• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    The invention relates to a method for producing a bimetallic catalyst containing palladium and platinum on a zeolitic carrier material, to a bimetallic catalyst that can be obtained by means of the method, and to the use of the catalyst in oxidation catalysis.
    公开号:AU2013220339A1
    申请号:U2013220339
    申请日:2013-02-18
    公开日:2014-09-25
    发明作者:Mika ENDLER；Frank Klose；Patrick Muller；Grigory Reznikov；Margit Schuschke；Andane Stein；Arno Tissler；Florian WEILERMANN
    申请人:Clariant Produkte Deutschland GmbH；
    IPC主号:B01J29-068
    专利说明:
    WO 2013/121041 1 PCT/EP2013/053185 Platinum/palladium zeolite catalyst The present invention relates to a method for producing a bimetallic catalyst comprising palladium and platinum on a zeolitic support material, 5 to a bimetallic catalyst obtainable by the method, and also to the use of the catalyst in oxidation catalysis. Supported precious metal catalysts in which relatively small precious metal particles are deposited on the surface of a solid support are used in 10 particular in synthesis-chemical and petrochemical processes to convert a very wide variety of starting materials into desired intermediates or end products and/or to chemically refine various cuts of petroleum processing. Moreover, supported precious metal catalysts are used in particular also as oxidation catalysts in exit-air purification for the oxidation of mostly organic 15 compounds. Supported catalysts laden with precious metal are generally produced by means of a multistage method. In this, for example in a first step, a support material is impregnated with a precious metal salt solution of the desired 20 precious metal. After removing the solvent from the support material in a subsequent step, the support material is then calcined in a further step, during which the precious metal can be converted to a metallic or oxidic form - often mixed phases of the two - as a result of the thermal treatment. In many cases, the oxide form is already the catalytically active species, 25 meaning that the catalyst can be used in this form. It is moreover possible to convert the oxidic precious metal species in a further step, for example by means of hydrogen, carbon monoxide or wet-chemical reducing agent, into the highly disperse precious metal of oxidation state 0, which can likewise act as catalytically active species. 30 The activity of supported precious metal catalysts is generally dependent on the size of the precious metal (oxide) particles. The supported precious metal catalysts known in the prior art have the disadvantage that they lose activity in the course of being used on account of a sintering of the precious 35 metal (oxide) particles to give larger units and an associated reduction in catalytically active surface area. In this connection, the rate of the so-called thermal aging process is dependent on the temperature level at which the WO 2013/121041 2 PCT/EP2013/053185 catalyst is used. In fact, as the use temperature rises, the rate of said aging process increases, the cause of which is presumably an increased mobility of the precious metal (oxide) particles on the support material surface and an associated increased sintering tendency. 5 In the prior art, attempts have already made to produce precious metal catalysts which, in high temperature applications, have a high activity and an only slight thermal aging process. 10 DE 10 2009 053 919 and DE 10 2009 053 944 disclose catalysts in which the precious metal is located as a matter of priority in the pores of zeolites. This results in a very high activity and aging stability of the catalyst. A disadvantage is the need for high calcination temperatures of more than 7000C for decomposing the sulfite precursor compounds used. A further 15 disadvantage of these catalysts is moreover the low sulfur tolerance, which is further reduced by using the sulfite precursor compounds. Moreover, the in particular platinum-containing catalysts known in the prior art exhibit too low an activity as regards the oxidation of alkanes. 20 The object of the present invention was therefore to provide a catalyst which, in oxidation reactions, in particular in the oxidation of alkanes, has a high activity as well as a high aging and sulfur resistance. The object was achieved by a method for producing a bimetallic catalyst 25 comprising the steps: a) impregnation of a zeolitic support material with sulfur-free Pt and Pd precursor compounds, b) drying of the impregnated zeolitic support material in air, c) calcination of the impregnated and dried zeolitic support 30 material under protective gas. Surprisingly, it has been found that, compared to the catalysts known in the prior art, bimetallic Pt/Pd zeolite catalysts can be produced by means of the modified production method which, during the oxidation reaction, in 35 particular during the reaction of alkanes, have an activity that is twice as high compared to conventional catalyst systems (based on the palladium content), without a deterioration in the aging and sulfur resistance arising.
