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    • 专利摘要:
    CATALYTIC FILTER MODULE AND CATALYTIC FILTER SYSTEM THAT UNDERSTANDS THE SAME This is a catalytic filter module for gaseous fluids that can be incorporated into a high integration density in a filter system. The filter module comprises a block-shaped filter element, a catalytic element and a cleaning gas collection and discharge arrangement. The catalytic element is substantially coextensive with the filter element, said filter element has a feed face and on its opposite side a discharge face from which the filtrate leaves to be received by the upstream face of the catalytic element. The gaseous fluid exits the catalytic element as a clean gas on a clean gas face opposite the upstream face. The cleaning gas collection and discharge arrangement comprises one or more channels that extend across the clean gas face of the catalytic element bypassing and directing the clean gas flow transverse to the vertical of the clean gas face of the catalytic element to a clean gas discharge opening of the filter module on the side of the filter module.
    公开号:BR102013020905B1
    申请号:R102013020905-8
    申请日:2013-08-15
    公开日:2021-02-23
    发明作者:Steffen Heidenreich
    申请人:Pall Corporation；
    IPC主号:
    专利说明:

    Field of the Invention
    [001] This invention relates to a catalytic filter module and a catalytic filter system that comprises the same. The catalytic filter modules and catalytic filter systems of the present invention are used, in general, for particle removal and the combined catalytic removal of gaseous components in gaseous fluids. an example for such an application is a combined removal of nitrogen oxides and particles from combustion or exhaust gases. Fundamentals of the Invention
    [002] A filter system for cleaning flue gas is known from U.S. patent 5,318,755 A in which a barrier filter element of a honeycomb structure is accommodated in a housing together with a separate catalyst element. The crude gas first passes through a barrier filter element in a clean gas space and then passes through the clean gas space through the catalyst element, which, likewise, has a hive. The catalyst element is substantially coextensive with the filter element. The clean gas is subsequently discharged from the housing in a direction substantially parallel to the direction of flow within the filter element and the catalytic element.
    [003] Catalytic filter modules in the form of cylindrical filter plugs and a filtration system comprising the same inside a filter container have been proposed in U.S. Patent 6,863,868 B1 for the filtration of hot gas. The filter plugs have a single porous body of sintered particles, said particles are coated with a catalytic layer on their surfaces. The upstream or feeding surface of the filter plugs is covered by a porous membrane that retains fine solids. The clean gas accumulates inside the filter plugs and is extracted from there in a common clean gas space where it is discharged from a system container.
    [004] The prior art catalytic filter modules in the form of single and cylindrical filter plugs are typically produced from ceramic materials. Conventional catalytic ceramic filter plugs typically have a length of 2 or sometimes up to 3 m which, due to the mechanical properties of the sintered ceramic material and the mechanical stress during the operation of the filter systems, cannot be increased. Therefore, the filter area of the individual plugs is limited and to handle the higher volume flow rates thousands or tens of thousands of filter plugs are required. Very large filter vessels or several vessels operating in parallel are necessary in order to accommodate such a large number of catalytic filter plugs.
    [005] However, volume flow rates in hot gas filtration applications can vary up to about 1 million m3 / h or more which are too high for the use of such conventional catalytic ceramic filter candles. Brief Summary of the Invention
    [006] The purpose of the present invention is to provide a filter module that can be incorporated at a high density of integration into a filter system.
    [007] This problem is solved by a filter module according to claim 1.
    [008] The catalytic filter modules of the invention provide an area of high volume filtration and can be easily integrated with high densities in a filter system. Therefore, the catalytic filter modules of the invention provide a solution for very high volume flow rates, while the filter container that accommodates the modules is still reasonably economical in size.
    [009] Catalytic filter modules and systems that comprise the same can advantageously be used in classic hot gas filtrations. Other fields of application are biomass gasification, cleaning of exhaust gases from sintering plants and coke plants, cleaning of exhaust gases from plants and incinerators, refinery processes as in FCC units (catalytic fluid cracking) ) or in chemical processes, in the cement industry, etc. Detailed Description of the Invention
    [010] The catalytic filter modules of the invention comprise a block-shaped filter element, a catalytic element and a clean gas collection and discharge arrangement.
    [011] The filter element and the catalytic element are substantially coexensive with each other. The filter element receives the feed gas (for example, combustion or hot gas) on its upstream or feed face. On the opposite surface of the block-shaped cup of the filter element (hereinafter, the filtrate side or the discharge side) the filtrate leaves to be received by the upstream face of the catalytic element.
    [012] The catalytic element can be arranged on the filtrate side of the filter element a small gap between the filter element and the catalytic element. In other preferred embodiments, the catalytic element is positioned in direct contact with the filter element and receives directly the filtrate for the catalytic treatment of the gaseous components still included within the filtrate gas.
    [013] Clean gas exits the catalytic element on its clean gas face. The direction of the gas flow through the filter element and the catalytic element is substantially uniform and linear.
    [014] The clean gas collection and discharge arrangement extends substantially across the clean gas face of the catalytic element and receives the clean gas flow / stream therefrom. The clean gas collection and discharge arrangement diverts and directs the flow of clean gas transversely to the vertical of the clean gas face of the catalytic element. The clean gas leaves the module of the invention through an opening in its side face.
    [015] Due to such a design, the filter element, the catalytic element and the clean gas collection and discharge arrangement can be supplied in a very compact structure and assembled in a large number by volume inside a housing or a container of a catalytic filter system.
    [016] The filter element of the catalytic filter module of the invention can be selected from different designs according to the challenges of a specific filtration application.
    [017] Typical designs include membranes, films, sheets, discs and honeycomb structured elements.
    [018] Preferably, the filter elements are produced from sintered ceramic, metal or plastic material.
    [019] The filter element can be developed as a unitary structure or a plurality of subunits fixed to each other by gluing, welding or sintering or by accommodating the subunits in a common frame.
