OPTICAL EFFECT LAYER (OEL), USE AND PROCESS FOR THE PRODUCTION OF THE SAME, OPTICAL EFFECT LAYER COA

专利摘要:
optical effect layer (oel), magnetic field generating device, printing set, use of magnetic field generating devices, optical effect layer (oec) coated substrate, security document, preferably a banknote or an identity document and use of optical effect layer. the invention relates to the field of protecting security documents such as, for example, bank notes and identity documents against forgery and illegal reproduction. in particular, the invention relates to optical effect (oel) layers showing an optical effect dependent angle of view, devices and processes for producing said oil and items carrying said oil, as well as uses of said optical effect layers as a medium anti-counterfeiting in documents. oel comprises a plurality of non-spherical magnetic or magnetizable particles, which are dispersed in a coating composition comprising a binder material, oel comprising two or more loop-shaped areas, being nested around a common central area that is encircled by the innermost loop-shaped area, wherein, in each of the loop-shaped areas, at least a part of the plurality of non-spherical magnetic or magnetizable particles are oriented such that, in a cross section perpendicular to the oel layer, extending from the center of the central area to the outer edge of the outermost loop-shaped area, the longest axis of the particles in each of the cross-sectional areas of the loop-shaped areas follow a tangent of either a negatively curved part or positively curved from hypothetical ellipses or circles.
公开号:BR112015011390B1
申请号:R112015011390-7
申请日:2013-12-20
公开日:2021-06-22
发明作者:Mathieu Schmid；Evgeny Loginov；Claude Alain Despland；Pierre Degott
申请人:Sicpa Holding Sa；
IPC主号:

专利说明:

