• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    The present invention relates to a fuel cell system (1) comprising at least one fuel cell stack (10) having an anode portion (11) and a cathode portion (12), a cathode supply portion (20) for supplying cathode gas (30) to the cathode portion (12), an anode supply portion (21) for supplying anode gas (31) to the anode section (11), a cathode exhaust section (22) for discharging cathode exhaust gas (32) from the cathode section (12), an anode exhaust section (23) for discharging anode exhaust gas (33) from the anode section (11 wherein the cathode exhaust portion (22) and the anode exhaust portion (23) open into an exhaust gas burner (40) for at least partially burning the cathode exhaust gas (32) and the anode exhaust gas (33), and an exhaust gas exhaust portion (24) for discharging fuel cell exhaust gas (34) from the exhaust gas burner (40). Furthermore, the present invention relates to a stationary power plant (100) for generating electrical energy, comprising a fuel cell system (1) and a method for operating a fuel cell system (1) or a stationary power plant (100) with a fuel cell system (1), wherein the fuel cell system ( 1) generates electrical energy for a downstream electrical consumer network (101).
    公开号:AT521209A1
    申请号:T503702018
    申请日:2018-05-03
    公开日:2019-11-15
    发明作者:Martin Hauth Dr
    申请人:Avl List Gmbh；
    IPC主号:
    专利说明:

    Summary
    The invention relates to a fuel cell system (1), comprising at least one fuel cell stack (10) with an anode section (11) and a cathode section (12), a cathode supply section (20) for supplying cathode gas (30) to the cathode section (12), and an anode supply section (21) for supplying anode gas (31) to the anode section (11), a cathode off-gas section (22) for discharging cathode off-gas (32) from the cathode section (12), an anode off-gas section (23) for discharging anode off-gas (33) from the anode section (11 ), the cathode exhaust gas section (22) and the anode exhaust gas section (23) opening into an exhaust gas burner (40) for at least partially burning the cathode exhaust gas (32) and the anode exhaust gas (33), and an exhaust gas discharge section (24) for removing fuel cell exhaust gas (34) from the exhaust burner (40). The invention also relates to a stationary power plant (100) for generating electrical energy, comprising a fuel cell system (1) and a method for operating a fuel cell system (1) or a stationary power plant (100) with a fuel cell system (1), the fuel cell system (1) 1) generates electrical energy for a downstream electrical consumer network (101).
    Fig. 1
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    Fuel cell system, stationary power plant and method for operating a fuel cell system
    The present invention relates to a fuel cell system, comprising at least one fuel cell stack with an anode section and a cathode section, a cathode supply section for supplying cathode gas to the cathode section, an anode supply section for supplying anode gas to the anode section, a cathode exhaust section for discharging cathode exhaust gas from the cathode section, and an anode exhaust gas section for discharging Anode exhaust gas from the anode section, the cathode exhaust gas section and the anode exhaust gas section opening into an exhaust gas burner for at least partially burning the cathode exhaust gas and the anode exhaust gas, and an exhaust gas discharge section for removing fuel cell exhaust gas from the exhaust gas burner. The invention further relates to a stationary power plant for generating electrical energy, comprising a fuel cell system. Another aspect of the present invention relates to a method for operating a fuel cell system or a stationary power plant with a fuel cell system, the fuel cell system generating electrical energy for a downstream electrical consumer network.
    In modern technology, fuel cell systems, often comprising one or more fuel cell stacks, each with a large number of fuel cells, are used, among other things, in stationary power plants for generating electrical energy for a downstream consumer network. A fuel cell system is, in particular, a particularly energy-efficient way of generating electricity. Solid oxide fuel cells (SOFC) in particular, which are operated at high temperatures, have proven to be particularly suitable for this use.
    A power plant that is used to power a downstream consumer network must ensure that the required electrical power is always available. There are various control levels (primary, secondary, tertiary), which specify the time span (seconds, 5 minutes, 15 minutes) within which changes in the consumer network must be responded to to ensure frequency stability in the consumer network. Fuel cells, especially SOFCs, are usually not suitable in such a way
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    AVL List GmbH for a short time to increase or decrease their performance. Also, such a fuel cell system essentially cannot simply be switched off and on again, since the fuel cell system always requires a certain operating temperature.
    It is known from the prior art, for example from DE 10 2013 207 349 A1, to convert the released electrical power of a resistive load into heat in the event of a sudden drop in the electrical power required in the consumer network. This heat can be used in various ways, for example to keep the fuel cell system at an operating temperature. However, it can be disadvantageous here that this consumption of electrical power in the resistive load often cannot occur suddenly and can therefore only be carried out with a certain delay.
    The object of the present invention is to at least partially take into account the problems described above or at least to provide alternative solutions. In particular, it is an object of the present invention to provide a fuel cell system, a stationary power plant and a method for operating a fuel cell system which improve a fuel cell system, a stationary power plant and a method for operating a fuel cell system in a particularly simple and cost-effective manner an electrical power that is released can be consumed particularly quickly, in particular, in order to enable operation of the fuel cell system with constant or at least substantially constant electrical output power.
