• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    The invention relates to a method for producing a foam body, as well as a foam body. It is provided a pourable starting granules of expanded particles of a thermoplastic material, which is subjected to non-melting heat treatment. In this case, an intermediate granulate is formed with a bulk density higher than that of the starting granules. Then a shaping of the foam body takes place by materially connecting the volume-reduced particles of the intermediate granules by the intermediate granules is heated in a mold space of a mold to a temperature greater than a glass transition temperature of the thermoplastic Kunstoffs, and then the thermoplastic material is solidified by cooling. The foam body has a total density of 80 kg / m³ to 600 kg / m³.
    公开号:AT519945A1
    申请号:T50353/2017
    申请日:2017-05-02
    公开日:2018-11-15
    发明作者:Ing Florian Nowy Dipl
    申请人:Ing Florian Nowy Dipl；Dipl Ing Alois Zorn；
    IPC主号:
    专利说明:

    Summary
    The invention relates to a method for producing a foam body and a foam body. A pourable starting granulate from expanded particles of a thermoplastic material is provided, which is subjected to non-melting heat treatment. An intermediate granulate is formed with a bulk density greater than that of the starting granulate. The foam body is then shaped by material-locking connection of the reduced-volume particles of the intermediate granulate, in that the intermediate granulate is heated in a mold space of a mold to a temperature greater than a glass transition temperature of the thermoplastic, and then the thermoplastic is solidified by cooling. The foam body has a total density of 80 kg / m 3 to 600 kg / m 3 .
    Fig. 2/41
    N2017 / 10300 AT-00
    The invention relates to a method for producing a foam body and a foam body.
    Foam products made of foamed plastics have been manufactured for various purposes for decades. By far the most common plastic used to make foams is polystyrene. In particular, expanded polystyrene particle foam (EPS), known for example under the name Styropor®, is used for various purposes, such as for packaging or as thermal insulation material.
    Usual methods for producing such foam products include at least one foaming process, in which a plastic material containing a blowing agent is heated and expands due to the evaporating blowing agent. Here, a raw or bulk density of the plastic material is reduced. Subsequently, for example, the foamed plastic material can be stored temporarily. Subsequently, a further foaming of the plastic is usually carried out, in which the corresponding foam product is also molded.
    The foam products that can be produced in this way can be used for some purposes due to their properties. However, the possible areas of application for these foam products are primarily limited by the inadequate mechanical properties, for example of foamed EPS products. For example, foam products of this type / 41
    N2017 / 10300-AT-00 are not used for applications in which sufficiently good mechanical properties, such as certain compressive, tensile and / or bending strengths are required.
    In the past, a method has been known in which an expanded foam body is subjected to a heat treatment of a plastic forming the foam. Such a method is disclosed for example from WO 2006/086813 A1, EP 1 853 654 B1 and US 8,765,043 B2. The heat treatment reduces a volume of the body compared to the initial state before the heat treatment. However, the known method still has deficits with regard to the procedure. In particular, the volume reduction or shrinkage of the starting body cannot be controlled well, so that shaping for the volume-reduced foam product requires shaping post-processing. The foam product obtained must be converted into a usable form, for example by cutting, milling, sawing. On the one hand, this results in an increased process outlay, and on the other hand waste material is also incurred, for example due to milling and / or waste losses and the like. Furthermore, due to the procedure, foam products with relatively large differences in density can result in different areas of a respective foam product.
    The object of the present invention was to overcome the remaining disadvantages of the prior art and to provide an improved method by means of which method foam bodies with good mechanical properties can be produced in an efficient manner and essentially without any waste material being produced , Furthermore, it was an object of the invention to provide an improved foam body with the smallest possible density differences in all areas of the foam body.
    This object is achieved by a method according to claims 1 to 18 and a foam body according to claims 19 and 20.
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    The method for producing a foam body comprises the steps
    Provision of a pourable starting granulate from expanded particles of a thermoplastic,
    Formation of a pourable intermediate granulate with a bulk density greater than that of the starting granulate by reducing the volume of the particles of the starting granulate by subjecting the starting granulate to a non-melting heat treatment, and
    - Forming the foam body by material-locking connection of the reduced-volume particles of the intermediate granulate, in that the intermediate granulate is heated in a mold space of a mold to a temperature greater than a glass transition temperature of the thermoplastic, and then the thermoplastic is solidified by cooling.
    In this document, the term “starting granulate” denotes a starting bulk material. In this document, the term intermediate granulate denotes an intermediate bulk material.
    Foam bodies with good mechanical properties can be produced by the stated process. In particular, foam bodies can be manufactured with improved compressive, tensile and flexural strength compared to the starting materials. Because of this, the foam bodies produced can also be used in areas of application in which increased mechanical strengths are required. The use of foam bodies as insulation elements for building constructions is mentioned purely by way of example, for example for the thermal decoupling of load-bearing components. The foam bodies or moldings produced can also be used as lightweight structural elements, for example in technical fields such as vehicle construction. Another example is the use of the foam body to generate buoyancy for loads in liquids.
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    As a result of the non-melting heat treatment, the volume of the expanded particles of the starting granulate is shrunk without the particles joining together. The degree of shrinkage can be influenced by the choice of temperature and the duration of the heat treatment. In this way, a desired bulk density for the intermediate granulate can advantageously be influenced in a targeted manner. As a result, an intermediate granulate with a desired bulk density can already be provided for the subsequent shaping of the foam body, so that a time period for the shaping step can be very short. Furthermore, the desired properties of the foam body resulting after the molding step, such as thermal insulation values, bending strength or compressive strength, can also be specifically influenced in this way.