    [020] The filter elements of a honeycomb structure are preferred when a high filtration area is required. The filter elements of a honeycomb structure typically have a plurality of crude gas ducts and filtrate ducts arranged co-extensively and in parallel, the crude gas ducts being opened on either the raw gas side or the feed side of the filter element and closed on the filtrate side or on the discharge side thereof. The filtrate ducts are closed on the raw gas side of the filter element and opened on the filtrate side. The crude gas ducts and the filtrate ducts are separated from each other by porous tubular wall parts.
    [021] The preferable axial length of the tubular wall parts of the filter elements ranges from about 10 mm to about 300 mm, more preferably from about 30 mm to about 200 mm, with the most preferred about 50 mm to about 150 mm. The preferable axial length of the tubular wall parts allows efficient discharge of the particulate material from the filter elements during the return thrust even when the longitudinal axis of the filter elements is in a horizontal orientation.
    [022] The number of filter elements per 10 cm2 of cross-section on the supply side of a unit preferably ranges from about 1 to about 100, more preferably from 2 to about 10. Typically, the same number of clean gas ducts is provided per 10 cm2 of cross-sectional area.
    [023] The tubular wall parts have cross-sectional areas that correspond to the area of a square with an edge length of about 3 mm to about 20 mm, preferably from about 5 mm to about 10 mm. The corresponding cross-sectional areas are also preferable for filter elements developed with other rectangular, oval or circular sections.
    [024] The average porosity of the tubular wall parts and optionally the closed ends of the crude gas pipelines and / or the clean gas pipelines in the range of about 25 to about 90% by volume.
    [025] In order to allow the regeneration of the filter element while it is accommodated in the filter container of a system gas filter, the return pulses are applied that separate and remove the particulate material collected in the crude gas pipelines during operation filtration.
    [026] The catalytic filter modules of the invention are typically accommodated in the housing of a catalytic filter system with the crude gas sides of the filter elements oriented vertically
    [027] An orientation of the crude gas ducts of the filter elements perpendicular to the crude gas side of them already allows an effective return impulse and the removal of particulate material from the crude gas ducts. The efficiency of removing particulate matter from the crude gas pipelines during the return pulse can be further improved by orienting the crude gas pipelines (and, likewise, the filtrate pipelines) in an inclined orientation. The angle between the longitudinal axis of the crude gas pipelines and the vertical of the feed face is preferably in the range of about 10 ° to about 60 °, preferably about 30 ° to about 60 °, at lower part of the crude gas pipelines with their ends open.
    [028] The preferred pore size of the filter elements ranges from about 0.1 μm to about 150 μm, more preferably from about 1 μm to about 100 μm, with the most preference from about 2 μm to about 10μm. In some embodiments, the filter elements are developed for particle filtration and are able to retain particles of a size less than about 1 μm, for example, about 0.5 μm.
    [029] The catalytic element according to a first preferred embodiment of the present invention has a compartment that accommodates the catalytic particulate material in the form of a fluidized bed or a fixed bed.
    [030] The catalyst particles of the fluidized bed or fixed bed oil preferably have an average particle size of about 10 μm to about 30 mm, more preferably from about 100 μm to about 10 mm.
    [031] In a preferred embodiment, the catalytic element comprises a body produced from sintered grains and / or a fibrous material or a foam material. The catalytic element can be produced from ceramic or metal materials. In some cases, the ceramic or metal material may have a catalytic activity per se sufficient for a specific application or incorporate a catalyst, optionally, a catalyst can be applied to the body of the catalytic element, for example, by impregnation or coating of the body of the catalytic element.
    [032] In general, the catalyst element can be of several structures, for example, a honeycomb structure, a type of cassettes, discs or in the form of a plate, or in the form of a fiber mat. The catalyst element can have a unitary structure or it can be composed of several subunits.
    [033] The body of the catalytic element preferably has a hive structure. The hive structure may have a shape similar to that of the hive structure explained in conjunction with the detailed description of the filter element. However, typically the ducts of the hive structure of a catalytic element are opened at both ends of the same, in contrast to the ducts of a filter element that has a closed end.
    [034] The advantage of this second preferred modality over the first preferred modality is that such catalytic elements can be designed with a smaller delta p and a more homogeneous distribution of the catalytically active components.
    [035] The lower the pressure drop by the catalytic element provides a more effective return pulse during the regeneration and calculation of the filter modules.
    [036] Preferably, the pore size of the catalytic element is made larger than the pore size of the filter element. Therefore, the catalytic element does not contribute to the perceptible effect the filter of the filter module, that is, it is more or less not actively involved in the separation of particles from the feed gas.
    [037] An average pore size of a preferred catalytic element ranges from about 10 to about 500 mm, more preferably from about 50 to about 200 μm
    [038] Preferred catalytic elements produced from ceramic foam can be characterized by a pore size of about 10 to about 60 ppi (pores per inch), more preferably from about 30 to 45 ppi. The ceramic foam is preferably produced from sintered particles with an average particle size of about 0.1 to about 100 µm, more preferably from about 0.3 to about 30 µm.
    [039] Catalytic elements in the form of porous bodies made of ceramic fibers are preferred when the fibers have an average fiber diameter of about 1 to 50 μm, more preferably, about 2 to 10 μm. The length of the fiber is preferable in the range of about 1 to about 20 mm.
    [040] The catalytic elements used in the catalytic filter modules of the present invention can be supplied on their upstream surface, with a safety filter layer. The catalytic elements then furthermore have the function of a safety fuse.
    [041] The catalytic filter module can be developed with different catalytic activities and also combined in order to adapt to the requirements of a specific application. Typical catalytic activities are, for example, redox reactions, no tar reduction or removal.
    [042] Depending on the application, the filter module of the present invention can be equipped with a second catalytic element that provides a catalytic activity different from the catalytic activity of the first catalytic element.
    [043] The clean gas collection and discharge arrangement can be developed to one or more parallel channels. Preferably, a channel has a weight measured as the clearance / space in the vertical direction of the clean gas face of the catalytic element, in the range of about 0.1 to about 0.7 times, preferably about 0, 3 at about 0.5 times the distance of the filter element supply face from the clean gas face of the catalytic element.
