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    • 专利摘要:
    The present invention relates to a nonwoven support for immobilizing superabsorbent polymer particles in an absorbent article, to an absorbent article such as a diaper made from such a support, to methods of manufacturing the above-mentioned support and the above-mentioned absorbent article, as well as to the use of a nonwoven support according to the invention for immobilizing superabsorbent polymer particles in an absorbent article, in particular a diaper.
    公开号:BE1022371A9
    申请号:E20145056
    申请日:2014-11-07
    公开日:2017-02-15
    发明作者:Ainas Weber；Poorter Annick De；Christel Mailinger
    申请人:Ontex Bvba；
    IPC主号:
    专利说明:

    NONWOVEN BEARER FOR AN ABSORBENT ARTICLE TECHNICAL FIELD
    The present invention relates to a non-woven carrier for immobilizing superabsorbent polymer particles, an absorbent article, to an absorbent article made of such carrier, to methods of manufacturing the above-mentioned carrier and to the above-mentioned absorbent article, as well as to the use of a non-woven carrier according to the invention for immobilizing superabsorbent polymer particles in an absorbent article, in particular a diaper. The present invention is of particular interest in the field of hygiene products, in particular diapers.
    BACKGROUND
    The use of superabsorbent polymeric material in disposable diapers is well known. The use of superabsorbent polymeric material facilitates disposable diapers that have a thinner absorbent core as opposed to the use of absorbent materials such as fluff pulp, especially while the disposable diaper is in the dry state.
    Today, most disposable diapers that are commercially available have absorbent cores that contain a mixture of cellulose fibers and superabsorbent polymer particles. The cellulose fibers contained by the absorbent core partially hold the particles in place. The particles are not fully immobilized and may still have some degree of freedom to move within the openings of the cellulose fibers.
    The prior absorbent structures generally consist of relatively low amounts (e.g., less than about 50% by weight) of these superabsorbent polymer particles. There are several reasons for this. The superabsorbent polymer particles used in prior absorbent structures have generally not had an absorption rate that would allow them to rapidly absorb body fluids, especially in "flow" situations. This has required the incorporation of fibers, typical wood pulp fibers, which serve as temporary reservoirs to hold the discharged liquids until they are absorbed by the superabsorbent polymer particles.
    More importantly, many of the well-known superabsorbent polymer particles exhibited gel blockage. "Gel blockage" occurs when the superabsorbent polymer particles are wetted and the particles swell and thereby inhibit fluid transmission to the other areas of the absorbent structure.
    The wetting of these other areas of the absorbent member therefore takes place through a very slow spreading process. In practical terms, this means that the absorption of liquids through the absorbent structure is much slower than the speed at which the liquids are discharged, especially in flow situations. The leakage of the absorbent article can occur before the SAP particles in the absorbent member are close to full saturation or before the liquid can disperse or wick past the "blocking" particles in the remainder of the absorbent member. Gel blocking can be a particularly acute problem if the superabsorbent polymer particles do not have adequate gel strength and spread deformed or stressed as soon as the particles swell with the absorbed liquid.
    These gel-blocking phenomena have typically required the use of a fibrous matrix in which the superabsorbent polymer particles are scattered. This fibrous mold keeps the superabsorbent polymer particles apart. This fibrous matrix also provides a capillary structure that allows fluid to reach the super-absorbent polymer particles that are located in areas far from the initial fluid release point. However, dispersing the superabsorbent polymer particles at relatively low concentrations in a fibrous mold to minimize or avoid gel blocking can reduce the overall fluid storage capacity of thinner absorbent structures. The use of lower concentrations of these superabsorbent polymer particles somewhat limits the real advantage of these materials, namely their capacity to absorb and retain large amounts of body fluids per given volume. Another reason why the extremely high concentrations of superabsorbent polymer particles were not possible resides in the physical integrity disadvantage of structures made from particle material. Creating a fibrous matrix therefore also had the advantage of providing a fiber-reinforced structure similar to that used in many other technical situations where structural reinforcement is provided by fibrous elements, such as in fiberglass.
    Using higher amounts of superabsorbent polymer particles is desirable since it allows thinner absorbent cores. However, in absorbent cores that have high amounts of superabsorbent polymer particles and few or no cellulose fibers, the superabsorbent polymer particles can no longer be held in place, since the ratio of particles to fibers is too high. In absorbent cores with very high amounts of superabsorbent polymer particles, such as more than 80%, the particles are generally immobilized by the use of an adhesive, such as a hot melt adhesive, which is used as a fine, fibrous network within the absorbent core.