    WO 2013/121041 3 PCT/EP2013/053185 Within the context of this invention, protective gases are gases or gas mixtures which are used as inert protecting atmosphere and are used for avoiding undesired chemical reactions, for example in order to keep 5 oxygen and/or nitrogen away from sensitive substances. The protective gases used are preferably noble gases, e.g. argon, helium, neon or nitrogen. According to one embodiment of the method according to the invention, the 10 impregnation of the zeolitic support material with Pt and Pd precursor compounds takes place by impregnating the zeolite material with a solution which comprises both the Pt as well as the Pd precursor compound. This ensures that the surface of the zeolite material is covered largely uniformly with Pt and Pd precursor compounds. The essentially uniform coating of 15 the zeolite material with the Pt and Pd precursor compounds forms the basis for the fact that in the subsequent calcination step, which leads to the decomposition of the Pt and Pd precursor compounds, and/or during conversion of the metal compound to the corresponding metal or to the metal oxide, the zeolite material is laden largely uniformly with the Pt and 20 Pd particles. The impregnation of the zeolitic support material can be carried out using all of the methods known to the person skilled in the art. Particularly preferably, the impregnation of the zeolite material takes place according to 25 the "incipient wetness" method known to the person skilled in the art. The Pt and Pd precursor compound used can be for example nitrates, acetates, oxalates, tartrates, formates, amines, sulfides, carbonates, halides or hydroxides of the corresponding precious metals, with nitrates being preferred. The precursor compounds here should be essentially sulfur-free. 30 In the context of the invention, it may also be preferred that the Pt and the Pd precursor compounds have the same anion, for example nitrate. The drying of the impregnated zeolitic support material preferably takes place below the decomposition point of the Pt and Pd precursor compound. 35 The drying preferably takes place in air. Drying temperatures are mostly in the range from 50 to 1500C, preferably 80 to 1200C.
    WO 2013/121041 4 PCT/EP2013/053185 After the drying, a calcination step takes place. The calcination takes place preferably at temperatures of 300 to 600cC, more preferably at 400 to 5500C. The calcination time is preferably 1 to 8 h, more preferably 2 to 6 h and in particular about 3-5 h. 5 According to a further embodiment of the process, the method comprises the further steps: d) production of a washcoat from the impregnated and calcined zeolitic support material, 10 e) coating of a support body with the washcoat, f) drying and calcination of the coated support body in air. In the method according to the invention, the support material used for the impregnation steps is a zeolitic support material or a zeolite material. These 15 two terms are used synonymously in the context of the invention. In the context of the present invention, a zeolite material is understood according to a definition of the International Mineralogical Association (D.S. Coombs et al., Can. Mineralogist, 35, 1997, 1571) as meaning a 20 crystalline substance with a structure characterized by a backbone made of tetrahedra joined together. Here, each tetrahedron consists of four oxygen atoms which surround a central atom, with the backbone containing open cavities in the form of channels and cages which are normally occupied by water molecules and extra backbone cations, which can be exchanged. 25 The channels of the material are large enough here to permit access to guest compounds. In the hydrated materials, the dehydration takes place at least at temperatures below about 4000C and is for the most part reversible. 30 According to one embodiment of the method according to the invention, it is provided that the aforementioned zeolite material is preferably a microporous or a mesoporous zeolite material. Here, the terms "microporous zeolite material" and "mesoporous zeolite material" should be understood according to the division of porous solids according to IUPAC 35 (International Union of Pure and Applied Chemistry) as meaning zeolite materials whose pores have a diameter of less than 2 nm or a diameter of 2 nm to 50 nm.