    [044] In accordance with yet another aspect of the present invention, the filter module may comprise a first set of a block-shaped filter element and a catalytic element and a second set of a block-shaped filter element and an element catalytic, the first and second sets being arranged spaced apart from each other and the clean gas faces of the respective oriented catalytic elements opposite each other, said clean gas collection and discharge arrangement which is positioned between the first and second sets which they receive clean gas from the clean gas faces of the catalytic elements of the first and second assemblies and serve both assemblies. Preferably, one or more channels of the clean gas collection and discharge arrangement have a weight, measured as the vertical clearance of the clean gas face of the assemblies, in the range of about 0.2 to about 1, 4 times, more preferably, about 0.6 to about 1 times the distance from the supply face of the filter element from the clean gas face of the catalytic element of an assembly.
    [045] In accordance with yet another aspect of the present invention, the channels of the clean gas collection and discharge arrangement are oriented with their longitudinal direction at an angle of about 30 ° or more, preferably about 60 ° or more, more preferably about 90 ° for the clean gas face of the catalyst element of the filter module.
    [046] This deflection angle is defined in a preferred mode by the orientation of a wall or walls of the channel (s) of the clean gas collection and discharge arrangement that extend through the discharge side of the unit (s) (s) in block format of the filter module.
    [047] Preferably, the filter element and catalytic element assemblies in an opposite arrangement are provided with their discharge faces in a parallel orientation. The deflection angle of the clean gas coming out of the clean gas ducts is then about 90 °.
    [048] However, block-shaped units in an opposite arrangement may have their discharge side surfaces arranged divergent from the parallel orientation. However, the angle of deviation for the clean gas leaving the clean gas ducts is preferably about 30 ° or more, more preferably about 60 ° or more.
    [049] The preferred catalytic filter modules of the invention are designed as a rectangular cross section catalytic filter plug that can be placed in a filter system container, depending on a tube blade similar to conventional cylindrical filter plugs. .
    [050] The filter module can be produced from a filter element that comprises several subunits assembled by gluing, sintering or welding the subunits together or by accommodating the subunits in a common frame. The catalytic element can consist of a unitary element that serves all the subunits of the filter element or several subunits, for example, a subunit of the catalytic element that serves four subunits of the filter element or the subunits of the catalytic element that correspond in number to the number of subunits that make up the filter element.
    [051] The filter modules of the present invention may also include a frame on their side faces, which facilitates the assembly of the filter modules in a housing.
    [052] The invention also relates to a catalytic filter system that incorporates one or more catalytic filter modules in a housing as explained above.
    [053] The housing comprises an interior space separated in a chamber of raw gas and clean gas. The filter module (s) is (are) disposed within said interior space, the feeding face (s) of the filter element (s) oriented substantially vertically and in communication fluid with the raw gas chamber. The clean gas discharge opening (s) of the filter module (s) is (are) in fluid communication with the clean gas chamber of the housing. Optionally, the system comprises a return impulse arrangement.
    [054] Preferably, the housing comprises a tube blade which separates the interior of the housing in the raw gas and clean gas chamber, said tube blade comprising the openings accommodating the two or more filter modules, preferably , in parallel orientation to each other.
    [055] According to a preferred mode of the system, the filter modules are accommodated in the housing with a parallel orientation of the supply sides, optionally the supply side of a filter module that faces the clean gas side of a module adjacent, filter modules which are preferably arranged in a staggered configuration.
    [056] According to an additional preferred mode of the system, the filter modules are accommodated in the housing with a parallel orientation of their supply sides, the supply sides of a module that faces the supply side of an adjacent module, preferably, the system additionally includes the dividing plates positioned between the two adjacent filter modules.
    [057] According to yet another preferred modality of the system, two or more filter modules are mounted in a common part and preferably have their clean gas collection and discharge arrangements fluidly connected to each other. Preferably, the system comprises a clean gas discharge channel in which the discharge ends of the clean gas collection and discharge arrangements feed substantially and directly the clean gas through the clean gas openings of the filter modules. Brief Description of Drawings
    [058] figure 1A shows a catalytic filter module according to a first embodiment of the present invention; figure 1B shows the catalytic filter module of figure 1A equipped with a safety fuse function; figure 2 shows a catalytic filter module according to a second embodiment of the present invention; figure 3 shows a catalytic module according to a third embodiment of the present invention; Figures 4A to 4C show in a schematic representation a first embodiment of a catalytic filter system that incorporates the catalytic filter modules according to the present invention and the details thereof; and figures 5A to 5C show in a schematic representation a second embodiment of a catalytic filter system that incorporates the catalytic filter modules according to the present invention and the details thereof. Detailed Description of Drawings
    [059] Figure 1A shows a catalytic filter module 10 according to the present invention that includes a catalytic filter element 12 in a block-shaped design, a catalytic element 14 and a clean gas collection and discharge arrangement 16.
    [060] The block-shaped filter element 12, and the catalyst element 14 are designed to be substantially coextensive with each other and are arranged side by side, preferably in direct contact with each other, in order to feed the filtered product exiting filter element 12, directly to catalyst element 14.
    [061] On the clean gas side of the catalyst element 14, the clean gas discharge and collection arrangement 16 is provided in a structure substantially coextensive with the clean gas or on the downstream side of the catalyst element 14.
    [062] The clean gas discharge and collection arrangement 16 includes a box-shaped channel 18 that opens on the front side 19 of the filter module 10 with an opening 20, for example, for a clean gas chamber of a catalytic filter system (not shown in figure 1A).
    [063] The filter element 12 can have several designs and will be selected according to the particle charge and the nature of the particles to be removed from a crude gas.
    [064] In the following description, the invention is explained in conjunction with a preferred and specific filter element 12 with a so-called honeycomb structure, but, of course, the invention is not limited to that specific type of filter element.
    [065] The filter element 12 of the catalytic filter module 10 essentially consists of a unit 22 comprising a plurality of crude gas ducts 24 having a porous and longitudinal tubular wall part 26 with an open end 28 and a second end closed 30.
