• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    The invention relates to a fuel cell system (100), comprising a fuel cell stack (1) with anode (1a) and cathode section (1b) for carrying out an electrolysis of water into hydrogen and oxygen in a SOEC operating state of the fuel cell system (100), a cathode section supply line ( 2) for supplying cathode supply gas to the cathode portion (1b), a cathode portion exhaust pipe (3) for discharging cathode exhaust gas from the cathode portion (1b), a cathode exhaust gas heat exchanger (4) disposed in the cathode portion exhaust pipe (3), and the Heating the cathode feed gas to the cathode section supply line (2) is in thermal communication, a burner (7) for generating a heated burner exhaust gas by combustion of a gas mixture comprising oxygen and fuel, with a burner exhaust pipe (6), in which a burner exhaust gas Heat exchanger (5) arranged and for heating the Kathodenzuführgases therm communicating with the cathode portion supply line (2), at least one oxygen supply unit (8, 9) with oxygen supply line (10) for supplying the oxygen into the burner (7), and at least one fuel source (11, 12) with a Fuel supply line (13) for supplying the fuel into the burner (7). Furthermore, the invention relates to an operating method for a fuel cell system (100) and a motor vehicle with a fuel cell system (100).
    公开号:AT519848A1
    申请号:T50308/2017
    申请日:2017-04-13
    公开日:2018-10-15
    发明作者:Ing Dipl (Fh) Richard Schauperl；Beppino Defner Bsc；Dipl Ing Rechberger Jürgen
    申请人:Avl List Gmbh；
    IPC主号:
    专利说明:

    Fuel cell system for an SOEC operating state
    The present invention relates to a fuel cell system, in particular an SOFC system, which can be operated in an SOEC operating state. For this purpose, the fuel cell system has a fuel cell stack with an anode section and a cathode section for performing an electrolysis of water in hydrogen and oxygen. The invention further relates to a method for heating a fuel cell stack in a fuel cell system, which is operated in a SOEC operating state. The invention also relates to a motor vehicle with a fuel cell system that can be operated in the SOEC operating state.
    SOEC systems are known in the prior art. WO 2016/097261 A1, for example, shows a SOEC system in which hydrogen can be generated by means of a SOEC reactor.
    US 2016/0248137 A1 shows a reversibly operable, stationary SOFC system. This means that the SOFC system can also be operated as a SOEC system. If electrical energy is required and fuel is available, the fuel cell system shown can be operated as an SOFC system in order to generate electricity in an electrochemical manner. If, on the other hand, fuel is required and electrical energy is available, the fuel cell system can be operated as a SOEC system in order to generate hydrogen in an electrochemical manner. With SOFC / SOEC systems, it is important to heat the fuel cell stack to a sufficiently high temperature so that the fuel cell system can be operated efficiently. This is particularly problematic when the fuel cell system is started. According to US 2016/0248137 A1, it is proposed for a temperature control of the fuel cell stack to burn fuel gas from a storage tank in order to heat the fuel cell stack as a result. Such a storage tank is heavy in the stationary system shown and takes up a large amount of space. In mobile applications in particular, however, it is important to keep the installation space and weight for a fuel cell system as small as possible.
    The object of the present invention is to at least partially take into account the problems described above. In particular it is the task of / 27
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    AVL List GmbH present invention to provide a compact fuel cell system, a method for operating the fuel cell system and a motor vehicle, by means of which a fuel cell stack can be efficiently heated in a SOEC operating state of the fuel cell system.
    The above object is solved by the claims. In particular, the above object is achieved by the fuel cell system according to claim 1, the method according to claim 10 and the motor vehicle according to claim 15. Further advantages of the invention result from the subclaims, the description and the drawings. Features and details that are described in connection with the fuel cell system apply here, of course, also in connection with the method according to the invention, the motor vehicle according to the invention and vice versa, so that with respect to the disclosure of the individual aspects of the invention, reference can always be made to one another.
    According to a first aspect of the present invention, there is provided a fuel cell system that has a fuel cell stack with an anode section and a cathode section for performing electrolysis of water in hydrogen and oxygen in an SOEC operating state of the fuel cell system. The fuel cell system further has a cathode section supply line for supplying cathode supply gas to the cathode section and a cathode section exhaust line for discharging cathode exhaust gas from the cathode section. In addition, the fuel cell system has a cathode exhaust gas heat exchanger, which is arranged in the cathode section exhaust line and is in thermal operative connection with the cathode section supply line for heating the cathode supply gas. The fuel cell system furthermore has a burner for generating a heated burner exhaust gas by burning a gas mixture comprising oxygen and fuel, with a burner exhaust gas line, in which a burner exhaust gas heat exchanger is arranged and for the heating of the cathode supply gas is connected to the cathode section supply line for transferring heat , on. In addition, the fuel cell system has at least one oxygen supply unit with an oxygen supply line for supplying the oxygen to the burner, and at least / 27
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    AVL List GmbH a fuel source with a fuel supply line for supplying the fuel to the burner.
