 PROCESS FOR MANUFACTURING LARGE FINESSE OFF-LIMITED MILK MILK AND HIGH FINENSE LIME MILK PRODUCED TH
专利摘要:
A process for producing a high fineness milk of lime comprising at least the steps of providing a lime compound and forming said lime milk with a process water and said lime compound. 公开号:BE1024520B1 申请号:E2017/5138 申请日:2017-03-07 公开日:2018-03-26 发明作者:Guillaume Criniere；Robert Sebastian Gärtner 申请人:S.A. Lhoist Recherche Et Developpement； IPC主号:
专利说明:
economy FPS Economy, SMEs, Middle Classes & Energy Intellectual Property Office 1024520 Bl Issue date: 03/26/2018 PATENT Priority date: 03/08/2016 International classification: C01F 11/02, C04B 28/10, C04B 2/06, C04B 2/08 Filing number: BE2017 / 5138 Filing date: 07/03/2017 Holder: S.A. LHOIST RESEARCH AND DEVELOPMENT 1342, OTTIGNIES-LOUVAIN-LA-NEUVE Belgium Inventor: CRINIERE Guillaume 1420 BRAINE-L'ALLEUD Belgium GARTNER Robert Sebastian 1501 BUIZINGEN Belgium PROCESS FOR THE MANUFACTURE OF A LITTLE EXTINGUISHED LIME MILK AND LARGE FINE LIME MILK THUS OBTAINED WITH TREATMENT WATER A method of manufacturing a very fine lime milk comprising at least the steps of supplying a lime compound and forming said lime milk with process water and said lime compound. BELGIAN INVENTION PATENT FPS Economy, SMEs, Middle Classes & Energy Publication number: 1024520 Deposit number: BE2017 / 5138 Intellectual Property Office International Classification: C01F 11/02 C04B 28/10 C04B 2/06 C04B 2/08 Issue date: 03/26/2018 The Minister of the Economy, Having regard to the Paris Convention of March 20, 1883 for the Protection of Industrial Property; Considering the law of March 28, 1984 on patents for invention, article 22, for patent applications introduced before September 22, 2014; Given Title 1 “Patents for invention” of Book XI of the Code of Economic Law, article XI.24, for patent applications introduced from September 22, 2014; Having regard to the Royal Decree of 2 December 1986 relating to the request, the issue and the maintenance in force of invention patents, article 28; Given the patent application received by the Intellectual Property Office on 07/03/2017. Whereas for patent applications falling within the scope of Title 1, Book XI of the Code of Economic Law (hereinafter CDE), in accordance with article XI. 19, §4, paragraph 2, of the CDE, if the patent application has been the subject of a search report mentioning a lack of unity of invention within the meaning of the §ler of article XI.19 cited above and in the event that the applicant does not limit or file a divisional application in accordance with the results of the search report, the granted patent will be limited to the claims for which the search report has been drawn up. Stopped : First article. - It is issued to S.A. LHOIST RESEARCH AND DEVELOPMENT, Rue Charles Dubois 28, 1342 OTTIGNIES-LOUVAINLA-NEUVE Belgium; represented by GEVERS PATENTS, Holidaystraat 5, 1831, DIEGEM; a 20-year Belgian invention patent, subject to the payment of the annual fees referred to in article XI.48, §1 of the Code of Economic Law, for: PROCESS OF MANUFACTURING AN LIME MILK HIGH FINESSE EXTINGUISH AND HIGH FINESSE LIME MILK OBTAINED WITH TREATMENT WATER. INVENTOR (S): CRINIERE Guillaume, Rue du Menil 175, 1420, BRAINE-L'ALLEUD; GARTNER Robert Sebastian, O. De Kerchove d'Exaerdestraat 186, 1501, BUIZINGEN; PRIORITY (S): 03/08/2016 EP PCT / EP2016 / 054941; DIVISION: divided from the basic application: filing date of the basic application: Article 2. - This patent is granted without prior examination of the patentability of the invention, without guarantee of the merit of the invention or of the accuracy of the description thereof and at the risk and peril of the applicant (s) ( s). Brussels, 03/26/2018, By special delegation: BE2017 / 5138 Process for the production of a very fine slaked lime milk and very fine lime milk thus obtained with process water The present invention relates to a process for the manufacture of a milk of lime of great fineness comprising at least the steps consisting in: a) providing a lime compound chosen from the group of quicklime, a first lime compound and their mixture, said first lime compound being chosen from the group consisting of pre-hydrated lime obtained by adding a first water to quicklime, lime paste obtained by adding a second water to quicklime, lime paste obtained by adding a third water to pre-hydrated lime, lime paste obtained by adding pre-hydrated lime to a third water and their mixture, and b) forming a very fine slaked lime milk with said lime compound by adding a fourth water to said lime compound or by adding the first lime compound to a fourth water. This process is described in the unpublished international patent application No. PCT / EP2015 / 060114 and PCT / EP2015 / 070367. According to this unpublished patent application, by adding water to a lime compound instead of adding a lime compound to water, it was possible to obtain a milk of lime of great finesse and controlled viscosity. Lime is a compound based on calcium and magnesium which will be referred to below as a compound based on calcium. Calcium-based compounds, such as CaO and Ca (OH) 2, have many practical uses. For example, these substances are BE2017 / 5138 used in the treatment of drinking water, waste water and sewage, in the treatment of flue gases as well as neutralizing agents and soil nutrients, for soil stabilization in construction, in the mining and metals industry as well as components of building materials. Calcium oxide CaO is often referred to as "quicklime", while calcium hydroxide Ca (OH) 2 is referred to as "hydrated lime", both of which are sometimes informally referred to as "lime". In other words, lime is an industrial product based on calcium oxide or hydroxide, respectively. Quicklime is usually in the form of fragments or granules, but it can also be a powder. Dry hydrated lime is usually a powder. According to current industrial practices, to further treat these compounds and improve the ease with which they are handled, dry CaO or dry Ca (OH) 2 can be mixed with water to form an aqueous suspension. that is to say a suspension also known as milk of lime, which is a fluid suspension of slaked lime, also called hydrated lime (calcium hydroxide-Ca (OH) 2 ), which can obviously include impurities, in particular silica, alumina, unburnt limestone (CaCOs), magnesium oxide or magnesium hydroxide at a rate of a few percent. Such a suspension is obtained by quenching quicklime (calcium oxide-CaO) with a large excess of water or by mixing hydrated lime with water. The aqueous suspensions obtained are characterized by the concentration of the mass of the solid material (% of solids), the chemical reactivity of the suspension to neutralize an acid and the size distribution of the particles in suspension (partly controlling the viscosity). These characteristics determine the properties of the suspension, mainly its viscosity and its reactivity. BE2017 / 5138 When milk of lime is obtained from hydrated lime, particles of hydrated lime are suspended in water. Hydrated lime is produced by common atmospheric hydrators which may or may not have size classification systems, where quicklime is added to water in a premixer in a specific mass ratio and allowed to mix together with said water in what is called an aging chamber. The temperature in the hydrator is below 100 ° C (212 ° F). The distribution of particle sizes will vary depending on the nature of the starting material of the quicklime used as well as the particular manufacturing process used (presence of a size classification system or not, sieving or grinding system). Lime milk made from hydrated lime will have a particle size distribution similar to that of the hydrated form that is produced and the solids content can commonly vary from 5 to 40% by weight. Lime milk made from quicklime in a continuous industrial process is typically produced by common dough, by retention or by ball mill extinguishers (Boyton, 1980). In all cases, quicklime is added to an excess amount of water and mixed with it to produce a suspension having a solids content ranging from 5 to 30% by weight. Water reacts with quicklime particles during the quenching operation via an exothermic reaction to form slaked lime. When quicklime is quenched with excess water, the hydration temperature is below 100 ° C (212 ° F). The size distribution of milk of lime is a function of both the nature of the quicklime and the coarse fraction removal systems that include sieving, sedimentation and grinding. Lime suspensions can be produced in batches or in a continuous process. BE2017 / 5138 An example of lime suspensions carried out in batches is disclosed in document US2004 / 0175324. According to this document, the quality of the milk of lime produced by batches is no longer different from one batch to another batch, because a temperature regulation system is applied. When the temperature increases, water is further added to cool the reaction medium and, when the temperature is too low, quicklime is also added as a means of extinction in exothermic reaction. This document says nothing about the real properties of the milk of lime thus produced. There is no information regarding particle size, reactivity, viscosity and similar characterization properties. No additives used during the extinction are mentioned. According to this document (refer to paragraph 0014), after each batch discharge, water is added to the reaction tank initially and lime is added thereafter. It is only after this initial step that temperature regulation occurs. Another example of manufacturing lime milk in batches is disclosed in document US Pat. No. 3,511,600. According to this document, water or a lime milk is confined in a reaction tank, forming an aqueous medium. to which lime (partially hydrated quicklime) is added. After this addition of lime in an aqueous medium, the temperature is adjusted. The particle size of the milk of lime is 8 μm after removal of the gravel. Numerous other attempts have been made to obtain very fine lime milk where manipulation of the final suspension is possible. Document US Pat. No. 5,275,650 discloses milk of lime produced with the addition of dispersant polymers during the grinding in an aqueous medium of milk of lime (already prepared). Example 1 relates to the lime milk of the state of the art with a grinding agent added at a rate of 1 to 2% by weight of dry / dry solid content. The average diameter BE2017 / 5138 after grinding is more or less between 2 and 5 pm. Example 2 relates to the invention of document US Pat. No. 5,275,650. The dispersing polymer of a specific nature is added to whitewash to grind the particles and the size reached is between 2 and 3 μm when the weight molecular weight of the polymer is less than 1,900. Document W002 / 092701 discloses a suspension of lime produced by the addition of lime to water, where the water comprises two additives. The first additive being an active polymer, typically an anionic polymer, such as a polymer of acrylic acid and sodium to an extent between 0.1 and 5, preferably between 0.1 and 3% by weight, and the Examples disclose an addition of 0.5 or 0.75% by weight of active polymer. The second additive is a base, preferably sodium hydroxide in an amount of between 0.1 and 5, preferably between 0.1 and 3% by weight, and the examples disclose an addition of 0, 5 or 0.75% by weight of sodium hydroxide to obtain a lime suspension with a particle size between 0.5 and 20 μm, preferably between 0.5 and 10 μm, with an acceptable viscosity of less than 2000 cP (mPa.s). Document WO 2014/064234 in the name of the present Applicant relates to an improvement in terms of stability of the viscosity of the milk of lime. To this end, an additive based on a phosphonate or a phosphonic acid is added in an amount equal to or less than 5% by weight, preferably equal to or less than 3% by weight, better still equal to or less than 2% by weight, more particularly equal to or less than 1.5% by weight of active acid relative to the total weight of the solid content. By this addition, the average particle size reached in milk of lime is between 1 and 20 μm and the viscosity is low and remains low over time (less than 1,500 mPa.s). Lime is added to an aqueous phase and phosphonate or phosphonic acid can be added BE2017 / 5138 in the aqueous phase before, during or after the formation of the lime suspension. Document FR No. 2,995,301 discloses a lime milk of great finesse having a monomodal distribution profile and for which the dgo-d 1o notation is less than or equal to 15 μm. As can be seen in the example, quicklime is added to water in a hydrator, the water possibly being process water, which means in the context of document FR 2 995 301 water having a temperature of 40 ° C., that is to say clean water, from which heat can be recovered to improve the distribution of the particle sizes of the milk of lime. No additive is mentioned in the document and great finesse is achieved by at least one classification step in order to produce a highly reactive lime milk. It is generally economically advantageous to be able to increase the solids content of the lime milk in order to reduce the transport costs and the dimensions of the equipment (storage tanks, pumps, etc.). The economics