    [066] The parts of the tubular wall 26 have a square cross section and are arranged in a checkerboard pattern, together with a plurality of filtrate ducts 32, which are substantially coextensive with, oriented parallel to and regularly interposed between the crude gas ducts 24 The filtrate ducts 32 are open at one end 34 and closed at the other end 36 thereof. The open ends 28 of the crude gas ducts 24 and the closed ends 36 of the filtrate ducts 32 form a first checkerboard pattern on the upstream 38 or feed face of the filter element 12. A closed-end chessboard pattern 30, the crude gas ducts 24 and the open ends 34 of the filtrate ducts 32 are provided on the opposite side or the discharge chamber 40 of the unit 22. The parts of the tubular walls 26 of the crude gas ducts 24 are of a porous material, for example example, sintered ceramic material, sintered metallic material or a porous polymer material with a certain pore size. The parts of the wall 26 at the same time delimit the filtrate ducts 32 along their longitudinal direction.
    [067] The crude gas entering the supply face 38 of the filter element 12 flows to the open ends 28 of the crude gas ducts 24, penetrates its tubular wall parts 26, and the filtered gas is received in the filtrate ducts 32 from where it is discharged to the discharge face 40 of the filter element 12.
    [068] On the discharge face 40 of the unit 22, the catalyst element 14 extends over all said surface of the filter element 12. The catalyst element 14 can be described, in an exemplary way, as an element that has catalytic activity DeNOx.
    [069] The catalyst element 14 comprises a support body of a ceramic foam, for example, alumina or silicon carbide, with a pore density of about 30 ppi. The support body is catalytically activated with a selective catalytic reduction (RCS) of the composition of the TiO2, V2O5, WO3 catalyst.
    [070] The clean gas collection and discharge arrangement 16 is provided, which is closed on the back side and on three side faces and opens only with the front side face 44 shown in figure 1. The clean gas comes out of the filter module 10 through opening 20.
    [071] In order to facilitate the assembly of the filter module 10 in a compartment or container of a filter system, the filter module 10 comprises on its front face 44 a flange that protrudes outwards 46.
    [072] The side surfaces of the filtration module 10 are preferably covered by a metal frame structure 48, which can incorporate the clean gas collection and discharge arrangement 16. On one of the side surfaces of the frame structure 48 (face of the front side 44 in figure 1A), the flange 46 can be provided, as well as the opening 20.
    [073] According to the present invention, preferably, the length of the crude gas ducts 14 is limited to about 300 mm or less, which allows for very surprisingly easy cleaning by return pulse of the filter module and its element of particulate filter collected during the filtration operation in the tubular wall parts 26, even if they have the horizontal orientation shown in figure 1A.
    [074] The supply side of the unit 22 can have a size of, for example, 250 x 250 mm2. This is a typical size when unit 22 is produced from a ceramic material, using an extrusion process to produce the duct structure of unit 22. Other manufacturing processes may allow for larger dimensions of unit 22. The length the crude gas pipelines and filtrate pipelines can be about 300 mm, as mentioned earlier.
    [075] Typically, catalytic filter modules are desired to have a substantially larger size. This need can be easily met by a multi-unit structure where multiple units 22 are connected side by side, to provide the largest surface areas on the supply side of an upstream module, for example, the areas surface area of 1500 x 1000 mm2 or 4000 x 250 mm2. In the case of the first example, a matrix of 6 x 4 units 22 is necessary, in the second example, the need is met with a matrix unit of 16 x 1.
    [076] The fixing of the units can be carried out by sintering, welding or gluing the units, with your side facing together. Alternatively, the multiple units can be mounted on a common structure, their side faces are sealed against each other.
    [077] The catalytic elements may also comprise more than one unit and be joined or assembled as a unitary structure by the methods mentioned in conjunction with the filter element.
    [078] In filter modules with a multiple unit arrangement, the collection of clean gases and the discharge arrangement are designed with one or more channels, each of the channels for receiving clean gas from more than one unit.
    [079] Figure 1B shows a filter module 1 ', which is a modification of the filter module 10 of figure 1A. Therefore, similar parts are designated with the same reference numbers as used in the description of figure 1A. In addition to the components already described with reference to figure 1A, the filter module 10 'includes a safety fuse 49 in the form of a disk-shaped element that covers the outlets of the filtrate ducts 32. Safety fuse 49 is substantially coextensive with the discharge face of the filter element 12. In the event of failure of one or more of the crude gas duos 24, for example, their tubular wall parts, the unfiltered raw gas entering the filtrate channels 32 cannot reach catalyst element 14 without first passing through safety fuse 49. Safety fuse 49 can be provided on the upstream face of catalyst element 14.
    [080] The distance from the closed back wall of channel 18 to the face of clean gas makes the catalytic element (gap h) preferably equivalent to about 0.3 to about 0.5 times the distance from the chamber of the clean gas face filter element.
    [081] The filtrate is received by the catalytic element 14 through which it enters the clean gas collection and discharge arrangement 16. The clean gas flow is then deflected by about 90 ° and directed parallel to the clean gas face of the element catalytic 14.
    [082] Figure 2 shows a second embodiment of a catalytic filter module 50 according to the present invention.
    [083] The filter module 50 comprises a block-shaped filter element 52, in the form of a unit 54 comprising a plurality of crude gas ducts 56 having a longitudinal section, porous tubular wall part 58 with the ends open 60 and a second closed end 62.
    [084] The parts of the tubular wall 58 have a square cross section and are arranged in a checkered pattern, together with a plurality of filtrate ducts 64, which are substantially coextensive with, oriented parallel to and regularly interposed between the gas ducts crude 56. The filtrate ducts 64 are open at one end 66 and closed at the other end 68 thereof. The open ends 60 of the crude gas ducts 56 and the closed ends 68 of the filtrate ducts 64 form a first checkerboard pattern on the upstream or feed face 70 of the filter element 52.
    [085] A checkerboard pattern of the closed ends 62 of the crude gas ducts 56 and the open ends 66 of the filtrate ducts 64 is provided on the opposite side or the discharge chamber 72 of the unit 54. The tubular wall pieces 58 of the gas ducts crude 56 are of a porous material, for example, sintered ceramic material, sintered metallic material or a porous polymer material with a cetain pore size. The wall parts 58, at the same time delimit the filtered ducts 64 along their longitudinal direction.
