GLAZING SUBSTRATE WITH INTERFERENTIAL COLORING FOR A PANEL.

专利摘要:
An interferentially colored glass substrate for a cladding panel comprising a glass sheet covered on one of its faces by a stack of coatings comprising successively at least: a first transparent coating of dielectric material of optical thickness at least greater than or equal to 5.0 nm and not more than 258.0 nm, a semitransparent functional coating of geometrical thickness not less than 0.1 nm and not less than 50.0 nm, a second transparent coating of dielectric material of a thickness not less than or equal to 20.0 nm and at most less than or equal to 300.0 nm, a coating providing opacity or quasi-opacity of geometric thickness at least greater than or equal to 30.0 nm.
公开号:BE1020182A3
申请号:E2011/0472
申请日:2011-07-29
公开日:2013-06-04
发明作者:Vincent Moens；Stijn Mahieu
申请人:Agc Glass Europe；
IPC主号:

专利说明:

Interferential staining glass substrate for facing panel 1. Field of the invention
The present invention is in the technical field of glass substrates with interferential coloration.
More specifically, the invention relates to a glass substrate interferential coloring for facing panel and its manufacturing process and its use.
The interferentially colored glass substrate for facing panel referred to in the present invention may more particularly be used as a glass substrate for facade cladding panel, also called a spandrel. The spandrel according to the present invention is more particularly in the form of a single sheet monolithic spandrel. It can alternatively be used as a decorative cladding panel, or even as a decorative reflective panel, for interior or exterior applications such as shelf elements, cupboard, door, ceiling lamp, support, glass table, wall lamp, partition, storefront,. ..
2. Solutions of the prior art
An interferentially colored glass substrate for facing panel, generally consists of a glass sheet on which is deposited a stack of coatings among which there are at least three different types of coatings: • so-called functional coatings which contribute mainly to the properties optical protective coatings, • protective coatings, generally made of transparent dielectric materials, whose role, in addition to providing chemical and / or mechanical protection of functional coatings, is to allow the construction of optical cavities • at least one coatings enamel or paint providing opacity or quasi-opacity of the stack of coatings, the enamel coating or paint being deposited, with respect to the glass sheet, at the top of the stack of coatings.
The colorimetric contribution of enamel or paint coating ensuring the opacity or quasi-opacity of the coating stack is mainly due to its chemical composition. The term "interferential coloration" is intended to denote a coloration obtained wholly or mainly by reflection and refraction phenomena of the light incident on the various thin coatings constituting the stack of coatings. By the term "colorimetric contribution" is meant the contribution to the color of the glass substrate perceived by an observer. By the terms "opacity or quasi-opacity of said stack" is meant that the light transmission rate is at most 4%, preferably at most 2%, more preferably at most 1.0. %, most preferably at most 0.1%, when said stack is applied to a 4 mm thick clear silico-sodo-calcium float glass, measured with a source in accordance with the illuminant "daylight" »Standardized D65 by the CIE and at a solid angle of 2 °, according to the EN410 standard.
The interferentially colored glass substrate for facing panel may more particularly be used as a glass substrate for facade cladding panel, also called a spandrel, the spandrel is more particularly in the form of a single sheet monolithic spandrel.
A fully glazed facade includes two zones, a viewing zone corresponding to the locations of the windows and an opaque zone typically corresponding to facade cladding panels, also called lighters. Facade cladding panels are in fact made of glass sheets which are opaque or quasi-opaque. The opacity or quasi-opacity of the glass sheets is provided by an enamel coating or a paint. Facade cladding panels because of their opacity or near-opacity are generally used to conceal or mask all or part of the non-aesthetic parts of a structure or building. For example, facade cladding panels can be used to conceal floor slabs, air conditioning equipment, heating pipes, etc.
Facade cladding panels, for reasons of cost and space, are installed directly on the structure or building to be covered. Such an installation causes increased problems of corrosion of the stack of coatings of the interferentially colored glass substrate constituting the facade cladding panel. It is therefore required a durability of the stack of coatings of the interferentially colored glass substrate constituting the facade cladding panel. This requirement of durability is both a physicochemical requirement, related to quenching and insensitivity to chemical and atmospheric agents (for example corrosion resistance), a mechanical requirement, related to the resistance claws for example when storing, handling or installing facade cladding panels.
In addition in the building sector, it is desirable, and even necessary, for security reasons, to use tempered glass sheets for the production of interferentially colored glass substrates for façade cladding panels. The quenching process consists in bringing the glass to an elevated temperature, higher than 600 ° C., followed by a rapid temperature drop so as to create mechanical stresses inside the glass. Preferably, for reasons of industrial viability, the quenching of the glass sheet constituting the interferentially colored glass substrate for facade cladding panel is not performed prior to the manufacture of said substrate but directly on it. It is therefore necessary that all the materials constituting the interferentially colored glass substrate constituting the facade cladding panel support the quenching process. In addition, it is sometimes desirable for the interferentially colored glass substrate constituting the facade facing panel to be subjected to a bending treatment in order to impart a curvature to said substrate, it is therefore essential that the interferential colored glass substrate for facade cladding panel can withstand such treatment without degradation of its properties.
Finally, a problem posed by the concomitant use of windows and facade cladding panels on a structure or building is related to the visual harmony of the window-facade cladding assembly when the building or structure is seen from the outside. This problem is increased when the facade is fully glazed. Indeed, for aesthetic reasons, it is desired that the viewing areas, corresponding to the windows, and the opaque areas, corresponding to the locations of the facade facing panels, located between the viewing areas, have the same appearance, it is ie the same color for the same angle of observation between 0 ° and 60 °, preferably for the same angle of observation between 0 ° and 55 °.
These same problems may arise for decorative cladding panels for interior or exterior applications. Thus, they may also require durability of the stack of coatings (for example vis-à-vis glues used to glue the panels or scratch resistance); they too, for certain applications, must be able to be tempered (for example for shelves); and they too must be able to present a visual harmony (for example, in a shop, a shelf, a table and a panel glued to the wall must be able to show the same aspect, the same color, regardless of the angle of observation).
Solutions for making such interferential colored glass substrates for facing panels have been proposed previously. In the patent application WO2007 / 008868 A2, there is disclosed a glass substrate comprising a glass sheet successively covered with a titanium dioxide coating, a silicon nitride coating all covered by an opaque colored coating, said opaque colored coating being obtained by applying enamel or paint. The absence of a titanium-based metallic functional coating inserted between the titanium dioxide and the silicon nitride makes it possible to remedy the problem related to the degradation of this functional coating during the quenching heat treatment. However, such glass substrates impose as a constraint the use of an opaque coating enamel or paint. The use of enamels or paints deposited directly on the stack of coatings can present a number of problems such as: • compatibility problems such as chemical reactions between the constituents of the enamel or paint and the coatings constituting the stack, • the use of an additional step of enamelling or application of a paint directly on the stack of coatings increases the risk of scratching said stack of coatings, • the use of a enamel poses the problem of the cooking of this enamel, this particularly sensitive step may lead to problems of porosity of the enamel coating which may lead to delamination thereof, or even to a problem of reproducibility of the colors obtained during the final production of the enamel. glass substrate for facade or siding panel, • enamel or paint used as opaciform coating This contribution is such that it considerably reduces the number of stacking structures of functional coatings and protective coatings able to give the desired color, • the choice of enamel allowing to obtain a desired color is limited.
3. OBJECTIVES OF THE INVENTION The object of the invention is notably to overcome these disadvantages of the prior art.
More specifically, an objective of the invention, in at least one embodiment, is to provide a glass substrate with interferential coloration for facing panel, having a good physicochemical and mechanical behavior. More specifically, it is a question of providing a facing panel compatible with a monolithic use and likely to be exposed in an external environment.
An objective of the invention, in at least one of its embodiments, is to provide a glass substrate with interferential coloration, said substrate being preferably monolithic, for facing panel which is particularly "hardenable".
The invention, in at least one of its embodiments, also has the objective of providing a glass substrate with interferential coloration, said substrate being preferably monolithic, for facade facing panel capable of visually matching with a glazing layer constituting the part corresponding to the windows in a facade for the same angle of observation between 0 ° and 60 °, more particularly for the same angle of observation between 0 ° and 55 ° C, said facing panel not requiring the use of enamel or paint.
4. Presentation of the invention
According to a particular embodiment, the subject of the invention is an interferentially colored glass substrate for facing panel.
According to the invention, such an interferentially colored glass substrate for facing panel comprises, consists, consists essentially of a glass sheet, preferably a single glass sheet, covered on one of its faces by a stack of coatings such as said stack of coatings comprises successively from the glass sheet at least: a first transparent coating of dielectric material, the optical thickness of the first transparent coating being at least greater than or equal to 5.0 nm, preferably at least greater than or equal to 10.0 nm, more preferably at least greater than or equal to 20.0 nm, most preferably at least 50.0 nm or more, more preferably at least 70.0 nm, more preferably at least greater than or equal to 70.0 nm, equal to 100.0 nm, most preferably at least greater than or equal to 110.0 nm and at most greater than or equal to 258.0 nm, preferably not more than 190.0 nm, more preferably less than or equal to 180.0 nm, most preferably not more than 150.0 nm, more preferably less than or equal to 120.0 nm. Preferably, the optical thickness being in the range of values ranging from 5.0 nm, preferably from 10.0 nm, more preferably from 20.0 nm to 258.0 nm, preferably from 50.0 nm to 190.0 nm. nm, more preferably from 70.0 nm to 180.0 nm, most preferably from 100.0 nm to 150.0 nm, preferably from 110.0 to 120.0 nm, a semi-transparent functional coating, the geometric thickness of the semi-transparent functional coating being at least greater than or equal to 0.1 nm, preferably at least greater than or equal to 0.3 nm, more preferably at least greater than or equal to 0.5 nm and at the lower or equal to 50.0 nm, preferably at most 25.0 nm or less, preferably the geometrical thickness is in the range of values ranging from 0.1 nm, preferably 0.3 nm, to 50 nm. , 0 nm, preferably from 0.5 nm to 25.0 nm, preferentially said semi-transparent functional coating having an absorption of between 10% and 70%, • a second transparent coating of dielectric material, the optical thickness of the second transparent coating being at least 20.0 nm or greater, preferably at least greater than or equal to 20.0 nm equal to 30.0 nm, more preferably at least greater than or equal to 100.0 nm, most preferably at least greater than or equal to 150.0 nm, more preferably greater than or equal to 170.0 nm and at most less than or equal to 300.0 nm, preferably at most less than or equal to 250.0 nm, more preferably at most less than or equal to 210.0 nm, most preferably at most less than or equal to 200.0 nm, preferably the optical thickness is in the range of values from 20.0 nm, preferably from 30.0 nm, more preferably from 100.0 nm to 300.0 nm, more preferably 150 0 nm to 250.0 nm, most preferably 170.0 to 200.0 nm.
A coating ensuring opacity or quasi-opacity of said stack, the geometric thickness of said coating providing opacity or quasi-opacity being at least 30.0 nm or greater, preferably at least 50 or more; , 0 nm, more preferably at least greater than or equal to 100.0 nm, the geometric thickness of the coating providing the opacity or the quasi opacity being at most less than or equal to 1000.0 nm, preferably at most less than or equal to 200.0 nm. Preferably, the geometric thickness of said coating is in the range of values ranging from 30.0 nm to 1000.0 nm, preferably from 50.0 nm to 1000 nm, most preferably from 100.0 nm to 200.0 nm, said coating providing opacity or near opacity comprising at least one metal, a metalloid, a nitride or a carbide.
The optical thickness of a coating is obtained by multiplying the geometric thickness of said coating by the refractive index of the material constituting said coating. The value of the refractive index considered is the value of said index at a wavelength of 550 nm.
The general principle of the invention rests firstly on the substitution of the enamel or paint-based coating with an opaque or quasi-opaque coating having a geometric thickness at least greater than or equal to 30.0 nm and of on the other hand, forming an optical cavity formed from the glass sheet of at least a first transparent dielectric coating, a semi-transparent functional coating, a second transparent dielectric coating and a coating ensuring the opacity or quasi-opacity of said stack and to obtain a desired color. The substitution of the coating based on enamel or paint with a coating ensuring the opacity or quasi-opacity of the stack requires an adaptation of the optical cavity in terms of thickness of the various coatings constituting it. The coloration of the interferential substrate results from the optical cavity formed of at least a first transparent dielectric coating, a semitransparent functional coating, a second transparent dielectric coating and a coating ensuring opacity or near-darkness. opacity of said stack. The coloring is related to the thicknesses and compositions of the first transparent dielectric coating, the semi-transparent functional coating, the second transparent dielectric coating and the coating ensuring the opacity or quasi-opacity of the stack.
Thus, the invention is based on a completely new and inventive approach. The inventors have in fact determined that, surprisingly, the substitution of the enamel or paint-based opacifying coating with an opaque or quasi-opaque coating having a geometrical thickness greater than or equal to 30.0 nm makes it possible to simplify the manufacture of the substrates. interferentially colored glass, said substrate being preferably monolithic, for facing panel by avoiding the use of a painting or enamel application step and problems related to this step. The invention makes it possible to avoid: • compatibility problems such as chemical reactions between the constituents of enamel or paint and the coatings constituting the stack of coatings, • the use of an additional step enamelling or application of a paint directly on the stack of coatings increases the risk of scratching of said stack, • the use of an enamel posing problems: o the cooking of this enamel, this particularly sensitive step may cause porosity problems in the enamel coating which may lead to delamination of the enamel, where the enamel or paint used as an opacifying coating has a significant contribution to the perceived color, this contribution is such that it reduces considerably the number of stacks of functional coatings and protective coatings able to give the desired color. In addition, the choice of enamel to obtain a desired color is limited.
The geometric thickness of the coating providing the opacity or quasi-opacity is advantageously greater than or equal to 100.0 nm, the inventors having determined that such a thickness makes it possible, in addition to guaranteeing the opacity or quasi-opacity of the panel. facing, to obtain better insensitivity vis-à-vis chemical and atmospheric agents (eg corrosion resistance). The geometric thickness of the coating ensuring opacity or quasi-opacity is advantageously in the range of values ranging from 100.0 nm to 200.0 nm, such a thickness making it possible to obtain a good insensitivity vis-à-vis chemical and atmospheric agents while allowing to obtain deposition times of said coating which are as low as possible.
By the term "transparent coating" is meant a coating that is transparent at the wavelengths of visible light. By the term "transparent" is meant that the light transmission rate is at least 50% when the coating is applied to a sheet of clear silico-soda-lime float glass of 4 mm geometric thickness, measured with a source conforming to the standard D55 "daylight" illuminant by the CIE and at a solid angle of 2 °, according to the EN410 standard.
The term "semitransparent functional coating" is intended to denote a semi-transparent functional coating at the wavelengths of visible light. By the term semi-transparent, it is meant that the light absorption rate is in the range of values from 10% to 70% when the coating is applied to a clear silico-soda-lime float glass sheet of 4 geometrical thickness mm, measured with a source conforming to the standard daylight illuminant D65 by the CIE and at a solid angle of 2 °, according to the EN410 standard.
The material constituting at least one layer of the first transparent dielectric coating comprises at least one oxide or nitride or an oxynitride. The oxide is selected from oxides of silicon, aluminum, titanium, zirconium, yttrium, hafnium, niobium, tin, tantalum, zinc and mixed oxides of at least two of them, preferentially among oxides of silicon, aluminum, titanium and mixed oxides of at least two of them, the preferred oxide being silicon oxide. The advantage of using silicon oxide is that it provides a good protective barrier of the semitransparent functional coating during quenching and thus to obtain a staining-facing panel interferential having a better resistance to quenching.
The nitride is chosen from silicon nitrides, aluminum nitrides and mixed nitrides of aluminum and silicon, the preferred nitride being silicon nitride. The advantage of using silicon nitride is that it provides a good protective barrier of the semi-transparent functional coating during quenching and thus to obtain an interferentially colored siding panel having better resistance to quenching The oxynitride is chosen from silicon oxynitride, aluminum oxynitride and mixed oxynitrides of silicon and aluminum, the preferred oxynitride being silicon oxynitride. The advantage of using silicon oxynitride is that it makes it possible to obtain a good protective barrier of the semitransparent functional coating during quenching and thus to obtain a panel with interferential coloration. showing better resistance to quenching. The first transparent dielectric coating may also contain in a very small amount, generally less than 10 atomic percent, additional components. These include doping elements whose main role is to improve the manufacture and / or implementation of cathodes in the production of layers in vacuum deposition techniques. These elements are traditionally intended in particular to improve the conductivity of the materials constituting the cathodes. Such doping elements are for example titanium, aluminum.
The material constituting at least one layer of the semi-transparent functional coating is a metal chosen from titanium, tungsten, niobium, chromium, nickel, copper, tantalum, zirconium, yttrium, palladium, iron, alloys or mixtures of at least two of these metals, stainless steels. Preferably, the material constituting at least one layer of the semitransparent functional coating is a metal chosen from titanium, chromium, nickel, tantalum, tungsten, zirconium, yttrium, palladium, aluminum alloys and the like. At least two of these metals, stainless steels, the advantage associated with the use of these metals, result from the fact that they allow, because of their physical properties such as thermal expansion, to obtain a cladding panel. interferential coloration with better quenching performance. Stainless steels are preferred because, in addition to their chemical and thermal expansion properties, they have good resistance to corrosion.
The material constituting at least one layer of the second transparent dielectric coating comprises at least one oxide or nitride or an oxynitride. The oxide is selected from oxides of silicon, aluminum, titanium, zirconium, yttrium, hafnium, niobium, tin, tantalum, zinc and mixed oxides of at least two of them, preferentially among the oxides of silicon, aluminum, titanium and mixed oxides of at least two of them. The nitride is chosen from silicon nitrides, aluminum nitrides and mixed nitrides of aluminum and silicon, the preferred nitride being silicon nitride. The advantage of using silicon nitride is that it provides a good protective barrier of the semi-transparent functional coating during quenching and thus to obtain an interferentially colored siding panel having better resistance to quenching The oxynitride is chosen from silicon oxynitride, aluminum oxynitride and mixed oxynitrides of silicon and aluminum, the preferred oxynitride being silicon oxynitride. The advantage of using silicon oxynitride is that it makes it possible to obtain a good protective barrier of the semitransparent functional coating during quenching and thus to obtain a panel with interferential coloration. showing better resistance to quenching. Of all these materials cited above, silicon nitride is the preferred material. The second transparent dielectric coating can also contain in a very small amount, generally less than 10% atomic percentage, additional components. These are doping elements whose main role is to improve the manufacture and / or implementation of cathodes in the production of layers in vacuum deposition techniques. These elements are traditionally intended in particular to improve the conductivity of the materials constituting the cathodes. Such doping elements are for example titanium, aluminum.
The coating ensuring the opacity or quasi-opacity of the stack is such that the facing panel comprising it has, on the opposite side to the face of the facing panel carrying said coating, a reflection coefficient greater than or equal to 9 % preferably greater than or equal to 15% and less than or equal to 98% or 95%, preferentially less than or equal to 90%, or 85% or 80% in the visible. The reflection coefficient is measured with a source conforming to the daylight illuminant normalized D65 by the CIE and at a solid angle of 2 °, according to the EN410 standard. The material constituting at least one layer of the coating ensuring the opacity or quasi-opacity of the stack is chosen from a metal, a metalloid, a carbide or a nitride. Preferably, the material constituting at least one layer of the coating ensuring opacity or quasi-opacity is a metal. Preferably, the metal is chosen from titanium, tungsten, niobium, chromium, nickel, copper, tantalum, zirconium, yttrium, palladium, iron, alloys or mixtures of at least two of these metals, stainless steels, stainless steels being preferred, the advantage associated with the use of these metals is that they allow, because of their physical properties such as thermal expansion, to obtain a cladding panel with interferential coloration having better quenching performance. Stainless steels are preferred because, in addition to their thermal expansion properties, they have good resistance to corrosion. The geometric thickness of the coating ensuring opacity or quasi-opacity of the stack is at least greater than or equal to 30.0 nm, preferably at least greater than or equal to 50.0 nm, more preferably at least greater than or equal to at 100.0 nm.
The geometric thickness of the coating providing opacity or quasi-opacity being at most less than or equal to 1000.0 nm, preferably at most less than or equal to 200.0 nm.
Preferably, the geometrical thickness of said coating is in the range of values ranging from 30.0 nm to 1000.0 nm, preferably from 50.0 nm to 1000 nm, most preferably from 100.0 nm to 200.0 nm. .
Moreover, when the interferentially colored glass substrate according to the invention is intended to be used as reflective decorative panel, or even partially reflective, for interior or exterior applications, the use of silver or aluminum, metals usually used in the context of this type of use, for example the mirrors, to constitute the semitransparent functional coating and / or the coating ensuring the opacity or quasi-opacity, preferably the two coatings, is excluded, the aluminum and silver being particularly reflective metals but very sensitive to corrosion and requiring additional enamel or paint protection.
By the term "glass sheet" is meant an inorganic glass sheet. By this is meant a glass sheet of thickness at least greater than or equal to 0.5 mm and not less than or equal to 20.0 mm, preferably at least greater than or equal to 4.0 mm and at most less than or equal to 10.0 mm, comprising silicon as one of the indispensable components of the vitreous material. Silico-soda-lime glasses which are clear, extra-clear or colored in the mass or on the surface are preferred. More preferentially, the clear or extra-clear silico-soda-lime glasses are preferred because of their low absorption. The interferentially colored glass substrate for facing panel according to the invention is such that the glass sheet is covered on one of its faces by the stack of coatings, said covered face being the face intended to be oriented on the building side, commonly called inside or face 2.
The stack of coatings covering one side of the glass sheet is opaque to the wavelengths of visible light, the term "opaque" means that the light transmission rate is at most 4.0%, preferentially at most 2.0%, more preferably at most 1.0%, most preferably at most 0.1%, when it is applied to a silico-soda-lime float glass of 4.0 mm thick, measured with a source conforming to the standard D65 "daylight" illuminant by the CIE and at a solid angle of 2 °, according to the EN410 standard.
According to a preferred embodiment, the interferentially colored glass substrate according to the invention is such that it comprises, consists, consists essentially of a glass sheet, preferably a single sheet of glass, covered on one of its faces by a stack coating such that said stack of coatings comprises successively from the glass sheet at least: a first transparent coating of dielectric material, the optical thickness of the first transparent coating being at least greater than or equal to 5.0 nm, preferentially at least greater than or equal to 10.0 nm, more preferably at least 20.0 nm or more, most preferably at least 50.0 nm, more preferably at least 70.0 nm, more preferred at least greater than or equal to 100.0 nm, most preferably at least greater than or equal to at 110.0 nm and at most less than or equal to 258.0 nm, preferably at most less than or equal to 190.0 nm, more preferably at most less than or equal to 180.0 nm, most preferably at most 150 or less; , 0 nm, preferably at most less than or equal to 120.0 nm, preferably the optical thickness being in the range of values of 5.0 nm, preferably 10.0 nm, more preferably 20.0 nm at 258.0 nm, preferably from 50.0 nm to 190.0 nm, more preferably from 70.0 nm to 180.0 nm, most preferably from 100.0 nm to 150.0 nm, more preferably from 110.0 nm to 0 to 120.0 nm, a semi-transparent metallic functional coating, the attenuation thickness of the color of the metal coating being at least 0.3 nm, preferably at least greater than or equal to 0, 9 nm, more preferably at least higher or equal at 1.5 nm, most preferably at least greater than or equal to 3.0 nm, more preferably at least greater than or equal to 6.5 nm, more preferably at least greater than or equal to 9.5 nm, and at most 30.0 nm or less, preferably 28.0 nm or less, more preferably 25.2 nm or less, most preferably at most 18.0 nm, or less; preferred at most 15.0 nm or less. Preferably, the attenuation thickness is in the range of values ranging from 0.3 nm, preferably from 0.9 nm, more preferably from 1.5 nm, most preferably from 3.0 nm to 30.0 nm. , preferably from 0.3 nm to 28.0 nm, more preferably from 0.3 nm to 25.2 nm, most preferably from 6.5 nm to 18.0 nm, more preferably from 9.5 nm to 15 nm. , 0 nm, the attenuation thickness of the color being equal to the product of the geometric thickness of the metallic functional coating by the complex part, k, of the refractive index at 550 nm of the metal constituting said coating, when the metal is stainless steel, the thickness of attenuation of the color of the metal coating corresponds to a geometric thickness is at least greater than or equal to 0.1 nm, preferably at least greater than or equal to 0.3 nm, plus preferably at least greater than or equal to 0.5 nm, the most preferred ntiellement at least greater than or equal to 2.0 nm, preferably at least greater than equal to 3.0 nm and at most less than or equal to 10.0 nm, preferably at most less than or equal to 8.4 nm, the more preferably at most less than or equal to 5.0 nm, more preferably at most less than or equal to 4.0 nm. Preferably, the geometric thickness of the stainless steel coating is in the range of values ranging from 0.1 nm, preferably from 0.3 nm, more preferably from 0.5 nm to 10.0 nm, more preferably from 0, 1 nm at 8.4 nm, most preferably from 2.0 nm to 5.0 nm, advantageously from 3.0 nm to 4.0 nm, a second transparent coating of dielectric material, the optical thickness of the second transparent coating being at least greater than or equal to 20.0 nm, preferably at least 30.0 nm or more, more preferably at least 100.0 nm, most preferably at least 150.0 nm, at least greater than or equal to 170.0 nm and at most less than or equal to 300.0 nm, preferably at most less than or equal to 250.0 nm, most preferably at most less than or equal to 210.0 nm, preferred way less than or equal to 200.0 nm. Preferably, the optical thickness is in the range of values ranging from 20.0 nm, preferably from 30.0 nm, more preferably from 100.0 nm to 300.0 nm, preferentially from 150.0 nm to 250.0 nm. nm, more preferably from 170.0 to 200.0 nm.
