight (Setosphaeria turcica), northern leaf blight (Setosphaeria turcica), leaf blight (Stemphylium botryosum), scab (Venturia carpophila), scab (Venturia Inaequalis), scab (Venturia nashicola), gummy stem blight ( Didymella bryoniae), leaf spot (Phoma exigua var. exigua), stripes (Phoma wasabiae), ring rot (Botryosphaeria berengeriana f. sp. piricola), soft rot (Botryosphaeria dothidea, Lasiodiplodia theobromae, Diaporthe sp.), common green mold (Penicillium digitatum), blue mold (Penicillium italitum) ), powdery downy mildew (Blumeria graminis f. sp. hordei), powdery downy mildew (Blumeria graminis f. sp. tritici), powdery mildew (Erysiphe betae, Leveillula taurica, Oidium sp., Podosphaera xanthiearryi, Levecholdio mildiole) taurica, Sphaerotheca fuliginea), powdery downy mildew (Erysiphe heraclei), powdery mildew (Erysiphe pisi), powdery mildew (Leveillula taurica, Oidium neolycopersici, Oidium pulverulent sp.), powdery mildew (Oidium pulverudium sp.), powdery downy mildew (Leveillula taurica, Oidium neolycopersici, Oidium pulverudium sp.), powdery mildew (Leveillula taurica, Oidium Podosphaera xanthii), powdery mildew (Oidium sp.), powdery mildew (Phyllactinia kakicola), powdery mildew (Podosphaera fusca), powdery mildew (Podosphaera leucotricha), powdery mildew (Podosph aera pannosa, Uncinuliella simulans var. simulans, U. s. var. tandae), powdery mildew (Podosphaera xanthii), powdery mildew (Sphaerotheca aphanis var. aphanis), powdery mildew (Sphaerotheca fuliginea), powdery mildew (Uncinula necator, U. n. var. black (Diplocarpon rosae), collar rot caused by gray mold (Botrytis allii), gray mold, blight caused by Botrytis (Botrytis cinerea), blight of leaves (Botrytis cinerea, B. byssoidea, B. squamosa) ), chocolate stain (Botrytis cinerea, B. elliptica, B. fabae), brown rot (Monilinia fructicola, M. fructigena, M. laxa), blossom blight (Monilinia mali), dollar spot (Sclerotinia homoeocarpa ), Cottony rot, Sclerotinia rot, stem rot (Sclerotinia sclerotiorum), false rust (Villosiclava virens), root necrosis (Calonectria ilicicola), Fusarium blight (Fusarium crookwellense, F. culmorum, Gibbe-rella). avenacea, G. zeae, Monograph ella nivalis), blight caused by Fusarium (Fusarium culmorum, Gibberella avenacea, G. zeae), dry rot (Fusarium oxisporum, F. solani f. sp. radicicola), brown rot (Fusarium oxisporum, F. solani f. sp. pisi, F. sf sp. radicicola), wilt caused by Fusarium (Fusarium oxisporum f. sp. adzukicola), basal rot caused by Fusarium (Fusarium oxisporum f. sp. allii, F. solani f. sp. radicicola), stem rot (Fusarium oxisporum f. sp. potatoes, F. solani), dry rot (Fusarium oxisporum f. sp. colocasiae), yellowing (Fusarium oxisporum f. sp. conglutinans), Panama disease (Fusarium oxisporum f. sp. cubense), wilt caused by Fusarium (Fusarium oxisporum f. sp. fragariae), root rot (Fusarium oxisporum f. sp. lactucae) ), wilt caused by Fusarium (Fusarium oxisporum f. sp. lagenariae, F. of sp. niveum), wilt caused by Fusarium (Fusarium oxisporum f. sp. lycopersici), wilt caused by Fusarium (Fusarium oxisporum f. sp. melonis), yellowing (Fusarium oxisporum f. sp. raphani), wilting caused by Fusarium (Fusarium oxisporum f. sp. spinaciae), synd rome of the sudden death of soybean (Fusarium solani f. sp. glycines, Fusarium virguliforme), bakanae disease (Gibberella fujikuroi), black spot caused by Verticillium (Verticillium albo-atrum, V. dahliae), wilt caused by Verticillium (Verticillium dahliae), cancer caused by Ceratocystis (Ceratocystis ficicola ), black rot (Ceratocystis fimbriata), gray blight (Pestalotiopsis longiseta, P. theae), cancer caused by Endothia (Cryphonectria parasitica), melanosis (Diaporthe citri), stem blight (Phomopsis asparagi), cancer caused by Phomopsis (Phomopsis fukushii), brown spot (Phomopsis vexans), anthracnose (Discula theae-sinensis), Waltz (Waltz ceratosperma), mangra (Magnaporthe grisea), crown rot (Colletotrichum acutatum, C. fragari-sinensis) cancer. ae, Glomerella cingulata), bitter rot (Colletotrichum acutatum, Glomerella cingulata), anthracnose (Colletotrichum acutatum, Glomerella cingulata), anthracnose (Colletotrichum acutatum), flower rot (Colletotrichum acutatum, Glomerella cingulata), anthracnose (Colletotrichum acutatum), anthracnose (Colletotrichum lindemuthianum), anthracnose (Colletotrichum orbiculare), anthracnose (Glomerella cingulata), anthracnose (Glomerella cingulata), anthracnose (Glomerella- podri- ma), anthracnose (Glomerella cingulata) stem (Phialophora gregata), leaf spot (Pseudophloeosporella dioscoreae), scald (Rhynchosporium se- salis),
blight (Phakopsora nishidana), blight (Phakopsora pachyrhizi), blight (Kuehneola japonica, Phragmidium fusiforme, P. mucronatum, P. rosae-multiflorae), blight (Gymnosporangium asia-ticum), blight (Gymnosporangium) Puccinia allii), rust (Puccinia horiana), brown rust (Puccinia recondita), rust (Puccinia tanaceti var. tanaceti), rust (Uromyces viciae-fabae var. viciae-fabae), charcoal (Sporisorium scitaminaum), charcoal (Ustilago maydis), bare charcoal (Ustilago nuda), reticular bullous blight (Exobasidium reticulatum), bullous blight (Exobasidium vexans), stem rot, southern blight (Athelia rolfsii), root and stem rot (Ceratobasidium cornigerum , Rhizoctonia solani), "ginger crest blight" (Rhizoctonia solani), tumbling (Rhizoctonia solani), tumbling (Rhizoctonia solani), base rot (Rhizoctonia solani), brown spot, large spot (Rhizoctonia solani), aphid of the sheath ( Thanatephorus cucumeri s), leaf blight caused by root rot (Thanatephorus cucumeris),
