AEROSOL GENERATING DEVICE AND SYSTEM

专利摘要:
aerosol generating device comprising a heat exchanger. an aerosol generating device (4) for use in an aerosol generating system, the aerosol generating device comprising: a cavity configured to receive an aerosol generating article (2); a heat exchanger (16) having a first portion (24) near the cavity and a second portion (26) distal to the cavity for capturing heat from a lighter; and a retractable cover (14). the retractable cover is movable from a first position, in which the retractable cover covers the second part of the heat exchanger, to a second position, in which the second part of the heat exchanger is exposed to be heated by a lighter . the retractable cover is configured to automatically return from the second position to the first position when the second part of the heat exchanger reaches a threshold temperature.
公开号:BR112016010826B1
申请号:R112016010826-4
申请日:2014-12-15
公开日:2021-06-15
发明作者:Evan Jochnowitz；Nicholas Martin Broadbent；Christopher James Rowe；Michael Cane
申请人:Philip Morris Products S.A.；
IPC主号:

专利说明:

[001] The present invention relates to an aerosol generating device for use in an aerosol generating system and an aerosol generating system comprising an aerosol generating device and an aerosol generating article. In particular, the present invention relates to an aerosol generating device and an aerosol generating system for generating an aerosol comprising nicotine salt particles.
[002] Devices for delivering nicotine to a user comprising a source of nicotine and a source of volatile delivery enhancing compound are known. For example, WO 2008/121610 A1 discloses a device in which nicotine and a volatile distribution enhancing compound are reacted together in the gas phase to form an aerosol of nicotine salt particles that is inhaled by the user. However, WO 2008/121610 A1 does not address how to optimize the ratio of nicotine to volatile distribution enhancing compound in the gas phase to minimize the amount of unreacted distribution enhancing compound vapor delivered to a user.
[003] For example, where the vapor pressure of the volatile distribution enhancing compound is greater than that of nicotine, this can cause a difference in the vapor concentration of the two reactants. Differences between volatile delivery enhancing compound and nicotine concentration can cause unreacted delivery enhancing compound vapor delivery to a user.
[004] It is desirable to produce a maximum amount of nicotine salt particles for delivery to a user using a minimum amount of reagents. Consequently, it would be desirable to provide an aerosol generating system of the type disclosed in WO 2008/121610 A1 that would further improve the formation of an aerosol of nicotine salt particles for delivery to a user. It is especially desirable to improve the proportion of the gas phase volatile distribution enhancing compound that is reacted with the gas phase nicotine.
[005] According to the invention, an aerosol generating device for use in an aerosol generating system is provided herein, the aerosol generating device comprising: a cavity configured to receive an aerosol generating article; a heat exchanger having a first portion proximal to the cavity and a second portion distal to the cavity for capturing heat from a lighter; and a retractable cover. The retractable cover is movable from a first position, in which the retractable cover covers the second part of the heat exchanger, to a second position, in which the second part of the heat exchanger is exposed to be heated by a lighter. The retractable cover is configured to automatically return from the second position to the first position when the second part of the heat exchanger reaches a threshold temperature.
[006] According to the invention, there is also provided an aerosol generating system comprising an aerosol generating device according to the invention and an aerosol generating article. In particular, there is provided an aerosol generating system comprising an aerosol generating device according to the invention and an aerosol generating article, wherein the aerosol generating article comprises: a source of nicotine; and a source of distribution-enhancing compound.
[007] As used herein, the term "aerosol generating device" refers to a device that interacts with an aerosol generating article to generate an aerosol that is directly inhalable into a user's lungs through the user's mouth.
[008] As used herein, the term "aerosol generating article" refers to an article comprising an aerosol forming substrate capable of releasing volatile compounds, which can form an aerosol. In particular, the term "aerosol generating article" refers to an article comprising a source of nicotine and a source of the delivery-enhancing compound capable of releasing nicotine and a delivery-enhancing compound that can react with each other in the step. gas to form an aerosol.
[009] As used herein, the term "lighter" refers to a lighter with a blue flame, a torch type lighter or any other lighter suitable for heating the second part of the heat exchanger.
[0010] The aerosol generating system according to the invention comprises a proximal end through which, during use, the aerosol leaves the aerosol generating system for delivery to a user. The proximal end may also be referred to as the mouth end. During use, a user brings on the proximal end of the aerosol generating article in order to inhale an aerosol generated by the aerosol generating system. The aerosol generating system comprises a distal end opposite the proximal end.
[0011] As used in this document, the term "longitudinal" is used to describe the direction between the proximal end and the opposite distal end of the aerosol generating systems of the aerosol generating devices according to the invention, and the term "transverse" is used to describe the direction perpendicular to the longitudinal direction.
[0012] As used in this document, by "length" is meant the maximum longitudinal dimension between the distal end and the proximal end of the components, or portions of the components, of the aerosol generating systems and the aerosol generating devices, according to with the invention.
[0013] As used in this document, the terms "upstream" and "downstream" are used to describe the relative positions of components, or parts of components, of aerosol generating systems aerosol generating devices according to the invention with respect to the direction of air flow through the aerosol generating system when a user draws on the proximal end of the aerosol generating system.
[0014] When a user draws at the proximal end of the aerosol generating system, air is drawn into the aerosol generating system, passes downstream through the aerosol generating system, and exits the aerosol generating system at the proximal end.
[0015] The proximal end of the aerosol generating systems and the aerosol generating devices according to the invention may also be referred to as the downstream end and components, or component parts, of the aerosol generating systems and the aerosol generating devices, according to the invention, can be described as being upstream or downstream of each other, based on their positions relative to the flow of air through the aerosol generating systems towards the proximal end.
[0016] The heat exchanger of the aerosol generating device is configured to transfer thermal energy from a lighter to an aerosol generating article received in the cavity of the aerosol generating device to heat the aerosol generating article to an operating temperature above ambient temperature .
[0017] As described further below, since the aerosol generating article comprises a source of nicotine and a source of delivery-enhancing compound, heating the aerosol generating article to an operating temperature above ambient temperature allows controlling the amount of nicotine vapor and delivery enhancing compound vapor released from the nicotine source and the delivery enhancing compound source, respectively. This advantageously allows the vapor concentrations of nicotine and delivery enhancing compound to be controlled and proportionally balanced so as to yield efficient reaction stoichiometry. This advantageously improves the efficiency of aerosol formation and the consistency of nicotine delivery to a user. This also advantageously reduces the delivery of unreacted nicotine vapor and unreacted delivery enhancing compound vapor to a consumer.
[0018] The heat exchanger of the aerosol generating device has a first part close to the cavity and a second part distal to the cavity for capturing heat from a lighter. In use, the retractable cover of the aerosol generating device is moved from the first position to the second position to expose the second part of the heat exchanger.
[0019] With the retractable cover in the second position, a user can use a blue flame lighter, blowtorch lighter or other suitable lighter to heat the second part of the heat exchanger and thereby activate the aerosol generating device in one way. similar to lighting a cigarette or other conventional smoking article. Heat captured from the lighter by the second part of the heat exchanger is transferred by the first part of the heat exchanger to an aerosol generating article received in the cavity of the aerosol generating device.
[0020] When the second part of the exchanger reaches the threshold temperature, the retractable cover automatically returns from the second position to the first position, in which the retractable cover covers the second part of the heat exchanger
[0021] The automatic movement of the retractable cover from the second position to the first position when the second part of the heat exchanger reaches a threshold temperature substantially reduces or prevents the capture of more heat from the lighter by the second part of the heat exchanger. This advantageously prevents or reduces the risk of overheating of the aerosol generating device, which can disadvantageously result in deterioration or decomposition of one or more components of the aerosol generating device. This also substantially reduces or prevents the transfer of further heat by the first part of the heat exchanger to an aerosol generating article received in the cavity of the aerosol generating device. This advantageously prevents or reduces the risk of overheating of the aerosol generating article, which can disadvantageously result in deterioration or decomposition of one or more components of the aerosol generating device. Since the aerosol generating article comprises a source of nicotine and a source of delivery-enhancing compound, it also advantageously reduces or avoids the risk of an undesirable aerosol being delivered to the user due to the release of excess nicotine vapor and delivery-enhancing compound vapor from the nicotine source and the delivery-enhancing compound source, respectively.