    The above object is solved by the claims. In particular, the above object is achieved by the fuel cell system according to independent claim 1, by the stationary power plant according to independent claim 9 and by the method according to independent claim 10. Further advantages of the invention result from the subclaims, the description and the drawings. Features and details that are described in connection with the fuel cell system according to the invention also apply, of course, also in connection with the stationary power plant according to the invention and the method according to the invention for operating a fuel cell system and
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    AVL List GmbH vice versa, so that with regard to the disclosure of the individual aspects of the invention, reference can always be made to one another.
    According to a first aspect of the present invention, the object is achieved by a fuel cell system comprising at least one fuel cell stack with an anode section and a cathode section, a cathode supply section for supplying cathode gas to the cathode section, an anode supply section for supplying anode gas to the anode section, and a cathode exhaust gas section for discharging cathode exhaust gas from the cathode section, an anode off-gas section for discharging anode off-gas from the anode section, the cathode off-gas section and the anode off-gas section opening into an off-gas burner for at least partially burning the cathode off-gas and the anode off-gas, and an off-gas discharge section for removing fuel cell off-gas from the off-gas burner. A fuel cell system according to the invention is characterized in that the cathode supply section and / or the exhaust gas discharge section has a flow element for varying a flow resistance for the gas flowing in each case and that a fan is provided for conveying the fuel cell exhaust gas.
    A fuel cell system according to the invention has at least one fuel cell stack with an anode section and a cathode section. For generating electrical energy, a cathode gas, in particular an oxygen-containing gas such as air, for example, is fed to the cathode section through a cathode supply section, and an anode gas, in particular a hydrogen-containing gas, is fed to the anode section through an anode supply section. The anode gas can in particular also be specially prepared, for example by a reformer as part of the fuel cell system. Such a reformer can be used, for example, to process natural gas, in particular the methane contained in the natural gas, with the addition of water and heat such that a hydrogen-containing gas mixture is formed as the anode gas , In the current-generating reaction in the fuel cell stack, oxygen ions mostly diffuse from the cathode section through an electrolyte to the anode section and react there with the anode gas. Unused cathode gas is discharged as cathode exhaust gas from the cathode section through a cathode exhaust section
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    AVL List GmbH derived, correspondingly unused anode gas and the reaction products formed are derived as anode exhaust gas from the anode section through an anode exhaust gas section. Downstream both the cathode exhaust gas section and the anode exhaust gas section open into an exhaust gas burner in which the cathode exhaust gas is at least partially burned together with the anode exhaust gas. This can provide, for example, a further purification of the entire exhaust gas of the fuel cell system, but also an additional thermal utilization of the cathode exhaust gas and the anode exhaust gas to increase the total energy efficiency. Subsequent to the exhaust gas burner, the fuel cell exhaust gas generated in the exhaust gas burner is discharged in an exhaust gas discharge section.
    The operation of a fuel cell system according to the invention requires at least essentially constant or at least partially constant conditions. In particular, a rapid change in the electrical output power, both in terms of an increase and in terms of a decrease, is not readily possible. In particular, a sudden drop in the demand for electrical power can prove to be problematic, in particular when using a fuel cell system according to the invention to generate the electrical energy.
    It is therefore provided in a fuel cell system according to the invention that the electrical power which is released, in particular when a need for electrical power drops, is at least partially consumed internally in the fuel cell system itself. Essential to the invention, the cathode supply section and / or the exhaust gas removal section therefor has a flow element for varying a flow resistance for the respective flowing gas and a blower for conveying the fuel cell exhaust gas. A flow resistance can be increased by the flow element, and the fan can be operated with increased power for at least partial compensation of this increase. This increase in performance goes hand in hand with an increased consumption of electrical energy, which is preferably provided directly or indirectly by the fuel cell system itself. In this way, an at least partial compensation of the electrical power released when the demand for electrical power decreases, can be provided
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    AVL List GmbH. Constant or at least substantially constant operation of the fuel cell system can thus be made possible in this way.
    In other words, in the flow path, the cathode supply section, cathode section, cathode exhaust section, exhaust gas burner and
    Exhaust gas discharge section is formed in a fluid-communicating manner, a flow element is arranged, through which a flow resistance in the entire flow path varies, in particular can be increased. This variation of the flow resistance can in particular be provided regardless of whether the flow element is already arranged in the cathode supply section or only in the exhaust gas discharge section. At the same time, a blower is arranged, by means of which the fuel cell exhaust gas can be conveyed. Within the scope of the invention, the blower can be designed as an exhaust gas blower and can be arranged in the exhaust gas guide section. Alternatively, this can also be designed as a cathode fan and arranged in the cathode supply section. In principle, it is also conceivable that both the acthode feed section and the exhaust gas feed section have a blower. As already described above, the cathode supply section, the cathode section, the cathode off-gas section, the exhaust gas burner and the off-gas discharge section are connected in a fluid-communicating manner as a common flow path. The blower is thus in particular also designed to convey the cathode gas in the cathode supply section and the cathode exhaust gas in the cathode exhaust section. For this task, the blower can in particular be designed as a suction blower. In other words, the blower in the exhaust gas discharge section generates a negative pressure which promotes both the fuel cell exhaust gas in the exhaust gas discharge section and the cathode exhaust gas in the cathode exhaust gas section and the cathode gas in the cathode supply section. The fan is particularly preferably arranged in the exhaust gas guide section. Placing the blower in the
    Exhaust gas discharge section has the particular advantage that the gases in the flow path, in particular the cathode gas in the cathode supply section, the cathode exhaust gas in the cathode exhaust gas section and the fuel cell exhaust gas in the exhaust gas discharge section, are drawn or sucked through the flow path. Particularly good flow properties, in particular avoiding congestion of the flowing gases and associated pressure peaks, can be provided in this way.
