• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    A method for preparing beer concentrate comprising the steps of: a) subjecting beer or cider (1) to a first concentration step comprising reverse osmosis to obtain a retentate (2) and a fraction comprising alcohol and volatile flavoring components (3) wherein the retentate is characterized by the concentration of non-filterable components equal to or higher than 5% (w / w), preferably 10% (w / w), most preferably 15% (w / w). / wt.), as calculated from density measurement corrected for the alcohol amount; b) subjecting the retentate (2) to a retentate concentrating step comprising nanofiltration to obtain a concentrated retentate (2) and a permeate comprising alcohol and volatile flavor components.
    公开号:BE1025468B1
    申请号:E2017/5870
    申请日:2017-11-30
    公开日:2019-03-13
    发明作者:Andre Joao；Miguel Monsanto
    申请人:Anheuser-Busch Inbev S.A.；
    IPC主号:
    专利说明:

    Method for the production of a beer or cider concentrate
    Technical area
    The present invention relates to a method for preparing beer or cider concentrate comprising alcohol and flavoring components, and furthermore beer or cider, respectively prepared therefrom. In particular, the invention relates to a two-step concentrating method wherein the first step involves a reverse osmosis that results in a concentrated retentate and an aqueous permeate fraction comprising alcohol and volatile flavoring components, and wherein the second step implies a further concentration of the retentate by a nanafiltration method that permits the obtaining of a highly concentrated extract fraction.
    BACKGROUND OF THE INVENTION
    The main advantage of producing concentrates is the reduction in weight and volume that makes it possible to save on storage and transport costs, in addition to that it often also has a beneficial effect on improving the shelf life of a product. Since beers and many other alcoholic beverages generally contain about 80 to 90% water, it has of course been recognized that the most economical way to store them or distribute them over considerable distances would be in the form of a concentrate.
    BE2017 / 5870
    In principle, a concentrate can be reconstituted at any place and time in the initial product by the addition of the solvent, usually water. Nevertheless, it is not easy to produce a beer or cider-like beverage concentrate, the greatest difficulty being in the fact that most concentration procedures lead to a reduction in many flavor or odor components. Beer in particular is a very challenging drink to produce a concentrate from because, unlike drinks produced from fruit juice fermentation such as wine or pear cider, the fragrances present in beer are more subtle and much less concentrated, meaning losing even a small portion have a profound effect on the organoleptic observation of the rehydrated end product at the concentration stage. In addition, due to the high popularity of the beverage and the existence of a wide audience of demanding beer aficionados, the reconstituted beverage is expected to meet expectations regarding the characteristic odor, taste, mouthfeel, foam properties, color, and even perception of cloudiness. . Reconstituted beer simply should not taste like a diluted beer that lacks some characteristics; in order to win consumer acceptance, it simply must have all the qualities of the 'real' unprocessed beer.
    Methods for producing beer concentrates and subsequently rehydrating them in final drinks are known in the art. Various methods for concentrating alcoholic beverages that
    BE2017 / 5870 known in the brewing industry include such processes as freeze drying, reverse osmosis and filtration. All of these processes begin with a substantially beer-ready beer and then remove the water. The resulting concentrated drinks can then be transported more cost-effectively and then reconstituted at a final destination by adding water, carbon dioxide and alternatively also alcohol.
    An example of one method for preparing a reconstitutable beer concentrate can be found in GB2133418. The method is based on subjecting beer to reverse osmosis and results in a low alcohol concentrate that can be rehydrated in a low alcoholic beer.
    On the other hand, US4265920 and US4532140 teach two-step methods for obtaining a high alcoholic beer concentrate that can be reconstituted in beers with normal alcohol content. The method of US4265920 comprises a first distillation step to separate ethanol and volatile odor components from the retentate which comprises the rest of the beer components, which is followed by a second step comprising a fairly expensive freeze concentration procedure to concentrate the retentate from the first step. Finally, the distilled ethanol from step 1 is combined with the freeze-concentrated retentate from step 2, resulting in the final ethanol-enriched beer concentrate. On the other hand, the method of US4532140 in the first step subjects beer
    BE2017 / 5870 ultrafiltration to obtain a concentrated retentate and an aqueous permeate which is then subjected to reverse osmosis in the second step to concentrate ethanol and volatile compounds; finally, the alcohol fraction from step 2 is combined with the retentate from step 1 to obtain the final beer concentrate.