of transporting lime milk with a solids content of 5 to 30% by weight is poor, as it requires large storage tanks, large pumps and a lot of equipment. This takes into account the fact that most of the lime milk extinguishers are found where the lime milk is used. Field extinguishing equipment and methods are notably disclosed in US Patent No. 5,507,572. Quick lime is added to water in a batch tank which is equipped with horizontal paddles for mixing. The lime milks obtained have a particle size distribution, with a dso value, of about 10 to 20 µm. Gypsum can be added to increase the particle size to reduce the initial viscosity of the lime milk. The solids content obtained is generally in the range of 30 to 40% by weight. BE2017 / 5138 However, extinguishing on site is not really feasible everywhere and can become very expensive when the availability of sufficiently clean water is difficult. In fact, the quality of the water has proven in recent years to be a critical element in order not to disturb the extinguishing operation and to be able to adjust the particle size and the viscosity, which are made relatively closely related to each other. By the term viscosity is meant in the present application the dynamic or absolute viscosity measured in centipoises (cP) or in millipascals per second (mPa.s). One centipoise is equal to one millipascalsecond (mPa.s) in the international system of units. With regard to lime milk applications, experience has shown that it is desirable not to exceed a viscosity of approximately 1,500 mPa.s, in certain industrial applications, not to preferably exceed about 400 mPa.s. The viscosity is controlled by both the solids content and the particle size. The higher the solids content, the more viscous the aqueous suspension. Furthermore, an aqueous suspension with the same solids content but with a different particle size distribution will have a different viscosity value. The finer the particle size, the higher the viscosity. The particle size of the milk of lime is an important characteristic considering in particular its relative neutralization and / or its kinetics of precipitation. This is called the reactivity of a milk of lime which can in particular be measured by a measurement of the conductivity of a solution produced by diluting a small quantity of said milk of lime in a large volume of demineralized water. This technique is disclosed in the European standard EN 12485. It is known that the rate of dissolution of lime particles in demineralized water is faster when the particle size is smaller. In other words, the reactivity of BE2017 / 5138 lime is usually higher when its constituent particles are smaller. The particle size of the milk of lime is also an important characteristic when considering the rate of deposition or the rate of sedimentation of the solid phase of the suspension. The coarser the particles, the faster the lime milk will settle and the faster it will settle, the more it will probably require intermittent or continuous mixing to maintain a consistent solid content. Deposition or sedimentation can also generate dense sediment which will not be easily suspended even with vigorous stirring. Fine lime milk with a high solids content, a relatively low viscosity and a high reactivity is particularly preferred in certain industrial applications. In addition, several attempts have been made to produce lime milks with unclean water, such as industrial water, as extinguishing water. However, these attempts have led to coarse lime milks or to complex and costly necessary processes for obtaining lime milks having a sufficiently fine particle size. Even in these cases, the lime milks obtained are generally too viscous and / or contain a high amount of organic compounds, the latter being undesirable for certain applications. Unfortunately, all of the existing solutions for producing fine lime milk from quicklime have drawbacks such as, without being limited, a restriction on the type of quicklime that can be used and the availability of qualitative clean water for set the shutdown operation. Consequently, at present, there is still a need for a reliable and easy mode for producing a very fine lime milk while avoiding the abovementioned drawbacks of the state of the art, in particular a restrictive dependence on the material properties of BE2017 / 5138 departure and availability of clean fire water or the costs of using clean fire water. To solve this problem, the present invention relates to a method for manufacturing a milk of lime of great fineness as mentioned in the preamble, characterized in that at least one of the first, of the second, of the third or fourth water is a treatment water chosen from the group consisting of alkaline water, saline water, sulphated water comprising 3 to 300 g of solute / dm 3 , preferably at least 5.5, preferably at least 7, preferably at least 10, more preferably at least 15, more particularly at least 20, very clearly 30 g of solute / dm 3 and preferably at most 250 g / dm 3 , more preferably at most 200 g / dm 3 , much better still at least 175 g / dm 3 , much better still less than 150 g / dm 3 and in that at least one of the first, second, third or fourth water is added to said lime compound , i.e. using a specific manufacturing process in which the water used for the the quenching operation is a process water which is added to the lime compound, said very fine lime milk having slaked lime particles having a dso greater than or equal to 1 μm and less than or equal to 6 μm, measured by laser diffraction using methanol as a carrier solvent after sieving the whitewash 2 mm through a sieve to remove the gravel and, if necessary, after applying an ultrasonic treatment. It has surprisingly been found according to the present invention that by adding water to a lime compound to produce a milk of lime, the purity of the water was not a restriction and could even promote the obtaining of '' a low viscosity lime milk with a small particle size and a high solids content. It has in fact proved possible according to the present invention to use process water such as: BE2017 / 5138 a) alkaline water, such as drainage water from alumina refinery processes, a white or green liquor from the production of paper pulp or solutions from caustification processes - these solutions commonly a pH ranging from 13 to 15 and generally comprising between 5 and 300 g / dm 3 of alkaline inorganic compounds relative to the volume of alkaline water; preferably at least 7, preferably at least 10, more preferably at least 15, more particularly at least 20, much more preferably 30 g of solute / dm 3 and, preferably at most 250 g / dm 3 , more preferably at most 200 g / dm 3 , much better still at least 175 g / dm 3 , much better still less than 150 g / dm 3 , b) saline water, such as sea water, brackish water or hypersaline water such as chloride brines, nanofiltration retentates or ultrafiltration of membrane desalination processes or desalination concentrates by evaporation such as multi-effect evaporation or flash (multi-stage evaporation) - these solutions may have concentrations of dissolved salts - frequently, but not exclusively, chloride salts (i.e., for example , magnesium, potassium or sodium chloride) - in the range of 3 to 300 g / dm 3 of saline compound relative to the volume of saline water; preferably at least 5.5, preferably at least 7, preferably at least 10, more preferably at least 15, more particularly at least 20, more preferably 30 g of solute / dm 3 and preferably at most 250 g / dm 3 , even better at most 200 g / dm 3 , much better still at most 175 g / dm 3 , much better still less than 150 g / dm 3 . c) waters containing sulphates, such as sulphate brines, of leaching solutions in the treatment of hydrometallurgical ores, such as, for example, the leaching of nickel, copper or cobalt ores, or any other solutions of processes, BE2017 / 5138 industrial effluents containing sulphates as well as effluents containing sulphates treated with lime, i.e. saturated solutions of gypsum - these solutions can typically contain inorganic sulphate or sulphite compounds of a concentration ranging from 1 to 100 g / dm 3 expressed in the form of SO3 relative to the volume of water containing the sulfates; preferably at least 3, preferably at least 5.5, preferably at least 7, preferably at least 10, more preferably at least 15, more particularly at least 20, more preferably 30 g of solute / dm 3 and preferably maximum 90 g / dm 3 , better still maximum 85 g / dm 3 , much better still maximum 75 g / dm 3 , significantly better still less than 65 g / dm 3 , to achieve a very fine lime milk with high reactivity and meeting the standards for the use of this lime milk. To dispel the doubt, the process water is used here unlike clean water and typically comprises between 3 and 300 g of solute / dm 3 . In the sense of the present invention, the addition of process water allows the addition of a solute content relative to the solids content of the lime milk with a mass ratio of between 0.15 and 15, of preferably greater than 0.20, more preferably greater than 0.30, and preferably less than 10, more preferably less than 5. This is even more surprising when we know that, typically, the presence of sulphates in water leads to a large magnification of lime milk in conventional extinction. The same is observed to a lesser degree also for highly saline water (especially seawater and brackish water). The present invention therefore opens up new perspectives for an on-site extinction process, even if it is not limited, when clean water is scarce and / or expensive, while the treatment rinse water, l 'water BE2017 / 5138 from process leakage, drainage water is more abundant and cheaper since it is in any case very often stored in a sedimentation lake and further treated as wastewater. In addition, according to the present invention, it has also been observed that the low viscosity of the milk of lime of great fineness is stable over time. The slaked lime milk obtained according to the invention therefore has a high reactivity due to its great fineness and which is not necessarily linked to the reactivity of the quicklime initially used, but also does not depend on the quality of the lime. water used in the extinguishing process. As can be understood in the light of what is mentioned above, the process for producing very fine lime milk according to the present invention is particularly useful insofar as a very fine slaked lime milk is easily obtained at competitive costs, as it does not require high quality water or require highly reactive quicklime or complex equipment. The milk of lime of great fineness according to the present invention was advantageously obtained by providing a specific selection of a lime compound chosen from the group consisting of a lime compound chosen from the group of quicklime, from a first compound of lime and their mixture, said first lime compound being chosen from the group consisting of pre-hydrated lime obtained by addition of a first water to quicklime, of lime paste obtained by addition of a second water quicklime, lime paste obtained by adding a third water to pre-hydrated lime, lime paste obtained by adding pre-hydrated lime to a third water and their mixture at a stage of formation of a very fine slaked lime milk by a subsequent quenching step or a subsequent dilution step. BE2017 / 5138 Pre-hydrated lime is made up of particles which consist of a quicklime (CaO) core and a hydrated lime (Ca (OH) 2) coating which forms a temporarily regular layer covering the CaO core. In a preferred embodiment, said pre-hydrated lime comprises a quick lime content of between 40 and 96% by weight relative to said total weight of said pre-hydrated lime and a hydrated lime content of between 60 and 4% by weight. weight relative to said total weight of said pre-hydrated lime. In a preferred embodiment of the method according to the present invention, said at least one of the first, second or fourth water is added to quicklime by progressive addition of said at least one of the first, of the second or fourth water to quicklime with stirring. By progressive addition of water is meant that the addition of water is distributed over time in the case of a discontinuous process or distributed in space for a continuous process. In some embodiments, the distribution is regular, but, within the framework of the optimization of the process, some addition can be done more quickly for non-critical phases of the process. In general terms, this means that the addition of water is distributed over the conversion of the lime compound. In the specific case of the discontinuous process, this can be understood as an amount of water added to an amount of lime compound over a certain period of time and this can be expressed in g of water per kg of lime compound per minute. In the specific case of the continuous process, it can be understood as a distributed flow of water added gradually over a stream of lime compound introduced at the entry of the process during a certain residence time and this can be expressed in g / min of water per kg / min of lime per minute of residence time. Finally, in both cases, this corresponds to g / kg / min. Typically, this report determines the addition scheme