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    • 专利摘要:
    refrigerator door/window. The present invention relates to refrigerator doors (which include freezer doors) for use in display areas where refrigerated merchandise (eg frozen or chilled food) is displayed. The aim is to increase the energy efficiency of the doors and thus of the cooled screen system, while reducing the visible reflectance of the doors to make it easier for consumers to see the merchandise being displayed behind the transparent doors. Refrigerator doors in accordance with certain exemplary embodiments of the present invention include one or more air coatings, some of which may include a transparent conductive layer (e.g., ito) to also function as a low e.g.
    公开号:BR112015012505B1
    申请号:R112015012505-0
    申请日:2013-11-21
    公开日:2021-06-22
    发明作者:David D. Mclean；Jose Nunez-Regueiro
    申请人:Guardian Glass, LLC；
    IPC主号:
    专利说明:

    FIELD OF THE INVENTION
    [0001] Certain exemplary embodiments of the present invention refer to the refrigerator/freezer doors/windows and/or manufacturing methods thereof. Exemplary embodiments of the present invention relate to refrigerator/freezer doors/windows that include at least one coating that functions as both an anti-reflective (AR) coating and a low emissivity (low E) coating. In certain exemplary embodiments, the coating may include an indium tin oxide (ITO) layer or including the same disposed between at least a first silicon oxynitride dielectric layer or including the same and a second silicon oxide dielectric layer. silicon or that includes it. BACKGROUND AND SUMMARY OF EXEMPLARY MODALITIES OF THE INVENTION
    [0002] Refrigerator doors are known in the art. For example, see U.S. Patent Document Nos. 2010/0209730 and 2012/0090246, the description of which is incorporated herein by reference.
    [0003] Refrigerator dealers often display food products in a product display area. In order to reduce the amount of heat entering the refrigerated area, they often include glass doors that also provide visibility and accessibility for consumers. Since glass is an inefficient thermal insulator, such doors often include two or three separate sheets of glass with one or two spaces between them to increase the door's thermal insulation. Thus, current refrigerator doors can often be designed to include one or two insulating units made of glass (IGUs).
    [0004] Due to the need to increase the energy efficiency of refrigerated display systems, increased thermal insulation of the IGU can be achieved by using low emissivity (low E) coatings on one or more internal surfaces of the IGU. In an application known as “retrofit,” refrigerated screens opened in food stores (ie screens without glass doors) can be retrofitted to single-pane type glass doors in order to minimize thermal loss from the area. refrigerated, thereby increasing the energy efficiency of the system. An unintended consequence of the provision of glass doors in refrigerated display areas is the loss or reduction in impulse sales, as consumers now have a physical barrier between the merchandise and them. In this sense, the increase in visible reflectance, which typically occurs when glass doors are provided in a refrigerated display area, increases distortion and makes merchandise (eg food) behind the doors difficult to be clearly seen by shoppers - this leads to a reduction in impulse sales.
    [0005] Unfortunately, an unintended consequence of this approach involves the rapid loss of light transmission through the IGU as more glass plates and more low E coatings are incorporated. This, in turn, results in a decrease in the market value of the door.
    [0006] In this way, it will be understood that there is a need, in the art, to increase the energy efficiency of the IGUs that make up the refrigerator doors and at the same time to increase the transmission of visible light through them, and methods of production thereof .
    [0007] US Patent Document No. 2012/0090246 describes a three plate refrigerator door which includes AR coatings and low E coatings. However, separate low E and silver based coatings such as those of The '246 patent document utilizes an entire available surface of a glass substrate which could otherwise be used for an AR coating. Therefore, in certain exemplary embodiments of the present invention, it is desirable to provide a solution that, at least in some cases, combines an infrared (IR), reflective, and low-E layer with an AR layer structure in a single coating.