[00294] Rhizopus rot (Rhizopus stolonifer var. stolonifer),
[00295] clubroot (Plasmodiophora brassicae),
Root rot caused by Aphanomyces (Aphanomyces cochlioides), white rust (Albugo macrospora), downy mildew (Bremia lactucae), downy mildew (Peronospora chrysanthemi- coronarii), downy mildew (Peronospora destructor) . sp. spinaciae), downy mildew (Peronospora manshurica), downy mildew (Peronospora parasitica), downy mildew (Peronospora sparsa), downy mildew (Plasmopara halstedii), downy mildew (Plasmopara-nivea), mopara viticola), downy mildew (Pseudoperonospora cubensis), root rot caused by Phytophthora (Phytophthora cactorum), brown rot (Phytophthora capsici), rot caused by Phytophthora (Phytophthora capsici), rot caused by Phytophthora capsici Phytophthora (Phytophthora cryptogea), late blight (Phytophthora infestans), white powdery rot (Phytophthora palmivora), blight leaves (Phytophthora porri), root and stem rot caused by Phytophthora (Phytophthora soybeane), stem rot caused by Phytophthora (Phytophthora vignae f. sp. adzukicola), tumbling (Pythium aphanidermatum, P. myriotylum, P. paroecandrum, P. ultimum var. ultimum), root rot (Pythium aristosporum), brown root rot (Pythium arrhenomanes, P. graminicola), tumbling (Pythium buismania, buismania). P. myriotylum), root rot (Pythium myriotylum), root rot (Pythium myriotylum, P. ultimum var. ultimum), brown spotted root rot (Pythium sulcatum),
[00297] bacterial cancer (Clavibacter michiganensis subsp. michiganensis), scabies (Streptomyces spp.),
Crown gall (Rhizobium radiobacter), bacterial streaks (Burkholderia andropogonis), soft rot (Burkholderia cepacia, Pseudomonas marginalis pv. marginalis, Erwinia rhapontici), bacterial grain rot (Burkholderia gladioli, B. glumae), pustula bacterial blight of fruits (Acidovorax avenae subsp. citrulli), bacterial blight of leaves (Acidovorax konjaci), bacterial wilt (Ralstonia solanacearum), bacterial bullet hole (Xanthomonas arboricola pv. pruni, Pseudomonas syria syringae, pv. ), bacterial leaf spot (Xanthomonas arboricola pv. pruni), bacterial spot (Xanthomonas axonopodis pv. vitians), black rot (Xanthomonas campestris pv. campestris), bacterial pustule (Xanthomonas campestris pv. glycines), bacterial spot (Xanthomonas) campestris pv. nigromaculans), bacterial spot (Xanthomonas campestris pv. vesicatoria), Citrus canker (Xanthomonas citri subsp. citri), garlic spring rot (Pseudomonas cichorii) , P. marginalis pv. marginalis, Erwinia sp.), bacterial rot (Pseudomonas cichorii, P. marginalis pv. marginalis, P. viridiflava), bacterial blight (Pseudomonas marginalis pv. marginalis, P. syringae pv. syringae, P. viridiflava), bacterial cancer (Pseudomonas syringae pv. actinidiae), cancer (Pseudomonas syringae pv. eriobotryae), bacterial spot (Pseudomonas syringae pv. lachrymans), bacterial black spot (Pseudomonas syringae pv. maculicola), bacterial cancer (Pseudomonas syringae pv. ), bacterial blight of shoots (Pseudomonas syringae pv. theae), bacterial soft rot (Dickeya sp., Pectobacterium carotovorum), fire blight (Erwinia amylovora), soft rot (Pectobacterium carotovorum), bacterial soft rot ( Pectobacterium carotovorum).
[00299] The "useful insects" in this report means useful insects in the sense that the products they produce can be used for human life, or they can contribute to the efficiency of agricultural operations as they can be used for pollination of fruits or vegetables. Specifically, for example, Japanese honey bee (Apis cerana japonica), western honey bee (Apis mellifera), manganbaba (Bombus consobrinus wittenburgi, B. diversus diversus, B. hypocrita hypocrita, B. ignitus, B. terrestris) , horned bee (Osmia cornifrons) and silkworm (Bombyx mori) may be mentioned, but useful insects are not limited to these.
[00300] The "natural enemies" in this report means organisms that, through predation and parasitism, will exterminate or inhibit the growth of a specific species of organism, especially a specific species of organism that harms crops. Specifically, the following organisms may, for example, be mentioned, but specific examples of natural enemies are not limited to these.
[00301] Parasitic wasps belonging to the Braconidae family such as Dacnusa sasakawai, Dacnusa sibirica, Aphidius colemani, Apanteles glomeratus, etc., Aphelinidae such as Aphelinus albipodus, Aphelinus asychis, Aphelinus gossypiicerus form, Aphelinus mavaricus form Aphelinus eremicus, Eretmocerus mundus, etc., and Eulophidae such as Chrysocharis pentheus, Neochrysocharis formosa, Diglyphus isaea, Hemiptarsenus varicornis), etc.; aphidophagous cecidomids (Aphidoletes aphidimyza); seven-spot ladybird (Coccinella septempunctata); Asian ladybird (Harmonia axyridis); predatory beetle (Propilea japonica); Anthocorid predatory stink bugs belonging to the Anthocoridae family such as Orius minutus, Orius nagaii, Orius sauteri, pirate stink bug (Orius strigicollis); predatory mirids belonging to the Miridae family such as Pilophorus typicus, Nesidiocoris tenuis, etc.; predatory thripses belonging to the Aeolothripidae family such as Franklinothrips vespiformis; chrysopids belonging to the Chrysopidae family such as Dichochrysa formosanus, Chrysoperla nipponensis, etc.; predatory mites belonging to the Phytoseiidae family such as Neoseiulus californicus, Amblyseius cucumeris, Amblyseius degenerans, Amblyseius swirskii, Phytoseiulus persimilis, etc.; wolf spider (Pardosa pseudoannulata); crab spider (Misumenops tricuspidatus).