Field of Invention
[0001] The present invention refers to the field of protection of documents of value and commercial goods of value against illegal reproduction and forgery. In particular, the present invention relates to optical effect layers (OEL) showing an angle-of-view dependent optical effect, devices and processes for producing said OEL and items carrying said OEL, as well as uses of said optical effect layers as a anti-counterfeiting means in documents. Fundamentals of Invention
[0002] It is known in the art to use inks, compositions or layers containing pigments, magnetizable particles or oriented magnetic particles, particularly also optically magnetic variable pigments for the production of security elements, for example, in the field of security documents. Coatings or layers comprising magnetizable or oriented magnetic particles are disclosed, for example, in US 2,570,856; US 3,676,273; US 3,791,864; US 5,630,877 and US 5,364,689. Coatings or layers comprising oriented magnetic color deflection pigment particles, resulting in particularly attractive optical effects, useful for protecting security documents, have been disclosed in WO 2002/090002 A2 and WO 2005/002866 A1 .
[0003] Security features, for example for security documents, can generally be classified into "hidden" security features on the one hand and "visible" on the other hand. The protection provided by hidden security features depends on the concept that such features are difficult to detect, usually requires specialized equipment and knowledge for detection, "visible" security features depend on the concept of being easily detectable with the unaided human senses, for For example, such features can be visible and/or detectable through the tactile sense, while still being difficult to produce and/or copy. However, the effectiveness of visible security features depends to a large extent on their easy recognition as a security feature, because most users, and particularly those who have no prior knowledge of the security features of a protected item or document with this, in fact, they will then only perform a security check based on said security feature if they have real knowledge of its existence and nature.
[0004] A particularly striking optical effect can be achieved if a security feature changes its appearance in view of a change in viewing conditions, such as the viewing angle. Such an effect can, for example, be achieved by optical dynamic appearance change devices (DACODs) such as convex Fresnel type reflective surfaces counted with oriented pigment particles in a hardened coating layer, as disclosed in EP-A 1 710 756 This document describes a way to obtain a printed image that contains pigments or flakes having magnetic properties by aligning the pigments in a magnetic field. The pigments or flakes, after being aligned in a magnetic field, show a Fresnel structure arrangement, such as a Fresnel reflector. By tilting the image and thereby changing the reflection direction towards a viewer, the area showing the greatest reflection to the viewer moves according to the alignment of the flakes or pigments. An example of this structure is the so-called "scroll bar" effect. This effect is currently used for a number of security features in banknotes, such as in the "50" of the South African 50 Rand banknote. However, such scroll bar effects are generally observable if the document security is slanted in a certain direction, that is, up and down or sideways from the viewer's perspective.
[0005] Since Fresnel type reflective surfaces are flat, they provide the appearance of a concave or convex reflective hemisphere. Fresnel-type reflective surfaces can be produced by exposing a wet coating layer comprising non-isotropically reflective magnetizable or magnetic particles to the magnetic field of a single dipole magnet, the latter being disposed above, respectively, below the plane of the coating layer, it has its north-south axis parallel to said plane, and is rotatable about the axis perpendicular to said plane, as illustrated in Figures 37A - 37D of EP-A 1 710 75. The particles thus oriented are consequently fixed in position and orientation by hardening the coating layer.
[0006] Moving ring images showing an apparently moving ring at a shifting angle of view ("rolling ring" effect) are produced by exposing a wet coating layer comprising non-isotropically reflective magnetizable or magnetic particles to the magnetic field of a dipole magnet. WO 2011/092502 discloses images of moving rings that can be obtained or produced by using a device to orient particles in a coating layer. The disclosed device allows the orientation of magnetic or magnetizable particles with the help of a magnetic field produced by the combination of a smooth magnetizable blade and a spherical magnet having its north-south axis perpendicular to the plane of the coating layer and disposed below said magnetizable blade smooth.
[0007] Prior art images of moving rings are generally produced by aligning the magnetic or magnetizable particles according to the magnetic field of just a rotating or static magnet. Since the field lines of just one magnet generally bend relatively smoothly, ie they have a low curvature, also the change in orientation of the magnetic or magnetizable particles is relatively smooth on the surface of the OEL. The magnetic field strength rapidly decreases with increasing distance from the magnet when a single magnet is used. This makes it difficult to obtain a highly dynamic and well-defined aspect through the orientation of the magnetic or magnetizable particles, thus resulting in "ring rolling" effects that can exhibit blurry ring edges. This problem increases with increasing size (diameter) of the "rolling ring" image when only a rotating or static magnet is used.
[0008] Therefore, there remains a need for security features, exhibiting a visually attractive live loop format effect covering an extended area over a document in good quality, which can be easily checked regardless of the orientation of the security document, which is difficult to produce on a mass scale with the equipment available to a counterfeiter, and that can be provided in a large number of possible shapes and forms. Invention Summary
[0009] Consequently, it is an object of the present invention to overcome the deficiencies of the prior art, as discussed above. This is achieved by providing an optical effect layer (OEL) comprising a plurality of nested loop-shaped areas surrounding a common central area, for example, over a document or other item, which exhibits apparent motion dependent on Viewing angle of the image features over an extended length, has good sharpness and/or contrast, and can be easily detected. The present invention provides such optical effect layers (OEL) as an enhanced easy-to-detect hidden security feature, or, in addition or alternatively, as a hidden security feature, for example, in the field of document security. That is, in one aspect the present invention pertains to an optical effect layer (OEL) comprising a plurality of non-spherical magnetizable or magnetic particles, which are dispersed in a coating composition comprising a binder material, the OEL, comprising two or more areas, each having a loop-shaped area (also referred to as loop-shaped areas), the loop-shaped areas being nested around a common central area that is surrounded by the innermost loop-shaped area, where, in each of the nested loop-shaped areas, at least a portion of the plurality of magnetizable or non-spherical magnetic particles are oriented such that, in a cross section perpendicular to the OEL layer and extending from the center of the central area to the boundary outside of the outermost loop-shaped area, the longest axis of the particles in each of the cross-sectional areas of the loop-shaped areas follows a tangent of a part negatively curved or positively curved of hypothetical circles or ellipses.
[010] Also described and claimed in this document are devices for producing the optical effect layers described herein. Specifically, the present invention also relates to a magnetic field generating device, comprising a plurality of elements selected from magnets and pole pieces and comprising at least one magnet, the plurality of elements, both (i) being located below a bearing surface or a space configured to receive a substrate acting as a bearing surface or (ii) forming a bearing surface, and being configured so as to be capable of providing a magnetic field, in which the magnetic field lines run substantially in parallel to said support surface or space in two or more areas above said support surface or space and wherein i) the two or more areas form loop-shaped areas nested around a central area; and/or ii) the plurality of elements comprises a plurality of magnets, and the magnets are arranged rotating about an axis of rotation such that areas with field lines running substantially parallel to the bearing surface or space are combined upon rotation. around the axis of rotation, thus forming, upon rotation about the axis of rotation, a plurality of nested loop-shaped areas surrounding a central area.
[011] Also described and claimed in this document are processes for producing the security element, the optical effect layers comprising it, and uses of the optical effect layers for protection against forgery of a security document or for a decorative application in the graphic arts . Specifically, the present invention relates to a process for producing an optical effect layer (OEL), comprising the steps of: a) applying a composition to a support surface of a magnetic field generating device or to a substrate surface. coating comprising a binder material and a plurality of non-spherical magnetizable or magnetic particles, said coating composition being in a first state (fluid), b) exposing the coating composition in a first state to the magnetic field of a field generating device magnetic, preferably one as defined in any one of claims 9-15, thereby orienting at least a portion of the non-spherical magnetizable or magnetic particles in a plurality of nested loop-shaped areas surrounding a central area such that the longest axis of the particles in each of the cross areas of the loop-shaped areas, each follow a tangent and either a negatively curved or a positively curved part of hypothetical circles or ellipses; and c) stiffening the coating composition to a second state so as to fix the magnetizable or non-spherical magnetic particles in their adopted positions and orientations. d)
[012] These and other aspects are summarized below: 1. An optical effect layer (OEL) comprising a plurality of non-spherical magnetic or magnetizable particles, which are dispersed in a coating composition comprising a binder material, the OEL comprising two or more loop-shaped areas, referred to as loop-shaped areas forming an optical impression of closed loop-shaped bodies surrounding a central area and being nested around a common central area which is surrounded by a more loop-shaped area. internal, wherein, in each of the loop-shaped areas, at least a portion of the plurality of non-spherical magnetic or magnetizable particles are oriented such that, in a cross section perpendicular to the OEL layer and extending from the center of the area central to the delimitation of the outermost loop-shaped area, the longest axis of the particles in each of the cross-sectional areas of the loop-shaped areas if gue a tangent of either a negatively curved or positively curved part of hypothetical circles or ellipses. 2. The optical effect layer (OEL), according to item 1, wherein the OEL additionally comprises an outer area outside the outermost loop-shaped area, the outer area surrounding the outermost loop-shaped area comprises a plurality of non-spherical magnetic or magnetizable particles, wherein at least a portion of the plurality of non-spherical magnetic or magnetizable particles within the outer area are oriented such that their longest axis is substantially perpendicular to the plane of the OEL or randomly oriented. 3. The optical effect layer (OEL) according to item 1 or 2, wherein the central area surrounded by the innermost loop-shaped area comprises a plurality of non-spherical magnetic or magnetizable particles, in which a part of the The plurality of non-spherical magnetic or magnetizable particles within the central area is oriented such that its longest axis is substantially parallel to the plane of the OEL, forming the optical effect of a bulge. 4. The optical effect layer (OEL) according to item 3, in which the outer peripheral shape of the boss is similar to the shape of the closed body in inner loop shape. 5. The optical effect layer (OEL), according to item 3 or 4, in which the loop-shaped areas each provide the optical effect or impression of a loop-shaped body in the shape of a ring and the protrusion is shaped like a half sphere or solid circle. 6. The optical effect layer (OEL) according to any one of items 1, 2, 3, 4 and 5, wherein at least a part of the plurality of non-spherical magnetic or magnetizable particles is constituted by magnetic or magnetizable pigments optically non-spherical variables. 7. The optical effect layer according to item 6, wherein the optically variable magnetic or magnetizable pigments are selected from the group consisting of magnetic thin-film interference pigments, magnetic cholesteric liquid crystal pigments and their mixtures. 8. The optical effect layer (OEL), according to any of the previous items, preferably item 3, 4 or 5, wherein the plurality of non-spherical magnetic or magnetizable particles within the loop-shaped areas and/or within of the central area surrounded by the loop-shaped areas are oriented such that they provide the optical effect of (a) three-dimensional object(s) extending from the surface of the OEL. 9. A magnetic field generating device comprising a plurality of elements selected from magnets and pole pieces and comprising at least one magnet, the plurality of elements being either (i) located below a support surface or a space configured to receive a substrate acting as a support surface or (ii) forming a support surface and being configured to be capable of providing a magnetic field, in which the magnetic field lines run substantially parallel to said support surface or space in two or further areas above said support surface or space, and wherein i) the two or more areas form nested loop-shaped areas surrounding a central area; and/or ii) the plurality of elements comprises a plurality of magnets, and the magnets are arranged rotating about an axis of rotation such that areas with field lines running substantially parallel to the support surface or space combine upon rotation in around the axis of rotation, thereby forming, upon rotation about the axis of rotation, a plurality of nested loop-shaped areas surrounding a central area. 10. The magnetic field generating device, according to item 9, option ii), in which the magnets are arranged such that in an area, which is above said surface or support space and which is centered on the axis of rotation, a magnetic field is generated with field lines running substantially parallel to the generated plane of magnets. 11. The magnetic field generating device, according to item 9, option i), in which two or more areas of parallel field lines, which form the nested loop-shaped areas surrounding a central area, are caused by a arranging a plurality of elements selected from magnets and pole pieces, at least one of said elements having a loop-shaped shape, corresponding to the loop-shaped area with parallel field lines above the supporting surface or space. 12. The magnetic field generating device according to item 11, wherein the arrangement of a plurality of elements selected from magnets and pole pieces comprises at least one magnet in a loop shape, having its magnetic axis substantially perpendicular to the said support surface or space, the arrangement of which preferably additionally contains a pole piece having a loop-shaped shape, the magnet in a loop shape and the pole piece in a loop shape surrounding a central area in a nested manner. 13. The magnetic field generating device according to item 12, wherein the central area comprises a bar dipole magnet having its magnetic axis substantially perpendicular to said support surface or space or a central pole piece, and wherein the pole piece and that magnet are arranged alternately starting from the center area. 14. The magnetic field generating device according to item 9, option ii), or item 10, wherein the plurality of magnets is arranged symmetrically about the axis of rotation and has its magnetic axis substantially parallel or substantially perpendicular to the support surface or space. 15. The magnetic field generating device, according to item 9, which is selected from the group consisting of the following: a) a magnetic field generating device, in which an axially magnetized dipole magnet in the form of a loop is provided such that the North-South axis is perpendicular to the support surface or space, in which the loop-shaped magnet surrounds a central area, and the device is further composed of a pole piece that is provided below the axially-shaped magnetized dipole magnet. of loop, in relation to the supporting surface, or to space and which closes one side of the loop formed by the magnet in the form of a loop, and in which the pole piece constitutes one or more projections extending into space, surrounded by the magnet in the form of a loop. loop and being spaced from there, where a1) the pole piece constitutes a projection that extends into the central area surrounded by the loop-shaped magnet, where the projection is laterally spaced away from the loop-shaped magnet and fills a p art from the central area; a2) the pole piece constitutes a loop-shaped projection and surrounds a central bar dipole magnet, having the same North-South direction as the loop magnet, the projection and the bar dipole magnet being spaced apart from each other , or a3) the pole piece forms two or more projections spaced apart, either all or all but one of these are loop-shaped, and, depending on the number of projections, one or more additional axially magnetized loop-shaped magnets having the same North-South direction as the first axially magnetized loop-shaped magnet are provided in the space formed between the spaced apart loop-shaped projections, the additional magnets being spaced apart from the loop-shaped projections, and in which the central area, surrounded by loop-shaped projections and the loop-shaped magnets is partially filled, either with a center bar dipole magnet having the same North-South direction as the surrounding loop-shaped magnets, or with a the central projection of the pole piece, such that, as seen from the supporting surface or space, an alternating arrangement of spaced apart pole piece projections in a loop shape and axially magnetized loop-shaped dipole magnets is formed, surrounding a central area , in which the central area is filled with a bar dipole magnet or a central projection as set out above; b) a magnetic field generating device comprising two or more bar dipole magnets and two or more polar pieces, wherein the device comprises an equal number of polar pieces and bar dipole magnets, wherein the bar dipole magnets have their north-south axis substantially perpendicular to the support surface or space, have the same North-South direction and are provided at different distances from the support surface or space, preferably along a line extending perpendicular to the support surface or spaced and spaced apart from each other; and the polar pieces being provided in the space between and in contact with the bar dipole magnets, wherein the polar pieces form one or more projections which, in a loop shape, surround a central area in which the dipole magnet in bar, located close to the support surface or space, is located; c) a magnetic field generator device, comprising a magnetic dipole bar located below the supporting surface or space and having its north-south direction perpendicular to said supporting surface or space, one or more loop-shaped polar pieces arranged above the magnet and below the support surface or space, where, for a plurality of loop-shaped pole pieces, spaced and nested coplanar pieces are arranged, one or more pole pieces laterally encircling a central area in which the magnet is located, the device further comprising a first plate-like polar piece having approximately the same size and the same peripheral shape as the outermost loop-shaped polar piece, the plate-like polar piece being arranged below the magnet such that its outer peripheral shape is superimposed with the periphery of the outermost of the loop-shaped pole pieces towards the supporting surface or space, and which is in contact with one of the poles of the magnet; and a central pole piece in contact with the other pole of the magnet respectively, the central pole piece having the outer peripheral shape of a loop, partially filling the central area and being laterally spaced apart and surrounded by one or more pole pieces in the shape of a loop; d) a magnetic field generating device according to item c) above, in which a second plate-type pole piece having the outer peripheral shape of a loop is provided in a position above and in contact with a pole of the magnet, and below and in contact with the one or more loop-shaped pole pieces, and below and in contact with the center pole piece, so that the center pole piece is no longer in direct contact with the magnet pole, the second pole piece plate type being approximately the same size and shape as the first plate type pole piece. e) a magnetic field generating device, in which two or more bar dipole magnets are arranged below the supporting surface or spaced apart and so as to be rotatable about an axis of rotation that is perpendicular to the supporting surface or space, the two or more bar dipole magnets being spaced apart from the axis of rotation and each other and provided symmetrically on opposite sides of the axis of rotation, the device optionally comprising a bar dipole magnet that is arranged below the support surface or space and about the axis of rotation, or wherein e1) the device comprises, on both sides of the axis of rotation, one or more bar bar dipole magnets, all having their north-south axis substantially perpendicular to the support surface or space and substantially parallel to the axis of rotation, the north-south direction of all magnets are identical with respect to the supporting surface or space and the magnets being spaced apart from each other, the device optionally complies resending a bar dipole magnet that is arranged below the support surface or space and on the axis of rotation, the north-south axis thereof, being substantially perpendicular to the support surface or space, and substantially parallel to the axis of rotation, and whose north-south direction is either identical with the north-south direction of magnets which are arranged rotating about the axis and spaced apart from this point or in opposition; e2) no optional bar dipole magnets on the axis of rotation are present and the device comprises, on both sides of the axis of rotation, two or more bar dipole magnets arranged spaced apart from each other and from the axis of rotation, the north axis -south of the magnets being substantially perpendicular to the bearing surface or space and substantially parallel to the axis of rotation, and wherein the magnets provided on both sides of the axis have alternating north-south directions, and the magnets more internal, with respect to the axis of rotation, have the same or opposite north-south directions; e3 no optional bar dipole magnets on the axis of rotation are present and the device comprises, on both sides of the axis of rotation, two or more bar dipole magnets arranged spaced apart from each other and from the axis of rotation, the north axis. south of the magnets being substantially perpendicular to the bearing surface or space and substantially parallel to the axis of rotation, and wherein magnets provided on both sides of the axis have the same north-south direction and magnets provided on different sides of the axis of rotation have opposite north-south directions; e4) the device comprises, on both sides of the axis of rotation, one or more bar dipole magnets that are arranged spaced apart from the axis of rotation and, if more than one magnet is present on one side, spaced apart from each other, the axis north-south of the magnets being substantially parallel to the bearing surface or space and substantially radial to the axis of rotation, and the north-south directions of the magnets being arranged such that the north-south directions of all magnets point essentially in the same direction, at that additionally both e4-1) no optional magnets are provided on the axis of rotation and at least two magnets are provided on either side of the axis of rotation; or e4-2) an optional magnet is provided on the axis of rotation, the magnets on both sides being arranged away from this point, the magnet on the axis of rotation, being a magnetic dipole magnet having its north-south axis substantially parallel to the surface of support and its north-south direction, pointing in the same direction as the other magnets provided on either side of the axis or rotation; e5) the device comprises no optional magnets provided on the axis of rotation and comprises, on both sides of the axis of rotation, two or more bar dipole magnets that are arranged spaced apart from the axis of rotation and spaced apart from each other, the north axis -south of the magnets being substantially parallel to the bearing surface or space and substantially radial to the axis of rotation, wherein the alternating north-south directions of all magnets are symmetrical with respect to the axis of rotation (i.e., all pointing in or away from the axis of rotation); e6) the device comprises no bar dipole magnets provided on the axis of rotation and comprises, on both sides of the axis of rotation, one or more pairs of bar dipole magnets arranged spaced apart from the axis of rotation and spaced apart from each other, the north-south axis of the magnets being substantially parallel to the bearing surface or space and substantially radial to the axis of rotation, and each pair of magnets being formed by two magnets with opposite north-south directions pointing towards each other or away from the other , respectively, and the innermost magnets of the innermost pairs of magnets on each side each have e6-1) symmetrical north-south directions with respect to the axis of rotation, both pointing either away from or towards the axis of rotation; or e6-2) north-south directions asymmetric in relation to the axis of rotation, one pointing away and the other pointing to the axis of rotation; or e7) the device either e7-1) comprises the optional bar dipole magnet on the axis of rotation and one or more magnets on either side of the axis of rotation, the north-south axis of all magnets being substantially parallel to the bearing surface and the north-south axis of the magnets on either side of the axis of rotation is essentially radial to the axis of rotation; or e7-2) the device does not comprise the bar dipole magnet on the axis of rotation and comprises two or more magnets on either side of the axis of rotation that are arranged spaced apart from the axis of rotation, the north-south axis of all the magnets, being substantially parallel to the supporting surface or space and substantially radial to the axis of rotation, wherein in both cases the north-south directions of the magnets arranged on one side of the axis of rotation are asymmetric to the north-south directions of the magnets arranged on the other side of the axis of rotation relative to the axis of rotation (ie pointing towards the axis of rotation on one side and away from the axis of rotation on the other side) such that the north-south directions are in the line from the outermost magnet on one side to the outermost magnet on the other side, the magnet about the axis of rotation in case e7-1 being aligned on this line; e8) the device comprises, on both sides of the axis of rotation, two or more bar dipole magnets, all having their north-south axes substantially perpendicular to the bearing surface or space and substantially parallel to the axis of rotation and, optionally, a bar dipole magnet arranged about the axis of rotation and also having its north-south axis substantially perpendicular to the bearing surface or space and substantially parallel to the axis of rotation; the north-south direction of adjacent magnets being opposite to the supporting surface or space, and the magnets being spaced apart from each other; or e9 the device comprises, on both sides of the axis of rotation, two or more bar dipole magnets all having their north-south axes substantially parallel to the bearing surface and substantially radial to the axis of rotation, and optionally a bar dipole magnet arranged about the axis of rotation and also having its north-south axis substantially parallel to the bearing surface or space and substantially perpendicular to the axis of rotation, the north-south directions of adjacent magnets pointing in opposite directions, and the magnets being spaced apart between themselves; f) a magnetic field generating device, in which two or more loop-shaped dipole magnets are provided such that their north-south axes are perpendicular to the supporting surface or space, the two or more loop-shaped magnets being arranged nested , spaced apart and surrounding a central area, the magnets being axially magnetized and adjacent loop-shaped magnets have north-south directions pointing either towards or away from the support surface or space, the device additionally comprising a bar dipole magnet provided in the central area, surrounded by the loop-shaped magnets, the bar dipole magnet having its north-south axis substantially perpendicular to the supporting surface and parallel to the north-south axis of the loop-shaped magnets, the north-south direction of the dipole magnet bar being opposite the north-south direction of the innermost loop-shaped magnet, the device optionally additionally comprising a pole piece on the opposite side of the supporting surface. or space and in contact with the central bar dipole magnet and the loop-shaped magnets; g) a magnetic field generating device, comprising a permanent magnetic plate that is magnetized perpendicular to the plane of the plate and having projections and impressions, the projections and impressions being arranged to form nested loop-shaped impressions and projections surrounding a central area, the projections and impressions forming opposite magnetic poles; and h) a magnetic field generating device comprising a plurality of bar dipole magnets provided around an axis of rotation, the magnets on either side of the axes of rotation either substantially parallel or perpendicular to the bearing surface or space, and optionally a bar dipole magnet arranged about the axis of rotation and also having its north-south axis substantially parallel or perpendicular to the bearing surface; respectively, the north-south directions of adjacent magnets pointing in the same or opposite directions, and the magnets being spaced apart or in direct contact with each other, the magnets optionally being provided on a grounding plate. 16. A printing set comprising the magnetic field generating devices recited in items 9-15, which is optionally a rotating printing set. 17. Use of the magnetic field generating devices recited in any of items 9-15 to produce the OEL recited in any of items 1 to 8. 18. A process for producing an optical effect layer (OEL), comprising the steps of ; a) applying on a support surface or a substrate surface, a coating composition comprising a binding material and a plurality of non-spherical magnetizable or magnetic particles, said coating composition being in a first state (fluid), b) exposing the coating composition in a first state to the magnetic field of a magnetic field generating device, preferably one as defined in any one of items 9-15, thereby orienting at least a portion of the non-spherical magnetizable or magnetic particles in a plurality of nested loop-shaped areas, surrounding a central area, such that the longest axis of the particles in each of the cross-sectional areas of the loop-shaped areas follows a tangent of either a negatively curved or a positively curved part of circles or ellipses hypothetical; and c) hardening the coating composition to a second state so as to fix the magnetizable or non-spherical magnetic particles in their adopted positions and orientations. 19. The process according to item 18, wherein the hardening step c) is done by curing by UV-Vis light radiation. 20. An optical effect layer according to any one of items 1-8, which is obtained by the process of item 18 or item 19. 21. An optical effect layer (OEC) coated substrate comprising one or more effect layers according to any one of items 1 to 8 or 20 on a substrate. 22. A security document, preferably a bank note or an identity document, comprising an optical effect layer recited in any of items 1 to 8 or 20. 23. Use of the optical effect layer recited in any of items 1 to 8 or 20 or of the optical effect coated substrate recited in item 21 for the protection of a security document against forgery or fraud or decorative application. Brief description of the figures
[013] The optical effect layer (OEL) comprising a plurality of areas in loop format according to the present invention and its production are now described in more detail with reference to the figures and particular embodiments, in which Fig. 1 illustrates schematically a toroidal body (Fig. 1 A) and the variation of orientation of the non-spherical magnetic or magnetizable particles in an area forming a closed loop-shaped body, which, in a cross section extending from the center of the central area ( that is, the center of the entire toroidal body) follows either a tangent of a negatively curved part (Fig. 1B) or a positively curved part (Fig. 1C) of a hypothetical ellipse having its center above or below the area forming a body looped in that cross section. Fig. 2 contains three views of the same security element comprising two loop shapes, each in the form of a ring, wherein Fig. 2a shows a photograph of an optical effect layer comprising a security element having two loop shapes; Fig. 2b illustrates the variation in the orientation of non-spherical magnetic or magnetizable particles with respect to the OEL plane in a cross section along the line indicated in Fig. 2A, and Fig. 2c shows three electron microphotographs of cross-sections of the shell. optical effect of the cut in Fig. 2a perpendicular to its top surface, where microphotographs were taken at locations A, B and C, respectively. Each photomicrograph shows the substrate (at the bottom), which is covered by the optical effect layer comprising oriented non-spherical magnetic or magnetizable particles forming two loop shapes; Fig. 3a schematically depicts an embodiment of a magnetic field generator device according to an embodiment of the present invention, the device comprising a support surface (S) for receiving a substrate on which the optical effect layer is provided, a dipole magnet (M) in the form of a hollow loop-shaped body (a ring), which is magnetized such that the north-su axis! of the magnet is perpendicular to the plane of the loop (ring) and an inverted T-shaped iron connection (Y). The magnet assembly (M) and the iron connection (Y), as well as the three-dimensional magnetic field, as illustrated by the field lines (F) of the magnet (M), in space are rotationally symmetrical with respect to a central vertical axis (z); Fig. 3b shows a photograph of a security element of the present invention comprising two loop shapes (two rings) formed using the magnetic field generating device shown in Fig. 3a; Fig. 4 schematically depicts an embodiment of a magnetic field generating device according to another embodiment of the present invention, the device comprising i) a bar dipole magnet (M1), which is magnetized, such as having its north-south axis perpendicular to the support surface (S), ii) a dipole magnet in the form of a hollow loop-shaped body (M2), which is also magnetized so as to have its north-south axis perpendicular to the support surface (S) and iii ) an inverted double T (Y) shaped iron connection. Fig. 5 schematically depicts the cross section of a magnetic field generating device according to a further embodiment of the present invention, comprising a first (M1) and second (M2) dipole magnet, each in the form of a loop-shaped body (ie, each of the magnets form a ring and the magnet M2 is fully embedded (nested) within the magnet ring M1), which are each magnetized so as to have their north-south axis perpendicular to the supporting surface (S ) and a pole piece (a triple T (Y) shaped iron connection); Fig 6 a) - d) schematically depicts further embodiments of a magnetic field generating device in accordance with embodiments of the present invention; Fig. 6 e) shows three photographs of the optical effect layer taken using the device shown in Figure 6d; Fig 7 a) - d) schematically depicts further embodiments of a magnetic field generating device according to embodiments of the present invention; Fig 8 schematically depicts a further embodiment of a magnetic field generating device according to embodiments of the present invention; Fig 9 schematically depicts a further embodiment of a magnetic field generating device according to the present invention; Fig 10 schematically depicts a further embodiment of a magnetic field generating device according to the present invention; Fig 11 schematically depicts a further embodiment of a magnetic field generating device according to the present invention; Fig 12 schematically depicts a further embodiment of a magnetic field generating device according to the present invention; Fig 13 schematically depicts a further embodiment of a magnetic field generating device according to the present invention; Fig 14 schematically depicts a further embodiment of a magnetic field generating device according to the present invention; Fig 15a schematically depicts a further embodiment of a magnetic field generating device according to the present invention; Fig. 15b shows a photograph of a security element comprising a plurality of loop shapes formed with the device shown in Fig. 15a at a distance d between the magnets in Fig. 15a and the surface of the bearing surface S receiving the substrate of 0 mm, that is, the supporting surface S is provided in direct contact with the magnet; Fig. 15c shows a photograph of a security element comprising a plurality of loop shapes formed with the device shown in Fig. 15a at a distance d between the magnets in Fig. 15a and the surface of the bearing surface S receiving the substrate of 1.5 mm; Fig 16 schematically depicts a further embodiment of a magnetic field generating device according to the present invention; Fig 17 schematically depicts a further embodiment of a magnetic field generating device according to the present invention; Fig 18 schematically depicts a further embodiment of a magnetic field generating device according to the present invention; Fig 19 schematically depicts a further embodiment of a magnetic field generating device according to the present invention; and Fig 20 schematically depicts a further embodiment of a magnetic field generating device in accordance with the present invention. Fig. 21a,b illustrate the orientation of non-spherical magnetic or magnetizable particles in loop-shaped areas of OEL modalities; Fig. 22 shows examples of loop formats; Fig 23 schematically depicts a further embodiment of a magnetic field generating device according to the present invention having a grounding plate; and Fig 24 schematically depicts a further embodiment of a magnetic field generating device in accordance with the present invention having a grounding plate. Fig 25 schematically depicts a further embodiment of a magnetic field generating device according to the present invention. Definitions
[014] The following definitions shall be used to interpret the meaning of terms discussed in the description and recited in the claims.
[015] As used in this document, the indefinite article "a"(a) indicates one, as well as more than one, and does not necessarily limit its noun of reference to the singular.
[016] As used in this document, the term "about" means that the quantity or value in question may be the specific designated value or some other value in its vicinity. Generally, the term "about" denoting a certain value is intended to denote a range within ±5% of the value. As an example, the phrase "about 100" denotes a range of 100 ± 5, that is, the range from 95 to 105. Generally, when the term "about" is used, one can expect similar results or effects from according to the invention can be obtained within a range of + 5% of the indicated value.
[017] As used in this document, the term "and/or" means that either all or only one of the elements of said group may be present. For example, "A and/or B" is understood to mean "only A, or only B or both A and B". In the case of "only A", the term also covers the possibility that B is absent, ie "only A but not B".
[018] The term "substantially parallel" refers to deviation of less than 20° from parallel alignment and the term "substantially perpendicular" refers to deviation of less than 20° from perpendicular alignment. Preferably, the term "substantially parallel" refers to deviation of no more than 10° from parallel alignment and the term "substantially perpendicular" refers to deviation of no more than 10° from perpendicular alignment.
[019] The term "at least partially" is intended to denote that the following property is fulfilled to some extent or completely. Preferably, the term denotes that the following property is fulfilled at least 50% or more, more preferably at least 75%, even more preferably at least 90%. It may be preferred that the term denote "completely".
[020] The terms "substantially" and "essentially" are used to denote that the following feature, property, or parameter is either completely (totally) realized or satisfied or to a greater degree that negatively affects the intended outcome. Thus, depending on the circumstances, the term "substantially" or "essentially" preferably means, for example, at least 80%, at least 90%, at least 95% or 100%.
[021] The term "comprising" as used in this document is intended to be non-exclusive and open ended. Thus, in the case of a coating composition comprising a compound A, it may include compounds other than A. However, the term "comprising" also encompasses the more restrictive meanings of "consisting essentially of" and "consisting of", so that, for example, "a coating composition comprising a compound A" may also (essentially) consist of compound A.
[022] The term "coating composition" refers to any composition that is capable of forming an optical effect layer (OEL) of the present invention on a solid substrate and that can be applied preferentially, but not exclusively, by a method Printing. The coating composition comprises at least a plurality of non-spherical magnetic or magnetizable particles and a binder. Due to their non-spherical shape, the particles have non-isotropic reflectivity.
[023] The term "optical effect layer (OEL)" as used herein denotes a layer comprising at least a plurality of oriented non-spherical magnetic or magnetizable particles and a binder, wherein the orientation of the non-spherical magnetic or magnetizable particles is fixed inside the binder.
[024] As used in this document, the term "coated optical effect substrate (OEC)" is used to denote the product resulting from the provision of the OEL on a substrate. The OEC may consist of the substrate and the OEL, but may also comprise materials and/or layers other than the OEL. The term OEC thus also encompasses security documents such as bank notes.
[025] The term "loop-shaped area" denotes an area within the OEL providing the optical effect or optical impression of a loop-shaped body recombining with each other. The area takes the form of a closed loop surrounding a central area. The "loop-shaped" can be a round, oval, ellipsoid, square, triangular, rectangular, or any polygonal shape. Examples of loop shapes include a circle, rectangle or square (preferably with rounded corners), triangle, pentagon, hexagon, heptagon, octagon, etc. Preferably, the area forming a loop does not intersect. The term "loop-shaped body" is used to denote the optical effect or optical impression that is obtained by orienting non-spherical magnetic or magnetizable particles in the loop-shaped area, such that the optical impression of a shaped body three-dimensional looping is provided. The term "nested loop-shaped areas" is used to denote an arrangement of loop-shaped areas, each providing the optical effect or optical impression of a loop-shaped body, nor that "nested" means one of the areas loop-shaped is at least partially surrounding another loop-shaped area, and the "nested" loop-shaped areas surround a common central area. Preferably, the term "nested" means that one or more loop-shaped areas completely surround one or more loop-shaped areas completely. A particularly preferred embodiment of "nested" is "concentric", in which one or more outer loop shape areas completely surround one or more inner loop shapes and define a common central area without intersecting with each other. In a further preferred embodiment, the plurality of "nested" loop-shaped areas take the form of concentric circles.
[026] The term "a security element comprising a plurality of nested loop-shaped bodies" refers to a security element in which the orientation of non-spherical magnetic or magnetizable particles within the OEL is such that there are two or more areas in nested loop format and where within these areas, the orientation of the non-spherical magnetic or magnetizable particles is such that an observable light reflection in a specific direction (usually perpendicular to the surface of the OEL) is obtained, thereby providing the effect view of a plurality of nested loop-shaped bodies. This usually means that, in a cross section, extending from the center of the central area to the outer boundary of the loop-shaped areas, in the central part of an area that is part of a loop-shaped area (for example, the central part of the layer L in figures 1b and 1c or in the central part of areas (1) in the lower part of figure 21A), the longer axis of the non-spherical magnetic or magnetizable particles is oriented to be substantially parallel to the plane for the surface of the OEL. The two or more nested loop-shaped bodies are usually arranged such that one of the loop-shaped bodies completely surrounds the other(s), as shown, for example, in Figure 3b, where there are two shaped bodies loop, in the form of two rings, in which one of the rings completely surrounds the other. Preferably, the plurality of loop-shaped bodies are identical or essentially identical in shape, such as two or more rings, two or more squares, two or more hexagons, two or more heptagons, two or more octagons, etc.
[027] The term "width of a loop-shaped area" is used to denote the width of a loop-shaped area in a cross section perpendicular to the OEL and extending from the center of the central area to the outer boundary of the outermost area in a loop shape, as represented by the width of the area (1) in Figure 21.
[028] The term "security element" is used to denote an image or graphic that can be used for authentication purposes. The security element can be a visible and/or hidden security element.
[029] The term "magnetic axis" or "North-South axis" denotes a theoretical line connecting and extending through the North and South poles of a magnet. The line does not have a certain direction. On the other hand, the term "north-south direction" denotes the direction along the North-South axis or magnetic axis from the North pole to the South pole. one axis of rotation and the magnetic North-South axis is radial to the axis of rotation, the expression "symmetrical magnetic North-South direction" means that the orientation of the North-South direction is symmetric with respect to the axis of rotation as the center of symmetry ( that is, the North-South direction of all multiple magnets either points away from the axis of rotation or the North-South direction of all multiple magnets toward it). In the context of magnetic field generating devices in which multiple magnets are provided rotatable about an axis of rotation and the magnetic North-South axis is radial to the axis of rotation and parallel to the bearing surface or substrate surface, the expression " Asymmetric magnetic North-South direction" means that the orientation of the North-South direction is asymmetric with respect to the axis of rotation as the center of symmetry (ie, the North-South direction of one of the magnet points towards and the North-South direction other magnet points away from the axis of rotation). Detailed Description
[030] In one aspect, the present invention relates to an OEL that is normally provided on a substrate. The OEL comprises a plurality of non-spherical magnetic or magnetizable particles that have a non-isotropic reflectivity. The non-spherical magnetic or magnetizable particles are dispersed in a binding material and, in nested loop-shaped areas surrounding a common central area, have a specific orientation to provide the optical effect or - optical impression of a plurality of shaped bodies. nested loop. Orientation is achieved by orienting particles according to an external magnetic field, as explained in more detail below. That is, the present invention provides an optical effect layer (OEL) comprising a plurality of magnetizable or non-spherical magnetic particles, which are dispersed in a coating composition comprising a binder material, the OEL comprising two or more areas, each having a loop-shaped (also referred to as loop-shaped areas), the loop-shaped areas being nested around a common central area that is surrounded by the innermost loop-shaped area, where in each of the areas forming a nested loop-shaped area, at least a part of the plurality of magnetizable or non-spherical magnetic particles is oriented such that, in a cross section perpendicular to the OEL layer and extending from the center of the central area to the outer boundary of the outermost loop-shaped area, the longest axis of the particles in each of the cross-sectional areas of the loop-shaped areas follows a tangent of a curved part. negatively curved or positively curved of hypothetical circles or ellipses. In this document, a portion of the non-spherical magnetic or magnetizable particles in the loop-shaped areas is oriented such that its longest axis is substantially parallel to the plane of the OEL.