    The use of adhesive, in particular hot melt adhesive, has a number of disadvantages, including (i) the potential to inhibit fluid distribution, (ii) process issues due to dirt and blocking nozzles during production, and (iii) ) high cost. In addition, the polymer material is sandwiched between carrier substrates. The carrier substrates are typically a non-woven web.
    It has been found that the dense structure of the superabsorbent polymer particles causes winding or tearing problems, even at low line speed in a diaper machine. Therefore, the use of a non-woven web that is filled with super-absorbent polymer particles is preferably not processed on rolls.
    Furthermore, with a high amount of superabsorbent particles and a low amount of fluff, and generally fluffless absorbent cores, the absorbent cores suffer from a lack of softness.
    Thus, there is a need for disposable diapers with absorbent cores with super-absorbent polymer particles that are easier to process. In addition, there is a need for an alternative attachment of the superabsorbent polymer particles. There is also a need for an absorbent core with a high amount of superabsorbent particles, which retains a degree of softness.
    The present invention seeks to solve at least some of the aforementioned problems.
    To this end, the invention seeks to provide an improved absorbent core and a process for making such a core.
    SUMMARY OF THE INVENTION
    The present invention relates to an absorbent article, preferably a disposable absorbent article, such as a diaper.
    In a first aspect, the present invention specifically relates to a nonwoven support (1) for immobilizing superabsorbent polymer particles (28) in an absorbent article, consisting of a top layer (7) consisting of a pile and / or spunbond fibers ( 19) is permeable to particles and non-woven bottom layer (8) bonded, such as thermally bonded, heat or pressure or ultrasonic, bonded by needle felting, chemically bonded and / or bonded by adhesives, preferably mechanically bonded, more preferably water entangled at the top layer; wherein the bottom layer is porous with a pore size smaller than the particles.
    A non-woven support according to the invention provides at least a two-layer structure with very different properties. The top layer is porous, soft and bulky. In contrast, the bottom layer has much smaller pores, but considerably higher mechanical strength.
    In a second aspect, the present invention provides an absorbent article consisting of a nonwoven support according to an embodiment of the invention that immobilizes superabsorbent polymer particles.
    The superabsorbent polymer particles can be trapped between the fibers of the upper layer, thereby preventing them from moving in the longitudinal and transverse direction (x-y plane) of the absorbent article. The particles are restrained by the material from falling, i.e. from moving in a cross-sectional direction (z-direction).
    In a third aspect, a process for manufacturing a non-woven support according to an embodiment of the invention, which comprises the steps of: providing a non-woven bottom layer and a top layer consisting of stack of fibers, and mechanically joining the stack of fibers on the non-woven bottom layer thereby providing the non-woven support in which the superabsorbent polymer particles are retained.
    The mechanical joining of stack and / or spunbond fibers to the bottom layer provides a substantially permanent attachment of stack of fibers to a non-woven support. A robust structure for enclosing and retaining superabsorbent polymer particles is provided.
    In a further aspect, the invention also provides a process for manufacturing an absorbent article according to an embodiment of the invention, comprising the steps of: providing a non-woven carrier and providing the non-woven carrier with super-absorbent polymer particles.
    The process provides a way to distribute superabsorbent polymer particles on a nonwoven support structure of the invention. Rather than simply lying on the surface of the top layer, the particles will also be trapped within the fibers. Their distribution is limited by the bottom layer. The pore size of the bottom layer is smaller than the particle size of the superabsorbent polymer particles, thereby preventing the particles from falling through the material.
    In a final aspect, the invention provides a use of a nonwoven support according to an embodiment of the invention for immobilizing superabsorbent polymer particles in a diaper.
    The nonwoven support provided by the invention can be particularly advantageous for use in an absorbent article such as a diaper.
    Preferred embodiments are as specified in the dependent claims.
    BRIEF DESCRIPTION OF THE FIGURES
    The invention will be further described in detail with respect to exemplary embodiments represented by the accompanying figures, in which FIG. 1 shows a schematic cross-sectional view of an absorbent article according to the present invention. FIG. 2 shows a schematic cross-sectional view of a core wrap including a non-woven backing that forms the absorbent article of FIG. 1 according to the present invention. FIGs. 3a-g shows a technical drawing of different patterns of clusters of superabsorbent polymer particles. FIG. 4 shows a top view of an embodiment of an absorbent article according to the present invention. FIG. 5 shows a top view of an embodiment of another type of absorbent article according to the present invention.
    DETAILED DESCRIPTION OF THE INVENTION
    Unless otherwise specified, all terms used to disclose the invention, including technical and scientific terms, have the meaning as generally understood by someone of ordinary skill in the art to which this invention belongs. By way of further guidance, term definitions are included to better appreciate the teachings of the present invention.