    Although at least some of the methods described above provide a general approach to concentrating beer including its alcohol content and to some extent volatile components, they achieve their goal at the expense of achieving high concentration factors and only provide final concentrates with a volume that half or at most a third of the volume of the starting beer. Therefore, there is clear room for improvement and for providing more concentrated beer bases that provide further reduction in transportation and storage costs.
    The present invention provides a method for producing a high density naturally concentrated alcohol-enriched beer concentrate, said method providing an advantageous concentration factor potential of at least 5, 10, 15, to 20 or more, while at the same time providing high and optionally selective retention of natural beer flavor compounds, including the volatile ones, are guaranteed. These and other advantages of the present invention are presented in the following.
    BE2017 / 5870
    Summary of the invention
    The present invention is defined in the appended independent claims. Preferred embodiments are defined in the dependent claims. In particular, the present invention relates to a method for preparing beer concentrate, comprising the steps of:
    a) subjecting beer or cider (1) to a first concentration step comprising reverse osmosis to obtain a retentate (2) and a fraction comprising alcohol and volatile flavor components (3), the retentate (2) being characterized by the concentration of non-filterable compounds equal to or higher than 5% (w / w), preferably 10% (w / w), most preferably 15% (w / w), as calculated from density measurement corrected for the amount of alcohol;
    b) subjecting the retentate (2) to a retentate concentration step (RC) comprising nanofiltration to obtain a concentrated retentate (4) and a permeate (5) comprising alcohol and volatile flavor components.
    Preferably, at least a portion of the permeate obtained in the retentate concentration step (RC) is recycled to the feed of the first concentration step to limit losses of volatile flavor components.
    The fraction (3) comprising alcohol and volatile flavor components obtained from the reverse osmosis
    BE2017 / 5870 is preferably supplied to a concentration step B) which allows recovery of volatile flavor components; such a recovery step may include, for example, freeze concentration, fractionation, reverse osmosis (with a membrane having a smaller mesh size than the reverse osmosis membrane of the first concentration step), adsorption and / or combinations of the above concentration steps. Potentially, the permeate of nanofiltration can be subjected to the same concentration steps to allow recovery of the volatile flavor components therein.
    At least a portion of the fraction (7) comprising volatile flavor components obtained from process steps B) is preferably added to the retentate (4) of the nanofiltration step.
    The present invention also relates to the use of a fraction comprising volatile flavoring components or of a concentrated fraction comprising volatile flavoring components obtained by a method as identified above as an ingredient for beer or cider, as a component in beer or cider reconstitution or as an flavoring component to be added to a beer or cider.
    Brief description of the figures
    For a more complete understanding of the nature of the present invention, reference is made to the following detailed description taken in conjunction with the accompanying figures wherein:
    BE2017 / 5870
    Figure 1: shows a block diagram that schematically illustrates the most important steps of the method according to the present invention. A - first concentration step comprising reverse osmosis; RC retentate concentration step by nanofiltration; B second concentration step comprising freeze concentration, fractionation or adsorption; C - a third process step comprising adsorption; D - a fourth process step comprising freeze concentration
    I - beer subjected to reverse osmosis; 2 retentate; 3 - permeate comprising ethanol and volatile odor components; 4 - retentate from the nanofiltration; Permeate of the nanofiltration; 6 - remaining fraction of the second concentration step B); 7 - concentrated fraction comprising volatile flavor components; 8 concentrated fraction comprising volatile flavor components after adsorption step C); 9 remaining fraction of the adsorption step C); 10 remaining fraction of the freeze concentration step D);
    II - concentrated extract fraction from the freezing concentration step D).
    Figure 2: shows a graph illustrating the relationship between the concentration factors of different retentates (4) obtained from different beers (beer 1-4) and the amount of non-filterable compounds ('% solids') achieved in said retentates after the first concentration step and retentate concentration step (RC) according to the method of the invention.
    BE2017 / 5870
    Definitions
    As used herein, the term "concentrate" is given the definition of the Oxford dictionary: "a substance made by removing or reducing the diluent; a concentrated form of something '(cf.
    http: // www. oxforddictionaries. com / definition / english / concentrate). In line with this, the term "beer or cider concentrate" or alternatively "(concentrated) beer or cider base" or "beer or cider syrup" means that it relates to beer or cider of which the major part of the solvent component - ie water - has been removed, while most of the dissolved components have been retained which impart such characteristics as taste, odor, color, mouthfeel etc.