    [0008] In certain exemplary embodiments of the present invention, refrigerator doors/windows (which includes freezer doors/windows) are provided for use in display areas where refrigerated merchandise (eg, frozen or chilled food) is displayed . It is desired to increase the energy efficiency of the doors and thus of the cooled screen system, while at the same time reducing the visible reflectance of the doors to make it easier for consumers to see the merchandise being displayed behind the transparent doors. Refrigerator doors (which include windows), in accordance with certain exemplary embodiments of the present invention, include one or more AR coatings, some of which may include a transparent conductive layer (e.g., ITO) that reflects IR to also function as a a Low E coating. Enhancements can be achieved by combining AR functionality and Low E functionality in one coating. It is also possible that low iron type glass can be used in doors in certain exemplary cases , which makes the doors even more transparent to visible light.
    [0009] In certain exemplary embodiments of the present invention, a transparent cooler door/window is provided, which comprises: at least first and second glass substrates; a combination of anti-reflective and low-E coatings on an interior surface of the first glass substrate so that the coating is not exposed to a refrigerated environment adjacent to the refrigerator door/window or a room environment adjacent to the refrigerator door/window; in which the coating comprises a transparent conductive layer composed of or consisting essentially of indium tin oxide (ITO) and which is located at least between a dielectric layer composed of or consisting essentially of silicon oxynitride and a dielectric layer composed of or consisting essentially of silicon oxide, and in which the dielectric layer composed of silicon oxynitride is located at least between the first glass substrate and the transparent conductive layer composed of ITO.
    [0010] In certain exemplary embodiments of the present invention, a transparent cooler door/window is provided, which comprises: at least first and second glass substrates; a combination of anti-reflective and low-E coatings on an interior surface of the first glass substrate so that the coating is not exposed to a refrigerated environment adjacent to the refrigerator door/window or a room environment adjacent to the refrigerator door/window; wherein the coating comprises an IR reflective conductive transparent oxide layer having a refractive index of 1.8 to 2.0 which is located at least between a first dielectric layer having a refractive index of 1.65 to 1. 85 and a second dielectric layer having a refractive index of 1.5 to 1.7, and in which the first dielectric layer is located at least between the first glass substrate and the conductive transparent oxide layer; and wherein the conductive transparent oxide layer has a refractive index (n) at least 0.1 higher than the respective refractive indices of the first and second dielectric layers.
    [0011] In certain exemplary embodiments of the present invention, a transparent cooler door/window is provided, which comprises: a glass substrate; first and second coatings on opposite main surfaces of the glass substrate; in which the first coating is an anti-reflective coating or a low-E coating; and in which the second coating is a combination of anti-reflective and low-E coatings comprising a transparent conductive layer composed of ITO that is located at least between a dielectric layer composed of silicon oxynitride and a dielectric layer composed of silicon oxide, and wherein the dielectric layer composed of silicon oxynitride is located at least between the glass substrate and the transparent conductive layer composed of ITO. BRIEF DESCRIPTION OF THE DRAWINGS
    [0012] These and other features and advantages may be better and more fully understood by referring to the following detailed description of illustrative and exemplary modalities, in conjunction with the drawings, in which:
    [0013] Figure 1(a) is a cross-sectional view illustrating a refrigerator door in accordance with an exemplary embodiment of the present invention;
    [0014] Figure 1(b) is a cross-sectional view illustrating a refrigerator door according to another exemplary embodiment of the present invention;
    [0015] Figure 2 is a cross-sectional view illustrating a refrigerator door according to another exemplary embodiment of the present invention;
    [0016] Figure 3 is a cross-sectional view illustrating a refrigerator door according to another exemplary embodiment of the present invention;
    [0017] Figure 4 is a cross-sectional view illustrating a coating according to an exemplary embodiment of the present invention, where the coating has both AR functionality and low E functionality. DETAILED DESCRIPTION OF THE EXEMPLARY MODALITIES OF THE INVENTION
    [0018] More particular reference will now be made to the drawings, in which like reference numerals indicate like parts/elements throughout the various views.