    As used herein, the following terms have the following meanings: "A," "an," and "an" as used herein refers to both singular and plural referents unless the context clearly dictates otherwise. As an example, a "compartment" refers to one or more than one compartment. "Approximately" as used herein refers to a measurable value such as a parameter, an amount, a temporary duration, and the like, intended to include variations of +/- 20% or less, preferably +/- 10% or less , more preferably +/- 5% or less, even more preferably +/- 1% or less, and even more preferably +/- 0.1% or less of the specified value, in so far such variations have been designated to the disclosed invention to function.
    However, it must be understood that the value to which the "approximately" provision refers itself is also specifically disclosed. "Consist of", "consisting of", and "consists of" and "consisting of" as used herein are synonymous with "include", "include", "include" or "contain", "contain", "contain" and are inclusive or open terms specifying the presence of what follows eg a component and do not exclude or prevent the presence of additional, non-recited components, properties, element, members, steps known in the prior art or disclosed therein.
    The recitation of numerical regions by end points includes all numbers and fractions that are housed within that range, as well as recited end points. "Absorbent article" refers to devices that absorb and contain liquid, and more specifically, refers to devices placed against or in proximity to the wearer's body to absorb and contain the various secretions discharged from the body. The absorbent articles include, but are not limited to, diapers, adult incontinence diapers, training pants, diaper holders and liners, sanitary napkins, and the like.
    The absorbent article of the present invention consists of a liquid permeable top sheet, preferably a liquid impervious back sheet, and of an absorbent suitable between top sheet and back sheet. The absorbent may consist of a non-woven backing according to the present invention. The absorbent article may also include one or more features such as, but not limited to, ears or side panels, leg cuffs, fastener components, and / or a belt. The top sheet, the back sheet and the absorbent could be made of any suitable material known to the person skilled in the art. "Absorbent" is the absorbent structure suitable between the top sheet and the back sheet of the absorbent article in at least the crotch region thereof. The absorbent material can be of any conventional type. Examples of commonly occurring absorbent materials are cellulose fluff pulp, tissue layers, highly absorbent polymers (so-called super-absorbent polymer particles), absorbent foam materials, absorbent non-woven materials or the like. It is common to combine cellulose fluff pulp with super-absorbent polymers in an absorbent material. The superabsorbent polymers are water-swellable, water-insoluble organic or inorganic materials capable of absorbing at least about 20 times their own weight of an aqueous solution containing 0.9% by weight of sodium chloride. Organic materials suitable for use as superabsorbent materials may include natural materials such as polysaccharides, polypeptides and the like, as well as synthetic materials such as synthetic hydrogel polymers. Such hydrogel polymers include, for example, alkali metal salts of polyacrylic acids, polyacrylamide, polyvinyl alcohol, polyacrylates, polyvinyl pyridine, and the like. Other suitable polymers include hydrolyzed acrylonitrile grafted starch, acrylic acid grafted starch, and isobutylene maleic anhydride copolymers and mixtures thereof. The hydrogel polymers are preferably lightly reinforced to make the material substantially water insoluble. The designated superabsorbent materials are further surface-reinforced so that the outer surface or shell of the superabsorbent particle, fiber, flake, sphere, etc. have a higher cross-link density than the inner portion of the superabsorbent. The superabsorbent materials can be in any form suitable for use in absorbent compositions including particles, fibers, flakes, atmospheres, and the like.
    Preferably, the absorbent comprises a non-woven backing according to the present invention. "Diaper" refers to an absorbent article generally worn by infants and incontinent persons on the lower torso. "Disposable" is used herein to describe absorbent articles that are generally not intended to be washed or otherwise repaired or reused as an absorbent article (ie, they are intended to be discarded after single use and, preferably, to be discarded). recycled, composted or disposed of in another environmentally compatible way). "Non-woven" refers to a manufactured sheet, web, or batch of directionally or randomly oriented fibers bonded by friction and / or cohesion and / or adhesion, excluding paper and products that are woven, knitted, sewn with binding yarns or threads, or felted by grinding in the wet state, whether or not additionally punctured. The fibers can be of natural or artificial origin. They may also be interrupted or continuous fibers or formed in situ.