[00302] The composition of the present invention can effectively control many plant diseases that occur in vascular plants (Tracheophyta) such as Pinales, magnoliids, monocots, eudicots, etc.
The pathogens can be, for example, Ascomycota fungi, Basidiomycota fungi, Chitridiomycota fungi, mangraocladiomycota fungi, Mucoromycotina fungi, Cercozoa protists, Heterokontophyta oomycetes, Gram-positive fungi Actinobacteria, Gram-positive fungi and Tenericuts Gram-negative fungi Proteobacteria, etc.
[00304] The composition of the present invention exhibits excellent control effects at a low concentration, especially against plant pathogenic fungi belonging to the family Ascomycota and Basidiomycota, among such pathogens.
[00305] The composition of the present invention can be used in the form of a mixture obtained by simple mixing of active ingredient A selected from oxime-substituted amide compounds of formula (I) and active ingredient B selected from known fungicidal or bactericidal active compounds , but normally in practice they can be used formulated as an optional formulation such as a soluble concentrate, an emulsifiable concentrate, a wettable powder, a water soluble powder, a water dispersible granule, a water soluble granule, a suspension concentrate, an emulsion concentrate, a suspoemulsion, a microemulsion, a dust, a granule, a tablet or an emulsifiable gel, by mixing with a suitable solid carrier or liquid carrier, and optionally further by adding surfactants, penetration agents, spreading agents, thickeners, antifreeze agents, binders, anti-caking agents, disintegrants, antifoams, preservatives, stabilizers, etc. From the standpoint of less labor and improved safety, the optional formulation above can be presented sealed in a water-soluble capsule or in a water-soluble packaging such as a pouch made of a water-soluble film.
[00306] Solid vehicles can be, for example, natural minerals, such as quartz, calcite, sepiolite, dolomite, chalk, kaolinite, pyrophyllite, sericite, haloysite, meta-haloysite, kibushi clay, frog-eye clay, pottery, zeolite ("zeeklite"), allophan, kaolin, "kira", talc, bentonite, activated clay, acid clay, pumice, attapulgite, zeolite, diatomaceous earth, etc.; products baked from natural minerals, such as calcined clay, perlite, Shirasu balloon, vermiculite, Ata Pal gas clay, calcined diatomaceous earth, etc.; inorganic salts such as magnesium carbonate, calcium carbonate, sodium carbonate, sodium hydrogen carbonate, ammonium sulfate, sodium sulfate, magnesium sulfate, diammonium hydrogen phosphate, ammonium dihydrogen phosphate, potassium chloride, etc. .; sugars such as glucose, fructose, sucrose, lactose, etc.; polysaccharides such as starch, powdered cellulose, dextrin, etc.; organic materials such as urea, urea derivatives, benzoic acid, a salt of benzoic acid, etc.; plants such as wood flour, cork dust, corn on the cob, nutshell, tobacco stalks, etc.; fly ash, white coal (eg water-based synthetic silica, anhydrous synthetic silica, water-based synthetic silicate, etc.), a fertilizer; etc.
Liquid carriers can be, for example, aromatic hydrocarbons such as xylene, alkyl (eg C9 or C10) benzene, phenylxylylethane and alkyl (eg C1 or C3) naphthalene, etc.; aliphatic hydrocarbons such as machine oil, normal paraffin, isoparaffin, naphthene, etc.; mixtures of aromatic hydrocarbons and aliphatic hydrocarbons such as kerosene, etc.; alcohols such as ethanol, isopropanol, cyclohexanol, phenoxyethanol, benzyl alcohol, etc.; polyhydric alcohols such as ethylene glycol, propylene glycol, diethylene glycol, hexylene glycol, polyethylene glycol, polypropylene glycol, etc.; ethers, such as propyl cellosolve, butyl cellosolve, phenyl cellosolve, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monopropyl ether, propylene glycol monobutyl ether, propylene glycol monophenyl ether, etc.; ketones such as acetophenone, cyclohexanone, Y-butyrolactone, etc.; esters such as fatty acid methyl esters, succinic acid dialkyl esters, glutamic acid dialkyl esters, adipic acid dialkyl esters, phthalic acid dialkyl esters, etc.; acid amides such as N-alkyl (C1, C8, C12, etc.) pyrrolidone, etc.; oils such as soybean oil, linseed oil, canola oil, coconut oil, cottonseed oil, castor oil, etc.; dimethylsulfoxide, water; etc.
[00308] These solid and liquid vehicles can be used singly or in combination of two or more of them.
[00309] Surfactants can be, for example, nonionic surfactants such as polyoxyethylene alkyl ethers, polyoxyethylene alkyl (mono- or di-)phenyl ethers, polyoxyethylene (mono-, di- or tri-)erythylphenyl ethers, copolymers in polyoxyethylene and polyoxypropylene blocks, polyoxyethylene (mono- or di-) fatty acid esters, sorbitan fatty acid esters, polyoxyethylene and sorbitan fatty acid esters, castor oil ethylene oxide adducts , acetylene glycol, acetylene alcohol, acetylene glycol ethylene oxide adducts, acetylene alcohol ethylene oxide adducts, alkyl glycosides, etc.; anionic surfactants, such as alkyl sulfates, alkylbenzene sulfonates, lignin sulfonates, alkyl sulfosuccinates, naphthalene sulfonates, alkylnaphthalene sulfonates, naphthalenesulfonic acid formalin condensate salts, alkyl naphthalene sulfonic acid formalin condensate salts, alkyl naphthalene sulfonic acid salts, polyoxyethylene alkyl ether sulfuric or phosphoric acid, polyoxyethylene (mono- or di-)alkylphenyl ether sulfate or phosphate ester salts, polyoxyethylene (mono-, di- or tri) styrylphenyl ether sulfuric or phosphoric ester salts , polycarboxylates (for example, polyacrylic acid salts, polymaleic acid salts, a copolymer of maleic acid and olefin, etc.), polystyrene sulfonate, etc.; cationic surfactants such as alkyl amine salts, alkyl quaternary ammonium salts, etc.; amphoteric amino acid-type, betaine-type, etc.; silicone-based surfactants, fluorine-based surfactants; etc.