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    In addition, as described above, the blower can preferably be controlled in such a way that the variation in flow resistance in the flow path generated by the flow element can be at least partially compensated for. This compensation enables the fuel cell system to operate at least substantially unchanged, at least with regard to the gas system of the fuel cell system. It also leads to an increased consumption of electrical energy in the blower. It can preferably be provided that the variation, in particular the increase, of the flow resistance through the flow element is carried out in such a way that the electrical energy increasingly required by the fan corresponds to, or at least essentially corresponds to, the electrical energy that occurs when a need for electrical power drops becomes free. In this way, at least substantially constant operation of the fuel cell system can also be made possible with regard to the electrical power provided by the fuel cell system.
    In summary, in a fuel cell system according to the invention, an internal consumption of the released electrical energy, which occurs when a load requirement is reduced, can be provided particularly simply, inexpensively and, in particular, quickly. This can be made possible in particular by the interaction of the flow element and the fan of the fuel cell system according to the invention.
    It is expedient if the cathode supply section and / or the exhaust gas discharge section has the blower for conveying the fuel cell exhaust gas. Within the scope of the invention, the blower can be designed as an exhaust gas blower and can be arranged in the exhaust gas guide section. Alternatively, this can also be designed as a cathode fan and arranged in the cathode supply section. In principle, it is also conceivable that both the cathode feed section and the exhaust gas feed section have a blower.
    A fuel cell system according to the invention can also be designed such that the flow element comprises at least one controllable throttle element in the cathode supply section. Such a controllable throttle element represents a mechanically particularly simple way of realizing a flow element. In particular, suitable controllable throttle elements can also preferably be used as flow elements in the sense of the invention
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    AVL List GmbH can be used, which are already present in the cathode feed section. Due to the possibility of control, the flow resistance in the flow path, in this embodiment in particular in the cathode supply section, can be set in a targeted and in particular reversible manner. In this way, a particularly appropriate and adapted setting of the flow resistance of the entire flow path can be provided. If the blower is arranged in the cathode supply section, the controllable throttle valve can advantageously be arranged upstream of the blower. It can also be favorable if two controllable throttle valves are provided in the cathode feed section, a first throttle valve being arranged upstream and a second throttle valve being arranged downstream of the fan.
    As an alternative or in addition, it can be provided in a fuel cell system according to the invention that the flow element comprises a controllable throttle element in the exhaust gas discharge section, the throttle element being arranged in particular downstream of the fan. It is therefore advantageously provided that the fan is arranged in the exhaust gas guide section. In this embodiment too, a controllable throttle element represents a mechanically particularly simple way of realizing a flow element. Furthermore, suitable controllable throttle elements which are already present in the exhaust gas discharge section can also be used as flow elements in the sense of the invention. Due to the possibility of control, the flow resistance in the flow path, in this embodiment in particular in the exhaust gas discharge section, can be set specifically and in particular reversibly. A particularly appropriate and adapted adjustment of the flow resistance of the entire flow path can also be provided in this way. Even if the blower is arranged in the cathode feed section, a controllable throttle element can advantageously be provided in the exhaust gas feed section.
    Alternatively or additionally, a fuel cell system according to the invention can be designed such that the flow element comprises a controllable throttle element in the exhaust gas discharge section, the throttle element being arranged in particular upstream of the exhaust gas suction fan. The blower is designed in particular as an exhaust gas blower and in the exhaust gas guide section
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    AVL List GmbH arranged. This embodiment of a fuel cell system according to the invention represents a further alternative or additional possibility for placing the flow element according to the invention in the flow path. All the advantages that have been described in relation to the flow element at other locations in the flow path can also be provided in this embodiment of a fuel cell system according to the invention.
    In summary, one or more flow elements can be arranged in the flow path, including in particular the cathode supply section and the exhaust gas discharge section. In this way, in particular a placement of the flow element that is particularly suitable and adapted to the needs, and thereby also a influencing of the flow resistance that is particularly suitable and adapted to the requirements, can be provided.
    Furthermore, it can be provided in a fuel cell system according to the invention that the exhaust gas discharge section with a heat exchanger element in the
    Cathode supply section is connected to deliver thermal energy to the cathode supply gas. The fuel cell exhaust gas, which is produced in the exhaust gas burner during the at least partial combustion of the cathode exhaust gas with the anode exhaust gas, usually has a high temperature. The heat energy thus stored in the fuel cell exhaust gas can be at least partially transferred to the cathode gas by means of a heat exchanger element. In this way, heating elements for heating up the cathode gas can be dispensed with or at least made smaller. Overall, an energy efficiency of a fuel cell system according to the invention can thus be increased in this way.