    A higher temperature during the heat treatment can achieve a greater volume reduction in the expanded particles of the starting granulate, and an intermediate granulate with a higher bulk density can be formed than at lower temperatures during the heat treatment. The temperature during the heat treatment ultimately determines the maximum achievable volume reduction for the particles of the starting granulate, or the maximum achievable bulk density of the intermediate granulate. An increase in the bulk density of the intermediate granules can also be achieved by a longer period of the non-melting heat treatment than by a comparatively shorter period of time. By selecting the parameters of temperature and duration of the non-melting heat treatment, a bulk density of the intermediate granulate can advantageously be influenced in a targeted manner.
    The non-melting heat treatment for forming the pourable intermediate granulate is preferably carried out at a temperature in the range or just above a glass transition temperature or softening temperature of the respective thermoplastic material. In this document, the term glass transition temperature refers to the material-dependent lower limit of a glass transition area, from which the amorphous parts begin to soften for a respective thermoplastic, as is the case for thermoplastic / 41
    N2017 / 10300 AT-00
    Plastics is known per se. The temperature is chosen for the non-melting heat treatment in such a way that it lies below any melting temperature of the respective thermoplastic.
    As a result of the non-melting heat treatment, the expanded particles of the starting granulate are converted into a soft, elastic state. In this soft-elastic state, the thin walls of the expanded particles of the starting granulate contract uniformly, starting from their state stretched by the expansion during production, which leads to a reduction in the volume of the particles and the intermediate granulate is formed with a bulk density greater than the bulk density of the starting granulate , Any residual blowing agent still present in the starting granulate is volatilized in the course of the non-melting heat treatment, so that the pourable starting granulate is subjected to a non-foaming heat treatment.
    It has proven advantageous over the prior art in the method that the heat treatment of a starting granulate and the formation of a pourable intermediate granulate as the basis for the subsequent shaping of the foam body enables the shaping of the foam body to take place directly in the molding tool. As a result, further shaping post-processing steps, such as cutting, sawing or milling, can in principle be dispensed with. Subsequently, waste material, such as waste, can also be prevented. Any minor post-processing, such as surface grinding etc., only produce small amounts of waste material. If appropriate, it can also be provided that waste material from metal-cutting postprocessing is reused in the process by adding such waste material to an intermediate granulate before the molding in the mold. It is possible for such waste material to be obtained again in granular, pourable form as a result of the post-processing, or for it to be comminuted into a pourable granulate.
    A foam body can be provided by the specified measures for the shaping of the foam body, wherein a geometric shape / 41
    N2017 / 10300-AT-00 of the boundary surfaces of the resulting foam body can be specified at least predominantly by the design of the molding space.
    A further advantage over the prior art is that, due to the procedure, foam products with very small density differences can be produced in different areas of a respective foam product. On the one hand, it has been found that the heat treatment of a starting granulate, in contrast to a heat treatment of a starting body, can compensate for differences in density of the starting material in an improved manner. Differences in bulk density of the volume-reduced particles of the intermediate granulate are therefore reduced by the heat treatment compared to bulk density differences of the expanded particles of the starting granulate provided. Furthermore, the method offers the possibility of separating or classifying the volume-reduced particles of the intermediate granulate with respect to a respective bulk density, and of using or using volume-reduced particles with at least predominantly uniform bulk density for the subsequent shaping of the foam body.
    Overall, the measures provided provide a simple method by means of which the properties of widely used and readily available starting materials can be modified and foam bodies can be produced which are suitable for new areas of application which are not accessible to the starting materials. Compared to the prior art, in which a body is subjected to a heat treatment, there are further advantageous possibilities for further processing due to the formation of the pourable intermediate granulate by the heat treatment.
    In principle, any expanded thermoplastic material can be provided for the process. In practice, in addition to foamed materials made of polyethylene or polypropylene, mainly polystyrene foam products are available as the starting material. Cross-linked, thermoset foam objects cannot be used for the process, since volume reduction by heat treatment cannot be achieved for these materials.
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    In one embodiment of the method, it can be provided that foam objects made from the thermoplastic material are comminuted to provide the starting granulate.
    This can be packaging made of polystyrene foam, for example, or thermal insulation panels made of polystyrene. Such starting materials can be comminuted into the starting granulate in a simple manner without great effort. In principle, any comminution means, such as a shredder, can be used for the comminution. Advantageously, a wide variety of starting objects can also be recycled and processed into usable foam bodies.
    It is quite possible that foam objects with different densities are shredded.
    This is quite possible with the method, since the non-melting heat treatment enables the formation of intermediate granules with an adjusted bulk density of the reduced-volume particles compared to the expanded particles of the starting granules. Furthermore, due to the pourable shape of the intermediate granulate, the intermediate granulate can be further classified according to density before the foam body is molded.
    In an expedient embodiment of the method, it can be provided that the heat treatment increases a bulk density of the intermediate granulate - based on a bulk density of the starting granulate before the heat treatment - 5 to 40 times.
    By forming intermediate granules compacted in this way with increased bulk density, foam bodies with improved mechanical properties can subsequently be molded. The increase in the bulk density by reducing the volume of the particles of the starting granulate can be selected mainly by selecting the temperature and duration of the non-melting heat treatment.
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    In particular, it can be provided that a bulk density of the intermediate granulate is set to a value selected from a range of 50 kg / m 3 to 500 kg / m 3 by the heat treatment.
    By specifically forming an intermediate granulate with a bulk density in the specified range, a foam body with adapted properties can be produced directly in the subsequent molding process step. Intermediate granules with a bulk density selected from the range specified are particularly suitable for the production of foam bodies with improved mechanical properties. For example, foam bodies with higher compressive, tensile or flexural strengths can be produced by forming intermediate granules with a high bulk density.