[00310] The content of such surfactants is not particularly limited, but normally ranges in the range preferably from 0.05 to 20 parts by weight, more preferably from 0.1 to 15 parts by weight, relative to 100 parts by weight of the formulation of the composition of the present invention. These surfactants can be used singly or in combination of two or more of them.
[00311] The application amount of the composition of the present invention may vary depending on the application scenario, application time, application method, cultivated plants, etc., but normally the amount of active ingredient preferably varies from 0.005 to 50 kg, more preferably from 0.01 to 2 kg, per hectare (ha).
[00312] Now, formulation examples using the composition of the present invention will be presented. However, the formulations of the present invention are not limited thereto.
[00313] In the Formulation Examples below, "parts" means parts by weight, and "compound as active ingredient" is a generic term for active ingredient A selected from oxime-substituted amide type compounds of formula (I), and for active ingredient B selected from known fungicidal or bactericidal active compounds. wettable powder
[00314] Others can be, for example, an anti-caking agent, a stabilizing agent, etc. Emulsion Compound as active ingredient Organic solvent Surfactant Water Other
[00315] Others can be, for example, a spreading agent, a stabilizing agent, etc. Suspension Compound as an active ingredient, a thickener, etc. Water-dispersible granules Compound as active ingredient Solid vehicle 0.1 to 90 parts 0 to 98.9 parts Surfactant 1 to 20 parts Others 0 to 10 parts
[00316] Others can be, for example, an antifreeze agent, a thickener, etc. Water-dispersible granules Compound as active ingredient 0.1 to 90 parts Solid vehicle 0 to 98.9 parts Surfactant 1 to 20 parts Others 0 to 10 parts
[00317] Others can be, for example, a binder, a stabilizing agent, etc. Solution Compound as active ingredient Liquid vehicle Other 0.01 to 70 parts 20 to 99.99 parts 0 to 10 parts
[00318] Others can be, for example, an antifreeze agent, a spreading agent, etc. Granules Compound as active ingredient Solid vehicle 0.01 to 80 parts 10 to 99.99 parts Others 0 to 10 parts
[00319] Others can be, for example, a binding agent, a stabilizing agent, etc. Powder Compound as active ingredient Solid vehicle 0.01 to 30 parts 65 to 99.99 parts Others 0 to 5 parts
[00320] Others can be, for example, a displacement prevention agent, a stabilizing agent, etc.
[00321] Now, Formulation Examples will be presented where the composition of the present invention using active ingredients is shown more specifically, but the present invention is not limited thereto.
In the Formulation Examples which follow, "parts" means parts by weight. Formulation Example 1 wettable powder Compound No. 20 10 parts Compound No. H35 10 parts Pyrophyllite 74 parts Sorpol 5039 4 parts (trade name, nonionic and anionic surfactant blend: produced by Toho Chemical Industry Co., Ltd.) CARPLEX # 80D 2 parts (tradename, synthetic hydrous silicic acid: produced by Shionogi & Co., Ltd.)
[00323] The above components are uniformly mixed and pulverized to obtain a wettable powder. Formulation Example 2 Emulsifiable concentrate Compound No. 11 3 parts Compound No. C17 2 parts Xylene 75 parts N-Mechiripiroridon 15 parts Sorpol 2680 15 parts (trade name, nonionic and anionic surfactant blend: produced by Toho Chemical Industry Co., Ltd.)
[00324] The above components are uniformly mixed to obtain an emulsifiable concentrate. Formulation Example 3 Emulsifiable concentrate Compound No. 24 2 parts Compound No. C18 2 parts DBE 36 parts (trade name, a mixture of dimethyl adipate, dimethyl glutarate and dimethyl succinate; produced by INVISTA Co., Ltd.) Isobutyl adipate 30 parts N-methylpyrrolidone 10 parts Soprophor BSU 14 parts (tradename, nonionic surfactant; manufactured by Rhodia (Rhodia) Co., Ltd.) Rhodacal 70BC 6 parts (tradename, anionic surfactant; manufactured by Rhodia Co., Ltd.)
[00325] The above components are uniformly mixed to obtain an emulsifiable concentrate. Formulation Example 4 Emulsifiable Concentrate Compound No. 27 2 parts Compound No. H10 2 parts DBE 11 parts (trade name, a mixture of dimethyl adipate, dimethyl glutarate and dimethyl succinate; produced by INVISTA Inc.) Isobutyl adipate 30 parts N-methylpyrrolidone 5 parts Soprophor BSU 14 parts (trade name, nonionic surfactant; produced by Rhodia Co., Ltd.) Rhodacal 70BC 6 parts (trade name, anionic surfactant; produced by Rhodia Co., Ltd.) Propylene glycol 10 parts Water 20 parts