    In addition, as an alternative or in addition, a fuel cell system according to the invention can also be designed in such a way that the exhaust gas discharge section is connected to a reformer in the anode supply section in order to provide thermal energy. In such a reformer, as already described above, the anode gas can be treated, for example by reforming natural gas, in particular the methane contained in the natural gas, with the addition of water and heat in such a way that a hydrogen-containing gas mixture is produced as the anode gas. By connecting the exhaust gas discharge section to the reformer in the anode supply section, the heat energy required for the treatment can be at least partially generated by the hot one
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    Fuel cell exhaust gas are provided. In this way, heating elements for heating the reformer can be omitted or at least made smaller. Overall, an energy efficiency of a fuel cell system according to the invention can thus also be increased in this way.
    Furthermore, in a fuel cell system according to the invention, it can be provided that the fuel cell system has an electrical connection element for the direct and / or indirect supply of the blower with electrical energy of the fuel cell stack. In this way, in particular by the electrical connecting element, provision of the electrical energy required by the blower can be ensured by the fuel cell system itself. A fuel cell system according to the invention mostly generates electrical energy in the form of direct current. In the case of a blower which also requires electrical energy in the form of direct current, the electrical connecting element can thus preferably be used to conduct the required electrical energy directly to the blower. In the case of an alternative blower that requires electrical energy in the form of alternating current, it can be advantageous to use the electrical connecting element to extract the electrical energy after a direct current / alternating current converter, as is usually present, for example, when connected to a downstream consumer network. In particular, a suitably designed electrical connecting element for all possible combinations of the electrical form of energy provided by the fuel cell system and the electrical form of energy required by the blower can thus make it possible for the fuel cell system itself to provide the electrical energy required by the blower.
    According to a second aspect of the invention, the object is achieved by a stationary power plant for generating electrical energy, comprising a fuel cell system. A stationary power plant according to the invention is characterized in that the fuel cell system is designed according to the first aspect of the invention. All the advantages, which have been described in detail in relation to a fuel cell system according to the invention according to the first aspect of the invention, can thus also be achieved by a stationary one
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    Power plant are provided according to the second aspect of the invention, the fuel cell system is designed according to the first aspect of the invention.
    According to a third aspect of the invention, the object is achieved by a method for operating a fuel cell system according to the first aspect of the invention or a stationary power plant with a fuel cell system according to the second aspect of the invention, the fuel cell system generating electrical energy for a downstream electrical consumer network. A method according to the invention is characterized by the following steps:
    a) detection of a load drop in the downstream consumer network,
    b) increasing a flow resistance through the flow element,
    c) Increasing a pump power of the fan for at least partially compensating for the flow resistance increased in step b) by at least partially supplying electrical energy generated by the fuel cell system, which is released by the load drop detected in step a).
    A method according to the invention operates a fuel cell system according to the first aspect of the invention or a stationary power plant according to the second aspect of the invention. All the advantages, which have been described in detail in relation to a fuel cell system according to the invention according to the first aspect of the invention or in relation to a stationary power plant according to the second aspect of the invention, can thus also be provided by a method according to the third aspect of the invention, which is designed to operate a fuel cell system according to the invention according to the first aspect of the invention or a stationary power plant according to the second aspect of the invention.
    A method according to the invention operates a fuel cell system or a stationary power plant with a fuel cell system. In particular, the fuel cell system, directly or as the preferred primary power generator in the power plant, will provide electrical energy for a downstream electrical consumer network. Such a consumer network
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    AVL List GmbH can particularly preferably be designed as a local, regional and / or supraregional power network.
    Such a downstream electrical consumer network can sometimes be subject to large fluctuations in the demand for electrical energy, up to a complete load shedding, in which suddenly, in particular within a few minutes or even seconds, the demand for electrical energy drops completely or at least essentially completely to zero , In order to be able to react to such fluctuations, a load drop in the downstream consumer network is recognized in the first step a) of a method according to the invention. Detection in the sense of the invention includes, in particular, the measures required for this, for example a preferably repeated measurement of the requested requirement or an evaluation of these measurements. In other words, after step a) of a method according to the invention has been carried out, the information is available that a load drop has occurred in the downstream consumer network.
    In the next two steps b) and c) of a method according to the invention, measures are taken to at least partially compensate for this load drop and at the same time continue to operate the fuel cell system, in particular the fuel cell stack of the fuel cell system, as unchanged as possible. For this purpose, a flow resistance through the flow element of the fuel cell system is increased in the next step b) of a method according to the invention. Such an increased flow resistance would lead to a reduced supply of cathode gas to the cathode section of the fuel cell stack. In order to at least partially compensate for this, a pump output of the blower of the fuel cell system is increased at a later point in time or preferably simultaneously, in step c) of a method according to the invention. In this way, the supply of the fuel cell stack with cathode gas can be kept at least partially, in particular sufficiently, constant. This increase in pump power automatically goes hand in hand with an increased fan demand for electrical energy. In order to serve this increased energy requirement of the blower, at least part of the electrical energy generated by the fuel cell system, which is generated by the step
    a) recognized load drop is released, used.