    The term "top sheet" refers to a liquid-permeable fabric material that forms an inner cover of the absorbent article and which, in use, is placed in direct contact with the wearer's skin. The top sheet may consist of a non-woven material, e.g. spunbond, melt spider, carded, water entangled, wetlaid, etc. Suitable non-woven materials may be composed of artificial fibers such as polyester, polyethylene, polypropylene, viscose, rayon etc. or natural fibers such as wood pulp or cotton fibers, or of a mixture of natural and artificial fibers. Further examples of top sheet materials are porous foam, apertured plastic films, laminates of non-woven materials and apertured plastic films, etc. The materials suitable as top sheet materials should be soft and non-irritating to the skin and easily permeable to body fluids, e.g. urine or menstrual fluid. The inner cover sheet may further be different in different parts of the absorbent article. The "back sheet" refers to a material that forms the outer cover of the absorbent article. The back sheet can be the same or different in different parts of the absorbent article. At least in the area of the absorbent, the back sheet consists of a liquid impermeable material in the form of a thin plastic film, e.g. a polyethylene or polypropylene film, a non-woven material covered with a liquid impermeable material, a hydrophobic non-woven material that resists liquid penetration, or a laminate of a plastic film and a non-woven material. The back sheet material can be air permeable to allow vapor to escape from the absorbent material, while still preventing liquids from passing through there. Examples of air-permeable back sheet materials are porous polymer films, non-woven laminates of spunbond and melt-spin layers and laminates of porous polymer films and non-woven materials.
    The "staple fibers" refer to commercially available fibers that have filaments with diameters ranging from less than about 0.001 mm to more than about 0.2 mm; they come in various different forms such as short fibers extending from about 10 to 50 mm in length and long fibers with a length higher than 50 mm, preferably up to 100 mm.
    The "spin bonded fibers" generally refer to continuous fibers that can be produced by the extrusion of molten polymer from either a large spin cap that has several thousands of holes per meter of width or with banks of smaller spinnerets, for example, containing so little as 40 holes. After coming out of the spin cap, the molten fibers are extinguished by a cross flow air extinguishing system, then pulled away from the spin cap and slowed down by the high speed air. The average diameter of spunbond fibers is typically in the range of 15-60 µm or higher.
    The stack and / or spunbonded fibers for use in the invention can be prepared from light and / or heavy fibers, preferably polypropylene and / or polyester fibers. The light fibers have a dtex below 3, preferably in the range of 1 to 3, while the heavy fibers have a dtex of at least 3 and preferably lighter than dtex 45. For the case that a mixture of light and heavy fibers is used, the heavy fibers preferably have a dtex value that is at least twice, but not greater than 15 times, than that of the light fiber.
    The "water entanglement process" refers to the production of a non-woven web. The process involves directing a series of water jets to a fibrous web that is supported by a moving porous belt. The water jets go down through the mass of fibers and when making contact with the surface of the belt, the jets turn and break up: the released energy causes the mass of fibers to become entangled. "Superabsorbent polymer particles" refer to water-swellable, water-insoluble organic or inorganic materials capable of absorbing, in the most favorable conditions, at least about 10 times their weight, or at least about 15 times their weight, or at least about 25 times their weight in an aqueous solution containing 0.9% sodium chloride by weight. In absorbent articles such as diapers, incontinent diapers, etc ..., the particle rootte preferably extends between 100 to 1500 μηη or further, preferably between 100 and 800 μηη, preferably between 300 to 600 μm, more preferably between 400 to 500 μηη.
    FIG. 1 and 2 shows two embodiments of an absorbent article according to the present invention. FIG. 1 is a general schematic cross-sectional view of the absorbent article while FIG. 2 is a detailed part of the schematic cross-sectional view of FIG. 1 showing the lower part of the absorbent article.
    The inventors have found a way to provide an improved absorbent core and a process to make such a core.
    In particular, in a first aspect, the present invention provides an absorbent core (18) including a nonwoven support (1) for immobilizing superabsorbent polymer particles (28) in an absorbent article consisting of a top layer (7) consisting of staple and / or spunbonded fibers (19) permeable to the superabsorbent polymer particles, which is preferably mechanically bonded to the top layer (Fig. 1). The absorbent core (18) is packaged between two layers of non-woven, the so-called core wrap. Lower core wrap (5) is attached to bottom layer (8) of non-woven backing (1) by thermoplastic adhesive (9). Higher core wrap (4) is attached to the upper surface of non-woven backing (1) by thermoplastic adhesive (10). The superabsorbent polymer particles (28) may be partially in contact with the self-adhesive cover layer (10) on top core wrap (4).
    In a preferred embodiment, the widths of the core wrap nonwovens exceed the width of the nonwoven support (1), so that the core wrap nonwovens can be bonded to each other along the side edges by thermoplastic adhesive (14).
    In a preferred embodiment, a non-woven wrap is at least partially and preferably fully folded around the core and sealed on top or bottom.
    In a preferred embodiment, a head-shape configuration is provided whereby the side edges of the lower core wrap are folded on top of the core.
    In an alternative embodiment, no core change is provided.