[031] The orientation of non-spherical magnetic or magnetizable particles is not uniform throughout the entire volume of the OEL. Instead, there are two or more loop-shaped areas nested within the OEL, where particles are oriented such that an observable reflectivity in a given second direction is obtained when light is radiated from a first direction in the OEL. Typically, the orientation of non-spherical magnetic or magnetizable particles within the areas, each forming a loop, is such that a maximum reflectivity perpendicular to the OEL surface is obtained when light is radiated from a direction perpendicular to the OEL surface. This usually means that within the loop-shaped areas, at least a portion of the particles are oriented such that their longest axis is substantially parallel to the plane or surface of the OEL.
[032] These areas form a plurality of nested loop-shaped areas. The plurality (i.e., two or more, such as three, four, five, six or more) of loop-shaped areas are preferably arranged such that one of the loop-shaped areas is completely surrounded by one or more other loop shapes. loop without crossing it or them, as shown in Figure 3b, where one loop shape (ring) is surrounded by another loop shape (another ring). For three loop shapes, preferably the arrangement is such that the innermost loop shape is completely surrounded by a middle and outermost loop shape, and the intermediate shape is interposed between the outermost loop shape, again without intersecting . This principle is logically applicable also to a larger number of loop shapes, as shown, for example, in figure 15b for five rings.
[033] It is particularly preferable that the plurality of loop-shaped areas arranged in this way are substantially identical in shape. This means that, for example, in the case of three loop-shaped areas, there are, for example, three circles, three rectangles, three triangles, three hexagons, etc. where an inner loop shape is surrounded by an outer loop shape.
[034] The shape of the OEL and in particular the orientation of the non-spherical magnetic or magnetizable particles within the loop-shaped areas of the OEL will now be described with reference to Figure 21, which schematically illustrates an OEL of the present invention. Notably, Figure 21 is not to scale.
[035] In the upper left corner of figure 21, a plan view of an OEL comprising two loop-shaped bodies formed by loop-shaped areas (1) provided on a support (S) in the form of ellipsoids is shown. At the top, the optical impression of two loop-shaped bodies is seen in a plan view of the OEL. The loop-shaped areas (1) surround a common central area (2) having a center (3).
[036] At the bottom of figure 21, a cross-sectional view perpendicular to the plane of the OEL and extending from the center (3) of the central area (2) to the outer boundary of the outermost loop-shaped area, i.e. , along the line (4), is shown. Logically, the line (4) is not actually present over the OEL, but merely illustrates the position of the cross-sectional view as also referred to in claim 1. In the cross-sectional view, it becomes apparent that the OEL (L) in the modality shown it is provided on a support surface (S), preferably on a substrate. In the OEL cross-sectional view (L), the areas (1), forming part of a loop shape, contain non-spherical magnetic or magnetizable particles (5), which, when viewed in the cross-sectional view along the line (4 ), in each area (1) forming part of a loop-shaped area, are oriented so as to follow a tangent of a negatively curved part of hypothetical ellipses or circles (6). Logically, also the opposite alignment, following a positively curved part, is possible. Notably, a portion of the non-spherical magnetic or magnetizable particles (preferably in a section over the center of a loop-shaped area (1) when viewed in cross-section illustrated in Figure 21 and referenced in claim 1) is oriented such that its longest axis is substantially parallel to the plane of the OEL and/or the substrate surface. In a cross-sectional view along the line (4) or referred to in claim 1, the hypothetical circles or ellipses normally have their respective centers above or below (in figure 21 below) each of the areas, each forming part of an area in loop-shaped and preferably along a vertical line extending from about the middle of an area (1), forming the loop-shaped area.
[037] Additionally, in cross-sectional view, preferably, the diameter of a hypothetical circle or the longer or shorter axis of a hypothetical ellipse is about the width of the respective area, forming part of a loop shape (the width of the areas (1) at the bottom of figure 21), so that the inner and outer boundaries of each of the areas (1) the long axis orientation of the non-spherical particles is substantially perpendicular to the plane of the OEL and gradually change in order of becoming substantially parallel to the plane of the support surface or substrate at the center of the area (1), forming part of a loop-shaped area, providing the optical impression of a loop-shaped body. In the case where, in such a cross-sectional view, the orientation of the non-spherical magnetic or magnetizable particles in a given loop-shaped area follows a tangent to the negatively or positively curved part of a hypothetical circle, having its center along a line extending perpendicular to OEL and starting from about the center of the width of the loop-shaped area, the rate of change of orientation would be constant, since the curvature of a circle is constant. If, however, the orientation of particles follows a tangent (positively or negatively curved part of) an ellipse, the rate of change in the orientation of non-spherical magnetic or magnetizable particles would not be constant (because the curvature of an ellipse is not constant) so that, for example, around the center of the width of a loop-shaped area only a small change in the orientation of substantially parallel oriented particles is observed, which then changes more rapidly towards a substantially perpendicular orientation at the boundaries of the area. loop-shaped in the cross-sectional view shown in Figure 21.
[038] This relationship on the position of the center and the diameter of the hypothetical circle or ellipse not only applies to the modality of figure 21, but to all areas in loop shape, forming the optical impression of the loop-shaped bodies present in the OELs of the present invention, since naturally different positions and/or diameters can be applicable to the different loop-shaped bodies formed in an OEL. Notably, the OEL (L) areas not forming part of the nested loop-shaped areas (ie, the areas inside and outside the areas (1) in Figure 21) may also contain non-spherical magnetic or magnetizable pigments (not shown in figure 21), which may have a specific or random orientation, as will be further explained below. Additionally, the non-spherical magnetic or magnetizable particles (5) can fill the entire volume and can be arranged in several layers in the OEL (L), since figure 21 only schematically represents some of the particles in their respective orientations.
[039] In OEL, the non-spherical magnetic or magnetizable particles are dispersed in a coating composition comprising a stiffened binding material that corrects the orientation of the non-spherical magnetic or magnetizable particles. The stiffened binding material is at least partially transparent to electromagnetic radiation of one or more wavelengths in the range 200 nm to 2500 nm. Preferably, the stiffened binder material is at least partially transparent to electromagnetic radiation of one or more wavelengths in the range 200 to 800 nm, more preferably in the range 400 to 700 nm. In this document, the term "one or more wavelengths" denotes that the binding material can be transparent to only one wavelength in a given wavelength range, or it can be transparent to several wavelengths in a given range. Preferably, the binder material is transparent to more than one wavelength in the given range and most preferably to all wavelengths in the given range. Thus, in a more preferred embodiment, the stiffened binder material is at least partially transparent for all wavelengths in the range of about 200 to about 2500 nm (or 200 to 800 nm or 400 to 700 nm), and even more preferably the hardened binder material is fully transparent to all wavelengths in these ranges.
[040] In this document, the term "transparent" denotes that the transmission of electromagnetic radiation through a 20 μm layer of the hardened binding material as present in the OEL (not including the non-spherical magnetic or magnetizable particles, but all other optional components of the OEL in case such components are present) is at least 80%, more preferably at least 90%, even more preferably at least 95%. This can be determined for example by measuring the transmittance of a test piece of hardened binding material (not including non-spherical magnetic or magnetizable particles) in accordance with well-established test methods, eg DIN 5036-3 (1979- 11).
[041] The non-spherical magnetic or magnetizable particles described in this document preferably have non-isotropic reflectivity in relation to an incident electromagnetic radiation for which the stiffened binding material is at least partially transparent. As used in this document, the term "non-isotropic reflectivity" denotes that the proportion of radiation incident from a first angle that is reflected by a particle in a given (viewing) direction (a second angle) is a function of the orientation of the particles, that is, a change in the particle's orientation relative to the first angle can lead to a different magnitude of reflection for the viewing direction.
[042] Additionally, preferably, each of the plurality of non-spherical magnetic or magnetizable particles described in this document has a non-isotropic reflectivity with respect to electromagnetic radiation incident on some parts or in the full wavelength range between about 200 and about 2500 nm, more preferably between about 400 and about 700 nm, such that a change in particle orientation results in a change in reflection by that particle.
[043] In the OEL of the present invention, the non-spherical magnetic or magnetizable particles are provided so as to form a dynamic security element, providing an optical effect or optical impression of at least a plurality of nested loop-shaped bodies.
[044] In this document, the term "dynamic" denotes that the appearance and light reflection of the security element changes depending on the viewing angle. In other words, the appearance of the security element is different when viewed from different angles, that is, the security element has a different appearance (for example, from an angle of about 22.5° to the surface of the substrate on which the OEL is provided at a viewing angle of about 90° relative to the surface of the substrate on which the OEL is provided), which is caused by the orientation of non-spherical magnetic or magnetizable particles having non-isotropic reflectivity and /or properties of the non-spherical magnetic or magnetizable particles such as having an angle-of-view dependent appearance (as optically variable pigments, described later).
[045] The term "loop-shaped body" denotes that non-spherical magnetic or magnetizable particles are provided such that the security element gives the viewer the optical or visual impression of a loop-shaped body recombining, forming a body closed surrounding a common central area. Depending on the lighting, one or more formats may appear to the viewer. The "loop-shaped body" can be a round, ellipsoid, square, triangular, rectangular, or any polygonal shape. Examples of loop shapes include a circle, a rectangle or square (preferably with rounded corners), a triangle, a pentagon (regular or irregular), a hexagon (regular or irregular), a heptagon (regular or irregular), an octagon ( regular or irregular), any polygonal shape, etc. Preferably, loop-shaped bodies do not intersect with each other (such as in a double loop or in a shape where multiple rings overlap each other, such as Olympic rings). Examples of loop shapes are also shown in Figure 22. In the present invention, the OEL provides optical printing of two or more bodies in a closed loop shape as defined above.
[046] In the present invention, the optical effect or optical impression of the nested loop-shaped bodies is formed by the orientation of non-spherical magnetic or magnetizable particles within the OEL, illustrated by a modality in Figure 21. That is, the shape of the shape looping is not achieved by applying, such as, for example, when printing, the coating composition comprising the binding material and the non-spherical magnetic or magnetizable particles in a loop shape, but by aligning the non-spherical magnetic or magnetizable particles accordingly with a magnetic field such that, in a loop-shaped area of the OEL, the particles are oriented so as to provide reflectivity, since in areas of the OEL not forming part of a loop-shaped area, the particles are oriented to provide little or no reflectivity. Loop-shaped areas thus represent portions of the OEL, which - in addition to the loop-shaped areas - also contain one or more portions where the non-spherical magnetic or magnetizable particles are either not aligned at all (ie. , have a random orientation) or are aligned in such a way that they do not contribute to the impression of a loop-shaped image. This can be achieved by orienting at least a portion of the particles in this portion so that its longest axis is substantially perpendicular to the plane of the OEL.
[047] In this document, a particle orientation providing light reflection is typically an orientation in which the non-spherical particle has its longest axis oriented so as to be substantially parallel to the plane of the OEL and the substrate surface (if the OEL is provided on a substrate) and an orientation providing no or only little light reflection is typically an orientation where the longest axis of the non-spherical particle is substantially perpendicular to the plane of the OEL or the substrate surface if the OEL is provided on a substrate . This is because normally the OEL is considered from a position where a plane view of the OEL is observed (that is, from a position perpendicular to the plane of the OEL), so that non-spherical magnetic or magnetizable particles, having its longest axis oriented so as to be substantially parallel to the plane of the OEL, provides light reflection in this direction when viewed under diffuse light conditions or under irradiation from a direction substantially perpendicular to the plane of the OEL.
[048] Preferably, the non-spherical magnetic or magnetizable particles are needle-shaped or platelet-shaped particles, ellipsoid-shaped prolate or oblate, or mixtures thereof. Thus, even if the intrinsic reflectivity per unit surface area (eg, per μm2) is uniform across the surface of such a particle due to its non-spherical shape, the reflectivity of the particle is non-isotropic, like the visible area of the particle. it depends on the direction from which it is viewed. In one embodiment, non-spherical magnetic or magnetizable particles having non-isotropic reflectivity due to their non-spherical shape may additionally have an intrinsic non-isotropic reflectivity, such as, for example, in optically variable magnetic pigments due to the presence of layers of different refractive indices and reflectivity. In this embodiment, the non-spherical magnetic or magnetizable particles comprise non-spherical magnetic or magnetizable particles having intrinsic non-isotropic reflectivity, such as non-spherical optically variable magnetic or magnetizable pigments.
[049] Suitable examples of non-spherical magnetic or magnetizable particles described herein include without limitation particles comprising a ferromagnetic or ferrimagnetic metal such as cobalt, iron or nickel; a ferromagnetic or ferrimagnetic alloy of iron, manganese, cobalt, iron or nickel; a ferromagnetic or ferrimagnetic oxide of chromium, manganese, cobalt, iron, nickel or mixtures thereof; as well as their mixtures. Ferromagnetic or ferrimagnetic oxides of chromium, manganese, cobalt, iron, nickel or their mixtures may be pure or mixed oxides. Examples of magnetic oxides include without limitation iron oxides such as hematite (Fe2O3), magnetite (Fe3O4), chromium dioxide (CrO2), magnetic ferrites (MFe2O4), magnetic spinel (MR2O4), magnetic hexaferrites (MFe12Oi9) , magnetic orthoferrites ( RFeO3), magnetic garnets M3R2 (AO4)3, where M stands for a two-valent metal ion and R for a three-valent and A for a four-valent and "magnetic" for iron- or ferrimagnetic properties.
[050] Optically variable elements are known in the field of security printing. Optically variable elements (also known in the art as goniochromatic elements or changeable color elements) exhibit a color dependent on the angle of view or angle of incidence and are used to protect banknotes and other security documents against forgery and/or Illegal reproduction by commonly available color copying, printing and scanning office equipment.
[051] Preferably, at least a portion of the plurality of non-spherical magnetic or magnetizable particles described herein is comprised of non-spherical optically variable magnetic or magnetizable pigments. Such optically variable non-spherical magnetic or magnetizable pigments are preferably needle-shaped or platelet-shaped particles, ellipsoid-shaped prolate or oblate, or mixtures thereof.
[052] The plurality of non-spherical magnetic or magnetizable particles may comprise non-spherical optically variable magnetic or magnetizable pigments and/or non-spherical magnetic or magnetizable particles having no optically variable properties.
[053] The OEL providing the optical effect or optical impression of a plurality of loop-shaped bodies is formed by orienting (aligning) the plurality of non-spherical magnetic or magnetizable particles according to the field lines of a magnetic field in a OEL's plurality of nested loop-shaped areas, leading to the appearance of highly dynamic, view-dependent, nested loop-shaped bodies. If at least a part of the plurality of non-spherical magnetic or magnetizable particles described in this document are optically variable magnetic or magnetizable pigments, an additional effect is obtained, since the color of optically variable magnetic or magnetizable pigments does not Remarkable spherical shapes depend on the viewing angle or the angle of incidence in relation to the plane of the pigment, thus resulting in an effect combined with the viewing angle-dependent dynamic loop-shaped effect. The use of optically variable non-spherical magnetically oriented pigments in the OEL areas increases the visual contrast of the bright areas and improves the visual impact of loop-shaped elements in document security and decorative applications. The combination of the dynamic loop shapes with the observed color shift for optically variable pigments, achieved by using a magnetically oriented non-spherical optically variable pigment, results in a different color margin on the loop-shaped bodies, which is easily checked with the naked eye. Thus, in a preferred embodiment of the present invention, the non-spherical magnetic or magnetizable particles in the loop-shaped areas are comprised at least in part of optically variable non-spherical magnetically oriented pigments.
[054] In addition to the visible security provided by the color-changing property of optically variable non-spherical magnetic or magnetizable pigments, which allows easy detection, recognition and/or discrimination of the OEC (such as a security document), loading the OEL according to the present invention from its possible falsifications with the human senses per se, for example, because such resources can be visible and/or detectable and still being difficult to produce and/or copy, the property of change of Non-spherical optically variable magnetic or magnetizable pigment color can be used as a machine readable tool for OEL recognition. Thus, the optically variable properties of the optically variable pigments can be simultaneously used as a hidden or semi-hidden security feature in an authentication process where the optical properties (eg spectral) of the optically variable pigments are analyzed .
[055] The use of non-spherical optically variable magnetic or magnetizable pigments increases the importance of the obtained OEL as a security element in document security applications, because such materials (ie, optically variable magnetic or magnetizable pigments) are reserved for the security document printing industry and are not commercially available to the public.
[056] As mentioned above, preferably, at least a part of the plurality of non-spherical magnetic or magnetizable particles is constituted by non-spherical optically variable magnetic or magnetizable pigments. These can be selected most preferably from the group consisting of magnetic thin film interference pigments, magnetic cholesteric liquid crystal pigments and mixtures thereof.
[057] Magnetic thin-film interference pigments are known to those skilled in the art and are disclosed in US 4,838,648; WO 2002/073250 A2; EP-A 686 675; WO 2003/000801 A2; US 6,838,166; WO 2007/131833 A1 and related documents. Due to their magnetic characteristics they are machine readable and therefore coating compositions comprising magnetic thin-film interference pigments can be detected, for example, with the use of specific magnetic detectors. Therefore, coating compositions comprising magnetic thin-film interference pigments can be used as a hidden or semi-hidden security element (authentication tool) for security documents.
[058] Preferably, the magnetic thin-film interference pigments comprise pigments having a five-layer Fabry-Perot multilayer structure and/or pigments having a six-layer Fabry-Perot multilayer structure of and/or pigments having a seven-layer Fabry-Perot multilayer structure. Preferred five-layer Fabry-Perot multilayer structures consist of absorbent/dielectric/reflective/dielectric/absorbent multilayer structures, wherein the reflector and/or the absorbent is also a magnetic layer. Preferred six-layer Fabry-Perot multilayer structures consist of absorbent/dielectric/reflective/magnetic/dielectric/absorbent multilayer structures. Preferred seven-layer Fabry-Perot multilayer structures consist of absorbent/dielectric/reflective/magnetic/reflective/dielectric/absorbent multilayer structures, such as disclosed in US 4,838,648; and more preferably a seven-layer Fabry-Perot absorbent/dielectric/reflective/magnetic/reflective/dielectric/absorbent multilayer structure. Preferably, the reflective layers described in this document are selected from the group consisting of metals, metal alloys and combinations thereof, preferably selected from the group consisting of reflective metals, reflective metal alloys and combinations thereof, and most preferably selected from the group consisting of aluminum (Al), chromium (Cr), nickel (Ni) and their mixtures and, even more preferably, aluminum (Al). Preferably, the dielectric layers are independently selected from the group consisting of magnesium fluoride (MgF2), silicon dioxide (SiO2) and their mixtures, and more preferably magnesium fluoride (MgF2). Preferably, the absorbent layers are independently selected from the group consisting of chromium (Cr), nickel (Ni), metal alloys comprising nickel (Ni) iron (Fe) and/or cobalt (Co) and mixtures thereof. Preferably, the magnetic layer is preferably selected from the group consisting of nickel (Ni), iron (Fe) and cobalt (Co) and their mixtures and alloys. It is particularly preferred that the magnetic thin film interference pigments comprise a seven-layer Fabry-Perot absorbent/dielectric/reflective/magnetic/reflective/dielectric/absorbent multilayer structure consisting of a multilayer Cr/MgF2/AI/Ni structure. /AI/MgF2/Cr.
[059] Magnetic thin film interference pigments described in this document are typically manufactured by vacuum deposition of the different layers required in a mesh. After deposition of the desired number of layers, eg by PVD, the stack of layers is removed from the mesh, either by dissolving a release layer in a suitable solvent, or extracting the material from the mesh. The material thus obtained is then divided into flakes which need to be further processed by milling, grinding or any suitable method. The resulting product consists of flat flakes with broken edges, irregular shapes and different aspect ratios. More information on the preparation of suitable magnetic thin-film interference pigments can be found, for example, in EP-A 1 710 756, which is hereby incorporated by reference.
[060] Suitable magnetic cholesteric liquid crystal pigments exhibiting optically variable characteristics include without limitation monolayer cholesteric liquid crystal pigments and multilayer cholesteric liquid crystal pigments and are disclosed, for example, in WO 2006/063926 A1, US 6,582. 781 and US 6,531,221. WO 2006/06392 A1 discloses monolayers and pigments obtained therefrom with high gloss and color changing properties with additional particular properties such as magnetibility. The disclosed pigments and monolayers, which are obtained therefrom by fragmenting said monolayers, comprise a mixture of three-dimensionally crosslinked cholesteric liquid crystal and magnetic nanoparticles. US 6,582,781 and US 6,410,130 disclose platelet-shaped cholesteric multilayer pigments which comprise the sequence A1/B/A2, wherein A1 and A2 can be identical or different and each comprises at least one cholesteric layer and B is an interlayer absorbing all or part of the light transmitted by layers A1 and A2 and providing magnetic properties for said interlayer. US 6,531,221 discloses cholesteric multilayer pigments in platelet format, which comprise the sequence A/B and if desired C, wherein A and C are absorption layers comprising pigments providing magnetic properties and B is a cholesteric layer.
[061] In addition to non-spherical magnetic or magnetizable particles (which may or may not comprise or consist of non-spherical optically variable magnetic or magnetizable pigments), non-magnetic or non-magnetizable particles may also be contained in the loop-shaped security element and/ or the OEL in the exterior and interior areas to the loop-shaped areas. These particles can be color pigments known in the art, having or not having optically variable properties. Additionally, the particles can be spherical or non-spherical and can have isotropic or non-isotropic optical reflectivity.
[062] In OEL, the non-spherical magnetic or magnetizable particles described in this document are dispersed in a binding material. Preferably, the non-spherical magnetic or magnetizable particles are present in an amount of about 5 to about 40% by weight, more preferably about 10 to about 30% by weight, the weight percentages being based on the total dry weight of the OEL, comprising the binding material, non-spherical magnetic or magnetizable particles and other optional components of the OEL.
[063] As described above, the hardened binder material is at least partially transparent to electromagnetic radiation of one or more wavelengths in the range 200 to 2500 nm, more preferably in the range 200 to 800 nm, even more preferably in the range of 400 to 700 nm. The binder material is thus, at least in its solid or hardened state (also referred to as the second state below), at least partially transparent to electromagnetic radiation of one or more wavelengths in the range of about 200 nm to about 2500 nm, that is, within the wavelength range, which is commonly referred to as the "optical spectrum" and which comprises infrared, visible and UV portions of the electromagnetic spectrum such that the particles contained in the binding material in its solid or hardened state and its orientation-dependent reflectivity can be perceived through the binding material.
[064] More preferably, the binding material is at least partially transparent in the visible spectrum range between about 400 nm to about 700 nm. Incident electromagnetic radiation, eg visible light, penetrating the OEL through its surface can then reach the dispersed particles within the OEL and be reflected there, and the reflected light can leave the OEL again to produce the desired optical effect. The incident radiation waveform is selected outside the visible range, for example in the near UV range, so the OEL can also serve as a covert security feature, so normally technical means will be needed to detect the (complete) optical effect generated. by the OEL in the respective illuminating conditions comprising the non-visible wavelength selected in this case, it is preferable that the OEL and/or loop-shaped elements contained therein are composed of luminescent pigments. The infrared, visible and UV portions of the electromagnetic spectrum approximately correspond to the wavelength ranges between 700-2500 nm, 400-700 nm and 200-400 nm respectively.
[065] If the OEL is to be provided on a substrate, it is, for applying a coating composition on a substrate in order to form the OEL, it is necessary that the coating composition comprising at least the binding material and the magnetic or magnetizable particles non-spherical are in a form which permits processing of the coating composition, for example, by printing, in particular printing on particular copper plate metal, screen printing, gravure printing, flexographic printing or roller coating, to thereby applying the coating composition to the substrate, such as a paper substrate or those described hereinafter. Additionally, after applying the coating composition to a surface, preferably a substrate, the non-spherical magnetic or magnetizable particles are oriented by applying a magnetic field, aligning the particles along the field lines. Hereby, the non-spherical magnetic or magnetizable particles are oriented and oriented along the field lines, at least in a plurality of nested areas in a loop format, in which the particles are oriented so as to provide the desired light reflection (Usually such that at least a portion of the particles are oriented with their magnetic axis for magnetic particles and their longer axes for magnetizable particles parallel to the plane of the OEL surface/substrate surface). In this document, non-spherical magnetic or magnetizable particles are oriented in loop-shaped areas of the coating composition on the support surface of a magnetic field generating device or on a substrate, such that, for a viewer with respect to the substrate, From a direction normal to the plane of the substrate, the optical impression of a plurality of nested loop-shaped bodies is formed. Subsequently or simultaneously with the orientation/alignment step of the non-spherical magnetic or magnetizable particles by applying a magnetic field, the orientation of the particles is fixed. The coating composition should thus notably have a first state, i.e. a liquid or pasty state, in which the coating composition is wet or soft enough so that the non-spherical magnetic or magnetizable particles dispersed in the composition. coating are freely movable, rotating and/or orientable upon exposure to a magnetic field, and a second hardened state (eg solid), in which non-spherical particles are fixed or frozen in their respective positions and orientations.
[066] Such first and second stage is preferably provided by the use of a certain type of coating composition. For example, components of the coating composition other than non-spherical magnetic or magnetizable particles may take the form of an ink or coating composition, such as those used in security applications, for example, for printing banknotes.
[067] The above-mentioned first and second states can be provided through the use of a material that shows a large increase in viscosity in reaction to a stimulus, such as, for example, a change in temperature or an exposure to electromagnetic radiation . That is, when the fluid binding material is hardened or solidified, said binding material converts to the second state, that is, a hardened or solid state, where the particles are fixed in their current positions and orientations and can no longer move or rotate inside the binding material.
[068] As known to those skilled in the art, ingredients comprised in a paint or coating composition to be applied to a surface such as a substrate and the physical properties of said paint or coating composition are determined by the nature of the process used to transfer the paint composition or coating for the surface. Accordingly, the binding material comprised in the ink or coating composition herein is usually chosen from those known in the art and depends on the coating or printing process used to apply the ink or coating composition and the curing process chosen. Alternatively, a polymeric thermoplastic binder material or a thermoset can be employed. Unlike thermosets, thermoplastic resins can be repeatedly melted and solidified by heating and cooling without incurring any major changes in properties. Typical examples of thermoplastic resin or polymer include without limitation polyamides, polyesters, polyacetals, polyolefins, styrenic polymers, polycarbonates, polyarylates, polyimides, polyether ether ketones (PEEK), polyetherketone ketones (PEKK), polyphenylene-based resins (eg, polyphenylene ethers , polyphenylene oxide, phenylene sulfides), polysulfones and mixtures thereof.
[069] After applying the coating composition on a support surface of a magnetic field generating device or a substrate and orientation of the non-spherical magnetic or magnetizable particles, the coating composition is hardened (ie, turned to a solid state or solid-like) in order to correct the orientation of the particles.
[070] The hardening can be of a purely physical nature, for example, in cases where the coating composition comprises a polymeric binder material and a solvent and is applied at high temperatures. Then, the particles are oriented at high temperature by applying a magnetic field, and the solvent is evaporated, followed by cooling of the coating composition. Thereby, the coating composition is hardened and the orientation of the particles is fixed.
[071] Alternatively and preferably, the "hardening" of the coating composition involves a chemical reaction, eg by curing, which is not reversed by a simple temperature increase (eg up to 80°C) that may occur during a typical use of a security document. The term "curing" or "curable" refers to processes including the chemical reaction, crosslinking or polymerization of at least one component in the applied coating composition in such a way that it transforms into a polymeric material having a molecular weight greater than the initiating substances. Preferably, the cure causes the formation of a three-dimensional polymeric network.
[072] Such cure is usually induced by applying an external stimulus to the coating composition (i) after its application to a support surface or a substrate, and (ii) subsequently, or simultaneously with the orientation of the magnetic or magnetizable particles. Therefore, preferably, the coating composition is a paint or coating composition selected from the group consisting of radiation curable compositions, thermal drying compositions, oxidative drying compositions and combinations thereof. Particularly preferably, the coating composition is a paint or coating composition selected from the group consisting of radiation curable compositions.
[073] Preferred radiation-curable compositions include compositions that can be cured by UV-visible light radiation (hereinafter referred to as UV-Vis-curable) or by electron beam radiation (E-beam) (hereinafter referred to as EB). Radiation curable compositions are known in the art and can be found in standard textbooks such as the "Chemistry & Technology of UV & EB Formulation for Coatings, Inks & Paints" series, published in 7 volumes in 1997-1998 by John Wiley & Sons in association with SITA Technology Limited.
[074] According to a particularly preferred embodiment of the present invention, the ink or coating composition described in this document is a UV-Vis-curable composition. UV-Vis curing advantageously allows very fast curing processes and therefore drastically decreases the preparation time of the OEL in accordance with the present invention and articles and documents comprising said OEL. Preferably, the UV-Vis-curable composition comprises one or more compounds selected from the group consisting of radically curable compounds, cationically curable compounds and mixtures thereof. Cationically curable compounds are cured by cationic mechanisms typically including the radiation activation of one or more photoinitiators that release the cationic species, such as acids, which in turn initiate the cure in order to react and/or crosslink the monomers and /or oligomers to thereby harden the coating composition. Radically curable compounds are cured by free radical mechanisms typically including radiation activation of one or more photoinitiators, thereby generating radicals which, in turn, initiate polymerization so as to harden the coating composition.
[075] The coating composition may further comprise one or more machine readable materials selected from the group consisting of magnetic materials, luminescent materials and/or phosphorescent materials, electrically conductive materials, infrared absorbing materials and mixtures thereof. As used in this document, the term "machine-readable material" refers to a material that exhibits at least one distinct property that is not perceptible to the naked eye, and that can be understood in a layer in order to provide a way of authenticating. said layer or article comprising said layer through the use of special equipment for its authentication.
[076] The coating composition may additionally include one or more coloring components selected from the group consisting of organic and inorganic pigments and organic dyes and/or one or more additives. The latter includes without limitation compounds and materials that are used to adjust the physical, rheological and chemical parameters of the coating composition such as viscosity (eg thickeners and surfactants), consistency (eg anti-settling agents, fillers and plasticizers), foam properties (eg antifoam agents), lubricating properties (waxes, oils), UV stability (photosensitizers and photostabilizers), adhesion properties, antistatic properties, storage stability (polymerization inhibitors) , etc. Additives described herein may be present in the coating composition in amounts and in forms known in the art, including in the form of so-called nano-materials where at least one of the dimensions of the additives is in the range of 1 to 1000 nm.
[077] Following or concurrently with the application of the coating composition on a substrate surface or a supporting surface of the magnetic field generating device, the non-spherical magnetic or magnetizable particles are oriented by using an external magnetic field to guide them according to a desired orientation pattern in areas corresponding to two or more loop shapes. In this way, a permanent magnetic particle is oriented such that its magnetic axis is aligned with the direction of the external magnetic field line at the particle's location. A magnetizable particle without an intrinsic permanent magnetic field is oriented by the external magnetic field in such a way that the direction of its longest dimension is aligned with an external magnetic field line at the particle's location. The above applies analogously in the case where the particles are to have a layer structure including a layer with magnetic or magnetizable properties.
[078] Upon the application of a magnetic field, the non-spherical magnetic or magnetizable particles adopt an orientation in the layer of the coating composition in a way that a security element (an OEL) providing an optical effect or optical impression that includes at least a plurality of nested loop-shaped bodies is produced which is visible from at least one surface of the OEL (see, for example, Figures 3b, 6e, 15b, 15c and 24). Consequently, the dynamic loop-shaped element can be seen by an observer as a reflection zone that exhibits a dynamic visual movement effect upon rotation or tilt of the OEL, said loop-shaped element that appears to move in a different plane from the rest of OEL. Subsequently or simultaneously with the orientation of the non-spherical magnetic or magnetizable particles, the coating composition is hardened to correct the orientation, for example, by irradiation with UV-Vis light, in the case of a UV-Vis-curable coating composition.
[079] Under a certain direction of incident light, for example, vertical (perpendicular to the OEL), the zone of greater reflectivity, that is, specular reflection in non-spherical magnetic or magnetizable particles, of an OEL (L) comprising the particles with fixed orientation changes location as a function of viewing (tilt) angle: looking at the OEL (L) from the left side, loop-shaped bright zones are seen at location 1, looking at the layer from the left side. top, loop-shaped bright zones are seen at location 2, and looking at the layer from the right side, loop-shaped bright zones are seen at location 3. When changing the viewing direction from left to right, the loop-shaped bright zones thus appear to move from left to right as well. You can also get the opposite effect, that after changing the viewing direction from left to right, the loop-shaped bright zones appear to move from right to left. Depending on the sign of curvature of the non-spherical magnetic or magnetizable particles present in the nested loop-shaped areas of the OEL, which can be negative (see Figure 1b) or positive (see Figure 1c), the dynamic loop-shaped bodies are observable as moving towards the observer (in the case of a positive curve, Figure 1c) or away from the observer (negative curve, Figure 1b) in relation to a movement performed by the observer in relation to the OEL. Notably, the observer's position is above the OEL in Figure 1. Such a dynamic optical effect or optical impression is observed if the OEL is tilted and, due to the loop shape, the effect can be observed regardless of the tilt direction of, for example , a banknote on which the OEL is provided. For example, the effect can be seen when a banknote carrying the OEL is tilted from left to right as well as up and down.
[080] The OEL's nested loop-shaped areas comprise the non-spherical magnetic or magnetizable particles and define a common central area. The outer shape(s) surrounding the central common area and one or more inner loop-shaped areas, preferably such that the nested loop-shaped areas do not intersect. As shown in Figure 21, in each of the loop-shaped areas of the OEL and in a cross section perpendicular to the plane of the OEL and extending from the center of the central area to the outer edge of the outermost loop-shaped area , the non-spherical magnetic or magnetizable particles in each of the loop-shaped areas follow a tangent to either the negatively curved part or the positively curved part of an ellipse or hypothetical circle (illustrated by circles in Figure 21A and by ellipses in Figure 21B) . In a cross-sectional view, the ellipse or circle for each loop-shaped area preferably has its center located along a perpendicular line from approximately the center of the width of the respective loop-shaped area, and/or the diameter of each of the circles and/or of the longer or shorter axis of each of the ellipses is approximately the same as the width of the respective area which forms a loop shape. Such orientation can also be expressed, such that the orientation of the major axis of the non-spherical magnetic or magnetizable particles follows the surface of a hypothetical semi-toroidal body resting in the plane of the optical effect layer, as illustrated in Figure 1.
[081] Preferably, the orientations of the non-spherical particles across the plurality of loop shapes follow the same curved part of the surface of a hypothetical toroidal-free body that lies in the plane of the OEL (that is, all following the tangent of a positively part the curve of a hypothetical ellipse or circle, or all following a tangent of the negatively curved part of an ellipse or hypothetical circle).
[082] In another preferred embodiment, the orientation of the non-spherical magnetic or magnetizable particles in their loop-shaped areas is alternated, such that, for example, the orientation of the non-spherical particles in the first (inner), third, fifth , etc. of the nested loop-shaped areas each follow a tangent of the negatively curved parts of the theoretical ellipses or circles, and where the orientation of the non-spherical magnetic or magnetizable particles in the second, fourth, etc. nested loop-shaped areas each follow a tangent to the positively curved parts of the theoretical ellipses or circles. Of course, the opposite orientation is also possible. Also, again, each of the hypothetical circles or ellipses has their respective centers preferably along hypothetical lines extending perpendicular to the OEL plane at positions that approximately correspond to the center of the area's width forming a loop shape in a cross-sectional view perpendicular to the surface of the OEL, and preferably the circles and ellipses have a longer or shorter diameter or axis, respectively, corresponding to the width of the respective area, as shown for the width of two loop-shaped areas in figures 21A and 21B . The orientation of particles in such an alternating arrangement is also illustrated in Figure 2b, where positions A, B and C correspond to the innermost parts of the nested loop-shaped areas, which is followed by a similar orientation on the right side of the figure. , forming the third loop-shaped area. Both in the innermost area and in the third loop-shaped, the orientation of the particles follows a tangent to the negatively curved part of the hypothetical ellipses, having its center along a line, extending from the middle of the respective area (the width ) and having a diameter corresponding to the width of the area. Between the innermost and the loop-shaped third area, the particles in the second loop-shaped area (to the center of Figure 2b) follow a tangent to the positively curved part of hypothetical ellipses, having their center along a line that extends from the middle of the respective area (the width). By providing an alternative arrangement, high contrast and a very striking optical effect can be achieved.
[083] The area in the central common area, surrounded by nested loop-shaped areas may be free of magnetic or magnetizable particles, in which case the void is usually not part of the OEL. This can be achieved by not supplying the coating composition in a vacuum when forming the OEL in the printing step.
[084] Alternatively and preferably, however, the central common area is part of the OEL and is not omitted when providing the coating composition to the substrate. This allows for easier fabrication of the OEL as the coating composition can be applied to a larger part of the substrate. In such a case, there are also non-spherical magnetic or magnetizable particles present in the common central area. They can have a random orientation, providing no particular effect other than a small reflection of light. However, preferably, the non-spherical magnetic or magnetizable particles present in the common central area are oriented such that their longest axis is substantially perpendicular to the plane of the OEL, thus providing little or no light reflection.
[085] The orientation of the non-spherical magnetic or magnetizable particles outside the outermost area of the plurality of nested loop-shaped areas can also be substantially perpendicular to the plane of the OEL, or it can be oriented randomly.
[086] Figure 1b depicts non-spherical magnetic or magnetizable particles (P) in an OEL (L) where the particles are fixed in the binding material, said particles, following the negatively curved part of a hypothetical ellipse (represented by a semi-toroidal body) . Figure 1c depicts non-spherical magnetic or magnetizable particles in an OEL, where the particles follow the positively curved portion of the hypothetical ellipse surface (represented by a semi-toroidal body).
[087] In Figures 1 and 21, the non-spherical magnetic or magnetizable particles are preferably dispersed throughout the entire volume of the OEL, while for the purpose of discussing their orientation within the OEL with respect to the OEL plane, preferably provided on a substrate, it is assumed that the particles are all located within the same planar cross-section of the OEL or similar. These non-spherical magnetic or magnetizable particles are each graphically represented by a short line representing their largest diameter that appears within their cross-sectional shape. In fact, as shown in Figure 14A, of course, some of the non-spherical magnetic or magnetizable particles may partially or fully overlap each other when viewed in the OEL.
[088] The total number of non-spherical magnetic or magnetizable particles in the OEL can be appropriately chosen depending on the desired application; however, to compose a surface coverage pattern generating a visible effect, thousands of particles, such as around 1,000 - 10,000 particles, are usually needed in a volume corresponding to one square millimeter of surface OEL.