A coating ensuring opacity or quasi-opacity of said stack, the geometric thickness of said coating providing opacity or quasi-opacity being at least 30.0 nm or greater, preferably at least 50 or more; , 0 nm, more preferably at least greater than or equal to 100.0 nm, most preferably at least greater than or equal to 150.0 nm, the geometric thickness of the coating ensuring opacity or quasi-opacity being at most or equal to 1000.0 nm, preferably not more than 200.0 nm. Preferably, the geometric thickness of said coating is in the range of values ranging from 30.0 nm to 1000.0 nm, preferably from 50.0 nm to 1000.0 nm, most preferably from 100.0 nm to 200.0 nm. said coating providing opacity or quasi-opacity comprising at least one metal, a metalloid, a nitride or a carbide.
According to a preferred embodiment of the preceding embodiment, the interferentially colored glass substrate according to the invention is such that the first and second transparent coating of dielectric material are based on silicon nitride, the first and second transparent coating based on nitride optionally containing an oxygen content expressed as an atomic percentage less than or equal to 10%, preferably less than or equal to 5%, more preferably less than or equal to 2%, most preferably equal to 0%.
According to one particular embodiment, the interferentially colored glass substrate, said substrate being preferably monolithic, for facing panel according to the invention is such that the semi-transparent functional coating and the coating ensuring the opacity or the quasi-opacity are metallic coatings.
According to a particular embodiment, the interferentially colored glass substrate, said substrate being preferably monolithic, for facing panel is such that it consists of a clear silico-soda-lime glass. Such glasses have a main composition which is in the following ranges, expressed in% of the weight of glass:
Si02 60 - 75 MgO 0 - 10
Na20 10 - 20 K20 0 - 10
CaO 0 - 16 BaO 0-2 with BaO + CaO + MgO 10 - 20 and Na20 + K20 10 - 20
Preferably, the glass of the interferentially colored glass substrate, said substrate being preferably monolithic, for facing panel is a float glass obtained in a method of floating the molten glass on a flat surface of liquid tin, commonly known as a "float" process. ".
According to a particular embodiment, the interferentially colored glass substrate, said substrate being preferably monolithic, for a facing panel according to the invention is such that it comprises, above the coating ensuring the opacity or the quasi-opacity of the stack, a protective coating, the geometric thickness of the protective coating being at least greater than or equal to 5.0 nm, preferably at least greater than or equal to 20.0 nm, the geometric thickness of the protective coating being not more than 500.0 nm. Preferably, the geometric thickness of the protective coating is in the range of values ranging from 5.0 nm to 500.0 nm, more preferably from 20.0 nm to 500.0 nm. The advantage offered by the protective coating is that it makes it possible to protect the stack of coatings deposited on the glass sheet from physical (for example claws) or chemical (for example oxidation (corrosion) and contamination by chemical and atmospheric agents). More particularly, the interferentially colored glass substrate for facing panel, said substrate being preferentially monolithic, comprising a protective coating has a better resistance with respect to the various quenching processes. The material constituting at least one layer of the protective coating is chosen from: • a chemical compound chosen from silicon, carbon, iron, chromium, nickel, aluminum, copper, molybdenum, zinc, tin, cobalt, vanadium, yttrium, zirconium, tantalum or an alloy or a mixture of at least two of these compounds such as nickel-chromium (NiCr) or NiCrAlY, stainless steel, preferentially the chemical compound is chosen from carbon, chromium, nickel, aluminum, • an oxide chosen from oxides of silicon, aluminum, titanium, tin, zinc, zirconium, mixed oxides of at least two of them, preferably chosen from titanium, tin, silicon oxides, mixed oxides of at least two of them, the oxide or the mixed oxide being optionally doped with aluminum, boron, yttrium, a nitride chosen from aluminum nitrides, silicon nitrides, mixed nitrides, aluminum and silicon, preferentially the silicon nitride, the nitride or the mixed nitride being optionally doped with aluminum, boron, yttrium, • an oxynitride chosen from oxynitrides of silicon, aluminum, oxynitrides mixtures of aluminum and silicon, preferably silicon oxynitride, the oxynitride or the mixed oxynitride being optionally doped with aluminum, boron, yttrium,
According to a particular embodiment of the preceding embodiment, the interferentially colored glass substrate, said substrate being preferably monolithic, for a facing panel according to the invention is such that the material constituting at least one layer of the protective coating is a chosen chemical compound. carbon, chromium, nickel, aluminum, stainless steel or an alloy of metals such as nickel-chromium (NiCr) or NiCrAlY, these compounds making it possible to obtain a better resistance to oxidation of the interferentially colored glass substrate according to the invention with respect to their corresponding oxides, oxynitrides or nitrides. The preferred material constituting at least one layer of the protective coating is stainless steel.
According to a particular embodiment of the two preceding modes, the interferentially colored glass substrate, said substrate being preferably monolithic, for facing panel according to the invention is such that the protective coating comprises at least one metal adhesion layer, said metal adhesion layer being the layer of the protective coating closest to the coating ensuring the opacity or quasi-opacity of the stack. Advantageously, this metal adhesion layer has a geometric thickness at least greater than or equal to 10.0 nm, preferably at least greater than or equal to 15.0 nm, the geometrical thickness of the metal adhesion layer being at least or equal to 100.0 nm, preferably at most less than or equal to 50.0 nm. Preferably, the geometric thickness of the adhesion layer is between 10.0 nm and 100.0 nm, preferably between 15.0 nm and 50.0 nm. The material constituting the adhesion layer is based on chromium
According to a particular embodiment, when the interferentially colored glass substrate, said substrate being preferably monolithic, for facing panel is intended to undergo quenching, the protective coating may advantageously comprise a terminal layer, in other words the layer the protective coating furthest from the glass sheet constituting the glass substrate, carbon. The advantage of this layer is that it makes it possible to obtain temporary mechanical and physicochemical protection, up to the quenching process, this layer being destroyed by oxidation during quenching.
According to a particular embodiment, the interferentially colored glass substrate, said substrate being preferably monolithic, for facing panel according to the invention is such that it comprises between the glass sheet and the first transparent coating of dielectric material, a coating transparent improving adhesion, said coating being of dielectric material. Advantageously, the material constituting the adhesion-improving coating has a refractive index close to the refractive index of the glass sheet. The term "refractive index close to the refractive index of the glass sheet" is intended to mean that the absolute value of the difference between the refractive index of the material constituting the coating improving adhesion and the index of refraction of the glass sheet has a value less than 0.13, said indices being the refractive indices of the different materials at a wavelength equal to 550 nm. Preferably, the refractive index of the material constituting the adhesion-improving coating has a value in the range of values between 1.4 and 1.65. The material constituting the adhesion-improving coating is preferably selected from silicon oxide or silicon oxynitride. The thickness of the coating improving the adhesion is at least greater than 0.0 nm, preferably at least greater than or equal to 10.0 nm, more preferably at least greater than or equal to 15.0 nm. The thickness of the coating improving the adhesion is at most less than or equal to 50.0 nm, preferably at most 30.0 nm or less. Preferably, the adhesion-improving coating has a geometric thickness in the range of values ranging from 0.0 nm to 50.0 nm, preferably from 10.0 nm to 50.0 nm, more preferably from 15.0 nm to 30.0 nm. The advantage of using the coating improving the adhesion is that it reduces or even avoid micro-cracks occurring during bending or tempering.
According to one particular embodiment, the interferentially colored glass substrate, said substrate being preferably monolithic, for facing panel according to the invention is such that at least one layer of the semi-transparent functional coating and at least one layer of the coating ensuring the opacity or quasi-opacity of the stack are of the same chemical nature.
According to a particular embodiment, the interferentially colored glass substrate, said substrate being preferably monolithic, for facing panel according to the invention is such that it comprises, consists, essentially consists of, successively from the glass sheet, at least: • a coating improving the silicon oxynitride adhesion, the geometric thickness of the coating improving the adhesion being at least greater than 0.0 nm, preferably at least greater than or equal to 10.0 nm, more preferably at least less than or equal to 15.0 nm, the geometric thickness of the coating improving the adhesion being at most less than or equal to 50.0 nm, preferably at most 30.0 nm or less. Preferably, the thickness of the coating improving the adhesion is at least greater than 0.0 nm and at most 50.0 nm or less, preferably at least greater than or equal to 10.0 and at most 50.0 mm or less. nm, more preferably at least greater than or equal to 15.0 and at most 30.0 nm or less, • a first transparent coating made of silicon nitride dielectric material, the geometric thickness of the transparent coating being at least greater than or equal to equal to 10.0 nm, preferably at least 25.0 nm or more, more preferably at least 35.0 nm or more, most preferably at least 50.0 nm or more, more preferably less than or equal to 55.0 nm, the geometric thickness of the transparent coating being not more than 129.0 nm, preferably not more than 95.0 nm, , more preferably at most less than or equal to 90.0 nm, most preferably at most less than or equal to 75.0 nm, more preferably at most less than or equal to 50.0 nm. Preferably, the thickness of said coating is between 10.0 nm and 129.0 nm, preferably between 25.0 nm and 95.0 nm, preferably between 35.0 nm and 90.0 nm, most preferably between 50, 0 nm and 75.0 nm, advantageously between 55.0 nm and 60.0 nm.
A semi-transparent metallic functional coating, the thickness of attenuation of the color of the coating being at least greater than or equal to 0.3 nm, preferably at least greater than or equal to 0.9 nm, more preferably at least greater than or equal to equal to 1.5 nm, most preferably at least greater than or equal to 3.0 nm, preferably at least greater than or equal to 6.5 nm, more preferably at least greater than or equal to 9.5 nm, the attenuation thickness being at most less than or equal to 30.0 nm, preferably at most 28.0 nm or less, more preferably at most 25.2 nm or less, most preferably at the lowest or 18.0 nm, preferably at most 15.0 nm or less. Preferably, the attenuation thickness is in the range of values ranging from 0.3 nm, preferably from 0.9 nm, more preferably from 1.5 nm, most preferably from 3.0 nm to 30.0 nm. , preferably from 0.3 nm to 28.0 nm, more preferably from 0.3 nm to 25.2 nm, most preferably from 6.5 nm to 18.0 nm, preferably from 9.5 nm to 15, 0 nm, the attenuation thickness of the color being equal to the product of the geometrical thickness of the metallic functional coating by the complex part, k, of the refractive index at 550 nm of the metal constituting said coating, when the metal is of stainless steel, the attenuation thickness of the color of the metallic coating corresponds to a geometric thickness at least greater than or equal to 0.1 nm, preferably at least greater than or equal to 0.3 nm, more preferably to less than or equal to 0.5 nm, the most preferential at least greater than or equal to 2.0 nm, advantageously at least greater than or equal to 2.0 nm, the geometrical thickness being at most 10.0 nm or less, preferably at most 8 or less; , 4 nm, most preferably less than or equal to 5.0 nm, advantageously at most less than or equal to 40 nm. Preferably, the geometric thickness of the stainless steel metallic functional coating is in the range of values ranging from 0.1 nm, preferably from 0.3 nm, more preferably from 0.5 nm to 10.0 nm, more preferably from 0.1 nm to 8.4 nm, most preferably from 2.0 nm to 5.0 nm, advantageously from 3.0 nm to 4.0 nm, a second transparent coating made of silicon nitride dielectric material, the thickness geometrical portion of the second transparent coating being at least greater than or equal to 10.0 nm, preferably at least greater than or equal to 50.0 nm, more preferably at least greater than or equal to 75.0 nm, most preferably at least greater than or equal to 85.0 nm, the geometric thickness of the second transparent coating being at most less than or equal to 150.0 nm, preferably at most less than or equal to 125.0 nm, most preferably at least or equal to 100.0 nm. Preferably, the geometric thickness of the second transparent coating being at most less than or equal to 150.0 nm, preferably less than or equal to 105.0 nm.
transparent coating being in the range of values from 10.0 nm to 150.0 nm, preferably from 50.0 nm to 150.0 nm, more preferably from 75.0 nm to 125.0 nm, most preferably 85.0 nm at 100.0 nm.
A metal coating ensuring the opacity or quasi-opacity of the stack comprising at least one layer, preferably the first layer, made of stainless steel, the geometrical thickness of the metallic coating ensuring opacity or quasi-opacity being at least less than or equal to 30.0 nm, preferably at least greater than or equal to 50.0 nm, more preferably at least greater than or equal to 100.0 nm, the geometrical thickness of the metallic coating ensuring the opacity or practically opacity being at most less than or equal to 1000.0 nm, preferably at most less than or equal to 200.0 nm. Preferably, the geometrical thickness of said coating is in the range of values ranging from 30.0 nm to 1000.0 nm, more preferably from 50.0 nm to 1000.0 nm, most preferably from 100.0 nm to 200 nm. 0 nm.
According to a particular embodiment of the previous embodiment, the interferentially colored glass substrate, said substrate being preferably monolithic, for facing panel is such that it comprises a protective coating comprising at least one layer of stainless steel.
According to another particular embodiment, the interferentially colored glass substrate, said substrate being preferably monolithic, for a facing panel according to the invention is such that it comprises at least: a first transparent coating made of nitride-based dielectric material silicon, the geometric thickness of the first transparent coating being between 10.0 nm and 120.0 nm, • a metallic titanium functional coating, the geometric thickness of the first metallic functional coating being in the range of values from 1.0 nm to 10.0 nm, preferably in the range of values from 1.0 nm to 5.0 nm, a second transparent coating made of silicon nitride dielectric material, the geometric thickness of the second transparent coating being within the range of 20.0 nm to 120.0 nm, • a metallic coating providing opacity or near-opacity ity of the stack comprising at least a first titanium layer, the geometric thickness of the metal coating ensuring opacity or quasi-opacity being at least greater than or equal to 30.0 nm, preferably at least greater than or equal to 50 , 0 nm, more preferably at least greater than or equal to 100.0 nm, the geometric thickness of the metal coating ensuring the opacity or the quasi-opacity being at most less than or equal to 1000.0 nm, preferably to the lowest or equal to 200.0 nm. Preferably, the geometric thickness of said coating is in the range of values ranging from 30.0 nm to 1000.0 nm, preferably from 50.0 nm to 1000.0 nm, most preferably from 100.0 nm to 200.0 nm.
According to another particular embodiment, the interferentially colored glass substrate, said substrate being preferably monolithic, for a facing panel according to the invention is such that it comprises at least: a first transparent coating made of silicon oxynitride dielectric material , the geometric thickness of the first transparent coating being between 10.0 nm and 120.0 nm, • a metallic titanium functional coating, the geometric thickness of the first metallic functional coating being in the range of values of 1.0 nm at 10.0 nm, preferably in the range of values from 1.0 nm to 5.0 nm, a second transparent coating made of silicon oxynitride dielectric material, the geometrical thickness of the second transparent coating being within the range of values. ranging from 20.0 nm to 120.0 nm, • a metallic coating ensuring opacity or near-opacity e of the stack comprising at least a first titanium layer, the geometric thickness of the metal coating ensuring the opacity or the quasi-opacity being at least greater than or equal to 30.0 nm, preferably at least greater than or equal to 50 , 0 nm, more preferably at least greater than or equal to 100.0 nm, the geometric thickness of the metal coating ensuring the opacity or the quasi-opacity being at most less than or equal to 1000.0 nm, preferably to the lowest or equal to 200.0 nm. Preferably, the geometric thickness of said coating is in the range of values ranging from 30.0 nm to 1000.0 nm, preferably from 50.0 nm to 1000.0 nm, most preferably from 100.0 nm to 200.0 nm.
According to an advantageous embodiment of the two preceding modes, a protective overlay is deposited above the metallic coating ensuring opacity or quasi-opacity, the material constituting said overcoating being based on a compound selected from carbon , silicon oxynitride, silicon nitride, silicon carbide, stainless steel, stainless steel being preferred, said overlayer having a geometric thickness at least greater than or equal to 5.0 nm and at the lowest or equal to 50.0 nm. The interferentially colored glass substrate, said substrate being preferably monolithic, for facing panel advantageously comprises a transparent coating improving adhesion, said coating being made of dielectric material selected from silicon oxide or silicon oxynitride. The thickness of the coating improving the adhesion is at least greater than 0.0 nm, preferably at least greater than or equal to 10.0 nm, more preferably greater than or equal to 15.0 nm. The thickness of the coating improving the adhesion is at most less than or equal to 50.0 nm, preferably less than or equal to 30.0 nm.
Preferably, the adhesion-improving coating has a geometric thickness in the range of values ranging from 0.0 nm to 50.0 nm, preferably from 10.0 nm to 50.0 nm, more preferably from 15.0 nm to 30.0 nm. The advantage of using the coating improving the adhesion is that it reduces or even avoid micro-cracks occurring during bending or tempering.
According to another particular embodiment, the interferential colored glass substrate for facing panel according to the invention is such that it comprises at least: • A coating improving the silicon oxynitride adhesion, the geometric thickness of the coating improving. the adhesion being at least greater than 0.0 nm and not more than 50.0 nm • A first transparent coating made of silicon nitride dielectric material, the geometric thickness of the first transparent coating being between 10.0 nm and 120.0 nm, a titanium metallic functional coating, the geometric thickness of the first metallic functional coating being in the range of values from 1.0 nm to 10.0 nm, preferably in the range of values from 1.0 nm to 5.0 nm • a second transparent coating made of silicon nitride dielectric material, the geometric thickness of the second coating with a transparency ranging from 20.0 nm to 120.0 nm, a metal coating ensuring the opacity or quasi-opacity of the stack comprising at least a first titanium layer, the geometrical thickness metal coating at least greater than or equal to 30.0 nm, preferably at least greater than or equal to 50.0 nm, more preferably at least greater than or equal to 100.0 nm, the geometric thickness of the metal coating ensuring opacity or the quasi-opacity being at most less than or equal to 1000.0 nm, preferably at most less than or equal to 200.0 nm.
Preferably, the geometric thickness of said coating is in the range of values ranging from 30.0 nm to 1000.0 nm, preferably from 50.0 nm to 1000.0 nm, most preferably from 100.0 nm to 200.0 nm.
According to a preferred embodiment, the interference-colored glass substrate for facing panel according to the invention is such that it comprises successively from the glass sheet, at least: • a coating improving the silicon oxynitride adhesion the geometric thickness of the adhesion-improving coating being at least greater than 0.0 nm and not more than 50.0 nm, • a first transparent coating of silicon nitride dielectric material, the geometric thickness of the first transparent coating being at least greater than or equal to 10.0 nm and not more than 129.0 nm, • a semitransparent metallic stainless steel functional coating, the geometrical thickness of said coating being within the range of values from 0.1 nm to 10.0 nm, a second transparent coating made of silicon nitride dielectric material, the geometric thickness of the second d transparent coating being at least greater than or equal to 10.0 nm and at most less than or equal to 150.0 nm, • a metal coating ensuring the opacity or quasi-opacity of the stack comprising at least one layer, preferably the first layer, stainless steel, the geometric thickness of the metal coating being greater than or equal to 30.0 nm, preferably at least greater than or equal to 50.0 nm, more preferably at least greater than or equal to 100.0 nm, the geometric thickness of the coating metal ensuring opacity or quasi-opacity being at most less than or equal to 1000.0 nm, preferably at most less than or equal to 200.0 nm. Preferably, the geometric thickness of said coating is in the range of values ranging from 30.0 nm to 1000.0 nm, preferably from 50.0 nm to 1000.0 nm, most preferably from 100.0 nm to 200.0 nm. nm.
According to another particular embodiment, the interferentially colored glass substrate, said substrate being preferably monolithic, for facing panel according to the invention is such that it comprises at least: a first transparent coating of dielectric material, the thickness geometry of the first transparent layer being between 10.0 nm and 120.0 nm, said first coating comprising at least two layers of different chemical nature, the first layer from the glass substrate comprising a silicon oxide also called "improving coating adhesion "and a second layer comprising a silicon oxynitride or" first transparent coating of dielectric material stricto senso ", • a functional metallic titanium coating, the geometric thickness of the first metallic functional coating being within the range of values from 1.0 nm to 10.0 nm, preferentially in the range of values from 1.0 nm to 5.0 nm, • a second transparent coating made of silicon oxynitride dielectric material, the geometrical thickness of the second transparent coating being in the range of values from 20, 0 nm to 120.0 nm, a metal coating ensuring the opacity or quasi-opacity of the stack comprising at least a first titanium layer, the geometric thickness of the metal coating ensuring opacity or quasi-opacity being at least greater than or equal to 30.0 nm, preferably at least greater than or equal to 50.0 nm, more preferably at least greater than or equal to 100.0 nm, the geometrical thickness of the metal coating ensuring the opacity or the quasi-opacity being at most less than or equal to 1000.0 nm, preferably at most less than or equal to 200.0 nm. Preferably, the geometric thickness of said coating is in the range of 30.0 nm to 1000.0 nm, preferably 50.0 nm to 1000.0 nm, most preferably 100.0 nm to 200.0 nm.
According to an advantageous embodiment of the preceding modes, a protective overlay is deposited above the metallic coating providing opacity or quasi-opacity, the material constituting said overcoat being based on a compound selected from carbon, silicon oxynitride, silicon nitride, silicon carbide, stainless steel, stainless steel being preferred, said overlayer having a geometric thickness at least greater than or equal to 5.0 nm and at most less than or equal to at 50.0 nm.
According to a particular embodiment, the interferentially colored glass substrate, said substrate being preferably monolithic, for facing panel according to the invention is such that said glass substrate is quenchable. The term "toughening glass substrate" is intended to mean that the stack of coatings of the interferentially colored glass substrate for facing panel according to the invention has good quench resistance, in other words that said substrate does not suffer from mechanical alterations (peeling, cracking) during quenching.
According to a particular embodiment, the interferentially colored glass substrate according to the invention does not undergo significant modifications of its colorimetric coordinates before and after quenching. By the terms "significant changes in its colorimetric coordinates" is meant a glass substrate interferentially colored whose colorimetric coordinates (L *, a *, b *) are little affected by the quenching process. By the terms "colorimetric coordinates (L *, a *, b *) are little affected", it is meant that the value AE * t, v, a is less than 6.0, preferentially less than 4.0, more preferably less than 2.0, with ΔΕ , 0 = - O2 + (<w - <") 2 + (bL.a ~ Ka) 2 For any viewing angle a between 0 and 60 °.
where L * atv, a represents the L * v colorimetric coordinates of the interferential stain-resistant glass substrate for quench facing panel, L * tv, a represents the L * v, a colorimetric coordinates of the interference-stained glass substrate for cladding board after quenching, a * atv, a represents the colorimetric coordinates a * v, "of the interferential coloring glass substrate for facing panel prior to quenching, a * tv, a represents the colorimetric coordinates a * v, 0 of the interferentially colored glass substrate. for facing panel after quenching, b * atv, a represents the colorimetric coordinates b * v, a of the interferential coloring glass substrate for facing panel before quenching, b * tv, a represents the colorimetric coordinates b * v, a of the substrate interferential stained glass for cladding board after quenching.
The index ν, α indicates that the measurement was made on the glass side, in other words on the uncoated side at the same angle a.
According to a particular embodiment, the interferentially colored glass substrate according to the invention is such that changes in the colorimetric coordinates after quenching are not very dependent on the quenching process. By the terms "significant modifications of these colorimetric coordinates" is meant a glass substrate with interferential coloration whose colorimetric coordinates (L * tv, a, a * tv, 0, b * tv <a) are little affected by the process thermal quenching. By the terms "colorimetric coordinates (L * tv, a / a * tv, a" b * tv, a) are little affected ", we mean that the value ΔΕ * 1ν, α is less than or equal to 4.0, preferably less than or equal to 2.0, more preferably less than or equal to 1.0, most preferably
equal to 0.0, with AE * t.v.a = for any angle of observation a between 0 and 60 °.
where L * t, v, a, tpsi, t ° i and L * t, v, a, tps2, t ° 2 respectively represent the colorimetric coordinates L * v, a of the interferentially colored glass substrate for facing panel after a quenched at a temperature t ° 1 and a time tps 1 and at a temperature t ° 2 and a time tps 2 a * t, v, a, tpsi, t ° i and a * t, v, a, tps2, to2 represent respectively the colorimetric coordinates a * t, v, 0 of the interference-colored glass substrate for facing panel after quenching at a temperature t ° 1 and a time tps 1 and at a temperature t ° 2 and a time tps 2 b * t , v, a, tpsi, t ° i and b * t, v, a, tps2, t ° 2 respectively represent the colorimetric coordinates b * t, v, a of the interference-colored glass substrate for facing panel after quenching at a temperature of temperature t ° l and a time tpsl and at a temperature t ° 2 and a time tps 2, the index ν, α indicates that the measurement was made on the glass side, in other words on the side not coated with a ngle a. Both quenching methods are distinguished by at least one of two parameters t ° or tps.
According to a particular embodiment, the interference-colored glass substrate for facing panel according to the invention is such that said interferentially colored glass substrate constitutes the opaque zone of a fully glazed facade and has the same color characteristics after quenching as those of the layered glazing, such as, for example, a glazing coated with a low-emissivity coating, constituting the zone of vision with which said interferential coloring glass substrate for a cladding board is to be associated, said interferential-stained glass and glazing substrate with layers are such that their respective coatings are deposited on a glass sheet of identical chemical composition.
By the terms "same color characteristics" is meant that the value ΔΕ * ίβν, 0 is less than 6.0, preferentially less than 4.0, more preferably less than 2.0, with
day any observation angle has between 0 and 60 °.
where AL * fav, Q represents the difference between the colorimetric coordinates L * av, a of an opaque zone consisting of the interferentially colored glass substrate for facing panel after quenching and L * fv, Q of a zone of vision corresponding to a layered glazing, Δ3 * av, a ν, α represents the difference between the colorimetric coordinates a * av, a of an opaque zone consisting of the interferentially colored glass substrate for facing panel after quenching and a * fV, a d a viewing zone corresponding to a layered glazing unit, Âb * fav, Q represents the difference between the colorimetric coordinates b * av, a of an opaque zone consisting of the interferentially colored glass substrate for facing panel after quenching and b * fV, has a viewing area corresponding to a layered glazing.
The index ν, α indicates that the measurement was made on the glass side, in other words on the uncoated side at an angle α.
The L *, a * and b * values correspond to the colorimetric coordinates according to the CIE Lab model of color representation developed by the International Commission on Illumination (CIE) (CIE 15: 2004). These coordinates are determined by a source conforming to the normalized "daylight" illuminant D65 by the CIE at an angle a.