    On top of the absorbent core (18), an acquisition and distribution layer (6) is placed which is fixed by thermoplastic adhesive (11). Preferably, the ADL (6) is based on Nonwovens Innovation & Research Institute's proprietary Hydrospace technology as described in EP 1644564A1. Note, however, that any type of self-adhesive application known in the prior art could be used to attach the ADL to other components or layers of an absorbent article. In particular, adhesion can be obtained by gluing, such as by contact coverage with full coverage or partial coverage, e.g. in stripes, or by mist coverage, e.g. random mist coverage or along a pattern, continuous or interrupted, e.g. by non-continuous lines of a spiral mist. Adhesion can also be obtained by alternative binding techniques, such as thermal binding, thermo-mechanical binding, mechanical binding and / or ultrasonic binding.
    The absorbent core (18) and ADL (6) are covered by a non-woven topsheet (23) connected to the underlying components with a layer of thermoplastic adhesive (24), by thermal bonding and / or by ultrasonic bonding.
    The non-woven support (1) according to the invention provides at least a two-layered structure with very different properties (Fig. 2). The highest layer (7) is porous, soft and bulky. In contrast, the bottom layer (8) has much smaller pores than the super-absorbent polymer particles and serves as a barrier. The pore size of bottom layer (8) is smaller than the particle size of the superabsorbent polymer particles, thereby preventing the particles from falling through the material. The particle size of the particles is preferably between 100 to 800 µm. In addition, the bottom layer (8) has a higher mechanical strength, adding robustness to the non-woven support (1). As a result, the superabsorbent polymer particles are confined within the stack of fibers (19) of top layer (7), which prevents them from moving in the longitudinal and transversal direction (x-y plane) of the absorbent article. Furthermore, the superabsorbent polymer particles (28) are prevented from falling through the material, i.e., kept from moving in a cross-sectional direction (z-direction).
    In a preferred embodiment, the bottom layer is a spunbonded fabric, preferably a spunbond meltblown spunbonded fabric. The term "spunbond meltblown spunbond" (SMS) nonwoven fabric as used herein refers to a multilayer composite fabric consisting of a web of meltblown fibers sandwiched between and bonded to two spin bonded layers.
    A non-woven fabric of SMS can be formed in-line by depositing a first layer of spin-bonded fibers, a layer of melt-blown fibers, and a second layer of spin-bonded fibers sequentially on a moving porous collection surface. The assembled layers can be bonded by allowing them to pass through a small opening formed between two rollers that may be heated or unheated and smooth or patterned. Alternately, the individual spin bonded and melt blown layers can be preformed and optionally bonded and collected individually such as by winding the fabrics on rolls. The individual layers can be assembled at a later date and bound together to form an SMS non-woven fabric. Extra spin-bonded and / or melt-blown layers can be incorporated into the SMS fabric, for example spin-bonded-melt-blown-melt-blown-spin bonded, etc.
    This multi-layer composite fabric product adds strength to the overall composition due to the outer layers of the SMS or SMMS non-woven fabric that provides barrier properties. The spin-bonded bottom layer (8) serves as effectively as a barrier for the super-absorbent polymer particles (28), but also adds robust mechanical properties to the non-woven support (1). As a result, the nonwoven carrier (1) can be converted to roll goods on a diaper machine without experiencing winds or tear problems, even at high line speed, e.g. 7 m / s. Due to the high resilience of the applied fibers (19), both by bonding with the bottom layer (8), the top layer (7) is likely to regain its bulk and porous state even after being rinsed and compressed on a role. As a result, the superabsorbent polymer particles (28) can penetrate and become entangled between the fibers (19), rather than simply lying on the surface of top layer (7). Bottom layer (8) serves as a barrier so that the superabsorbent polymer particles (28) are, for a large part, confined within the nonwoven support (1). SMS or SMMS nonwovens are typically composed of a thermoplastic polymer, such as polypropylene, which causes nonwoven to be naturally hydrophobic. As a result, the SMS or SMMS nonwovens are treated with a topical hydrophilic treatment to increase absorption, such as a capillary-active surface treatment. In a preferred embodiment, the grammage of the top layer (7) is 30 gsm.
    In a preferred embodiment, the grammage of the top layer (7) is at least 1 gsm, preferably at least 5 gsm, more preferably at least 10 gsm, more preferably at least 15 gsm, more preferably at least 20 gsm, and / or at preferably at most 200 gsm, more preferably at most 100 gsm, more preferably at most 50 gsm, more preferably at most 40 gsm, e.g. 20, 25, 30, 35, 40 gsm, most preferably about 30 gsm.
    In a preferred embodiment, the grammage of bottom layer (8) is 8 gsm.