    WO 2013/121041 5 PCT/EP2013/053185 The zeolite material to be used in the method according to the invention can preferably correspond to one of the structure types below: ABW, ACO, AEI, AEL, AEN, AET, AFG, AFI, AFN, AFO, AFR, AFS, AFT, AFX, AFY, 5 AHT, ANA, APC, APD, AST, ASV, ATN, ATO, ATS, ATT, ATV, AWO, AWW, BCT, BEA, BEC, BIK, BOG, BPH, BRE, CAN, CAS, CDO, CFI, CGF, CGS, CHA, CHI, CLO, CON, CZP, DAC, DDR, DFO, DFT, DOH, DON, EAB, EDI, EMT, EON, EPI, ERI, ESV, ETR, EUO, EZT, FAR, FAU, FER, FRA, GIS, GIU, GME, GON, GOO, HEU, IFR, IHW, ISV, ITE, ITH, 10 ITW, IWR, IWV, IWW, JBW, KFI, LAU, LEV, LIO, LIT, LOS, LOV, LTA, LTL, LTN, MAR, MAZ, MEl, MEL, MEP, MER, MFI, MFS, MON, MOR, MOZ, MSE, MSO, MTF, MTN, MTT, MTW, MWW, NAB, NAT, NES, NON, NPO, NSI, OBW, OFF, OSI, OSO, OWE, PAR, PAU, PHI, PON, RHO, RON, RRO, RSN, RTE, RTH, RUT, RWR, RWY, SAO, SAS, SAT, SAV, 15 SBE, SBS, SBT, SFE, SFF, SFG, SFH, SFN, SFO, SGT, SIV, SOD, SOS, SSY, STF, STI, STT, SZR, TER, THO, TON, TSC, TUN, UEI, UFI, UOZ, USI, UTL, VET, VFI, VNI, VSV, WEI, WEN, YUG and ZON, with zeolite materials having a 12-ring pore system (BEA, FAU) and of the structure type beta (BEA) being particularly preferred. The above three-letter code 20 nomenclature corresponds here to the "IUPAC Commission of Zeolite Nomenclature". According to the invention, preference is likewise given to the members of mesoporous zeolite materials of the family which are summarized in the 25 literature under the name "MCM", this name not being a specific structure type (cf. http://www.iza-structure.org/databases). According to the invention, particular preference is given to mesoporous silicates which are referred to as MCM-41 or MCM-48. MCM-48 has a 3D structure of mesopores, as a result of which the catalytically active metal in the pores is 30 particularly readily accessible. MCM-41 is very particularly preferred and has an hexagonal arrangement of mesopores with uniform size. The MCM-41 zeolite material has an Si0 2 /Al 2 0 3 molar ratio of preferably greater than 100, more preferably of greater than 200 and most preferably of greater than 300. Further preferred mesoporous zeolite materials which 35 can be used in the context of the present invention are those which are referred to in the literature as MCM-1, MCM-2, MCM-3, MCM-4, MCM-5, MCM-9, MCM-10, MCM-14, MCM-22, MCM-35, MCM-37, MCM-49, WO 2013/121041 6 PCT/EP2013/053185 MCM-58, MCM-61, MCM-65 or MCM-68. Which zeolitic support material or zeolite material is to be used in the method according to the invention depends in the first instance on the 5 intended use of the catalyst to be produced by means of the method according to the invention. A large number of methods is known in the prior art for tailoring the properties of zeolite materials, such as for example the structure type, the pore diameter, the channel diameter, the chemical composition, the ion exchangeability and also activation properties, to a 10 corresponding intended application. The zeolite material to be used in the method according to the invention can be for example a silicate, an aluminum silicate, an aluminum phosphate, a silicon aluminum phosphate, a metal aluminum phosphate, a 15 metal aluminum phosphosilicate, a gallium aluminum silicate, a gallium silicate, a boroaluminum silicate, a borosilicate, a titanium silicate, a titano aluminum phosphate (TAPO) or a titano-silicon aluminum phosphate (TAPSO), with aluminum silicates and titanium silicates being particularly preferred. 20 According to the definition of the International Mineralogical Association (D.S. Coombs et al., Can. Mineralogist, 35, 1997, 1571), the term "aluminum silicate" is understood as meaning a crystalline substance with three-dimensional network structure of the general formula 25 M"*[(AIO 2 )x(SiO 2 )y]xH 2 0, which is composed of SiO 4
    /
    2 and A104/ 2 tetrahedra which are joined by common oxygen atoms to give a regular three dimensional network. The atomic ratio of Si/Al = y/x is always greater than/equal to 1 according to the so-called "L6wenstein rule", which precludes the adjacent occurrence of two adjacent negatively charged 30 A104/ 2 tetrahedra. Although there are more exchange places available for metals in the case of a low Si/Al atomic ratio, the zeolite becomes increasingly hydrophilic and thermally unstable. In the context of the present invention, the aforementioned zeolite materials 35 can be used either in the alkali metal form, for example in the Na and/or K form, or in the alkaline earth metal form, ammonium form or in the H form in the process. Moreover, it is also possible to use the zeolite material in a WO 2013/121041 7 PCT/EP2013/053185 mixed form, for example in an alkali metal/alkaline earth metal mixed form. The invention further provides a catalyst which has been produced by the method according to the invention, wherein the catalyst comprises a 5 bimetallic catalytically active composition comprising Pt and Pd on a zeolitic support material. Preferably, the bimetallic catalytically active composition, i.e. the zeolitic material laden with precious metal, has a BET surface area of more than 10 400 m 2 /g. The bimetallic catalytically active composition preferably has a Pt content of 0.2 to 1.5% by weight, based on the catalytically active composition. 