    The cathode supply gas can be heated efficiently by the burner and in particular the arrangement according to the invention thereof upstream, in particular directly upstream, of the burner exhaust gas heat exchanger. As a result, the fuel cell stack and thus also the fuel cell system can be brought to the desired temperature in an efficient manner.
    By combining the cathode exhaust gas heat exchanger with the burner exhaust gas heat exchanger, the cathode supply gas can be heated in a particularly flexible manner, particularly quickly if required. The fuel cell system is to be understood as a SOFC / SOEC system, i.e. a fuel cell system that can be operated in a SOEC operating state for fuel generation and in a SOFC operating state for power generation.
    Due to the arrangement of the burner, the present fuel cell system has a compact design. As a result, the fuel cell system can advantageously be operated in mobile use.
    The SOEC operating state can be understood as a regeneration operation of the fuel cell system. Downstream of the burner exhaust gas heat exchanger, the burner exhaust gas is discharged directly or at least essentially directly into the surroundings of the fuel cell system. A continuation of the burner exhaust gas is therefore not necessary. This is conducive to the compactness of the fuel cell system.
    The cathode section supply line is arranged for supplying the cathode supply gas to the cathode section correspondingly upstream of the cathode section. The cathode section exhaust line is arranged for discharging the cathode exhaust gas from the cathode section correspondingly downstream of the cathode section.
    The burner exhaust line is preferably arranged on the burner and / or at least in sections outside the burner. More specifically, the fuel cell system has the burner and the burner exhaust line, which are downstream of the burner and at least in sections upstream of the burner from / 27
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    AVL List GmbH gas heat exchanger is arranged for a fluid connection between the burner and the burner exhaust gas heat exchanger.
    The oxygen supply line is preferably arranged on the oxygen supply unit and / or at least in sections outside the oxygen supply unit. More specifically, the fuel cell system has the oxygen supply unit and the oxygen supply line, the oxygen supply line being arranged downstream of the oxygen supply unit and at least in sections upstream of the burner for a fluid connection between the burner and the oxygen supply unit.
    The fuel supply line is preferably arranged on the fuel source and / or at least in sections outside the fuel source. More specifically, the fuel cell system has the fuel source and the fuel supply line, the fuel supply line being arranged downstream of the fuel source and at least partially upstream of the burner for a fluid connection between the burner and the fuel source.
    In the present case, a line is to be understood in particular to mean a line system which can have a plurality of line sections. Thus, the cathode section supply line can have a line section which is arranged upstream of the cathode exhaust gas heat exchanger and a line section which is arranged downstream of the cathode exhaust gas heat exchanger. The same applies analogously to the other lines of the present fuel cell system. A component such as a heat exchanger in a line can be understood to mean that the component is in thermal and / or fluidic connection with the corresponding line.
    According to a development of the present invention, it is possible for the at least one fuel source to have a fuel tank for storing fuel in a fuel cell system. The fuel can be made available in a reliable manner by the fuel tank. The fuel container is to be understood as a container which is at least partially, preferably exclusively or essentially exclusively filled with fuel, preferably hydrogen or methane. The fuel in the fuel tank can, in particular during a starting process of the fuel cell system, in which / 27
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    AVL List GmbH chem in the SOEC operating state of the fuel cell system has not yet generated any fuel that can reliably heat the cathode supply gas.
    Furthermore, in a fuel cell system according to the invention, it is possible for the at least one fuel source to have at least one cathode exhaust gas aftertreatment unit, in particular a condenser, which is arranged downstream of the cathode exhaust gas heat exchanger. Accordingly, it is possible in the present case to use the cathode exhaust gas to generate fuel which can be burned by the burner and can be used again as a correspondingly heated burner exhaust gas to heat the cathode exhaust gas. As a result, the fuel container described above could in principle be dispensed with, with the result that corresponding costs, weight and the space required could be reduced. At least a quantity of fuel which is stored in the fuel tank before the fuel cell system is in operation can thereby be reduced and the fuel tank can be made correspondingly small. The condenser is designed to split the cathode exhaust gas, in particular in water and hydrogen. The hydrogen generated can then be stored separately or used for combustion in the burner. To supply the fuel from the condenser to the burner, the condenser is in fluid communication with the burner via the fuel supply line.