[089] The plurality of non-spherical magnetic or magnetizable particles, which together produce the optical effect, can correspond to all or only a subset of the total number of particles in the OEL. For example, non-spherical magnetic or magnetizable particles nested in the loop-shaped areas of the OEL, producing the optical effect of nested loop-shaped bodies, can be combined with other particles contained in the binding material, which can be pigment particles of conventional or special color.
[090] In a particularly preferred embodiment of the present invention, the OEL described in this document may additionally comprise a so-called "protrusion", which is surrounded by the innermost loop-shaped element and partially fills the central area thus defined. The protrusion provides the illusion of a three-dimensional object, such as a half-sphere, present in the central area. The three-dimensional object apparently extends from the OEL surface to the viewer (similar to looking into a vertical or inverted concavity, depending on whether the particles follow a negative or positive curve), or apparently extends from the OEL away from the viewer. In these cases, the OEL comprises non-spherical magnetic or magnetizable particles in the central area, which are, in the region around the center of the central area, oriented, such as to have their longest axis substantially parallel to the plane of the OEL, forming the effect of the boss. The central area of the innermost dynamic loop shaped body is thus filled with a center effect picture element which can be a solid circle of a half sphere, for example in the case of loop shaped bodies it forms circles , or that it can have a triangular base in the case of triangular loop bodies. In such embodiments, at least a portion of the outer peripheral shape of the boss is similar to the shape of the innermost of the nested loop-shaped bodies, and the outer periphery of the boss preferably follows the shape of the innermost of the nested loop-shaped bodies (this that is, the protrusion is shaped like a solid circle or provides the optical effect or optical impression of a filled hemisphere when the loop-shaped areas are round, or it is a solid triangle or a triangular pyramid in the case the loop-shaped areas are triangles). According to an embodiment of the present invention, at least a part of the outer peripheral shape of the protrusion is similar to the shape of the innermost loop-shaped body, and preferably, the loop-shaped body is in the shape of a ring, and the protrusion it is shaped like a solid circle or half sphere. Particularly preferably, the outer peripheral shape of the protrusion is similar to the shape of all looped bodies, such as in a solid circle surrounded by several rings (such as 2, 3, 4, 5, 6, 7 or more) . One possible embodiment of such an embodiment is illustrated in Figure 21B. As shown at the top of Figure 21B, the central common area (2) is filled with a boss. In a cross-sectional view along a line (4) extending from the center (3) of the central common area (2) surrounded by the loop-shaped areas providing the optical effect or optical impression of two loop-shaped bodies ( 1), the orientation in the loop-shaped areas is the same as described above. In the area forming the bulge in the central area, the orientation of the non-spherical magnetic or magnetizable particles (5) follows a tangent of the positively curved or negatively curved part of a hypothetical ellipse or circle, the ellipse or circle preferably having its center along a line perpendicular to the cross-section (i.e., vertical in figure 21B) and located, such as extending through about the center (3) of the central common area surrounded by the innermost loop-shaped area (in the part of Figure 21B, only the part of the protrusion from the center to its boundary is shown). Additionally, the longest or shortest axis of the hypothetical ellipse or the diameter of the hypothetical circle is preferably approximately the same as the diameter of the protrusion, so that the orientation of the longest axis of the non-spherical particles at the center of the protrusion is substantially parallel to the plane of the OEL and substantially perpendicular to the plane of the OEL at the boundary of the boss. Again, in the common central area forming the bulge, the rate of change in orientation can be constant in such a cross-sectional view (the orientation of the particles follows a tangent to a circle) or it can vary (the orientation of the particles follows a tangent of a circle). Ellipse). In addition, preferably the change in orientation of the non-spherical magnetic or magnetizable particles on the protrusion follows the same direction as in the loop-shaped areas (following either a positive or a negative curvature), or the change in orientation follows alternating directions on the protrusion, the Monday, Wednesday, Friday, etc. of the nested loop-shaped areas and the first, third, fifth, etc. of the nested loop-shaped areas.
[091] Preferably, there is the optical impression of a gap between the inner edge of the innermost loop-shaped body and the outer edge of the protrusion. The optical impression of such a gap can be achieved by orienting non-spherical magnetic or magnetizable particles in the area between the inner boundary of the loop-shaped area and the outer boundary of the protrusion substantially perpendicular to the OEL plane or by orienting the magnetic particles or non-spherical magnetizables in the area between the inner boundary of the loop-shaped area and the outer boundary of the protrusion substantially with an opposite signal curve as compared to the protrusion curve and the innermost loop-shaped element. Additionally, the protrusion preferably occupies about at least 20% of the area defined by the inner boundary of the innermost of the nested loop-shaped areas, more preferably about at least 30% and most preferably about at least 50%.
[092] Next, referring to Figures 3-20 and 23-25, a description will be given of the magnetic field generating devices of the present invention, which are capable of orienting non-spherical magnetic or magnetizable particles in the OEL to provide reflection of light in nested loop-shaped areas, thereby forming the OEL providing the optical impression of a plurality of nested loop-shaped bodies of the present invention. Alternatively, the magnetic field generating devices described in this document can be used to provide a partial OEL, ie a security feature displaying part or parts of loop shapes, such as eg % circles, % circles, etc. .
[093] In the broadest aspect, the magnetic field generating device of the present invention comprises a plurality of elements selected from magnets and pole pieces and comprising at least one magnet, the plurality of elements being or (i) located below a surface of support or a space configured to receive a substrate acting as a support surface or (ii) forming a support surface and being configured, such as to be able to provide a magnetic field in which the magnetic field lines run substantially parallel to said support surface or space in two or more areas above said support surface or space, and wherein i) the two or more areas from nested loop-shaped areas surrounding a central area; and/or ii) the plurality of elements comprises a plurality of magnets and the magnets are arranged rotating about an axis of rotation such that areas with field lines running substantially parallel to the bearing surface or space combine upon rotation around the axis of rotation, thereby forming, upon rotation about the axis of rotation, a plurality of nested loop-shaped areas surrounding a central area. The magnetic field generating devices of the present invention can therefore be generally classified into static magnetic field generating devices (option i)) and rotational magnetic field generating devices (option ii)). In static magnetic field generating devices, the OEL loop-shaped areas where the orientation of non-spherical magnetic or magnetizable particles is to be effected are reflected in the design of the magnetic field generating device. Put differently, in static magnetic field generating devices, no movement of the magnetic field generating devices with respect to the coating composition comprising the non-spherical magnetic or magnetizable particles is necessary to orient the non-spherical magnetic or magnetizable particles in the areas in nested loop shape, and the orientation of non-spherical magnetic or magnetizable particles in the nested loop shape areas is achieved by putting the coating composition or a support bringing the coating composition into a first state in contact with or near the device magnetic field generator. On the other hand, in rotational magnetic field generating devices, the loop shape of the nested loop-shaped areas is not as such reflected in the design of the magnets of the magnetic field generating device, but rather the orientation of the magnetic particles or Non-spherical magnetizable elements in the OEL's loop-shaped areas are affected by a loop-shaped movement of the magnets of the magnetic field generating devices in relation to the support or a support surface of a magnetic field generating device leading to the coating composition in a first state.
[094] In one embodiment, the magnetic field generating devices of the present invention typically comprise a support surface, above or on which a layer (L) of the coating composition in a fluid state (before hardening) and comprising the plurality of non-spherical magnetic or magnetizable particles (P) is provided. This support surface is positioned at a given distance (d) from the poles of the magnet(s) (M) and is exposed to the mean magnetic field of the device.
[095] Such a supporting surface may be a part of a magnet that is part of the magnetic field generating device. In such an embodiment, the coating composition can be directly applied to the bearing surface (the magnet), where orientation of the non-spherical magnetic or magnetizable particles takes place. After orienting or simultaneous with orientation, the binding material is converted to a second state (eg irradiation in the case of a radiation curable composition), forming a hardened film that can be removed from the bearing surface of the field generating device magnetic. In this way, an OEL in the form of a film or sheet can be produced, in which the oriented non-spherical particles are fixed in a binder material (usually a transparent polymeric material in this case).
[096] Alternatively, the supporting surface of the magnetic field generating device of the present invention is formed by a thin plate (usually less than 0.5mm thick, such as 0.1mm thick) made of a non-material material. magnetic, such as a polymeric material or a metal plate made of a non-magnetic material, such as, for example, aluminium. Such a plate forming the bearing surface is provided above the one or more magnets of the magnetic field generating device. Then, the coating composition can be applied to the board (the bearing surface), followed by orienting and hardening the coating composition, forming an OEL in the same manner as described above.
[097] Naturally, in both of the above embodiments (where the supporting surface is either part of a magnet or is formed by a plate above a magnet), a substrate (made, for example, of paper or any other substrate described below) in which the coating composition is applied may also be provided on the bearing surface, followed by orientation and setting. Perceptibly, the coating composition can be provided on the substrate before the substrate with the applied coating composition is placed on the bearing surface, or the coating composition can be applied to the substrate at a point in time where the substrate is already placed on the surface. of support. In either case, the OEL can be provided on a substrate, which is a preferred embodiment of the present invention.
[098] However, if the OEL is to be provided on a substrate, the substrate can also assume the role of a support surface, replacing the plate. In particular if the substrate is dimensionally stable, it may not be necessary to provide, for example, a plate to receive the substrate, but the substrate can be provided on or above the magnet without a backing plate interposed between them in a space of the generator. magnetic field that is configured to receive a substrate (ie, the space that would otherwise be taken up by the backplate). In the following description, the term "support surface", in particular with respect to the orientation of magnets relative thereto, may in such embodiments therefore relate to a position or plane which is taken up by the substrate surface without a plate intermediate being provided, i.e. where the substrate replaces the support surface. In the following, the term "support surface" may therefore be replaced by "substrate" or "space configured to receive a substrate" in order to describe such modalities. For the sake of brevity, this is not explicitly stated in each case.
[099] One embodiment of a static magnetic field generating device in accordance with the present invention is one in which an axially magnetized loop-shaped dipole magnet is provided such that the north-south axis is perpendicular to the bearing surface or space, wherein the loop-shaped magnet surrounds a central area, and the device further comprises a pole piece which is provided below the axially magnetized loop-shaped dipole magnet, with respect to the bearing surface, or space and which closes one of the sides of the loop formed by the loop-shaped magnet, and where the pole piece forms one or more projections extending into the space surrounded by the loop-shaped magnet and being spaced from there, where a1) the pole piece forms a projection which extends into the central area surrounded by the loop-shaped magnet, where the projection is laterally spaced away from the loop-shaped magnet and fills a portion of the central area. A possible embodiment of such a device is schematically represented in Figure 3a. Described differently, the device comprises a loop-shaped (M) dipole magnet (a ring in Figure 3a) positioned on a periphery of the device, which is magnetized in the axial direction (ie, the north-south direction points towards or away from the support surface or substrate (S) carrying the coating composition in a first state, forming the layer (L). The device additionally comprises a pole piece, in this case an inverted T-shaped iron connection (Y), which is provided below the magnet in a loop shape and closes one side of the loop opposite the side where the supporting surface (S) carrying the coating composition in a first state is to be provided. A pole piece denotes a structure composed of a material having high magnetic permeability, preferably a permeability between about 2 and about 1,000,000 NA'2 (Newton per square Ampere), more preferably between about 5 and about 50,000 N A'2 and even more preferably in between about 10 and about 10,000 NA'2. The pole piece serves to direct the magnetic field produced by a magnet. Preferably, the pole piece described in this document comprises or consists of an inverted T-shaped iron connection (Y). The pole piece additionally extends from this side into the center of the space surrounded by the loop-shaped magnet (M). In a cross-sectional view, the device is thus shaped like an inclined E, as shown in the left part of Figure 3a, with the top and bottom lines of the E being formed by the loop-shaped magnet (M ) and the rest of the E-frame through the pole piece (Y). The device and the three-dimensional field of the magnet (M) in space are rotationally symmetric with respect to a central vertical axis (z).
[0100] As derivable from the field lines in Figure 3a, the device leads to the orientation of non-spherical magnetic or magnetizable particles (P), such as to provide the impression of two closed bodies in a loop format, each in the shape of a ring.
[0101] Additionally, it is immediately evident that the field lines at a given position on the support surface or substrate (S), which determine the orientation of the magnetic or magnetizable particles (P), vary with the distance (d) from the surface of support or substrate (S) of the magnet of the magnetic field generating device. In the present invention, the distance (d) between the supporting surface or the substrate surface (S) on the side facing the magnetic field generating device and the surface closest to a magnet of the magnetic field generating device is generally in the range between 0 to about 5 millimeters, preferably between about 0.1 and about 5 millimeters, and is selected such as to produce the appropriate dynamic loop shaped element, according to the needs of the project. The support surface can be a support plate that preferably has a thickness equal to distance (d), which allows a mechanically solid mounting of the magnetic field generating device, without intermediate central areas. The bearing surface may be a bearing plate made of a non-magnetic material such as a polymeric material or a non-magnetic metal, for example aluminium. If distance (d) is too great, the orientation of the non-spherical magnetic or magnetizable particles in the loop-shaped element may not give the impression of well-defined loop-shaped bodies, ie the visual effect or visual impression may be blurred, and it can be difficult to distinguish between or analyze loop shapes or different loop-shaped bodies. This problem does not occur if there is direct contact with the magnetic field generating device, it may still be preferable for production purposes to have a small gap (eg less than 3 mm, preferably less than 1 mm) between the magnetic field generating device and the substrate in order to avoid contact of the substrate - or the coating composition in a first state present therein - with the magnetic field generating device, in particular if the magnetic field generating device is positioned on the same side of the substrate as the coating composition is applied (in order to obtain an orientation of the particles in the loop-shaped areas that follow a tangent to a positively curved part of a hypothetical ellipse, in particular a hypothetical circle, as shown in Figure 1c). Of course, the above applies not only to the magnetic field generating device shown in Figure 3a, but to all static and rotational magnetic field generating devices of the present invention.
[0102] Figure 3b shows photographs of the resulting OEL, comprising two loop-shaped bodies nested in the form of concentric rings surrounding a common central area. The photograph in the middle of Figure 3b shows a plan view of the OEL, and the photographs on the left and right of Figure 3b show the OEL when viewed from a left or right direction to the normal OEL, respectively. As seen in these figures, the optical effect or optical impression is dynamic, that is, the rings appear to move by changing the angle of view: In the photograph on the left, the distance between the inner and outer rings appears to be smaller on the side. left of the inner ring than on the right side of the inner ring, whereas the opposite effect is observed if the OEL is viewed from the other side, as in the photograph to the right of Figure 3b.
[0103] In another embodiment of the present invention related to a magnetic field generating device in which an axially magnetized dipole magnet in a loop shape is provided such that the north-south axis is perpendicular to the support surface or space, in which the magnet loop-shaped surrounds a central area, and the device further comprises a pole piece which is provided below the axially magnetized dipole magnet in a loop shape, with respect to the supporting surface, or space and which closes one side of the loop. formed by the loop-shaped magnet, and wherein the pole piece forms one or more projections extending into the space surrounded by the loop-shaped magnet and being spaced away from there, where a2) the pole piece forms a shaped projection loop and surrounds a central bar dipole magnet having the same north-south direction as the loop magnet, the projection and bar dipole magnet being spaced apart. A possible realization of such a device is schematically illustrated in Figure 4. The device is similar to that of Figure 3 in that it also comprises a loop-shaped ring magnet (M2) on the periphery of the device, which is magnetized in the axial direction ( that is, the north-south direction points towards or away from the surface bringing the coating composition into a first state). In addition, the device has the pole piece (an iron connection (Y)) positioned below, ie opposite to the side where the support surface or substrate (S) carrying the coating composition in a first state, must be provided , in a shape corresponding to the magnet's loop shape (M) and close one side of the loop. The pole piece also extends from this side into the central area surrounded by the loop-shaped magnet, although, unlike in Figure 3, this extension of the pole piece is not solid but defines another inner loop. Within this inner loop formed by the extension of the pole piece, a bar dipole magnet (M1) having the same orientation as the north-south magnetic direction is positioned. In a cross-sectional view (left in Figure 4), the pole piece takes on a double inverted T-shape.
[0104] Again, in the mode shown in Figure 4, the magnetic field generating device and the magnetic field generated in this way are rotationally symmetric to a central vertical axis (z). Additionally, as derivable from the field lines shown in Figure 4, such a device will lead to the orientation of the non-spherical magnetic or magnetizable particles, as defined in claim 1, in three loop-shaped areas (ring shape in Figure 4) of OEL provided on the support surface or substrate (S), leading to the visual impression of three nested rings surrounding a central area.
[0105] An alternative embodiment of a static magnetic field generating device of the present invention is one in which an axially magnetized dipole magnet in a loop shape is provided such that the north-south axis is perpendicular to the bearing surface or space, where the loop-shaped magnet surrounds a central area, and the device further comprises a pole piece which is provided below the magnetized dipole magnet axially in a loop with respect to the supporting surface or space and which closes one side of the loop formed by the loop-shaped magnet, and wherein the pole piece forms one or more projections extending into the space surrounded by the loop-shaped magnet and being spaced away from there, where a3) the pole piece forms two or more projections interspaced, or all of these or all but one of these are loop-shaped, and, depending on the number of projections, one or more additional axially magnetized loop-shaped magnets having the same north-south direction as the first axially magnetized loop-shaped magnet is/are provided in the space formed between the interspaced loop-shaped projections, the additional magnets being spaced from the loop-shaped projections, and in which the central area surrounded by the shaped projections loop and loop-shaped magnets is partially filled with either a central bar dipole magnet having the same north-south direction as the surrounding loop-shaped magnets or with a central projection of the pole piece such that, as seen in from the supporting surface or in space, an alternating array of interspaced loop-shaped pole piece projections and axially magnetized loop-shaped dipole magnets is formed, surrounding a central area, where the central area is filled or with a magnet bar dipole or a center projection as set out above. A possible embodiment of such a device is illustrated in Figure 5. The device is similar to Figures 3 and 4 in that it also comprises a loop-shaped ring magnet (M1) on the periphery of the device, which is magnetized in the axial direction. (ie the north-south direction points towards or away from the support carrying the coating composition in a first state, not shown in Figure 5). In addition, the device has the pole piece (an iron connection (Y)) positioned below, i.e., opposite the side where the support surface or substrate (S) carrying the coating composition in a first state is to be provided, in a shape corresponding to the loop shape of the magnet (M1) and close one side of the loop. As seen in the right part of Figure 4, the pole piece of the device in Figure 5 extends from the side of the closed loop, forming an (inner) loop within the space defined by the loop-shaped magnet (M1). Within this inner loop defined by the length of the pole piece (Y), another loop-shaped magnet (M2) is provided, defining a more internal space. The pole piece then also extends to the space within this innermost space in a similar manner as shown in Figure 3. In a cross-sectional view, the pole piece takes on an inverted triple-T shape.
[0106] As derivable from the field lines shown in Figure 5, such a device will lead to the orientation of non-spherical magnetic or magnetizable particles in four loop-shaped areas (ring shape in Figure 5) on the support surface or substrate (S), leading to the visual impression of four nested rings surrounding a central area.
[0107] From the description of the devices above and as illustrated in Figures 3, 4 and 5, it is immediately evident that similar devices can be used to achieve an orientation of non-spherical magnetic or magnetizable particles in a larger number of shaped areas. loops nested in a substrate by modifying the structure of a central part (being either an extension of a pole piece or a bar dipole magnet having its magnetic axis essentially perpendicular to the substrate surface, such as the M1 magnet in Figure 4) and alternately providing loop-shaped magnets or loop-shaped extensions of the pole piece, respectively, thereby forming, for example, five, six, seven or eight nested loop-shaped areas.
[0108] It is also evident that an orientation of non-spherical magnetic or magnetizable particles in areas on the substrate defining different loop shapes from a circle or ring (for example, triangles, squares, pentagons, hexagons, heptagons or octagons) can be achieved by modifying the shape of the loop-shaped magnets and the loop-shaped pole piece (Y) in these devices.
[0109] In the embodiments illustrated in Figures 3 to 5, except for the center bar dipole magnet (as shown in Figure 4), loop-shaped magnets are used. However, it is possible to obtain similar effects using bar magnets if the shape of the pole piece is adapted accordingly. Examples of such additional embodiments of the magnetic field generating device of the present invention are shown in Figures 6a to 6d.
[0110] Figures 6a, bed illustrate possible embodiments of an embodiment of the magnetic field generating device of the present invention, in which the device comprises two or more bar dipole magnets and two or more polar pieces, wherein the device comprises a number the same as polar parts and bar dipole magnets, in which the bar dipole magnets have their north-south axis substantially perpendicular to the support surface or space, have the same north-south direction and are provided at different distances from the support surface or space, preferably along a line extending perpendicular from the support surface or space and spaced apart; and the polar pieces being provided in the space between and in contact with the bar dipole magnets, wherein the polar pieces form one or more projections which, in a loop-shaped form, surround a central area in which the bar dipole magnet located close to the support surface or space is located.
[0111] Specifically, in Figure 6a, there is a central bar dipole magnet having an axial north-south orientation. Below the central (upper) bar dipole magnet an upper pole piece is arranged which, spaced apart, laterally surrounds the bar dipole magnet, forming a closed loop format in which one side of the loop is closed. Instead of left or right to the side surrounding part of the pole piece, as in Figures 4 and 5, a lower bar dipole magnet having the same north-south orientation as the central (upper) bar dipole magnet is arranged below the pole piece. higher. The upper pole piece is in contact with one of the poles of the upper bar dipole magnet and the (opposite) pole of the lower bar dipole magnet. Additionally, a lower pole piece is provided below the lower bar dipole magnet, which also in a loop shape, laterally and spaced apart, surrounds the lower bar dipole magnet and also the upper pole piece. In addition, there is a defined side space between the loop-shaped shape of the lower polar piece and the loop-shaped shape of the upper polar piece.
[0112] The field lines caused by the magnetic field generating device illustrated in Figure 6a extend from the north pole of the central magnet to the extension of the upper pole piece surrounding the upper bar dipole magnet and from the extension of the upper pole piece encircling the upper bar dipole magnet to the extension of the lower pole piece which, laterally and spaced apart, surrounds the lower bar dipole magnet, the upper pole piece, and the central magnet, as shown in Figure 6a. Consequently, non-spherical magnetic or magnetizable particles are oriented along field lines, which include regions that are substantially parallel to the bearing surface in the areas between the central (upper) bar dipole magnet and the extension of the upper pole piece surrounding it. and between the extension of the upper pole piece surrounding the center magnet and the extension of the lower pole piece surrounding the center magnet (ie, in the area above the defined space between the two pole pieces). Consequently, this device is capable of orienting non-spherical magnetic or magnetizable particles in two nested loop-shaped areas.
[0113] An alternative but similar arrangement is illustrated in Figure 6b. Here, the bottom of the lower pole piece in Figure 6a is replaced by a plate-shaped magnet (a flat bar dipole magnet). The configuration in Figure 6b allows the orientation of non-spherical magnetic or magnetizable particles into three loop-shaped areas, two inner loop-shaped areas in a similar manner as in Figure 6a, and an additional loop-shaped area caused by the field lines extending from the outermost loop shape of the polar (outer) piece surrounding the upper (inner) polar piece to the bottom of the lower plate-shaped bar magnet (the south pole of the lower magnet in Figure 6b).
[0114] Figure 6d illustrates an additional alternative arrangement of the magnetic field generator device. Essentially, the magnets and pole piece have the same configuration as in figure 6a, although the extension of the lower pole piece laterally encircles, in a loop shape and spaced apart, the top pole piece, the top center magnet and the bottom magnet are missing. As a result, the origin and destination of the field lines have a different distance from the support surface bringing the coating composition into a first state, leading to a very interesting three-dimensional effect, as shown in figure 6e. Figure 6e shows an OEL obtained using a device having the configuration illustrated in Figure 6d. The OEL is shown to give the impression of three nested rings, where the inner and outer rings extend from the surface of the OEL, and where the intermediate ring appears to be submerged below the surface. In the inner and outer rings, the long axis orientation of non-spherical magnetic or magnetizable pigments follows a tangent of a negatively curved part of the circle, and in the intermediate ring, the longest axis orientation of non-spherical magnetic or magnetizable pigments follows a tangent of a positively curved part of the circle. Additionally, the change in the orientation of the particles forming the impression of the outer ring is less rapid (ie, the curvature appears to be smaller, or, in other words, the radius of the theoretical circle to a tangent whose orientation the particles follow is larger).
[0115] In another embodiment, the present invention relates to a magnetic field generator device, in which two or more loop-shaped dipole magnets are provided such that its north-south axis is perpendicular to the support surface or space, the two or more loop-shaped magnets being arranged nested, spaced apart and surrounding a central area, the magnets being axially magnetized and adjacent to the loop-shaped magnets have opposite north-south directions pointing either towards or away from the supporting surface or space , the device additionally comprising a bar dipole magnet provided in the central area surrounded by the loop-shaped magnets, the bar dipole magnet having its north-south axis substantially perpendicular to the supporting surface and parallel to the north-south axis of the magnets at loop shape, the north-south direction of the bar dipole magnet being opposite to the north-south direction of the innermost loop-shaped magnet. Such a device is illustrated in Figure 24. The device may optionally further comprise a pole piece on the side opposite the support surface or space and in contact with the central bar dipole magnet and the loop-shaped magnets. Such a device is illustrated in Figure 6c.
[0116] Figure 6c shows the combination of an axially magnetized bar dipole magnet (M) in the center and two axially magnetized dipole magnets in the shape of a loop with a single polar piece (iron (Y) connection). The orientation of the magnetic direction of the magnet is switched from the center to the periphery of the loop-shaped magnetic field generating device.
[0117] In another embodiment, the present invention relates to a magnetic field generator device comprising a bar dipole magnet located below the support surface or space and having its north-south direction perpendicular to said support surface or space, one or more loop-shaped polar pieces arranged above the magnet and below the support surface or space, which, for a plurality of loop-shaped polar pieces, are arranged spaced apart and nested coplanar, to one or more laterally encircling polar pieces a central area under which the magnet is located, the device further comprises a first pole piece having a plate-like base of approximately the same size and approximately the same external peripheral shape as the outermost loop-shaped pole piece, the plate-like pole piece being arranged below the magnet such that its outer peripheral shape is superimposed with the periphery of the outermost of the pole pieces looped in the direction of the support surface or space, and which is in contact with one of the poles of the magnet; and a central pole piece in contact with respectively the other pole of the magnet, the central pole piece having the outer peripheral shape of a loop, in part filling the central area and being laterally and spaced from and surrounded by the one or more pole pieces at loop format. One possible embodiment of such a device is schematically represented in Figure 7a. The first pole piece may also be complemented by one or more projections extending from the plate-like base, which laterally and spaced apart encircle the central magnet, as illustrated schematically in Figures 7b and 7d.
[0118] The device may additionally comprise a second plate-like pole piece having the outer peripheral shape of a loop, which is provided in a position above and in contact with a pole of the magnet and below and in contact with one or more loop-shaped pole pieces and below and in contact with the center pole piece so that the center pole piece is no longer in direct contact with the magnet pole, the second plate-type pole piece being approximately the same size and shape than the first plate-like pole piece. One possible embodiment of such a device is schematically represented in Figure 7c.
[0119] It has been found that the magnetic field from the poles of a bar dipole magnet (M) can be channeled through a set of coplanar nested loop-shaped polar pieces, such as iron connections (Y1, Y2, Y3, Y4), having magnetic gaps reflecting the loop shape between them (annular iron connections in figure 7a and 7b). The magnetic fields at the locations of said gaps are suitable for producing clustered ring-effect picture elements of different sizes.
[0120] Figure 7a shows a device comprising a bar dipole magnet (M) magnetized in the axial direction and arranged with a magnetic pole on an iron plate (Y). A set of coplanar nested annular iron connections (Y1, Y2, Y3, Y4) is disposed on the other magnetic pole (N) of the bar dipole magnet (M). Figure 7b shows a device, in which the iron plate (Y) is replaced by a U-shaped iron connection (Y), thereby forming a polar piece whose loop-shaped base is complemented by one or more projections. extending from the plate-like base, which laterally and spaced apart surround the central magnet.
[0121] As shown in figures 7c and 7d, the set of coplanar nested loop-shaped polar pieces (iron connections) can be complemented with a second plate-like polar piece having the outer peripheral shape of a loop, which is provided at a position (i) above and in contact with a pole of the magnet and (ii) below and in contact with one or more loop-shaped pole pieces and the center pole piece so that the center pole piece is no longer in direct contact with the pole of the magnet, the second plate-type pole piece being approximately the same size and shape as the first plate type pole piece. In combination this corresponds to an engraved plaque as shown in the top part of figures 7c and 7d. Such engraved plate in particular and also the pole pieces used in the present invention, in general, can be made of iron (iron connections), but they can also be made of a plastic material in which the magnetic particles are dispersed, as used in the Figures 7c and 7d. This is, therefore, an alternative embodiment of the magnetic field generating device of the present invention which also comprises at least one pole piece.
[0122] Figures 3 to 7 show modalities of static magnetic field generator devices of the present invention. In the following, modalities of the rotational magnetic field generating devices will be described, as illustrated in Figures 8-20, 23 and 24. As known to the person skilled in the art, the speed and number of rotations per minute used by the rotational magnetic field generating devices described in this document are adjusted to orient non-spherical magnetic or magnetizable particles as described in this document, that is, to follow the tangent or a negatively curved or positively curved portion of a hypothetical ellipse.
[0123] A common feature of all rotational magnetic field generating devices of the present invention is that they comprise one or more magnets that are provided rotatable about an axis of rotation and spaced apart from the axis of rotation (z). Additionally, the axis of rotation is provided substantially perpendicular to the plane in which the support surface or substrate (S) is provided in orienting the non-spherical magnetic or magnetizable particles. When an unequal number of magnet(s) is used and for reasons of mechanical balance, an additional dummy part having approximately the same size/weight and provided at approximately the same distance from the axis of rotation can be used.
[0124] In the following description of rotational magnetic field generating devices, the orientation of the magnetic north-south direction of a magnet that is provided spaced apart from the axis of rotation is expressed in relation to the axis of rotation, so that or the magnetic axis of such a magnet is parallel to the axis of rotation (the north-south direction is pointing either towards the substrate surface or away from it), or the magnetic axis is substantially radial to the axis of rotation and substantially parallel to the bearing surface on which the coating composition or a substrate comprising the coating composition must be provided (or in relation to a space configured to receive the substrate acting as a support surface) and the north-south direction or pointing towards or away from the axis of rotation. In the context of magnetic field generating devices in which multiple magnets are provided rotating about an axis of rotation and the north-south magnetic axis is radial to the axis of rotation, the expression "symmetrical magnetic north-south direction" means the orientation from the north-south direction is symmetric with respect to the axis of rotation as the center of symmetry (ie, the north-south direction of all multiple magnets either points away from the axis of rotation or the north-south direction of all multiple magnets towards you). In the context of magnetic field generating devices in which multiple magnets are provided rotatable about an axis of rotation and the north-south magnetic axis is radial to the axis of rotation and parallel to the bearing surface or substrate surface, the expression " Asymmetric magnetic north-south direction" means that the orientation of the north-south direction is asymmetric with respect to the axis of rotation as the center of symmetry (that is, the north-south direction of one of the magnets points towards and the north-south direction of the magnets. other magnet points away from the axis of rotation).
[0125] Rotational magnetic field generating devices can be further divided into rotational magnetic field generating devices that are capable of orienting non-spherical magnetic or magnetizable particles present in a coating composition in a first state on a substrate such that , in a plurality of nested loop-shaped areas, the non-spherical magnetic or magnetizable particles are oriented, such as to provide the optical appearance of a plurality of nested loop-shaped bodies surrounding a central area where the central area is apparently "empty" and such rotational magnetic field generating devices in which the central area comprises a "bulge". The protrusion provides the impression of a three-dimensional object, such as a half-sphere, present in the central area surrounded by the loop-shaped bodies. The three-dimensional object apparently extends from the surface of the OEL to the viewer (similar to looking into a vertical or inverted concavity, depending on whether the particles follow a negative or positive curve), or extends from the OEL to away from the viewer. In these cases, the OEL comprises non-spherical magnetic or magnetizable particles in the central area that are oriented substantially parallel to the plane of the OEL, providing a reflection zone.
[0126] In cases where the central area is apparently empty, the central area defined by the innermost of the nested loop-shaped bodies is either free of non-spherical magnetic or magnetizable particles or the central area comprises such particles either in a random orientation or preferably in such an orientation that the longest axis of the particles is substantially perpendicular to the plane of the OEL. In the latter case, particles normally provide only little reflectivity.
[0127] In the case where the central area comprises a "bump", there is a region in the central area - usually in the center of the central area - in which the particles are oriented, such that its longest axis is substantially parallel to the plane of the OEL, thereby providing a reflection zone. Perceptibly, there is preferably the optical impression of a gap between the "bulge" and the innermost loop-shaped body. This can be achieved by the absence of particles in this area, but it is very normal and preferably achieved by orienting particles in this area, such that its longest axis is substantially perpendicular to the plane of the OEL/substrate surface. More preferably, the particles within the central area forming the center of the protrusion and the particles at the center of the width of the loop-shaped area forming the optical appearance of the innermost loop-shaped body are oriented substantially parallel to the substrate surface and the plane of the OEL, and the orientation of the particles between these areas gradually changes from substantially parallel to substantially perpendicular and again to substantially parallel along a line extending from the center of the central area to the center of the area defining the shaped body. innermost loop, as illustrated in part in Figure 21B (not showing the area between the loop-shaped area and the central area where a substantially perpendicular orientation of the particles is present). Such particle orientation can be achieved by rotational magnetic field generating devices capable of forming a "bump" described below.
[0128] In embodiments of the present invention, the rotational magnetic field generating device comprises two or more bar dipole magnets that are arranged below the supporting surface or spaced apart configured to receive a substrate, and which are arranged such as to be rotatable in around an axis of rotation that is perpendicular to the support surface or space, the two or more bar dipole magnets being spaced apart from the axis of rotation and each other and provided symmetrically on opposite sides of the axis of rotation, the device optionally comprising additionally, a bar dipole magnet which is arranged below the support surface or space and about the axis of rotation, or wherein e1) the device comprises, on both sides of the axis of rotation, one or more bar dipole magnets in bar, all having their north-south axis substantially perpendicular to the support surface or space and substantially parallel to the axis of rotation, the north-south direction of all magnets are identical. unique with respect to the support surface or space and the magnets being spaced apart [as illustrated in Figures 8 and 14], the device optionally comprising a bar dipole magnet that is arranged below the support surface or space and over the axis of rotation, the north-south axis thereof being substantially perpendicular to the bearing surface or space, and substantially parallel to the axis of rotation, and whose north-south direction is both identical to the north-south direction of the magnets which are arranged rotating about from the axis and spaced from this point [as shown in Figures 10, 23a] or oppositely [as shown in Figure 9]; e2) no optional bar dipole magnets on the axis of rotation are present and the device comprises, on both sides of the axis of rotation, two or more bar dipole magnets arranged spaced apart from each other and of the axis of rotation, the north axis. south of the magnets being substantially perpendicular to the bearing surface or space and substantially parallel to the axis of rotation, and wherein the magnets provided on both sides of the axis have alternating north-south directions, and the more internal magnets, with respect to the axis of rotation, have symmetrical [Figure 13] or opposite north-south directions [as illustrated in Figure 18]; e3 no optional bar dipole magnets on the axis of rotation are present and the device comprises, on both sides of the axis of rotation, two or more bar dipole magnets arranged spaced apart from each other and of the axis of rotation, the north-south axis of the magnets being substantially perpendicular to the bearing surface or space and substantially parallel to the axis of rotation, and wherein the magnets provided on both sides of the axis have symmetrical north-south directions with respect to the axis of rotation and the magnets provided on different sides the axis of rotation have opposite north-south directions [as illustrated in Figure 19]; e4) the device comprises, on both sides of the axis of rotation, one or more bar-dipole magnets that are arranged spaced apart from the axis of rotation and, if more than one magnet is present on one side, spaced apart from each other, the north axis -south of the magnets being substantially parallel to the bearing surface or space and substantially radial to the axis of rotation, and the north-south directions of the one or more magnets on one side of the axis or rotation point towards the axis of rotation, while the directions north-south one or magnets on the other side of the axis or rotation point away from the axis of rotation, so that the respective north-south directions are in line from the outermost magnet on one side to the outermost magnet on the other side of the axis of rotation (ie, the north-south directions of the innermost magnets are asymmetrical with respect to the axis of rotation and the magnets are arranged such that the north-south directions of all magnets essentially point in the same direction), or wherein additionally e4-1) no magnet o Optional is provided on the axis of rotation and at least two magnets are provided on either side of the axis of rotation [Figure 20]; or e4-2) an optional magnet is provided on the axis of rotation, the magnets on both sides being arranged away from this point, the magnet on the axis of rotation, being a bar dipole magnet having its north-south axis substantially parallel to the bearing surface and its north-south direction pointing in the same direction as the magnets provided on either side of the axis or rotation (ie, in line with the north-south directions of magnets arranged away from the axis of rotation, from the outermost magnet on one side of outermost magnet on the other side of rotation axis) [as illustrated in Figure 16]; e5) the device does not comprise any optional magnets provided on the axis of rotation and comprises, on both sides of the axis of rotation, two or more bar dipole magnets that are arranged spaced apart from the axis of rotation and spaced apart, the north axis -south of the magnets being substantially parallel to the bearing surface or space and substantially radial to the axis of rotation, wherein the north-south directions of all magnets are symmetrical with respect to the axis of rotation (i.e., all pointing towards or toward away from the axis of rotation) [as illustrated by an embodiment in Figure 12]; e6) the device does not comprise any optional magnets provided on the axis of rotation and comprises, on both sides of the axis of rotation, one or more pairs of bar dipole magnets arranged spaced from the axis of rotation and spaced apart from each other, the north axis -south of all magnets being substantially parallel to the supporting surface or space and substantially radial to the axis of rotation, and each pair of magnets being formed by two magnets with opposite north-south directions pointing towards each other or away from each other, respectively, and wherein the innermost magnets of the innermost magnet pairs on each side each have e6-1) symmetrical north-south directions with respect to the axis of rotation, both pointing either away or towards the axis of rotation [ as illustrated in Figure 11]; or e6-2) asymmetric (opposite) north-south direction with respect to the axis of rotation, one pointing away and one toward the axis of rotation [as illustrated in Figure 17]; or e7) or device e7-1) comprises the optional bar dipole magnet on the axis of rotation and one or more magnets on either side of the axis of rotation, the north-south axis of all magnets being substantially parallel to the bearing surface and the north-south axis of the magnets on either side of the axis of rotation is essentially radial to the axis of rotation; or e7-2) the device does not comprise the optional bar dipole magnet on the axis of rotation and comprises two or more magnets on either side of the axis of rotation that are arranged spaced apart from the axis of rotation, the north-south axis of all the magnets being substantially parallel to the bearing surface or space and substantially radial to the axis of rotation, in which case the north-south directions of the magnets arranged on one side of the axis of rotation are asymmetric to the north-south directions of the arranged magnets. on the other side of the axis of rotation relative to the axis of rotation (that is, pointing towards the axis of rotation on one side and away from the axis of rotation on the other side), such that the north-south directions are in line with the outermost magnet on one side to outermost magnet on the other side, the magnet on the axis of rotation in case e7-1 being aligned on this line [as illustrated in Figures 15 and 23c]; e8) the device comprises, on both sides of the axis of rotation, two or more bar dipole magnets all having their north-south axes substantially perpendicular to the bearing surface or space and substantially parallel to the axis of rotation, and optionally a dipole magnet bar arranged about the axis of rotation and also having its north-south axis substantially perpendicular to the bearing surface or space and substantially parallel to the axis of rotation; the north-south direction of adjacent magnets being opposite to the supporting surface or space, and the magnets being spaced (Figure 23 b1) from each other; or e9) the device comprises, on both sides of the axis of rotation, two or more bar dipole magnets all having their north-south axes substantially parallel to the bearing surface or space and substantially radial to the axis of rotation, and optionally a magnet bar dipole arranged about the axis of rotation and also having its north-south axis substantially parallel to the bearing surface or space and substantially perpendicular to the axis of rotation; the north-south directions of adjacent magnets pointing in opposite directions, and the magnets being spaced [as illustrated in Figure 23d1] from each other; In this document, "adjacent" magnets are magnets that are placed next to each other.