    As used herein, the term "beer" is to be interpreted according to a fairly broad definition:
    the drink obtained by fermentation from a wort prepared with raw starch or sugar materials, including hop powder or hop extracts and drinking water. In addition to barley malt and wheat malt, only the following can be considered for brewing, mixed with, for example, wheat malt, raw starch or sugar materials in which the total amount must not exceed 80%, preferably 40% of the total weight of the raw starch - or sugar materials:
    (a) tender, rice, sugar, wheat, barley and its various forms;
    BE2017 / 5870 (b) Sucrose, converted sugar, dextrose and glucose syrup. "
    Although according to certain national legislation not all fermented malt-based beverages can be called beer, in the context of the present invention the terms "beer" and "fermented malt-based beverage" are used herein as synonyms and can be used interchangeably. It follows that, as used herein, the terms "reconstituted beer" and "reconstituted malt-based fermented beverage" are to be interpreted as beverages that are essentially identical to beer in composition but obtained by adding the solvent, ie water or carbonated water, to a previously prepared beer concentrate.
    Furthermore, the term "cider" as used herein is to be interpreted as any alcoholic beverage resulting from the fermentation of apple juice or apple juice mixed with up to 10% pear juice. This term also includes any product of this fermented apple juice that has been further modified by adding such standard cider making additives as acids (lemon or tartar) and / or sugar, filtering, cooling, saturation with carbon dioxide, pasteurizing, etc. term cider is being commercialized.
    As used herein, the term "non-filterable compounds" should be interpreted as referring to all the different compounds included in any type of beer or cider that cannot pass through a nanofiltration membrane, ie beer compounds with the average size greater than 150 Da, 180 Da or 200 Da , which depends on one
    BE2017 / 5870 given the nanofiltration membrane is the limit of the molecular weight retention size. In contrast to the 'filterable compounds' which include water, monovalent and single bivalent ions, low molecular weight alcohols such as ethanol, low molecular weight esters and a number of volatile flavor components, the non-filterable compounds essentially comprise sugars, mainly polysaccharides; sugar alcohols, polyphenols, pentosans, peptides and proteins, high molecular weight alcohols, high molecular weight esters, partly multivalent ions and many other essentially organic and very different compounds that vary depending on the beer or cider type. Due to the complexity and differences between different beer or cider compositions, the collective concentration of the non-filterable compounds is often (in great simplification and without being precise) called "sugar concentration" or "solid concentration" and can be easily calculated from mass balance considerations that take into account parameters such as density, viscosity, beer rheology, original density or original extract, actual density or actual extract, fermentation degree (RDF) and / or alcohol content. In brewing practice, the concentration of non-filterable compounds is routinely estimated from density measurement (actual extract) corrected for the density of the measured ethanol amount, with ethanol being the most predominant compound of density <1 g / cm 3 and
    BE2017 / 5870 thereby substantially influences the density measurement. Such measurements are well known in the art, are routinely performed using standard beer analysis systems such as the Anton Paar Alcolyzer device, and are therefore quick and easy to carry out by the average beer brewer.
    The amount of components dissolved in beer can also be expressed as so-called specific density (relative density) or apparent specific density. The first is measured as the density (weight per unit volume) of beer divided by the density of water used as a reference substance, the second as the weight of a volume of beer relative to the weight of an equal volume of water. A specific density of 1.050 ('50 points'), for example, indicates that the substance is 5% heavier than an equal volume of water. The densities of water, and consequently also of beer, vary with temperature; therefore, for both specific density and apparent specific density, the measurement of the sample and the reference value is done under the same specified temperature and pressure conditions. The pressure is almost always 1 atm equal to 101.325 kPa, while temperatures may differ depending on the choice of further systems for approximate beer density. Examples of such systems are two empirical dishes, the Plato and the Brix dishes, which are commonly used in the brewing and wine industries respectively. Both scales represent
    BE2017 / 5870 the strength of the solution as a percentage of sugar in terms of mass; one degree of Plato (abbreviated ° P) or one degree of Brix (symbol ° Bx) is 1 gram of sucrose in 100 grams of water. There is primarily a difference between these units in that both trays have been developed for sucrose solutions at different temperatures, but it is so insignificant that they can be used practically interchangeably. For example, beer measured at 12 ° Plato at 15.5 ° C has the same density as a water-sucrose solution containing 12 mass% sucrose at 15.5 ° C, which is approximately equal to 12 ° Brix, which is the same density as a water sucrose solution containing 12 mass% sucrose at 20 ° C. The Plato and Brix dishes have an advantage over specific density in that they express the density measurement in terms of the amount of fermentable materials, which is particularly useful at early stages of brewing. Since both beer and wort are naturally composed of more solids than just sucrose, it is not exact. The relationship between degrees Plato and specific density is not linear, but a good approximation is that 1 ° P equals 4 brewer's points (4 x 0.001); so 12 ° Plato corresponds to a specific density of 1.048 [1+ (12 x 4 x 0.01).