and its BE2017 / 5138 value is between 30 and 300 g of water per kg of quicklime per minute, which corresponds, for example, for a milk of lime with 45% solids content to a residence time of approximately 2 to 20 minutes. When the addition of said at least one of the first, second or fourth water added to quicklime is done gradually with stirring, this comes down to the fact that during the gradual addition of the first, the second or even the fourth quicklime water, a first intermediate compound is formed which is pre-hydrated lime. In a first embodiment, quicklime progressively hydrated by the first or fourth forming the pre-hydrated lime is further hydrated by the fourth water which is also gradually added. The pre-hydrated lime then gradually disappears following the gradual addition of the fourth water. This gradual addition of water makes it possible to reach a high temperature during the hydration stage by forming very small particles. In a second embodiment, quicklime progressively hydrated by the first or fourth water by forming the pre-hydrated lime is also hydrated by the fourth water to which said pre-hydrated lime is added, gradually or not. This gradual addition of the first or fourth water made it possible to reach a high temperature during the pre-hydration stage by forming very small particles. In a third embodiment, quicklime progressively hydrated by the first or fourth water by forming the pre-hydrated lime is stored before another hydration. This can be storage on site or remotely before shipment to site where another hydration by the fourth water will be made, gradually or not, or by addition of the fourth water to pre-hydrated lime or by addition of pre-hydrated lime. hydrated with fourth water. This gradual addition of the BE2017 / 5138 first or fourth water made it possible to reach a high temperature during the pre-hydration stage by forming very small particles. In another preferred embodiment, said third water or said fourth water is added to the pre-hydrated lime by progressive addition of said third or said fourth water to the prehydrated lime with stirring. According to this other embodiment, said third water added to the pre-hydrated lime can be added to commercial pre-hydrated lime or to pre-hydrated lime formed by progressive addition of the first water to quicklime . In the case where the third water is gradually added to pre-hydrated lime to form a lime paste, the fourth additional water added to the lime paste can be added gradually or not to the lime paste. In a variant where the third water is gradually added to pre-hydrated lime to form a lime paste, the lime paste is also added to the fourth water. In another preferred embodiment, said fourth water is added to the lime paste by progressive addition of said fourth water to the lime paste with stirring. In a first particular embodiment of the method according to the present invention, said progressive addition of said at least one of the first, of the second, of the third or of the fourth water to said lime compound presents a diagram of addition of said one of the first, second, third or fourth water to control the absorption of water by the lime compound in a batch process or in a continuous process. By the expression diagram of addition of water, it is understood according to the present invention that the addition of water must be adjusted relative, by BE2017 / 5138 example, at its flow rate, the duration of the addition of water or even the distance along which water is added to the lime if the pre-hydrated lime, the lime paste or the milk of lime is produced in continuous mode. If the step of forming pre-hydrated lime, lime paste or milk of lime concerned by the present invention is a discontinuous process, the key factor will be the amount of water absorbed by a predetermined amount of lime, optionally containing additives and / or the dispersion of water on or in quicklime or prehydrated lime in the batch process and / or the stirring parameters. Said progressive addition of said at least one of the first, second, third or fourth water to said lime compound having an addition scheme for regulating the absorption of water by the lime compound may, depending on the present invention to be said at least one of the first, second or fourth water added to quicklime, said third water or said fourth water added to pre-hydrated lime, the fourth water added to paste of lime. In a second particular embodiment of the method according to the present invention, said gradual addition of said at least one of the first, second, third or fourth water is a continuous process during which the gradual hydration of said lime compound is carried out by adjusting the flow rate of lime compound in a hydrator, in which a predetermined atmosphere is created / supplied containing a limited amount of said at least one of the first, second, third or fourth water for addition of said one of the first, second, third or fourth water to said lime compound. In fact, if the stage of formation of pre-hydrated lime, lime paste or milk of lime is a continuous process, quicklime is transported in a hydrator or a hydrator type tank and therefore has BE2017 / 5138 a residence time. To regulate the absorption of water by quicklime, one can act on the water flow taking into account the speed of introduction of lime during transport in the hydrator or in the hydrator type tank, the size of at least the water droplets and / or the distance along which the water is added. Said progressive addition of said at least one of the first, third or fourth water to said lime compound being a continuous process during which the progressive hydration of said lime compound is carried out by adjusting the feed rate of the compound of lime in the hydrator supplied by the predetermined atmosphere of a limited quantity of said at least one of the first, second, third or fourth water can be made according to the present invention, said at at least one of the first, second or fourth water being added to quicklime, said third water or said fourth water being added to pre-hydrated lime, or said fourth water being added to slurry lime. In a third particular embodiment of the process according to the present invention, said progressive addition of said at least one of the first, second, third or fourth water is a discontinuous process during which the progressive hydration of said lime compound is carried out by placing a predetermined amount of lime compound in a hydrator, in which a predetermined atmosphere is created / provided containing a limited amount of said at least one of the first, second, third or the fourth water for adding said at least one of the first, second, third or fourth to said lime compound. In a fourth particular embodiment of the process according to the present invention, said progressive addition of said at least one of the first, second, third or fourth water is carried out by spraying a mist of said at BE2017 / 5138 minus one of the first, second, third or fourth water in a hydrator. Preferably, said mist of said at least one of the first, second, third or fourth water has a controlled size of droplets of addition of said at least one of the first, second, third or fourth water. The size of the water droplets also makes it possible to control the hydration reaction to form the pre-hydrated lime, the lime paste or even the lime milk and, consequently, the quality of the lime compound obtained supplied to the l 'stage in the process of formation of very fine slaked lime milk. In fact, the size of the water droplets can reveal a significant impact, because they must be large enough not to evaporate before reaching quicklime and allow the hydration reaction to take place. , but at the same time not be too large to avoid a non-homogeneous local hydration of the particles which would undesirably lead to a non-homogeneous lime compound. Said progressive addition of said at least one of the first, second, third or fourth water to said lime compound carried out by spraying a mist of said at least one of the first, of the second, of the third or fourth water in a hydrator may be according to the present invention said at least one of the first, second or fourth water added to quicklime, said third water or said fourth water added to pre lime -hydrated, said fourth water added to lime paste. In a particular embodiment of the process according to the present invention, said lime compound is quicklime onto which a said fourth water which is process water is gradually added until said milk of large lime finesse be obtained. BE2017 / 5138 In another particular embodiment according to the present invention, said first lime compound is chosen from the group consisting of pre-hydrated lime, lime paste or their mixture obtained from quicklime on which a first water or a second water which is process water is gradually added to form said first lime compound. Advantageously, said very fine lime milk is obtained by another addition of a fourth water which is an aqueous phase chosen from the group of clean water, process water, clean water with additives , process water with additives and their mixture with said first lime compound. In a variant of the process according to the present invention, said very fine lime milk is obtained by addition addition of said first lime compound to a fourth water which is an aqueous phase chosen from the group of clean water, a process water, clean water with additives, process water with additives and their mixture. In another particular embodiment according to the present invention, said first lime compound is a lime paste obtained from pre-hydrated lime on which said third water which is process water is added gradually. Advantageously, said very fine lime milk is obtained by another addition of a fourth water which is an aqueous phase chosen from the group of clean water, process water, clean water with additives , process water with additives and their mixture with said first lime compound. As a variant, said very fine lime milk is obtained by another addition of said first lime compound to a fourth water which is an aqueous phase chosen from the group of clean water, of a BE2017 / 5138 process water, clean water with additives, process water with additives and their mixture. In yet another particular embodiment, said third and said fourth water are one and the same water and wherein said first lime compound is pre-hydrated lime on which said third water, which is said fourth water and l the process water is added gradually until said milk of lime is obtained. In a particularly advantageous embodiment of the process according to the present invention, the process comprises the addition of at least one additive, said additive being added or confined in said at least one of the first, second, third and the fourth water or added or confined in said lime compound. The additive may be a solid additive, a liquid additive, for example, but not limited to, a suspension of said additive or a solution of said additive. Preferably, said additive is chosen from the group consisting of carbohydrates, sugars, alcohol sugars, in particular sorbitol, carbon dioxide, phosphates, sulfates, bicarbonates, silicates, phosphonates , polyacrylates, polycarboxylic acids, low molecular weight organic acids, their mixtures and their derivatives. More preferably, said at least one of the first, second, third and fourth water which is process water is an aqueous phase selected from the group consisting of water comprising an endogenous salt, an industrial alkaline aqueous phase, an industrial water with a high sulphate content, saturated gypsum solutions, sea water, saline water and hypersaline water, brackish water and their mixtures, recycled or not. In particular, the process water according to the present invention can be recycled water comprising an endogenous salt, a recycled industrial alkaline aqueous phase, industrial water with a high content of BE2017 / 5138 recycled sulfate, recycled saturated gypsum solutions, recycled seawater, recycled saline and recycled hypersaline water, recycled brackish water and their mixture. In yet another preferred embodiment of the process according to the present invention, said process water comprises at least 1 g / dm 3 , in particular at least 5 g / dm 3 , preferably at least 10 g / dm 3 , more preferably at least 20 g / dm 3 , in particular at least 40 g / dm 3 of mineral salt comprising a mineral sulphate or a sodium salt and their mixture. In a specific embodiment of the process according to the present invention, the proportion of process water to the total amount of water used is greater than 40% by weight, preferably greater than 60% by weight, better still greater than 80 % by weight and up to 100% by weight. In another specific embodiment of the process according to the present invention, the process further comprises a sieving or selection step to remove coarse particles greater than 1 mm, preferably greater than 500 μm, better still 200 μm, from the milk. very fine lime. Preferably, the sieving or selection step is carried out by a stainless steel sieve. Other embodiments of the process according to the present invention are mentioned in the appended claims. The present invention also relates to a very fine slaked lime