    In a preferred development of the method it can be provided that the heat treatment is carried out at a temperature in the range of the glass transition temperature of the thermoplastic.
    In this way, sufficient mobility of the polymer chains of the thermoplastic material of the starting granulate can be provided for the volume reduction during the heat treatment. Furthermore, a time period of the heat treatment necessary for a sufficient volume reduction can advantageously also be limited.
    In particular, it can be provided that the heat treatment is carried out at a temperature selected from a range from 90 ° C. to 120 ° C.
    As a result, a suitable temperature range for the non-melting heat treatment is provided for most common foam products made of expanded thermoplastic materials, and such foam products can thus advantageously be processed or recycled using the method.
    However, it can also be provided that the heat treatment is carried out at ambient pressure.
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    In this way, the heat treatment can also be carried out without much effort in simply constructed heat treatment devices, such as furnaces or continuous-flow heating devices.
    In a development of the method it can be provided that a time period of the heat treatment is selected from a range from 0.01 h to 50 h.
    By selecting a time period for the non-melting heat treatment from the specified range, a respective desired bulk density of the intermediate granulate can be influenced in a targeted manner. Here, the selection of a time period from the specified range has proven to be particularly suitable for the heat treatment. In particular, a duration of the heat treatment can be selected from a range from 0.1 h to 40 h, in particular from 0.5 h to 30 h.
    In a further development it can be provided that the intermediate granulate is divided into several density fractions after the heat treatment by separation according to density.
    This possibility arises from the presence of the intermediate granulate in granular, pourable form. In this way, the intermediate granulate can be classified according to density. The density fractions of the intermediate granulate can then be used in a targeted manner for further processing. Such a method measure cannot be carried out in the previously known method in which a body is subjected to a heat treatment.
    It can subsequently be provided, for example, that only intermediate granules of one of the density fractions are used for the subsequent shaping of the foam body.
    In this way, the molding step can produce foam bodies with a particularly uniform density over all areas of the foam body, or local density differences in the foam body / 41
    N2017 / 10300-AT-00 as far as possible. This in turn has a positive effect on the properties, in particular a positive effect on the mechanical properties of the foam body.
    It can also be expedient to carry out a method in which at least one additive is mixed into the intermediate granules before the foam body is formed.
    The type and amount of additives can be selected depending on the intended use or use of the respective foam body. For example, additives can be added to improve the fire resistance of the foam body. Color pigments, antioxidants or light stabilizers may be mentioned as further examples of possible additives. In contrast to the prior art, in which a body is subjected to a heat treatment, this measure is possible because in the course of the heat treatment a pourable intermediate granulate is formed or produced.
    In a further variant of the method, provision can be made for the intermediate granules and at least one additional structural element to be placed in the molding space of the molding tool before the foam body is molded, the at least one structural element becoming part of the foam body in the course of the molding of the foam body.
    In contrast to the previously known prior art, this measure can also be carried out, since a pourable intermediate granulate is produced from the heat treatment. The mechanical properties of the foam bodies can be further influenced by this process measure. For example, it can be provided that one or more scrims or fabrics made of fibrous material (s) are placed together with the intermediate granulate in the mold space of the first part of the mold. Such fabrics or fabrics can be formed, for example, from textile or plastic fibers. By additionally using such structural elements, for example, the flexural strength of the foam body can be further increased. In contrast to the prior art with heat treatment / 41
    N2017 / 10300-AT-00 of a body, this measure can also be carried out, since a pourable intermediate granulate is formed from the heat treatment.
    In a further development of the method, provision can be made for the intermediate granules in the molding space to be heated to a temperature selected from a range from 120 ° C. to 150 ° C. to form the foam body. The intermediate granulate can preferably be heated in the molding space to a temperature selected from a range from 130 ° C. to 140 ° C. to form the foam body.
    A temperature selected from the range specified is suitable for materially connecting the reduced-volume particles of the intermediate granulate to one another or to one another in the molding space. In particular, the volume-reduced particles can be softened on the surface, and a material connection can be carried out by superficial gluing, sintering and / or welding of the individual particles to one another, and a foam body can be produced in this way.
    In principle, several options for heating the thermoplastic in the mold space are conceivable, such as molds that can be heated by means of heating elements or heating media.
    It can preferably be provided that water vapor is introduced into the molding space to heat the intermediate granulate during the molding of the foam body.
    In this way, a particularly efficient method for heating all areas of the molding space or all particles of the intermediate granulate in the molding space as quickly and as simultaneously as possible can be provided. In this way, for example, possible inhomogeneities in the foam bodies produced, which may result from heating the molding space from the outside, can be prevented.
    Furthermore, provision can also be made for the intermediate granules to be selected with a mechanical tension in the molding space during molding / 41
    N2017 / 10300-AT-00 is applied from a range of 0.01 N / mm 2 to 2 N / mm 2 , preferably selected from a range of 0.1 N / mm 2 to 1 N / mm 2 .
    In this way, the material-locking connection of the reduced-volume particles of the intermediate granulate in the molding space can be effectively supported, so that a foam body can be produced. As a result, the duration of the molding process step can also be advantageously shortened. A mechanical tension can be applied to the intermediate granulate, for example, by pressing two molded parts of a molding tool against each other. Along with this, the mold space can be reduced in size. In this case, a molded part can be designed or used, for example, in the manner of a press die.
    In a further development of the method it can also be provided that at the end of the molding of the foam body, before the plastic is solidified, a pressure in the molding space is reduced to ambient pressure by cooling.