    [086] The crude gas entering the supply side of the catalytic filter module 50 flows into the open ends 60 of the crude gas ducts 56, penetrates its tubular wall parts 58, and the filtrate is received in the filtrate ducts 64 from from where it is discharged on the discharge side 72 of the unit 54.
    [087] On the discharge side 72 of the unit 54, a catalytic element 74 extends over the entire surface of that side.
    [088] The catalyst element 74 can be designed as the catalyst element 14 shown in figures 1A and 1B.
    [089] The clean gas collection and discharge arrangement 76 is provided in the clean gas range 77 of the catalyst element 74. The clean gas collection and discharge arrangement comprises a box-shaped channel 78 that is closed in the the back and the three side faces and open only to the side face 80, as shown in figure 2.
    [090] Clean gas exits filter module 50 through opening 82. To facilitate the assembly of filter module 50 in a compartment of a filter system, the filter module 50 comprises on its front side a flange designed for out 86.
    [091] In contrast to the catalytic filter module 10 in figure 1, the catalytic filter module 50 in figure 2 has crude gas ducts 56 (and filtrate ducts 64) arranged in an oblique orientation in relation to the vertical from the feed face 70, the open ends of the crude gas ducts positioned lower than their closed ends. The angle of the longitudinal axis of the crude gas pipelines with the horizontal can vary from about 30 ° to about 60 °.
    [092] By means of the return pulse, the interior space of the crude gas ducts 56 can be more easily cleaned from the particulate matter that has accumulated during the process due to the sloping configuration of the tubular walls 58 of the filtration crude gas ducts 56.
    [093] Due to the sloping configuration of the crude gas ducts 56 inside the unit 54, a surface slightly less filtration by reason of volume is obtained. This, however, is compensated by the improved impulse return properties of the filter module 50, which allow, at the end of the longer cycle times of this type of module, compared to the filter module 10.
    [094] Figure 3 shows a third embodiment of the present invention in the form of a filtration module 100. The filter module 100 comprises two sets of filter elements and the catalytic elements. Units 102, 104 of the two sets have a basic structure identical to that of filter element 12 of filter module 10 of Figure 1A.
    [095] The two units 102, 104 comprise a plurality of gas ducts 106, 108 materials having a longitudinal section, part of the porous tubular wall 110, 112 with an open end 114, 116 and a second closed end. The tubular wall parts 110, 112 have a square cross section and are arranged in a checkerboard pattern, along with a plurality of filtrate ducts 122, 124 that are substantially coextensive with, oriented parallel to and regularly interposed between the gas ducts 106, 108 Subjects.
    [096] Filtrate ducts 122, 124 are open at one end and closed at the other end 130, 132 thereof. The open ends 122, 124 of the crude gas ducts 106, 108 and the closed ends 130, 132 of the filtrate ducts 122, 124 form first checkered patterns on the upstream or feed sides 134, 136 of the filter modules 100.
    [097] A checkerboard pattern of the closed ends of the raw gas ducts 106, 108 and the open ends of the filtrate ducts 122, 124 is provided on the opposite faces 140, 142 of the units 102, 104. These faces 140, 142 are downstream or discharge faces of the units 102, 104. The parts of the tubular walls 110, 112 of the gas ducts 106, 108 materials are of a porous material, for example, sintered ceramic material, sintered metallic material or a porous polymer material with a certain pore size. The wall pieces 110, 112, at the same time delimit the filtrate ducts 122, 124 along their longitudinal directions.
    [098] The crude gas entering the feed faces 134, 136 of the filter module 100 flows to the open ends 122, 124 of the crude gas ducts 106, 108, penetrates its tubular wall parts 110, 112, and the filtrate is received in the filtrate ducts 122, 124, from where it leaves through the discharge faces 140, 142 of the units 102, 104.
    [099] The catalytic elements 144, 146 can be designed as described together with the catalyst element 14, of the filter module 10 of figure 1A.
    [0100] However, in contrast to the filter module 10 of figure 1A, the filter module 100 of figure 3 has the two sets of units 102, 104 and the catalytic elements 144, 146 arranged in an opposite configuration in such a way that the catalytic elements 144, 146 positioned at the closed ends of the crude gas tubes and at the open ends of the filtrate ducts face each other.
    [0101] Therefore, a common clean gas collection and discharge arrangement 154 is sufficient to collect and discharge the clean gas supplied by both sets of units 102, 104 and catalytic elements 144, 146. Clean gas from both the catalytic elements 144, 146 when it enters the clean gas collection and discharge arrangement 156 is deflected by about 90 ° and directed transversely to the gas flow directions inside the filter elements 102, 104 and the catalytic elements 144, 146 from the filter module 100. The clean gas leaving the catalytic filter module 100 through the opening 160 to be discharged from a filtration system comprising the modules 100.
    [0102] While the filter modules 10 and 50 of Figures 1A, 1B and 2 can be easily arranged in a multi-module configuration within a compartment or container with the front faces 28, 68 facing the rear from the clean gas collection and discharge channel arrangement 16, 76, the particulate material separated from the filter elements by means of a return pulse can be easily discarded and removed from such a filtration system.
    [0103] However, a precautionary measure has to be taken in an array of multiple filter modules 100 in a compartment or container, as shown in figure 3.
    [0104] Upon return impulse, in a system comprising filter modules 100, cross contamination of the two filter modules facing each other may occur and, therefore, it is preferable to have a separating plate 180 arranged between the supply faces of the two adjacent filter modules 100, as shown in figure 3.
    [0105] Figure 4A shows a first embodiment of a catalytic filtration system 200 according to the present invention. The filter system 200 comprises a compartment 202, which is of an elongated box configuration. Enclosure 202 is compatible with base frame 203.
    [0106] Within the box-shaped compartment 202, two rows of a plurality of stacks of catalytic filter modules 204, 204 ', 204' ', ... and 206, 206', 206 '', ... are with the discharge openings of the filter modules the two rows facing in opposite directions. Along the longitudinal axis of the box-shaped compartment 202 the batteries are arranged in parallel at a certain distance from each other (see Figures 4B and 4C).