    In a preferred embodiment, the grammage of bottom layer (8) is at least 0.5 gsm, preferably at least 1 gsm, more preferably at least 2 gsm, more preferably at least 3 gsm, more preferably at least 4 gsm, more preferably at least 5 gsm and / or preferably at most 50 gsm, more preferably at most 40 gsm, more preferably at most 30 gsm, more preferably at most 20 gsm, more preferably at most 12 gsm, e.g. 5, 6, 7, 8, 9, 10, 11, 12 gsm, most preferably about 8 gsm.
    In a preferred embodiment, the stack of fibers consists of a mixture of two types of fibers, preferably polyester fibers, polyethylene fibers and / or polypropylene fibers. Preferably, a first type of fiber is short, more preferably shorter than 50 mm, even more preferably shorter than 47 mm, even more preferably shorter than 43 mm, even more preferably shorter than 40 mm, most preferably preferably about 38 mm, and / or the above-mentioned first type of fibers is fine, more preferably thinner than 3 dtex, even more preferably thinner than 2.5 dtex, even more preferably thinner than 2 dtex, even more preferably thinner than 1.5 dtex, most preferably about 1.3 dtex. Also preferred, a second type of fiber of the above two types is long, more preferably longer than 50 mm, even more preferably longer than 55 mm, even more preferably longer than 60 mm, even more preferably longer than 65 mm , most preferably about 68 mm, and / or the above-mentioned second type of fibers is rough, more preferably thicker than 3 dtex, even more preferably thicker than 4 dtex, even more preferably thicker than 5 dtex, even more preferably thicker than 6 dtex, most preferably about 6.7 dtex. In a particular preferred embodiment, the above-mentioned first type of fibers is short and fine, most preferably about 38 mm and 1.3 dtex and the second type of fibers is long and rough, most preferably about 68 mm and 6.7 dtex.
    In a more appropriate embodiment, the mixture consists of between 10% and 50%, more preferably between 20% and 40%, even more preferably between 25% and 35%, most preferably from about 30% of the first type of fibers and / or 50% to 90%, more preferably between 60% and 80%, even more preferably between 65% and 75%, most preferably about 70% of the second type of fibers.
    Preferably, the stack of fibers consists of a substantially round cross-section, a substantially trilobic cross-section and / or a substantial quadrilobic cross-section.
    In a preferred embodiment, the nonwoven carrier is rolled up and thereby typically compressed. The non-woven support devoid of superabsorbent polymer particles can be transported better at this stage. The composition of top layer (7) provides good recovery after compression. In a preferred embodiment, top layer (7) consists of a mixture of two different types of pile fibers: one type is short and fine, while the other type is long and rough. In a preferred embodiment, top layer (7) is mechanically bonded to bottom layer (8) by water entanglement. The short and fine fibers included in the top layer (7) are particularly advantageous to achieve good bonding strength between top layer (7) and bottom layer (8) during the water entanglement process. Preferably, the short and fine fibers have a shrink frequency of 12 / cm, and the long and raw fibers have a shrink frequency of 3.5 / cm. The recovery after compression of high loft non-woven fabrics can be determined with the EDANA standard method WSP 120.R4 (12). In a preferred embodiment, the recovery of the nonwoven support (1) according to this method is greater than 90%.
    In a preferred embodiment, the nonwoven support consists of superabsorbent polymer particles that are at least partially immobilized by the pile of fibers and retained by the bottom layer. The superabsorbent polymer particles are trapped within the fibers. That limits their movement within the absorbent article, both in the longitudinal and transversal directions (x-y plane) as well as up and down (z direction). The bottom layer serves as an additional barrier. The average pore size of the bottom layer is smaller than the average particle size of the superabsorbent polymer particles, so that even the fine fraction of the particles is prevented from falling through the material. The size of superabsorbent polymer particles depends on the precise application, but for absorbent articles such as a diaper, the major fraction ranges between 100 to 800 μηη, preferably between 300 to 600 μηη, more preferably between 400 and 500 μηη.
    Therefore, in a preferred embodiment, the bottom layer has a pore size of less than 300 μηη, more preferably less than 100 µm, even more preferably less than 50 µm, even more preferably less than 25 µm, even more preferably less than 10 µm µm, thereby retaining the superabsorbent polymer particles. In a more preferred embodiment, the above-mentioned SAPs are divided into a pattern, preferably the above-mentioned pattern consists of areas that are substantially free of SAPs, such as a grouped pattern. Such SAP-free zones are mentioned in the cross-sectional views of Figs. 1 and 2 as zones (30).
    In a preferred embodiment, the non-woven backing, the bottom layer and / or the top layer are hydrophilic. The nonwoven support, the bottom layer and / or the top layer can of course be hydrophobic because they can be composed of polypropylene and / or polyester, respectively; the nonwoven support, the bottom layer and / or the top layer can be treated with a, preferably topical, hydrophilic treatment to increase absorption, such as a surface active treatment.