[00326] The above components are uniformly mixed to obtain an emulsifiable concentrate. Formulation Example 5 suspension concentrate Compound No. 25 15 parts Compound No. H31 10 parts Agrisol S-710 10 parts (trade name, nonionic surfactant; produced by Kao Corporation) Lennox 1000C 0.5 parts (trade name, anionic surfactant : produced by Toho Chemical Industry Co., Ltd.) Xanthan gum 0.2 parts Water 64.3 parts
[00327] The above components are uniformly mixed, followed by wet spraying to obtain a suspension concentrate. Formulation Example 6 Water-dispersible granule Compound No. 4 40 parts Compound No. E04 35 parts High tenor NE-15 5 parts (trade name, anionic surfactant; manufactured by Dai-ichi Kogyo Seiyaku Co., Ltd.) VANILLEX N 10 parts (tradename, anionic surfactant; made by Nippon Paper In-dustries Co., Ltd.) CARPLEX #80D 10 parts (tradename, synthetic hydrous silicic acid; made by Shionogi & Co., Ltd.)
[00328] The above components are uniformly mixed and pulverized, and then, after adding a small amount of water, are stirred and mixed, and granulated in a granulator for extrusion, followed by drying to obtain a granule dispersible in Water. Formulation Example 7 granule Compound No. 8 Compound No. F01 Bentonite Talc
[00329] The above components are uniformly mixed and pulverized, and then, after adding a small amount of water, are stirred and mixed, and granulated in a granulator for extrusion, followed by drying to obtain granules. Formulation Example 8 dust Compound No. 9 2 parts Compound No. D02 1 part CARPLEX #80D 0.5 part (trade name, synthetic hydrous silicic acid; produced by Shionogi & Co., Ltd.) kaolinite 95 parts Di- 1.5 part isopropyl phosphate
[00330] The above components are uniformly mixed and pulverized to obtain a dust.
[00331] In use, the respective formulations above will be diluted 1 to 20,000 times with water, and will be applied so the active ingredient varies from 0.005 to 50 kg per hectare (ha).
[00332] In the present invention, it is possible to formulate and use, as mentioned above, a composition comprising one or more compounds of active ingredient A and one or more compounds selected from group BI to group B-XII of active ingredients B, but it is also It is possible that an agent containing active ingredient A and an agent containing active ingredient B are prepared separately, and these agents are used for treatment or application at the same time or in close temporal proximity, thus making it possible to obtain excellent synergistic control effects . Here, when they are applied in close temporal proximity, it is desirable to carry out the subsequent application after the initially applied agent is sufficiently dry, although this may also depend on the means of control, the target disease to be controlled, etc.
[00333] Here, the use ratio of the separate agents containing active ingredient A and active ingredient B, respectively, as active ingredients, is the same including the preferred modalities, as well as the ratio of the content of active ingredient A and ingredient active B in the composition comprising both active ingredient A and active ingredient B. Furthermore, from the viewpoint of work efficiency, etc., it is preferable to use the composition comprising both active ingredient A and active ingredient B as ingredients active. EXAMPLES
[00334] Now, for the purpose of specifically demonstrating the utility of the present invention, Test Examples will be given below, but the present invention is in no way limited to these Examples. Test Example 1 Preventive test against gray mold
[00335] Using the following compound listed in Table 2 (the active ingredient A) and the compound listed in Table 5 to Table 15 (active ingredient B), an agent was prepared according to the above preparation example. This agent was diluted with water to a predetermined concentration to obtain a test solution. Then cucumber (variety: Sagami-hanjiro) was planted in a 90 cm3 plastic pot, and at the cotyledon stage, 5 ml of the obtained test solution was sprayed with a spray gun and air dried. Then, the treated sheet was cut and placed in a plastic container that was filled with water to a depth of approximately 0.5 cm. A conidia suspension of the cucumber gray mold fungus (Botrytis cinerea) and a dissolved PDA culture medium were mixed at a ratio of 1:1 (mass ratio), and the mixture was dripped to inoculate the 30 µl treated leaf. . After inoculation, the plastic container was sealed and left at 20°C for 3 days, the ratio of the lesion formed occupying the inoculated leaf was measured, and the preventive value was calculated according to the formula calculated below. The results are shown in Table 17 to Table 26. Preventive value = [1- (ratio of area with lesion in treated batch/ratio of area with lesion in untreated batch)] x 100
[00336] Furthermore, from the preventive value at each concentration of agent, synergy was calculated using the Colby method (Colby S.R. 1976, Weeds 15, 20-22). The calculation method is as follows. E=X+Y-XY/100
[00337] X: preventive value of agent A at a concentration x
[00338] Y: preventive value of agent B at concentration y
[00339] E: theoretical value expected by treating the mixture of agent A and agent B.
[00340] The result obtained is considered synergy if the observed value is greater than the expected value, it is considered antagonism if the expected value is greater than the observed value, and it is considered an additive effect if the observed value and the expected value are equal . Table 17