milk comprising slaked lime particles suspended in an aqueous phase, in which the slaked lime particles have a dso greater than or equal to 1.5 μm and less than or equal to 5 pm, more preferably less than or equal to 4 pm, much more preferably less than or equal to 3 pm, and in which said milk of lime or said aqueous phase additionally contains a mineral salt comprising a mineral sulfate or BE2017 / 5138 a sodium salt and their mixture, at a level of at least 1 g / dm 3 , in particular at least 5 g / dm 3 , preferably at least 10 g / dm 3 , better still at least 20 g / dm 3 , in particular at least 40 g / dm 3 . The notation d x represents a diameter expressed in pm with respect to which X% of the particles or grains measured are smaller. The milk of slaked lime of great fineness according to the present invention is therefore a milk of lime, in which not only dso is reduced compared to conventional lime milk of great fineness, but also the presence of agglomerates of coarse fraction is reduced. Advantageously, in the milk of slaked lime according to the present invention, said aqueous phase comprises an additive chosen from the group consisting of carbohydrates, sugars, sugars of alcohols, in particular sorbitol, carbon dioxide, phosphates , sulfates, bicarbonates, silicates, phosphonates, polyacrylates, polyacrylic acids, low molecular weight organic acids, their mixtures and their derivatives. In a preferred embodiment according to the present invention, the slaked lime milk has a solids content greater than 20% by weight, preferably greater than 30% by weight, better still greater than 35% by weight, much better still greater at 40% by weight, relative to the total weight of the milk of lime, said solids content being less than or equal to 55% by weight, preferably less than or equal to 50% by weight, in particular less than or equal to 45% by weight weight in relation to said total weight of slaked lime milk. In a preferred embodiment according to the present invention, stabilizing additives, a viscosity reducer, a viscosity stabilizer can be added to adjust the viscosity of the slaked lime milk. Preferably, the slaked lime milk according to the present invention has a viscosity measured with a DV-3B rheometer from Brookfield. BE2017 / 5138 using the predetermined spindle (as mentioned below) at a rotation speed of 100 rpm, less than 1,500mPa.s, preferably less than 1,200 mPa.s, in particular less than 1,000 mPa. s, more particularly less than 900 mPa.s, more particularly less than 800 mPa.s, still less than 600 mPa.s, very particularly less than 450 mPa.s, much better still less than 300 mPa.s. Refer to the table below for the predetermined spindle for the respective viscosity range at a rotational speed of 100 rpm: Brooch Min viscosity Max viscosity 61 or LV-1 60 mPa.s 62 or LV-2 60 mPa.s 300 mPa.s 63 or LV-3 300 mPa.s 1200 mPa.s 64 or LV-4 1200 mPa.s 6000 mPa.s In the context of the present invention, the term viscosity has been used to denote a dynamic or absolute viscosity. Dynamic viscosity or absolute viscosity denotes the viscosity which is measured in centipoise (cP) or in units of millipascals-second (mPa.s). In a particularly advantageous embodiment according to the present invention, the milk of slaked lime of great fineness has a deposition rate of between approximately 1 and 2% by volume after 24 hours as measured according to standard ASTM C110-11.14. In another preferred embodiment according to the present invention, said aqueous phase of the milk of lime comprises less than 2 g / dm 3 of total organic carbon, preferably less than 1.2 g / dm 3 , better still less than 0, 8 g / dm 3 of total organic carbon. Other embodiments of the slaked lime milk according to the present invention are mentioned in the appended claims. BE2017 / 5138 The present invention also relates to the use of process water for the manufacture of a milk of lime of great finesse in a hydration process with a fourth water of a lime compound chosen from the group of quicklime, a first lime compound and their mixture, said first lime compound being chosen from the group consisting of pre-hydrated lime obtained by addition of a first water to quicklime, of a lime paste obtained by adding a second water to quicklime, a lime paste obtained by adding a third water to pre-hydrated lime, a lime paste obtained by adding pre-hydrated lime to a third water and their mixture, said process water being used as first, second, third or fourth water, said third and said fourth water being identical or different, to form a slaked lime milk of large fineness with said lime compound. Preferably, according to the use of the present invention, at least one additive is added, said additive being added or confined in said at least one of the first, second, third and fourth water or added or confined in said lime compound. More particularly, in the use according to the present invention, said additive is chosen from the group consisting of carbohydrates, sugars, alcohol sugars, in particular sorbitol, carbon dioxide, phosphates, sulfates, bicarbonates, silicates, phosphonates, polyacrylates, polycarboxylic acids, low molecular weight organic acids, their mixtures and their derivatives. In a preferred use according to the present invention, said at least one of the first, second, third and fourth water which is process water is an aqueous phase chosen from the group consisting of water comprising an endogenous salt, an industrial alkaline aqueous phase, industrial water with a high sulphate content, BE2017 / 5138 saturated gypsum solutions, seawater, saline and hypersaline water, brackish water and their mixture, recycled or not. In a particularly preferred use according to the present invention, said at least one of the first, second, third and fourth water which is process water comprises at least 1 g / dm 3 , preferably at at least 5 g / dm 3 , in particular at least 10 g / dm 3 , more particularly at least 20 g / dm 3 and better still at least 40 g / dm 3 of mineral salt comprising a mineral sulfate or a sodium salt and their mixture . Other embodiments of the use of process water to manufacture a milk of lime of great fineness according to the present invention are mentioned in the appended claims. The present invention also relates to a device for producing a milk of lime of great fineness comprising a hydration zone provided for comprising a lime compound chosen from the group of quicklime, a first lime compound and their mixture, said first lime compound being chosen from the group consisting of pre-hydrated lime obtained by adding a first water to quicklime, a lime paste obtained by adding a second water to quicklime , a lime paste obtained by adding a third water to pre-hydrated lime, a lime paste obtained by adding pre-hydrated lime to a third water and their mixture, said zone of hydration comprising an opening connected to a supply means supplied for conveying at least a first, a second, a third or a fourth water which is process water on said lime compound, said m feed means being in fluid communication with a means for storing process water, and a second opening connected to a collecting means provided for collecting a second lime compound chosen from the group consisting of pre-hydrated lime, of a lime paste and milk of lime, said means BE2017 / 5138 for supplying further comprising other spraying means or flow control means. Other embodiments of the device according to the present invention are mentioned in the appended claims. The present invention also relates to a factory for producing a milk of lime of great fineness comprising a device according to the present invention and a means of storage of process water containing means of outlet of process water connected to said means of powering said device. Other embodiments of the plant according to the present invention are mentioned in the appended claims. Other features, details and advantages of the present invention are explained in the following description given below with reference to the drawings and examples, without being limited thereto. The present invention relates to a process for the manufacture of a milk of lime of great fineness comprising at least the steps consisting in: a) providing a lime compound chosen from the group of quicklime, a first lime compound and their mixture, said first lime compound being chosen from the group consisting of pre-hydrated lime obtained by addition of a first water to quicklime, a lime paste obtained by adding a second water to quicklime, a lime paste obtained by adding a third water to pre-hydrated lime , a lime paste obtained by adding prehydrated lime to a third water and their mixture, and b) forming a very fine slaked lime milk with said lime compound by adding a fourth water to said lime compound or by adding the first lime compound to a fourth water, in which at least one of the first , second, third or fourth water is process water and in which at least BE2017 / 5138 one of the first, second, third or fourth water is added to said lime compound. Milk of slaked lime is a suspension of hydrated lime in water and can be formed from hydrated lime or quicklime; however, the preferred slaked lime milk used here is produced from pre-hydrated lime or lime paste obtained by adding water to lime instead of lime to water. The quicklime used for the purposes discussed here may be "high calcium" lime, which contains no more than about 5 percent magnesium oxide or hydroxide. According to the present invention, several embodiments are encompassed within the framework of the process for manufacturing a very fine lime milk. Most of them will be described below without any limiting effect. In a first preferred embodiment, an aqueous phase called fourth water which is process water is added to quicklime gradually until a milk of lime is produced. Successively, quicklime is partly hydrated by locally forming a pre-hydrated lime which gradually disappears during the addition of water to form a lime paste, which is then gradually diluted until a lime milk of great finesse. In a second preferred embodiment, an aqueous phase called first water is added to quicklime to form a pre-hydrated lime. The pre-hydrated lime is then further hydrated to form a lime milk. The other hydration may or may not pass through the stage in which a lime paste is formed to gradually disappear and form the milk of lime. The other hydration is done by adding the fourth water to the pre-hydrated lime or by adding the pre-hydrated lime to the fourth water. Lime milk of great finesse is BE2017 / 5138 obtained even if the first or fourth water or even the first and fourth water is process water. According to this second preferred embodiment, the prehydrated lime can be formed in a hydrator which can be on site or at a distance from the hydrator, in which the milk of lime is produced. It also means that the pre-hydrated lime can also be a commercially available pre-hydrated lime which is shipped to the site where the very fine lime milk is produced. In a third preferred embodiment, an aqueous phase called second water is added to quicklime to form a lime paste. The lime paste is then further hydrated to form a milk of lime. The other hydration is done by adding the fourth water to the lime paste and adding the lime paste to the fourth water. Lime milk of great finesse is obtained even if the second or fourth water or even the second or fourth water is a process water. According to this third preferred embodiment, the lime paste can be formed in a hydrator which can be on site or distant from the hydrator in which the milk of lime is produced. It also means that the lime paste can be a commercial lime paste that is shipped to the site where the very fine lime milk is produced. In a fourth preferred embodiment, an aqueous phase called third water is added to pre-hydrated lime to form a lime paste. The lime paste is then further hydrated to form a milk of lime. The other hydration is done by adding the fourth water to the lime paste or by adding the lime paste to the fourth water. Lime milk of great finesse is obtained even if the third or fourth water or even the third and fourth water constitutes a process water. BE2017 / 5138 According to this fourth preferred embodiment, the lime paste can be formed in a hydrator which can be on site or distant from the hydrator in which the milk of lime is produced. This also means that the lime paste can also be a paste. commercial lime which is shipped to the site to where the fine lime milk is produced. In a fifth embodiment, prehydrated lime is added to an aqueous phase called third water to form a lime paste. The lime paste is then further hydrated to form a milk of lime with the fourth water which is identical to or different from the third water. The other hydration is then carried out by adding the fourth water to the lime paste or can be carried out by adding the lime paste to the fourth water. This very fine lime milk is obtained even if the third or fourth water or even the third and fourth water constitutes process water. In some cases where the third water is clean water, the pre-hydrated lime has been obtained by adding process water to quicklime and the fourth water may be process water or l clean water, which fourth water can be added to