    In a second aspect, the invention provides an absorbent article consisting of a non-woven backing according to an embodiment of the invention.
    In a third aspect, the invention provides a process for manufacturing a non-woven backing according to an embodiment of the invention, comprising the steps of: providing a non-woven bottom layer in which the bottom layer is porous with a pore size smaller than that of the pore size superabsorbent polymer particles and a top layer consisting of staple and / or spunbond fibers, and the bonding, such as thermal bonding, bonding by melting by heat or pressure or ultrasonic, bonding by needle felting, chemical bonding and / or bonding by adhesives, preferably mechanically bonding the stack and / or spunbond fibers to the non-woven bottom layer thereby providing the non-woven support. In a preferred embodiment, the soil layer and the pile and / or spunbond fibers are bound by water entanglement.
    In a preferred embodiment, the process provides a way to distribute superabsorbent polymer particles over the support structure of the invention. Rather than simply being on the surface of the top layer, the superabsorbent polymer particles will also be trapped within the fibers. Their distribution is limited by the bottom layer. Its density prevents the particles from falling through the material. The superabsorbent polymer particles (28) are arranged in a pattern of individual clusters (15) (Figs. 3a-g). In a preferred embodiment, those clusters (15) are rectangles, but other cluster shapes and patterns are also possible. Other patterns are shown in Figs. 3a-g. Along the SAP-free zones (16), upper core wrap (4) is attached to the top layer (7) of non-woven backing (1) by thermoplastic adhesive (10). In the dry state, the superabsorbent polymer particles (28) are contained in bag-like compartments. In the wet state, to allow full swelling of the superabsorbent polymer particles (28), those bag-like compartments are no longer maintained. This is due to two consequences: the self-adhesive connections between the pile of fibers (19) and the higher core wraps (4) partially break up, and the pile of fibers (19) are loosely bonded to the bottom layer (8), ie the free fiber length between connecting points is quite long; as a result, even if the self-adhesive connections to the upper core cover (4) remain intact, the pile of fibers (19) do not exert considerable force against the volume expansion of the absorbent core (18). The wet immobilisation (ie, immobilisation of superabsorbent polymer particles when the disposable diaper and thus the nonwoven carrier is at least partially wetted) is improved due to entanglement between the top layer of fibers (19) of nonwoven carrier (1) and due to a portion of the superabsorbent polymer particles (28) that still adhere to the thermoplastic adhesive (10) on top core wrap (4).
    In a preferred embodiment, the process further comprises the step of treating a nonwoven support (1), the bottom layer (8) and / or the top layer (7) with a surfactant after the water entanglement process. The nonwoven support (1), the bottom layer (8) and / or the top layer (7) are rendered hydrophilic by the use of a post-treatment application of a surfactant. The hydrophilic characteristics of the nonwoven support (1), the bottom layer (8) and / or the top layer (7) improve the wettability, and thus improve the absorbency when the support is employed for absorbent articles such as baby diapers or adult incontinence diapers.
    In a preferred embodiment, the top layer (7) is made of stack of fibers provided in the form of a preformed carded web, or the stack of fibers are fed directly in the water entanglement process. The pile of fibers are preferred for the top layer (7) because the carded process of web formation is known to produce particularly bulky non-woven web. However, the top layer (7) can also be made from spun or spunbonded filaments that are bonded to the preformed bottom layer (8) by any non-woven binding process known in the prior art, preferably by a water entanglement process. Alternatively, for the top layer (7), it is possible to use bicomponent fibers where one of the components has a lower melting point than the other component, e.g. PE / PP, and a heat transfer step, e.g. by hot air or an infrared lamp, in the process. In that case, bottom layer (8) would also include similar bicomponent fibers, so that top layer (7) and bottom layer (8) are bonded as a result of the softening of the lower melting point polymers. The bicomponent fibers may have core / sheath or side / side or other configurations known in the prior art. It is preferable to use a side / side configuration because in that case the fibers will reach a pleated state through the heat transfer process. Instead of a bicomponent pile of fibers, the top layer (7) can also be made from bicomponent spun or spin-bound filaments
    In a preferred embodiment, the process further comprises the step of rolling up the nonwoven carrier.
    In a further aspect, the invention provides a process for manufacturing an absorbent article according to an embodiment of the invention, comprising the steps of: providing a nonwoven support according to an embodiment of the invention and providing the top layer with the non-woven support of superabsorbent polymer particles to produce an absorbent article.
    In a final aspect, the invention provides a use of a nonwoven support according to an embodiment of the invention for immobilizing superabsorbent polymer particles in an absorbent article, in particular in a diaper.