[0022] As described above, the automatic movement of the retractable cover from the second position to the first position, when the second part of the heat exchanger reaches a threshold temperature, controls the maximum temperature that can be reached as a result of a user warming up the second part of the aerosol generating device heat exchanger with a lighter. This advantageously prevents or reduces the risk of overheating of the aerosol generating devices and aerosol generating articles of the aerosol generating systems according to the invention.
[0023] The automatic movement of the retractable aerosol generating device cover from the second position to the first position when the second part of the heat exchanger reaches a threshold temperature also advantageously provides a visual indication to the user that the aerosol has reached a suitable operating temperature and is ready to use.
[0024] Preferably, the retractable cover is manually movable from the first position to the second position by a user. In these embodiments, the maximum force required to be exerted by a user to manually move the retractable cover from the first position to the second position is preferably less than or equal to about 2 N.
[0025] The aerosol generating device may comprise electrically driven means to automatically return the retractable cover from the second position to the first position when the second part of the heat exchanger reaches a threshold temperature. For example, the aerosol generating device may comprise electrically actuated means for automatically returning the retractable cover from the second position to the first position, comprising an electronic temperature sensor and feedback system.
[0026] Preferably, the aerosol generating device comprises mechanically driven means to return the retractable cover automatically from the second position to the first position when the second part of the heat exchanger reaches a threshold temperature. This advantageously avoids the need to include a battery or other source of electrical energy in the aerosol generating device.
[0027] In certain preferred embodiments, the aerosol generating device comprises operable mechanical tilt means to tilt the retractable cover to the first position and operable mechanical locking means to maintain the retractable cover in the second position to the second part of the heat exchanger reach a threshold temperature.
[0028] In certain particularly preferred embodiments, the aerosol generating device comprises one or more springs operable to tilt the retractable cover in the first position and locking means comprising a thermal bimetallic switch operable to maintain the retractable cover in the second position until the second part of the heat exchanger reach a threshold temperature. In these modes, the thermostatic bimetallic switch automatically releases the locking means when the second part of the heat exchanger reaches a threshold temperature. Upon release of the locking means, the one or more springs operate to return the retractable cover from the second position to the first position.
[0029] Since the aerosol generating article comprises a source of nicotine and a source of delivery-enhancing compound, the threshold temperature is preferably between about 60 degrees Celsius and about 150 degrees Celsius. More preferably, between about 80 degrees Celsius and about 110 degrees Celsius.
[0030] The retractable cover of the aerosol generating device can be movable towards the cavity from the first position to the second position and movable away from the cavity from the second position to the first position. For example, the retractable cover may be a retractable open ended sleeve that circumscribes the second part of the heat exchanger in the first position and the second part of the heat exchanger in the second position.
[0031] Preferably, the retractable cover of the aerosol generating device is movable, moving away from the cavity, from the first position to the second position and movable, towards the cavity, from the second position to the first position. In certain particularly preferred embodiments, the retractable cover of the aerosol generating device is a retractable cover which is movable away from the cavity from the first position to the second position and is movable towards the cavity from the second position. to the first position. In these embodiments, the retractable cover surrounds the second part of the heat exchanger in the first position and is distanced longitudinally from the second part of the heat exchanger in the second position.
[0032] The heat exchanger of the aerosol generating device can be formed of any suitable thermally conductive material or materials. Suitable materials include, but are not limited to, metals such as aluminum and copper.
[0033] Preferably, the first part of the heat exchanger of the aerosol generating device comprises one or more thermally conductive hollow tubes.
[0034] In certain preferred embodiments, the first part of the heat exchanger comprises one or more thermally conductive hollow tubes circumscribing at least a part of the length of the cavity.
[0035] Preferably, the second part of the heat exchanger of the aerosol generating device comprises a plurality of thermally conductive fins. The inclusion of a plurality of thermally conductive fins advantageously facilitates the capture of heat from a lighter by the second part of the heat exchanger.
[0036] The first part of the heat exchanger is configured to transfer heat captured from the lighter by the second part of the heat exchanger to an aerosol generating article received in the cavity of the aerosol generating device.
[0037] The first part of the heat exchanger can be configured to directly transfer heat to an aerosol generating article received in the cavity of the aerosol generating device.
[0038] Alternatively, or in addition, the first part of the heat exchanger may be configured to indirectly transfer heat to an aerosol generating article received in the cavity of the aerosol generating device.
[0039] As used herein, by "indirectly" is meant that the first part of the heat exchanger is configured to transfer heat to an aerosol generating article received in the cavity of the aerosol generating device through one or more components of the device aerosol generator.
In certain particularly preferred embodiments, the aerosol generating device is used in cooperation with an aerosol generating article comprising a source of nicotine and a source of delivery enhancing compound. However, it will be contemplated that aerosol generating devices in accordance with the invention may be used in cooperation with other types of aerosol generating article.
[0041] In these embodiments, the first part of the heat exchanger may be configured to transfer heat to one or both of the nicotine source and the aerosol generating article delivery enhancing compound source. Preferably, the first part of the heat exchanger is configured to transfer heat to the nicotine source of the aerosol generating article.
[0042] In certain particularly preferred embodiments, the aerosol generating device is used in cooperation with an aerosol generating article comprising a nicotine source, a source of delivery enhancing compound and a heat transfer barrier between the nicotine source. and the source of distribution enhancement compound.
[0043] In these embodiments, the heat transfer barrier separates the source of nicotine and the source of distribution-enhancing compound from the aerosol generating article and is configured to reduce heat transfer between the source of nicotine and the source of compound of improving the distribution of the aerosol generating article.
[0044] The inclusion of a heat transfer barrier between the nicotine source and the aerosol generating article delivery enhancing compound source advantageously allows the aerosol generating article delivery enhancing compound source to be maintained at a lower temperature while the nicotine source is heated to a higher temperature. In particular, the inclusion of a heat transfer barrier between the nicotine source and the delivery-enhancing compound source advantageously allows the nicotine delivery of the aerosol generating system to be significantly greater, increasing the temperature of the aerosol source. nicotine while the source of the delivery-enhancing compound is maintained at a temperature below the thermal decomposition temperature of the delivery-enhancing compound.
[0045] As used in this document, "heat transfer barrier" is used to describe a physical barrier that reduces the amount of heat transferred from the nicotine source to the source of the delivery enhancing compound compared to an aerosol generating article where no barriers are present. The physical barrier can comprise a solid material. Alternatively, or in addition, the physical barrier may comprise a gas, vacuum or partial vacuum between the source of nicotine and the source of the aerosol generating article delivery enhancing compound.
[0046] In these embodiments, the first part of the heat exchanger is preferably configured to transfer heat to the nicotine source of the aerosol generating article, heating the nicotine source to a temperature of between about 80°C and about about 150 °C.
[0047] In these embodiments, the heat transfer barrier is preferably configured so that, during use, the temperature of the distribution-enhancing compound source is less than 60 °C when the nicotine source is heated to a temperature between 80°C and 150°C.
[0048] Preferably, the cavity of the aerosol generating device is substantially cylindrical.
[0049] The cavity of the aerosol generating device may have a cross section of any suitable shape. For example, the cavity may have a substantially circular, elliptical, triangular, square, rhomboid, trapezoid, pentagonal, hexagonal or octagonal cross section.