Test Example 2 Preventive test against gray mold
[00341] Using the following compound listed in Table 2 (active ingredient A) and the following compound listed in Table 5 to Table 15 (active ingredient B) as active ingredients, a preventive test against gray mold was conducted according to the method described in Test Example 1. The results are shown in Table 27



Test Example 3 Preventive test against gray mold
[00342] Using the following compound listed in Table 2 (active ingredient A) and the following compound listed in Table 5 or Table 6 (active ingredient B) as active ingredients, a preventive test against gray mold was conducted according to the described method in Test Example 1. The results are shown in Table 34 through Table 48.







Test Example 4 Preventive test against gray mold
[00343] Using the following compound listed in Table 2 (active ingredient A) and the following compound listed in Table 6 to Table 16 (active ingredient B) as active ingredients, a preventive test against gray mold was conducted according to the method described in Test Example 1. The results are shown in Table 49 through Table 63.














Test Example 5 Efficacy test on rice sheath aphid (spray treatment and preventive test)
[00344] An agent comprising the following compound listed in Table 2 (active ingredient A) and the compound listed in Table 6 (C17: active ingredient B) as active ingredients, was prepared according to the above preparation example. The agent was diluted with water to a predetermined concentration to obtain a test solution. Then, in a plastic pot of 90 cm3, rice (Nipponbare) was sown for 5 grains in one area, and to the seedlings developed in the 4 seedling stage, the test solution was applied by a spray gun in an amount of 5 ml per pot for treatment.
[00345] One day after treatment, 1 g of mycelial flora of the rice sheath aphid fungus (Rhizoctonia solani) cultivated in bran medium, was placed for 5 g in a part of the seedlings close to the ground, and the pot was placed in a humidity chamber at a temperature of 25°C and humidity greater than 95% RH for eight days. The height of the lesions that appeared at the highest position from the part close to the ground (height of the lesion) was investigated, and the preventive value was calculated according to the following formula. Preventive value = [1-(height of lesion in treated batch/height of lesion in untreated batch)] x 100
[00346] Furthermore, from the preventive value for each concentration of agent, synergy was calculated using the Colby method (Colby SR 1976, Weeds 15, 20-22). The results are shown in Table 64 and Table 65. [Table 64]