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    In this way, there are several advantages of a method according to the invention. Thus, by at least partially compensating for the increased flow resistance in the flow path by simultaneously increasing the pumping power of the blower, the operation of the fuel cell system with regard to supply with cathode gas can be continued at least essentially without change. At the same time, the electrical energy generated by the fuel cell stack is at least partially consumed internally in the fuel cell system due to the increased demand of the fan, so that the reduced electrical energy requirement in the downstream consumer network can also be at least partially compensated for. By using the blower as a consumer of the electrical energy released, this can be provided particularly quickly and with no or only a slight delay to the load drop determined in step a). In other words, the fuel cell system, in particular the fuel cell stack, can be operated with an at least substantially constant generation rate of electrical energy, regardless of a need for electrical energy in the downstream consumer network.
    Furthermore, it can be provided in a method according to the invention that in step c) to increase the pump power, all or at least essentially all of the electrical energy released by the load drop detected in step a) is fed to the blower. A complete or at least substantially complete compensation of the load drop determined in step a) due to the increased consumption of electrical energy by the fan can be provided in this way.
    As an alternative or in addition, a method according to the invention can also be designed such that in step c) the flow resistance increased in step b) is compensated completely or at least essentially completely by increasing the pumping power of the fan. In other words, the volume flow of cathode gas in the cathode supply section or of fuel cell exhaust gas in the exhaust gas discharge section does not change, or at least does not change significantly, even if the flow resistance has been increased in step b) by the flow element. Operation of the fuel cell system
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    AVL List GmbH with regard to the supply of cathode gas can continue in this way without change or at least essentially without change.
    In a method according to the invention, it can also be particularly preferred that step a) comprises continuous or at least essentially continuous monitoring of the downstream consumer network. In this way, fluctuations in the demand for electrical energy in the consumer network, in particular load drops up to a complete load shedding, can be determined particularly quickly and promptly. Compensation of the electrical energy released by consumption in the fan can thus also be initiated particularly quickly and promptly.
    A method according to the invention can also be designed such that in step c) the electrical energy released is fed directly from the fuel cell stack to the blower as direct current. A direct supply of electrical energy in the sense of the invention includes in particular supply as direct current without a conversion into alternating current being carried out. A correspondingly designed connecting element can preferably be used for this. In particular in the case of a blower that requires electrical energy in the form of direct current, this embodiment of a method according to the invention is advantageous since it enables particularly simple supply of the electrical energy to the blower.
    Alternatively or additionally, it can further be provided in a method according to the invention that in step c) the released electrical energy of the fuel cell stack is converted into alternating current and then fed to the blower. In the sense of the invention, this represents an indirect supply of the electrical energy to the blower. A correspondingly designed connecting element can also be used here. In particular in the case of a blower that requires electrical energy in the form of alternating current, this embodiment of a method according to the invention is advantageous since it enables particularly simple supply of the electrical energy to the blower. In particular, the electrical energy can also be drawn from the downstream consumer network.
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    A method according to the invention can particularly preferably be further developed in such a way that an increased waste heat of the blower generated by the increased pump power is at least partially supplied to a heat consumer and / or a heat store. An increased pump power in the blower usually goes hand in hand with an increased power loss in the blower. This often leads to an increase in the waste heat generated by the fan. By supplying this waste heat to a heat consumer, for example as a possible heat source for heating the fuel cell stack, and / or to a heat store, for example for later use of the thermal energy, use of this waste heat can be provided. Energy efficiency when operating a fuel cell system can be increased in this way.
    Further measures improving the invention result from the following description of various exemplary embodiments of the invention, which are shown schematically in the figures. Elements with the same function and mode of operation are given the same reference numerals in FIGS. 1 to 4.
    Each shows schematically:
    Figure 1 is a view of a power plant according to the invention;
    Figure 2 shows a first embodiment of a connecting element;
    Figure 3 shows a second embodiment of a connecting element;
    FIG. 4 shows a method according to the invention;
    Figure 5 is a view of another power plant according to the invention.
    1 schematically shows a power plant 100 according to the invention or a fuel cell system 1 according to the invention. A method according to the invention, which is shown by way of example in FIG. 4, can be carried out by such a power plant 100 or fuel cell system 1. The individual steps of the method a), b) and c) according to the invention are each identified with capital letters in FIG. 4. The two figures are therefore described together below, with the individual figures being dealt with separately.