    In addition, in a fuel cell system according to the present invention, it is possible for the fuel tank to be arranged downstream of the at least one cathode exhaust gas aftertreatment unit. That is, the fuel tank is in fluid communication with the cathode exhaust gas aftertreatment unit or between the fuel tank and the cathode exhaust gas aftertreatment unit the fluid connection can at least be established by suitable line valves. This has the advantage that fuel which is generated by the cathode exhaust gas aftertreatment unit and is passed to the burner can be stored in the fuel tank.
    It can be particularly advantageous if, in a fuel cell system according to the invention, the fuel tank is arranged in a bypass line which forms a bypass to the fuel supply line. With such a configuration, it is possible to directly burn the burner with the fuel generated by the cathode exhaust aftertreatment unit and / or with the fuel from the burner / 27
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    AVL List GmbH to supply fabric containers. This allows the burner to be supplied with fuel in a flexible manner. Switching between the bypass line and the fuel supply line can be implemented by valve control of the fuel cell system. It is thus possible that a first bypass valve for releasing and closing the bypass line is arranged upstream of the fuel tank in the bypass line. When the first bypass valve is closed, the supply of fuel into the fuel tank can be prevented. In this case, the fuel can be fed directly from the cathode exhaust aftertreatment unit to the burner via the fuel supply line. It can also be advantageous if a second bypass valve for releasing and closing the bypass line is arranged in the bypass line downstream of the fuel tank. When the first bypass valve is open and the second bypass valve is closed, fuel can be passed from the cathode exhaust aftertreatment unit into the fuel tank, but from there it cannot be passed on to the burner. For this purpose, the second bypass valve is preferably arranged directly on the fuel tank. In this switching configuration, the fuel tank can be filled with fuel. Furthermore, it can be advantageous if a fuel valve for releasing and closing the fuel supply line is arranged in the fuel supply line. This makes further advantageous switching configurations possible. If, for example, the first bypass valve is opened, the second bypass valve is closed and the fuel valve is open, the burner can be supplied with fuel and the fuel tank can be filled with fuel at the same time. When the fuel cell system is started, the first bypass valve and the fuel valve are preferably closed and the second bypass valve is open, so that fuel can be supplied to the burner from the fuel tank.
    According to a further embodiment variant of the present invention, it is possible for the burner in a fuel cell system to have a heating device, in particular an electric heating device, for heating the burner. In the context of the present invention, it has been found that it is advantageous for the combustion of the gas mixture in the burner if it has a certain operating temperature. This operating temperature can be achieved quickly and reliably by the heating device. At the specified operating temperature, the fuel mixture in the burner can ver / 27 particularly efficiently
    PP31204AT
    AVL List GmbH be burned. This leads to a correspondingly efficient heating of the burner exhaust gas heat exchanger and thus also of the cathode supply gas. For the desired thermal interaction between the burner and the heating device, the heating device is preferably arranged directly on or in the burner.
    In addition, it can be advantageous if, in a fuel cell system according to the invention, the at least one oxygen supply unit has a fluid delivery unit which is arranged to provide oxygen from the surroundings of the fuel cell system directly or at least essentially directly upstream of the burner. The fluid delivery unit can be a blower or a pump that sucks or pumps ambient air into the oxygen supply line. The combustion in the burner can be controlled particularly flexibly and spontaneously through the direct or essentially direct supply of oxygen, that is to say the air, to the burner. The fact that the fluid delivery unit is arranged directly or at least essentially directly upstream of the burner should preferably be understood to mean that no or essentially no chemical or thermal functional components are arranged upstream of the burner. For this purpose, the burner is preferably in fluid communication with a fuel cell stack bypass line which connects the burner directly or essentially directly to the blower or the pump. The fuel cell stack bypass line forms a bypass to the fuel cell stack.
    Furthermore, it is possible that in a fuel cell system according to the present invention, the at least one oxygen supply unit is designed in the form of the anode section, the anode section being arranged upstream of the burner for providing oxygen-containing fluid to the burner. Using the anode exhaust gas, an oxygen-containing gas can be used, which is present or generated in the fuel cell system anyway. Using the anode exhaust gas, the combustion in the burner can be carried out efficiently.
    It can also be advantageous if the burner in a fuel cell system according to the invention has a burner catalyst for the combustion of the gas mixture. In the context of the present invention, it has been found that a particularly efficient combustion in the burner can be achieved by means of a burner catalytic converter, in particular at least one oxidation catalytic converter.