Preferably, the cavity of the aerosol generating device has a cross section of substantially the same shape as the cross section of the aerosol generating article to be received in the cavity.
[0051] In certain embodiments, the cavity of the aerosol generating device may have a diagonal cross section of substantially the same shape and dimensions as the diagonal cross section of the aerosol generating article to be received in the cavity in order to maximize conductive heat transfer of the aerosol generating device to the aerosol generating article.
[0052] As used herein, the term "cross section" is used to describe the cross section of the cavity of the aerosol generating article perpendicular to the main axis of the cavity and the aerosol generating article, respectively.
[0053] Preferably, the cavity of the aerosol generating device has a substantially circular diagonal cross-section or a substantially elliptical diagonal cross-section. More preferably, the cavity of the aerosol generating device is of substantially circular diagonal cross-section.
[0054] Preferably, the cavity length of the aerosol generating device is less than the length of the aerosol generating article so that when the aerosol generating article is received in the cavity of the aerosol generating device, the proximal or downstream end of the article aerosol generator projects out of the cavity of the aerosol generating device.
[0055] Preferably, the cavity of the aerosol generating device has a diameter substantially equal to or slightly larger than the diameter of the aerosol generating article.
[0056] As used herein, by "diameter" is meant the maximum transverse dimension of the cavity of the aerosol generating article.
[0057] In certain particularly preferred embodiments, the aerosol generating device further comprises a first solid-liquid phase change material positioned on a perimeter of the cavity, wherein the first part of the heat exchanger is configured to heat the first solid-liquid phase change material at a temperature above the melting point of the first solid-liquid phase change material.
[0058] In these preferred embodiments, the first part of the heat exchanger is in thermal contact with the first solid-liquid phase change material and is configured to transfer heat captured from the lighter by the second part of the heat exchanger to the first solid-liquid phase change material.
[0059] During use, when heated to its melting point by the first part of the heat exchanger of the aerosol generating device, the first solid-liquid phase change material absorbs thermal energy as it phases from a solid to a liquid. Upon subsequent cooling, the first solid-liquid phase change material releases the absorbed thermal energy as it phases from a liquid to a solid.
[0060] The thermal energy released by the first solid-liquid phase change material, as it solidifies, heats an aerosol generating article received in the cavity of the aerosol generating device to an operating temperature above ambient temperature.
[0061] The first solid-liquid phase change material is positioned on the perimeter of the cavity of the aerosol generating device so that the thermal energy released by the first solid-liquid phase change material as it changes phase of a liquid to a solid, heat an aerosol generating article received in the cavity.
[0062] The first solid-liquid phase change material may extend wholly or partially around the circumference of the cavity. Preferably, the first solid-liquid phase change material extends fully around the circumference of the cavity.
[0063] The first solid-liquid phase change material may extend wholly or partially along the length of the cavity.
[0064] The first solid-liquid phase change material can be any suitable material that has a melting point in a desired operating temperature range of the aerosol generating system and a high latent heat of fusion.
[0065] Preferably, the first solid-liquid phase change material has a melting point of between about 30 degrees Celsius and about 70 degrees Celsius. In certain embodiments, the first solid-liquid phase change material can have a melting point of between about 40 degrees Celsius and about 60 degrees Celsius.
[0066] Preferably, the first solid-liquid phase change material has a latent heat of melting of at least about 150 kJ/kg, more preferably at least 200 kJ/kg, more preferably at least 250 kJ/kg.
[0067] Preferably, the first solid-liquid phase change material has a thermal conductivity of at least about 0.5 W.m-1.K.
[0068] Preferably, the first solid-liquid phase change material undergoes small volumetric changes in phase change from a solid to a liquid and from a liquid to a solid.
[0069] Preferably, the first solid-liquid phase change material has a low vapor pressure in the desired operating temperature range of the aerosol generating system.
[0070] Preferably, the first solid-liquid phase change material is non-flammable.
[0071] Examples of early solid-liquid phase change materials suitable for use in aerosol generating devices in accordance with the invention include, but are not limited to: organic phase change materials such as fatty acids and paraffins; and inorganic phase change materials such as inorganic salt hydrates.
[0072] Fatty acids suitable for use as the first solid-liquid phase change material include, but are not limited to: lauric acid and myristic acid. Suitable paraffins for use as the first solid-liquid phase change material include, but are not limited to: icosan, pentacosane, hexacosan, heptacosane, octasosan, nonacosane, n-triacontane, hentriacontane, dotriacontane, and tritriacontane.
[0073] In preferred embodiments, the first solid-liquid phase change material is an inorganic salt hydrate. Suitable inorganic salt hydrates for use as the first solid-liquid phase change material include, but are not limited to: phosphoric acid disodium salt dodecahydrate, calcium nitrate tetrahydrate, sodium thiosulfate pentahydrate, and sodium acetate. sodium trihydrate.
In particularly preferred embodiments, the first solid-liquid phase change material is sodium acetate trihydrate.
[0075] The amount of the first solid-liquid phase change material in the aerosol generating device must be sufficient for the first solid-liquid phase change material to release sufficient thermal energy as it phases from a liquid to a solid, to heat the aerosol generating article to a desired operating temperature range of the aerosol generating system.
[0076] Preferably, the first solid-liquid phase change material in the aerosol generating device is configured to release at least about 250 J of thermal energy, more preferably at least about 500 J of thermal energy, as it changes from phase from a liquid to a solid.
[0077] In certain preferred embodiments, the first solid-liquid phase change material in the aerosol generating device is configured to release between about 250 J and about 1500 J of thermal energy, more preferably between about 500 J and about 1250 J of thermal energy as it changes phase from a liquid to a solid.
[0078] Preferably, the first solid-liquid phase change material is configured to heat an aerosol generating article received in the cavity of the aerosol generating device to at least about 40 degrees Celsius. More preferably, the first solid-liquid phase change material is configured to heat an aerosol generating article received in the cavity of the aerosol generating device to at least about 40 degrees Celsius within about 10 seconds to about 15 seconds .
[0079] In certain preferred embodiments, the first solid-liquid phase change material is configured to heat an aerosol generating article received in the cavity of the aerosol generating device to between about 40 degrees Celsius and 60 degrees Celsius. In certain particularly preferred embodiments, the first solid-liquid phase change material is configured to heat an aerosol generating article received in the cavity of the aerosol generating device to between about 40 degrees Celsius and 60 degrees Celsius within about 10 seconds to about 15 seconds.
[0080] Preferably, the first solid-liquid phase change material is configured to release thermal energy for between about 3 minutes and about 10 minutes as it phases from a liquid to a solid.
[0081] As stated above, in certain particularly preferred embodiments, an aerosol generating device is used in cooperation with an aerosol generating article comprising a source of nicotine and a source of delivery enhancing compound.
[0082] In these embodiments, the first solid-liquid phase change material can be configured to heat one or both of the nicotine source and the aerosol generating article delivery enhancing compound source. Preferably, the first solid-liquid phase change material is configured to heat the nicotine source of the aerosol generating article.
[0083] As also stated above, in certain particularly preferred embodiments, the aerosol generating device is used in cooperation with an aerosol generating article comprising a source of nicotine, a source of delivery enhancing compound and a heat transfer barrier between the nicotine source and the delivery-enhancing compound source.
In these embodiments, the first solid-liquid phase change material is preferably configured to heat the nicotine source of the aerosol generating article to a temperature of between about 80 °C and about 150 °C.
[0085] In these embodiments, the heat transfer barrier is preferably configured so that, during use, the temperature of the distribution-enhancing compound source is less than 60 °C when the nicotine source is heated to a temperature between 80°C and 150°C.