    [0019] In certain exemplary embodiments of the present invention, refrigerator doors (which include freezer doors) 100 are provided for use in display areas where refrigerated merchandise (e.g., frozen or chilled food) is displayed. It is desired to increase the energy efficiency of the doors and thus of the refrigerated screen system and at the same time reduce the visible reflectance of the doors to make it easier for consumers to see the merchandise being displayed behind the transparent doors 100. The doors cooler (which includes windows) 100 in accordance with certain exemplary embodiments of the present invention include one or more AR coatings (e.g., 7a, 7b, 7c, 9a, 9b), at least one/some of which (7a, 7b) , 7c) include a transparent conductive layer (eg made from or including ITO) to also function as a low E coating. Enhancements can be achieved by combining it into a coating (eg 7a, 7b, 7c) , the AR functionality and the low E functionality. It is also possible that a glass of the low iron content type (1, 2 and/or 3) can be used in the 100 ports in certain exemplary cases, which makes the ports of cooler 100 even more s transparent to visible light. In certain exemplary embodiments, the AR/low-E coating combination (7a, 7b, and/or 7c) may include an IR reflective layer 20 made of or including indium tin oxide (ITO) disposed between at least one first dielectric layer made of or including silicon oxynitride 23 and a second dielectric layer made of or including silicon oxide 25 (for example, see Figure 4). In certain exemplary embodiments, two such AR/low-E coatings in combination 7a, 7b are provided on the refrigerator door (eg see Figures 1(a), 2 and 3). In other exemplary embodiments, three such AR/low-E liners in E-combination 7a, 7b and 7c are provided on the refrigerator door (for example, see figure 1(b)). In still other exemplary embodiments, only such a combination of AR/Low E 7a coatings can be provided on the refrigerator door (for example, see Figures 2-3).
    [0020] Figures 1(a), 1(b), 2 and 3 illustrate refrigerator doors/windows in accordance with various embodiments of the present invention, the doors including AR coatings 9a, 9b, low E 11 coatings and AR coatings /low E in combination E 7a, 7b, 7c. For example, the transparent refrigerator door of Figures 1(a)-(b) includes three glass substrates 1, 2 and 3 which are spaced apart by spacers 4 so that air gaps 5 are defined between adjacent substrates. Warm edge spacers 4 may be provided around the periphery of substrates 1-3, for example, to help keep substrates 1-3 spaced apart in a substantially parallel relationship to each other. Air gaps 5 can optionally be filled with gas such as argon, xenon or similar. Each glass substrate 1, 2 and 3 can be between about 1 and 8 mm thick, more preferably from about 2 and 6 mm thick. Floatable glass substrates, which are based on soda-lime glass, are used in the exemplary embodiments of the present invention.
    [0021] In Figure 1(a), for example, the AR/Low E coating combination 7a is provided over (directly or indirectly) the inner surface 1a of outer glass substrate 1 and the AR/Low coating combination And 7b is provided on (directly or indirectly) the inner surface 3a of inner glass substrate 3. However, the AR coating 9a (which has no metallic or reflective IR TCO layer) is provided on an inner surface main 2a of inner glass substrate 2 and the AR coating 9b (which has no metallic or IR TCO reflective layer) is provided on the other main inner surface 2b of inner glass substrate 2. An "inner" surface of a Refrigerator door/window glass substrate here is defined as the surface not directly facing the refrigerated environment or the room environment environment. Thus, in Figure 1(a)-(b) and 3, for example, surfaces 1a, 2a, 2b and 3a are interior substrate surfaces of the glass substrate, while surfaces 1b and 3b are exterior substrate surfaces.
    [0022] In figure 1(b), for example, combination AR/low-E coating 7a is provided over (directly or indirectly) the outer surface 1b of glass substrate 1, the AR/low-E coating 7b is provided over (directly or indirectly) the inner surface 2a of the glass substrate 2, and the AR/Low E coating 7c is provided over (directly or indirectly) the inner surface 3a of the inner glass substrate 3. However, the AR coating 9a (which has no metallic or IR TCO reflective layer) is provided on the inner surface 2b of inner glass substrate 2 and the low E coating 11 (which has one or more Ag-based IR reflective layers ) is provided on the inner surface 1a of the glass substrate 1.
    [0023] Exemplary AR/low-E coatings in combination E 7a, 7b, 7c, AR coatings 9a, 9b and low E coatings 11, which can be used in figures 1-3, are described below.