According to a particular embodiment, the interferentially colored glass substrate, said substrate being preferably monolithic, for facing panel according to the invention is such that it comprises, consists, essentially consists of, successively from the glass sheet, at least: a first transparent coating made of dielectric material based on at least one compound chosen from silicon nitride, aluminum nitride, mixed aluminum-silicon nitride, zinc oxide, zinc-zinc mixed oxides, tin, the nitrides being preferred, their compositions causing little change in the optical properties of the semi-transparent functional coating during quenching of the substrate, said coating having an optical thickness of between 60.0 nm and 135.0 nm; functional semi-transparent metal based on at least one compound selected from titanium, chromium, stainless steel, palladium, nitride itane, stainless steel being preferred because of its mechanical and chemical stability, the geometric thickness of said coating being in the range of values from 0.5 nm to 7.0 nm, • a second transparent coating of dielectric material based on at least one compound selected from silicon nitride, aluminum nitride, mixed aluminum-silicon nitride, zinc oxide, zinc-tin mixed oxides, nitrides being preferred, their compositions causing little modifying the optical properties of the semi-transparent functional coating during their deposition or a quenching of the substrate, said coating having an optical thickness of between 80.0 nm and 210.0 nm, a metal coating ensuring the opacity or the quasi opacity of said stack, the geometric thickness of said coating providing opacity or quasi-opacity being greater than or equal to 100.0 nm, preferably comprised in the range of a range from 100.0 nm to 200.0 nm, more preferably of the order of 200.0 nm, said coating ensuring opacity or quasi-opacity comprising at least one metal, a metalloid, a nitride or a carbide, preferentially said coating providing opacity or quasi-opacity comprises at least one metal, preferably said metal is selected from chromium, titanium, stainless steel, nickel-chromium alloys.
According to a particular embodiment of the preceding embodiment, the interferential coloring glass substrate for facing panel according to the invention is such that it comprises between the glass sheet and the first transparent coating of dielectric material, at least one coating improving the adhesion in a material having a refractive index at 550 nm between 1.40 and 1.65 such as silicon oxynitride, the geometric thickness of the coating improving the adhesion being at least greater than 0.0 nm and not more than 30.0 nm. Such a coating makes it possible to increase the stability of the stack
According to a particular embodiment of the two preceding modes, the interferentially colored glass substrate for facing panel according to the invention is such that it comprises above the metal coating providing opacity or quasi-opacity an overlayer, the material constituting said overcoat being based on a compound selected from carbon, silicon oxynitride, silicon nitride, silicon carbide, said overlayer having a geometric thickness at least greater than or equal to 5.0 nm and not more than 50.0 nm.
The substrate according to any one of the three preceding embodiments is a quenchable substrate that can be used as a spandrel and has the same color characteristics as the Stopray Vision-50, Stopray Vision-50T, Stopray Vision-60T , Stopray Safir, Planibel Energy N, Planibel Energy NT, Stopray Galaxy, UltraVision-50 (UV50) marketed by AGC constituting the viewing areas, corresponding to the windows of a fully glazed facade.
According to a preferred embodiment, the interferentially colored substrate, said substrate being preferably monolithic, for facing panel according to the invention is such that it comprises, consists, consists essentially of, successively from the glass sheet: a coating improving the adhesion of silicon oxynitride, the geometric thickness of the coating improving the adhesion being at least greater than 0.0 nm and at most 30.0 nm or less, preferably of the order of 15, 0 nm, a first transparent coating made of silicon nitride dielectric material, said coating having an optical thickness in the range of values ranging from 114.4 nm to 122.4 nm, preferably of the order of 118.4 nm A semitransparent functional coating made of stainless steel, the geometrical thickness of said coating being in the range of values from 3.0 nm to 3.8 nm preferentie element being of the order of 3.4 nm, a second transparent coating of dielectric material made of silicon nitride, said coating having an optical thickness in the range of values ranging from 183.0 nm to 204.8 nm, preferentially of the order of 194.0 nm, a metal coating ensuring opacity or quasi-opacity of said stack, the geometric thickness of said coating ensuring opacity or quasi-opacity being at least 100.0 nm , preferably lying in the range from 100.0 nm to 200.0 nm, more preferably of the order of 200.0 nm, said coating providing opacity or quasi-opacity being made of stainless steel.
Said substrate being a quenchable substrate capable of being used as a spandrel and having the same color characteristics as the Stopray Vision-50T type layer glazings.
According to a preferred embodiment, the interferentially colored substrate, said substrate being preferably monolithic, for facing panel according to the invention is such that it comprises, consists, consists essentially of, successively from the glass sheet: a coating improving the adhesion of silicon oxynitride, the geometric thickness of the coating improving the adhesion being at least greater than 0.0 nm and at most 30.0 nm or less, preferably of the order of 15, 0 nm, a first transparent coating made of silicon nitride dielectric material, said coating having an optical thickness in the range of values ranging from 109.4 nm to 116.6 nm, preferably of the order of 114.2 nm A semi-transparent functional stainless steel coating, the geometric thickness of said coating being in the range of values from 3.4 nm to 4.2 nm preferentie this being of the order of 3.8 nm, a second transparent coating made of silicon nitride dielectric material, said coating having an optical thickness in the range of values ranging from 172.2 nm to 190.4 nm, preferentially of the order of 181.4 nm, a metal coating ensuring the opacity or quasi-opacity of said stack, the geometric thickness of said coating providing opacity or quasi-opacity being at least greater than or equal to 100, 0 nm, preferably lying in the range of values ranging from 100.0 nm to 200.0 nm, more preferably of the order of 200.0 nm, said coating ensuring opacity or quasi-opacity being made of stainless steel .
Said substrate being a quenchable substrate capable of being used as a spandrel and having the same color characteristics as the Stopray Vision-60T type layer glazings.
According to a preferred embodiment, the interferentially colored substrate, said substrate being preferably monolithic, for facing panel according to the invention is such that it comprises, consists, consists essentially of, successively from the glass sheet: a coating improving the silicon oxynitride adhesion, the geometric thickness of the coating improving the adhesion being at least greater than 0.0 nm and at most 30.0 nm or less, preferably of the order of 15 nm A first transparent coating made of silicon nitride dielectric material, said coating having an optical thickness in the range of values ranging from 113.6 nm to 124.0 nm, preferably of the order of 118.8 nm, a semi-transparent functional stainless steel coating, the geometric thickness of said coating being in the range of values from 3.2 nm to 4.0 nm preferentiell which is of the order of 3.6 nm, a second transparent coating made of silicon nitride dielectric material, said coating having an optical thickness in the range of values ranging from 166.2 nm to 180.2 nm, preferably from in the order of 173.2 nm, a metal coating ensuring the opacity or quasi-opacity of said stack, the geometric thickness of said coating providing opacity or quasi-opacity being at least 100.0 or greater nm, preferably lying in the range of values ranging from 100.0 nm to 200.0 nm, more preferably of the order of 200.0 nm, said coating providing opacity or quasi-opacity being made of stainless steel.
Said substrate being a quenchable substrate capable of being used as a spandrel and having the same color characteristics as Planibel Energy NT type glazing units.
According to a preferred embodiment, the interferentially colored substrate, said substrate being preferably monolithic, for facing panel according to the invention is such that it comprises, consists, consists essentially of, successively from the glass sheet: a coating improving the silicon oxynitride adhesion, the geometric thickness of the coating improving the adhesion being at least greater than 0.0 nm and at most 30.0 nm or less, preferably of the order of 15 nm A first transparent coating made of silicon nitride dielectric material, said coating having an optical thickness in the range of values ranging from 107.3 nm to 117.8 nm, preferably of the order of 112.8 nm, a semi-transparent functional stainless steel coating, the geometric thickness of said coating being in the range of values from 2.9 nm to 3.7 nm preferentiell which is of the order of 3.3 nm, a second transparent coating made of silicon nitride dielectric material, said coating having an optical thickness in the range of values ranging from 171.6 nm to 197.6 nm, preferentially of the order of 184.6 nm, a metal coating ensuring the opacity or quasi-opacity of said stack, the geometric thickness of said coating ensuring opacity or quasi-opacity being at least greater than or equal to 100, 0 nm, preferably in the range of 100.0 nm to 200.0 nm, more preferably of the order of 200.0 nm, said coating providing opacity or quasi-opacity being stainless steel.
Said substrate being a quenchable substrate that can be used as a spandrel and having the same color characteristics as the Stopray Galaxy type layer glazings.
According to a preferred embodiment, the interferentially colored substrate, said substrate being preferably monolithic, for facing panel according to the invention is such that it comprises, consists, consists essentially of, successively from the glass sheet: a coating improving the adhesion of silicon oxynitride, the geometric thickness of the coating improving the adhesion being at least greater than 0.0 nm and at most 30.0 nm or less, preferably of the order of 15, 0 nm, a first transparent coating made of silicon nitride dielectric material, said coating having an optical thickness in the range of values ranging from 42.8 nm to 48.3 nm, preferably of the order of 45.6 nm A semi-transparent functional coating made of stainless steel, the geometric thickness of said coating being in the range of values ranging from 4.2 nm to 5.6 nm preferential which is of the order of 5.0 nm, a second transparent coating made of silicon nitride dielectric material, said coating having an optical thickness in the range of values from 92.0 nm to 296 μm, preferably from the order of 94.3 nm, a metal coating ensuring the opacity or quasi-opacity of said stack, the geometric thickness of said coating ensuring opacity or quasi-opacity being at least 100.0 or greater nm, preferably, the geometrical thickness of said coating is in the range of values ranging from 100.0 nm to 200.0 nm, more preferably of the order of 200.0 nm, said coating ensuring opacity or quasi -opacity being in stainless steel.
Said substrate being a quenchable substrate capable of being used as a spandrel and having the same color characteristics as Stopray UltraVision-50 layered glazing units.
According to a particular embodiment, the interferentially colored glass substrate, said substrate being preferably monolithic, for facing panel according to the invention is such that it comprises, consists, essentially consists of, successively from the glass sheet, at least: a first transparent coating made of dielectric material based on at least one compound chosen from silicon nitride, aluminum nitride, mixed aluminum-silicon nitride, zinc oxide, zinc-zinc mixed oxides, tin, the nitrides being preferred, their compositions causing little change in the optical properties of the semi-transparent functional coating during quenching of the substrate, said coating having an optical thickness of between 50.0 nm and 90.0 nm; semi-transparent functional based on at least one compound selected from metals or nitrides, preferably based on at least one compound among others, titanium, chromium, stainless steel, palladium, titanium nitride, stainless steel being preferred because of its mechanical and chemical stability, the geometric thickness of said coating being within the range of values ranging from 0.1 nm to 3.0 nm, a second transparent coating made of dielectric material based on at least one compound chosen from silicon nitride, aluminum nitride, mixed aluminum-silicon nitride, and zinc oxide, zinc-tin mixed oxides, the nitrides being preferred, their compositions causing little change in the optical properties of the semi-transparent functional coating during their deposition or a quenching of the substrate, said coating having an optical thickness of between 100.0 nm and 170.0 nm, a metal coating ensuring opacity or quasi-opacity of said stack, the geometric thickness of said coating ensuring opacity or quasi-opacity being greater less than or equal to 100.0 nm, preferably in the range of 100.0 nm to 200.0 nm, more preferably of the order of 200.0 nm, said coating ensuring the opacity or practically opacity comprising at least one metal, a metalloid, a nitride or a carbide, preferentially said coating providing opacity comprises at least one metal, preferably said metal is selected from chromium, titanium, stainless steel, nickel-nickel alloys; chromium.
According to a particular embodiment of the preceding embodiment, the interferential coloring glass substrate for facing panel according to the invention is such that it comprises between the glass sheet and the first transparent coating of dielectric material, at least one coating improving the adhesion in a material having a refractive index at 550 nm between 1.40 and 1.65 such as silicon oxynitride, the geometric thickness of the coating improving the adhesion being at least greater than 0.0 nm and not more than 30.0 nm. Such a coating makes it possible to increase the stability of the stack
According to a particular embodiment of the two preceding modes, the interferentially colored glass substrate for facing panel according to the invention is such that it comprises above the metal coating providing opacity or quasi-opacity an overlayer, the material constituting said overcoat being based on a compound selected from carbon, silicon oxynitride, silicon nitride, silicon carbide, said overlayer having a geometric thickness at least greater than or equal to 5.0 nm and not more than 50.0 nm
The substrate according to any one of the three preceding embodiments is a quenchable substrate capable of being used as a spandrel and having the same color characteristics as the Stopray Vision-36T type layer glazings marketed by AGC constituting the zones of vision. , corresponding to the windows of a fully glazed facade.
According to a preferred embodiment, the interferentially colored substrate, said substrate being preferably monolithic, for facing panel according to the invention is such that it comprises, consists, consists essentially of, successively from the glass sheet: a coating improving the adhesion of silicon oxynitride, the geometric thickness of the coating improving the adhesion being at least greater than 0.0 nm and at most 30.0 nm or less, preferably of the order of 15, 0 nm, a first transparent coating made of silicon nitride dielectric material, said coating having an optical thickness in the range of values ranging from 65.8 nm to 89.0 nm, preferably of the order of 77.4 nm A semitransparent functional coating made of stainless steel, the geometrical thickness of said coating being in the range of values ranging from 0.1 nm to 1.3 nm, preferential 0.7 nm, a second transparent coating made of silicon nitride dielectric material, said coating having an optical thickness in the range of values ranging from 114.6 nm to 151.8 nm, preferably from in the order of 133.2 nm, a metal coating ensuring opacity or quasi-opacity of said stack, the geometric thickness of said coating ensuring opacity or quasi-opacity being at least 100.0 or greater nm, preferably lying in the range of values ranging from 100.0 nm to 200.0 nm, more preferably of the order of 200.0 nm, said coating providing opacity or quasi-opacity being made of stainless steel.
Said substrate being a quenchable substrate capable of being used as a spandrel and having the same color characteristics as the Stopray Vision-36T type layer glazings.
According to a particular embodiment, the interferentially colored glass substrate, said substrate being preferably monolithic, for facing panel according to the invention is such that it comprises, consists, essentially consists of, successively from the glass sheet, at least: a first transparent coating made of dielectric material based on at least one compound chosen from silicon nitride, aluminum nitride, mixed aluminum-silicon nitride, zinc oxide, zinc-zinc mixed oxides, tin, the nitrides being preferred, their compositions causing little change in the optical properties of the semi-transparent functional coating during quenching of the substrate, said coating having an optical thickness of between 110.0 nm and 190.0 nm, a coating semi-transparent functional based on at least one compound selected from metals or nitrides, preferably based on at least one compound selected from among titanium, chromium, stainless steel, palladium, titanium nitride, stainless steel being preferred because of its mechanical and chemical stability, the geometrical thickness of said coating being within the range of values. ranging from 2.0 nm to 12.0 nm, a second transparent coating made of dielectric material based on at least one compound selected from silicon nitride, aluminum nitride, mixed aluminum-silicon nitride, oxide zinc, zinc-tin mixed oxides, the nitrides being preferred, their compositions causing little change in the optical properties of the semi-transparent functional coating during their deposition or a quenching of the substrate, said coating having an optical thickness of between , 0 nm and 80.0 nm, a metal coating ensuring the opacity or quasi-opacity of said stack, the geometric thickness of said coating ensuring opacity or quasi-opacity being greater than 100.0 nm or less, preferably in the range of 100.0 nm to 200.0 nm, more preferably of the order of 200.0 nm, said coating providing opacity or virtually opacity comprising at least one metal, a metalloid, a nitride or a carbide, preferably said coating providing opacity comprises at least one metal, preferably said metal is selected from chromium, titanium, stainless steel, nickel-chromium alloys .
According to a particular embodiment of the preceding embodiment, the interferential coloring glass substrate for facing panel according to the invention is such that it comprises between the glass sheet and the first transparent coating of dielectric material, at least one coating improving the adhesion in a material having a refractive index at 550 nm between 1.40 and 1.65 such as silicon oxynitride, the geometric thickness of the coating improving the adhesion being at least greater than 0.0 nm and not more than 30.0 nm. Such a coating makes it possible to increase the stability of the stack
According to a particular embodiment of the two preceding modes, the interferentially colored glass substrate for facing panel according to the invention is such that it comprises above the metal coating providing opacity or quasi-opacity an overlayer, the material constituting said overcoat being based on a compound selected from carbon, silicon oxynitride, silicon nitride, silicon carbide, said overlayer having a geometric thickness at least greater than or equal to 5.0 nm and not more than 50.0 nm.
The substrate according to any one of the three preceding embodiments is a quenchable substrate that can be used as a spandrel and has the same color characteristics as the Stopray Neo layer glazings marketed by the AGC company constituting the corresponding zones of vision. the windows of a fully glazed facade.
According to a preferred embodiment, the interferentially colored substrate, said substrate being preferably monolithic, for facing panel according to the invention is such that it comprises, consists, consists essentially of, successively from the glass sheet: a coating improving the adhesion of silicon oxynitride, the geometric thickness of the coating improving the adhesion being at least greater than 0.0 nm and at most 30.0 nm or less, preferably of the order of 15, 0 nm, a first transparent coating of silicon nitride dielectric material, said coating having an optical thickness in the range of values ranging from 130.6 nm to 153.8 nm, preferably of the order of 142.4 nm A semi-transparent functional coating made of stainless steel, the geometrical thickness of said coating being in the range of values from 2.8 nm to 8.4 nm preferentie in the order of 5.6 nm, a second transparent coating made of silicon nitride dielectric material, said coating having an optical thickness in the range of values from 23.2 nm to 69.4 nm, preferentially of the order of 46.2 nm • a metal coating ensuring the opacity or quasi-opacity of said stack, the geometric thickness of said coating ensuring opacity or quasi-opacity being at least 100.0 or greater nm, preferably lying in the range of values ranging from 100.0 nm to 200.0 nm, more preferably of the order of 200.0 nm, said coating providing opacity or quasi-opacity being made of stainless steel.
Said substrate being a quenchable substrate capable of being used as a spandrel and having the same color characteristics as the Stopray Neo type layer glazings.
According to an alternative embodiment, the interferentially colored substrate, said substrate being preferably monolithic, for a facing panel according to the invention is such that it comprises, consists, essentially consists of, successively from the glass sheet: a coating improving the adhesion of silicon oxynitride, the geometric thickness of the coating improving the adhesion being at least greater than 0.0 nm and at most 30.0 nm or less, preferably of the order of 15, 0 nm, a first transparent coating of silicon nitride dielectric material, said coating having an optical thickness in the range of values ranging from 108.0 nm to 130.0 nm, preferably of the order of 119.0 nm A semi-transparent functional coating made of stainless steel, the geometrical thickness of said coating being in the range of values from 1.0 nm to 6.0 nm preferentie the element being of the order of 2.5 nm, a second transparent coating made of silicon nitride dielectric material, said coating having an optical thickness in the range of values ranging from 185.0 nm to 225.0 nm, preferentially of the order of 205.0 nm • a metal coating ensuring opacity or quasi-opacity of said stack, the geometric thickness of said coating providing opacity or quasi-opacity being at least 100.0 or greater nm, preferably lying in the range of values ranging from 100.0 nm to 200.0 nm, more preferably of the order of 200.0 nm, said coating providing opacity or quasi-opacity being made of stainless steel.
Said substrate being a quenchable substrate capable of being used as a spandrel and having the same color characteristics as the Stopray Neo type layer glazings.
According to a particular embodiment, the interferentially colored glass substrate, said substrate being preferably monolithic, for facing panel according to the invention is such that it comprises, consists, essentially consists of, successively from the glass sheet, at least: a first transparent coating of dielectric material based on at least one compound selected from an oxide of at least one element selected from zinc, silicon, titanium, tin, aluminum, an oxide mixture of at least two of these elements, preferably the zinc-tin mixed oxide, a silicon nitride, an aluminum nitride, a mixed aluminum-silicon nitride, said coating having an optical thickness of between 100.0 nm and 165.0 nm, a semi-transparent functional coating based on at least one compound selected from metals or nitrides, preferably based on at least one compound selected from titanium, chromium, stainless steel, palladium, titanium nitride, stainless steel being preferred because of its mechanical and chemical stability, the geometric thickness of said coating being in the range of values of 0.5 nm at 20.0 nm, a second transparent coating of dielectric material based on at least one compound chosen from an oxide of at least one element selected from zinc, silicon, titanium, tin, aluminum a mixed oxide of at least two of these elements, preferably the zinc-tin mixed oxide, a silicon nitride, an aluminum nitride, a mixed aluminum-silicon nitride, the nitrides being preferred their deposition leading to little modifying the optical properties of the semitransparent functional coating, said coating having an optical thickness of between 235.0 nm and 315.0 nm, a metal coating ensuring the opacity or quasi-opacity of said stack, the thickness ometric said coating providing opacity or quasi-opacity being greater than or equal to 100.0 nm, preferably in the range of 100.0 nm to 200.0 nm, more preferably of the order of 200, 0 nm, said coating providing opacity or quasi-opacity comprising at least one metal, a metalloid, a nitride or a carbide, preferably said coating ensuring opacity comprises at least one metal, preferably said metal is selected from chromium, titanium, stainless steel, nickel-chromium alloys.
According to a particular embodiment of the preceding embodiment, the interferential coloring glass substrate for facing panel according to the invention is such that it comprises between the glass sheet and the first transparent coating of dielectric material, at least one coating improving the adhesion in a material having a refractive index at 550 nm between 1.40 and 1.65 such as silicon oxynitride, the geometric thickness of the coating improving the adhesion being at least greater than 0.0 nm and not more than 30.0 nm. Such a coating makes it possible to increase the stability of the stack
According to a particular embodiment of the two preceding modes, the interferentially colored glass substrate for facing panel according to the invention is such that it comprises above the metal coating providing opacity or quasi-opacity an overlayer, the material constituting said overcoat being based on a compound selected from carbon, silicon oxynitride, silicon nitride, silicon carbide, said overlayer having a geometric thickness at least greater than or equal to 5.0 nm and not more than 50.0 nm
The substrate according to any one of the three preceding embodiments is a substrate, possibly tempered, which can be used as a decorative facing panel for interior or exterior applications having color characteristics L *, a *, b * in the CIELAB system. such that 57 <L * <71, -2.7 <a * <1.3, -4.8 <b * <1.2, more particularly L * = 64, a * = -0.7, b * = -1.8 and measured according to the illuminant D65 at 10 ° in reflection on the side of the face of the glass sheet not covered by an UltraScan type apparatus and a reflectance of between 27.6% and 37.6 %, more particularly equal to 32.6%, measured according to the illuminant D65 at 2 ° in reflection on the side of the face of the glass sheet not covered by an UltraScan type apparatus.
According to a particular embodiment, the interferentially colored glass substrate, said substrate being preferably monolithic, for facing panel according to the invention is such that it comprises, consists, essentially consists of, successively from the glass sheet, at least: • a coating improving the silicon oxynitride adhesion, the geometric thickness of the coating improving the adhesion being at least greater than 0.0 nm and at most 30.0 nm or less, preferably of order of 15.0 nm, a first transparent coating made of silicon nitride dielectric material, said coating having an optical thickness of between 120.3 nm and 146.0 nm, preferably of the order of 134.2 nm, a semi-transparent functional coating made of stainless steel, the geometrical thickness of said coating being in the range of values ranging from 1.5 nm to 2.5 nm, preferably from in the order of 1.9 nm, a second transparent coating made of silicon nitride dielectric material, said coating having an optical thickness of between 250.8 nm and 294.4 nm, preferably of the order of 272.6. nm, a metal coating ensuring the opacity or quasi-opacity of said stack, the geometric thickness of said coating providing opacity or quasi-opacity being greater than or equal to 100.0 nm, preferably lying in the range of value. ranging from 100.0 nm to 200.0 nm, more preferably being of the order of 200.0 nm, said coating providing opacity or quasi-opacity being made of stainless steel.
• Substrate, optionally tempered, may be used as a decorative facing panel for indoor or outdoor applications with L *, a *, b * color characteristics in the CIELAB system such that 57 <L * <71, - 2.7 <a * <1.3, -4.8 <b * <1.2, more particularly L * = 64, a * = -0.7, b * = -1.8 and measured according to the illuminant D65 at 10 ° in reflection on the side of the face of the glass sheet not covered by an UltraScan type apparatus and a reflectance of between 27.6% and 37.6%, more particularly equal to 32.6% , measured according to the illuminant D65 at 2 ° in reflection on the side of the face of the glass sheet not covered by an apparatus of the type; the colorimetric coordinates of said substrate being little dependent on the angle of observation. By the terms "colorimetric coordinates of said substrate being little dependent on the angle of observation" is meant a variation of the colorimetric coordinates ΔΕ * less than or equal to 6 and for any angle of observation ranging from 0 ° to 55 ° .
According to a particular embodiment, the interferentially colored glass substrate, said substrate being preferably monolithic, for facing panel according to the invention is such that it comprises, consists, essentially consists of, successively from the glass sheet, at least: a first transparent coating of dielectric material based on at least one compound selected from an oxide of at least one element selected from zinc, silicon, titanium, tin, aluminum, an oxide mixture of at least two of these elements, preferably the zinc-tin mixed oxide, a silicon nitride, an aluminum nitride, a mixed aluminum-silicon nitride, said coating having an optical thickness of between 100.0 nm and 160.0 nm, a semi-transparent functional coating based on at least one compound selected from metals or nitrides, preferably based on at least one compound selected from titanium , chromium, stainless steel, palladium, titanium nitride, stainless steel being preferred because of its mechanical and chemical stability, the geometrical thickness of said coating being in the range of values from 1.0 nm at 20.0 nm, a second transparent coating made of dielectric material based on at least one compound chosen from an oxide of at least one element selected from zinc, silicon, titanium, tin, aluminum, a mixed oxide of at least two of these elements, preferably the zinc-tin mixed oxide, a silicon nitride, an aluminum nitride, a mixed aluminum-silicon nitride, the nitrides being preferred their deposition resulting in little for modifying the optical properties of the semi-transparent functional coating, said coating having an optical thickness of between 200.0 nm and 270.0 nm, a metal coating ensuring the opacity or quasi-opacity of said stack, the thickness the geometry of said coating ensuring opacity or quasi-opacity being greater than or equal to 100.0 nm, preferably lying in the range of values ranging from 100.0 nm to 200.0 nm, more preferably of the order of 200, 0 nm, said coating providing opacity or quasi-opacity comprising at least one metal, a metalloid, a nitride or a carbide, preferably said coating ensuring opacity comprises at least one metal, preferably said metal is selected from chromium, titanium, stainless steel, nickel-chromium alloys.
According to a particular embodiment of the preceding embodiment, the interferential coloring glass substrate for facing panel according to the invention is such that it comprises between the glass sheet and the first transparent coating of dielectric material, at least one coating improving the adhesion in a material having a refractive index at 550 nm between 1.40 and 1.65 such as silicon oxynitride, the geometric thickness of the coating improving the adhesion being at least greater than 0.0 nm and not more than 30.0 nm. Such a coating makes it possible to increase the stability of the stack