[0086] Since the aerosol generating devices according to the invention comprise a first solid-liquid phase change material positioned on a perimeter of the cavity, the automatic movement of the retractable cover from the second position to the first position when the second part of the heat exchanger reaches a threshold temperature advantageously reduces the risk of overheating of the first solid-liquid phase change material by the first part of the heat exchanger. By reducing the risk of overheating of the first solid-liquid phase change material, the retractable cover advantageously increases the operational lifetime of the aerosol generating device.
[0087] To further reduce the risk of overheating of the first solid-liquid phase change material by the first part of the heat exchanger, the aerosol generating device preferably further comprises a second solid-liquid phase change material. liquid, wherein the melting point of the second solid-liquid phase change material is greater than the melting point of the first solid-liquid phase change material.
[0088] Upon heating, once the first solid-liquid phase change material has changed phase from a solid to a liquid, the first solid-liquid phase change material can continue to absorb additional thermal energy from the first part of the heat exchanger. This will cause the temperature of the first solid-liquid phase change material to continue to rise above its melting point and the absence of a second solid-liquid phase change material could result in the first change material overheating of solid-liquid phase.
[0089] However, where the aerosol generating device comprises a second solid-liquid phase change material with a melting point greater than the first solid-liquid phase change material, the second phase change material of solid-liquid will undergo a solid-to-liquid phase change when the temperature of the first solid-liquid phase change material reaches the melting point of the second solid-liquid phase change material. As it undergoes phase change from solid to liquid, the second solid-liquid phase change material absorbs thermal energy. The second solid-liquid phase change material thereby stores the amount of additional thermal energy absorbed by the first solid-liquid phase change material. This reduces the risk of overheating the first solid-liquid phase change material.
[0090] By reducing the risk of overheating of the first solid-liquid phase change material, the inclusion of a second solid-liquid phase change material also advantageously increases the operational lifetime of the aerosol generating device .
[0091] Preferably, the melting point of the second solid-liquid phase change material is between 15 degrees Celsius and 25 degrees Celsius higher than the melting point of the first solid-liquid phase change material.
[0092] Preferably, the second solid-liquid phase change material has a melting point of between about 70 degrees Celsius and about 90 degrees Celsius.
[0093] Preferably, the second solid-liquid phase change material has a latent heat of fusion of at least about 150 kJ/kg, more preferably at least 200 kJ/kg.
[0094] Preferably, the second solid-liquid phase change material undergoes small volumetric changes in the phase change from a solid to a liquid and from a liquid to a solid.
[0095] Preferably, the second solid-liquid phase change material has a low vapor pressure in the desired operating temperature range of the aerosol generating system.
[0096] Preferably, the second solid-liquid phase change material is non-flammable.
[0097] Examples of solid-liquid second phase change materials suitable for use in aerosol generating devices in accordance with the invention include, but are not limited to: organic phase change materials such as paraffins; and inorganic phase change materials such as inorganic salt hydrates.
Suitable paraffins for use as the second solid-liquid phase change material include, but are not limited to: triatriacontane, tetratriacontane, pentatryacontane, hexatriacontane, heptatriacontane, octatriacontane, nonatriacontane, tertracontane, hen-tetracontane, and dotetracontane.
[0099] Inorganic salt hydrates, suitable for use as the second solid-liquid phase change material, include, but are not limited to: magnesium nitrate hexahydrate and magnesium chloride hexahydrate.
[00100] In preferred embodiments, the second solid-liquid phase change material is a paraffin.
In particularly preferred embodiments, the second solid-liquid phase change material is hexatriacontane.
[00102] The second solid-liquid phase change material is in thermal contact with the first solid-liquid phase change material and the first part of the heat exchanger.
[00103] Preferably, thermal energy is transferred from the first part of the heat exchanger to the first solid-liquid phase change material through the second solid-liquid phase change material.
[00104] The second solid-liquid phase change material may be positioned upstream of the cavity and the first solid-liquid phase change material.
[00105] Alternatively, the second solid-liquid phase change material can be positioned on the perimeter of the cavity. In such embodiments, the second solid-liquid phase change material may be upstream of the first solid-liquid phase change material, downstream of the first solid-liquid phase change material, or it may circumscribe the first material of solid-liquid phase change.
[00106] As described above, since the aerosol generating device comprises a first solid-liquid phase change material, the first part of the heat exchanger is in thermal contact with the first solid-liquid phase change material liquid. Since the aerosol generating device further comprises a second solid-liquid phase change material, the first part of the heat exchanger is also in thermal contact with the second solid-liquid phase change material. In these modalities, the first part of the heat exchanger, the first solid-liquid phase change material and the second solid-liquid phase change material are preferably configured so that thermal energy is transferred from the first part of the heat exchanger to the second solid-liquid phase change material and then from the second solid-liquid phase change material to the first solid-liquid phase change material.
[00107] In certain preferred embodiments, the first part of the heat exchanger surrounds the first solid-liquid phase change material. For example, the first part of the heat exchanger may comprise a thermally conductive hollow tube that surrounds the first solid-liquid phase change material.
[00108] Alternatively, or in addition, since the aerosol generating device comprises a second solid-liquid phase change material, the first part of the heat exchanger may surround the second solid-liquid phase change material .
[00109] The aerosol generating device may comprise a housing containing the cavity, the first part of the heat exchanger and, when present, the first solid-liquid phase change material and the second solid-phase change material- liquid.
[00110] The first part of the heat exchanger and, when present, the first solid-liquid phase change material and the second solid-liquid phase change material may be moved away from the housing by an air gap or by a layer of insulation.
[00111] The housing may be designed to be gripped or held by a user.
[00112] Preferably, the housing is substantially cylindrical.
[00113] In certain preferred embodiments, the housing and the retractable cover of the aerosol generating device form a cylindrical heating sleeve.
In certain particularly preferred embodiments, aerosol generating device is used in cooperation with aerosol generating article comprising a first compartment comprising a source of nicotine and a second compartment comprising a source of delivery enhancing compound.
[00115] As used herein, the term "compartment" is used to describe a chamber or container within the aerosol generating article which comprises the source of nicotine or the source of delivery enhancing compound.
[00116] In these embodiments, the aerosol generating device preferably further comprises a piercing member positioned within the cavity of the aerosol generating device to pierce the first compartment and the second compartment of the aerosol generating article. The piercing element can be formed from any suitable material.
[00117] The first compartment and the second compartment of the aerosol generating article may abut each other. Alternatively, the first compartment and the second compartment of the aerosol generating article may be spaced apart from one another.
[00118] The first compartment of the aerosol generating article can be sealed by one or more frangible barriers. In certain preferred embodiments, the first compartment is sealed by a pair of opposing transverse frangible barriers.
[00119] Alternatively, or in addition to this, the second compartment of the aerosol generating article may be sealed by one or more frangible barriers. In certain preferred embodiments, the second compartment is sealed by a pair of opposing transverse frangible barriers.
[00120] The one or more frangible barriers can be formed from any suitable material. For example, the one or more frangible barriers can be formed from a metallic foil or film.
[00121] In these embodiments, the aerosol generating device preferably further comprises a piercing member positioned within the cavity of the aerosol generating device to perforate one or more frangible barriers, sealing one or both of the first compartment and the second compartment of the aerosol generating article.
[00122] The volumes of the first compartment and the second compartment can be the same or different from each other. In a certain preferred embodiment, the volume of the first compartment is greater than the volume of the second compartment.
[00123] As described in more detail below, the first compartment and the second compartment may be arranged in series or parallel within the aerosol generating article.
[00124] As used in this document, by "series" it is understood that the first compartment and the second compartment are arranged within the aerosol generating article such that, when in use, the air flow is drawn through the aerosol generating article passes through one of the first compartment and the second compartment, then passes through the other of the first compartment and the second compartment. Nicotine vapor is released from the nicotine source in the first compartment into the air flow drawn through the aerosol generating article and the delivery enhancing compound is released from the delivery enhancing compound source in the second compartment to the inside. of the flow of air drawn through the aerosol generating article. Nicotine vapor reacts with the vapor from the delivery-enhancing compound in the gas phase to form an aerosol, which is delivered to a user.