the lime paste or, conversely, lime paste can be added to the fourth water. In a variant where the third water is clean water, the pre-hydrated lime was obtained by adding clean water to quicklime and the fourth water is process water, which fourth water can be added to the lime paste or, conversely, the lime paste can be added to the fourth water. In fact, if the milk of very fine slaked lime is formed from pre-hydrated lime, the particles of pre-hydrated lime are still slaked with a predetermined volume of third water to form the lime paste. The third water can be added to the pre-hydrated lime or, on the contrary, the pre-hydrated lime can be added to the third water. BE2017 / 5138 The other addition of the fourth water forms slaked lime milk. In the latter case, the volume of the fourth water can be added to the lime paste or, on the contrary, pre-hydrated lime can be added to the volume of water. Naturally, pre-hydrated lime is exclusively formed by adding water to quicklime and not the other way around. The third or fourth or even both the third and fourth water is process water. According to this fifth preferred embodiment, the lime paste can be formed in a hydrator which can be on site or distant from the hydrator in which the lime milk is produced. It also means that the lime paste can also be a commercial lime paste which is shipped to the site to where the very fine lime milk is produced. In a sixth embodiment, the third water and the fourth water are the same water and the pre-hydrated lime is added to the aqueous phase called the third water which is also the fourth water to form the milk of lime, continuously and gradually . The lime paste formed accordingly in situ gradually disappears during another hydration to form a milk of lime with the fourth water which is identical to the third water. In this case, the third and fourth water are both the same process water. The preferred slaked lime milk used here will contain about 20 to 55% by weight of solids, preferably about 40 to 50% by weight of solids and more preferably about 45% by weight of solids, based on the total weight of the slaked lime milk. The object of the invention is to produce slaked lime milk with a fine distribution of particle sizes. This property is obtained by the method according to the invention comprising a first step of supplying a lime compound chosen from the group of quicklime, a first lime compound and their mixture, said first compound BE2017 / 5138 of lime being chosen from the group consisting of pre-hydrated lime obtained by adding a first water to quicklime, a lime paste obtained by adding a second water to quicklime, a lime paste obtained by adding a third water to prehydrated lime, a lime paste obtained by adding pre-hydrated lime to a third water and their mixture. The first step is followed by a step of forming a milk of slaked lime of great finesse which, in its preferred form, has a distribution of particle sizes dso of between 2 and 5 μm or even between 2.5 and 3, 5 μm, having a slaked lime content of 20 to 55% by weight of solids, with said lime compound by the addition of a fourth water to said lime compound or by addition of the first lime compound to a fourth water, wherein at least one of the first, second, third or fourth water is process water and at least one of the first, second, third or fourth water is added to said lime compound. In the following discussion, the particle size distributions (also referred to as particle sizes) are measured using a laser particle size analyzer in methanol; these distributions are characterized, for example, in terms of dso, dgo and dgs which are interpolated values of the particle size distribution curves. The dimensions d 50 , dgo and dge correspond to the dimensions for which, respectively, 50%, 90% and 98% of the particles are less than a given value. The viscosity of these lime milks is measured according to standard industrial practice, in particular by the use of a "Brookfield DV III rheometer" viscometer, with the spindle predetermined at 100 rpm. In fact, in this method, the spindle must be adapted according to the viscosity range of the sample measured. For a rotation speed of 100 rpm, the predetermined spindle is spindle n ° 1 (or 61) for a sample BE2017 / 5138 having a viscosity up to 60 cP; spindle no. 2 (or 62) for a viscosity of around 60 to 300 cP; spindle no. 3 (or 63) for a viscosity of around 300 to 1,200 cP; and spindle no. 4 (or 64) for a viscosity of around 1,200 up to 6,000 cP. The measurement is carried out at the 30 th second, once the viscometer engine has started. The present invention will be described more precisely with the example of a lime compound as the starting material which is quicklime. However, the milk of slaked lime of great fineness according to the present invention can be obtained from a lime compound chosen from the group of quicklime, a first lime compound and their mixture, said first compound lime being chosen from the group consisting of pre-hydrated lime obtained by adding a first water to quicklime, a lime paste obtained by adding a second water to quicklime, a paste lime obtained by adding a third water to pre-hydrated lime, a lime paste obtained by adding pre-hydrated lime to a third water and their mixture. In fact, it has been discovered that the selection of a specific lime compound selected from the group consisting of a lime compound selected from the group of quicklime, a first lime compound and their mixture, said first lime compound being chosen from the group consisting of pre-hydrated lime obtained by adding a first water to quicklime, a lime paste obtained by adding a second water to quicklime, d '' a lime paste obtained by adding a third water to pre-hydrated lime, a lime paste obtained by adding pre-hydrated lime to a third water and their mixture obtained by adding at least one of said first, second, third and fourth water to the lime compound instead of adding said lime compound to water shared the concept that very fine slaked lime milk is obtained due to the intermediate existence in upstream or during the process according to the present invention BE2017 / 5138 of pre-hydrated lime compounds, which intermediate product gradually disappears more or less along with the addition of water until the lime paste or lime milk is formed. According to the present invention, said progressive addition of said at least one of said first, second, third and / or fourth water is a step of spraying said at least one of said first, second, third and / or fourth water to adjust the absorption. of water by the lime compound, or a continuous scheme of adding said at least one of said first, second, third and / or fourth water to regulate the absorption of water by the lime compound, with stirring. This means that the volume of said at least one of said first, second, third and / or fourth water added to the lime compound required to completely quench the lime cannot be added all at once, but gradually, to ensure the intermediate existence of prehydrated lime. In a preferred embodiment according to the present invention, the process water, but also any other water added in the process according to the present invention, can comprise one or more additives, for example, chosen from the group consisting of carbohydrates , sugars, alcohol sugars, in particular sorbitol, carbon dioxide, phosphates, sulfates, bicarbonates, silicates, phosphonates, polyacrylates, polycarboxylic acids, low-weight organic acids molecular, their mixtures and their derivatives. The process water is an aqueous phase chosen from the group consisting of water comprising an endogenous salt, an industrial alkaline aqueous phase, industrial water with a high sulphate content, saturated gypsum solutions, water sea water, saline water and hypersaline water, brackish water and their mixture, recycled or not, and can be, for example, recycled water comprising an endogenous salt, a BE2017 / 5138 recycled aqueous alkaline phase, an industrial phase of water with high recycled sulphate content, recycled saturated gypsum solutions, recycled sea water, saline water and recycled hypersaline water, recycled brackish water and their mixture. In yet another variant, the process water comprises at least 1 g / dm 3 , preferably at least 5 g / dm 3 , in particular at least 10 g / dm 3 , more particularly at least 20 g / dm 3 and, better still, at least 40 g / dm 3 of mineral salt comprising a mineral sulfate or a sodium salt and their mixture. EXAMPLES In the examples below, the lime used is a lime from the Tapah factory, which is typically quicklime which produces under normal quenching conditions the addition of quicklime to water. relatively high viscosity lime. EXAMPLE 1 100 g of finely ground quicklime as a lime compound with a size greater than 2 mm were placed in a horizontally stirred 20 dm 3 laboratory paste mixer of the Lödige M-20 MK type. This mixer provides agitation by two plowshares and two wall scrapers, which have been fixed to the axis of the agitator and makes it possible to mix products in powder, paste and suspension. The lid at the top of the mixer was fitted with a water metering system, i.e. a water pipe ending in a nozzle and a thermally and chemically resistant filter, which allowed any vapor formed from escaping from the mixer into an external ventilation system. Industrial process water (fourth water) was supplied with a flow rate of 3.0 g / s to the reactor and therefore sprayed through the nozzle on the lime. A total of 4.2 kg of this process water was added over a period of approximately 25 min. BE2017 / 5138 The industrial process water contained approximately 2 g / dm 3 of sodium hydroxide, 11 g / dm 3 of sodium carbonate, approximately 7 g / dm 3 of sodium aluminate, approximately 2 g / dm 3 of sodium sulfate sodium, about 0.5 g / dm 3 of sodium chloride and 5 to 15 g / dm 3 of organic impurities, which were derived from humates. In addition, about 10 g of sorbitol was added to the water. At the end of the dosing, the mixture is left to stir in the mixer until it cools to below 50 ° C. Then it is removed from the mixer, sieved to 2 mm through a sieve and analyzed for its solids content, viscosity and particle size distribution. The particle size distribution is measured with a Beckman-Coulter LS 13 320 laser diffraction particle calibrator with an internal sonication cell in the recirculation circuit of the methanolic sample suspension. Sonication is applied in this cell for 30 s at the rate of 50% of the maximum intensity before two measurement tests on the same sample. The results of these two tests are checked and compared and, if the two results of particle size distribution agree with a good level of confidence (based on the common standard deviation for this type of measurement with the equipment), the mean of the two tests is taken as the final result of the particle size distribution. Otherwise, the measurement is repeated on the same sample, but without a second sonication. This experiment is repeated under the same conditions a second time. The solid content was determined by a residual weight after drying in an infrared thermobalance at 110 ° C. The viscosity was measured with a Brookfield DV-3B rheometer using the predetermined spindle at a rotational speed of 100 rpm. BE2017 / 5138 The particle size distribution was measured with a Beckman-Coulter LS 13 320 laser diffraction particle calibrator using methanol as the carrier solvent. The results are shown in Table 1. Table 1 Test Viscosity[cPs] Contentsolids [%in weight] dso[m] d90[m] dg7[m] 1 230 45.0 2.29 21.2 40.8 2 190 45.0 2.37 11.7 33.6 The suspensions were then diluted by adding demineralized water to the milk of lime to a solids content of 23.0% by weight for an easier comparison of the viscosity with the comparative examples. The viscosity and solid content results are shown in Table 2. BE2017 / 5138 Table 2 Test Viscosity[cPs] Solid content[% in weight] 1 22 23.0 2 18 23.0 COMPARATIVE EXAMPLE 1 The same experimental conditions as those of Example 1 were used, in particular the quantity of quicklime, the quantity of quenching water and sorbitol. Likewise, the same finely ground quicklime was used. But instead of the process water, demineralized water was used. The results are shown in Table 3. Table 3 Test Viscosity[cPs] Contentsolids [%in weight] dso[m] dgo[m] dg7[m] 3 240 39.1 2.76 32.1 54.8 As can be seen, the solid content of Comparative Example 1 was reduced compared to Example 1 insofar as a significant amount of pasty material adhered to the agitator. It can also be observed that the viscosity is similar despite the lower solids content and that the particle size is less fine for this product obtained with clean water in comparison with the two previous ones obtained with the treatment water. COMPARATIVE EXAMPLE 2 The same type of finely ground quicklime as in Example 1 is quenched with the same industrial process water in a continuous pilot quenching plant, which means that lime is BE2017 / 5138 added to water in place of the present invention where water is added to quicklime. This pilot installation consists of a stirred tank reactor of 10 dm 3 with a double jacket, a screw feeder with a hopper for continuous dosing of quicklime, a metering pump to continuously