[Test Example 6] Efficacy test on rice sheath aphid (spray treatment and preventive test)
[00347] Using the following compound listed in Table 2 (active ingredient A) and the compound listed in Table 6 (C17: active ingredient B) as active ingredients, a preventive test on rice sheath aphid was conducted according to Example Test 5 above. The results are shown in Table 66 and Table 67. [

[Test Example 7] Efficacy test on cucumber downy mildew (spray treatment and preventive test)
[00348] An agent comprising the following compound listed in Table 2 (active ingredient A) and the compound listed in Table 6 (C40: active ingredient B) as active ingredients, was prepared according to the preparation example above. This agent was diluted with water to a predetermined concentration to obtain a test solution. Then, on cucumber seedlings (variety: Sagami-hanjiro) at the 1.5 leaf stage grown in a pot with a diameter of 7 cm, the test solution was applied by a spray gun in an amount of 10 ml per pot, for treatment. One day after treatment, a spore suspension (2x100,000 cfu/ml) of cucumber downy mildew (Pseudoperenospora cubensis) was inoculated by spraying, and the vessel was placed in a humidity chamber at a temperature of 20°C and humidity greater than 95% RH for 24 hours. After placing the pot in a glass greenhouse for 6 days, the ratio of the area with formed lesions occupying the inoculated leaves was measured, and the preventive value was calculated according to the following formula. Preventive value = [1-(ratio of area with injury in treated batch / ratio of area with injury in untreated batch)] x 100
[00349] Furthermore, from the preventive value for each concentration of agent, synergy was calculated using the Colby method (Colby SR 1976, Weeds 15, 20-22). The results are shown in Table 68 and Table 69. [Table 68]
[Test Example 8] Efficacy test on wheat glume pustule (spray treatment and preventive test)
[00350] An agent comprising the following compound listed in Table 2 (active ingredient A) and the following compound listed in Table 6, Table 11 or Table 15 (active ingredient B) as active ingredients, was prepared according to the preparation example above. This agent was diluted with water to a predetermined concentration to obtain a test solution. Then, on wheat seedlings (variety: Haruyutaka) at the 1-leaf stage, sown in a pot with a diameter of 7 cm, with 5 seeds per pot, and grown for 7 days, the test solution was applied by a pistol of spray in an amount of 5 ml per pot, for treatment. One day after treatment, a spore suspension (1*100,000 cfu/ml) of wheat glume pustule (Leptosphaeria nodorum) was inoculated by spraying, and the vessel was placed in a humidity chamber at a temperature of 20°C and humidity greater than 95% RH for 48 hours. After placing the pot in a glass greenhouse for 7 days, the ratio of the area with formed lesions occupying the inoculated leaves was measured, and the preventive value was calculated according to the following formula. Preventive value = [1-(ratio of area with injury in treated batch/ratio of area with injury in untreated batch)] * 100
[00351] Furthermore, from the preventive value for each concentration of agent, synergy was calculated using the Colby method (Colby SR 1976, Weeds 15, 20-22). The results are shown in Table 70 through Table 84.















Test Example 9 Efficacy test on wheat glume pustule (seed treatment)
[00352] An agent comprising the following compound listed in Table 2 (active ingredient A) and the compound listed in Table 11 (H35: active ingredient B) as active ingredients, was prepared according to the preparation example above. This agent was diluted with water to a predetermined concentration to obtain a test solution. A predetermined amount of test solution was placed in a 5 ml glass bottle, and 0.5 g (approximately 15 grains) of wheat seeds (variety: Haruyutaka) was added, stirred and air dried. In each pot with a diameter of 7 cm with soil placed inside, 3 grains were sown and cultivated for 14 days. In wheat seedlings (variety: Haruyutaka) grown to the 1-leaf stage, a spore suspension (100,000 cfu/ml) of wheat gluma pustule (Leptosphaeria nodorum) was inoculated by spraying, and the pot was placed in a chamber humid at a temperature of 20°C and humidity above 95% RH for 48 hours. After placing the pot for 7 days in a glass greenhouse, the ratio of the area with formed lesions occupying the inoculated leaves was measured, and the preventive value was calculated according to the following formula. Preventive value = [1-(ratio of area with injury in treated batch/ratio of area with injury in untreated batch)] x 100
Furthermore, from the preventive value at each concentration of agent, synergy was calculated using the Colby method (Colby S.R. 1976, Weeds 15, 20-22).
[00354] The results are shown in Table 85 and Table 86.

Test Example 10 Efficacy test on wheat powdery mildew (seed treatment)
[00355] An agent comprising the following compound listed in Table 2 (active ingredient A) and the compound listed in Table 11 (H35: active ingredient B) as active ingredients, was prepared according to the above preparation example. This agent was diluted with water to a predetermined concentration to obtain a test solution. A predetermined amount of test solution was placed in a 5 ml glass bottle, and 0.5 g (approximately 15 grains) of wheat seeds (variety: Norin 61) was added, stirred and air dried. In each pot with a diameter of 7 cm and having soil placed inside, 3 grains were sown and cultivated for 14 days. On wheat seeds grown to the 1-leaf stage, a spore suspension (100,000 cfu/ml) of wheat powdery mildew (Blumeria graminis) was inoculated by spraying. After placing the vase in a glass greenhouse for 10 days, the ratio of the area with formed lesions occupying the inoculated leaves was measured, and the preventive value was calculated according to the following formula. Preventive value = [1-(ratio of area with injury in treated batch/ratio of area with injury in untreated batch)] x 100
[00356] Furthermore, from the preventive value at each concentration of agent, synergy was calculated using the Colby method (Colby S.R. 1976, Weeds 15, 20-22).
[00357] The results are shown in Table 87 and Table 88.