    [0024] Figure 4 is a cross-sectional view of an exemplary coating, which is a combination of AR/low-E coatings 7 that can be used for one, two or all three of AR/low-E coatings in combination. 7a, 7b and 7c in Figures 1(a), 1(b), 2 and 3. The coating can be deposited by sputtering in the exemplary embodiments. In this embodiment, the transparent dielectric layer 23 adjacent to the glass substrate (1, 2 or 3) is made of or includes silicon oxynitride, the conductive, transparent and reflective IR layer 20 is a transparent conductive oxide (TCO) made of or which includes indium tin oxide (ITO), and the transparent dielectric layer 25 is made of or includes silicon oxide (eg, SiO2). Any silicon nitride or silicon oxynitride inclusive layer (e.g., layer 23) herein may optionally be doped with a metal, such as aluminum, in certain exemplary embodiments. For example, the silicon oxynitride layer 23 can be doped with about 0.5-10% aluminum, more preferably from about 2-6% aluminum (atomic% for all these percentages here) in the exemplary modalities.
    [0025] In the combination of AR/low-E coatings, layers 23 and 25 are provided for AR purposes, while the transparent conductive layer 20 is provided for low-E IV reflection purposes. Thus, the coating 7 (i.e., 7a, 7b, and/or 7c) functions as both a Low E coating and an AR coating for the reasons explained here. The silicon oxide layer 25 preferably has a refractive index (n) of from about 1.5 to 1.7, more preferably from about 1.5 to 1.6, in the exemplary embodiments of present invention. Silicon oxynitride layer 23 preferably has a refractive index (n) of from about 1.65 to 1.85, more preferably from about 1.65 to 1.75, in the exemplary embodiments of present invention. And the inclusive ITO layer 20 preferably has a higher refractive index than layers 23 and 25, in providing an AR-type layer structure for the coating 7. The ITO layer 20 preferably has an index refractive index (n) at least about 0.2 or 0.1 higher than layers 23 and 25. In exemplary embodiments, the ITO layer 20 has a refractive index (n) of about 1.8 to 2.0, more preferably from about 1.85 to 1.95, with an exemplary index being about 1.9. The refractive index ranges here (measured at a wavelength of 450 nm) of the layers shown in figure 4 allow the coating 7 to function as an AR coating (in addition to having low E properties), and in exemplary embodiments a coating (7a, 7b or 7c) reduces the visible reflex by approximately 2.5 to 4.0% (eg approximately 3.2%) per side/application. In exemplary embodiments of the present invention, the inclusive silicon oxynitride layer 23 is between about 10-150 nm thick, more preferably from about 10-100 nm thick, most preferably from about 10-100 nm thick, most preferably from about 10-100 nm thick. from 20-60 nm thick, and even more preferably from about 30-50 nm thick. In exemplary embodiments of the present invention, silicon oxide inclusive layer 25 may be doped with small amounts of another material (eg, nitrogen and/or aluminum) and is between about 10-200 nm thick, most preferably a from about 40-140 nm thick, and even more preferably from about 70110 nm thick, with an example being about 90 nm thick.