[00125] Since the first compartment and the second compartment are arranged in series within the aerosol generating article, the second compartment is preferably downstream of the first compartment, so that, when in use, an engulfed air flow through the aerosol generating article it passes through the first compartment and then passes through the second compartment.
[00126] The location of the second compartment comprising the source of delivery enhancing compound downstream of the first compartment of the nicotine source advantageously improves the consistency of nicotine delivery of the aerosol generating systems according to the invention.
[00127] Without being bound by theory, it is believed that the location of the distribution-enhancing compound source downstream of the nicotine source reduces or prevents the deposition of the distribution-enhancing compound vapor released from the source of the nicotine compound. improving distribution in the source of nicotine during use. This reduces the fading over time of nicotine delivery in the aerosol generating systems according to the invention.
[00128] In these embodiments, the nicotine vapor can react with the vapor of the delivery-enhancing compound in the second compartment to form an aerosol. In such embodiments, the aerosol generating article may further comprise a third compartment downstream of the second compartment and the nicotine vapor may alternatively or in addition react with the vapor of the delivery-enhancing compound in the third compartment to form an aerosol.
[00129] Since the first compartment and the second compartment are arranged in series within the aerosol generating article, the aerosol generating device may further comprise a piercing member positioned centrally within the cavity of the aerosol generating device, along the main shaft of the cavity, for piercing the first compartment and the second compartment of the aerosol generating article.
[00130] As used in this document, "parallel" is understood to mean that the first compartment and the second compartment are arranged within the aerosol generating article such that, when in use, a first air flow is drawn through of the aerosol generating article passes through the first compartment and a second stream of air drawn through the aerosol generating article passes through the second compartment. Nicotine vapor is released from the nicotine source in the first compartment in the first air flow drawn through the aerosol generating article and the delivery-enhancing compound vapor is released from the delivery-enhancing compound source in the second compartment into the second flow of air drawn through the aerosol generating article. The nicotine vapor in the first air stream reacts with the delivery enhancing compound vapor in the second air stream in the gas phase to form an aerosol, which is delivered to a user.
[00131] In these embodiments, the aerosol generating article may further comprise a third compartment downstream of the first compartment and the second compartment and the nicotine vapor in the first air stream may mix and react with the vapor of the distribution enhancing compound in the second air flow in the third compartment to form an aerosol.
[00132] Since the first compartment and the second compartment of the aerosol generating article are arranged in parallel within the aerosol generating article, the aerosol generating device may further comprise a piercing member comprising a first piercing member positioned within of the cavity of the aerosol generating device for piercing the first compartment of the aerosol generating article and a second piercing member positioned within the cavity of the aerosol generating device for piercing the second compartment of the aerosol generating article.
[00133] In particularly preferred embodiments, the aerosol generating article comprises: a housing comprising: an air inlet; a first compartment in communication with the air inlet, the first compartment comprising a first of a source of nicotine and a source of the volatile distribution enhancing compound; a second compartment in communication with the first compartment, the second compartment comprising a second of the source of nicotine and the source of the volatile distribution enhancing compound; and an air outlet, in which the air inlet and air outlet are in communication with each other and are configured so that air can pass through the housing through the air inlet, through the housing and out of the housing through the outlet of air.
[00134] As used herein, the term "air inlet" is used to describe one or more openings through which air could be drawn into the aerosol generating article.
[00135] As used herein, the term "air outlet" is used to describe one or more openings through which air can be drawn out of the aerosol generating article.
[00136] In such embodiments, the first compartment and the second compartment are arranged in series from the air inlet to the air outlet inside the housing. That is, the first compartment is downstream of the air inlet, the second compartment is downstream of the first compartment and the air outlet is downstream of the second compartment. When in use, an air flow is drawn into the housing through the air inlet downstream through the first compartment and the second compartment and out of the housing through the air outlet.
In these embodiments, the first compartment may preferably comprise the source of nicotine and the second compartment may preferably comprise the source of the delivery enhancing compound.
[00138] The aerosol generating article may further comprise a third compartment in communication with: the second compartment and the air outlet. During use in such embodiments, an air flow is drawn into the housing through the air inlet, downstream through the first compartment, second compartment and third compartment, and out of the housing through the air outlet.
[00139] The aerosol generating article may further comprise a mouthpiece in communication with: the second compartment, or the third compartment, when present; and the air outlet. During use in such embodiments, an air flow is drawn into the housing through the air inlet, downstream through the first compartment, the second compartment, the third compartment, where present, and the mouthpiece and out of the housing through the air outlet.
[00140] In other preferred embodiments, the aerosol generating article comprises: a housing comprising: an air inlet; a first compartment in communication with the air inlet, the first compartment comprising a source of nicotine; a second compartment in communication with the air inlet, the second compartment comprising a source of distribution enhancing compound; and an air outlet, in which the air inlet and air outlet are in communication with each other and are configured so that air can pass through the housing through the air inlet, through the housing and out of the housing through the outlet of air.
[00141] In such embodiments, the first compartment and the second compartment are arranged in parallel from the air inlet to the air outlet inside the housing. The first compartment and the second compartment are both downstream of the air inlet and upstream of the air outlet. During use, an air flow is drawn into the housing through the air inlet, a first part of the air flow is drawn downstream through the first compartment and a second part of the air flow is drawn downstream through the second compartment.
[00142] The aerosol generating article may further comprise a third compartment in communication with: the first compartment and/or the second compartment; and the air outlet.
[00143] The aerosol generating article may further comprise a mouthpiece in communication with: the first compartment and the second compartment, or the third compartment, when present; and the air outlet.
[00144] In still other preferred embodiments, the aerosol generating article comprises: a housing comprising: a first air inlet; a second air intake; a first compartment in communication with the first air inlet, the first compartment comprising a source of nicotine; a second compartment in communication with the second air inlet, the second compartment comprising a source of the distribution-enhancing compound; and an air outlet, wherein the first air inlet, the second air inlet and the air outlet are in communication with each other and are configured so that air can pass through the housing through the first air inlet, through the housing and out of the housing through the air outlet and so that air can pass through the housing through the first air inlet, through the housing and out of the housing through the air outlet.
[00145] In such embodiments, the first compartment and the second compartment are arranged in parallel within the housing. The first compartment is downstream of the first air inlet and upstream of the air outlet and the second compartment is downstream of the second air inlet and upstream of the air outlet. During use, the first air flow is drawn into the housing through the first air inlet and downstream through the first compartment and a second air flow is drawn into the housing through the second air inlet and the downstream through the second compartment.
[00146] The aerosol generating article may further comprise a third compartment in communication with: the first compartment and/or the second compartment; and the air outlet.
[00147] The aerosol generating article may further comprise a mouthpiece in communication with: the first compartment and the second compartment, or the third compartment, when present; and the air outlet.
[00148] The aerosol generating article housing can simulate the shape and dimensions of a tobacco smoking article, such as a cigarette, a cigar, a cigarillo or a pipe, or a pack of cigarettes. In a preferred embodiment, the carcass simulates the shape and dimensions of a cigarette.
[00149] When present, the third compartment may comprise one or more aerosol modifying agents. For example, the third compartment can comprise an adsorbent such as activated carbon, a flavoring such as menthol, or a combination thereof.
[00150] When present, the nozzle may comprise a filter. The filter may have low particulate filtration efficiency or very low particulate filtration efficiency. Alternatively, the mouthpiece may comprise a hollow tube.