    The term "original density" or "original extract" refers to specific density as measured before fermentation, while the term "final density" or "final extract" refers to specific density measured at the completion of the
    BE2017 / 5870 fermentation. In general, density refers to the specific density of the beer at various stages in its fermentation. Initially, before alcohol production by the yeast, the specific density of wort (i.e., the ground malt before beer fermentation) is primarily dependent on the amount of sucrose. Therefore, the reading of the original density at the beginning of the fermentation can be used to determine the sugar content in Plato or Brix dishes. As fermentation progresses, the yeast converts sugars into carbon dioxide, ethanol, yeast biomass and flavor components. The reduction in the amount of sugar and the increase in the presence of alcohol, which has a noticeably lower density than water, both contribute to reducing the specific density of the fermenting beer. Reading of the original density compared to reading of the final density can be used to estimate the amount of sugar used and thus the amount of ethanol produced. For example, for a regular beer, the original density could be 1.050 and the final density could be 1.010. Similarly, knowing the original density of a beverage and its alcohol content can be used to estimate the amount of sugars used during fermentation. The degree to which sugar is fermented in alcohol is expressed by the term "actual degree of fermentation" or "RDF" and is often given as a fraction of the
    BE2017 / 5870 original density converted into ethanol and CO2. Beer RDF is theoretically indicative of its sweetness, since beers usually have more residual sugar and therefore a lower RDF.
    Concentration steps may involve any of the variety of techniques recognized in the art that allow for partial or substantial separation of water from the beer and thus retention of most of the components dissolved therein in a lower than initial volume. Many of the techniques currently used in the beverage industry rely on so-called membrane technologies, which provide a cheaper alternative to conventional heat treatment processes and involve separation of substances into two fractions using a semi-permeable membrane. The fraction comprising particles smaller than the membrane pore size passes through the membrane and is referred to as "permeate" or "filtrate" as used herein. Everything else that is retained on the supply side of the membrane is referred to as "retentate" as used herein.
    Typical membrane filtration systems include, for example, pressure driven techniques, microfiltration, ultrafiltration, nanofiltration and reverse osmosis. As used herein, the term "microfiltration" refers to a membrane filtration technique for the retention of particles with a size of 0.1 to 10 μm and larger. Usually microfiltration is a process at low pressure, typically operating at pressures
    BE2017 / 5870 extend between 0.34-3 bar. 1 Microfiltration allows separation of particles such as yeast, protozoa, large bacteria, organic and inorganic sediments, etc. Next, the term "ultrafiltration" as used herein denotes a membrane filtration technique for the retention of particles with a size of approximately 0.01 μm and bigger. Ultrafiltration usually retains particles with molecular weights greater than 1000 Dalton, such as most viruses, proteins of certain sizes, nucleic acids, dextrins, pentosan chains, etc. Typical operating pressures for ultrafiltration range between 0.48-10 bar. Furthermore, the term "nanofiltration" as used herein will be interpreted as a membrane filtration technique for the retention of particles with a size of 0.001 μm to 0.01 μm and larger. Nanofiltration is capable of retaining divalent or multivalent ions, such as divalent salts, and most organic compounds greater than about 180 Daltons, which include oligosaccharides and many flavoring compounds; while allowing water, ethanol, monovalent ions and some organic molecules such as many aromatic esters to pass through. Operating pressures of 8-41 bar are typical for nanofiltration. Where nanofiltration is performed under inlet pressure within the upper limit of this range, from 18 bar upwards, it will be referred to as "high pressure nanofiltration" as used herein. Finally, the term "reverse osmosis" as used herein will be interpreted to refer to a 1 where the unit bar is 100,000 Pa, in accordance with the definition of IUPAC, [1 Pa = 1 N / m A 2 = 1 kg / m * s A 2 in SI units.]