    This can be carried out, for example, by opening one or more outlet members which are connected to the molding space in terms of flow technology. Simultaneously or immediately afterwards, molded parts of a molding tool can be separated from one another before the plastic is solidified by cooling. As a result, an overpressure which is presumably still present in the interior of the particles compared to the ambient pressure, allows expansion of the particles forming the foam body, and thus re-expansion of the foam body before the plastic solidifies. In the case of uniaxial loading of the intermediate granulate with a mechanical tension, for example through the design and use of a molded part as a press ram, density inhomogeneities due to the uniaxial loading with mechanical tension can be prevented. In general, foam bodies of particularly good quality can be produced by such a procedure.
    In particular, provision can also be made for a negative pressure to be generated in the mold space by cooling in the molding space before the plastic is solidified.
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    In this way, a pressure difference between the interior of the particles and the molding space can be increased even further, whereby a re-expansion of the particles forming the foam body or the foam body can be supported.
    However, the object of the invention is also achieved by providing a foam body, which foam body can be produced in particular according to one of the specified process procedures.
    The foam body has a total density of 80 kg / m 3 to 600 kg / m 3 , with test pieces cut out of any areas of the foam body having a density with a deviation of less than 20% from the total density of the foam body.
    In this way, a foam body can be provided which has hardly any local inhomogeneities in its density. With such a foam body, any damage under load, which may result, for example, from areas with a density lower than the total density, can be prevented.
    In particular, it can be provided that a value for the compressive stress at 10% compression is between 0.9 N / mm 2 and 10.5 N / mm 2 .
    In this way, a foam body can be provided which can also withstand higher pressure loads.
    For a better understanding of the invention, this will be explained in more detail with reference to the following figures.
    Each show in a highly simplified, schematic representation:
    1 shows an exemplary embodiment of a first method step of the method for producing a foam body;
    2 shows an exemplary embodiment of a second method step of the method for producing the foam body;
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    3 shows a further exemplary embodiment for the second method step of the method for producing the foam body;
    Fig. 4 shows an embodiment for a further process step of the method for producing the foam body.
    In the introduction, it should be noted that in the differently described embodiments, the same parts are provided with the same reference numerals or the same component names, and the disclosures contained in the entire description can be applied analogously to the same parts with the same reference numerals or the same component names. The location information selected in the description, e.g. above, below, to the side, etc., referring to the figure described and illustrated immediately, and if the position is changed, these are to be applied accordingly to the new position.
    The process for producing a foam body comprises several process steps. In a first process step, a pourable or free-flowing starting granulate 1 made of expanded particles of a thermoplastic is provided. In principle, any foamed material comprising expanded particles made of a thermoplastic, such as polyolefins or polystyrene, can be used as the starting or raw material. Foamed polystyrene products are available in large quantities. For example, it can be provided that waste from free-flowing, foamed polystyrene from a production of foamed polystyrene products is provided as starting material 1.
    As an alternative or in addition, it can also be provided, for example, that foam objects 2 made of thermoplastic material, for example packaging made of expanded polystyrene (EPS), or other recycled foam objects 2 are shredded to provide the starting granulate.
    Comminution can be carried out by means of comminution devices 3 known per se, as is shown purely schematically in FIG. 1 using a shredder 4.
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    It is entirely possible that the foamed starting materials have different geometrical shapes, sizes and densities or bulk densities. For example, it can easily be provided that foam objects with different densities are crushed to provide the starting granulate 1. In such cases, the starting granulate provided can have expanded particles or pieces with different bulk densities. The starting granulate 1 can, for example, have a bulk density of 5 kg / m 3 to 30 kg / m 3 .
    Furthermore, it is possible for the starting granulate 1 to have slight residues of dirt or impurities which have no significant influence on the subsequent process steps and the foam body produced by the process. Minor amounts of other substances, such as residual blowing agent or other substances used during the production of the starting material, may also be present in the starting granulate, and these substances also have no significant influence on the process or the properties of the foam bodies produced.
    Foamed material made from at least predominantly a single thermoplastic, for example polystyrene, is preferably provided as starting granulate 1. This is partly because different thermoplastic materials can also have different (processing) properties, such as different glass transition temperatures or different mechanical properties. From this, different process parameters can also be required for different thermoplastic materials, so that different plastics cannot be processed efficiently together.
    After preparation, the starting granulate 1 is processed further in a second process step. As schematically illustrated in FIG. 2, in the second process step the starting granulate 1 becomes a pourable or free-flowing intermediate granulate 5 with a bulk density greater than that / 41
    N2017 / 10300-AT-00 of the starting granulate 1 formed. This is done by reducing the volume of the expanded particles of the starting granulate 1 by subjecting the starting granulate 1 to a non-melting heat treatment.
    The starting granulate 1 can be placed in a furnace 6 for heat treatment, which furnace 6 is illustrated in a sectional view in the flow diagram shown in FIG. 2. As can be seen from the exemplary embodiment shown in FIG. 2, the furnace 6 can have, for example, one or more heating element (s) 7 and a temperature control device 8. Furthermore, for example, a circulating air device 9 can be provided. The furnace 6 preferably additionally has thermal insulation 10. The heating elements 7 can be formed, for example, by electrical heating elements, or else by infrared radiators or other heating means. Basically, heating the furnace 6 instead of the heating elements 7 also involves charging the furnace with a heated heat transfer medium, such as air, water vapor or an air-water vapor mixture.
    In order to initiate the volume reduction for the expanded particles of the starting granulate 1 as uniformly as possible, the temperature in the furnace 6 can preferably be slowly increased to the desired temperature for the heat treatment. Here, the furnace 6 can also be preheated to a certain temperature, for example 60 ° C. to 80 ° C., before the starting granulate 1 is introduced into the furnace 6. During the heat treatment, the desired temperature can be kept as constant as possible by means of the temperature control device 8.