[0129] Figure 8 schematically represents a modality of a magnetic field generator device comprising two bar dipole magnet magnets (M) spaced apart from an axis of rotation (z), the magnets having their magnetic axis substantially perpendicular to the supporting surface or substrate (S) and substantially parallel to the axis of rotation and to the same magnetic north-south direction pointing away from the bearing surface (S). As is apparent from the field lines (F) shown in Figure 8, the magnetic or magnetizable (P) particles in the coating layer (L) of the coating composition in a first state, which are present in the areas to the left and to the right of each magnet, are oriented to be substantially parallel to the supporting surface (S). By rotating the magnets around the axis of rotation (z), two loop-shaped bodies (rings in Figure 8) are formed. Also as derivable from the field lines, the particles present in the central area on the axis of rotation are either not oriented at all or too oriented to have their longest axis substantially perpendicular to the support surface (S), so that none bulge is formed.
[0130] Of course, in another modality the arrangement in Figure 8 can be changed by reversing the north-south direction of the magnets, or by providing additional magnets around the axis of rotation in the same orientation as the north-south direction, for example , three, four, five or six magnets. This allows you to reduce the amount of rotation that is required to form a closed loop.
[0131] Figure 9 illustrates another modality of a magnetic field generator device of the present invention, in which three bar dipole magnets are provided in the device. Two of the three bar dipole magnets are located spaced apart and opposite the axis of rotation and have the same magnetic north-south direction (substantially perpendicular to the bearing surface (S) / substantially parallel to the axis of rotation, for example, both pointing for the support surface (S)). The third bar dipole magnet is positioned on the axis of rotation and has its north-south direction in the opposite direction to the two magnets that are spaced apart. As is apparent from the field lines, an orientation of particles essentially parallel to the plane of the OEL layer/substrate surface is obtained in the areas between the center magnet and the two outer magnets and in the areas beyond the two spaced magnets when viewed from the axis of rotation). Therefore, the device of Figure 9 makes it possible to produce a security element giving the impression of two nested rings surrounding a central (empty) area.
[0132] Figure 10 illustrates another modality of a magnetic field generator device of the present invention that is similar to that shown in Figure 9, the only difference being that the north-south direction of the central magnet provided on the rotation axis is not opposite to the north-south direction of the spaced magnets, but that all three magnets have the same north-south direction (perpendicular and pointing towards the support surface (S), parallel to the axis of rotation). As is apparent from the field lines, particles in six areas of the cross-sectional view are oriented to be substantially parallel to the plane of the OEL, which combine with each other by rotation, forming three nested loop-shaped areas. That is, in the left and right area of the central magnet an orientation parallel to the OEL plane is achieved, forming by rotation the innermost loop-shaped area, in the area right to the magnet shown on the left and in the area to the left of the magnet shown on the right, upon rotation a half-loop-shaped area is formed, and the area to the left of the magnet shown to the left and right of the magnet shown to the right of an outer loop-shaped area is formed. Therefore, the device of Figure 9 makes it possible to produce a security element giving the impression of three nested rings surrounding a central (empty) area.
[0133] Figure 11 illustrates another embodiment of a magnetic field generator device of the present invention. Here, two pairs of magnets having magnetic north-south directions opposite each other are provided on either side of the axis of rotation. All magnets are provided spaced apart from the axis of rotation and the two inner magnets of a pair have symmetrical north-south directions with respect to the axis of rotation (both pointing away from the axis of rotation), the two outer magnets of a pair have the North-south directions symmetrical with respect to the axis of rotation (both pointing towards the axis of rotation). Each of the four magnets has its magnetic axis substantially parallel to the bearing surface (S) and radial to the axis of rotation. By rotating around the axis of rotation, the device allows the particles to be oriented in two loop-shaped areas in the OEL, forming the impression of the nested rings surrounding a central (empty) area. Of course, it is possible to provide additional pairs of magnets with the same orientation on both sides of the axis of rotation.
[0134] Figure 12 illustrates another embodiment of a magnetic field generator device of the present invention. Similar to the embodiment shown in Figure 11, two pairs of magnets are provided spaced apart from the axis of rotation with their magnetic axis substantially parallel to the bearing surface (S) and radial to the axis of rotation. Unlike the mode illustrated in Figure 11, all magnets here have north-south directions symmetrical with respect to the axis of rotation (ie pointing towards the axis of rotation).
[0135] The device illustrated in Figure 12 shows an interesting effect in which an area where a substantially parallel orientation of the particles is not only achieved directly above each of the four magnets, but also between the magnets on either side of the axis of rotation due to the magnets having the same north-south direction. In this way, a pole of the outer magnet (eg a north pole) is provided, such as to turn the opposite pole of the inner magnet (eg a south pole). This leads to a magnetic field having field lines that run substantially parallel to the surface S above the magnets in an area between the magnets. However, the area where a parallel particle orientation is achieved by this field is significantly smaller than the area above each of the magnets, which affects the "thickness" or line width of the loop-shaped bodies. Therefore, the device illustrated in Figure 12 leads, upon rotation around, to the formation of an OEL giving the visual impression of three nested rings surrounding a central (empty) area, where the thickness or line width of the outer ring is the inner ring is noticeably larger than that of the middle ring. This effect is also observed in related magnetic field generating devices of the present invention and is very noticeable, for example, in Figure 15b.
[0136] Figure 13 illustrates another embodiment of a magnetic field generator device of the present invention. She demonstrates a four bar dipole magnet device, in which all magnets are located away from the axis of rotation. Each of them has its magnetic axis substantially perpendicular to the bearing surface and substantially parallel to the axis of rotation. The north-south directions of the inner magnets are the same and opposite to the north-south directions of the outer magnets as seen from the axis of rotation. By rotating around the axis of rotation, an orientation of the particles parallel to the plane of the OEL in the three loop-shaped areas is obtained. One of the loop shapes (the half loop shape) is formed by combining, by rotating, the areas between the magnets on each side. The width of this area, and hence the apparent "thickness" of the closed loop-shaped body appearing in the OEL, can be adjusted by adjusting the distance between the magnets on either side of the axis of rotation and/or modifying the distance d . However, as described above, too great a distance d can lead to a blurred appearance of the loop-shaped body and/or a loss of contrast. The inner and outer loop shapes are formed by combining, by rotation around z, the areas between the innermost magnets and the axis of rotation and by combining, by rotation, the areas beyond the outer magnets (viewed from the axis of rotation).
[0137] Figure 14 illustrates another embodiment of a magnetic field generator device of the present invention. The device of this embodiment is similar to one of the embodiment illustrated in Figure 13, the only difference being that all magnets have identical north-south directions substantially parallel to the axis of rotation and substantially perpendicular to the support surface or substrate (S). The device allows the formation of a security element giving the optical impression of four bodies in a loop shape surrounding a central (empty) area.
[0138] Figure 15 illustrates another embodiment of a magnetic field generator device of the present invention. The device comprises 6 magnets spaced apart from the axis of rotation, three on each side. When viewed from one magnet to another, the north-south directions of all magnets are identical, while, when viewed in relation to the axis of rotation, the north-south direction of a set of three magnets on one side of the axis of rotation. rotation points towards the axis of rotation, while the north-south direction of the other set of three magnets points away from the axis of rotation (ie, the orientation of the magnets on both sides is asymmetrical with respect to the axis of rotation). Each north pole of a magnet faces the south pole of the magnet near along the axis of rotation.
[0139] The device illustrated in Figure 15 is related to the device shown in Figure 12, in that the magnets provided on one side of the axis of rotation have the same north-south direction (compare only the left side of Figure 12 with only the left side of Figure 15). An additional difference is that the set of magnets on one side of the axis of rotation is extended by a magnet, ie there are three magnets on both sides. Again, a substantially parallel orientation area of the particles with respect to the plane of the OEL/S surface is present directly above each of the magnets and also between each of the magnets. Upon rotation, each of these areas combines with itself along the rotational path, forming a loop-shaped area that corresponds to the loop-shaped body. Since the parallel orientation area is larger directly above the magnets than between the magnets, alternate loop shapes of different "thickness" or line width are formed upon rotation. In this way, the device illustrated in Figure 15 leads to the formation of five nested loop-shaped bodies, of which (viewed from the central area) the first, third and fifth have a greater thickness than the second and fourth.
[0140] Additionally, by the field lines between the magnets provided close to the axis of rotation, an alignment area substantially parallel to the surface S is formed directly over the axis of rotation, leading to the formation of a "bump". Consequently, the device illustrated in Figure 15 allows the formation of an OEL giving the optical impression of five nested rings of alternating thickness surrounding a protrusion.
[0141] It is immediately evident that the device of Figure 15 can be easily complemented by additional magnet on each side. The addition of a magnet on each side increases the number of loop-shaped bodies (rings) by two, so the device can be easily modified to provide the optical appearance of 7, 9, 11 or 13 nested rings surrounding an area. center that is filled with a "bump". Naturally, by reducing the number of magnets, two or three loop-shaped bodies surrounding an area with a protrusion can also be provided, as illustrated in Figure 20 (identical to the device in Figure 15, except for the reduced number of magnets).
[0142] Figure 15b shows a photograph of an OEL produced using the device of Figure 15a. Figure 15c illustrates the effect of a modification of the distance d, being Omm in Figure 15b and 1.5 mm in Figure 15c. As explained earlier, too great a distance d leads to blur and loss of contract, so that individual loop-shaped bodies can no longer be differentiated from each other. However, an OEL as shown in Figure 15c also provides a distinct optical appearance and three-dimensional effect caused by an overlap of the magnetic field lines, so a slightly larger distance d can also be used in practice. In fact, it would be difficult for a forger to reconstruct not only the magnetic field generating device used to produce such an OEL, but also to find the right distance d. Therefore, a distance d of 0.5mm or more or 1.0mm or more may be preferred for certain applications.
[0143] Figure 16 illustrates another embodiment of a magnetic field generator device of the present invention. The device comprises three magnets, two of which are spaced apart from the axis of rotation and one being provided on the axis of rotation. As in Figure 15, the north-south direction of the magnets is identical from one magnet to another, so that a north pole (or south pole) of a spaced magnet faces the south pole (or north pole, respectively) of the magnet provided on the axis of rotation. Put differently, the spaced magnets have asymmetric north-south directions with respect to the axis of rotation (one towards and one away from the axis of rotation), and the north-south direction of the magnet provided on the axis of rotation is the same as that of the magnet having its north-south direction pointing towards the axis of rotation.
[0144] The device is related to the one shown in Figure 15, the main difference - except for the reduced number of magnets - being that a magnet is provided on the axis of rotation. In this way, in the area directly above the magnet about the axis of rotation, an orientation area of the particles substantially parallel to the surface S is formed. This area is larger than the corresponding area in Figure 15 as it is formed above a magnet (not between two magnets). Thus, the "bump" in the central area surrounded by the innermost loop-shaped body in the OEL (i.e., at the location above the center of rotation) formed by the device of Figure 16 is larger than the bump at the corresponding location on a OEL produced by the device, as illustrated in Figure 15. In this way, the device of Figure 16 leads to particle orientation, such as to form an OEL giving the impression of two nested loop-shaped bodies (rings) surrounding a central area that is filled with a "boss".
[0145] As for the device of Figure 15, it is also immediately evident that the device shown in Figure 16 can be easily modified by adding additional magnets, thereby increasing the number of loop-shaped bodies. Also, loop-shaped bodies with alternating "thickness" will be formed. Thus, by adding additional magnets having the proper orientation (as shown in Figure 15) the corresponding devices can be used to prepare the OELs providing the optical appearance of, for example, four, six, eight or ten loop-shaped bodies nested (usually having alternating "thicknesses") surrounding a central area filled with a "bulge".
[0146] Figure 17 illustrates another modality of a magnetic field generator device of the present invention. The device is related to the one illustrated in Figure 11, the only difference being that the north-south direction of each of the two magnets on the right side has been reversed. While the magnets are arranged on each side of the axis of rotation such that they have, respectively, opposite north-south directions, the inversion of the north-south axis orientation of the magnets on only one side of the axis of rotation (as compared to Figure 11) leads to an arrangement in which the north-south directions of the two inner magnets point in the same direction when viewed from one another (but are naturally asymmetrical with respect to the axis of rotation, ie, one pointing away and one toward the other. axis of rotation) and the north-south directions of the two outer magnets point in the same direction when viewed from one to the other (but are naturally asymmetric with respect to the axis of rotation, ie, one pointing away and one toward the axis. rotation). This arrangement leads to the formation of an area directly on the axis of rotation allowing substantial parallel alignment of the particles along the field lines extending between the two internal magnets (similar to Figure 15). Thus, while the device illustrated in Figure 11 provides an OEL having the optical appearance of two nested loop-shaped bodies surrounding a central empty area, the device illustrated in Figure 17 provides an OEL having the optical appearance of two loop-shaped bodies. nested loop encircling a central area that is filled with a boss.
[0147] Figure 18 illustrates another modality of a magnetic field generator device of the present invention. The device comprises four magnets, two on each side of the axis of rotation. All magnets have their magnetic axis substantially parallel to the axis of rotation and substantially perpendicular to the surface S. The north-south direction of the two internal magnets is different (one pointing towards the surface S, the other away) and the north-south direction. south of a magnet further spaced from the axis of rotation is respectively opposite to the north-south direction of the inner magnet provided on the same side of the axis of rotation.
[0148] Figure 18 illustrates well that symmetrical magnetic fields can be formed by an alternate arrangement of magnets having their magnetic axis parallel to the axis of rotation and perpendicular to the surface S, where each magnet is interposed between two other magnets having a north direction. -south opposite. In such an arrangement, an orientation area of the non-spherical magnetic or magnetizable particles with respect to the plane of the OEL/S surface is formed between each of the magnets, forming a reflection zone. On the other hand, directly above the magnets, a substantially perpendicular orientation of the particles is achieved, showing substantially no reflection. Since there is no magnet provided on the axis of rotation, and consequently an area of substantially parallel alignment of the particles with the plane of the OEL is formed in this position, there is a bulge formed in the central area of the OEL prepared using the device. shown in Figure 18. Additionally, the device leads to the formation of two loop-shaped bodies surrounding the central area containing the protrusion.
[0149] Of course, it is evident that the device of Figure 18 can be easily modified by providing a magnet on the axis of rotation having an opposite north-south direction compared to adjacent magnets, so that no protrusion is formed, and /or by increasing the number of magnets on each side, forming three, four, five, six, seven or eight loop-shaped bodies. Additionally, interestingly, the magnetic fields in such devices between the magnets are very similar or identical, so loop shapes with apparently identical "thicknesses" can be formed.
[0150] Figure 19 illustrates an additional embodiment of a magnetic field generator device of the present invention. The device comprises four dipole magnets which are located beyond the axis of rotation, two on each side, each of the magnets having its magnetic axis substantially perpendicular to the surface S and substantially parallel to the axis of rotation. The orientation of the north-south direction is the same on each pair of magnets on each side and opposite on different sides of the axis of rotation (upwards towards the surface S on both magnets on one side and down on both magnets on the other side). As the north-south axis of the two internal magnets is opposite, an area capable of orienting the particles to be substantially parallel to the plane of the OEL is formed between the two magnets and over the axis of rotation, allowing the formation of a bulge. In addition, three nested loop-shaped bodies are formed within the OEL by rotating around the axis of rotation, caused by the magnetic field lines, extending to both sides of the outer magnets (forming the two loop-shaped bodies by rotation) and by the field lines of the two inner magnets extending outwards (toward the outer magnets).
[0151] Figure 20 shows a modality of a magnetic field generator device that is similar to the device of figure 15, except for the reduced number of magnets. In this sense, a separate discussion of the modality can be omitted.
[0152] In the rotational modes above the magnetic field generating device, the magnets are arranged in a rotational way around an axis of rotation when they are fixed radially to a bar extending from the axis of rotation. However, it is also possible, of course, to achieve a rotational arrangement of magnets differently, for example, by providing the magnets on a ground plate. In such an arrangement, a magnetic field generating device may comprise a plurality of bar dipole magnets provided around an axis of rotation, the magnets on either side of the axes of rotation being two or more dipole magnets all having their North-axis. South either substantially parallel or perpendicular to the bearing surface or space configured to receive a substrate, and optionally a bar dipole magnet disposed about the axis of rotation and also having its north-south axis substantially parallel or perpendicular to the bearing surface; respectively, the north-south directions of adjacent magnets pointing in the same or opposite directions, and the magnets being spaced far apart (see Figures 23a, 23b1, 23c and 23d1) or in direct contact with each other [see Figures 23b1 and 23d1] , the magnets optionally being provided on a grounding plate.
[0153] Figure 23 shows illustrative modalities of such an arrangement, which otherwise correspond with respect to the magnet configuration and the respective field lines for some of the other rotating magnetic field generating devices described above.
[0154] In figure 23a, an array of magnets (M) is arranged on a grounding plate (GP). Each remarkable magnet produces an arc-shaped section of magnetic field lines, with areas where the field lines run parallel to the plane of the arrangement of magnets between each of the magnets. By rotating such an arrangement of magnets (M) around an axis (z) perpendicular to the plane in which the magnets are arranged, an average magnetic field in space is dynamically produced, which is capable of orienting the magnetic or magnetizable particles in one layer.
[0155] The magnets (M) in the magnet arrangement need not be the same size, nor equidistant from each other, nor do the nested annular areas resulting from the arc-shaped sections of magnetic field lines need to have the same cross sections and distances each other. This, of course, not only applies to the embodiments shown in Figure 23, but also to all other devices of the present invention, especially rotary devices. However, preferably all magnets are approximately the same size and the same distance from each other.
[0156] Figure 24 shows a set of two or more nested annular area (M) magnets of alternate magnetic polarity, which can be arranged on a ground (GP) plate. Each pair of North and South poles on said surface of magnets (M) statically produces a loop-shaped (annular) area of arc-shaped magnetic field lines capable of orienting magnetic or magnetizable particles in a layer, so to produce nested null-effect graphics elements of different size.
[0157] The static annular areas of arc-shaped magnetic field lines need not be nested, nor circular, nor the same size, nor the same shape, nor equidistant from each other. In fact, any shape and combination of shapes is possible in the static mode of the magnetic guiding device.
[0158] In another embodiment, the present invention is related to a magnetic field generator device generating magnetic field, comprising a permanent magnetic plate that is magnetized perpendicular to the plane of the plate and having projections and impressions, the projections and impressions being arranged to form loop-shaped prints and projections nested encircling a central area, the projections and prints forming opposite magnetic poles. Such a device is illustrated in Fig. 25 and can be produced by any method which is capable of providing the desired structure, such as by etching or polishing a permanent magnetic plate, for example by physical means, laser ablation or chemical means. Alternatively, a device is illustrated in Figure 25 and can be produced by injection molding or a casting process.
[0159] Figure 25 shows a device that has a set of two or more magnets concentrically in a loop (annular) format, in which the alternating sequence of north and south magnetic poles is produced by engraving one of the pole faces of the permanent magnetic plate (MP), magnetized perpendicular to its extended surface. Such a modality as engraved permanent magnetic plate is particularly advantageous in the case of non-circular shapes, because an engraving of arbitrary shape is easily perceived in a permanent magnetic material composed of a permanent magnetic powder composed in a matrix of the rubber or plastic type.
[0160] The magnets of the field generating magnetic devices described herein may comprise or consist of any permanent magnetic material (magnetic-rigid), for example alnico, barium or strontium-hexaferrite alloy, cobalt alloy or ground iron alloy rare as neodymium-iron-boron alloy. Particularly preferred are, however, easily practicable permanent magnetic composite materials comprising a permanent magnetic filler, such as strontium-hexaferrite (SrFe12O19) or neodymium-iron-boron (Nd2Fe14B) powder, in a plastic or plastic-type matrix. rubber.
[0161] Also described herein are rotary printing assemblies comprising magnetic field generating devices to produce the OEL described in this document, said magnetic field generating devices being mounted and/or inserted into the printing cylinder as a part of the rotary printing machine . In this case, the magnetic field generating device is correspondingly designed and adapted to the cylindrical surface of the rotating unit to ensure smooth contact with the surface to be printed.
[0162] Also described herein are processes for producing the OEL described in this document, said processes comprising the steps of: a) applying on a support surface or substrate surface (which may or may not be present on a support surface) a coating composition in a first state (liquid), comprising a binder material and a plurality of non-spherical magnetic or magnetizable particles described herein, b) exposing the coating composition in a first state to the magnetic field of a magnetic field generating device preferably one as described above in this document, thereby orienting at least a portion of the magnetizable or non-spherical magnetic particles in a plurality of nested loop-shaped areas surrounding a central area such that the longest axis of the particles in each of the cross-sectional areas of the loop-shaped areas follow a tangent of either a negatively curved part or one positively curved from hypothetical circles or ellipses; and c) hardening the coating composition to a second state so as to fix the magnetizable or non-spherical magnetic particles in their adopted positions and orientations.
[0163] The application of step a) is preferably a printing process selected from the group consisting of copper plate relief printing, screen printing, gravure printing, Flexography printing and roll coating and most preferably from the group consisting of screen printing, rotogravure printing and flexo printing. These processes are well known to the skilled man and are described for example in Printing Technology, J.M. Adams and P.A. Dolin, Delmar Thomson Learning, 5th Edition.
[0164] While the coating composition comprising the plurality of non-spherical magnetic or magnetizable particles described herein is still wet or soft enough that the non-spherical magnetic or magnetizable particles therein can be moved and rotated (i.e., while the composition of coating is in a first state), the coating composition is subjected to a magnetic field to obtain particle orientation. The step of magnetically orienting the non-spherical magnetic or magnetizable particles comprises a step of exposing the applied coating composition, while it is "wet" (i.e. still liquid and not too viscous, i.e., in a first state), to a certain magnetic field generated on or above a supporting surface of the magnetic field generating device described in this document, thereby orienting the non-spherical magnetic or magnetizable particles along the field lines of the magnetic field so as to form an orientation pattern in loop format. In this step, the coating composition is brought sufficiently close to or in contact with the bearing surface of the field generating magnetic device.
[0165] When bringing the coating composition close to the supporting surface of the magnetic field generating device and the loop-shaped element is to be formed on one side of a substrate, the side of the substrate carrying the coating composition may be of facing the backing side of the device, or the side of the substrate not carrying the coating composition may face the backing side. In case the coating composition is applied to only one surface of the substrate or is applied to both sides, and one side on which the coating composition is applied is oriented so as to face the support surface of the device, it is preferable that no direct contact with the support surface is established (the substrate is only brought close enough to, but not in contact with, the support surface of the device).
[0166] Remarkably, the coating composition can practically be placed in contact with the supporting surface of the magnetic field generating device. Alternatively, a small air opening, or an intermediate separating layer, can be provided. In an additional and preferred alternative, the method can be carried out such that the surface of the substrate not carrying the coating composition can be brought close to or in direct contact with the one or more magnets (i.e., the magnet(s)( s) form the support surface).
[0167] If desired, a primer layer can be applied to the substrate prior to step a). This can improve the quality of a magnetically transferred particle orientation image or promote adhesion. Examples of such primer layers can be found in WO 2010/058026 A2.
[0168] The step of exposing the coating composition comprising the binding material and the plurality of non-spherical magnetic or magnetizable particles to a magnetic field (step b)) can be performed simultaneously with step a) or after step a). That is, steps a) and b) can be performed simultaneously or subsequently.
[0169] The processes for the production of the OEL described herein comprise, concurrently with step (b) or, subsequently, with step (b), a hardening step (step c)) of the coating composition in order to fix the magnetic particles or magnetizable non-spherical in their adopted positions and orientations, thus transforming the coating composition to a second state. By this fixation, a solid coating or layer is formed. The term "hardening" refers to processes, including drying or solidifying, reacting, curing, crosslinking or polymerizing the binder components in the applied coating composition, including an optionally present crosslinking agent, an optionally present polymerization initiator, and additives additional optionally present, such that an essentially solid material which strongly adheres to the substrate surface is formed. As mentioned above, the hardening step (step c)) can be carried out by different means or processes, depending on the binder material composed in the coating composition which also comprises the plurality of non-spherical magnetic or magnetizable particles.
[0170] The hardening step generally can be any step that increases the viscosity of the coating composition such that a solid material substantially adhering to the bearing surface is formed. The hardening step can involve a physical process based on the evaporation of a volatile component, such as a solvent, and/or the evaporation of water (ie, physical drying). In this document, hot air, infrared, or a combination of hot air and infrared can be used. Alternatively, the curing process may include a chemical reaction, such as a cure, polymerization or crosslinking of the binder and optional initiator compounds and/or optional crosslinking compounds comprised in the coating composition. Such a chemical reaction may be initiated by heat or IR radiation as noted above for the physical hardening processes, but preferably may include the initiation of a chemical reaction by a radiation mechanism including without limitation Visible UV light radiation curing (hereafter as UV-Vis cure) and electronic beam radiation cure (E-beam cure); oxypolymerization (oxidative cross-linking, usually induced by the joint action of oxygen and one or more catalysts, such as cobalt-containing and manganese-containing catalysts); crosslinking reactions or any combination thereof.
[0171] Radiation curing is particularly preferred, and UV-Vis light radiation curing is even more preferred, as these technologies advantageously lead to very fast curing processes and therefore drastically shorten the preparation time of any article that comprises the OEL described here. Furthermore, radiation cure has the advantage of producing an instantaneous increase in the viscosity of the coating composition after exposure to radiation cure, thus minimizing any further movement of the particles. As a result, any loss of information after the magnetic orientation step can essentially be avoided. Particularly preferred is radiation curing by photopolymerization, under the influence of actinic light, having a wavelength component in the blue part of the electromagnetic or UV spectrum (typically 300 nm to 550 nm; more preferably 380 nm to 420 nm ; "visible UV cure"). Equipment for UV visible curing may comprise a high power light emitting diode (LED) lamp, or an arc discharge lamp such as a medium pressure mercury arc (MPMA) or a metal vapor arc lamp. , as the source of actinic radiation. The hardening step (step c) can be carried out simultaneously with step b) or subsequent to step b). However, the time from the end of step b) to the beginning of step c) is preferably relatively short, in order to avoid any orientation and loss of information. Typically, the time between the end of step b) and the beginning of step c) is less than 1 minute, preferably less than 20 seconds, more preferably less than 5 seconds, even more preferably less than 1 second. It is particularly preferable that there is essentially no time difference between the end of the orientation step b) and the beginning of the hardening step c), i.e. that step c) is immediately after step b) or already starts while the step b) is still in progress.
[0172] As described above, step (a) (application onto the support surface, or preferably substrate surface on a support surface formed by a magnet or plate) can be performed simultaneously with step b) or previously to step b) (orientation of particles by a magnetic field), and also step c) (hardening) can be carried out simultaneously with step b) or after step b) (orientation of particles by a magnetic field). While this may also be possible for certain types of equipment, normally not all three steps a), b) and c) are performed simultaneously. Also, steps a) and b), and steps b) and c) can be performed, so that they are partially performed simultaneously (that is, the execution times of each of the steps partially overlap, so that for example the hardening step c) is started at the end of the orientation step b).
[0173] In order to increase durability by chemical or dirt resistance and cleaning and, therefore, the circulation lifetime of security documents, or in order to modify their aesthetic appearance (for example, optical gloss), one or more protective layers can be applied on top of the OEL. When present, the one or more protective layers are usually made of protective varnishes. These can be transparent or lightly colored or tinted and can be more or less shiny. Protective varnishes can be radiation curable compositions, thermal drying compositions or any combination thereof. Preferably, the one or more protective layers are made from radiation curable compositions, more preferably UV-Vis curable compositions. Protective layers can be applied after the formation of the OEL in step c).
[0174] The above processes allow to obtain a substrate bearing an OEL comprising by nested areas in a loop format that are capable of providing the optical appearance or optical impression of nested bodies in a loop format, surrounding a central area, in which, in a cross-sectional view perpendicular to the plane of the OEL and extending from the center of the central area, the orientation of the non-spherical magnetic or magnetizable particles present in the closed loop-shaped areas each follow the negatively curved part (see figure 1b) or positively part curved (see figure 1c) of the surface of the respective hypothetical semi-toroidal bodies that lie in the plane of the OEL, depending on whether the magnetic field of the magnetic field generating device is applied from below or above to the coating composition layer comprising magnetic particles or non-spherical magnetizables. Furthermore, depending on the type of equipment used, the central area surrounded by the loop-shaped bodies may comprise a so-called "protrusion", i.e. an area comprising the magnetic or magnetizable particles in an orientation that is substantially parallel to the surface of the substrate. In such modalities, the orientation changes to the surrounding loop-shaped body, following a negative or positive curve, when from a cross-section extending from the center of the center area to the closed-loop-shaped body. Between the innermost loop-shaped body and the "bump" is preferably an area in which the particles are oriented substantially perpendicular to the substrate surface, showing no or only little reflection.
[0175] This is particularly useful in applications where the OEL is formed from an ink, for example, a security ink, or some other coating material and is permanently disposed on a substrate as a security document, for example, through printing as described above.
[0176] In the processes described above and when the OEL must be provided on a substrate, said OEL may be provided directly on a substrate surface on which it will remain permanently (such as banknote applications). However, in an alternative embodiment of the present invention, the OEL may be provided on a temporary substrate for production purposes, from which the OEL is later removed. This can, for example, facilitate the production of the OEL, particularly while the binding material is still in its fluid state. Afterwards, after hardening of the coating composition to produce the OEL, the temporary substrate can be removed from the OEL. Of course, in these cases, the coating composition must be in a form that is physically integral after the hardening step, such as for instances in cases where a plastic or sheet type material is formed by hardening. Thus, a translucent and/or transparent film-like material consisting of the OEL as such (i.e., essentially consisting of orienting magnetic or magnetizable particles having hardened binding components of non-isotropic reflectivity to fix the particles in their orientation and form a material of the film type, such as a plastic film and additional optional components) can be provided.
[0177] Alternatively, in another embodiment the substrate may comprise an adhesive layer on the opposite side of the side where the OEL is provided, or an adhesive layer may be provided on the same side as the OEL and above the OEL, preferably after the hardening step has been completed. In such cases, an adhesive label comprising the adhesive layer and the OEL is formed. Such a label can be attached to all kinds of documents or other articles or items without printing or other processes that involve machinery and quite high effort.
[0178] According to one embodiment, the OEC is manufactured in the form of a transfer sheet, which can be applied to a document or article in a separate transfer step. For this purpose, the substrate is provided with a release coating, on which an OEL is produced as described in this document. One or more layers of adhesive can be applied over the OEL then produced.
[0179] The term "substrate" is used to denote a material to which a coating composition can be applied. Typically, a substrate is in sheet format and has a thickness of no more than 1 mm. Preferably not more than 0.5 mm, more preferably not more than 0.2 mm. The substrate described in this document is preferably selected from the group consisting of papers or other fibrous materials such as cellulose, paper-containing materials, glasses, ceramics, plastics and polymers, glasses, composite materials and mixtures or combinations thereof. Typical paper, paper-like, or other fibrous materials are made from a variety of fibers including without limitation abaca, cotton, linen, wood pulp, and mixtures thereof. As is well known to those skilled in the art, cotton and cotton/linen blends are preferred for banknotes, while wood pulp is commonly used in security documents other than banknotes. Typical examples of plastics and polymers include polyolefins such as polyethylene (PE) and polypropylene (PP), polyamides, polyesters such as poly(ethylene terephthalate) (PET), poly(1,4-butylene terephthalate) (PBT), poly (ethylene 2,6-naphthoate) (PEN) and polyvinyl chlorides (PVC). Woven olefin fibers such as those sold under the Tyvek® brand name can also be used as a substrate. Typical examples of composite materials include without limitation multilayer structures or laminates of paper and at least one plastic or polymer material such as those described above as well as plastic and/or polymer fibers incorporated in fibrous or paper-like materials such as those described above. Of course, the substrate may comprise additional additives that are known to the person skilled in the art, such as sizing agents, bleaches, adjuvants, builders or wet strength agents etc.
[0180] According to an embodiment of the present invention, the optical effect layer (OEC) coated substrate comprises more than one OEL in the substrate described herein, for example, it may comprise two, three, etc. OELs. In this document, one, two, or more OELs can be formed using a single magnetic field generating device, or can be formed using multiple magnetic field generating devices.
[0181] The OEC may include a first OEL and a second OEL, both of which are present on the same side of the substrate or where one is present on one side of the substrate and the other is present on the other side of the substrate. If provided on the same side of the substrate, the first and second OEL can be adjacent or non-adjacent to each other. Additionally, or alternatively, one of the OELs may partially or fully overlap another OEL.
[0182] If more than one magnetic field generating device is used to produce a plurality of OELs, the magnetic field generating devices to orient the plurality of non-spherical magnetic or magnetizable particles to produce an OEL and the field generating device magnetic to produce another OEL can be placed i) on the same side of the substrate, as well as to produce two OELs displaying a negatively curved part (see figure 1b) or a positively curved part (see figure 1c) or ii) on opposite sides of the substrate in order to have one OEL exhibiting a negatively curved part and the other exhibiting a positively curved part. The magnetic orientation of the non-spherical magnetic or magnetizable particles to produce the first OEL and the non-spherical magnetic or magnetizable particles to produce the second OEL can be performed simultaneously or sequentially, with or without intermediate hardening or partial hardening of the binding material.
[0183] In order to further increase the level of security and resistance against forgery and illegal reproduction of security documents, the substrate may comprise printed, coated or laser-marked or laser-perforated indicia, watermarks, security topics, fibers, platelets, luminescent compounds, windows, sheets, decals, coatings, pimers and combinations thereof. With the same aim of further increasing the level of security and resistance against forgery and illegal reproduction of security documents, the substrate may comprise one or more marker substances or taggants and/or machine-readable substances (for example, luminescent substances, UV/visible/IR absorbing substances, magnetic substances and combinations thereof).
[0184] The OEL described in this document can be used for decorative purposes as well as to protect and authenticate a security document.
[0185] The present invention also encompasses articles and decorative objects, comprising the OEL described herein. Decorative articles and objects may comprise more than one optical effect layer described herein. Typical examples of decorative items and objects include without limitation luxury goods, cosmetic packaging, auto parts, electronics/appliances, furniture, etc.
[0186] An important aspect of the present invention relates to security documents, comprising the OEL described herein. The security document may include more than one optical effect layers described herein. Security documents include, without limitation, documents of value and assets of commercial value. Typical examples of documents of value include, without limitation, banknotes, deeds, tickets, checks, vouchers, tax stamps and tax labels, agreements and the like, identity documents such as passports, identity documents, visas, driver's licenses, bank cards, credit cards, transaction cards, documents or access cards, entrance tickets, public transport tickets and the like. By example, genuine medicines. Examples of these packaging materials include, without limitation, labels such as brand authentication labels, tamper proof labels and seals.
[0187] Preferably, the security document described in this document is selected from the group consisting of banknotes, identity documents, documents conferring rights, driving licenses, credit cards, access cards, transport tickets, bank checks and labels of products safely. Alternatively, the OEL can be produced on an auxiliary substrate, such as, for example, a security thread, security strip, a sheet, a decal, a window or a label and subsequently transferred to a security document in a separate step .
[0188] The person skilled in the art can envisage various modifications to the specific embodiments described above without departing from the spirit of the present invention. Such modifications are encompassed by the present invention.
[0189] In addition, all documents referenced throughout this specification are hereby incorporated by reference in their entirety, as defined in full in this document.
[0190] The present invention will now be described later by way of examples. However, the examples are not intended to limit the scope of the invention in any way. EXAMPLES Example 1
[0191] A magnetic field generating device according to Figure 3 was used to orient non-spherical optically variable magnetic pigments in a printed layer of a UV-curable screen printing ink on a black paper substrate. The ink had the following formula:

(*) flakes of non-spherical green-to-blue optically variable magnetic pigments, approximately 15μm in diameter d50, and approximately 1μm thick obtained from JDS-Uniphase, Santa Rosa, CA.
[0192] A magnetic field generating device according to Figure 3 was used to orient non-spherical optically variable magnetic pigments in a printed layer of a UV-curable screen printing ink, according to the formula of Example 1 in a black paper as a substrate.
[0193] The field generating magnetic device comprised a magnetic-smooth iron grounding plate, an axially annular permanent magnetized plastoferrite charged plastoferrite magnet 15mm inner diameter, 19mm outer diameter and 4mm thickness, and a connection cylindrical magnetic soft iron, 6mm in diameter and 4mm thick, arranged in the center of the annular permanent magnet.
[0194] The paper substrate carrying the printed layer of a UV curable screen printing ink was arranged at a distance of 1mm from the magnetic pole of the annular permanent magnet and the iron connection. The magnetic orientation pattern obtained in this way from the optically variable pigments was, after the application stage, fixed by UV curing of the printed layer, comprising the pigments.
[0195] The resulting image of the magnetic orientation is given in Figure 3, in three different points of view, illustrating the angle-of-view dependent change of the image. Example 2
[0196] A magnetic field generating device according to Figure 6d was used to orient non-spherical optically variable magnetic pigments in a printed layer of a UV-curable screen printing ink, according to the formula of Example 1 in a black paper as a substrate.
[0197] The magnetic field generator device comprised a magnetic-smooth iron grounding plate, on which an axially magnetized NdFeB permanent magnetic disk 6mm in diameter and 1mm thick was arranged, with the magnetic South Pole on the smooth grounding plate -magnetic. A rotationally symmetric U-shaped, 10mm outside diameter, 8mm inside diameter, and 1mm deep magnetic smooth iron connection was disposed at the magnetic North Pole of the permanent magnetic disk. A second axially magnetized NdFeB permanent magnetic disk 6mm in diameter and 1mm thick was placed in the center of the U-shaped rotationally symmetrical magnetic-smooth iron connection with the magnetic South Pole in the magnetic-soft iron connection.
[0198] The paper substrate carrying the printed layer of a UV-curable screen printing ink comprising optically variable magnetic pigments was immediately disposed on the magnetic pole of the second permanent magnet disk and the iron connection. The magnetic orientation pattern obtained in this way from the optically variable pigment particles was, after the application stage, fixed by UV curing of the printed layer, comprising the pigments.
[0199] The resulting image of the magnetic orientation is given in Figure 6, in three different points of view, illustrating the change dependent on the angle of view of the image. Example 3
[0200] A magnetic field generating device according to Figure 24 was used to orient non-spherical optically variable magnetic pigments in a printed layer of a UV-curable screen printing ink, according to the formula of Example 1 in a black paper as a substrate.
[0201] The field generating magnetic device comprised a non-magnetic grounding plate, and disposed on said grounding plate, a series of four axially nested annular permanent magnets of plastoferrite loaded with strontium-hexaferrite, with an axially cylindrical permanent magnet magnetized plastoferrite loaded with strontium hexaferrite in the center. All magnetic rings are 4mm high and 2mm thick, the magnetic cylinder is 4mm high and has a diameter of 3mm, and the gap between all magnets is 2mm. The north and south magnetic poles of the magnets are arranged in alternating sequence.
[0202] The paper substrate carrying the printed layer of a UV-curable screen printing ink comprising optically variable magnetic pigments was immediately disposed on the poles of the magnets. The magnetic orientation pattern obtained in this way from the optically variable pigment particles was, after the application stage, fixed by UV curing of the printed layer, comprising the pigments.
[0203] The resulting image of the magnetic orientation is given in Figure 24, in three different viewpoints, illustrating the angle-of-view dependent change of the image. Example 4
[0204] A magnetic field generating device according to Figure 15 was used to orient non-spherical optically variable magnetic pigments in a printed layer of a UV-curable screen printing ink, according to the formula of Example 1 in a black paper as a substrate.
[0205] The magnetic field generating device comprised a linear sequence of six NdFeB permanent magnets, each of dimensions 3x3x3mm, mounted together on a non-magnetic ground plate capable of rotating. The interstices between the permanent magnets were 1mm in size. The magnetic axes of the magnets were all aligned in the same direction along the direction of the linear sequence of magnets, resulting in a linear NS-NS-NS-NS-NS-NS array.
[0206] In a first embodiment, the paper substrate carrying the printed layer of a UV-curable screen printing ink comprising optically variable magnetic pigments was immediately disposed on the magnetic poles of the magnets and the non-magnetic grounding plate capable of rotating bearing the linear sequence of magnets was rotated rapidly to produce an average magnetic field to orient the particles. The magnetic orientation pattern obtained in this way from the optically variable pigment pigments was, after the application stage, fixed by UV curing of the printed layer, comprising the pigments. The resulting images of the magnetic orientation are given in Figure 15b, in three different viewpoints, illustrating the angle-of-view dependent change of the image.
[0207] In a second embodiment, the paper substrate carrying the printed layer of a UV-curable screen printing ink comprising optically variable magnetic pigments was disposed at a distance of 1.5 mm from the magnetic poles of the magnets, resulting in an image of slightly different ring effect. The resulting images of magnetic orientation are given in Figure 15c, in three different viewpoints, illustrating the angle-of-view dependent change of the image.