    BE2017 / 5870 high pressure membrane process where the applied pressure is used to overcome osmotic pressure. Reverse osmosis usually makes it possible to retain particles with a size of 0.0005 μm to 0.0001 μm and larger, i.e. virtually all particles and ion species. Substances with a molecular weight above 50 Dalton are retained almost without exception. Operating pressures are typically between 21 and 76 bar, but can reach up to 150 bar in specific applications.
    Furthermore, the term "volatile flavoring components" as used herein is to be interpreted as including any of the substances contained in beer that contribute to its complex olfactory profile, said chemicals having a boiling point lower than that of water due to their chemical nature. Examples of volatile flavor components of beer include, but are not limited to, acetaldehyde, N-propanol, ethyl acetate, isobutyl alcohol, isoamyl alcohol, isoamyl acetate, ethyl hexanoate, ethyl octanoate, phenylethyl alcohol, 2-methyl-1-butanol, and much more.
    Detailed description of the invention
    The present invention relates to a method for the production of a beer or cider concentrate, said method comprising the steps of:
    a) supplying a stream of beer or cider (1) to a first concentration step comprising reverse osmosis (A) to obtain an alcohol retentate (2) and a permeate (3)
    BE2017 / 5870 alcohol and volatile flavor components, wherein the retentate (2) is characterized by the concentration of non-filterable compounds equal to or higher than 5% (w / w), preferably 10% (w / w) , most preferably 15% (w / w), as calculated from density measurement corrected for the alcohol amount;
    b) subjecting the retentate (2) to a retentate concentration step (RC) comprising nanofiltration to obtain a concentrated retentate (4) and a permeate (5) comprising alcohol and volatile flavor components.
    Usually beer (1) is subjected to reverse osmosis (A) according to the invention, preferably clear beer that has been treated using any regular beer clearance technique to remove yeast and most of the other particles above 0.2 µm in diameter. Such techniques are standard and well known in the field of beer preparation. They include, for example, centrifugation, filtration through, for example, kieselguhr (diatomaceous earth), optionally preceded by centrifugation, or other types of standard microfiltration techniques.
    As can be seen from the present disclosure, the method of the invention is particularly advantageous for obtaining low volume and high density beer or cider concentrates with limited or ideally no loss of volatile flavor components. The degree of concentration of the end product largely depends on the degree of concentration of the retentate obtained via
    BE2017 / 5870
    nanofiltration in step B). Therefore provided the present invention a method at which it retentate not only it largest part of the flavoring components of beer (or cider) includes, but potential too characterized by a high concentration factor of 5, 1 0, 15, or even 20 or higher. Like this one used, the term 'concentration factor' interpreted too be already s de
    ratio of the beer or cider volume subjected to nanofiltration or reverse osmosis in step A) to the volume of the retentate obtained at the end of the nanofiltration or reverse osmosis in step a), ie the ratio of the input volume to the volume of the retentate obtained in the step a) of the method of the present invention. In a particularly preferred embodiment, a method according to the preceding embodiments is provided, wherein the retentate obtained in step a) is characterized by a concentration factor of 5 or higher, preferably 10 or higher, more preferably 15 or higher, most preferably 20 or higher. A relationship between the concentration factor within the meaning defined above and the concentration of non-filterable compounds that may be obtained in the retentate from step a), of course, depends on the type of beer or cider that is initially subjected to nanofiltration or reverse osmosis, what is shown and can be understood from the graph presented in Figure 2, where each line has a different one
    BE2017 / 5870 represents drink (lines 1-4 were obtained for different beers, line 5 was obtained for cider).
    Concentration factors of 10 and higher can, in terms of speed and efficiency, be preferably obtained by, as used herein, a high pressure nanofiltration, i.e. a nanofiltration carried out under a pressure of at least 18 bar. Thus, in preferred embodiments of the invention, a method is provided wherein the nanofiltration in step a) is a high pressure nanofiltration, defined as nanofiltration performed under a pressure in the range of about 18-41 bar, preferably in the range of about 20 -35 bar, most preferably about 30 bar.
    In the case of cross-flow filtration, we can always obtain the concentration in one pass. But to make the action more economical, a multi-stage action is done.