[00151] The aerosol generating article preferably comprises a source of volatile distribution enhancing compound. As used herein, by "volatile" is meant the distribution enhancing compound has a vapor pressure of at least about 20 Pa. Unless otherwise indicated, all vapor pressures referred to herein are vapor pressures at 25°C. °C, measured in accordance with ASTM E1194 - 07.
Preferably, the volatile distribution enhancing compound has a vapor pressure of at least about 50 Pa, more preferably at least about 75 Pa, most preferably at least 100 Pa at 25°C.
Preferably, the volatile distribution enhancing compound has a vapor pressure less than or equal to about 400 Pa, more preferably less than or equal to about 300 Pa, even more preferably less than or equal to about 275 Pa, plus preferably less than or equal to about 250 Pa at 25°C.
In certain embodiments, the volatile distribution enhancing compound can have a vapor pressure between about 20 Pa and about 400 Pa, more preferably between about 20 Pa and about 300 Pa, even more preferably between about 20 Pa. Pa and about 275 Pa, more preferably between about 20 Pa and about 250 Pa at 25°C.
[00155] In other embodiments, the volatile distribution enhancing compound may have a vapor pressure between about 50 Pa and about 400 Pa, more preferably between about 50 Pa and about 300 Pa, even more preferably between about about 50 Pa and about 275 Pa, more preferably between about 50 Pa and about 250 Pa at 25°C.
In further embodiments, the volatile distribution enhancing compound may have a vapor pressure between about 75 Pa and about 400 Pa, more preferably between about 75 Pa and about 300 Pa, even more preferably between about 75 Pa and about 275 Pa, more preferably between about 75 Pa and about 250 Pa at 25°C.
In further embodiments, the volatile distribution enhancing compound may have a vapor pressure between about 100 Pa and about 400 Pa, more preferably between about 100 Pa and 300 Pa, even more preferably between about 100 Pa Pa and about 275 Pa, more preferably between about 100 Pa and about 250 Pa at 25°C.
The volatile distribution enhancing compound may comprise a single compound. Alternatively, the volatile distribution enhancing compound can comprise two or more different compounds.
Where the volatile distribution enhancing compound comprises two or more different compounds, the two or more different compounds combined will preferably have a vapor pressure of at least about 20 Pa at 25°C.
[00160] Preferably, the distribution enhancing compound is a volatile liquid.
[00161] The distribution enhancing compound may comprise a mixture of two or more different liquid compounds.
The distribution-enhancing compound may comprise an aqueous solution of one or more compounds. Alternatively, the delivery-enhancing compound can comprise a non-aqueous solution of one or more compounds.
[00163] The distribution enhancing compound may comprise two or more different volatile compounds. For example, the delivery enhancing compound can comprise a mixture of two or more different volatile liquid compounds.
[00164] Alternatively, the distribution enhancing compound may comprise one or more non-volatile compounds and one or more volatile compounds. For example, the delivery enhancing compound can comprise a solution of one or more nonvolatile compounds in a volatile solvent or a mixture of one or more liquid nonvolatile compounds and one or more liquid volatile compounds.
In certain embodiments, the distribution-enhancing compound comprises an acid. The delivery-enhancing compound may comprise an organic acid or an inorganic acid. Preferably, the delivery enhancing compound comprises an organic acid, more preferably a carboxylic acid, most preferably an alpha-keto or 2-oxo acid.
[00166] In certain preferred embodiments, the distribution enhancing compound comprises an acid selected from the group consisting of 3-methyl-2-oxopentanoic acid, pyruvic acid, 2-oxopentanoic acid, 4-methyl-2-oxopentanoic acid, 3-methyl-2-oxobutanoic acid, 2-oxo-octanoic acid and combinations thereof. In certain particularly preferred embodiments, the delivery enhancing compound comprises pyruvic acid.
In certain preferred embodiments, the source of the distribution enhancing compound comprises a sorption element and a distribution enhancing compound sorbed onto the sorption element.
[00168] As used herein, by "sorbed" it is meant that the distribution enhancing compound is adsorbed onto the surface of the sorption element, or adsorbed onto the sorption element, or adsorbed onto and absorbed onto the sorption element. Preferably, the distribution enhancing compound is adsorbed onto the sorption element.
[00169] The sorption element can be formed from any suitable material or combination of materials. For example, the absorption element can comprise one or more of glass, stainless steel, aluminum, polyethylene (PE), polypropylene, polyethylene terephthalate (PET), polybutylene terephthalate (PBT), polytetrafluoroethylene (PTFE), expanded polytetrafluoroethylene (ePTFE) ) and BAREX®.
[00170] In a preferred embodiment, the sorption element is a porous sorption element.
[00171] For example, the sorption element may be a porous sorption element comprising one or more materials selected from the group consisting of porous plastic materials, porous polymeric fibers and porous glass fibers.
[00172] The sorption element is preferably chemically inert towards the distribution enhancing compound.
[00173] The sorption element can be of any suitable size and shape.
[00174] In certain preferred embodiments, the sorption element is a substantially cylindrical plug. In a particularly preferred embodiment, the sorption element is a substantially cylindrical porous plug.
[00175] In other preferred embodiments, the sorption element is a substantially cylindrical hollow tube. In another particularly preferred embodiment, the sorption element is a substantially cylindrical porous hollow tube.
[00176] The size, shape and composition of the sorption element can be chosen to allow a desired amount of the distribution-enhancing compound to be sorbed onto the sorption element.
[00177] In certain preferred embodiments, between about 20 µl and about 200 µl, more preferably between about 40 µl and about 150 µl, most preferably between about 50 µl and about 100 µl of the delivery enhancing compound are sorbed onto the absorption element.
[00178] The sorption element advantageously acts as a reservoir for the distribution enhancing compound.
The nicotine source may comprise one or more of nicotine, nicotine base, a nicotine salt, such as nicotine-HCl, nicotine bitartrate, or nicotine ditartrate, or a nicotine derivative.
[00180] The source of nicotine can comprise natural nicotine or synthetic nicotine.
[00181] The source of nicotine may comprise pure nicotine, a solution of nicotine in an aqueous or non-aqueous solvent or a liquid tobacco extract.
[00182] The nicotine source may further comprise an electrolyte-forming compound. The electrolyte forming compound can be selected from the group consisting of alkali metal hydroxides, alkali metal oxides, alkali metal salts, alkaline earth metal oxides, alkaline earth metal hydroxides and combinations thereof.
[00183] For example, the nicotine source may comprise an electrolyte-forming compound selected from the group consisting of potassium hydroxide, sodium hydroxide, lithium oxide, barium oxide, potassium chloride, sodium chloride, carbonate sodium, sodium citrate, ammonium sulfate and combinations thereof.
In certain embodiments, the nicotine source can comprise an aqueous solution of nicotine, nicotine base, a nicotine salt or a nicotine derivative, and an electrolyte-forming compound.
Alternatively or additionally, the nicotine source may further comprise other components including, but not limited to, natural flavors, artificial flavors and antioxidants.
[00186] The nicotine source may comprise an sorption element and nicotine sorbed on the sorption element.
[00187] The aerosol generating article is preferably substantially cylindrical in shape.
[00188] The aerosol generating article may have a cross section of any suitable shape.
[00189] Preferably, the aerosol generating article is of substantially circular cross-section or of substantially elliptical cross-section. Most preferably, the aerosol generating article is of substantially circular cross-section.
[00190] The aerosol generating article can simulate the shape and dimensions of a smoking tobacco article, such as a cigarette, a cigar, a cigarillo or a pipe, or a pack of cigarettes. In a preferred embodiment, the aerosol generating article simulates the shape and dimensions of a cigarette.
[00191] For the avoidance of doubt, the features described above in relation to one embodiment of the invention may also be applicable to another embodiment of the invention. In particular, the characteristics described above in relation to aerosol generating devices according to the invention also refer, where appropriate, to aerosol generating systems according to the invention and vice versa.