权利要求:
Claims (21)
[0001]
1. Optical effect layer (OEL) characterized in that it comprises a plurality of non-spherical magnetic or magnetizable particles (P), wherein at least a part of the plurality of non-spherical magnetic or magnetizable particles (P) consists of pigments non-spherical optically variable magnetic or magnetizable particles, and in which the non-spherical (P) magnetic or magnetizable particles are dispersed in a coating composition comprising a binding material, the OEL, comprising two or more loop-shaped areas, being nested around a common central area that is surrounded by an innermost loop-shaped area, wherein, in each of the loop-shaped areas, at least a part of the plurality of non-spherical magnetic or magnetizable particles (P) are oriented such that, in a cross section perpendicular to the OEL layer and extending from the center of the central area to the outermost loop-shaped area delimitation. na, the longest axis of the particles (P) in each of the cross-sectional areas of the loop-shaped areas follows a tangent of both a negatively and positively curved part of hypothetical circles or ellipses, in which the optically variable magnetic or magnetizable pigments (P) are selected from the group consisting of magnetic thin-film interference pigments, magnetic cholesteric liquid crystal pigments and their mixtures.
[0002]
2. Optical effect layer (OEL) according to claim 1, characterized in that the OEL additionally comprises an outer area outside the outermost loop-shaped area, the outer area around the loop-shaped area outermost comprises a plurality of non-spherical (P) magnetic or magnetizable particles, wherein at least a portion of the plurality of non-spherical (P) magnetic or magnetizable particles (P) within the outer area are oriented such that their longest axis is perpendicular to the plane. of OEL or randomly oriented .
[0003]
3. Optical effect layer (OEL) according to claim 1 or 2, characterized in that the central area surrounded by the innermost loop-shaped area comprises a plurality of non-spherical magnetic or magnetizable particles (P), wherein a part of the plurality of non-spherical magnetic or magnetizable particles (P) within the central area are oriented such that their longest axis is parallel to the plane of the OEL, forming the optical effect of a protrusion.
[0004]
4. Optical effect layer (OEL) according to claim 3, characterized in that the outer peripheral shape of the protrusion is similar to the shape of the innermost loop-shaped area.
[0005]
5. Optical effect layer (OEL) according to claim 3 or 4, characterized in that the loop-shaped areas each have the shape of a ring, and the protrusion is shaped like a half. - sphere or solid circle.
[0006]
6. Optical effect layer (OEL) according to any one of claims 1 to 5, preferably claim 3, characterized in that the plurality of non-spherical magnetic or magnetizable particles (P) within the loop-shaped areas and/or within the central area, surrounded by loop-shaped areas are oriented such that they provide the optical effect of (a) three-dimensional object(s) extending from the surface of the OEL.
[0007]
7. Magnetic field generator device, characterized in that it is to form the optical effect layer (OEL) as defined in any one of claims 1 to 6 and comprising a plurality of elements selected from magnets (M) and parts polar (Y) and comprising at least one magnet, the plurality of elements, being either (i) located below a support surface as a space configured to receive a substrate (S) acting as a support surface or (ii) forming a bearing surface, and being configured so as to be able to provide a magnetic field, in which magnetic field lines (F) run parallel to said bearing surface or space in two or more areas above said bearing surface or space and wherein: i) the two or more areas form nested loop-shaped areas surrounding a central area; and/or ii) the plurality of elements comprises a plurality of magnets, and the magnets (M) are arranged rotating around an axis of rotation such that the areas with field lines (F) running parallel to the support surface or space they combine by rotation about the axis of rotation, thereby forming, upon rotation about the axis of rotation, a plurality of nested loop-shaped areas surrounding a central area.
[0008]
8. Magnetic field generator device, according to claim 7, option ii), characterized in that the magnets (M) are arranged such that in an area, which is above said surface or support space and which is centered on the axis of rotation, a magnetic field is generated with field lines (F) running parallel to the plane of magnets (M).
[0009]
9. Magnetic field generator device, according to claim 7, option i), characterized in that two or more areas of parallel field lines (F), which form the loop-shaped areas nested around a central area, are caused by an arrangement of a plurality of elements selected from magnets (M) and polar pieces (Y), at least one of said elements having a loop-shaped shape, corresponding to the loop-shaped area with parallel field lines (F) above the support surface or space.
[0010]
10. Magnetic field generator device according to claim 9, characterized in that the arrangement of a plurality of elements selected from magnets (M) and polar parts (Y) comprises at least one magnet in a loop format (M), having its magnetic axis perpendicular to said support surface or space, whose arrangement preferably additionally contains a polar piece (Y) having a loop-shaped shape, the magnet in a loop shape (M) and the polar piece in loop (Y) shape surrounding a central area in a nested manner.
[0011]
11. Magnetic field generator device according to claim 10, characterized in that the central area comprises a bar dipole magnet (M) having its magnetic axis perpendicular to said support surface or space or a central pole piece ( Y), and in which the pole piece (Y) and that magnet (M) are arranged alternately starting from the center area.
[0012]
12. Magnetic field generator device, according to claim 7, option ii), or claim 8, characterized in that the plurality of magnets (M) is symmetrically arranged around the axis of rotation and has its magnetic axis parallel or perpendicular to the support surface or space.
[0013]
13. Magnetic field generating device according to claim 7, characterized in that it is selected from the group consisting of the following: a) a magnetic field generating device, in which an axially magnetized dipole magnet in the form of a loop ( M) is provided such that the north-south axis is perpendicular to the support surface or space, in which the loop-shaped magnet (M) surrounds a central area, and the device is additionally composed of a polar piece (Y) that is provided below the axially magnetized dipole magnet in the form of a loop (M), in relation to the supporting surface, or space and which closes one side of the loop formed by the magnet in a loop shape, and in which the polar part (Y) constitutes one or more projections extending into space, surrounded by the loop-shaped magnet (M) and being spaced from there, where: a1) the pole piece (Y) constitutes a projection extending into the central encircled area by the loop-shaped magnet, in which the projection is laterally spaced away from the magnet in a loop (M) shape and fills a part of the central area; a2) the polar piece (Y) constitutes a loop-shaped projection and surrounds a central bar dipole magnet (M) having the same north-south direction as the loop magnet, the projection and the bar dipole magnet ( M) being spaced apart from each other, or a3) the pole piece (Y) forms two or more interspaced projections, both all of these and all but one of these are in a loop format, and, depending on the number of projections, one or more Axially magnetized loop-shaped magnets (M) having the same north-south direction as the first axially magnetized loop-shaped magnet (M) is provided in the space formed between the interspaced loop-shaped projections, the additional magnets (M) being spaced apart from the loop-shaped projections, and in which the central area surrounded by loop-shaped projections and the loop-shaped magnet (M) is partially filled with both a central bar dipole magnet (M) having the same north-south direction as the surrounding loop-shaped magnets (M) or with a central projection of the pole piece (Y), such that, as seen from the supporting surface or space, an alternating arrangement of spaced apart pole piece projections in a loop (Y) format and axially magnetized dipole magnets loop-shaped (M) is formed around a central area, wherein the central area is filled with either a bar dipole magnet (M) or a central projection as set out above; b) a magnetic field generating device comprising two or more bar dipole magnets (M) and two or more polar pieces (Y), wherein: the device comprises an equal number of polar pieces (Y) and dipole magnets in bar, in which the bar dipole magnets (M) have their north-south axis perpendicular to the support surface or space, have the same north-south direction and are provided at different distances from the support surface or space, preferably to the along a line extending perpendicular to the support surface or space and spaced apart from each other; and the polar pieces (Y) being provided in the space between the bar dipole magnets (M) and in contact therewith, wherein the polar pieces (Y) form one or more projections that, in a loop-shaped form, surround a central area in which the bar dipole magnet, located close to the support surface or space, is located; c) a magnetic field generator device, comprising a bar dipole magnet (M) located below the support surface or space and having its north-south direction perpendicular to said support surface or space, one or more polar pieces in the shape of a loop (Y) arranged above the magnet (M) and below the support surface or space, where, for a plurality of loop (Y) shaped polar pieces, spaced and nested coplanar pieces are arranged to one or more polar pieces (Y) laterally encircling a central area in which the magnet (M) is located, the device further comprising a first plate-type pole piece (Y) having the same size and the same peripheral shape as the loop-shaped pole piece outermost (Y), the plate-type polar piece (Y) being arranged below the magnet (M), such that its outer peripheral shape is superimposed with the periphery of the outermost loop-shaped polar piece (Y) in direction from the support surface the u space, and which is in contact with one of the poles of the magnet; and a central pole piece (Y) in contact with the other pole of the magnet respectively, the central pole piece (Y) having the outer peripheral shape of a loop, partially filling the central area and being laterally and spaced apart and surrounded by a or more polar pieces in a loop (Y) shape; d) a magnetic field generating device according to item c) above, in which a second plate-type polar piece (Y) having the outer peripheral shape of a loop is provided in a position above and in contact with a pole of the magnet (M), and below and in contact with the one or more loop-shaped pole pieces (Y), and below and in contact with the center pole piece (Y), so that the center pole piece (Y) does not is more in direct contact with the pole of the magnet, the second plate-type polar piece (Y) being the same size and shape as the first plate-type polar piece (Y); e) a magnetic field generating device, in which two or more bar dipole magnets (M) are arranged below the supporting surface or spaced apart and so as to be rotatable about an axis of rotation that is perpendicular to the supporting surface or space, the two or more bar dipole magnets (M) being spaced apart from the axis of rotation and each other and provided symmetrically on opposite sides of the axis of rotation, the device optionally additionally comprising a bar dipole magnet (M) which is arranged below the support surface or space and on the axis of rotation, or in which either: e1) the device comprises, both on each side of the axis of rotation, one or more bar dipole magnets (M) all having their north-south axis perpendicular to the support surface or space and parallel to the axis of rotation, the north-south direction of all magnets (M) being identical with respect to the support surface or space, and magnets (M) being interspaced between itself, the device, optionally , comprising a bar dipole magnet (M) which is arranged below the support surface or space and on the axis of rotation, the north-south axis thereof, being perpendicular to the support surface or space, and parallel to the axis of rotation, and whose north-south direction is both identical to the north-south direction of magnets (M) which are arranged rotating about the axis and spaced apart from this point or in opposition; e2) no optional bar dipole magnets (M) on the axis of rotation are present and the device comprises, on each side of the axis of rotation, two or more bar dipole magnets (M) arranged interspaced from each other and from the axis of rotation, the north-south axis of the magnets (M) being perpendicular to the support surface or space and parallel to the axis of rotation, and in which the magnets (M) provided on each side of the axis have alternating north-south directions, and the magnets innermost (M) with respect to the axis of rotation have the same or opposite north-south directions; e3) no optional bar dipole magnets (M) on the axis of rotation are present and the device comprises, on each side of the axis of rotation, two or more bar dipole magnets (M) arranged interspaced from each other and from the axis of rotation, the north-south axis of the magnets (M) being perpendicular to the support surface or space and parallel to the axis of rotation, and wherein the magnets (M) provided on each side of the axis have the same north-south direction and the magnets (M) provided on different sides of the axis of rotation have opposite north-south directions; e4) the device comprises, on each side of the axis of rotation, one or more bar dipole magnets (M) which are arranged interspaced from the axis of rotation and, if more than one magnet (M) is present on one side , interspaced with each other, the north-south axis of the magnets (M) being parallel to the support surface or space and radial to the axis of rotation, and the north-south directions of the magnets (M) being arranged such that the north-south directions of all magnets (M) point in essentially the same direction, in addition both e4-1) no optional magnet (M) is provided on the axis of rotation and at least two magnets (M) are provided on either side of the axis of rotation ; as e4-2) an optional magnet (M) is provided on the axis of rotation, the magnets (M) on each side being arranged interspaced therefrom, the magnet (M) on the axis of rotation being a bar dipole magnet (M ) having its north-south axis parallel to the support surface and its north-south direction pointing in the same direction as other magnets (M) provided on each side of the axis or rotation; e5) the device does not comprise any optional magnet (M) provided on the axis of rotation and comprises, on each side of the axis of rotation, two or more bar dipole magnets (M) which are arranged interspaced from the axis of rotation and interspaced to each other, the north-south axis of the magnets (M) being parallel to the bearing surface or space and radial to the axis of rotation, where the north-south directions of all magnets (M) are symmetrical with respect to the axis of rotation. (ie, all pointing towards or away from the axis of rotation); e6) the device comprises no optional magnets (M) provided on the axis of rotation and comprises, on both sides of the axis of rotation, one or more pairs of bar dipole magnets (M) arranged spaced apart from the axis of rotation and spaced apart spaced apart, the north-south axis of the magnets (M) being parallel to the support surface or space and radial to the axis of rotation, and each pair of magnets (M) being formed by two magnets (M) with north-south directions opposites pointing towards or away from each other, respectively, and where the innermost magnets (M) of the innermost pairs of magnets (M) on each side each have: e6-1) symmetric north-south directions with respect to the axis of rotation, both pointing both apart and towards the axis of rotation; or e6-2) asymmetric north-south direction with respect to the axis of rotation, one pointing away and one toward the axis of rotation; or e7) the device either e7-1) comprises the optional bar dipole magnet (M) on the axis of rotation and one or more magnets (M) on either side of the axis of rotation, the north-south axis of all magnets (M), being parallel to the bearing surface and the north-south axis of the magnets on either side of the axis of rotation is essentially radial to the axis of rotation; as e7-2) the device does not comprise the optional bar dipole magnet (M) on the axis of rotation and comprises two or more magnets (M) on both sides of the axis of rotation that are arranged spaced apart from the axis of rotation, the north-south axis of all magnets (M) being parallel to the bearing surface or space and radial to the axis of rotation, in which case the north-south directions of the magnets (M) are arranged on one side of the axis of rotation are asymmetric to the north-south directions of magnets arranged on the other side of the axis of rotation relative to the axis of rotation (ie pointing towards the axis of rotation on one side and away from the axis of rotation on the other side ), such that the north-south directions are in line with the outermost magnet (M) on one side to the outermost magnet (M) on the other side, the magnet (M) on the axis of rotation in case e7-1 being aligned on this line; e8) the device comprises, on each side of the axis of rotation, two or more bar dipole magnets (M) all having their north-south axis perpendicular to the support surface or space and parallel to the axis of rotation, and optionally a dipole magnet in bar (M) arranged on the axis of rotation and also having its north-south axis perpendicular to the support surface or space and parallel to the axis of rotation; the north-south direction of adjacent magnets (M) being opposite with respect to the support surface or space, and the magnets (M) being interspaced with each other; or e9) the device comprises, on each side of the axis of rotation, two or more bar dipole magnets (M) all having their north-south axis parallel to the support surface or space and radial to the axis of rotation, and optionally a magnet bar dipole (M) arranged on the axis of rotation and also having its north-south axis parallel to the support surface or space and perpendicular to the axis of rotation; the north-south directions of adjacent magnets (M) pointing in opposite directions, and the magnets (M) being interspaced with each other; f) a magnetic field generating device, in which two or more loop-shaped dipole magnets (M) are provided such that their north-south axes are perpendicular to the support surface or space, the two or more magnets in a loop shape (M) being arranged nested, spaced apart and surrounding a central area, the magnets (M) being axially magnetized and adjacent loop-shaped magnets (M) have north-south directions pointing either towards or away from the support surface or space , the device additionally comprising a bar dipole magnet (M) provided in the central area surrounded by the loop-shaped magnets (M), the bar dipole magnet (M) having its north-south axis perpendicular to the supporting surface and parallel to the north-south axis of the loop-shaped magnets (M), the north-south direction of the bar dipole magnet (M) being opposite to the north-south direction of the innermost loop-shaped magnet (M), the device optionally , additionally comprising a polar piece (Y) on the op side face of the support surface or space and in contact with the central bar dipole magnet (M) and the loop-shaped magnets (M); g) a magnetic field generating device, comprising a permanent magnetic plate that is magnetized perpendicular to the plane of the plate and having projections and impressions, the projections and impressions being arranged to form nested loop-shaped impressions and projections surrounding a central area, the projections and impressions forming opposite magnetic poles; and h) a magnetic field generating device comprising a plurality of bar dipole magnets (M) provided around an axis of rotation, the magnets (M) on both sides of the axes of rotation being two or more bar dipole magnets (M), all, having their north-south axis either parallel or perpendicular to the support surface or space, and optionally a bar dipole magnet (M) arranged about the axis of rotation and also having its north-south axis parallel or perpendicular to the support surface; respectively, the north-south directions of adjacent magnets (M) pointing in the same or opposite directions, and the magnets (M) being spaced apart or in direct contact with each other, the magnets (M) optionally being provided on a plate grounding device.
[0014]
14. Printing set, characterized in that it comprises the magnetic field generating devices recited in claims 7 - 13, which optionally is a rotating printing set.
[0015]
15. Use of magnetic field generating devices, as defined in any one of claims 7 to 13, characterized in that it is for the production of OEL, defined in any one of claims 1 to 6.
[0016]
16. Process for the production of the optical effect layer (OEL), as defined in any one of claims 1 to 6, characterized in that it comprises the steps of: a) applying on a support surface or a substrate surface (S ) a coating composition comprising a binder material and a plurality of non-spherical magnetic or magnetizable particles (P), wherein at least a part of the plurality of non-spherical magnetic or magnetizable particles (P) is comprised of optically variable magnetic or magnetizable pigments non-spherical, said coating composition, being in a first state (fluid), b) exposing the coating composition in a first state to the magnetic field of one of the magnetic field generating devices, as defined in any one of claims 7 - 13 , thereby orienting at least a portion of the non-spherical magnetic or magnetizable particles (P) in a plurality of a shaped area a nested loop loop surrounding a central area such that the longest axis of the particles (P) in each of the cross-sectional areas of the loop-shaped areas follow a tangent of either a negatively curved or positively curved part of hypothetical ellipses or circles ; and c) hardening the coating composition to a second state so as to fix the magnetizable or non-spherical magnetic particles (P) in their adopted positions and orientations.
[0017]
17. Process according to claim 16, characterized in that the hardening step c) is done by curing by UV-Vis light radiation.
[0018]
18. Optical effect layer, according to any one of claims 1 to 6, characterized in that it is obtainable by the process, as defined in claim 16 or 17.
[0019]
19. Optical effect layer (OEL) coated substrate, characterized in that it comprises one or more optical effect layers, as defined in any one of claims 1 to 6 or 18 on a substrate (S).
[0020]
20. Security document, preferably a banknote or an identity document, characterized in that it comprises an optical effect layer, as defined in any one of claims 1 to 6 or 18.
[0021]
21. Use of the optical effect layer, as defined in any one of claims 1 to 6 or 18, or of the optical effect layer coated substrate, as defined in claim 19, characterized in that it is for the protection of a document of security against forgery or fraud or for a decorative application.