    It can be provided here that the heat treatment is carried out at a temperature in the range of the glass transition temperature of the thermoplastic material of the starting granulate 1 provided in each case. For example, it can be provided that the heat treatment is carried out at a temperature selected from a range from 90 ° C. to 120 ° C. This temperature range is particularly expedient for the heat treatment of the starting granulate 1, since on the one hand a sufficient volume / 41 in this temperature range
    N2017 / 10300-AT-00 can be achieved for the particles of the starting granulate 1. On the other hand, a temperature for the heat treatment can also be selected from the specified temperature range, which is below a possible melting temperature of the plastic of the respective starting granulate 1 provided, so that the particles are not connected to one another during the heat treatment. Furthermore, it has proven to be advantageous if the heat treatment is carried out at ambient pressure.
    As is schematically illustrated in FIG. 2, the heat treatment brings about a volume reduction for the particles of the starting granulate 1, so that after the heat treatment an intermediate granulate 5 with particles reduced in volume is obtained. Accordingly, the intermediate granulate 5 has a greater bulk density than the starting granulate 1, as can also be seen from FIG. 2.
    In principle, an extent of the volume reduction of the particles, and thus a desired bulk density for the intermediate granulate 5, can be influenced by the choice of the temperature and the duration of the heat treatment. By selecting a higher temperature for the heat treatment, on the one hand an acceleration of the volume reduction for the particles can be achieved. The degree of volume reduction of the particles can also be increased by higher temperatures. On the other hand, by selecting a lower temperature for the heat treatment, the volume reduction is slowed down and, overall, a lower degree of volume reduction is achieved.
    The extent of the volume reduction for the particles can also be increased by extending the duration of the heat treatment, whereas a reduction in the duration of the heat treatment brings about a smaller extent of the volume reduction. A duration of the heat treatment can preferably be selected from a range from 0.01 h to 50 h, preferably from a range from 0.1 h to 40 h, in particular from a range from 0.5 h to 30 h.
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    The volume reduction of the particles during the heat treatment results from the reduction of internal stresses in the particles, which were introduced by foaming and freezing the foamed structure during the production of the starting material. A particle size of the particles gradually decreases due to the reduction of these internal stresses during the heat treatment.
    By choosing a respective temperature and duration of the heat treatment, a bulk density of the intermediate granulate 5 resulting after the heat treatment due to the volume reduction of the particles can be influenced. A heat treatment temperature and time period suitable for achieving a desired bulk density of the intermediate granulate 5 depends in particular on the type of thermoplastic material of the starting granulate 1 and on the bulk density of the starting granulate 1. Suitable temperatures and durations of the heat treatment can, for example, be determined experimentally for each case in a simple manner by experiments.
    For the production of foam bodies with particularly useful insulation properties and mechanical properties, it has proven to be expedient if, by the heat treatment, a bulk density of the intermediate granulate - based on a bulk density or compared to the bulk density of the starting granulate before the heat treatment - is 5 times to Is magnified 40 times. For example, it can be provided that a heat density of the intermediate granulate is set to a value selected from a range of 50 kg / m 3 to 500 kg / m 3 by the heat treatment.
    An alternative embodiment variant of the non-melting heat treatment is shown in FIG. 3. In FIG. 3, the same reference numerals or component designations are used for the same parts as in the previous FIGS. 1 and 2. In order to avoid unnecessary repetition, reference is made to the detailed description in the preceding FIGS. 1 and 2.
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    In the embodiment shown in FIG. 3, the heat treatment in a continuous furnace 11 is carried out continuously. The continuous furnace 11 shown in a sectional view in turn has a plurality of heating elements 7 which can be controlled by one or more temperature control device (s) 8, as well as a plurality of circulating air devices 9 and thermal insulation 10. Furthermore, a conveying means 12, for example a driven conveyor belt 13, is provided for transporting the particles through the continuous furnace 11.
    The expanded particles of the starting granulate 1 can be continuously fed onto the conveying means 12 at an input side 14 of the continuous furnace 11 and conveyed through the continuous furnace 11 in a transport direction 15. In this case, a duration of the heat treatment can be determined by the conveying speed through the continuous furnace 11. Furthermore, it can be provided, for example, that a temperature in the continuous furnace near the inlet side 14 is set lower than further inside the continuous furnace 11.
    As illustrated in FIG. 3, the particles of the starting granulate 1 are again reduced in volume in the course of the heat treatment in the continuous furnace 11. After transport through the continuous furnace 11, the intermediate granules 5 having a bulk density greater than the bulk density of the starting granules 1 can be continuously obtained on an output side 16 of the continuous furnace 11.
    In a variant of the method it can be provided that the intermediate granulate 5 is divided into several density fractions after the heat treatment by separation according to density. A separation according to density can be carried out using customary methods, for example wind sifting, centrifugation, (settling) settling or sedimentation or heavy turbidity separation.
    After such a division or classification of the intermediate granulate 5 into density fractions, it can subsequently be provided that in each case only Zwi / 41 for a subsequent process step for shaping the foam body
    N2017 / 10300-AT-00 granulate 5 one of the density fractions is used. This procedure allows foam bodies with a largely uniform density to be produced in all areas, which ultimately has a positive effect on the properties, in particular a positive effect on the mechanical properties of the foam body.
    It may also be expedient to carry out a process in which at least one additive is admixed with the intermediate granulate before the foam body is formed. For example, an additive can be added which can improve the fire resistance of a foam body. Color pigments, antioxidants or light stabilizers may be mentioned as further examples of possible additives.