According to a particular embodiment of the two preceding modes, the interferentially colored glass substrate for facing panel according to the invention is such that it comprises above the metal coating providing opacity or quasi-opacity an overlayer, the material constituting said overcoat being based on a compound selected from carbon, silicon oxynitride, silicon nitride, silicon carbide, said overlayer having a geometric thickness at least greater than or equal to 5.0 nm and not more than 50.0 nm
The substrate according to any one of the three preceding embodiments is a substrate, possibly tempered, which can be used as a decorative facing panel for interior or exterior applications having color characteristics L *, a *, b * in the CIELAB system. such that 52 <L * <66, -4.9 <a * <-0.9, -15.8 <b * <-9.8, more particularly L * = 59, a * = -2.9, b * = -12.8 and measured according to the illuminant D65 at 10 ° in reflection on the side of the face of the glass sheet not covered by an UltraScan type apparatus and a reflectance of between 21.4% and 31%. , 4%, more particularly equal to 26.4%, measured according to the D65 illuminant at 2 ° in reflection on the side of the face of the glass sheet not covered by an UltraScan type apparatus.
According to a particular embodiment, the interferentially colored glass substrate, said substrate being preferably monolithic, for facing panel according to the invention is such that it comprises, consists, essentially consists of, successively from the glass sheet, at least: • a coating improving the silicon oxynitride adhesion, the geometric thickness of the coating improving the adhesion being at least greater than 0.0 nm and at most 30.0 nm or less, preferably of order of 15.0 nm, a first transparent coating made of silicon nitride dielectric material, said coating having an optical thickness of between 116.0 nm and 142.0 nm, preferably of the order of 129.0 nm, a semitransparent functional coating made of stainless steel, the geometric thickness of said coating being in the range of values ranging from 2.8 nm to 4.4 nm, preferably from in the order of 3.6 nm, a second transparent coating made of silicon nitride dielectric material, said coating having an optical thickness of between 218.4 nm and 246.4 nm, preferably of the order of 232.4. nm, a metal coating ensuring the opacity or quasi-opacity of said stack, the geometric thickness of said coating providing opacity or quasi-opacity being greater than or equal to 100.0 nm, preferably lying in the range of value. ranging from 100.0 nm to 200.0 nm, more preferably being of the order of 200.0 nm, said coating providing opacity or quasi-opacity being made of stainless steel.
• The substrate, optionally tempered, is suitable for use as a decorative facing panel for indoor or outdoor applications with L *, a *, b * color characteristics in the CIEL AB system such as 52 <L * <66, -4.9 <a * <-0.9, -15.8 <b * <-9.8, more particularly L * = 59, a * = -2.9, b * = -12.8 and measured according to the illuminant D65 at 10 ° in reflection on the side of the face of the glass sheet not covered by an UltraScan type apparatus and a reflectance of between 21.4% and 31.4%, more particularly equal to 26 , 4%, measured according to the illuminant D65 at 2 ° in reflection on the side of the face of the glass sheet not covered by a device of the type; the colorimetric coordinates of said substrate being little dependent on the angle of observation. By the terms "colorimetric coordinates of said substrate being little dependent on the angle of observation" is meant a variation of the colorimetric coordinates ΔΕ * less than or equal to 6 and for any angle of observation ranging from 0 ° to 55 ° .
According to a particular embodiment, the interferentially colored glass substrate, said substrate being preferably monolithic, for facing panel according to the invention is such that it comprises, consists, essentially consists of, successively from the glass sheet, at least: a first transparent coating of dielectric material based on at least one compound selected from an oxide of at least one element selected from zinc, silicon, titanium, tin, aluminum, an oxide mixture of at least two of these elements, preferably the zinc-tin mixed oxide, a silicon nitride, an aluminum nitride, an aluminum-silicon mixed nitride, said coating having an optical thickness of between 40.0 nm and 90.0 nm, a semi-transparent functional coating based on at least one compound selected from metals or nitrides, preferably based on at least one compound selected from titanium, chromium, stainless steel, palladium, titanium nitride, silver, silver nitride, said silver nitride may optionally be nitrided, silver optionally nitrided or nitrided being preferred, the thickness geometrically, said coating being in the range of values from 2.0 nm to 20.0 nm; a second transparent coating of dielectric material based on at least one compound selected from an oxide of at least one element selected from zinc, silicon, titanium, tin, aluminum, a mixed oxide of at least two of these elements, preferentially zinc-tin mixed oxide, silicon nitride, aluminum nitride, a mixed aluminum-silicon nitride, the nitrides being preferred their deposition causing little change in the optical properties of the semi-transparent functional coating, said coating having an optical thickness of between 135.0 nm and 215.0 nm, • a coating metal ensuring the opacity or quasi-opacity of said stack, the geometric thickness of said coating providing opacity or quasi-opacity being greater than or equal to 100.0 nm, preferably in the range of value of 100.0 nm at 200.0 nm, more preferably of the order of 200.0 nm, said coating ensuring opacity or quasi-opacity comprising at least one metal, a metalloid a nitride or a carbide, preferably said coating ensuring the opacity comprises at least one metal, preferably said metal is selected from chromium, titanium, stainless steel, nickel-chromium alloys.
According to a particular embodiment of the preceding embodiment, the interferential coloring glass substrate for facing panel according to the invention is such that it comprises between the glass sheet and the first transparent coating of dielectric material, at least one coating improving the adhesion in a material having a refractive index at 550 nm between 1.40 and 1.65 such as silicon oxynitride, the geometric thickness of the coating improving the adhesion being at least greater than 0.0 nm and not more than 30.0 nm. Such a coating makes it possible to increase the stability of the stack
According to a particular embodiment of the two preceding modes, the interferentially colored glass substrate for facing panel according to the invention is such that it comprises above the metal coating providing opacity or quasi-opacity an overlayer, the material constituting said overcoat being based on a compound selected from carbon, silicon oxynitride, silicon nitride, silicon carbide, said overlayer having a geometric thickness at least greater than or equal to 5.0 nm and not more than 50.0 nm
The substrate according to any one of the three preceding embodiments is a substrate, possibly tempered, which can be used as a decorative facing panel for interior or exterior applications having color characteristics L *, a *, b * in the CIELAB system. such that 38.5 <L <52.5, -5.1 <a * <-1.1, -32 <b * <-26, more particularly L * = 45.5, a * = -3, 1, b * = -29 and measured according to the illuminant D65 at 10 ° in reflection on the side of the face of the glass sheet not covered by an UltraScan type apparatus and a reflectance of between 9% and 19%, more particularly equal to 14%, measured according to the illuminant D65 at 2 ° in reflection on the side of the face of the glass sheet not covered by an UltraScan type apparatus.
According to a particular embodiment, the interferentially colored glass substrate, said substrate being preferably monolithic, for facing panel according to the invention is such that it comprises, consists, essentially consists of, successively from the glass sheet, at least: • a coating improving the silicon oxynitride adhesion, the geometric thickness of the coating improving the adhesion being at least greater than 0.0 nm and at most 30.0 nm or less, preferably of order of 15.0 nm, a first transparent coating made of silicon nitride dielectric material, said coating having an optical thickness of between 31.8 nm and 101.0 nm, preferably of the order of 66.4 nm, a semi-transparent functional silver coating, optionally under nitrided, the geometric thickness of said coating being in the range of values ranging from 4.2 nm to 6.4 n m, preferably of the order of 5.4 nm, a second transparent coating made of silicon nitride dielectric material, said coating having an optical thickness of between 162.8 nm and 195.4 nm, preferably of the order of 181.6 nm, a metal coating ensuring the opacity or quasi-opacity of said stack, the geometric thickness of said coating providing opacity or quasi-opacity being greater than or equal to 100.0 nm, preferably included in FIG. a range of values ranging from 100.0 nm to 200.0 nm, more preferably being of the order of 200.0 nm, said coating providing opacity or quasi-opacity being made of stainless steel.
• Substrate, optionally tempered, may be used as a decorative facing panel for interior or exterior applications with L *, a *, b * color characteristics in the CIELAB system such as 38.5 <L <52 , 5, -5.1 <a * <-1.1, -32 <b * <-26, more particularly L * = 45.5, a * = -3.1, b * = -29 and measured according to the illuminant D65 at 10 ° in reflection on the side of the face of the glass sheet not covered by an UltraScan type apparatus and a reflectance of between 9% and 19%, more particularly equal to 14%, measured according to the illuminant D65 at 2 ° in reflection on the side of the face of the glass sheet not covered by an apparatus of the type; the colorimetric coordinates of said substrate being little dependent on the angle of observation. By the terms "colorimetric coordinates of said substrate being little dependent on the angle of observation" is meant a variation of the colorimetric coordinates ΔΕ * less than or equal to 10 and for any angle of observation ranging from 0 ° to 55 ° .
According to a particular embodiment, the interferentially colored glass substrate, said substrate being preferably monolithic, for facing panel according to the invention is such that it comprises, consists, essentially consists of, successively from the glass sheet, at least: a first transparent coating of dielectric material based on at least one compound selected from an oxide of at least one element selected from zinc, silicon, titanium, tin, aluminum, an oxide mixture of at least two of these elements, preferably zinc-tin mixed oxide, silicon nitride, aluminum nitride, aluminum-silicon mixed nitride, said coating having an optical thickness of between 8.0 nm and 60.0 nm, a semi-transparent functional coating based on at least one compound selected from metals or nitrides, preferably based on at least one compound selected from titanium, chromium, stainless steel, palladium, titanium nitride, stainless steel being preferred because of its mechanical and chemical stability, the geometric thickness of said coating being in the range of values of 2.0 nm , 0 nm, a second transparent coating made of dielectric material based on at least one compound chosen from an oxide of at least one element selected from zinc, silicon, titanium, tin, aluminum, a mixed oxide of at least two of these elements, preferably the zinc-tin mixed oxide, a silicon nitride, an aluminum nitride, a mixed aluminum-silicon nitride, the nitrides being preferred their deposition leading to little modification of the optical properties of the semi-transparent functional coating, said coating having an optical thickness of between 130.0 nm and 220.0 nm, a metal coating ensuring the opacity or quasi-opacity of said stack, the geometrical thickness said coating providing opacity or quasi-opacity being greater than or equal to 100.0 nm, preferably in the range of 100.0 nm to 200.0 nm, more preferably of the order of 200, 0 nm, said coating providing opacity or quasi-opacity comprising at least one metal, a metalloid, a nitride or a carbide, preferably said coating ensuring opacity comprises at least one metal, preferably said metal is selected from chromium, titanium, stainless steel, nickel-chromium alloys.
According to a particular embodiment of the preceding embodiment, the interferential coloring glass substrate for facing panel according to the invention is such that it comprises between the glass sheet and the first transparent coating of dielectric material, at least one coating improving the adhesion in a material having a refractive index at 550 nm between 1.40 and 1.65 such as silicon oxynitride, the geometric thickness of the coating improving the adhesion being at least greater than 0.0 nm and not more than 30.0 nm. Such a coating makes it possible to increase the stability of the stack
According to a particular embodiment of the two preceding modes, the interferentially colored glass substrate for facing panel according to the invention is such that it comprises above the metal coating providing opacity or quasi-opacity an overlayer, the material constituting said overcoat being based on a compound selected from carbon, silicon oxynitride, silicon nitride, silicon carbide, said overlayer having a geometric thickness at least greater than or equal to 5.0 nm and not more than 50.0 nm
The substrate according to any one of the three preceding embodiments is a substrate, possibly tempered, which can be used as a decorative facing panel for interior or exterior applications having color characteristics L *, a *, b * in the CIELAB system. such that 41.0 <L * <55.0, -5.3 <a * <-1.3, -34.0 <b * <-26.0, more particularly L * = 48.0, a * = -3.3, b * = -30.0 and measured according to the illuminant D65 at 10 ° in reflection on the side of the face of the glass sheet not covered by an UltraScan type apparatus and a reflectance between 11.0% and 21.0%, more particularly equal to 16.0%, measured according to the D65 illuminant at 2 ° in reflection on the side of the face of the glass sheet not covered by an UltraScan type apparatus.
According to a particular embodiment, the interferentially colored glass substrate, said substrate being preferably monolithic, for facing panel according to the invention is such that it comprises, consists, essentially consists of, successively from the glass sheet, at least: • a coating improving the silicon oxynitride adhesion, the geometric thickness of the coating improving the adhesion being at least greater than 0.0 nm and at most 30.0 nm or less, preferably of order of 15.0 nm, a first transparent coating made of silicon nitride dielectric material, said coating having an optical thickness of between 2.8 nm and 26.0 nm, preferably of the order of 14.4 nm, a semitransparent functional coating made of stainless steel, the geometrical thickness of said coating being in the range of values ranging from 3.3 nm to 4.9 nm, preferably from 4.1 nm, a second transparent coating made of silicon nitride dielectric material, said coating having an optical thickness of between 160.0 nm and 195.8 nm, preferably of the order of 178.0 nm, a metal coating ensuring the opacity or quasi-opacity of said stack, the geometric thickness of said coating ensuring opacity or quasi-opacity being greater than or equal to 100.0 nm, preferably in the range of 100 , 0 nm to 200.0 nm, more preferably being of the order of 200.0 nm, said coating providing opacity or quasi-opacity being made of stainless steel.
• the substrate, possibly tempered, is suitable for use as a decorative facing panel for indoor or outdoor applications with L *, a *, b * color characteristics in the CIELAB system such as 41.0 <L * <55 , 0, -5.3 <a * <-1.3, - 34.0 <b * <-26.0, more particularly L * = 48.0, a * = -3.3, b * = - 30.0 and measured according to the illuminant D65 at 10 ° in reflection on the side of the face of the glass sheet not covered by an UltraScan type apparatus and a reflectance of between 11.0% and 21.0%, more particularly equal to 16.0%, measured according to the illuminant D65 at 2 ° in reflection on the side of the face of the glass sheet not covered by a type of apparatus; the colorimetric coordinates of said substrate being little dependent on the angle of observation. By the terms "colorimetric coordinates of said substrate being little dependent on the angle of observation" is meant a variation of the colorimetric coordinates ΔΕ * less than or equal to 10 and for any angle of observation ranging from 0 ° to 55 ° .
According to a particular embodiment, the interferentially colored glass substrate, said substrate being preferably monolithic, for facing panel according to the invention is such that it comprises, consists, essentially consists of, successively from the glass sheet, at least: a first transparent coating of dielectric material based on at least one compound selected from an oxide of at least one element selected from zinc, silicon, titanium, tin, aluminum, an oxide mixture of at least two of these elements, preferably zinc-tin mixed oxide, silicon nitride, aluminum nitride, aluminum-silicon mixed nitride, said coating having an optical thickness of between 80.0 nm and 200.0 nm, when the semi-transparent functional coating is based on oxidized stainless steel, the optical thickness of the first functional coating of dielectric material is between 90 nm and t 150.0 nm, a semi-transparent functional coating based on at least one compound chosen from metals, nitrides and oxides, preferably based on at least one compound chosen from copper, steel and optionally oxidized stainless steel, iron oxide in Fe 2 O 3 and / or Fe 3 O 4 form, titanium nitride, optionally oxidized stainless steel and titanium nitride, preferably oxidized stainless steel, being preferred because of their mechanical and chemical stability, geometric thickness of said coating being in the range of values from 0.5 nm to 50.0 nm, when the semi-transparent functional coating is based on oxidized stainless steel, the geometric thickness of said coating is between 10.0 nm at 40.0 nm, a second transparent coating made of dielectric material based on at least one compound chosen from an oxide of at least one element selected from zinc, silicon, titanium, tin, aluminum, a mixed oxide of at least two of these elements, preferably the zinc-tin mixed oxide, a silicon nitride, an aluminum nitride, a mixed aluminum-silicon nitride, the nitrides being preferred their deposition resulting in little modification of the optical properties of the semi functional coating -transparent when the semi-transparent functional coating is based on copper or titanium nitride, said second transparent coating having an optical thickness of between 100.0 nm and 300.0 nm, when the semi-transparent functional coating is based on stainless steel oxidized iron oxide Fe203 form and / or Fe304 the optical thickness of the second transparent coating is between 150.0 nm and 245.0 nm, • a metal coating ensuring the opacity or quasi-opacity of said stack, l geometric thickness of said coating ensuring opacity or quasi-opacity being greater than or equal to 100.0 nm, preferably included in the range of ur ranging from 100.0 nm to 200.0 nm, more preferably of the order of 200.0 nm, said coating ensuring opacity or quasi-opacity comprising at least one metal, a metalloid a nitride or a carbide, preferably, said coating ensuring opacity comprises at least one metal, preferably said metal is selected from chromium, titanium, stainless steel, nickel-chromium alloys.
According to a particular embodiment of the preceding embodiment, the interferential coloring glass substrate for facing panel according to the invention is such that it comprises between the glass sheet and the first transparent coating of dielectric material, at least one coating improving the adhesion in a material having a refractive index at 550 nm between 1.40 and 1.65 such as silicon oxynitride, the geometric thickness of the coating improving the adhesion being at least greater than 0.0 nm and not more than 30.0 nm. Such a coating makes it possible to increase the stability of the stack
According to a particular embodiment of the two preceding modes, the interferentially colored glass substrate for facing panel according to the invention is such that it comprises above the metal coating providing opacity or quasi-opacity an overlayer, the material constituting said overcoat being based on a compound selected from carbon, silicon oxynitride, silicon nitride, silicon carbide, said overlayer having a geometric thickness at least greater than or equal to 5.0 nm and not more than 50.0 nm
The substrate according to any one of the three preceding embodiments is a substrate, possibly tempered, which can be used as a decorative facing panel for interior or exterior applications having color characteristics L *, a *, b * in the CIELAB system. such that 61.0 <L <75.0, 2.5 <a * <6.5, 2.0 <b * <8.0, more particularly L * = 68.0, a * = 4.5 , b * = 5.0 and measured according to the illuminant D65 at 10 ° in reflection on the side of the face of the glass sheet not covered by an UltraScan type apparatus and a reflectance of between 33% and 43%, more particularly equal to 38%, measured according to the illuminant D65 at 2 ° in reflection on the side of the face of the glass sheet not covered by an UltraScan type apparatus
According to a particular embodiment, the interferentially colored glass substrate, said substrate being preferably monolithic, for facing panel according to the invention is such that it comprises, consists, essentially consists of, successively from the glass sheet, at least: • a coating improving the silicon oxynitride adhesion, the geometric thickness of the coating improving the adhesion being at least greater than 0.0 nm and at most 30.0 nm or less, preferably of order of 15.0 nm, a first transparent coating made of silicon nitride dielectric material, said coating having an optical thickness of between 102.8 nm and 132.4 nm, preferably of the order of 122.6 nm, a semitransparent functional coating made of stainless steel, the geometrical thickness of said coating being in the range of values from 23.8 nm to 35.8 nm, preferentially of the order of 29.8 nm, a second transparent coating made of silicon nitride dielectric material, said coating having an optical thickness of between 120.5 nm and 232.1 nm, preferably of the order of 193.6. nm, a metal coating ensuring the opacity or quasi-opacity of said stack, the geometric thickness of said coating providing opacity or quasi-opacity being greater than or equal to 100.0 nm, preferably lying in the range of value. ranging from 100.0 nm to 200.0 nm, more preferably being of the order of 200.0 nm, said coating providing opacity or quasi-opacity being made of stainless steel.
• the substrate, possibly tempered, is suitable for use as a decorative facing panel for interior or exterior applications with L *, a *, b * color characteristics in the CIELAB system such as 61.0 <L * <75 , 0, 2.5 <a * <6.5, 2.0 <b * <8.0, more particularly L * = 68.0, a * = 4.5, b * = 5.0 and measured according to the illuminant D65 at 10 ° in reflection on the side of the face of the glass sheet not covered by an UltraScan type apparatus and a reflectance of between 33.0% and 43.0%, more particularly equal to 38, 0%, measured according to the illuminant D65 at 2 ° in reflection on the side of the face of the glass sheet not covered by an apparatus of the type; the colorimetric coordinates of said substrate being little dependent on the angle of observation. By the terms "colorimetric coordinates of said substrate being little dependent on the angle of observation" is meant a variation of the colorimetric coordinates ΔΕ * less than or equal to 6 and for any angle of observation ranging from 0 ° to 55 ° .
A second object of the invention is a method of manufacturing the interferential colored glass substrate for facing panel. The process for manufacturing the interferential colored glass substrate for facing panel according to the invention comprises the following successive steps: depositing on a glass sheet a first transparent dielectric coating by a vacuum cathode sputtering technique assisted by a magnetic field, the optical thickness of the first transparent coating being at least greater than or equal to 5.0 nm, preferably at least greater than or equal to 10.0 nm, more preferably at least greater than or equal to 20.0 nm, the most preferably at least greater than or equal to 50.0 nm, more preferably at least 70.0 nm or more, more preferably at least 100.0 nm, most preferably at least 110 or higher, 0 nm and at most less than or equal to 258.0 nm, preferably at most less than or equal to 190.0 nm, more preferably at most less than or equal to 180.0 nm, most preferably not more than 150.0 nm, more preferably less than or equal to 120.0 nm, preferably the optical thickness being within range of values ranging from 5.0 nm, preferably from 10.0 nm, more preferably from 20.0 nm to 258.0 nm, preferably from 50.0 nm to 190.0 nm, more preferably from 70.0 nm to 180 nm. , 0 nm, most preferably from 100.0 nm to 150.0 nm, preferably from 110.0 to 120.0 nm, • deposition of a semi-transparent functional coating by a vacuum assisted sputtering technique a magnetic field, the geometric thickness of the metallic functional coating being at least greater than or equal to 0.1 nm, preferably at least greater than or equal to 0.3 nm, more preferably at least greater than or equal to 0.5 nm and not more than 50.0 nm, preferably at most 25.0 nm or less, preferably the geometrical thickness being in the range of values ranging from 0.1 nm, preferably from 0.3 nm to 50.0 nm, preferably from 0, 5 nm to 25.0 nm, preferably said semitransparent functional coating having an absorption of between 10% and 70%, depositing a second transparent dielectric coating by a vacuum assisted cathode sputtering technique, the optical thickness of the second transparent coating being at least greater than or equal to 20.0 nm, preferably at least greater than or equal to 30.0 nm, more preferably at least greater than or equal to 100.0 nm, most preferably at least greater than or equal to 150.0 nm, preferably greater than or equal to 170.0 nm and not more than 300.0 nm, preferably at most less than or equal to at 250.0 nm, more preferably at most less than or equal to 210.0 nm, most preferably at most less than or equal to 200.0 nm, preferably the optical thickness being in the range of values from 20, 0 nm, preferably 30.0 nm, more preferably 100.0 nm to 300.0 nm, more preferably 150.0 nm to 250.0 nm, most preferably 170.0 to 200.0 nm.
Depositing a coating ensuring the opacity or the quasi-metallic opacity of said stack by a vacuum cathodic sputtering technique assisted by a magnetic field of a metal coating, the geometrical thickness of said coating ensuring opacity or quasi-opacity being at least greater than or equal to 30.0 nm, preferably at least greater than or equal to 50.0 nm, more preferably at least greater than or equal to 100.0 nm, the geometric thickness of the coating ensuring opacity or the quasi-opacity being at most less than or equal to 1000.0 nm, preferably at most less than or equal to 200.0 nm. Preferably, the geometrical thickness of said coating is in the range of values ranging from 30.0 nm to 1000.0 nm, preferably from 50.0 nm to 1000 nm, most preferably from 100.0 nm to 200.0 nm. .
A third object of the invention is the use of the interferential colored glass substrate for facing panel according to the invention as facade or lightening facing panel, preferably as facade cladding panel or monolithic spandrel. Other uses of this type of facing panel are also possible, for example include reflective or even partially reflective decorative products for indoor or outdoor use in the form of eg shelf elements, cabinet , door, ceiling, support, glass table, wall lamp, partition, shop front, ...
5. List of figures
The interferential colored glass substrate for facing panel according to the invention will now be illustrated with the aid of the following figures. The figures show in a nonlimiting manner a number of layer stack structures constituting said glass substrate for facing panel. These figures are purely illustrative and do not constitute a scaled presentation of stacking structures.
Fig. 1: Cross section of a glass substrate with interferential coloration for facing panel according to the invention
Fig. 2: Cross section of an interferentially colored glass substrate for facing panel according to the invention comprising a protective coating.
Fig. 3: Cross section of an interferentially colored glass substrate for facing panel according to the invention comprising a first transparent dielectric coating comprising two layers.
Fig. 4: Cross section of a glass substrate with interferential coloration for facing panel according to the invention, the protective coating comprises an adhesion layer.
FIG. 1 represents an example of a stack constituting an interferentially colored glass substrate for facing panel according to the invention. The interferentially colored glass substrate has the following structure from the glass sheet (1): • A first transparent dielectric coating (2) • A semi-transparent functional coating (3) • A second transparent electrical coating (4) • A coating ensuring opacity or near-opacity (5)
Figure 2 shows an alternative example of stacking. This comprises, in addition to the coatings already present in Figure 1, a protective coating. The interferentially colored glass substrate has the following structure from the glass sheet (1): • A first transparent dielectric coating (2) • A semi-transparent functional coating (3) • A second transparent dielectric coating (4) • A coating ensuring opacity or near-opacity (5) • A protective coating (6)
Figure 3 shows another example of stacking. This comprises, in addition to the coatings already present in FIG. 2, a first transparent dielectric coating comprising two layers. The interferentially colored glass substrate has the following structure from the glass sheet (1): • An adhesion improving coating (7) • A first transparent dielectric coating (2) • A semi-transparent functional coating (3) • A second transparent dielectric coating (4) • A coating providing opacity or near-opacity (5) • A protective coating (6)
Figure 4 shows an alternative example of stacking. This is distinguished from the structure described in Figure 2 by the presence of a protective coating (6) comprising two layers including an adhesion layer (60). The interferentially colored glass substrate has the following structure from the second face of the substrate (1): • A first transparent dielectric coating (2) • A semi-transparent functional coating (3) • A second transparent electrical coating (4) • A coating ensuring opacity or quasi-opacity (5) • A protective coating (6) comprising an adhesion layer (60) 6. Description of an embodiment of the invention
The interferentially colored glass substrate for a facing panel according to the invention, its embodiment and its use as a facade cladding panel or reflective decorative panel will now be characterized, with the aid of the examples of embodiments described and incorporated in the tables below. These examples are in no way limitative of the invention. The symbols SiON and SiN respectively represent silicon oxynitride and silicon nitride.
Examples of glass substrate according to the invention are presented in Table I below, the geometric thicknesses given in brackets are expressed in nanometers, the glass substrate presented can be used as a spandrel or as a reflective decorative facing panel.
Table I: Examples of glass substrate coating stack according to the invention. The thicknesses are geometric thicknesses. The glass substrate consists of a clear glass sheet not colored in the mass.
Table I