15 Furthermore, the bimetallic catalytically active composition preferably has a Pd content of 0.8 to 4.0% by weight, based on the catalytically active composition. The catalytically active composition can preferably be processed with a 20 preferably silicatic binder to give a washcoat and be applied as washcoat coating to a support body. The mass ratio of binder/catalytically active composition here is 0.05-0.5, preferably 0.1-0.3 and particularly preferably 0.15-0.25, based in each case on the solids fractions of binder and catalytically active composition. 25 The catalytically active composition can likewise be in the form of an unsupported catalyst, for example as extrudate of a zeolite coated with precious metal. 30 The catalyst in the form of a coating catalyst or of an unsupported catalyst moreover has 0.5 to 3.0% by weight of Pt, preferably 0.15 to 1.45% by weight of Pt, and also 1 to 5% by weight of Pt, preferably 0.6 to 3.8% by weight of Pd, based on the solids fraction of the unsupported catalyst or of the coated washcoat. 35 The Pd/Pt weight ratio in the bimetallic catalytically active composition or in the washcoat coating is preferably in the range from 6:1 to 1:1 and WO 2013/121041 8 PCT/EP2013/053185 particularly preferably about 4:1 to 2:1. Here, the Pt and Pd is located essentially in the pores of the zeolitic support material. 5 Pt and Pd are present here preferably in aggregates of < 5 nm. The precious metal aggregate size/cluster size is essentially determined by the size of the pore intersections. In the case of the BEA zeolite with a 10 three-dimensional system of pores of max. 7.7 angstrom (0.77 nm), the diameter of a pore intersection is about 12 angstrom, i.e. 1.2 nm. This corresponds to a cluster size of about 100 atoms. Moreover, the invention provides the use of the above-described catalyst 15 as oxidation catalyst, in particular as catalyst for the oxidation of alkanes, for example ethane, methane, propane etc., but also of olefins and solvent vapors. The invention is now illustrated in more detail by reference to examples, 20 although these should not be considered to have a limiting effect on the scope of protection. Here, reference is additionally made to the figures. Figure 1: shows the XRD spectrum of a PtPd-BEA150 zeolite produced according to the invention (bottom) and also of 25 comparative example 1 (top); Figures 2 and 3: show IR spectra of the PtPd-BEA150 zeolite according to the invention, and also of comparative example 1 following CO chemisorption with and without metered 30 addition of adamantanecarbonitrile; Figures 4a, 4b: show performance data in the oxidation of alkanes (methane, ethane) of the PtPd-BEA150 zeolite according to the invention, and also of comparative examples 1 and 35 2, in each case with different precious metal chargings in the fresh state; WO 2013/121041 9 PCT/EP2013/053185 Figures 5a, 5b: show performance data in the oxidation of alkanes (methane, ethane) of the PtPd-BEA150 zeolite according to the invention, and also of comparative example 2 with different precious metal chargings in the fresh state, 5 following thermal aging and after poisoning with SO 2 ; Figures 6a, 6b: show performance data in the oxidation of ethylene and ethyl acetate of the PtPd-BEA1 50 zeolite according to the invention, and also of comparative example 2, in each 10 case fresh, following thermal aging and after poisoning with S02; Figure 7: shows a performance comparison of inventive vs. comparison catalyst. 15 Example 1: The catalysts according to the invention were produced in a 2-step process. In a first step, a BEA150 zeolite was supplied with a solution of 20 platinum nitrate and palladium nitrate by means of "incipient wetness" technology. The supplied zeolite was then dried for 16 h under air at 90C and then calcined under argon for 5 h at 5500C. Comparative example 1: 25 As comparative example 1, a BEA1 50 zeolite was supplied in an analogous manner with platinum nitrate and palladium nitrate by means of "incipient wetness" technology, dried at 900C and then calcined under air for 5 h at 550 *C. 30 Table 1 summarizes the properties of the zeolite samples (formulation according to the invention and comparative example 1) produced in the course of the investigation. 