    Regardless of the embodiment of the process step of the heat treatment, and of any additional process steps thereafter, a further process step for shaping the foam body 17 is carried out. 4 schematically shows an exemplary embodiment for the shaping of the foam body 17 by means of a molding tool 18. In FIG. 4, the same reference numerals or component designations are used for the same parts as in the previous FIGS. 1 to 3. In order to avoid unnecessary repetition, reference is made to the detailed description in the preceding FIGS. 1 to 3. 4 shows four states during the step of shaping the foam body 17, the arrows drawn between the states indicating a sequential sequence of the states. 4, the elements or apparatuses shown are again illustrated in a sectional view.
    As schematically illustrated in FIG. 4, the intermediate granules 5 are filled into a molding space 19 of a molding tool 18 in order to shape the foam body 17. In the exemplary embodiment shown, the molding tool 18 consists of a first molded part 20 and a second molded part 21, the second molded part 21 being adjustable relative to the first molded part 20. At the / 41
    N2017 / 10300-AT-00 illustrated embodiment, the mold 18 is thus designed in the manner of a molding press.
    In the exemplary embodiment shown in FIG. 4, the molding tool 18 or its molded parts 20, 21 are arranged in a closable steam chamber 22, consisting of a first chamber part 23 and a second chamber part 24. As an alternative to the exemplary embodiment shown, a steam chamber 22 can also be made in one piece, for example, and have an opening which can be closed by means of a flap or door, in order to allow access to the molding tool 18, for example for removing a finished foam body 17.
    The first molded part 20 can be mounted in the interior of the steam chamber 22, for example on one or more support plates. The second molded part 21 can be connected to a uniaxial drive, not shown, for adjusting the first molded part 21 relative to the second molded part 22.
    The intermediate granules 5 can be filled into the mold space 19, for example, via an injection line 26. Thereafter, the injection line 26 can be closed off from the mold space 19, if necessary after removing excess intermediate granulate, for example again by means of compressed air or negative pressure, for example by closing a flap, as can be seen from the state shown at the top right in FIG. 4. Alternatively, manual filling of the first molded part 20, for example, is also conceivable, while the molded parts 20, 21 of the molding tool 18 are spaced apart from one another.
    In one variant of the method, provision can also be made for the intermediate granules 5 and at least one additional structural element to be placed in the mold space 19 of the mold 18 before the foam body is molded. Such a constructive element is not shown in FIG. 4 for reasons of clarity. For example, a structural element can be formed by a scrim or fabric made of fibrous material. One or more such constructive elements can, for example, alternate with Zwi / 41
    N2017 / 10300-AT-00 granulate 5 can be introduced or inserted into the first molded part 20, such introduction being able to be controlled by machine, but in principle it can also be done manually. In the course of shaping the foam body 17, the at least one structural element becomes part of the foam body 17.
    To form the foam body 17, the intermediate granules 5 are heated in the molding space 19 to a temperature greater than a glass transition temperature of the respective thermoplastic material. In the exemplary embodiment shown in FIG. 4, the steam chamber 22 has a steam connection 28 connected to a source (not shown in detail) for this purpose via a shut-off element 27. The source of the heated steam can be formed, for example, by a heatable steam boiler.
    To heat the intermediate granules 5 during molding, water vapor can be let into a vapor space 29 of the vapor chamber 22 by opening the shut-off member 27. The molded parts 20, 21 can be perforated, as illustrated in FIG. 4, and have openings 30 through which the water vapor introduced into the steam space 29 is also conducted into the molded space 19. This allows the intermediate granulate 5 to be heated very quickly and uniformly. Alternatively, of course, other methods for heating the intermediate granules 5 in the mold space 19 are also conceivable, for example by means of infrared radiation or electrical heating elements.
    In principle, provision can be made for the intermediate granulate 5 in the molding space 22 to be heated to a temperature selected from a range from 120 ° C. to 150 ° C. to form the foam body 17. The intermediate granules can preferably be heated in the molding space to a temperature selected from a range from 130 ° C. to 140 ° C. to form the foam body.
    By heating the intermediate granulate 5 in the molding space 19, the volume-reduced particles of the intermediate granulate 5 soften on the surface, and the volume-reduced particles of the intermediate granulate 5 become material-tight by / 41
    N2017 / 10300-AT-00 surface gluing, sintering or welding connected so that a foam body 17 is formed.
    To support the material-locking connection of the particles of the intermediate granulate 5, provision can also be made for the intermediate granulate 5 to be subjected to a mechanical tension, selected from a range from 0.01 N / mm 2 to 2 N / mm 2 , during the shaping in the mold space 19. preferably selected from a range of 0.1 N / mm 2 to 1 N / mm 2 is applied. This can be carried out, for example, by reducing the size of the molding space 19 by drivingly adjusting the second molding 21 relative to the first molding 20, as can be seen from the state shown at the top right in FIG. 4. In the illustrated embodiment, mechanical stress is applied or the second molded part 21 is adjusted along an adjustment axis, that is to say uniaxially.
    The heating of the intermediate granulate 5 in the molding space 19, optionally with the application of mechanical tension, can be carried out within a period of, for example, 3 seconds to 20 seconds. The thermoplastic material to form the foam body 17 is then solidified by cooling.
    In this context, a pressure in the molding space 19 is preferably reduced to ambient pressure at the end of the shaping of the foam body 17 before the plastic is solidified by cooling. For this purpose, on the one hand, the second molded part 21 can be adjusted away from the first molded part 20, as is illustrated by the state shown at the bottom left in FIG. 4. Furthermore, it can be provided that an excess pressure prevailing in the molding space 19 or the steam chamber 22 is reduced. In the embodiment shown in FIG. 4, the first chamber part 23 has a drain line 31 with a shut-off element 32 for this purpose. By opening the shut-off element 32 of the discharge line 31, the water vapor and other gases can be discharged from the steam chamber 22, and thus also from the mold space 19, and thus a pressure in the steam chamber 22 or the mold space 19 can be reduced to ambient pressure.