Table II shows the conditions according to which the successive deposits were made on a clear glass sheet not colored in the mass and corresponding to Example 9 shown in Table I. These deposits are made by magnetron sputtering in a laboratory installation.
Table II
Example 9 in the table
It satisfies in terms of chemical resistance properties to the standards IS012543-4, ISO10545-13, ASTM G53-88 (UV 1000 hours). In addition, good adhesion of the coating stack to the substrate is important. In order to qualify this membership, we defined a membership test, called the AWRT Test, which looks like this:
A flat circular Teflon head covered with a cotton fabric is dragged on the layer with a constant and integrated load. The surface of the layer covered by the friction of the fabric (reference: CODE 40700004 provided by ADSOL) is 2.81 cm 2 and the applied load is 3.850 g. Abrasion of the cotton on the coated surface will damage (or remove) the stack of coatings after a number of cycles (250 cycles, preferably 500 cycles). Cotton should be kept moist with deionized water for the duration of the test. The speed must be adjusted between 60 and 90 full oscillations (back-and-forth) per minute. The test is used to define the threshold where the layer will fade and / or the threshold where scratches appear in the stack of coatings. The sample is observed under an artificial sky to determine if discoloration or scratches can be seen on the sample. No detachment should be identified to pass the test.
Table III shows the evolution of the colorimetric coordinates expressed in the L *, a *, b * system of the interferential staining panel according to the invention of Example 1 and Example 10 presented in Table I during of the quenching process. The panel of interferential staining according to
the invention is dipped in an oven, said oven being preheated to a temperature at least greater than 600 ° C, preferably at a temperature equal to 670 ° C. The facing panel is tempered for a period of time ranging from 7 minutes to 15 minutes, the parameters L * tv> a, a * tv, a, b * tv, a are measured as a function of the quenching time. The parameters L *, a *, b * are measured with an "ULTRASCAN" device with a source conforming to the "daylight" illuminant normalized D65 by the CIE and at a solid angle of 10 °. The colorimetric coordinates L *, a *, b * measured after quenching are very little affected by the quenching process (quenching time). Indeed, we observe that the variation of these values expressed in the form of ΔΕ * ν, α, with AE * tv, D
where L * t, v, dD7min., 67o ° c / a * t, v, □□ 7min., 67o ° c / b * t, v, DD7mni., 67ooc represent the colorimetric coordinates L *, a *, b of the interferential colored glass substrate for facing panel after 7 minutes of quenching at a temperature equal to 670 ° C., and L * t, v, aps, t ° # a * t, v, DDtPs, t ° and b * t, v, DDtps, t ° respectively represent the colorimetric coordinates L *, a *, b * after a quench treatment of the same interferential coloring glass substrate for facing panel for a time tps at a temperature t °.
Table III