35 Example 2: Production of a washcoat: In a second step, the calcined PtPd zeolite according to the invention and WO 2013/121041 10 PCT/EP2013/053185 also that of comparative example 1 were processed with Bindzil (binder material) and water to give a washcoat and this washcoat was then coated onto corderite honeycombs. The coated corderite honeycombs were blown out with compressed air, then dried overnight at 1500C under air and finally 5 calcined for 3 h at 5500C. Batch PtPd-BEA1 50 Formulation according Comparative to the invention, formulation 1, calcination under argon calcination under air Pt [% by weight] 0.69 0.78 Pd [% by weight] 2.1 2.3 BET surface area [m 2 /g] 601 585 Table 1: PtPd-BEA 150 zeolites (step 1) Figure 1 shows the XRD spectrum of a PtPD-BEA150 zeolite according to 10 the invention produced according to the above procedure, as well as that of the comparison formulation. In both samples, no reflections for metallic Pt and Pd are present. The signals for precious metal oxides are also barely detectable. All large reflections contain virtually exclusively signal fractions of the BEA150 zeolite. It can be concluded from this that both Pt and also 15 Pd are present in highly disperse form favorable for the performance. The absence of precious metal agglomerates > 5 nm is thus clearly demonstrated. Figures 2 and 3 show the IR spectra of the PtPd-BEA150 zeolite according 20 to the invention, as well as of comparative example 1 following CO chemisorption with and without the metered addition of adamantanecarbonitrile. Measuring IR spectra after CO chemisorption is a widespread technique for investigating the nature and dispersion of precious metal species in precious-metal-containing catalysts. CO can here 25 achieve precious metal species both on the inside and outside of the pores and interact with them and, in so doing, generate signals that can be evaluated by means of IR spectroscopy. Nitriles such as adamantanecarbonitrile enter into a greater interaction with 30 precious metal species and are therefore preferentially adsorbed by these. It is therefore possible to mask precious metal species for the CO WO 2013/121041 11 PCT/EP2013/053185 chemisorption with the help of nitriles. Nitrile molecules with diameters greater than or equal to the pores of the zeolites are unable to penetrate into zeolite pores and therefore selectively mask precious metal species on the outside of the pores. Adamantanecarbonitrile has a molecular diameter 5 > 0.6 nm. This is comparable to the diameters of the pore openings of the BEA zeolite (0.56-0.7 nm), and consequently adamantanecarbonitrile can be used in order to mask precious metal species on the outside of the zeolite pores in a selective manner for the CO chemisorption. The IR absorption bands of adamantanecarbonitrile itself do not interfere here with 10 the IR absorption bands of the CO chemisorption on precious metal species. For the IR investigations described below, samples of the PtPd-BEA150 zeolite according to the invention and of comparative sample 1 were firstly 15 degassed at 10-6 mbar for 3 hours at 4000C and then reduced with nitrogen for 30 min the IR measuring cell. The samples were then supplied with 20 mbar of CO and a first IR spectrum was recorded. The CO was then further removed by gassing at 4000C under vacuum for 30-60 min. After cooling, adamantanecarbonitrile vapor was dosed onto the samples in 20 order to mask the precious metal species on the outside of the zeolite pores, followed by a further supplying with 20 mbar of CO. The second IR spectrum was then recorded. The difference between the two IR spectra shows the precious metal species which are located on the outside of the zeolite pores and can therefore be masked by adamantanecarbonitrile 25 vapor. All the spectra themselves were recorded using a thermo 4700 FTIR spectrometer with a resolution of 4 cm- 1 . Figure 2 shows the IR spectra of the CO chemisorption of the Pt-Pd-BEA150 zeolite according to the invention, figure 3 shows that of 30 comparative example 1, in each case before and after selective masking of the precious metal species on the outside of the zeolite pores with adamantanecarbonitrile. Firstly to be noted are for both samples the two main bands around 2000 cm 1 (assignable to Pd) and 2100 cm 1 (assignable to Pt). Both