    [0107] Within an individual stack 204, 206 of the filter modules 204 a, b, c, d, and 206a, b, c, d, respectively, the filter modules can be mutually fixed to each other by means of gluing , welding or sintering together or mounted in a frame.
    [0108] In an exemplary arrangement of the filter system 200, the supply side of a filter module 204a, 206a can have a length of 1500 mm and a height of 1000 mm, the depth of the filter module can be about 400 mm. Such a filter module may comprise, for example, 24 units in block form, the side feed surface of which may be 250 mm x 250 mm in size and the length of the tubular wall parts of the filter element which are approximately 140 mm .
    [0109] The catalyst element for the discharge chamber of the filter element can be a plate-shaped body with a thickness of 200 mm, in the direction of the fluid flow.
    [0110] The clearance h of the clean gas collection and discharge channel can reach approximately 60 mm.
    [0111] The distance between the two adjacent stacks 204 and 204 'or 206 and 206' of the filter modules can be set, for example, to about 100 mm.
    [0112] The compartment comprises on its top surface a crude gas supply channel 208 that feeds the crude gas in compartment 202 and its filter modules 204, 206. The crude gas supply channel 208 has a cross-sectional area which decreases from the front end of the front shown in figure 4A to the dead end located at the rear end 214 of the system 200.
    [0113] On both side faces in a longitudinal direction, compartment 202 includes clean gas passages 210, 212 that open at the rear end 214 of system 200, where the clean gas can be discharged.
    [0114] In order to accommodate the increase in the amount of clean gas received from the multiple stacks of filter modules 204, 206 along the longitudinal axis of compartment 202, the cross section of the clean gas passages 210, 212 gradually increases in the direction of rear end 214 of system 200.
    [0115] Clean gas discharge channels 210, 212 can, according to a variant of being removable as a whole, when filter module batteries 204, 206 have to be changed. Alternatively, as shown in Figure 4A of the clean gas discharge channels 210, 212 can be provided with a number of ports 218, which allow access to the filter and exchange modules even without the complete removal of the gas discharge channels. clean 210, 212.
    [0116] The system 200 incorporates a return impulse mechanism that receives the gas by return impulse through a tube 216 which is only represented schematically. Figure 4A shows only tube 216 that supplies the pulsed back gas to the filter modules of batteries 204 for regeneration. A corresponding tube is required (not shown) for the regeneration of 206 batteries.
    [0117] Extending from the return pulse gas tube 260, a plurality of return pulse supply tubes 264 directs the return pulse gas to the various stacks of filter modules 204, 204 ', 204' ',
    [0118] The return pulse pressure supplied through the clean gas discharge channel to the individual filter modules 204a, 204B, 204C, 204D and 206a, 206b, 206c, 206D separates the particles that were collected during the filtration operation filter elements of these filter modules.
    [0119] The particles discharged during the return impulse from the catalytic filter modules are collected in dust collectors 220 arranged conically in the bottom of the housing 202.
    [0120] In the case of catalytic removal of components from the crude gas requires a reagent and / or if a sorbent necessary to complete the filtration, the crude gas supply channel can be provided with a sorbent injection unit and / or reagent 222.
    [0121] In figure 5A, a second embodiment of a catalytic filter system 300 of the invention is shown that comprises a shell 302, which essentially consists of a cylindrical wall part 304 which is closed at its upper end by a lid in the form of a dome 306 and connected at its lower end to a 308 dust collector with a conical shape.
    [0122] The compartment 302 is divided into a raw gas chamber 310 and 312 and a clean gas chamber by a tube blade 314 that extends along the entire cross section of the cylindrical wall part 304, at its end higher.
    [0123] The crude gas chamber 310 is accessible through a feed gas inlet 316 through which the crude gas can be introduced into the crude gas chamber 310.
    [0124] The dome-shaped portion 306 of compartment 302 comprises a clean gas outlet 318 through which the clean gas can be discharged.
    [0125] The tube blade 314 comprises a plurality of rectangular openings 320, which accommodates a plurality of catalytic filter candle type modules 330 according to the present invention.
    [0126] The candle-shaped catalytic filter modules 320 are shown in more detail in Figure 5B, and include at its upper end and extends outward from the peripheral flange 332 that serves for the assembly of the catalytic filter modules 330 inside the openings 320 of the tube sheet 314 in a downwardly downward direction.
    [0127] Figure 5C shows a cross section of the system 300 along the line V - V in figure 5A.
    [0128] The individual catalytic filter modules 330 comprise five units 334, 335, 336, 337 and 338 stacked on top of each other, all facing upstream or feeding side to the left as shown in Figure 5B. Units 334 to 338 have approximately the same configuration, with crude gas ducts and filtrate ducts, alternately arranged in a chess shape, as shown in Figure 1A, for which a more detailed explanation in this regard is omitted here. Block shaped units 334 to 338 can be mounted on a common frame structure 352 holding the units together and providing a common clean gas channel 346. The top surface of the common frame structure 352 can integrally incorporate flange 332 and providing aperture 350.
    [0129] On the opposite side, the block-shaped units 334 to 338 are covered by a common catalytic element 340.
    [0130] On the downstream or discharge side 342 of the common catalytic element 340, a provision for collecting and discharging common clean gas 344 is provided, consisting essentially of a clean gas channel 346, which at its upper end 348 discharges the clean gas, through opening 350 into the clean gas chamber 312 of compartment 302. Similar to what was shown in figure 1B and described in context with it, filter modules 330 can be supplied with separate safety fuse elements that extend across the entire surface of the discharge side of the filter module (not shown in Figures 5A to 5C).
    [0131] The candle type 330 filter modules are arranged on the tube blade 314 in a parallel staggered arrangement where the upstream or feed sides of the individual filter modules 330 face the clean gas channels of the filter modules adjacent 330.
    [0132] For the regeneration of the catalytic filter modules 330 of the catalytic filter system 300 360, a return impulse system is provided comprising a pressure source 362, as well as a plurality of supply lines 364 that terminate inside the dome cover 306 above individual filter modules 330.