    [0026] In the exemplary embodiments of the present invention, the transparent conductive ITO inclusive layer 20 of the coating 7 (referring to coatings 7a, 7b and 7c) is considerably thick to provide low emissivity and low sheet strength, and at the same time thin the enough to still allow visible transmission through you so that consumers can see the food in the refrigerated area behind the door(s). In exemplary embodiments, the ITO-based layer 20 is between about 60-220 nm thick, more preferably from about 75-180 nm thick, even more preferably from about 90130 nm thick, and more preferably from about 100-120 nm thick (for example, about 90 nm thick). Thus, in exemplary embodiments, the ITO layer 20 has a low sheet strength and at the same time maintains visible transmission of at least about 30%, 40%, 50% or at least about 60%. In exemplary embodiments, the ITO layer 20 (and thus, coating 7) can have an emissivity (normal or hemispherical) of less than or equal to 0.40, more preferably less than or equal to about 0.30, even more preferably less than or equal to about 0.25, with an exemplary emissivity being about 0.2. In exemplary embodiments, the ITO layer 20 (and thus, coating 7) can have a sheet strength (Rs) of less than or equal to about 40 ohms/square, more preferably less than or equal to at about 30 ohms/square, and most preferably less than or equal to about 20 ohms/square. Optionally, layer 23 can be silicon nitride (eg, Si3N4), which can be doped with small amounts of aluminum and/or oxygen, and can have the same thickness ranges discussed above, in connection with layer 23 And optionally, other layers not shown can also be included in the coating. For example, a layer made of or including titanium oxide and a layer made of or including silicon nitride may be provided between the supporting glass substrate and layer 23, with the silicon nitride layer being closer to the glass substrate. This coating, shown in figure 4 and described above, for example, can be used for the combination of low E/AR coatings 7a, 7b and 7c shown in figures 1(a), 1(b), 2 and 3.
    [0027] Table 1 (Exemplary Materials/Thicknesses for coatings 7a, 7b, 7c)

    [0028] To increase the visible transmission of a refrigerator door 100, one or more plates thereof may include a single thin-film coating or a multi-layer anti-reflective (AR) coating 9a, 9b. Exemplary AR coatings 9a and/or 9b are shown on the refrigerator doors of Figures 1(a), 1(b), 2 and 3. Exemplary anti-reflective (AR) coatings 9a, 9b are described, for example, in the US Patent Document US. 7,588,823; 6,589,658; 6,586,102, 12/923,146, 20090148709; 20090133748; 20090101209; 20090032098; and 20070113881, the contents of which are incorporated herein by reference. In certain exemplary embodiments, an estimated increase of approximately 3-4% in visible transmission is achievable when an AR 9a, 9b coating is applied to one side of a 1, 2 or 3 glass substrate and an estimated increase of approximately 6-8 % in visible transmission is achievable when an AR 9a, 9b coating is applied to both sides of a 1, 2, or 3 glass substrate.
    [0029] Exemplary ranges for the thicknesses of each layer in an exemplary AR coating (9a and/or 9b) are as follows, moving away from the supporting glass substrate (1, 2 or 3): Table 2 (Exemplary Materials/ Thicknesses for coatings 9a and 9b)

    [0030] Similar to the table above, low E 11 coatings may also be used in certain exemplary embodiments of the present invention (for example, see Figures 1(b), 2 and 3) and they may be provided with one or more both surfaces of one or more glass substrates. A silver-based low E coating suitable for certain exemplary embodiments of the present invention may be any of the low E coatings described in US Patent Document Nos. 2009/0214880; 2009/0205956; 2010/0075155; 2010/0104840, and 12/662,561, the contents of which are incorporated herein by reference. Exemplary low E 11 silver-based two-layer coatings are described, for example, in US Patent Document Nos. 12/453,125 and 2009/0324934, the contents of which are incorporated herein by reference. Another exemplary low E 11 coating is described in US Patent Publication 2012/0090246 (incorporated herein by reference) and shown graphically as follows with the layers being identified moving away from the supporting glass substrate 1, 2 or 3.Table 3: Exemplary Materials/Thicknesses - Low E 11 Coating(s)


    [0031] To further increase light transmission through the refrigerator door, low iron substrates can optionally be used for one or more of glass substrates 1, 2 and/or 3. Exemplary low iron substrates are described, for example, in US Patent Application Serial No. 12/385,318, as well as in US Publication Nos. 2006/0169316; 2006/0249199; 2007/0215205; 2009/0223252; 2010/0122728; and 2009/0217978, the contents of which are incorporated herein by reference. Exemplary details of a low iron (1, 2 and/or 3) substrate will now be provided. Figures 1(a)-(b) illustrate, for example, exemplary refrigerator doors in accordance with exemplary embodiments of the present invention, which include glass substrates 1, 2, and 3. In certain exemplary embodiments, all three substrates 1-3 can be low iron substrates. In other exemplary embodiments, the center plate 2 can be a low iron content substrate and the other two substrates 1 and 3 can be floatable glass substrates with a higher and thus traditional iron content range. Substrates 1-3 can, however, be mixed and matched between traditional floatable glass substrates and low iron floatable glass substrates in different exemplary embodiments. In certain exemplary embodiments, no low-iron substrates can be provided and in other exemplary embodiments, only low-iron substrates can be provided.