    In line with the above, the present invention is based on the finding that by concentrating the beer in a first concentration step comprising reverse osmosis, the loss of volatile flavor components can be limited, although at the expense of concentration capacity. Regarding nanofiltration or ultrafiltration, the maximum concentration factor that can be achieved by concentrating beer with reverse osmosis is limited. By subsequently performing a nanofiltration such as high pressure nanofiltration on the retentate of the reverse osmosis, a further concentration of the beer can be achieved. Further
    BE2017 / 5870 high pressure nanofiltration provides concentration potential that is considerably better than the one of ultrafiltration or reverse osmosis, which makes it possible to obtain retentate of a density comprised between 20-50 ° P or higher, even after a single filtration pass . In an economically preferred embodiment, nanofiltration is performed as a multi-stage operation, with the retentate continuing from one stage to the next while becoming more and more concentrated. The preferred final density value of the retentate available according to step a) of the present invention is comprised between 30-80 ° P or higher, preferably between 50-70 ° P, most preferably about 60 ° P. Therefore, in one preferred embodiment of the invention, the retentate from step a) is obtained in a single pass of nanofiltration, which is preferably nanofiltration at high pressure, more preferably nanofiltration at high pressure under a pressure range between 18-35 bar, with most preferably between about 20-30 bar.
    It has been observed that such a high concentration potential can be achieved in particular using polymeric spiral wound membranes in the range of 150-200 Daltons or similar. Examples of such membranes include thin film composite ATF (alternating tangential filtration, Refine Technology) membranes such as those currently available from DOW and Parker Domnick Hunter.
    BE2017 / 5870
    After the nanofiltration step, the highly concentrated retentate (4) is collected while the aqueous permeate is either recycled to the reverse osmosis feed or processed by either distillation, freeze concentration or adsorption to recover selectively volatile flavor components and optionally ethanol.
    The permeate of the first concentration step by reverse osmosis is preferably processed by either distillation, freeze concentration or adsorption in order to selectively recover volatile flavor components and optionally ethanol. In the case that the permeate of the nanofiltration step is processed by distillation, freeze concentration or adsorption, this permeate can be processed together with the permeate of the first concentration step.
    Figure 1 schematically illustrates a diagram of the method according to the present invention in which a beer (1) is subjected to a first concentration step comprising reverse osmosis (semipermeable membrane acting as a physical barrier against passage of most beer components of average molecular weight (MW)> 50 Da ) to obtain a retentate (2) comprising concentrated extract of the beer and a permeate (3) that mainly comprises water and ethanol, but also a small amount of volatile flavor components and possibly some extract. The retentate is then attached to a nanofiltration membrane (semi-permeable membrane acting as a physical barrier against passage of most beer components of average molecular weight (MW)
    BE2017 / 5870> 150-200 Da). The nanofiltration allows a further concentration of the retentate (2) obtained by the reverse osmosis, but at the expense of slightly higher losses of volatile flavor components. To limit these losses, the present invention provides for recirculation of the nanofiltration permeate (5) to the feed of the first concentration step and / or downstream processing of the permeate (5) to selectively recover volatile flavor components and optionally alcohol.
    The downstream processing of the permeate (5) can be combined with a downstream processing of the permeate from the first concentration step (A) or can be carried out in parallel with it. For both permeates, the downstream operation may include a second concentration step (B) that either distillation, freeze concentration (freeze concentration essentially relates to the removal of pure water in the form of ice crystals at temperatures below zero) or adsorption processes of the volatile flavor components on a column and subsequent elution of the volatile flavor components with water or ethanol.
    Distillation is a classic example of a fractionation technique that is known to be particularly suitable for separating alcohol and volatile components from water. The term "distillation" as used herein refers to the separation of the liquid mixture into its components using the difference in relative volatility
    BE2017 / 5870 and / or boiling point between the components by inducing their consecutive evaporation and condensation in the process of heating and cooling. Examples of the distillation may include simple distillation, fractional distillation, multi-stage distillation, azeotropic distillation, and steam distillation. In a preferred embodiment, a method of the invention is provided wherein the concentration in step b) comprises aromatic distillation, said distillation being defined as distillation designed to ensure high recovery of odor-producing compounds. Figure 2 shows a specific embodiment of the general method according to the invention, wherein the second concentration (B) is performed by fractional distillation, as schematically illustrated by the presence of a fractionation column.