    [0133] The particulate matter that is separated from the crude gas conduits of the block shaped units 334, 335, 336, 337, 338 of the catalytic filter modules 330 is collected by gravity inside the dust collection portion cone-shaped housing 308.
    [0134] Through the return impulse, when the particulate material is separated from the crude gas ducts of the block-shaped units 334, 335, 336, 337, 338 of the filter modules 330, no cross contamination between the filter modules adjacent 330 can occur because of its parallel orientation described above.
    [0135] The advantages of the present invention will be explained in more detail by means of an exemplary design.
    [0136] The system 200 of figures 4A to 4C, with catalytic filter modules 204, 206 can be designed to treat a flue gas volume rate of 234,000 cubic meters per hour, for removing particulate matter and nitrogen oxides as follows: Filter modules 204, 206 each have an area of the feed side 1500 x 1000 mm2. The filter elements are of a honeycomb structure with cross sections of the crude gas and filtrate ducts, 10 mm x 10 mm in dimensions, the axial length of the crude gas and filtrate ducts, being 140 mm. The filter element of each module is made up of 24 units, with an area of the 250 mm x 250 mm provisioning face in 6 x 4.
    [0137] The filter modules are equipped with plate-shaped catalyst elements with a thickness of 200 mm, in the direction of a flow of SiC ceramic foam with a pore density of 30 ppi (pores per inch), which it is catalytically activated with an SCR catalyst of the composition TiO2 V2O5, WO3.
    [0138] At an atmospheric pressure and an operating temperature of around 300 ° C, 192 filter modules are required to handle the volume rate identified above.
    [0139] The size of a compartment 202 to accommodate filter modules 192 in four stacks of modules 204, 206, as shown in figures 4A to 4C would have the dimensions 3.5 m wide and 12.5 m long and a height of 4 m. The filter modules can be incorporated in the compartment with a stack-to-stack distance in the longitudinal direction of the box of 100 mm.
    [0140] In cases where the operating pressure is about 1 bar or more above ambient pressure, it is preferred to use the container-type compartments 302 shown for the modality of figure 5A.
    权利要求:
    Claims (16)
    [0001]
    1. Catalytic filter module (10, 50) for gaseous fluids, comprising: a block-shaped filter element (12, 52); a catalytic element (14, 74); and a clean gas collection and discharge arrangement (16, 78); wherein said catalytic element (14, 74) is coextensive with the filter element (12, 52); said filter element (12, 52) having a supply face and on its opposite side a discharge face from which the filtrate exits to be received by the upstream face of the catalytic element (14, 74), the gaseous fluid which leaves the catalytic element (14, 74) as a clean gas on a clean gas face opposite the upstream face; CHARACTERIZED in that said filter element (12, 52) comprises a honeycomb structure, which comprises a plurality of crude gas ducts (24, 56) and filtrate ducts (32, 64), the crude gas ducts ( 24, 56) being separated from the filtrate ducts (32, 64) by tubular wall parts (26, 58), the crude gas ducts being opened on the supply side of the filter element (12, 52) and closed on the face discharge, said filtrate ducts being closed on the supply face of the filter element (12, 52) and open on the discharge side of the filter element, in which said clean gas collection and discharge arrangement (16, 78) comprises one or more channels extending across the clean gas face of the catalytic element (14, 74) deflecting and directing the clean gas flow transverse to the vertical of the clean gas face of the catalytic element (14, 74) to a clean gas discharge opening of the filter module (10, 50) on a side of the filter module, where the one or more rod of the clean gas collection and discharge arrangement (16, 78) has a height, measured as the clearance in the vertical direction of the clean gas face of the catalytic element (14, 74), in the range of 0.3 to 0 , 5 times the distance of the filter element supply face (12, 52) from the clean gas face of the catalytic element (14, 74), and in which the axial length of the tubular wall parts (26, 58) of the filter elements (12, 52) is 10 to 300 mm.
    [0002]
    2. Catalytic filter module (10, 50), according to claim 1, CHARACTERIZED by the fact that said catalytic element (14, 74) is a compartment that accommodates a fluidized bed or fixed bed of catalytic particles.
    [0003]
    3. Catalytic filter module (10, 50), according to claim 1, CHARACTERIZED by the fact that said catalytic element (14, 74) is a porous body of a fibrous and / or foam material comprising a catalyst , the catalyst being optionally applied to the body of the catalytic element by coating or impregnating it.
    [0004]
    4. Catalytic filter module (10, 50), according to claim 3, CHARACTERIZED by the fact that the pore size of the catalytic element (14, 74) is greater than the pore size of the filter element (12, 52).
    [0005]
    5. Catalytic filter module (10, 50), according to any one of claims 1 to 4, CHARACTERIZED by the fact that the catalytic element (14, 74) is a redox catalytic element, a catalytic element for reducing NO and / or a catalytic element for removing tar.
    [0006]
    6. Catalytic filter module (10, 50), according to any one of claims 1 to 4, CHARACTERIZED by the fact that the catalytic element (14, 74) comprises on its upstream face a filter layer to provide a functionality - safety fuse to the catalytic element.
    [0007]
    7. Filter module (100) for gaseous fluids comprising: a first set of a block-shaped filter element (102) and a catalytic element (144); and a second set of a block-shaped filter element (104) and a catalytic element (146), the first and second sets being arranged spaced apart from each other and oriented in opposition to the clean gas faces of the respective catalytic elements , CHARACTERIZED by said filter elements (102, 104) having a feeding face and on its opposite side a discharge face from which the filtrate leaves to be received by the upstream face of the catalytic element (144, 146), the gaseous fluid that exits the catalytic elements as a clean gas on the respective clean gas faces of the same opposite to the upstream face; a clean gas collection and discharge arrangement (156), wherein said clean gas collection and discharge arrangement (156) comprises one or more channels that extend across the clean gas face of the catalytic elements bypassing and directing the flow of clean gas transverse to the vertical of the clean gas face of the catalytic elements (144, 146) to a clean gas discharge opening of the filter module (100) on a side face thereof, said collection and disposal arrangement. discharge of clean gas (156) being developed as a common arrangement for the first and second assemblies and positioned between the first and second assemblies that receive the clean gas from the clean gas faces of the catalytic elements of the first and second assemblies; wherein said filter elements (102, 104) comprise a honeycomb structure, comprising a plurality of crude gas ducts (106, 108) and filtrate ducts (122, 124), the crude gas ducts ( 106, 108) being separated from the filtered gas ducts (122, 124) by tubular wall parts (110, 112), the crude gas ducts (106, 108) being opened at the supply face of the filter element and closed at the discharge side thereof, said filtrate ducts (122, 124) being closed on the supply face of the filter element (102, 104) and open on the discharge face of the same, and in which the axial length of the wall parts tube (110, 112) of the filter elements (102, 104) is 10 to 300 mm, the one or more channels of the clean gas collection and discharge arrangement (156) have a height, measured as the clearance in the direction from the vertical of the clean gas faces of the assemblies, in the range of 0.6 to about 1 times the distance from the supply face of the filter element (102, 104 ) from the clean gas face of the catalytic element (122, 124) of an assembly.