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    A stationary power plant 100 according to the invention has a fuel cell system 1 according to the invention as the central element. The fuel cell system 1 generates electrical energy that is fed to a downstream consumer network 101 (not shown). 1 shows the essential components of such a fuel cell system 1. The generation of electrical energy is carried out in a fuel cell stack 10. For this purpose, the fuel cell stack 10 has an anode section 11 and a cathode section 12. The cathode section 12 is supplied with cathode gas 30, preferably an oxygen-containing gas such as air, via a cathode supply section 20. Analogously, an anode gas 31, preferably a hydrogen-containing gas, is fed to anode section 11 through an anode supply section 21. A desulfurization element 43 is arranged in the anode feed section 21 for cleaning the anode gas 31 from sulfur components. An anode gas delivery unit 45, for example a blower, ensures delivery of the anode gas 31. As shown, the anode gas 31 can also be processed in a reformer 42, in which, for example, natural gas, in particular methane, is split into a hydrogen-containing gas mixture together with water and with the addition of heat. In the fuel cell stack 10 are the
    Cathode section 12 and the anode section 11 separated by an electrolyte, which is mostly permeable to oxygen ions. In the current-generating reaction in the fuel cell stack 10, oxygen ions diffuse from the cathode section 12 through the electrolyte to the anode section 11 and react there with the anode gas 31. Unused cathode gas 30 is discharged as cathode off-gas 32 from the cathode section 12 through a cathode off-gas section 22, correspondingly unused anode gas 31 and the resulting reaction products are derived as anode exhaust gas 33 from the anode section 11 through an anode exhaust gas section 23. Downstream both the cathode exhaust gas section 22 and the anode exhaust gas section 23 open into an exhaust gas burner 40. A part of the anode exhaust gas 33 is further introduced into the anode supply section 21 through an anode exhaust gas return section 44. As a result, in particular unused anode gas 31 can be reused as part of the anode exhaust gas 33. Since the anode exhaust gas 33 is heated by the reactions in the anode section 11, a heat exchanger element 41 is arranged in the anode discharge section 21 in order to heat anode gas 31 conducted in the anode supply section 21 before it enters the anode section 11
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    AVL List GmbH or to heat up. The reactions in the fuel cell stack 10 can be supported in this way. In the exhaust gas burner 40, the cathode exhaust gas 32 is at least partially burned together with the anode exhaust gas 33. This can provide, for example, a further purification of the entire exhaust gas of the fuel cell system 1, but for example also an additional thermal utilization of the cathode exhaust gas 32 and the anode exhaust gas 33 to increase the total energy efficiency. Subsequent to the exhaust gas burner 40, the fuel cell exhaust gas 34 generated in the exhaust gas burner 40 is discharged in an exhaust gas discharge section 24. In order to further use the thermal energy of the fuel cell exhaust gas 34, both a heat exchanger element 41 of the cathode supply section 20 is arranged in the exhaust gas discharge section 24, and the exhaust gas discharge section 24 is connected to the reformer 42. In this way, both the cathode gas 30 can be heated and thermal energy can be supplied to the reformer 42. Overall, in addition to other components (not shown) of a fuel cell system 1 according to the invention, in particular the fuel cell stack 10, the exhaust gas burner 40 and the reformer 42 are arranged in a hot cell 5. The high temperatures, often several hundred degrees Celsius, required for efficient operation of the fuel cell system 1 are particularly easy to provide. Further possible elements of a fuel cell system 1, for example a water supply and disposal, direct supply lines for providing cathode gas 30 and anode gas 31 for starting the exhaust gas burner 40 are not shown for the sake of clarity.
    According to the invention, the fuel cell system 1 shown has a blower 4 which is arranged in the exhaust gas discharge section 24. Arranging the blower 4 in the exhaust gas removal section 24 has the particular advantage that the gases in the flow path, in particular the cathode gas 30 in the cathode supply section 20, the cathode exhaust gas 32 in the cathode exhaust gas section 22 and the fuel cell exhaust gas 34 in the exhaust gas removal section 24, are drawn or sucked through the flow path become. Particularly good flow properties, in particular avoiding congestion of the flowing gases and the pressure peaks associated therewith, can be provided in this way. Furthermore, a fuel cell system 1 according to the invention has at least one flow element 2, which in the
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    Represented as a controllable throttle element 3 and is shown at three possible arrangement positions, in the cathode supply section 20 and in the exhaust gas discharge section 24 upstream and downstream of the blower 4. In other embodiments, only one or two flow elements 2 can be provided in each of these arrangement positions.
    A method according to the invention, as shown in FIG. 4, is provided for operating a fuel cell system 1 shown by way of example in FIG. 1. In particular, the fuel cell system 1 generates electrical energy for a downstream electrical consumer network 101. In a first step
    a), labeled A in FIG. 4, this electrical consumer network 101 is monitored in order to detect a drop in performance. In order to be able to provide this as quickly and promptly as possible, step a) can preferably be carried out continuously or at least essentially continuously. A drop in performance can be problematic in particular because the operation of the fuel cell system 1, in particular with regard to the electrical energy generated by it, essentially does not permit rapid changes. In the event of a load drop in the downstream electrical consumer network 101, electrical energy is thus released. In order to compensate for this, preferably completely or at least substantially completely, step b) of a method according to the invention, designated B in FIG. 4, controls the flow element 2 in such a way that a flow resistance in the flow path is increased. Subsequently or preferably even simultaneously, a pump power of the blower 4 is increased in step c) of a method according to the invention, designated C in FIG. 4, in order to compensate for the increased flow resistance at least partially, preferably completely or at least substantially completely. An operation of the fuel cell system 1 that is unchanged at least with regard to a gas supply can thereby be provided. Essential to the invention, the increase in the pump power of the blower 4 is achieved in that the blower 4 is supplied with at least part of the electrical energy released by the load drop in the consumer network 101, which is generated by the fuel cell stack 10. Preferably, in order to increase the pump power, all or at least essentially all of the electrical energy that has become free can be supplied to the blower 4. In addition, an increased heat of the blower 4 can also be used by increasing the pump power,
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    AVL List GmbH, for example, by supplying this waste heat to a heat consumer and / or a heat store. An overall energy efficiency of a fuel cell system 1 according to the invention or a power plant 100 according to the invention can thereby be increased further.