    / 41
    N2017 / 10300 AT-00
    As has been found here, an expansion of the particles forming the foam body 17 and thus a re-expansion of the foam body 17 before the plastic solidifies can be achieved by such a procedure. This is probably due to an overpressure still present inside the particles compared to the ambient pressure.
    In a further embodiment variant of the method, such a re-expansion process can also be further supported in that a negative pressure is generated in the mold space by cooling in the molding space before the plastic is solidified. In the exemplary embodiment shown in FIG. 4, the steam chamber 22 has a vacuum connection 33 for this purpose, which in turn can be operatively connected to a vacuum pump via a shut-off device 34, for example. When the shut-off device 34 is open and the vacuum pump is running, a negative pressure can then be generated in the steam chamber 22 or the mold space 19.
    As the last step in the shaping process, the foam body 17 is solidified by cooling. The cooling can take place passively, i.e. by exchanging heat with the surroundings. The cooling can also be actively supported, in particular in order to shorten the time for solidification. For example, spray devices 35 can be provided in the steam chamber 22, by means of which, for example, cooling water can be sprayed onto the molded parts 20, 21 or into the molded space 19.
    After the plastic has cooled, the finished foam body 17 can finally be removed after separating the two molded parts 20, 21 and opening the steam chamber 22.
    The foam body 17 can basically have a wide variety of geometric shapes and dimensions. This primarily depends on the geometric configuration of the molding space 19 of the molding tool 18. For example, cuboidal foam bodies 17 can be produced which are particularly well suited for structural purposes. The dimensions of such cuboid foam bodies 17 can in principle be chosen arbitrarily, cuboids with a length of 50 mm to 4000 mm, a width / 41
    N2017 / 10300-AT-00 from 50 mm to 15000 mm and a thickness from 10 mm to 200 mm have proven their worth. As already described, however, other geometries are also possible, for example foam body 17 with a trapezoidal cross section.
    By means of the method, foam body 17 can be produced with improved mechanical properties compared to, for example, starting objects which are used for producing the starting granulate 1.
    The foam body 17 has a total density of 80 kg / m 3 to 600 kg / m 3 , and is characterized in that test pieces cut out from any areas of the foam body 17 have a density with a deviation of less than 20% from the total density of the foam body 17 have. By way of example only, such test pieces can have dimensions of 10 cm × 10 cm × 10 cm. Such a uniform density in all areas can in particular prevent damage in the event of a load, since, for example, predetermined breaking points are avoided in areas of lower density. This also has a positive effect on the mechanical properties.
    A value for the compressive stress at 10% compression of the foam body is preferably between 0.9 N / mm 2 and 10.5 N / mm 2. For comparison, a value for the compressive stress at 10% compression is for common, foamed foam objects, such as packaging or insulation boards made of expanded polystyrene (EPS), in about 0.2 N / mm 2 to 0.3 N / mm 2 .
    The method, in particular the volume reduction of the particles or the increase in bulk density during the heat treatment, can thus provide foam bodies with significantly improved mechanical properties, which nevertheless have, for example, good thermal insulation properties. Due to the improved mechanical properties, the foam body 17 can also be used in areas that are not suitable for conventional foam objects. For example, the foam bodies can be used as load-bearing thermal insulation elements on building bases to avoid thermal bridges or for thermal decoupling / 41
    N2017 / 10300-AT-00 of load-bearing components, such as between supports and ceilings.
    The exemplary embodiments show possible design variants, it being noted at this point that the invention is not limited to the specially illustrated design variants of the same, but rather also various combinations of the individual design variants with one another are possible and this variation possibility is based on the teaching of technical action through the present invention Ability of the specialist working in this technical field.
    The scope of protection is determined by the claims. However, the description and drawings are to be used to interpret the claims. Individual features or combinations of features from the different exemplary embodiments shown and described can represent independent inventive solutions. The object on which the independent inventive solutions are based can be found in the description.
    All information on value ranges in the objective description is to be understood so that it includes any and all sub-areas, e.g. the information 1 to 10 is to be understood so that all sub-areas, starting from the lower limit 1 and the upper limit 10, are included, i.e. all sections start with a lower limit of 1 or greater and end with an upper limit of 10 or less, e.g. 1 to 1.7, or 3.2 to 8.1, or 5.5 to 10.
    For the sake of order, it should finally be pointed out that, for a better understanding of the structure, elements have sometimes been shown to scale and / or enlarged and / or reduced.
    / 41
    N2017 / 10300 AT-00
    LIST OF REFERENCE NUMBERS
    1 output granulate 31 drain line 2 Foam article 32 shutoff 3 comminution device 33 vacuum connection 4 Shredder 34 shutoff 5 between granules 35 sprayer 6 oven 7 heating element 8th Temperature control device 9 forced air device 10 thermal insulation 11 Continuous furnace 12 funding 13 conveyor belt 14 input side 15 transport direction 16 output side 17 foam body 18 mold 19 cavity 20 molding 21 molding 22 steam chamber 23 chamber member 24 chamber member 25 support plate 26 injection line 27 shutoff 28 steam connection 29 steam room 30 opening
    / 41
    N2017 / 10300 AT-00
    权利要求:
    Claims (20)
    [1]
    claims
    1. A method for producing a foam body (17), comprising the steps
    Provision of a pourable starting granulate (1) made from expanded particles of a thermoplastic,
    Formation of a pourable intermediate granulate (5) having a bulk density greater than that of the starting granulate (1) by reducing the volume of the particles of the starting granulate (1) by subjecting the starting granulate (1) to a non-melting heat treatment, and
    - Forming the foam body (17) by material-locking connection of the reduced-volume particles of the intermediate granulate (5) by heating the intermediate granulate (5) in a mold space of a mold (18) to a temperature higher than a glass transition temperature of the thermoplastic, and then the thermoplastic Plastic is solidified by cooling.