    [0008]
    8. Filter module (10, 50, 100) according to any one of claims 1 to 7, CHARACTERIZED by the fact that said crude gas ducts (106, 108) and filtrate ducts (122, 124) being oriented parallel or inclined at an angle from about 10 ° to about 60 °, more preferably from 30 ° to 60 ° to the vertical of the supply face of the filter element (12, 52, 102, 104).
    [0009]
    9. Filter module (10, 50, 100), according to claim 8, CHARACTERIZED by the fact that the cross section of the tubular wall parts (110, 112) of the filter elements (12, 52, 102, 104 ) is of a polygonal shape, especially rectangular, more preferably square, circular or oval.
    [0010]
    10. Filter module (10, 50, 100), according to claim 9, CHARACTERIZED by the fact that the tubular wall parts (110, 112) have an area in cross section that corresponds to the area of a square with a edge length from 3 to 20 mm, preferably from 5 to 10 mm.
    [0011]
    11. Filter module (10, 50, 100) according to any one of claims 1 to 10, CHARACTERIZED by the fact that the axial length of the tubular wall parts (110, 112) of the filter elements (12, 52 , 102, 104) is 30 to 200 mm, preferably 50 to 150 mm.
    [0012]
    12. Catalytic filter system (300) CHARACTERIZED by the fact that it comprises a filter housing (302) and one or more catalytic filter modules (330) defined in any one of claims 1 to 11, accommodated in said housing (302) , wherein said housing (302) which comprises a separate interior space in a raw gas and clean gas chamber (310, 312), said filter module (s) (330) which is (are) disposed within said interior space, the supply side (s) of the filter element (s) (330) oriented substantially vertically, the (s) said supply side (s) of the filter element (s) (330) being in fluid communication with the crude gas chamber (310) and said opening (s) ) for clean gas discharge from the filter module (s) (330) being in fluid communication with the clean gas chamber (312) of the housing (302), the system (300) optionally comprising an impulse arrangement of return (360).
    [0013]
    13. Catalytic filter system (300) according to claim 12, CHARACTERIZED by the fact that the housing (302) comprises a tube blade (314) that separates the interior of the housing (302) in the crude gas chambers and of clean gas (310, 312), said tube blade (314) comprising the openings accommodating the two or more filter modules (330), preferably in parallel orientation to each other.
    [0014]
    14. Filter system according to claim 12 or 13, CHARACTERIZED by the fact that the filter modules (330) are accommodated in the housing (302) with a parallel orientation of the supply sides, optionally the supply side of a filter module (330) faces the clean gas side of an adjacent module (330), the filter modules (330) are preferably arranged in a staggered configuration.
    [0015]
    15. Filter system (300) according to claim 12 or 13, CHARACTERIZED by the fact that the filter modules (330) are accommodated in the housing (302) with a parallel orientation of their feeding sides, the sides of supplying a module (330) facing the supply side of an adjacent module (330), preferably the system additionally includes dividing plates positioned between the two adjacent filter modules (330).
    [0016]
    16. Filter system (300) according to any one of claims 12 to 15, CHARACTERIZED by the fact that the two or more filter modules (330) are mounted on a common part (352) and, preferably, have its clean gas collection and discharge arrangements fluidly connected to each other, preferably the system (300) comprises a clean gas discharge channel in which the discharge ends of the gas collection and discharge arrangements Clean feed substantially directly the clean gas through the clean gas openings of the filter modules (330).
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    同族专利:
    公开号 | 公开日
    EP2698188B1|2018-01-31|
    US20140050626A1|2014-02-20|
    BR102013020905A2|2017-07-04|
    KR20140023238A|2014-02-26|
    KR101670006B1|2016-10-27|
    SG10201602025XA|2016-05-30|
    US9504958B2|2016-11-29|
    CN103585825B|2016-04-20|
    ES2663770T3|2018-04-17|
    CA2821749A1|2014-02-17|
    JP5884786B2|2016-03-15|
    NO2698188T3|2018-06-30|
    TW201412383A|2014-04-01|
    JP2014039925A|2014-03-06|
    AU2013211459A1|2014-03-06|
    CN103585825A|2014-02-19|
    EP2698188A1|2014-02-19|
    PL2698188T3|2018-05-30|
    SG2013058011A|2014-03-28|
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    法律状态:
    2017-07-04| B03A| Publication of a patent application or of a certificate of addition of invention [chapter 3.1 patent gazette]|
    2018-03-06| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|
    2018-03-13| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|
    2018-03-20| B06I| Publication of requirement cancelled [chapter 6.9 patent gazette]|Free format text: ANULADA A PUBLICACAO CODIGO 6.6.1 NA RPI NO 2462 DE 13/03/2018 POR TER SIDO INDEVIDA. |
    2020-01-07| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|
    2020-12-08| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|
    2021-02-23| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 15/08/2013, OBSERVADAS AS CONDICOES LEGAIS. |
    优先权:
    申请号 | 申请日 | 专利标题
    EP12180891.9|2012-08-17|
    EP12180891.9A|EP2698188B1|2012-08-17|2012-08-17|Catalytic filter module and catalytic filter system comprising same|
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