    In summary, in a fuel cell system 1 according to the invention or by a method according to the invention, an internal consumption of the released electrical energy, which occurs in the case of a load drop in the downstream electrical consumer network 101, can thus be provided particularly easily, inexpensively and in particular quickly. This can be provided in particular by the interaction of the flow element 2 and the blower 4 of the fuel cell system 1 according to the invention.
    2 and 3 show two options for supplying the fan 4 with electrical energy which is generated by the fuel cell stack 10 of a fuel cell system 1 according to the invention or a power plant 100 according to the invention and which is released by a load drop in the downstream electrical consumer network 101. A correspondingly designed electrical connecting element 50 is used for this. In the figures, only the essential components are shown, in particular the fuel cell stack 10 and the blower 4. Furthermore, the downstream electrical consumer network 101 is shown, into which the electrical energy generated by the fuel cell stack 10 is fed via an AC converter 102. 2 shows the case in which the blower 4 requires electrical energy in the form of direct current. Since the fuel cell stack 10 already generates electrical energy in the form of direct current, this electrical energy can be supplied directly to the blower 4 by the appropriately designed electrical connecting element 50. Alternatively, preferably if the blower 4 requires electrical energy in the form of alternating current, the electrical connecting element 50 can be arranged downstream of the alternating current converter 102, see FIG. 3. This can still be done internally in the fuel cell system 1, but also as part of the downstream consumer network 101 be realized. Overall, this represents an indirect supply of the electrical energy released by the load drop. In particular, this can be done by a suitably designed electrical energy
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    Connection element 50 for all possible combinations of the electrical energy form provided by the fuel cell system 1 and the electrical energy form required by the blower 4 enables the electrical energy required by the blower 4 to be reliably provided by the fuel cell system 1 itself.
    FIG. 5 schematically shows another power plant 100 according to the invention or a fuel cell system 1 according to the invention. The elements which correspond to those of the power plant 100 shown in FIG. 1 and have the same function will not be described again. That is, all those elements that are not described correspond to those from FIG. 1 or FIG. 2. In contrast to the embodiment according to FIG. 1, the blower 4 is arranged in the cathode supply section 20. Furthermore, this fuel cell system 1 also has at least one flow element 2, which in the illustration is designed as a controllable throttle element 3 and is arranged at a possible arrangement position in the cathode supply section 20 upstream of the blower 4. Basically, the throttle element 3 can also be arranged in the exhaust gas discharge section 24. In other configurations, two flow elements 2 can also be arranged in the cathode supply section 20 upstream and downstream of the blower 4 or one flow element 2 downstream of the blower 4 in the cathode supply section 20.
    In addition to the illustrated embodiments, the invention permits further design principles. That is, the invention is not to be considered limited to the exemplary embodiments explained with reference to the figures.
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    LIST OF REFERENCE NUMBERS
    The fuel cell system
    flow element
    throttle element
    fan
    hot cell
    fuel cell stack
    anode section
    cathode portion
    Kathodenzuführabschnitt
    Anodenzuführabschnitt
    Cathode exhaust section
    Anode exhaust section
    Exhaust gas discharge section
    cathode gas
    anode gas
    cathode exhaust
    anode exhaust gas
    fuel cell exhaust gas
    exhaust gas burner
    Heat exchanger element
    reformer
    desulfurizing
    Anode exhaust gas recirculation section
    Anode gas feed unit
    connecting element
    100 power plant
    101 Consumer network
    102 AC transformers
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    权利要求:
    Claims (16)
    [1]
    claims
    1. Fuel cell system (1), comprising at least one fuel cell stack (10) with an anode section (11) and a cathode section (12), a cathode supply section (20) for supplying cathode gas (30) to the cathode section (12), an anode supply section (21) for supplying anode gas (31) to the anode section (11), a cathode off-gas section (22) for discharging cathode off-gas (32) from the cathode section (12), an anode off-gas section (23) for discharging anode off-gas (33) from the anode section (11), wherein the cathode exhaust gas section (22) and the anode exhaust gas section (23) open into an exhaust gas burner (40) for at least partially burning the cathode exhaust gas (32) and the anode exhaust gas (33), and an exhaust gas discharge section (24) for removing fuel cell exhaust gas (34) from the exhaust gas burner ( 40), characterized in that the cathode supply section (20) and / or the exhaust gas discharge section (24) has a flow element (2) for varying a flow resistance has for each flowing gas, and that a fan (4) for conveying the fuel cell exhaust gas (34) is provided.
    [2]
    2. Fuel cell system (1) according to claim 1, characterized in that the cathode supply section (20) and / or the exhaust gas discharge section (24) has the blower (4) for conveying the fuel cell exhaust gas (34).