    [0032] As used herein, the terms "on," "supported by" and the like are not to be interpreted to mean that two elements are directly adjacent to each other, unless explicitly stated in this way. In other words, a first layer can be described as “over” or “supported by” a second layer, even if there are one or more layers in between.
    [0033] In certain exemplary embodiments of the present invention, a transparent cooler door/window is provided, which comprises: at least first and second glass substrates; a combination of anti-reflective and low-E coatings on an interior surface of the first glass substrate so that the coating is not exposed to a refrigerated environment adjacent to the refrigerator door/window or a room environment adjacent to the refrigerator door/window; in which the coating comprises a transparent conductive layer composed of or consisting essentially of indium tin oxide (ITO) which is located at least between a dielectric layer composed of or consisting essentially of silicon oxynitride and a dielectric layer composed of or consisting essentially of silicon oxide, and in which the dielectric layer composed of silicon oxynitride is located at least between the first glass substrate and the transparent conductive layer composed of ITO.
    [0034] In the refrigerator door/window of the immediately preceding paragraph, a gap may be provided between the first and second glass substrates. The gap can be filled with air and/or an inert gas.
    [0035] On the refrigerator door/window of either of the two preceding paragraphs, a spacer seal may be provided near one edge of the first and second glass substrates so as to couple the first and second glass substrates together. and provide a gap between them.
    [0036] In the refrigerator door/window of any of the three preceding paragraphs, the refrigerator door/window may have a visible transmission of at least about 50%, more preferably at least about 60%.
    [0037] In the refrigerator door/window of any of the four previous paragraphs, the layer composed of silicon oxynitride can be disposed between and directly contacting the first glass substrate and the transparent conductive layer composed of ITO.
    [0038] In the refrigerator door/window of any of the five previous paragraphs, the layer composed of silicon oxide can directly contact the transparent conductive layer composed of ITO.
    [0039] In the refrigerator door/window of any of the six previous paragraphs, the layer composed of silicon oxide can be the outermost layer of the coating.
    [0040] On the refrigerator door/window of any of the seven preceding paragraphs, the coating may consist essentially of the transparent conductive layer composed of indium tin oxide (ITO), the dielectric layer composed of silicon oxynitride and the dielectric composite layer by silicon oxide.
    [0041] In the refrigerator door/window of any of the eight previous paragraphs, the transparent conductive layer composed of indium tin oxide (ITO) may have a refractive index (n) at least 0.1 higher (more so preferred at least 0.15 higher) than the respective refractive indices of the dielectric layer composed of silicon oxynitride and the dielectric layer composed of silicon oxide.
    [0042] In the refrigerator door/window of any of the previous nine paragraphs, the transparent conductive layer composed of ITO can be from about 60-220 nm thick, more preferably from about 90-130 nm thick.
    [0043] In the refrigerator door/window of any of the ten preceding paragraphs, the second glass substrate may be closer or farther from a refrigerated environment adjacent to the door/window than the first glass substrate.
    [0044] The refrigerator door/window of any of the eleven preceding paragraphs may also comprise a third glass substrate, in which the second glass substrate can be disposed at least between the first and third glass substrates, and in which another combination of anti-reflective and low-E coatings may be disposed on an inner surface of the third glass substrate, in which the other coating may comprise or consist essentially of a transparent conductive layer composed of indium tin oxide (ITO) which is located at least between a dielectric layer composed of silicon oxynitride and a dielectric layer composed of silicon oxide, and in which the dielectric layer composed of silicon oxynitride can be disposed at least between the third glass substrate and the transparent conductive composite layer by ITO of the other coating.
    [0045] On the refrigerator door/window of any of the twelve preceding paragraphs, an anti-reflective coating may be disposed on an interior surface of the second glass substrate.