Test Example 11 Efficacy test on cucumber powdery mildew (treatment by irrigation)
[00358] An agent comprising the following compound listed in Table 2 (active ingredient A) and the compound listed in Table 6 (C18: active ingredient B), was prepared according to the above preparation example. This agent was diluted with water to a predetermined concentration to obtain a test solution. 5 ml of the test solution was irrigated by means of a pipette in the part close to the soil of 1-leaf stage cucumber seedlings (variety: Sagami-hanjiro), grown in a styrol pot with a diameter of 10 cm, and in the the next day, the seedlings were transplanted into the 4 "cun" pots. Then, after cultivation for 7 days in a glass greenhouse, until the first true cucumber leaf, a spore suspension (100.00 cfu/ml) of powdery cucumber mildew (Sphaerotheca cucurbitae) was inoculated by spraying. After 10 days in a glass greenhouse, the ratio of the area with lesions formed occupying the inoculated leaves was measured, and the preventive value was calculated according to the following formula. Preventive value = [1-(ratio of area with injury in treated batch/ratio of area with injury in untreated batch)] x 100
[00359] Furthermore, from the preventive value at each concentration of agent, synergy was calculated using the Colby method (Colby SR 1976, Weeds 15, 20-22). The results are shown in Table 89 and Table 90.
INDUSTRIAL APPLICABILITY
[00360] The composition of the present invention and the method of the present invention require excellent synergistic control effects against pathogens that cause various diseases and can be used in a wide range of fields in the fields of agriculture/horticulture.
[00361] The entirety of Japanese Patent Application No. 2014-022529 filed on February 7, 2014, including the descriptive report, claims and abstract, is hereby incorporated in its entirety by way of reference.

权利要求:
Claims (12)
[0001]
1. Composition for a fungicide, insecticide, nematicide or bactericide, characterized in that it comprises synergistically effective amounts of at least two types of the following compounds, said composition comprising a compound selected from active ingredient A to below, and a compound selected from active ingredient B below: (1) Active ingredient A: an oxime-substituted amide type compound represented by the following formula, or its N-oxide or its salt,
[0002]
2. Composition for a fungicide, an insecticide, a nematicide or a bactericide according to claim 1, characterized in that it contains a compound selected from the active ingredients of group B-II.
[0003]
3. Composition for a fungicide, an insecticide, a nematicide or a bactericide according to claim 1, characterized in that it contains a compound selected from the active ingredients of group B-III.
[0004]
4. Composition for a fungicide, an insecticide, a nematicide or a bactericide according to claim 1, characterized in that it contains a compound selected from the active ingredients of group B-IV.
[0005]
5. Composition for a fungicide, an insecticide, a nematicide or a bactericide according to claim 1, characterized in that it contains a compound selected from the active ingredients of group B-V.
[0006]
6. Composition for a fungicide, an insecticide, a nematicide or a bactericide according to claim 1, characterized in that it contains a compound selected from the active ingredients of group B-VI.
[0007]
7. Composition for a fungicide, an insecticide, a nematicide or a bactericide according to claim 1, characterized in that it contains a compound selected from the active ingredients of group B-VII.
[0008]
8. Composition for a fungicide, an insecticide, a nematicide or a bactericide according to claim 1, characterized in that it contains a compound selected from the active ingredients of group B-XI.
[0009]
9. Composition for a fungicide, an insecticide, a nematicide or a bactericide according to claim 1, characterized in that it contains a compound selected from the active ingredients of group B-XII.
[0010]
10. Method to control pests, harmful insects, nematodes or bacteria in plants, characterized by treatment at the same time or in close temporal proximity with a compound selected from the active ingredients A defined in claim 1 and a compound selected from the active ingredients B defined in claim 1.
[0011]
11. Method to control pests, harmful insects, nematodes or bacteria according to claim 10, characterized in that the application rate of each of the active ingredients A and B varies from 0.1 to 1,000 g ai/ there is.
[0012]
12. Method to control pests, harmful insects, nematodes or bacteria according to claim 10 or 11, characterized in that the application dosage, as the amount of active ingredients, varies from 0.005 to 50 kg/ha.

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法律状态:
2019-08-20| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|

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2021-02-09| B07A| Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]|

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2021-05-18| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|

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2021-07-13| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 06/02/2015, OBSERVADAS AS CONDICOES LEGAIS. |

优先权:

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申请号 | 申请日 | 专利标题

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JP2014-022529|2014-02-07|

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JP2014022529|2014-02-07|

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PCT/JP2015/053385|WO2015119246A1|2014-02-07|2015-02-06|Sterilising or bactericidal composition and disease control method|

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