Tables IV, V, VI, VII and VIII present the simulation of the evolution of the colorimetric coordinates expressed in the system L *, a *, b * as a function of the angle of observation for glass substrates for facing panel , Examples 2, 3, 4, 11, 12 of Table I, according to the invention. These properties are compared with those of various layered glazing units marketed by AGC (Table IV: Stopray Vision-50T IGU, Table V: Stopray Vision-60T IGU, Table VI: Planibel Energy NT IGU, Table VII Stopray Galaxy IGU, Table VIII: Stopray Ultravision 50 IGU). The term IGU designates a structure of "double glazing" type formed from the sun side face of a first sheet of clear glass with a thickness of 6 mm and a second sheet of clear glass with a thickness of 4 mm, the distance separating the two sheets being 16 mm, the atmosphere trapped in the space between the two sheets being made of 90% argon, the first sheet of glass being a Stopray Vision-50T type layered glass, Stopray Vision-60T, Planibel Energy IGU NT, Stopray Ultravision 50 IGU, the layer being located on the inner face of the double glazing (position P2 in the terms used by the skilled person). The glass sheets constituting the layered glazing and the interferentially colored facing panel according to the invention having the same chemical composition. The measurements of the L *, a * and b * coordinates of the layered glazings were carried out with a "SPETRASCAN" apparatus with a source conforming to the standard daylighting illuminant D65 by the CIE and at a solid angle of 10 °. The simulations of the glass substrates according to the invention were carried out using the CODE program developed by W. Theis Coating designer 3.16. ΔΕ α represents the difference of the colorimetric coordinates with
depending on the angle a.
where AL * i, a represents the difference between the colorimetric coordinates L * iitl of an opaque zone consisting of the interferentially colored glass substrate for a facade panel obtained by simulation and a viewing zone corresponding to a measured layer glazing,
Aa * i (a represents the difference between the colorimetric coordinates a * i, a of an opaque zone consisting of the interferentially colored glass substrate for a facade panel obtained by simulation and a vision zone corresponding to a measured layer glazing
Ab * i, o represents the difference between the colorimetric coordinates b * j, a of an opaque zone consisting of the interferentially colored glass substrate for a facade panel obtained by simulation and a vision zone corresponding to a measured layer glazing .
Table IV:

Table V:
Table VI:

Table VII:
Table VIII

Table IX shows the colorimetric coordinates of Examples 5, 6, 7 before quenching and the evolution of the colorimetric coordinates of Examples 5 and 7 before and after quenching. The quenching time being of the order of 7 minutes at a temperature of the order of 670 ° C. The glass substrate consists of a clear glass sheet not colored in the mass.
Table IX
It is observed that Example 5 can be used as a spandrel. Example 7, despite the variations in its colorimetric coordinates as a result of the thermal quenching treatment, can be used both as a lighter and as a cladding panel that does not require thermal tempering, or as a siding panel that can be quenched. This type of panel can be used in the form of reflective or even partially reflective products, decorative products for indoor or outdoor use in the form for example of shelf elements, cabinet, door, ceiling, support , glass table, wall, partition, storefront, ...
Table X presents examples of panels of examples of glass substrate according to the invention that can be used as a spandrel associated with a Stopray Vision-50T type glazing layer, the geometrical thicknesses given in parentheses are expressed in nanometers, the glass substrate presented for use as a spandrel or as a decorative reflective wall panel. The glass substrate consists of a clear glass sheet not colored in the mass. The symbol ZS09 represents a mixed zinc tin oxide containing 10% by weight of tin relative to the total weight of the zinc and tin metals.
Paintings

Table XI shows the colorimetric coordinates of Example 20 of Table X before quenching before and after quenching. The quenching time varies from 7 to 15 minutes at a temperature of the order of 670 ° C. The glass substrate consists of a clear glass sheet not colored in the mass, the value ΔΕν, α is given with respect to the colorimetric coordinates L *, a *, b * measured after a quenching time of 7 minutes.
Table XI
It is observed that Example 20 can be used as a spandrel associated with a Stopray Vision-50T-type layer glazing because of the small variation in its colorimetric coordinates during the thermal quenching treatment.
Table XII presents examples of glass substrate according to the invention that can be used as a spandrel associated with a Stopray Vision-36T-type glazing layer marketed by the company AGC, the geometrical thicknesses given in parentheses are expressed in nanometers, the substrate presented glassware that can be used as a lighter or as a decorative reflective wall panel. The glass substrate consists of a clear glass sheet not colored in the mass. The symbol ZS09 represents a mixed zinc tin oxide containing 10% by weight of tin relative to the total weight of the zinc and tin metals.
Table XII

Table XIII presents the simulation of the evolution of the colorimetric coordinates expressed in the system L *, a *, b * as a function of the angle of observation for a glass substrate for facing panel, example 21 of Table XII, in accordance with to the invention. These properties are compared to those of a Stopray type vison vison-36T sold by the company AGC. The glass sheets constituting the layered glazing and the interferentially colored facing panel according to the invention having the same chemical composition. The measurements of the L *, a * and b * coordinates of the layered glazings were carried out with a "SPETRASCAN" apparatus with a source conforming to the standard daylighting illuminant D65 by the CIE and at a solid angle of 10 °. The simulations of the glass substrates according to the invention were carried out using the CODE program developed by W. Theis Coating designer 3.16. ΔΕ * ,, α represents the difference of the colorimetric coordinates with ΔΕ * ,, α =
depending on the angle a.
where Δί * ί, α represents the difference between the colorimetric coordinates L * iia of an opaque zone consisting of the interferentially colored glass substrate for a facade panel obtained by simulation and a vision zone corresponding to a measured layer glazing,
Aa * j, a represents the difference between the colorimetric coordinates a * i (0 of an opaque zone consisting of the interferentially colored glass substrate for a facade panel obtained by simulation and a vision zone corresponding to a measured layer glazing
Ab * i, 0 represents the difference between the colorimetric coordinates b * ii0 of an opaque zone consisting of the interferentially colored glass substrate for a facade panel obtained by simulation and a vision zone corresponding to a measured layer glazing.
Table XIII:
Table XIV shows the colorimetric coordinates of Example 28 of Table XII before quenching before and after quenching. The quenching time varies from 7 to 15 minutes at a temperature of the order of 670 ° C. The glass substrate consists of a clear glass sheet not colored in the mass, the value ΔΕν, α is given with respect to the colorimetric coordinates L *, a *, b * measured after a quenching time of 7 minutes.
Table XIV
It is observed that Example 28 can be used as a spandrel associated with a Stopray Vision-50T layer-type glazing because of the small variation in its colorimetric coordinates during the thermal quenching treatment.
Table XV shows examples of panels of examples of glass substrate according to the invention that can be used as a spandrel associated with a Stopray Neo type glazing layer marketed by the company AGC, the geometric thicknesses given in parentheses are expressed in nanometers, the presented glass substrate can be used as a spandrel or as a reflective decorative facing panel. The glass substrate consists of a clear glass sheet not colored in the mass. The symbol ZS09 represents a mixed zinc tin oxide containing 10% by weight of tin relative to the total weight of the zinc and tin metals.
Table XV

Tables XVI and XVII respectively show the simulation of the evolution of the colorimetric coordinates expressed in the system L *, a *, b * as a function of the observation angle for glass substrates for facing panel, example 29 of the table. XV and Example 36 of Table XV, conform to the invention. These properties are compared to those of a Stopray Neo layer glazing marketed by the company AGC. The glass sheets constituting the layered glazing and the interferentially colored facing panel according to the invention having the same chemical composition. The measurements of the L *, a * and b * coordinates of the layered glazings were carried out with a "SPETRASCAN" apparatus with a source conforming to the standard daylighting illuminant D65 by the CIE and at a solid angle of 10 °. The simulations of the glass substrates according to the invention were carried out using the CODE program developed by W. Theis Coating designer 3.16. ΔΕ * ί> α represents the difference of the colorimetric coordinates with ΔΕ * ,, α =
depending on the angle a.
where ΔΙ_ * ί> α represents the difference between the colorimetric coordinates L * i <a of an opaque zone consisting of the interferentially colored glass substrate for a facade panel obtained by simulation and a viewing zone corresponding to a layered glazing unit measured,
Aa * if0 represents the difference between the colorimetric coordinates a * iia of an opaque zone consisting of the interferentially colored glass substrate for a facade panel obtained by simulation and a vision zone corresponding to a measured layer glazing
Ab * i, a represents the difference between the colorimetric coordinates b * i, 0 of an opaque zone consisting of the interferentially colored glass substrate for a facade panel obtained by simulation and a vision zone corresponding to a measured layer glazing .
Table XVI:

Table XVII:
Examples of glass substrate according to the invention are also presented in Table XVIII below, the geometrical thicknesses given in brackets are expressed in nanometers.
Table XVIII: Examples of glass substrate coating stack according to the invention. The glass substrate consists of a clear glass sheet not colored in the mass. The type X / Y presentation indicates from the glass a first layer of material X followed by a second layer of material Y.