    [0046] On the refrigerator door/window of any of the thirteen previous paragraphs, a low E coating, which includes at least one IR reflective layer composed of silver, disposed at least between the first and second dielectric layers, can be disposed over an interior surface of the second glass substrate.
    [0047] On the refrigerator door/window of any of the fourteen preceding paragraphs, the coating and/or the other coating may have a sheet resistance of less than or equal to about 30 ohms/square.
    [0048] Although the invention has been described in connection with what is presently considered to be the most practical and preferred embodiment, it should be understood that the invention is not to be limited to the described embodiment, rather it is intended to cover various modifications and arrangements equivalents included in the spirit and scope of the appended claims.
    权利要求:
    Claims (17)
    [0001]
    1. Transparent refrigerator door/window (100), characterized in that it comprises: at least first and second glass substrates (1, 2, 3) of the refrigerator door/window (100), the refrigerator door/window being secured to a cooler housing a refrigerated environment; a combined anti-reflective and low E coating deposited by sputtering (7a, 7b, 7c) onto an interior surface of the first glass substrate (1), so that the sputter deposited coating (7a, 7b, 7c) is not exposed to the refrigerated environment adjacent to the refrigerator door/window or to a room environment adjacent to the refrigerator door/window; wherein the sputter deposited coating (7a, 7b, 7c) comprises a transparent conductive layer (20) comprising indium tin oxide (ITO) which is located at least between a dielectric layer (23) comprising silicon oxynitride and a dielectric layer (25) comprising silicon oxide. silicon, and wherein the dielectric layer (23) comprising silicon oxynitride is located at least between the first glass substrate (1) and the transparent conductive layer (20) comprising ITO.
    [0002]
    2. Refrigerator door/window according to claim 1, characterized in that a gap (5) is provided between the first (1) and second (2) glass substrates.
    [0003]
    3. Door/window of the refrigerator according to claim 2, characterized in that the gap (5) is filled with air and/or an inert gas.
    [0004]
    4. Refrigerator door/window according to any one of claims 1 to 3, characterized in that the layer comprising silicon oxynitride (23) is located between and directly contacting the first glass substrate (1) and the conductive layer transparent (20) comprising ITO.
    [0005]
    5. Refrigerator door/window according to any one of claims 1 to 4, characterized in that the layer comprising silicon oxide (25) may include nitrogen and directly contacts the transparent conductive layer (20) comprising ITO.
    [0006]
    6. Refrigerator door/window according to any one of claims 1 to 5, characterized in that the coating (7a, 7b, 7c) consists essentially of the transparent conductive layer (20) comprising indium-tin oxide (ITO) , in the dielectric layer (23) comprising silicon oxynitride and in the dielectric layer (25) comprising silicon oxide.
    [0007]
    7. Refrigerator door/window according to any one of claims 1 to 6, characterized in that the transparent conductive layer (20) comprising indium tin oxide (ITO) has a refractive index (n) of at least 0, 1 higher than the respective refractive indices of the dielectric layer (23) comprising silicon oxynitride and the dielectric layer (25) comprising silicon oxide.
    [0008]
    8. Refrigerator door/window according to any one of claims 1 to 7, characterized in that the transparent conductive layer (20) comprising indium tin oxide (ITO) has a refractive index (n) of at least 0, 15 higher than the respective refractive indices of the dielectric layer (23) comprising silicon oxynitride and the dielectric layer (25) comprising silicon oxide.
    [0009]
    9. Refrigerator door/window according to any one of claims 1 to 8, characterized in that the glass of the first and/or second glass substrates (1, 2, 3) comprises the following ingredients in the following weight percentages :
    [0010]
    10. Refrigerator door/window according to any one of claims 1 to 9, characterized in that it also comprises a third glass substrate (3), in which the second glass substrate (2) is located at least between the first (1) and third (3) glass substrates, and wherein another combined anti-reflective and low E coating (7b) is located on an interior surface (3a) of the third glass substrate (3), wherein the other coating ( 7b) comprises a transparent conductive layer (20) comprising indium tin oxide (ITO) which is located at least between a dielectric layer (23) comprising silicon oxynitride and a dielectric layer (25) comprising silicon oxide, and wherein the dielectric layer (23) comprising silicon oxynitride is located at least between the third glass substrate (3) and the transparent conductive layer (20) comprising ITO of the other coating.