[00192] The invention will be described below with reference to the attached figures in which:
[00193] Figure 1 shows a schematic longitudinal cross-section of an aerosol generating system according to a first embodiment of the invention with the retractable cover of the aerosol generating device in the first position;
[00194] Figure 2 shows a schematic longitudinal cross-section of the aerosol generating system according to the first embodiment of the invention shown in Figure 1 with the retractable cover of the aerosol generating device being moved to the second position;
[00195] Figure 3 shows a schematic longitudinal cross-section of an aerosol generating system according to the first embodiment of the invention shown in Figure 2 with the retractable cover of the aerosol generating device automatically returning to the first position from the second position ; and
[00196] Figure 4 shows the mechanically actuated means to automatically return the retractable cover of the aerosol generating device of the aerosol generating system according to the first embodiment of the invention, shown in Figures 1-3, from the second position to the first position .
[00197] Figure 1 schematically shows an aerosol generating system according to a first embodiment of the invention comprising an aerosol generating article 2 and an aerosol generating device 4.
[00198] The aerosol generating article 2 has an elongated cylindrical shape and comprises a housing comprising a first compartment 6 comprising a source of nicotine, a second compartment 8 comprising a source of delivery enhancing compound, and a third compartment 10 (shown by the dashed lines in Figure 1). The first compartment 6, the second compartment 8 and the third compartment 10 are arranged serially and in coaxial alignment within the aerosol generating article 2. The first compartment 6 is located at the distal or upstream end of the aerosol generating article 2. the second compartment 8 is located immediately downstream and abuts the first compartment 6. The third compartment 10 is located downstream of the second compartment 8 at the proximal or downstream end of the aerosol generating article 2. Instead of or in addition to the third compartment 10, the aerosol generating article 2 may comprise a mouthpiece at the proximal or downstream end thereof.
[00199] The upstream and downstream ends of the first compartment 6 and the second compartment 8 of the aerosol generating article 2 are sealed by frangible barriers (not shown). A heat transfer barrier (not shown) may be provided between the first compartment 6 and the second compartment 8 to reduce heat transfer between the nicotine source and the aerosol generating article delivery enhancing compound source.
[00200] The aerosol generating device 4 comprises a housing 12 comprising an elongated cylindrical cavity in which the aerosol generating article 2 is received, a retractable cover 14, a heat exchanger 16, first solid-phase change material. liquid 18 and a second solid-liquid phase change material 20.
The aerosol generating device 4 further comprises a piercing member 22 positioned centrally within the cavity of the aerosol generating device 4 and extending along the main axis of the cavity.
[00202] As shown in Figure 1, the length of the cavity is less than the length of the aerosol generating article 2 so that the proximal or downstream end of the aerosol generating article 2 projects from the cavity.
[00203] In the aerosol generating system, according to the first embodiment of the invention, the first solid-liquid phase change material 18 is positioned on the perimeter of the cavity and extends partially along the length of the cavity and fully along the cavity. around the circumference of the cavity. The second solid-liquid phase change material 20 is positioned upstream of the first solid-liquid phase change material 18 at the distal or upstream end of the cavity.
[00204] The heat exchanger 16 comprises a first part 24 close to the cavity comprising a thermally conductive hollow tube and a second distal part 26 of the cavity comprising an array of thermally conductive fins. The thermally conductive hollow tube of the first part 24 of the heat exchanger 16 is in thermal contact with the thermally conductive fin array of the second part 26 of the heat exchanger 16. As shown in Figure 1, the thermally conductive hollow tube of the first part 24 of the heat exchanger 16 surrounds the distal or upstream end of the first solid-liquid phase change material 18 and the second solid-liquid phase change material 20.
[00205] During use, as the aerosol generating article 2 is inserted into the cavity of the aerosol generating device 4, the piercing member 22 of the aerosol generating device 4 is inserted into the aerosol generating article 2 and pierces the frangible barriers ( not shown) at the upstream and downstream ends of the first compartment 6 and second compartment 8 of the aerosol generating article 2. This allows a user to draw air into the casing of the aerosol generating article 2 through the distal end or upstream thereto, downstream through the first compartment 6, the second compartment 8 and the third compartment 10 and out of the housing through the proximal or downstream end thereof.
[00206] After the aerosol generating article 2 is inserted into the cavity of the aerosol generating device 4, the user pulls the retractable cover 14 of the aerosol generating device 4 in the direction indicated by the arrow in Figure 2 to move the retractable cover 14 from from the first position shown in Figure 1, in which the retractable cover 14 covers the matrix of the thermally conductive fins of the second part 26 of the heat exchanger 16, to the second position shown in Figure 2, in which the matrix of the thermally conductive fins of the second part 26 of heat exchanger 16 is exposed to be heated by a lighter.
[00207] Since the retractable cover 14 is in the second position shown in figure 2, the user heats the matrix of the thermally conductive fins of the second part of the heat exchanger 16 using a blue flame lighter or torch type. Thermal energy captured from the lighter by the matrix of the thermally conductive fins of the second part 26 of the heat exchanger 16 is transferred from the matrix of the thermally conductive fins of the second part 26 of the heat exchanger 16 to the first solid-liquid phase change material 18 through the hollow conductive tube of the first part 24 of the heat exchanger 16. Thermal energy is absorbed by the first solid-liquid phase change material 18, causing the temperature of the first solid-liquid phase change material 18 increase. When the temperature reaches the melting temperature of the first solid-liquid phase change material 18, the first solid-liquid phase change material 18 stores thermal energy as it phases from a solid to a liquid.
[00208] Once liquid, the temperature of the first solid-liquid phase change material 18 will continue to increase after further heating the thermally conductive fin matrix of the second part 26 of the heat exchanger 16 by the blue or type flame lighter torch. However, when the temperature of the first solid-liquid phase change material 18 reaches the melting temperature of the second solid-liquid phase change material 20, the second solid-liquid phase change material 20 will store energy thermal as it changes phase from a solid to a liquid. This stores the amount of thermal energy transferred to the first solid-liquid phase change material 18 and thus prevents the first solid-liquid phase change material 18 from overheating.
[00209] Once the array of thermally conductive fins the second part 26 of the heat exchanger 16 reaches threshold temperature, the retractable cover 14 of the aerosol generating device 4 automatically returns in the direction indicated by the arrow in figure 3, from the second position shown in figure 2, in which the matrix of the thermally conductive fins of the second part 26 of the heat exchanger 16 is exposed, to the first position shown in figure 3, in which the retractable cover 14 covers the matrix of thermally conductive fins of the second part 26 of the heat exchanger 16. The heating of the thermally conductive fin array of the second part 26 of the heat exchanger 16 by a blue flame lighter or torch type is then discontinued.
[00210] As shown in Figure 4, the aerosol generating device 4 comprises mechanically driven means to return the retractable cover 14 automatically from the second position shown in Figure 2 to the first position shown in Figure 3 when the the thermally conductive fins of the second part 26 of the heat exchanger 16 reach a threshold temperature. Particularly, the aerosol generating device 4 comprises an operable spring (not shown) to tilt the retractable cover 14 in the first position and the locking means comprising a thermal bimetallic switch 28 operable to maintain the retractable cover 14 in the second position to the matrix of the thermally conductive fins of the second part 26 of the heat exchanger 16 reach a threshold temperature.
[00211] In the first position, the spring is in a bent configuration. As the user pulls the retractable cover 14 of the aerosol generating device 4 in the direction indicated by the arrow in Figure 2, to move the retractable cover 14 from the first position, shown in Figure 1, to the second position, shown in Figure 2, the spring is stretched from the folded configuration. The retractable cover 14 is held in the second position by the thermal bimetal switch 28, which comprises a bimetallic cantilever (circled in Figure 4) that prevents the stretched spring from contracting.