    Distillation is part of a larger group of separation processes based on phase transition, collectively called 'fractionation'. Other examples of fractionation include column chromatography based on difference in affinity between stationary phase and the mobile phase, and fractional crystallization and fractional freezing both using the difference in crystallization or melting points of different components of a mixture at a given temperature. In a preferred device of the present invention, method b) may comprise such a factioning device, preferably distillation, wherein different fractions for the presence of different components such as
    BE2017 / 5870 different volatile flavor component types are analyzed, and then selectively directed to merge with the retentate from step a) or discarded,
    somewhat larger check about odor profile from it finally beer concentrate of the invention would provide. In it case Which the second concentration step (B) distillation includes, can the upper fraction (7) That alcohol and fleeting
    flavor component, are further subjected to an adsorption process (C) to selectively recover volatile flavor component (8). This fraction of volatile flavoring components (8) can be wholly or partially mixed with the retention (4) of the nanofiltration step (RC) to obtain a beer concentrate or can be used as an ingredient for beer, as a component in beer reconstitution or as an flavoring component to be added to a beer or cider. When used as a component in beer reconstitution starting from a beer concentrate, the beer concentrate can be either the beer concentrate obtained by the process of the present invention or another beer concentrate.
    The lower fraction of the distillation step (B) (remaining fraction (6)) can be subjected to a freeze concentration process (D) to recover potential extract (11) that can be added to the nanofiltration retentate (4) or can be used as an ingredient for beer, as a component
    BE2017 / 5870 in beer reconstitution or as a flavoring component to be added to a beer or cider. When used as a component in beer reconstitution starting from a beer concentrate, the beer concentrate can be either the beer concentrate obtained by the process of the present invention or another beer concentrate.
    In addition to the methods disclosed above, the beer or cider may be pretreated prior to being subjected to the first concentration step. The pre-treatment preferably comprises a decarbonation of the beer or the cider. Alternatively, the fraction comprising alcohol and volatile flavor components (3) and / or the permeate (5) can be treated for removal of carbon dioxide. Decarbonation of the liquid can be achieved by simply exposing the beer, the cider, the fraction (3) or the permeate (5) to a vacuum for a period of time sufficient to remove a desired amount of carbon dioxide from the respective liquid. However, such a decarbonation process has the disadvantage that, in addition to the carbon dioxide, volatile flavor components are also removed from the liquid. Therefore, decarbonation is preferably carried out over a membrane, in which beer, cider, fraction (3) or permeate (5) is passed over one side of the membrane, while a vacuum or nitrogen flow is provided on the other side of the membrane, whereby carbon dioxide is removed from the liquid via the membrane. Such decarbonation membranes have been commercialized by, for example, 3M (Liqui-Cel
    BE2017 / 5870
    Membrane Contractors). Ideally, decarbonation of the beer, cider, fraction (3) or permeate (5) is carried out to a level where the carbon dioxide content of the liquid is less than or equal to 1 g / l, preferably less than or equal to
    0.5 g / l. The decarbonation of the beer, the cider, the fraction (3) or the permeate (5) to that extent is particularly preferred when the beer, the cider, the fraction (3) or the permeate (5) is subjected to freeze concentration. In other words, decarbonation is preferably up to a CC 2 content of 1 g / l or less, preferably 0.5 g / l or less and can be done at the level of the beer, the cider, the fraction (3 ) or the permeate (5).
    权利要求:
    Claims (7)
    [1]
    CONCLUSIONS
    A method for preparing beer concentrate, comprising the steps of:
    a) subjecting beer or cider (1) to a first concentration step comprising reverse osmosis to obtain a retentate (2) and a fraction comprising alcohol and volatile flavor components (3), the retentate (2) being characterized by the concentration of non-filterable compounds equal to or higher than 5% (w / w), preferably 10% (w / w), most preferably 15% (w / w), as calculated from density measurement corrected for the amount of alcohol;
    b) subjecting the retentate (2) to a retentate concentration step comprising nanofiltration to obtain a concentrated retentate (2) and a permeate comprising alcohol and volatile flavor components.
    [2]
    The method of claim 1, comprising recirculating at least a portion of the permeate (4) from the nanofiltration to the feed of the first concentration step.
    [3]
    Method according to claim 1 or 2, comprising the steps of:
    b) subjecting the fraction comprising alcohol and volatile flavor components (3) and / or the permeate (5) of the nanofiltration (RC) to a subsequent concentration step (B) comprising freeze concentration, fractionation, which is preferably distillation,
    BE2017 / 5870 reverse osmosis or adsorption, to obtain a concentrated fraction comprising volatile flavor components (7) and a remaining fraction (6).