    [0011]
    11. Refrigerator door/window according to claim 10, characterized in that an anti-reflective coating (7b, 9a) is located on an interior surface of the second glass substrate (2).
    [0012]
    12. Transparent refrigerator door/window (100), characterized in that it comprises: at least the first (1) and second (2) glass substrates; a combined anti-reflective and low-E coating (7a, 7b, 7c) on a interior surface of the first glass substrate (1), so that the coating (7a, 7b, 7c) is not exposed to a refrigerated environment adjacent to the refrigerator door/window or to a room environment adjacent to the refrigerator door/window; wherein the coating (7a, 7b, 7c) comprises an IR reflective and conductive transparent oxide layer (20) having a refractive index of 1.8 to 2.0 which is located between at least a first dielectric layer (23) which has a refractive index of 1.65 to 1.85 and a second dielectric layer (25) which has a refractive index of 1.5 to 1.7, and wherein the first dielectric layer (23) is located at least between the first glass substrate (1) and the conductive transparent oxide layer (20); and wherein the conductive transparent oxide layer (20) has a refractive index (n) at least 0.1 higher than the respective refractive indices of the first and second dielectric layers.
    [0013]
    13. Refrigerator door/window according to claim 12, characterized in that a gap (5) is provided between the first (1) and second (2) glass substrates, wherein the gap is filled with air and /or an inert gas.
    [0014]
    14. Door/window of the refrigerator according to claim 12 or 13, characterized in that the first dielectric layer (23) is located between and directly contacting the first glass substrate (1) and the conductive transparent oxide layer ( 20).
    [0015]
    15. Transparent refrigerator door/window (100) characterized in that it comprises: a glass substrate (2); first (9a) and second (7b) coatings on the main opposite surfaces of the glass substrate (2); first coating (9a) is an anti-reflective coating; and in which the second coating is a combined anti-reflective and low E coating comprising a transparent conductive layer (20) comprising indium tin oxide (ITO) which is located at least between a dielectric layer (23) comprising silicon oxynitride and a dielectric layer (25) comprising silicon oxide, and wherein the dielectric layer (23) comprising silicon oxynitride is located at least between the glass substrate and the transparent conductive layer (20) comprising ITO.
    [0016]
    16. Refrigerator door/window according to claim 15, characterized in that the dielectric layer (23) comprising silicon oxynitride and/or the dielectric layer (25) comprising silicon oxide is doped with aluminum.
    [0017]
    17. Refrigerator door/window according to claim 15, characterized in that the dielectric layer (25) comprising silicon oxide also comprises nitrogen.
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    同族专利:
    公开号 | 公开日
    US9332862B2|2016-05-10|
    MX2015006753A|2015-08-05|
    PL2925193T3|2020-04-30|
    CN105025755B|2020-09-22|
    CN105025755A|2015-11-04|
    BR112015012505A2|2017-07-11|
    US20140154434A1|2014-06-05|
    EP2925193B1|2019-10-30|
    TW201438636A|2014-10-16|
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    EP2925193A1|2015-10-07|
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    法律状态:
    2018-11-21| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|
    2019-12-24| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|
    2020-04-28| B25A| Requested transfer of rights approved|Owner name: GUARDIAN GLASS, LLC (US) |
    2021-05-04| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|
    2021-06-22| B16A| Patent or certificate of addition of invention granted|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 21/11/2013, OBSERVADAS AS CONDICOES LEGAIS. |
    优先权:
    申请号 | 申请日 | 专利标题
    US13/690,133|2012-11-30|
    US13/690,133|US9332862B2|2012-11-30|2012-11-30|Refrigerator door/window|
    PCT/US2013/071147|WO2014085171A1|2012-11-30|2013-11-21|Refrigerator door/window|
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