    Figs. 4 and 5 are top views of disposable diapers of a pants-type (adult) incontinence diaper and a baby diaper according to a particular embodiment of the present invention. The disposable diaper is shown out in its extended, uncontracted state (i.e., without elastic induced contraction). The central portion of the disposable diaper (27) is shown which is limited by the outer portion of the disposable diaper (29). The superabsorbent polymer particles (28) can be substantially continuous or grouped within the central portion of the disposable diaper (27).
    Although the present invention has been described with respect to preferred embodiments thereof, many modifications and alternations can be made by a person having ordinary skill in the art without departing from the scope of this invention as defined by the appended claims .
    权利要求:
    Claims (15)
    [1]
    CONCLUSIONS
    A nonwoven support for immobilizing superabsorbent polymer particles in an absorbent article, which comprises a non-woven top layer, preferably comprising fibers and / or spunbond fibers, permeable to the particles and a non-woven bottom layer, wherein said top layer is bonded, wherein the bottom layer is porous with a pore size smaller than the above particles.
    [2]
    The non-woven backing of claim 1, wherein the top layer is a carded non-woven made of staple fibers or wherein the top layer comprises spun filaments.
    [3]
    The nonwoven support of any of the preceding claims, wherein said top layer is mechanically bonded, thermally bonded, bonded by heat or pressure melting or ultrasonic, bonded by needle felting, chemically bonded and / or bonded by adhesives, to preferably mechanically bound, more preferably connected by water entanglement to the bottom layer.
    [4]
    The nonwoven support of any of the preceding claims, wherein the bottom layer is a spin bonded fabric, preferably a spin bonded meltblown spin bonded fabric.
    [5]
    The nonwoven carrier of any of the preceding claims, wherein the grammage of the top layer (7) is between 1 to 200 gsm, preferably 5 to 100 gsm, more preferably 10 to 50 gsm, most preferably 15 to 40 gsm and the grammage of the bottom layer (8) is between 0.5 to 50 gsm, preferably 1 to 40 gsm, more preferably 2 to 30 gsm, more preferably 3 to 20 gsm, most preferably 4 to 12 gsm and / or wherein the fiber stack is a mixture of at least two types of polyester, polyethylene and / or polypropylene fibers, preferably comprising at most 50% of a first type of fibers that are short and light, and preferably comprising at least 50 % of a second type of long and heavy fibers.
    [6]
    The nonwoven support according to any of the preceding claims, comprising superabsorbent polymer particles that are at least partially immobilized by the fiber stack and retained by the bottom layer.
    [7]
    The nonwoven support according to any of the preceding claims, wherein the bottom layer has a pore size of less than 100 µm.
    [8]
    The non-woven backing according to any of the preceding claims, wherein the non-woven backing, the bottom layer and / or the top layer are hydrophilic.
    [9]
    An absorbent article comprising a nonwoven support according to any of claims 1 to 8.
    [10]
    A process for manufacturing a nonwoven support according to any of claims 1 to 8, comprising the steps of: providing a nonwoven bottom layer in which the bottom layer is porous with a pore size smaller than that of the superabsorbent polymer particles and a top layer comprises fibers and / or spunbond fibers, and the joining, preferably mechanically, more preferably by water entanglement, of the fibers to the non-woven bottom layer, thereby providing the non-woven support.
    [11]
    The process of claim 10, further comprising the step of treating the non-woven backing, the bottom layer and / or the top layer with a surfactant.
    [12]
    The process according to any of claims 10 to 11, wherein the stack of fibers is provided in the form of a preformed carded web and / or the stack of fibers are fed directly into the water entanglement process.
    [13]
    A process according to any of claims 10 to 12, comprising the step of rolling up the nonwoven carrier.
    [14]
    A process for manufacturing an absorbent article according to claim 9, comprising the steps of: providing a nonwoven support according to claims 1 to 8, providing the top layer of the nonwoven support with superabsorbent polymer particles to produce an absorbent article .
    [15]
    Use of a nonwoven support according to any of claims 1 to 8 for at least immobilizing superabsorbent polymer particles in a diaper.
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    同族专利:
    公开号 | 公开日
    EP3085346B1|2018-03-28|
    EP3085346A1|2016-10-26|
    ES2584181T3|2016-09-26|
    EP3348246A1|2018-07-18|
    EP2901991A1|2015-08-05|
    ES2667216T3|2018-05-10|
    EP2901991B1|2016-04-27|
    BE1022371B1|2016-03-25|
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    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    EP14153467.7A|EP2901991B1|2014-01-31|2014-01-31|Nonwoven carrier for absorbent article|
    EP14153467.7|2014-01-31|
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