    [4]
    A method according to claim 2 or 3, wherein the following concentration step (B) comprises a fractionation process and wherein the remaining fraction (6) is subjected to a freeze concentration process (D) to obtain a concentrated extract fraction (11).
    [5]
    The method according to claim 2 or 3, wherein the following concentration step (B) comprises a fractionation process and wherein the concentrated fraction comprising alcohol and volatile flavor components (7) is subjected to an adsorption process (C), wherein at least a part of the volatile flavoring components from the fraction is adsorbed, and then eluting the adsorbed volatile flavoring components into a volume of water or ethanol to obtain a concentrated fraction of volatile flavoring components (8).
    [6]
    A method according to any one of the preceding claims, comprising adding at least a portion of the fraction comprising volatile flavoring components (7) obtained from process steps B) to the retentate (4) of the nanofiltration step (RC).
    [7]
    7. - Use of a fraction comprising volatile flavoring components or of a concentrated fraction comprising volatile flavoring components obtained by a method such as
    BE2017 / 5870 identified in any of claims 1 to 6 as an ingredient for beer or cider, as a component in beer or cider reconstitution or as a flavoring component to be added to a beer or cider.
    类似技术:
    公开号 | 公开日 | 专利标题
    AU2015352559B2|2020-01-23|Beer or cider concentrate
    BE1025898B1|2019-08-12|Process for the production of a beer or cider concentrate
    EP3026104A1|2016-06-01|Beer or cider concentrate
    BE1025834B1|2019-08-14|Process for the production of a beer or cider concentrate
    BE1025741B1|2019-07-01|Process for the production of a beer or cider concentrate with little or no alcohol
    BE1025468B1|2019-03-13|Process for the production of a beer or cider concentrate
    BE1025453B1|2019-03-05|Beer or cider concentrate
    AU2016282713B2|2020-10-08|Beer or cider base
    EP3101114A1|2016-12-07|Beer concentrate
    BE1025551B1|2019-04-09|Process for the production of a beer or cider concentrate
    EP3165595A1|2017-05-10|Beer or cider base
    Bekassy-Molnar2017|Wine Production Using Membranes
    BR112017027181B1|2022-02-01|METHOD TO PREPARE AN AROMATIC DRINK
    同族专利:
    公开号 | 公开日
    EP3330363A1|2018-06-06|
    WO2018100044A1|2018-06-07|
    BE1025468A1|2019-03-06|
    AR110287A1|2019-03-13|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    EP0116462A1|1983-02-09|1984-08-22|A.G. Limited|Concentration of alcoholic beverages|
    WO1992008783A1|1990-11-13|1992-05-29|Dow Danmark A/S|Membrane process for the dealcoholization of naturally fermented beverages|
    EP1611940A1|2004-06-14|2006-01-04|Warsteiner Brauerei Haus Cramer KG|Process for the production of beer having modified beer ingredients|
    EP3026104A1|2014-11-25|2016-06-01|Anheuser-Busch InBev S.A.|Beer or cider concentrate|
    WO2016083482A1|2014-11-25|2016-06-02|Anheuser-Busch Inbev S.A.|Beer or cider concentrate|
    GB1570944A|1977-03-19|1980-07-09|Douwe Egberts Tabaksfab|Process for the concentration of aqueous solutions|
    FR2524000B1|1982-03-24|1985-05-10|Union Brasseries|
    DK568683A|1982-12-10|1984-06-11|Uop Inc|PROCEDURE FOR CONCENTRATING ALCOHOLIC DRINKS|WO2016081399A1|2014-11-17|2016-05-26|Massachusetts Institute Of Technology|Concentration control in filtration systems, and associated methods|
    BE1026801B1|2018-11-22|2020-06-25|Anheuser Busch Inbev Sa|METHOD FOR OBTAINING A CONCENTRATED FRAGRANCE AND TASTE MIX AND USE THEREOF|
    法律状态:
    2019-05-02| FG| Patent granted|Effective date: 20190313 |
    优先权:
    申请号 | 申请日 | 专利标题
    EP16201532.5|2016-11-30|
    EP16201532.5A|EP3330363A1|2016-11-30|2016-11-30|Process for the production of a beer or cider concentrate|
    [返回顶部]