bands are attenuated by the 35 adamantanecarbonitrile addition, the attenuation in the case of the Pt-Pd-BEA150 zeolite according to the invention being less marked than in the case of comparative example 1. This means there are more precious WO 2013/121041 12 PCT/EP2013/053185 metal species in the zeolite pores in the Pt-Pd-BEA150 zeolite according to the invention than in comparative example 1. Furthermore, in the case of comparative example 1, at 1900 cm- 1 there is an absorption band that can be masked virtually completely by adamantanecarbonitrile addition and 5 which is not present in the Pt-Pd-BEA150 zeolite according to the invention. Also in the case of more highly charged ("supercharged") PtPd-BEA1 50/Ar zeolites, the 1900 cm- 1 band can arise, for example at 1.13% Pt and 3.4% 10 Pd, but not at 0.92% Pt/2.8% Pd. However, the former material exhibits a considerably lower performance in the alkane oxidation. Table 2 shows the catalyst sample produced therefrom (including comparison sample). Figures 4a-c and 5a, 5b summarize the performance 15 data obtained, measured in the simultaneous oxidation of 800 ppmv CO, 1000 ppmv methane, 360 ppmv ethane, 200 ppmv ethylene and 180 ppmv propane in a carrier gas consisting of 10% oxygen and 3% water in nitrogen. The measurements were carried out at a GHSV of 40 000 h 1 . The catalyst samples were then tested again in the oxidation of 200 ppmv 20 ethyl acetate in air at a GHSV of 40 000 h- 1 . The aging was carried out with the samples of the fresh test, these were treated for 24 h at 6500C in a muffle furnace and then tested again. For the thionation, fresh samples were exposed to a mixture of 100 ppm SO 2 , 250 ppm C 3
    H
    8 and 5% H 2 0 in air for 125 h at 500 C. The activity loss of EnviCat 50300 in the alkane 25 oxidation is typically about 60-75% under these conditions.
    WO 2013/121041 13 PCT/EP2013/053185 Honeycomb Pt [% by weight] Pd [% by weight] number PtPd-BEA150 - 1 0.13 0.39 formulation according to 2 0.37 1.11 the invention and catalyst PtPd-BEA150 - 1 0.17 0.49 comparative example 1 2 0.70 2.1 Comparative example 2 1 0.35 1.05 (EnviCat 50300) 2 0.62 1.85 Table 2: Produced PtPd-BEA 150 zeolite catalyst samples (step 2) and comparison samples The data shown in figures 4a, 4b and 5a, 5b show that the catalyst 5 honeycombs based on the formulation according to the invention have a performance in the alkane oxidation that is considerably increased compared to comparative example 2 (Envicat 50300), with a comparable conversion level being achieved in the case of the formulation according to the invention with only half of the precious metal content compared to 10 Envicat 50300. This is true for fresh, aged and sulfur-poisoned catalyst samples. Comparative example 1, by contrast, exhibits barely any significant activity. As can be seen in figures 6a and 6b, the advantages of the catalysts according to the invention are also given in the oxidation of ethyl acetate. In the case of the oxidation of ethylene, catalysts according 15 to the invention and comparison catalysts exhibit an approximately identical performance. Further results are shown in figure 7. Here, the methane conversion of various catalysts according to the invention and known catalysts was 20 compared: a) of a PtPd-BEA150 honeycomb, in which the precious metal zeolite powder was calcined in air (BEEZ 00664-1); b) of a PtPd-BEA150 honeycomb, which was firstly calcined in 25 air and then treated for five hours at 5000C with a mixture of about 1% hydrogen in nitrogen (BEEZ 00664-3), c) and of two argon-calcined PtPd-BEA150 honeycombs according to the invention with comparable precious metal WO 2013/121041 14 PCT/EP2013/053185 content (BEEZ 00387-2) and with considerably lower precious metal content (BEEZ 00812-1) compared to the comparative examples. 5 As can be seen clearly, the hydrogen reduction only influences the activity to an insignificant degree. It is not possible to convert by means of reduction an air-calcined catalyst with low methane oxidation activity to one with higher methane oxidation activity, such as the argon-calcined variants according to the invention. 10
    权利要求:
    Claims (17)
    [1] 1. A method for producing a bimetallic catalyst comprising the steps: 5 a) impregnation of a zeolitic support material with sulfur-free Pt and Pd precursor compounds, b) drying of the impregnated zeolitic support material in air, c) calcination of the impregnated and dried zeolitic support material under protective gas. 10
    [2] 2. The method as claimed in claim 1, wherein the Pt and Pd precursor compounds used are solutions of nitrates.