    [2]
    2. The method according to claim 1, characterized in that to provide the starting granulate (1) foam objects made of the thermoplastic material are crushed.
    [3]
    3. The method according to claim 2, characterized in that foam objects are shredded with different densities.
    [4]
    4. The method according to any one of the preceding claims, characterized in that a bulk density of the intermediate granules (5) - based on a bulk density of the starting granules (1) before the heat treatment - is increased by 5 to 40 times by the heat treatment.
    29/41
    N2017 / 10300 AT-00
    [5]
    5. The method according to any one of the preceding claims, characterized in that a bulk density of the intermediate granules (5) is set to a value selected from a range of 50 kg / m 3 to 500 kg / m 3 by the heat treatment.
    [6]
    6. The method according to any one of the preceding claims, characterized in that the heat treatment is carried out at a temperature in the range of the glass transition temperature of the thermoplastic.
    [7]
    7. The method according to claim 6, characterized in that the heat treatment is carried out at a temperature selected from a range from 90 ° C to 120 ° C.
    [8]
    8. The method according to any one of the preceding claims, characterized in that the heat treatment is carried out at ambient pressure.
    [9]
    9. The method according to any one of the preceding claims, characterized in that a time period of the heat treatment is selected from a range from 0.01 h to 50 h.
    [10]
    10. The method according to any one of the preceding claims, characterized in that the intermediate granulate (5) is divided into several density fractions after the heat treatment by separation according to density.
    [11]
    11. The method according to claim 10, characterized in that only intermediate granules of one of the density fractions are used for the subsequent shaping of the foam body.
    30/41
    N2017 / 10300 AT-00
    [12]
    12. The method according to any one of the preceding claims, characterized in that at least one additive is added to the intermediate granules before the foam body is formed.
    [13]
    13. The method according to any one of the preceding claims, characterized in that before the molding of the foam body, the intermediate granules and at least one additional structural element are added to the mold cavity of the molding tool, the at least one structural element in the course of the molding of the foam body to form a component of the foam body.
    [14]
    14. The method according to any one of the preceding claims, characterized in that for forming the foam body (17), the intermediate granulate (5) in the molding space (22) is heated to a temperature selected from a range from 120 ° C to 150 ° C ,
    [15]
    15. The method according to any one of the preceding claims, characterized in that for heating the intermediate granules (5) during the molding water vapor is introduced into the mold space (22).
    [16]
    16. The method according to any one of the preceding claims, characterized in that the intermediate granules (5) during the molding in the molding space (19) with a mechanical tension, selected from a range from 0.01 N / mm 2 to 2 N / mm 2 is applied.
    [17]
    17. The method according to any one of the preceding claims, characterized in that at the end of the molding of the foam body (17), before the solidification of the plastic by cooling, a pressure in the molding space (19) is reduced to ambient pressure.
    31/41
    N2017 / 10300 AT-00
    [18]
    18. The method according to claim 17, characterized in that before the solidification of the plastic by cooling in the mold space (19), a negative pressure is generated.
    [19]
    19. foam body (17), in particular produced by a method according to one of claims 1 to 18, characterized in that it has a total density of 80 kg / m 3 to 600 kg / m 3 , and that from any areas of the foam body (17) cut-out test pieces have a density with a deviation of less than 20% from the total density of the foam body (17).
    [20]
    20. Foam body according to claim 19, characterized in that a value for the compressive stress at 10% compression is between 0.9 N / mm 2 and 10.5 N / mm 2 .
    32/41
    N2017 / 10300 AT-00
    Nowy Florian
    Anger Alois
    33/41
    Nowy Florian
    Anger Alois
    34/41 m
    Nowy Florian
    Anger Alois
    35/41
    33 34
    Nowy Florian
    Anger Alois
    36/41
    类似技术:
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    DE2361727A1|1974-07-04|METHOD FOR MANUFACTURING SHAPED THERMOPLASTIC PRODUCTS
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    同族专利:
    公开号 | 公开日
    US20200139593A1|2020-05-07|
    EP3628036A1|2020-04-01|
    CA3061345A1|2019-10-24|
    AT519945B1|2019-03-15|
    WO2018201175A1|2018-11-08|
    引用文献:
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    DE1817590A1|1968-01-02|1969-10-16|Shell Int Research|Process for molding objects from thermoplastics|
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    US20080224357A1|2005-08-23|2008-09-18|Basf Se|Method for Producing Foamed Slabs|AU2019279907B1|2019-04-11|2020-02-27|Polystyrene Reforming Pty Ltd|A method for recycling expanded polystyrene|
    DE102019119488A1|2019-07-18|2021-01-21|Niemeyer Teubert Wörthwein GbR |Process for the production of molded parts from particle foams|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    ATA50353/2017A|AT519945B1|2017-05-02|2017-05-02|Process for producing a foam body and foam body|ATA50353/2017A| AT519945B1|2017-05-02|2017-05-02|Process for producing a foam body and foam body|
    US16/608,998| US20200139593A1|2017-05-02|2018-04-26|Method for producing a foam body, and foam body|
    CA3061345A| CA3061345A1|2017-05-02|2018-04-26|Method for producing a foam body, and foam body|
    EP18729551.4A| EP3628036A1|2017-05-02|2018-04-26|Method for producing a foam body, and foam body|
    PCT/AT2018/060080| WO2018201175A1|2017-05-02|2018-04-26|Method for producing a foam body, and foam body|
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