[00212] The bimetallic cantilever changes shape upon heating and when the matrix of the thermally conductive fins of the second part 26 of the heat exchanger 16 reaches the threshold temperature, the bimetallic cantilever bends out of place, thus allowing the spring to stretch. contract to the folded position. Contraction of the spring pulls the retractable cover 14 of the aerosol generating device 4 in the direction indicated by the arrow in figure 3, thus returning the retractable cover 14 from the second position shown in figure 2, in which the matrix of thermally conductive fins of the second part 26 of the heat exchanger 16 is exposed, for the first position shown in Figure 3, in which the retractable cover 14 covers the matrix of the thermally conductive fins of the second part 26 of the heat exchanger 16.
[00213] The threshold temperature is preferably such that heating of the matrix of the thermally conductive fins of the second part 26 of the heat exchanger 16 by the blue flame lighter or torch type is discontinued before the second solid phase change material -liquid 20 complete the phase change from a solid to a liquid. Once heating of the matrix of the thermally conductive fins of the second part 26 of the heat exchanger 16 by the blue flame lighter or torch type is discontinued, the temperature of the first solid-liquid phase change material 18 decreases. After reaching its melting temperature, the first solid-liquid phase change material 18 releases stored thermal energy as it phases from a solid to a liquid. The stored thermal energy released by the first solid-liquid phase change material 18 as it solidifies heats the first compartment 6 of the aerosol generating article 2 received in the cavity of the aerosol generating device 4 for an extended period of time. .
[00214] Once the retractable cover 14 of the aerosol generating device 4 has returned from the second position shown in figure 2 to the first position shown in figure 3, the user draws from the proximal or downstream end of the aerosol generating article 2 to swallow the air through the aerosol generating article.
[00215] As the user draws air through the aerosol generating article 2, the nicotine vapor is released from the nicotine source in the first compartment 6 in the flow of air drawn through the aerosol generating article 2 and the enhancement compound vapor is released from the source of the delivery-enhancing compound in the second compartment 8 into the air flow drawn through the aerosol generating article 2. The nicotine vapor reacts with the vapor from the delivery-enhancing compound in the second gas phase. compartment 8 and in the third compartment 10 to form an aerosol, which is delivered to the user through the proximal or downstream end of the aerosol generating article 2.
[00216] The invention has been exemplified above by reference to an aerosol generating system comprising an aerosol generating article comprising a first compartment and a second compartment arranged in series within the aerosol generating article. However, it will be contemplated that aerosol generating systems in accordance with the invention may comprise aerosol generating articles which comprise a first compartment and a second compartment disposed in parallel within the aerosol generating article.
[00217] The invention has also been exemplified above by reference to an aerosol generating device comprising a heat exchanger configured to heat the first solid-liquid phase change material to a temperature above the melting point of the first change material of solid-liquid phase. However, it will be appreciated that aerosol generating devices in accordance with the invention may include heat exchangers that are configured to heat, directly or indirectly, an aerosol generating article received in the cavity of the aerosol generating device in other ways.
[00218] The invention has also been exemplified above by reference to an aerosol generating system comprising an aerosol generating article comprising a source of nicotine and a source of delivery enhancing compound. However, it will be contemplated that aerosol generating devices in accordance with the invention may be used in cooperation with other types of aerosol generating article.

权利要求:
Claims (18)
[0001]
1. Aerosol generating device (4) for use in an aerosol generating system, the aerosol generating device characterized in that it comprises: a cavity configured to receive an aerosol generating article (2); a heat exchanger (16 ) having a first portion (24) near the cavity and a second portion (26) distal to the cavity for capturing heat from a lighter; and a retractable cover (14), wherein the retractable cover (14) is movable from a first position, in which the retractable cover (14) covers the second part (26) of the heat exchanger (16) to a second position, in which the second part (26) of the heat exchanger (16) is exposed to be heated by a lighter, and in which the retractable cover (14) is configured to automatically return from the second position to the first position when the second part (26) of the heat exchanger (16) reaches a threshold temperature.
[0002]
2. Aerosol generating device (4), according to claim 1, characterized in that the retractable cover (14) is manually movable from the first position to the second position.
[0003]
3. Aerosol generating device (4), according to claim 1 or 2, characterized in that the retractable cover (14) is mobile, moving away from the cavity, from the first position to the second position and mobile, towards the cavity, from the second position to the first position.
[0004]
4. Aerosol generating device (4), according to any one of claims 1 to 3, characterized in that the second part (26) of the heat exchanger (16) comprises a plurality of thermally conductive fins.
[0005]
5. Aerosol generating device (4), according to any one of claims 1 to 4, characterized in that the first part (24) of the heat exchanger (16) comprises one or more thermally conductive hollow tubes.
[0006]
6. Aerosol generating device (4), according to any one of claims 1 to 5, characterized in that the aerosol generating device (4) comprises a thermal bimetallic switch (28).
[0007]
7. Aerosol generating device (4), according to any one of claims 1 to 6, characterized in that it further comprises: a first solid-liquid phase change material (18) positioned on a perimeter of the cavity wherein the first part (24) of the heat exchanger (16) is configured to heat the first solid-liquid phase change material (18) to a temperature above the melting point of the first phase change material of solid-liquid (18).
[0008]
8. Aerosol generating device according to claim 7, characterized in that the first solid-liquid phase change material has a melting point between 30 degrees Celsius and 70 degrees Celsius.
[0009]
9. Aerosol generating device according to claim 7 or 8, characterized in that the solid-liquid phase change material is sodium acetate trihydrate.
[0010]
10. Aerosol generating device (4) according to any one of claims 7 to 9, characterized in that it further comprises: a second solid-liquid phase change material (20), in which the point of melting of the second solid-liquid phase change material is greater than the melting point of the first solid-liquid phase change material.
[0011]
11. Aerosol generating device according to claim 10, characterized in that the melting point of the second solid-liquid phase change material is between 15 degrees Celsius and 25 degrees Celsius higher than the melting point. fusion of the first solid-liquid phase change material.
[0012]
12. Aerosol generating device according to claim 10 or 11, characterized in that the first solid-liquid phase change material has a melting point between 70 degrees Celsius and 90 degrees Celsius.
[0013]
13. Aerosol generating device according to any one of claims 10 to 12, characterized in that the second solid-liquid phase change material is hexatriacontane.
[0014]
14. Aerosol generating system characterized in that it comprises: an aerosol generating device (4), as defined in any one of claims 1 to 13; and an aerosol generating article (2).
[0015]
15. Aerosol generating system according to claim 14, characterized in that the aerosol generating article (2) comprises: a source of nicotine; and a source of distribution enhancement compound.
[0016]
An aerosol generating system according to claim 15, characterized in that the distribution enhancing compound comprises an acid.
[0017]
17. Aerosol generating system according to claim 16, characterized in that the acid is a pyruvic acid.
[0018]
18. Aerosol generating system, according to any one of claims 15 to 17, characterized in that the aerosol generating article (2) comprises: a first compartment (6) comprising the source of nicotine; and a second compartment (8) comprising the source of delivery enhancing compound, and wherein the aerosol generating device (4) further comprises: a piercing member (22) positioned within the cavity for piercing the first compartment (6) and the second compartment (8) of the aerosol generating article (2).

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RU2665438C1|2018-08-29|

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法律状态:
2020-02-11| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|

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2021-04-06| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|

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2021-06-15| B16A| Patent or certificate of addition of invention granted|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 15/12/2014, OBSERVADAS AS CONDICOES LEGAIS. |

优先权:

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申请号 | 申请日 | 专利标题

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EP13197483.4|2013-12-16|

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EP13197483|2013-12-16|

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