    [3]
    3. Fuel cell system (1) according to claim 1 or 2, characterized in that the flow element (2) comprises at least one controllable throttle element (3) in the cathode supply section (20).
    [4]
    4. Fuel cell system (1) according to one of claims 1 to 3, characterized in that the flow element (2) comprises a controllable throttle element (3) in the exhaust gas discharge section (24), the throttle element (3) being arranged in particular downstream of the fan (4) is.
    [5]
    5. Fuel cell system (1) according to one of the preceding claims, characterized in that the flow element (2) comprises a controllable throttle element (3) in the exhaust gas discharge section (24), wherein the
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    Throttle element (3) is arranged in particular upstream of the fan (4).
    [6]
    6. Fuel cell system (1) according to one of the preceding claims, characterized in that the exhaust gas discharge section (24) is connected to a heat exchanger element (41) in the cathode supply section (20) for delivering thermal energy to the cathode gas (30).
    [7]
    7. Fuel cell system (1) according to one of the preceding claims, characterized in that the exhaust gas discharge section (24) is connected to a reformer (42) in the anode supply section (21) for providing thermal energy.
    [8]
    8. The fuel cell system (1) according to one of the preceding claims, characterized in that the fuel cell system (1) has an electrical connecting element (50) for the direct and / or indirect supply of the blower (4) with electrical energy of the fuel cell stack (10).
    [9]
    9. Stationary power plant (100) for generating electrical energy, comprising a fuel cell system (1), characterized in that the fuel cell system (1) is designed according to one of the preceding claims.
    [10]
    10. A method for operating a fuel cell system (1) according to one of claims 1 to 6 or a stationary power plant (100) with a fuel cell system (1) according to claim 7, wherein the fuel cell system (1) electrical energy for a downstream electrical consumer network (101) generated, characterized by the following steps:
    a) detection of a load drop in the downstream consumer network (101),
    b) increasing a flow resistance through the flow element (2),
    c) Increasing a pump power of the blower (4) for at least partially compensating for the flow resistance increased in step b) by at least partially supplying electrical energy generated by the fuel cell system (1), which is released by the load drop detected in step a).
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    [11]
    11. The method according to claim 10, characterized in that in step c) to increase the pump power, all or at least substantially all of the electrical energy released by the load drop detected in step a) is fed to the blower (4).
    [12]
    12. The method according to claim 10 or 11, characterized in that in step
    c) by increasing the pump power of the blower (4), the flow resistance increased in step b) is completely or at least substantially completely compensated.
    [13]
    13. The method according to any one of claims 10 to 12, characterized in that step a) comprises a continuous or at least substantially continuous monitoring of the downstream consumer network (101).
    [14]
    14. The method according to any one of claims 10 to 13, characterized in that in step c) the released electrical energy is fed directly from the fuel cell stack (10) to the blower (4) as direct current.
    [15]
    15. The method according to any one of claims 10 to 14, characterized in that in step c) the released electrical energy of the fuel cell stack (10) is converted into alternating current and then fed to the blower (4).
    [16]
    16. The method according to any one of claims 10 to 15, characterized in that an increased waste heat generated by the increased pump power of the fan (4) is at least partially supplied to a heat consumer and / or a heat accumulator.
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    1/4, 100

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    2.4


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    3.4
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    同族专利:
    公开号 | 公开日
    DE102019111462A1|2019-11-07|
    AT521209B1|2020-11-15|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    WO2010044772A1|2008-10-14|2010-04-22|Utc Power Corporation|Solid oxide fuel cell with anode exhaust recycle|
    WO2011089082A2|2010-01-19|2011-07-28|Robert Bosch Gmbh|Method for operating a cogeneration plant|
    US20170260902A1|2012-10-31|2017-09-14|Mitsubishi Hitachi Power Systems, Ltd.|Power generation system|
    DE102015215927A1|2015-08-20|2017-02-23|Volkswagen Aktiengesellschaft|Fuel cell system and method for operating such|
    CA3009462A1|2015-12-25|2017-06-29|Nissan Motor Co., Ltd.|Fuel cell system and control method for fuel cell system|
    DE102019220148A1|2019-12-19|2021-06-24|Robert Bosch Gmbh|Fuel cell system|
    DE102020200676A1|2020-01-22|2021-07-22|Robert Bosch Gesellschaft mit beschränkter Haftung|Fuel cell system and method for operating a fuel cell system|
    DE102020206522A1|2020-05-26|2021-12-02|Robert Bosch Gesellschaft mit beschränkter Haftung|Peripheral device for a fuel cell unit and fuel cell system with at least one fuel cell unit and at least one peripheral device|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    ATA50370/2018A|AT521209B1|2018-05-03|2018-05-03|Fuel cell system, stationary power plant and method for operating a fuel cell system|ATA50370/2018A| AT521209B1|2018-05-03|2018-05-03|Fuel cell system, stationary power plant and method for operating a fuel cell system|
    DE102019111462.4A| DE102019111462A1|2018-05-03|2019-05-03|Fuel cell system, stationary power plant and method for operating a fuel cell system|
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