convey the extinguishing water and another metering pump for continuously removing the slaked lime suspension from the reactor. The reactor is equipped with a thermostatic heating bath to regulate its temperature, a large capacity reflux refrigeration device with an attached ventilation system to remove any steam generated and thermocouples in different positions to monitor the temperature of the reactor. Reactor agitation has been designed and validated to provide agitation similar to that of industrial retention fire extinguishers. The reactor was fed continuously with 90 g / min of quicklime and 450 g / min of slaked lime for an average residence time of about 20 min. The quenching temperature in the reactor was 80 ° C. The results of the quality of the milk of lime are shown in Table 4 and were obtained under regular condition (after approximately 7 operating residence times). Table 4 Test Viscosity[cPs] Contentsolids [%in weight] dso[m] dgo[m] D97[m] 1 40 25.6 8.33 52.6 75.7 COMPARATIVE EXAMPLE 3 Comparative Example 2 was reproduced, but demineralized water was used in place of the process water. The results are shown in Table 5. BE2017 / 5138 Table 5 Test Viscosity[cPs] Contentsolids [%in weight] dso[m] dgo[m] dg7[m] 2 200 23.0 4.5 20 40 As can be seen, the effect of industrial process water under continuous conventional extinction, as it is practiced in industry, is therefore a significant magnification of the lime milk (comparative example 2) in comparison with the clean water (comparative example 3). EXAMPLE 2 The same experiment under the same conditions as according to Example 1 was carried out, but using a solution of sulfate salts, that is to say 10 g / dm 3 of magnesium sulfate and 2 g / dm 3 of sodium sulfate. The two salts were added in anhydrous form as chemicals to deionized water to produce this solution. At the end of the quenching experiment, the obtained whitewash suspension was sieved through stainless steel sieves, first 1000 µm and then 200 µm. The rejects from the sieves were dried, weighed and the weight expressed as a fraction of the total solids content in the suspension. While the solid content and viscosity were determined before sieving, the particle size distribution was measured after sieving as described in Example 1. The results shown in Table 6 were obtained. BE2017 / 5138 Table 6 Test Viscosity[cPs] Contentinsolid[% inweight] dso[m] dgo[m] dg7[m] Rejection>200 pm[% inweightofsolids] Rejection>1 mm[% inweightofsolid 1 215 43.7 3.74 29.3 51.8 15.7% 1.0% The suspensions were then diluted by adding demineralized water to 26.6% by weight of solid content for an easier comparison of the viscosity with that of the comparative examples. The results are shown in Table 7. Table 7 Test Viscosity[cPs] Solid content[% in weight] 1 8 26.6 COMPARATIVE EXAMPLE 4 The same lime as that according to Example 1 was quenched in an experimental installation as described in standard EN 459-2, section 5.10: "Reactivity". 150 g of finely ground lime with a maximum particle size of 2 mm are added to 600 g of the same solution as in Example 2 with an initial temperature of the solution of 20 ° C and quenched with stirring as described in the standard . The suspension obtained is then sieved through sieves of stainless steel first of 1000 μm, then of 200 μm. The rejects from the sieves were dried, weighed and the weight expressed as a fraction of the total solids content in the suspension. While the solids content and viscosity were determined before sieving, the particle size distribution was BE2017 / 5138 measured after sieving as described in Example 1. The results shown in Table 8 were obtained. Table 8 Test Viscosity[cPs] Contentinsolid[% inweight] dso[m] dgo[m] d97[m] Rejection>200 pm[% inweightofsolids] Rejection>1 mm[% inweightofsolid 1 5 18 16.5 73 91 1.2% 2.8% EXAMPLE 3 The same experiment under the same conditions according to Example 1 was carried out, but using another solution of sulfate salts, that is to say 30 g / dm 3 of magnesium sulfate and 5 g / dm 3 of sodium sulfate. The two salts were added in anhydrous form as chemicals to deionized water to produce this solution. At the end of the quenching experiment, the obtained whitewash suspension was sieved through stainless steel sieves, first 1000 µm and then 200 µm. The rejects from the sieves were dried, weighed and the weight expressed as a fraction of the total solids content of the suspension. While the solids content and viscosity were determined before sieving, the particle size distribution was measured after sieving as described in Example 1. The results shown in Table 9 were obtained. BE2017 / 5138 Table 9 Test Viscosity[cPs] Contentinsolid[% inweight] dso[m] dgo[m] dg7[m] Rejection>200 pm[% inweightofsolids] Rejection>1 mm[% inweightofsolid 1 215 44.9 4.5 40.3 59.1 19.0% 1.4% The suspensions were then diluted by adding demineralized water to a content of 26.6% by weight of solids for an easier comparison of the viscosity to that of the comparative example. The results are shown in Table 10. Table 10 Test Viscosity[cPs] Solid content[% in weight] 1 8 26.6 COMPARATIVE EXAMPLE 5 The same lime as in Example 1 was quenched in an experimental installation described in standard EN 459-2, section 5.10: "Reactivity". 150 g of finely ground lime with a maximum size of 2 mm are added to 600 g of the same solution as in Example 3 with an initial temperature of the solution of 20 ° C and quenched with stirring as described in the standard. The suspension obtained is then sieved through sieves of stainless steel first of 1000 μm and then of 200 μm. The rejects from the sieves were dried, weighed and the weight expressed as a fraction of the total solids content in the suspension. While the solids content and viscosity were determined before sieving, the particle size distribution was BE2017 / 5138 measured after sieving as described in Example 1. The results shown in Table 11 were obtained. Table 11 Test Viscosity[cPs] Contentinsolid[% inweight] 050[m] dgo[m] dg7[m] Rejection>200 pm[% inweightofsolids] Rejection>1 mm[% inweightofsolid 1 14 21.8 10.2 57.3 80.9 11.3% 3.4% EXAMPLE 4 The same experiment under the same conditions according to Example 1 was carried out, but using a saturated solution of calcium sulfate, therefore containing approximately 1.4 g / dm 3 of dissolved calcium sulfate. Analytical grade gypsum was used to saturate the solution. At the end of the quenching experiment, the obtained whitewash suspension was sieved through stainless steel sieves, first 1000 µm and then 200 µm. The rejects from the sieves were dried, weighed and the weight expressed as a fraction of the total solids content in the suspension. While the solids content and viscosity were determined before sieving, the particle size distribution was measured after sieving as described in Example 1. The results shown in Table 12 were obtained. BE2017 / 5138 Table 12 Test Viscosity[cPs] Contentinsolid[% inweight] dso[m] <^ 90[m] dg7[m] Rejection>200 pm[% inweightofsolids] Rejection>1 mm[% inweightofsolid 1 1300 40.1 2.81 24.8 43.3 9.6% 15.7% The suspensions were then diluted by adding demineralized water to a solids content of 22% by weight for an easier comparison of the viscosity with that of the comparative examples. The results are shown in Table 13. Table 13 Test Viscosity[cPs] Solid content[% in weight] 1 63 22.0 COMPARATIVE EXAMPLE 6 The same lime as in Example 1 was quenched in a test facility described in standard EN 459-2, section 5.10: "Reactivity". 150 g of finely ground lime with a maximum size of 2 mm are added to 600 g of the same solution as in Example 4 with an initial temperature of the solution of 20 ° C and quenched with stirring as described in the standard. The suspension obtained is then sieved through sieves of stainless steel first of 1000 μm and then of 200 μm. The rejects from the sieves were dried, weighed and the weight expressed as a fraction of the total solids content in the suspension. While the solids content and viscosity were determined before sieving, the particle size distribution was BE2017 / 5138 measured after sieving as described in Example 1. The results shown in Table 14 were obtained. Table 14 Test Viscosity[cPs] Contentinsolid[% inweight] dso[m] dgo[m] dg7[m] Rejection>200 pm[% inweightofsolids] Rejection>1 mm[% inweightofsolid 1 3 26.4 16.45 66.4 112.7 0.3% 1.8% EXAMPLE 5 The same experiment under the same conditions according to Example 1 was carried out, but using a sodium chloride solution, that is to say 10 g / dm 3 of sodium chloride of analytical grade were added to demineralized water to produce this solution. At the end of the quenching experiment, the obtained whitewash suspension was sieved through stainless steel sieves, first 1000 µm and then 200 µm. The rejects from the sieves were dried, weighed and the weight expressed as a fraction of the total solids content in the suspension. While the solids content and viscosity were determined before sieving, the particle size distribution was measured after sieving as described in Example 1. The results shown in Table 15 were obtained. BE2017 / 5138 Table 15 Test Viscosity[cPs] Contentinsolid[% inweight] deo[m] dgo[m] dg7[m] Rejection>200 pm[% inweightofsolids] Rejection>1 mm[% inweightofsolid 1 1480 37.8 2.80 31.3 64.6 4.8% 5.3% The suspensions were then diluted by adding demineralized water to a solids content of 20.4% by weight for an easier comparison of the viscosity with that of the comparative examples. The results are shown in Table 16. Table 16 Test Viscosity[cPs] Solid content[% in weight] 1 43 20.4 COMPARATIVE EXAMPLE 7 The same lime as in Example 1 was quenched in a test installation described in standard EN 459-2, section 5.10: "Reactivity". 150 g of finely ground lime with a maximum size of 2 mm are added to 600 g of the same solution as in Example 5 with an initial temperature of the solution of 20 ° C and quenched with stirring as described in the standard. The suspension obtained is then sieved through sieves of stainless steel first of 1000 μm and then of 200 μm. The rejects from the sieves were dried, weighed and the weight expressed as a fraction of the total solids content in the suspension. While the solids content and viscosity were determined before sieving, the particle size distribution was BE2017 / 5138 measured after sieving as described in Example 1. The results shown in Table 17 were obtained. Table 17 Test Viscosity[cPs] Contentinsolid[% inweight] dso[m] dgo[m] dg7[m] Rejection>200 pm[% inweightofsolids] Rejection>1 mm[% inweightofsolid 1 21 28 6.22 31.9 52.5 8.0% 0.5% EXAMPLE 6 The same experiment under the same conditions as according to example 1 was carried out, but using another solution of sodium chloride, that is to say that 40 g / dm 3 of sodium chloride of analytical quality were added to demineralized water to produce this solution. At the end of the quenching experiment, the obtained whitewash suspension was sieved through stainless steel sieves, first 1000 µm and then 200 µm. The rejects from the sieves were dried, weighed and the weight expressed as a fraction of the total solids content in the suspension. While the solids content and viscosity were determined before sieving, the particle size distribution was measured after sieving as described in Example 1. The results in Table 18 were obtained. BE2017 / 5138 Table 18 Test Viscosity[cPs] Contentinsolid[% in weight] deo[m] dgo[m] dg7[m] Rejection>200 pm[% inweightofsolids] Rejection>1 mm[% inweightofsolid 1 2400 43.1 2.87 11.7 29.7 5.9% 12.4% The suspensions were then diluted by adding demineralized water to a solid content of 21.0% by weight for an easier comparison of the viscosity to that of the comparative example. The results are shown in Table 19. Table 19 Test Viscosity[cPs] Solid content[% in weight] 1 59 21.0 COMPARATIVE EXAMPLE 8 The same lime as in Example 1 was quenched in a test facility described in standard EN 459-2, section 5.10: "Reactivity". 150 g of finely ground lime with a maximum size of 2 mm are added to 600 g of the same solution as in Example 6 with an initial temperature of the solution of 20 ° C and quenched with stirring as described in the standard. The suspension obtained is then sieved through sieves of stainless steel first of 1000 μm and then of 200 μm. The rejects from the sieves were dried, weighed and the weight expressed as a fraction of the total solids content in the suspension. While the solids content and viscosity were determined before sieving, the particle size distribution was BE2017 / 5138 measured after sieving as described in Example 1. The results in Table 20 were obtained. Table 20 Test Viscosity[cPs] Contentinsolid[% inweight] dso[m] d90[m] dg7[m] Rejection>200 pm[% inweightofsolids] Rejection>1 mm[% inweightofsolid 1 17 29.6 7.86 45.9 67 7.6% 0.4% EXAMPLE 7 The same experiment under the same conditions as in Example 1 was carried out, but using another solution with the composition of seawater, that is to say: 27.4 g / dm 3 of NaCI 3.4 g / dm 3 of MgCL 2.1 g / dm 3 of MgSC> 4 1.4 g / dm 3 of CaSC> 4 0.7 g / dm 3 of KCI This solution was produced from anhydrous analytical grade salts added to demineralized water. At the end of the quenching experiment, the obtained whitewash suspension was sieved through stainless steel sieves, first 1000 µm, and then 200 µm. The rejects from the sieves were dried, weighed and the weight expressed as a fraction of the total solids content in the suspension. While the solid content and viscosity were determined before sieving, the particle size distribution was measured after sieving as described in Example 1. The results shown in Table 21 were obtained. BE2017 / 5138 Table 21 Test Viscosity[cPs] Contentinsolid[% inweight] dso[m] dgo[m] dg7[m] Rejection>200 pm[% inweightofsolids] Rejection>1 mm[% inweightofsolid 1 2400 43.4 3.86 52.8 71.7 19.1% 8.4% The suspensions were then diluted by adding demineralized water to a solids content of 21.8% by weight for an easier comparison of the viscosity to that of the comparative example. The results are shown in Table 22. Table 22 Test Viscosity[cPs] Solid content[% in weight] 1 27 21.8 COMPARATIVE EXAMPLE 9 The same lime as in Example 1 was quenched in a test facility described in standard EN 459-2, section 5.10: "Reactivity". 