    [3] 3. The method as claimed in claim 1 or 2, wherein the calcination takes 15 place at temperatures from 350 to 6500C.
    [4] 4. The method as claimed in one of claims 1 to 3, wherein the drying of the impregnated zeolitic support material takes place below the decomposition point of the Pt and Pd precursor compounds. 20
    [5] 5. The method as claimed in one of claims 1 to 4, comprising the further steps: d) production of a washcoat from the impregnated and calcined 25 zeolitic support material, e) coating of a support body with the washcoat, f) drying and calcination of the coated support body in air.
    [6] 6. The method as claimed in claim 5, wherein the calcination takes 30 place at temperatures from 300 to 6000C.
    [7] 7. A catalyst produced by a method as claimed in one of claims 1 to 6, wherein the catalyst comprises a bimetallic catalytically active composition comprising Pt and Pd on a zeolitic support material. 35
    [8] 8. The catalyst as claimed in claim 7, wherein the bimetallic catalytically active composition has a BET surface area of more than WO 2013/121041 16 PCT/EP2013/053185 400 m 2 /g.
    [9] 9. The catalyst as claimed in one of claims 7 and 8, wherein the bimetallic catalytically active composition has a Pt content of 0.2 to 5 1.5% by weight, based on the catalytically active composition.
    [10] 10. The catalyst as claimed in one of claims 7 to 9, wherein the bimetallic catalytically active composition has a Pd content of 0.8 to 4.0% by weight, based on the catalytically active composition. 10
    [11] 11. The catalyst as claimed in one of claims 7 to 10, wherein the catalytically active composition is applied as washcoat coating to a support body. 15
    [12] 12. The catalyst as claimed in claim 11, wherein the catalyst has 0.5 to 3% by weight of Pt based on the coated washcoat.
    [13] 13. The catalyst as claimed in claim 11 or 12, where the catalyst has 1 to 5% by weight of Pd based on the coated washcoat. 20
    [14] 14. The catalyst as claimed in one of claims 7 to 13, wherein the bimetallic catalytically active composition or the washcoat coating has a Pd/Pt weight ratio of 6:1 to 1:1. 25
    [15] 15. The catalyst as claimed in one of claims 7 to 14, wherein the Pt and Pd is located essentially in the pores of the zeolitic support material.
    [16] 16. The catalyst as claimed in one of claims 7 to 15, where the Pt and Pd is present in aggregates of < 5 nm. 30
    [17] 17. The use of a catalyst as claimed in one of claims 7 to 16 as oxidation catalyst.
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    同族专利:
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    EP2814605A1|2014-12-24|
    引用文献:
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    法律状态:
    2016-06-23| FGA| Letters patent sealed or granted (standard patent)|
    2020-09-17| MK14| Patent ceased section 143(a) (annual fees not paid) or expired|
    优先权:
    申请号 | 申请日 | 专利标题
    DE102012003032A|DE102012003032A1|2012-02-17|2012-02-17|Platinum / palladium-zeolite catalyst|
    DE102012003032.0||2012-02-17||
    PCT/EP2013/053185|WO2013121041A1|2012-02-17|2013-02-18|Platinum/palladium zeolite catalyst|
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