The chemical compounds appearing in the form TZO, AZO, ZS05, ZS09 correspond for TZO to a mixed oxide of titanium and zirconium, ΓΑΖΟ to an aluminum-doped zinc oxide, ZS05 to a mixed oxide of zinc and of tin comprising a percentage by weight of zinc of 50%, ZS09 with a mixed oxide of zinc and tin comprising a weight percentage of zinc of 90%, the weight percentage of zinc is expressed relative to the total weight metals present in the layer. Abbreviations link rev. Diel. transp, Rev. improving adhesion in mat. diell., link rev. Diel. transp. - stricto senso, Rev. tbd. semi-transp., 2nd rev. Diel. transp., Rev. ensuring opacity ep. Geo, Rev. to protect. respectively signify first transparent dielectric coating, coating improving adhesion of dielectric material, first transparent dielectric coating - stricto senso, semi-transparent functional coating, second transparent dielectric coating, protective coating. The abbreviation "ep. Geom. Means geometric thickness
Table XIX shows an example of interferential coloring glass substrate for facing panel according to the invention. The glass substrate consists of a clear glass sheet not colored in the mass.
Table XIX

Table XX shows the conditions according to which the successive deposits were made on a clear glass sheet not colored in the mass and corresponding to the example shown in Table XIX. These deposits are made by magnetron sputtering in a laboratory facility.
Table XX

The example in Table XIX satisfies in terms of chemical resistance properties to IS012543-4, ISO10545-13, ASTM G53-88 (UV 1000 hours).
Table XXI shows the optical properties of the interferentially colored facing panel according to the invention presented in Table XIX after quenching, these properties are compared to those of AGC type V50T layer glazing. The glass sheets constituting the layered glazing and the interferentially colored facing panel according to the invention having the same chemical composition. Measurements were made with a "SPETRASCAN" device with a source conforming to the C65 standard daylight illuminant by the CIE and at a solid angle of 10 °.
Table XXI:
101
Table XXII shows examples of glass substrate according to the invention that can be used as reflective decorative panel, the geometric thicknesses given in parentheses are expressed in nanometers.
Table XXII
The oxidized stainless steel layer of Example 38 is obtained by magnetized sputtering assisted by a magnetic field from a stainless steel target in an atmosphere containing mainly oxygen.
The set of examples presented in Table XXII satisfies in terms of the properties of resistance to the various tests described below: CASS test
The CASS test provides an indication of the corrosion resistance by subjecting the sample to an accelerated salt spray corrosion test in the presence of accelerated copper-acetic acid solution. The test sample is placed in a chamber at 50 ° C. and is subjected to the action of a mist formed by spraying with an aqueous solution containing 50 g / l of sodium chloride, 0.25 g / l of chloride anhydrous cuprous with sufficient glacial acetic acid to bring the pH of the sprayed solution to between 3.1 and 3.3. All the details of this test are described in the international standard ISO 9227-1990. The samples can be subjected to salt spray for different periods of time, after which the reflection properties of the artificially aged sample can be compared with the reflection properties of the freshly formed sample. It is found that the 120 hour exposure time provides a useful indication of the aging resistance of the sample. The CASS test is performed on square-shaped samples with a surface area of 100 cm2 and having freshly cut edges. After 120 hours of exposure to acetic acid-based fog containing the copper salt, each cell is subjected to microscopic examination. The main visible evidence of corrosion is a darkening of the coating ensuring the opacity or near-opacity and peeling of said coating on the perimeter of the reflective decorative panel. The extent of corrosion is observed at five regularly spaced locations on each of the two opposite edges of the sample and an arithmetic mean of the ten measurements is calculated. It is also possible to measure the maximum corrosion at the margin of the sample in order to obtain a result, also measured in micrometers, preferably the maximum corrosion is less than 300 μ, preferably less than 250 μ. In order to obtain a good representation of the measurement, the CASS test can be performed on ten samples and the arithmetic average of the ten samples calculated from the arithmetic mean of each sample. Preferably, the samples have less than five white spots per dm2 after the CASS test, preferably less than one white spot per dm2.
Test in a bain-marie and in a humid chamber
The bain-marie and wet chamber tests are designed to test the strength and / or compatibility with adhesives. A drop of glue with a diameter of about 5 cm is placed on the back of a sample of 10x10 cm, in other words on the coating providing opacity or near-opacity. The thickness of the glue is 2 mm, this thickness is obtained by the use of a spacer 2 mm thick. In the bain-marie test, the samples are dispensed into the water bath immediately after application of the glue. The water temperature of the water bath is regulated at 35 ° C. For each family of glue, a separate water bath is used. In the wet chamber test, the samples are placed in a wet chamber after 10 days of polymerization of the adhesive at room temperature and ambient conditions. The humid chamber is regulated at a temperature of 40 ° C. The two tests have a duration of 20 days. The evaluation of the results of these tests are classified under 4 headings: • Unacceptable: a modification of the "Haze" is observed when measured under daylight.
• limit of the acceptable: a modification of the "Haze" is observed when it is measured in a dark room under diffuse light.
• Acceptable: A modification of the "Haze" is observed when measured in a dark room under a spot.
• O.K .: no change in the "Haze" is observed.
Samples with a "limit of acceptable", "acceptable" and "OK" rating are considered to have met the 104 test. It should be noted that the modification of the "Haze" can appear under the place of glue or next to the place of glue. The adhesives used in the context of these tests are of the oxime, alkoxy, MS polymer and rubber type.
AWT test
The adhesion of the coating stack to the substrate is measured using the AWRT test described above.

权利要求:
Claims (15)
[1]
1. Interferentially colored glass substrate for facing panel comprising a glass sheet (1) covered on one of its faces by a stack of coatings, characterized in that said stack of coatings comprises successively from the glass sheet (1). ) at least: • a first transparent coating of dielectric material (2), the optical thickness of the first transparent coating (2) being at least greater than or equal to 5.0 nm and not more than 258.0 nm, • a semi-transparent functional coating (3), the geometric thickness of the semitransparent functional coating being at least 0.1 nm and not more than 50.0 nm, • a second transparent coating of dielectric material (4) the optical thickness of the second transparent coating (4) being at least 20.0 nm and not more than 300.0 nm, or depending on the opacity or quasi-opacity (5) of said stack, the geometric thickness of said opacity or quasi-opacity coating (5) being at least 30.0 nm or greater, said coating providing the opacity or quasi-opacity (5) comprising at least one metal, a metalloid, a nitride or a carbide.
[2]
2. interferential color glass substrate for facing panel according to claim 1, such that said stack of coatings comprises successively from the glass sheet at least: a first transparent coating of dielectric material (2), the optical thickness; the first transparent coating (2) being at least greater than or equal to 5.0 nm and not more than 258.0 nm, • a semi-transparent metallic functional coating (3), the attenuation thickness of the color of the metal coating being at least 0.3 nm and not more than 30.0 nm, the attenuation thickness of the color being equal to the product of the geometric thickness of the metallic functional coating by the part complex, k, of the index of refraction at 550 nm of the metal constituting said coating, • a second transparent coating of dielectric material (4), the optical thickness of u the second transparent coating being at least 20.0 nm and at most 300.0 nm or less, • a coating ensuring the opacity or quasi-opacity of said stack (5), the geometric thickness of said coating providing opacity or quasi-opacity being at least greater than or equal to 30.0 nm, said coating providing opacity or quasi-opacity comprising at least one metal, a metalloid a nitride or a carbide.
[3]
3. interferential colored glass substrate for facing panel according to any one of the preceding claims, characterized in that the semitransparent functional coating (3) and the coating ensuring opacity or quasi-opacity (5) are metallic coatings. .
[4]
4. interferential color glass substrate for facing panel according to any one of the preceding claims, characterized in that the glass sheet (1) consists of a clear soda-lime glass.
[5]
5. interferential color glass substrate for facing panel according to any one of the preceding claims, characterized in that it comprises, above the coating ensuring the opacity or quasi-opacity (5) of the stack, a coating protection device (6), the geometric thickness of the protective coating (6) being at least greater than or equal to 5.0 nm.
[6]
6. interferentially colored glass substrate for facing panel according to claim 5, characterized in that the material constituting at least one layer of the protective coating (6) is a chemical compound chosen from carbon, chromium, nickel, aluminum, stainless steel or an alloy of metals such as nickel-chromium (NiCr) or NiCrAlY,
[7]
7. interferential color glass substrate for facing panel according to any one of the preceding claims, characterized in that it comprises between the glass sheet and the first transparent coating of dielectric material (2), a coating improving the adhesion, said coating being of transparent dielectric material (7).
[8]
8. interferential color glass substrate for facing panel according to any one of the preceding claims, characterized in that at least one layer of the semi-transparent functional coating (3) and at least one layer of the coating ensuring the opacity or the quasi-opacity (5) of the stack are of the same chemical nature.
[9]
9. interferential color glass substrate for facing panel according to any one of claims 7 to 8, characterized in that it comprises, successively from the glass sheet, at least: • a coating improving the adhesion ( 7) of silicon oxynitride, the geometric thickness of the adhesion-improving coating being at least greater than 0.0 nm and at most 50.0 nm or less; • a first transparent coating of silicon nitride dielectric material ( 2), the geometric thickness of the transparent coating being at least greater than or equal to 10.0 nm and at most 129.0 nm or less, • a semi-transparent metallic functional coating (3), the thickness of the color attenuation of the metallic functional coating (3) being at least 0.3 nm and at most 30.0 nm or less, the attenuation thickness of the color being equal to the product of the geometric thickness of the functional coating by the complex part, k, of the refractive index at 550 nm of the metal constituting said coating. A second transparent coating made of silicon nitride dielectric material (4), the geometric thickness of the second transparent coating (4) being at least greater than or equal to 10.0 nm and at most less than or equal to 150.0 nm, An opacity or quasi-opacity metal coating (5) comprising at least one stainless steel layer, the geometric thickness of the metal coating being at least 30.0 nm or greater;
[10]
10. interferential color glass substrate for facing panel according to claim 8, characterized in that it comprises at least: a first transparent coating of dielectric material (2) based on silicon nitride, the geometric thickness of the first transparent coating being between 10.0 nm and 120.0 nm, • a semi-transparent metal functional coating (3) made of titanium, the geometric thickness of the first metallic functional coating being in the range of values from 1.0 nm at 10.0 nm, a second transparent coating made of silicon nitride dielectric material (4), the geometric thickness of the second transparent coating being in the range of values from 20.0 nm to 120.0 nm, A metal coating ensuring the opacity or quasi-opacity of the stack (5) comprising at least a first titanium layer, the geometric thickness of the metal coating; ensuring opacity or near-opacity being at least 30.0 nm or greater.
[11]
11. interferential color glass substrate for facing panel according to claim 9 characterized in that it comprises successively from the glass sheet (1), at least: • a coating improving the adhesion (7) of oxynitride; silicon, the geometric thickness of the coating improving the adhesion being at least greater than 0.0 nm and at most less than or equal to 50.0 nm, • a first transparent coating of silicon nitride dielectric material (2), the geometric thickness of the first transparent coating being at least greater than or equal to 10.0 nm and not more than 129.0 nm; • a semi-transparent metallic functional coating (3) made of stainless steel, the geometric thickness of said coating being in the range of values from 0.1 nm to 10.0 nm, • a second transparent coating of silicon nitride dielectric material (4), the geometrical thickness of the wherein the transparent coating is at least 10.0 nm and not more than 150.0 nm, or a metal coating providing opacity or quasi-opacity of the stack (5) comprising at least one layer, preferably the first layer, made of stainless steel, the geometric thickness of the metal coating being greater than or equal to 30.0 nm, preferably at least greater than or equal to 50.0 nm, more preferably at least greater than or equal to 100, 0 nm, the geometric thickness of the metal coating providing opacity or quasi-opacity being at most less than or equal to 1000.0 nm, preferably at most less than or equal to 200.0 nm. Preferably, the geometrical thickness of said coating is in the range of values ranging from 30.0 nm to 1000.0 nm, preferably from 50.0 nm to 1000.0 nm, most preferably from 100.0 nm to 200, 0 nm.
[12]
12. interferential color glass substrate for cladding panel according to any one of claims 5 to 11, characterized in that said glass substrate is quenchable.
[13]
13. interferential color glass substrate for facing panel according to any one of claims 9 to 11, characterized in that said interferentially colored glass substrate for facing panel constitutes the opaque zone of a fully glazed facade and has the same characteristics of color after quenching that those of the layered glazing constituting the area of vision with which said interferential staining glass substrate for cladding board is to be associated, said interferential staining glass substrate and layered glazing are such that their respective coatings are deposited on a glass sheet of identical chemical composition.
[14]
14. A method of manufacturing the interferential colored glass substrate for facing panel according to any one of the preceding claims characterized in that it comprises the following successive steps: • deposit on a glass sheet (1) of a first transparent dielectric coating (2) by magnetic field assisted vacuum sputtering technique, the optical thickness of the first transparent dielectric coating (2) being at least greater than or equal to 5.0 nm and not more than 258, 0 nm, • deposition of a semitransparent functional coating (3) by a magnetic field vacuum assisted sputtering technique, the geometric thickness of the semitransparent functional coating being at least greater than or equal to 0.1 nm and at most less than or equal to 50.0 nm, • deposition of a second transparent dielectric coating (4) by a spraying technique a cathodic vacuum assisted by a magnetic field, the optical thickness of the second transparent dielectric coating being at least greater than or equal to 20.0 nm and at most 300.0 nm, or less; the opacity or quasi-opacity (5) of said stack by a technique of vacuum sputtering assisted by a magnetic field, the geometrical thickness of said coating ensuring opacity or quasi-opacity (5) being greater than or equal to at 30.0 nm.
[15]
15. Use of the interferential staining glass substrate for facing panel according to any one of claims 1 to 13 as facade cladding panel.

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EA201291393A1|2013-07-30|

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US20130120842A1|2013-05-16|

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BR112013002224A2|2019-09-24|

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EA024159B1|2016-08-31|

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WO2012013796A2|2012-02-02|

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WO2012013796A3|2012-06-14|

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法律状态:
2019-04-01| MM| Lapsed because of non-payment of the annual fee|Effective date: 20180731 |

优先权:

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申请号 | 申请日 | 专利标题

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BE201000470|2010-07-29|

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BE201000470|2010-07-29|

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EP11165073|2011-05-06|

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EP11165048|2011-05-06|

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EP11165107|2011-05-06|

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EP11165048|2011-05-06|

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EP11165107|2011-05-06|

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EP11165073|2011-05-06|

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