150 g of finely ground lime with a maximum size of 2 mm are added to 600 g of the same solution as in Example 7 with an initial temperature of the solution of 20 ° C and quenched with stirring as described in the standard. The suspension obtained is then sieved through sieves of stainless steel first of 1000 μm and then of 200 μm. The rejects from the sieves were dried, weighed and the weight expressed as a fraction of the total solids content in the suspension. While the solids content and viscosity were determined before sieving, the particle size distribution was BE2017 / 5138 measured after sieving as described in Example 1. The results shown in Table 23 were obtained. Table 23 Test Viscosity[cPs] Contentinsolid[% inweight] dso[m] dgo[m] dg7[m] Rejection>200 pm[% inweightofsolids] Rejection>1 mm[% inweightofsolid 1 8 20.9 14.7 79.5 119 1.4% 3.6% EXAMPLE 8 The same experiment under the same conditions as in Example 1 was carried out, but using a solution of the following composition: 195 g / dm 3 of NaCI g / dm 3 of MgSC> 4 g / dm 3 of Na2SO4 1.4 g / dm 3 of CaSCU 1.5 g / dm 3 of KCI This solution was produced from anhydrous analytical grade salts added to demineralized water. At the end of the quenching experiment, the obtained whitewash suspension was sieved through stainless steel sieves, first 1000 µm and then 200 µm. The rejects from the sieves were dried, weighed and the weight expressed as a fraction of the total solids content in the suspension. While the solids content and viscosity were determined before sieving, the particle size distribution was measured after sieving as described in Example 1. The results shown in Table 24 were obtained. BE2017 / 5138 Table 24 Test Viscosity[cPs] Contentinsolid[% inweight] dso[m] dgo[m] dg7[m] Rejection>200 pm[% inweightofsolids] Rejection>1 mm[% inweightofsolid 1 147 49.6 5.49 61 85.9 8.8% 3.2% The suspensions were then diluted by adding demineralized water to a solids content of 28.1% by weight for an easier comparison of the viscosity with that of the comparative examples. The results are shown in Table 25. Table 25 Test Viscosity[cPs] Solid content[% in weight] 1 9 28.1 COMPARATIVE EXAMPLE 10 The same lime according to Example 1 was quenched in a test installation described in standard EN 459-2, section 5.10: "Reactivity". 150 g of finely ground lime with a maximum size of 2 mm are added to 600 g of the same solution as in Example 8 with an initial temperature of the solution of 20 ° C and quenched with stirring as described in the standard. The suspension obtained is then sieved through sieves of stainless steel first of 1000 μm and then of 200 μm. The rejects from the sieves were dried, weighed and the weight expressed as a fraction of the total solids content in the suspension. While the solids content and viscosity were determined before sieving, the particle size distribution was BE2017 / 5138 measured after sieving as described in Example 1. The results shown in Table 26 were obtained. Table 26 Test Viscosity[cPs] Contentinsolid[% inweight] dso[m] 090[m] dg7[m] Rejection>200 pm[% inweightofsolids] Rejection>1 mm[% inweightofsolid 1 18 35.7 15.1 70.2 91.8 14.1% 1.5% COMPARATIVE EXAMPLE 11 The same lime according to Example 1 was quenched in a test installation described in standard EN 459-2, section 5.10: "Reactivity". 150 g of finely ground lime with a maximum size of 2 mm are added to 600 g of demineralized water with an initial temperature of the solution of 20 ° C and quenched with stirring as described in the standard. The suspension obtained is then sieved through sieves of stainless steel first of 1000 μm and then of 200 μm. The rejects from the sieves were dried, weighed and the weight expressed as a fraction of the total solids content in the suspension. While the solid content and viscosity were determined before sieving, the particle size distribution was measured after sieving as described in Example 1. The results shown in Table 27 were obtained. BE2017 / 5138 Table 27 Test Viscosity[cPs] Contentinsolid[% inweight] dso[m] dgo[m] dg7[m] Rejection> 200 pm[% inweightofsolids] Rejection>1 mm[% inweightofsolid 1 175 26.7 4.56 26.8 62.9 13.0% 0.2% COMPARATIVE EXAMPLE 12 The same experimental conditions as in Comparative Example 5 were used, but with another starting quicklime. If the quicklime of comparative example 1 had a reactivity t6o of 2.5 min (measured according to the procedure mentioned in standard EN459-2), the quicklime sample used in this example is of low reactivity, that is to say with a teo of 4.2 min and also contains impurities, in particular sulphates with a content of about 0.18% by weight of SO3, which would reduce the fineness of the milk of lime obtained. Demineralized water was supplied at a rate of 3.0 g / s to the reactor and therefore sprayed through the nozzle onto the lime. About 10 g of sorbitol was added and dissolved in water beforehand. A total of 4.2 kg of this water was added over a period of approximately 25 min. At the end of the dosing, the mixture is left to stir in the mixer until it cools to below 50 ° C. Then it is removed from the blender, first sieved 1 mm through a sieve and analyzed for its solid content and viscosity. Then it is sieved to 200 µm and its particle size distribution is determined. The results shown in Table 28 were obtained. BE2017 / 5138 Table 28 Test Viscosity[cPs] Contentinsolid[% inweight] dso[m] dgo[m] dg7[m] Rejection>200 pm[% inweightofsolids] Rejection>1 mm[% inweightofsolid 1 52 44.2 2.72 9.33 27.7 0.2% 1.0% The suspensions were then diluted by adding demineralized water to a solids content of 21.2% by weight for an easier comparison of the viscosity with that of the comparative examples. The results are shown in Table 29. Table 29 Test Viscosity[cPs] Solid content[% in weight] 1 10 21.2 COMPARATIVE EXAMPLE 13 The same lime as in Comparative Example 12 was quenched in an experimental installation as described in standard EN 459-2, in the same way as in Comparative Example 4. While the solids content and viscosity were determined before sieving, the particle size distribution was measured after sieving as described in Example 1. The results shown in Table 30 were obtained. BE2017 / 5138 Table 30 Test Viscosity[cPs] Contentinsolid[% inweight] dso[m] dgo[m] dg7[m] Rejection>200 pm[% inweightofsolids] Rejection>1 mm[% inweightofsolid 1 123 26.7 4.96 11.61 27.5 0.0% 0.0% Compared to Comparative Example 12, it can be seen that a significantly lower dso and a lower viscosity were obtained in Comparative Example 12. COMPARATIVE EXAMPLE 14 The same lime as in Example 1 was quenched in an experimental installation as described in standard EN 459-2, section 5.10: "Reactivity". 150 g of finely ground lime with a maximum size of 2 mm are added to 600 g of the same process water as in Example 9 with an initial temperature of the solution of 20 ° C and quenched with stirring as described in the standard. The suspension obtained is then sieved through sieves of stainless steel first of 1000 μm and then of 200 μm. The rejects from the sieves were dried, weighed and the weight expressed as a fraction of the total solids content in the suspension. While the solids content and viscosity were determined before sieving, the particle size distribution was measured after sieving as described in Example 1. The results shown in Table 31 were obtained. BE2017 / 5138 Table 31 Test Viscosity[cPs] Contentinsolid[% inweight] dso[m] dgo[m] dg7[m] Rejection>200 pm[% inweightofsolids] Rejection>1 mm[% inweightofsolid 1 184 28.2 8.2 21.4 31.4 0.0% 0.0% Compared with the reactivity test with demineralized water, the extinction in the same test installation with process water did not reach 60 ° C, even if the test was checked for more than 15 min. This lack of heat generation was not noted on the extinction of Example 9, that is to say according to the invention, where again a lime milk of lower dso and lower viscosity was obtained in comparison with this example. EXAMPLE 9 The same experiment under the same conditions as in Comparative Example 12 was carried out, but using industrial process water as described in Example 1 (i.e. the process of the present invention with weakly reactive quicklime). This industrial process water contained approximately 2 g / dm 3 of sodium hydroxide, 11 g / dm 3 of sodium carbonate, approximately 7 g / dm 3 of sodium aluminate, approximately 2 g / dm 3 of sodium sulfate , about 0.5 g / dm 3 of sodium chloride and 5 to 15 g / dm 3 of organic impurities, which were derived from humates. As in the other examples, approximately 10 g of sorbitol was added to the water. At the end of the extinction experiment, the suspension of lime milk obtained was sieved through sieves of stainless steel while BE2017 / 5138 first 1000 pm and then 200 pm. The rejects from the sieves were dried, weighed and the weight expressed as a fraction of the total solids content in the suspension. While the solids content and viscosity were determined before sieving, the particle size distribution was measured after sieving as described in Example 1. The results shown in Table 32 were obtained. Table 32 Test Viscosity[cPs] Contentinsolid[% inweight] dso[m] dgo[m] dg7[m] Rejection>200 pm[% inweightofsolids] Rejection>1 mm[% inweightofsolid 1 976 46.7 2.3 9.6 36.9 0.5% 0.0% The suspensions were then diluted by adding demineralized water to a solids content of 23.7% by weight for an easier comparison of the viscosity with that of the comparative examples. The results are shown in Table 33. Table 33 Test Viscosity[cPs] Solid content[% in weight] 1 80 23.7 If the invention has been illustrated in several of its forms, it is therefore not limited and is subject to various changes and modifications without departing from its spirit and from the claims appended hereto. BE2017 / 5138
权利要求:
Claims (10) [1] 1. A method of manufacturing a very fine lime milk comprising at least the steps consisting in: a) providing a lime compound chosen from the group of quicklime, a first lime compound and their mixture, said first lime compound being chosen from the group consisting of pre-hydrated lime obtained by adding a first water to quick lime, a lime paste obtained by adding a second water to quick lime, a lime paste obtained by adding a third water to pre-hydrated lime, a lime paste obtained by adding prehydrated lime to a third water and their mixture, and b) forming a very fine slaked lime milk with said lime compound by adding a fourth water to said lime compound or by adding the first lime compound to a fourth water, characterized in that at least one first, second, third or fourth water is a treatment water chosen from the group consisting of alkaline water, saline water, sulphated water comprising 3 to 300 g of solute / dm 3 and in that at least one of the first, second, third or fourth water is added to said lime compound, said very fine lime milk having slaked lime particles having a dso greater than or equal to 1 pm and less than or equal to 6 pm, measured by laser diffraction using methanol as a carrier solvent after sieving the whitewash 2 mm through a sieve to remove the fragments and, if necessary, after applying an ultrasonic treatment. [2] 2. A method of manufacturing a milk of lime of great fineness according to claim 1, wherein said at least one of the first, second or fourth water is added to milk of lime by progressive addition of said at least one of the first , second or fourth water with quicklime with stirring. BE2017 / 5138 [3] 3. A method of manufacturing a milk of lime of great fineness according to claim 1 or claim 2, wherein said third water or said fourth water is added to pre-hydrated lime by progressive addition of said third or fourth water to prehydrated lime with stirring. [4] 4. A method of manufacturing a milk of lime of great fineness according to any one of claims 1 to 3, wherein said fourth water is added to lime paste by progressive addition of said fourth water to the lime paste under agitation. [5] 5 of process water, and a second opening connected to a collecting means supplied to collect a second lime compound chosen from the group consisting of pre-hydrated lime, lime paste and lime milk, said supply means comprising other spraying means or flow control means. 