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同族专利:

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公开号 | 公开日

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CA2890164A1|2014-07-17|

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CN104918715B|2018-06-05|

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PH12015501286A1|2015-08-24|

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US20150352883A1|2015-12-10|

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TW201431712A|2014-08-16|

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US10682877B2|2020-06-16|

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AU2013372261B2|2017-08-24|

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JP6535926B2|2019-07-03|

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MX2015008872A|2015-10-30|

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KR20150102980A|2015-09-09|

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EP2943290A1|2015-11-18|

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US20180093518A1|2018-04-05|

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EP3623058A1|2020-03-18|

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JP2016511703A|2016-04-21|

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RU2015133188A|2017-02-14|

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WO2014108303A1|2014-07-17|

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CN104918715A|2015-09-16|

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KR102197889B1|2021-01-06|

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BR112015011390A2|2017-07-11|

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AU2013372261A1|2015-05-21|

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RU2655355C2|2018-05-25|

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HK1210092A1|2016-04-15|

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US9849713B2|2017-12-26|

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ES2831605T3|2021-06-09|

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EP2943290B1|2020-09-02|

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JP2018141960A|2018-09-13|

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AR094363A1|2015-07-29|

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法律状态:
2018-03-06| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|

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2018-03-13| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|

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2018-03-20| B06I| Publication of requirement cancelled [chapter 6.9 patent gazette]|Free format text: ANULADA A PUBLICACAO CODIGO 6.6.1 NA RPI NO 2462 DE 13/03/2018 POR TER SIDO INDEVIDA. |

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2019-10-15| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|

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2021-04-06| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|

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2021-06-22| B16A| Patent or certificate of addition of invention granted|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 20/12/2013, OBSERVADAS AS CONDICOES LEGAIS. |

优先权:

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申请号 | 申请日 | 专利标题

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EP13150693|2013-01-09|

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EP13150693.3|2013-01-09|

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PCT/EP2013/077698|WO2014108303A1|2013-01-09|2013-12-20|Optical effect layers showing a viewing angle dependent optical effect, processes and devices for their production, items carrying an optical effect layer, and uses thereof|

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