5. A method of manufacturing a milk of lime of great fineness according to any one of claims 2 to 4, wherein said progressive addition of said at least one of the first, second, third or fourth water to said lime compound present a scheme for adding said at least one of the first, second, third or fourth water to control the absorption of water by the lime compound in a batch process or a continuous process. [6] 6. A method of manufacturing a milk of slaked lime of great fineness according to any one of claims 2 to 5, wherein said progressive addition of said at least one of the first, second, third or fourth water is a continuous process during which the progressive hydration of said lime compound is carried out by adjusting the rate of supply of lime compound in a hydrator in which a predetermined atmosphere is created containing a limited quantity of said at least one of the first, second, third or fourth water for the addition of said at least one of the first, second, third or fourth water to said lime compound. [7] 7. A method of manufacturing lime milk of great fineness according to any one of claims 2 to 6, wherein the progressive addition of said at least one of the first, second, third or fourth water is carried out by spraying a mist of said at least BE2017 / 5138 one of the first, second, third or fourth water in a hydrator. [8] 8. A method of manufacturing milk of slaked lime of great fineness according to any one of claims 2 to 5 or 7, wherein the progressive addition of said at least one of the first, second, third or fourth water is a process discontinuous during which a gradual hydration of said lime compound is carried out by placing a predetermined amount of lime compound in a hydrator, in which a predetermined atmosphere is created, containing a limited amount of said at least one of the first, second, third or fourth water for addition of said at least a first, second, third or fourth water to said lime compound. [9] 9. A method of manufacturing a milk of lime of great fineness according to any one of claims 2 to 8, wherein said lime compound is quicklime on which said fourth water which is process water is gradually added until said very fine lime milk is obtained. 10. A method of manufacturing a milk of lime of great fineness according to any one of claims 2 to 8, wherein said first lime compound is chosen from the group consisting of pre-hydrated lime, lime paste and their mixture obtained from quicklime on which a first water or a second water which is process water is gradually added to form said first lime compound. 11. A method of manufacturing a milk of lime of great fineness according to any one of claims 2 to 8, wherein said first lime compound is a lime paste obtained from pre-hydrated lime on which said third water which is process water is gradually added. BE2017 / 5138 12. A method of manufacturing a milk of lime of great fineness according to any one of claims 2 to 8, wherein said third and said fourth water constitute one and the same water and wherein said first lime compound is pre-hydrated lime on which said third water, which is said treatment water, is gradually added until said milk of lime is obtained. 13. A method of manufacturing a lime milk of great fineness according to any one of claims 1 to 12, further comprising an addition of at least one additive, said additive being added or contained in said at least one of the first, second, third or fourth water or added to or contained in said lime compound. 14. A method of manufacturing a milk of lime of great fineness according to claim 13, wherein said additive is chosen from the group consisting of carbohydrates, sugars, alcohol sugars, in particular sorbitol, carbon dioxide, phosphates, sulfates, bicarbonates, silicates, phosphonates, polyacrylates, polycarboxylic acids, low molecular weight organic acids, their mixtures and their derivatives. 15. A method of manufacturing a milk of lime of great fineness according to any one of claims 1 to 14, wherein said at least one of the first, second, third and fourth water which is process water is an aqueous phase chosen from the group consisting of water comprising an endogenous salt, an industrial alkaline aqueous phase, industrial water with a high sulphate content, saturated gypsum solutions, sea water, saline water and hypersaline water, brackish water and their mixture, recycled or not. 16. Method for manufacturing a milk of lime of great fineness according to any one of claims 1 to 15, in which said treatment water comprises at least 1 g / dm 3 , in particular at least 5 g / dm 3 , preferably at least 10 g / dm 3 , better still at least BE2017 / 5138 20 g / dm 3 , in particular at least 40 g / dm 3 of mineral salt comprising a mineral sulfate or a sodium salt and their mixture. 17. A method of manufacturing lime milk of great fineness according to any one of claims 1 to 16, wherein the proportion of process water to the total amount of water used is greater than 40% by weight, preferably greater than 60% by weight, better still greater than 80% by weight and up to 100% by weight. 18. A method of manufacturing a lime milk of great fineness according to any one of claims 1 to 17, further comprising a sieving or selection step to remove particles greater than 1 mm, preferably greater than 500 μm , better still 200 µm. 19. Very fine slaked lime milk comprising slaked lime particles suspended in an aqueous phase, in which the slaked lime particles have a d 5 o greater than or equal to 1.5 μm and less than or equal to 5 μm, more preferably less than or equal to 4 µm, much more preferably less than or equal to 3 µm, and wherein said milk of lime further contains a mineral salt comprising a mineral sulfate or a sodium salt and their mixture at a level of at least at least 1 g / dm 3 , in particular at least 5 g / dm 3 , preferably at least 10 g / dm 3 , more preferably at least 20 g / dm 3 , in particular at least 40 g / dm 3 . 20. slaked lime milk according to claim 19 having a solids content greater than 20% by weight, preferably greater than 30% by weight, better still greater than 35% by weight, much better still greater than 40% by weight, relative to the total weight of the milk of lime, said solids content being less than or equal to 55% by weight, preferably less than or equal to 50% by weight, in particular less than or equal to 45% by weight relative to said total weight slaked lime milk. BE2017 / 5138 21. slaked lime milk according to any one of claims 19 to 20, having a viscosity measured with a Brookfield DV-3B rheometer using a predetermined spindle at a rotation speed of 100 rpm less than 1,200 mPa.s, preferably less than 600 mPa.s, in particular less than 450 mPa.s and better still less than 300 mPa.s. 22. Very fine slaked lime milk according to any one of claims 19 to 21, in which said aqueous phase comprises less than 2 g / dm 3 of total organic carbon, preferably less than 1.2 g / dm 3 , much better still less than 0.8 g / dm 3 of total organic carbon. 23. Use of process water for the production of very fine lime milk in a hydration process with a fourth water of a lime compound chosen from the group of quicklime, of a first compound of lime and their mixture, said first lime compound being chosen from the group consisting of prehydrated lime obtained by adding a first water to quicklime, a lime paste obtained by adding a second water to quicklime, a lime paste obtained by adding a third water to pre-hydrated lime, a lime paste obtained by adding prehydrated lime to a third water and their mixture, said water of treatment being used as first, second, third or fourth water, said third and said fourth water being identical or different, to form a slaked lime milk of great finesse with said lime compound. 24. Use of process water according to claim 23, in which at least one additive is additionally added, said additive being added or contained in said at least one of the first, second, third and fourth water or added or contained in said lime compound. 25. Use of process water according to claim 24, wherein said additive is chosen from the group consisting of hydrates of BE2017 / 5138 carbon, sugars, alcohol sugars, in particular sorbitol, carbon dioxide, phosphates, sulfates, bicarbonates, silicates, phosphonates, polyacrylates, polycarboxylic acids, acids organic compounds of low molecular weight, their mixtures and their derivatives. 26. Use of process water according to any one of claims 23 to 25, wherein said at least one of the first, second, third and fourth water which is process water is an aqueous phase chosen from the group consisting of water comprising an endogenous salt, an industrial alkaline aqueous phase, industrial water with a high sulphate content, saturated gypsum solutions, sea water, saline water and hypersaline water, brackish water and their mixture, recycled or not. 27. Use of process water according to any one of claims 23 to 26, wherein said at least one of the first, second, third and fourth water which is process water comprises at least 1 g / dm 3 , preferably at least 5 g / dm 3 , in particular at least 10 g / dm 3 , more particularly at least 20 g / dm 3 and clearly better still at least 40 g / dm 3 of mineral salt comprising a mineral sulfate or a sodium salt and their mixture. 28. Device for producing a milk of lime of great finesse comprising a hydration zone provided for comprising a lime compound chosen from the group of quicklime, a first lime compound and their mixture, said first lime compound being chosen from the group consisting of pre-hydrated lime obtained by adding a first water to quicklime, a lime paste obtained by adding a second water to quicklime, a lime paste obtained by adding a third water to pre-hydrated lime, a lime paste obtained by adding pre-hydrated lime to a third water and their mixture, said hydration zone comprising a BE2017 / 5138 opening connected to a supply means supplied for conveying at least a first, a second, a third or a fourth water which is process water on said lime compound, said supply means being in communication fluidic with storage [10] 29. A plant for the production of very fine lime milk comprising a device according to claim 28 and a means for storing process water containing a means for leaving process water connected to said means for supplying said device. BE2017 / 5138 "ABBREVIATE" "Process for the production of slaked lime milk of great finesse and lime milk of great fineness thus obtained with process water" A method of manufacturing a very fine lime milk comprising at least the steps of supplying a lime compound and forming said lime milk with process water and said lime compound. PATENT COOPERATION TREATY
类似技术:
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公开号 | 公开日 US10919803B2|2021-02-16| WO2017153379A1|2017-09-14| FR3048694A1|2017-09-15| AU2017230307A1|2018-10-11| BR112018067814A2|2019-01-15| EP3426603A1|2019-01-16| PH12018501869A1|2019-01-28| CA3016768A1|2017-09-14| US20190092684A1|2019-03-28| PE20181933A1|2018-12-13| CO2018009875A2|2018-09-28| BE1024520A1|2018-03-21| CL2018002519A1|2018-10-26| WO2017152960A1|2017-09-14|
引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题 US3511600A|1968-05-08|1970-05-12|Monsanto Co|Preparation of aqueous slaked lime slurry and dicalcium orthophosphate| US4464353A|1982-06-21|1984-08-07|Chemlime Corporation|Quicklime slaking process| US5275650A|1987-10-23|1994-01-04|Coatex S.A.|Agent for grinding lime to augment its reactivity| US5223239A|1990-07-24|1993-06-29|Research Corporation Technologies, Inc.|Method of preparing hydrated lime| US5507572A|1994-09-02|1996-04-16|Chemical Lime Company|Method and apparatus for supplying a continuous product stream of lime slurry to a remote jobsite| GB0111706D0|2001-05-14|2001-07-04|Ciba Spec Chem Water Treat Ltd|Fine particle size lime slurries and their production| US7105146B2|2003-03-04|2006-09-12|Chemco Systems L.P.|Method and apparatus for hydration of calcium oxide| US7326400B2|2005-08-11|2008-02-05|Chemical Lime Company|Treatment of high sulfate containing quicklime| EP1840097A1|2006-03-27|2007-10-03|Carmeuse S.A.|Stabilisation of lime suspensions| BE1021522B1|2012-09-12|2015-12-07|S.A. Lhoist Recherche Et Developpement|HIGH FINENSE LIME MILK COMPOSITION| BE1021199B1|2012-10-25|2015-07-28|S.A. Lhoist Recherche Et Developpement|CALCO-MAGNESIAN HANDHELD SUSPENSION| WO2016041643A1|2014-09-08|2016-03-24|S.A. Lhoist Recherche Et Developpement|Process for manufacturing a milk of slaked lime of great fineness and milk of lime of great fineness thereby obtained| WO2016037972A1|2014-09-08|2016-03-17|S.A. Lhoist Recherche Et Developpement|Process for manufacturing a milk of slaked lime of great fineness and milk of lime of great fineness thereby obtained|EP3820820A1|2018-07-11|2021-05-19|S.A. Lhoist Recherche Et Developpement|Process for obtaining size-calibrated tri-calcium aluminate particles and use of such particles in a process of alumina refining|
法律状态:
2018-04-09| FG| Patent granted|Effective date: 20180326 |
优先权:
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申请号 | 申请日 | 专利标题 PCT/EP2016/054941|WO2017152960A1|2016-03-08|2016-03-08|Process for manufacturing a milk of slaked lime of great fineness and milk of lime of great fineness thereby obtained with process water| EPPCT/EP2016/054941|2016-03-08| 相关专利
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