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    The above-described heating device for heating the burner and thus also the burner catalytic converter has proven to be particularly advantageous. As soon as the burner catalytic converter has been brought to the desired operating temperature by means of the heating device, a particularly efficient and effective combustion can take place in the burner by means of the burner catalytic converter.
    According to a further aspect of the present invention, a method for heating the fuel cell stack in a fuel cell system as described in detail above is provided. The process has the following steps:
    Feeding the cathode feed gas through the cathode section feed line to the cathode section,
    - supplying oxygen through the oxygen supply line to the burner,
    - supplying fuel through the fuel supply line to the burner,
    - Burning a gas mixture, which has the supplied oxygen and the supplied fuel, in the burner, and
    - Feeding a burner exhaust gas resulting from the combustion of the gas mixture through the burner exhaust line from the burner to the burner exhaust gas heat exchanger for heating the cathode feed gas.
    A method according to the invention thus brings with it the same advantages as have been described in detail with reference to the fuel cell system according to the invention. The cathode supply gas is preferably fed to the cathode section by a pump. The cathode supply gas is preferably water or a water-containing fluid in the SOEC operating state of the fuel cell system. The oxygen is preferably fed to the burner by means of a pump or a fan. The gas mixture is preferably burned in the burner by means of the burner catalyst. The burner exhaust gas is brought into thermal operative connection with the cathode section supply line by the burner exhaust gas heat exchanger, whereby the cathode supply gas can be heated or heated. The heating of the fuel cell stack takes place according to the invention, in particular indirectly, by heating the cathode supply gas, through which the fuel / 27
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    AVL List GmbH cell stack or at least the cathode section of the fuel cell stack is heated.
    According to a development of the present invention, it is possible in one method that the burner for the combustion of the gas mixture is preheated to a predefined temperature, in particular to a burner catalyst activation temperature at which a predefined catalytic effect of the burner catalyst is achieved. Experiments carried out in the context of the present invention have shown that the burner can be operated particularly efficiently using a burner catalytic converter and a defined high operating temperature. The burner is preferably heated to a burner catalyst activation temperature which is in a range between 100 ° C. and 300 ° C., in particular in a range between 150 ° C. and 250 ° C., particularly preferably around 200 ° C. The burner is especially heated electrically. This is particularly space-saving and can be implemented effectively.
    Furthermore, it is possible in a method according to the invention that the cathode supply gas, after and / or during the heating of the cathode supply gas by the burner exhaust gas, by means of the cathode exhaust gas heat exchanger and / or by means of an exhaust gas burner for burning the cathode exhaust gas, that is downstream of the cathode section and upstream of the cathode exhaust gas -Heat exchanger is arranged, is additionally heated. This allows the cathode supply gas to be quickly heated to the desired operating temperature. The method according to the invention for heating the fuel cell stack can be carried out in several stages. In other words, the burner or the oxidation catalyst is first heated therein to the desired operating temperature of, for example, approximately 200 ° C. by the heating device. The gas mixture, which has, for example, hydrogen and oxygen or methane and oxygen, can then be burned in an exothermic reaction. Thereafter, the burner exhaust gas generated by the burner, for example a water vapor / air mixture, can heat the cathode feed gas and an anode feed gas via the burner exhaust gas heat exchanger until the fuel cell stack has reached an activation temperature of, for example, approximately 450 ° C. A further temperature increase can now be achieved on the fuel cell stack by the exothermic reactions taking place there.
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    It can be further advantageous here if an operating state of the fuel cell system is determined in a method according to the invention and if it is established that the operating state is in a desired operating state, the supply of fuel to the burner is terminated. The target operating state can correspond to an operating state in which the fuel cell stack has a predefined target temperature or the fuel cell stack has a predefined power. As soon as such a target operating state is reached, less power is required on the burner or the oxidation catalytic converter located therein. Fuel can now be saved by stopping the supply of fuel. The fuel could now be collected in the fuel tank as described above. The completion of the supply of the fuel is preferably carried out continuously. That is, the supply is not stopped suddenly, but in particular depending on the operating state of the fuel cell system, continuously or in stages or essentially in stages. In this way, the less fuel can be fed to the burner, the more the fuel cell stack heats up or the higher the output on the fuel cell stack.
    In addition, it is possible that in a method according to the present invention methane or hydrogen is used as fuel, which is generated upstream of the burner, in particular by means of the condenser. Accordingly, the fuel consists predominantly, preferably exclusively or essentially exclusively, of hydrogen or methane. A particularly effective combustion can be carried out in the burner using one of these two substances. The hydrogen can be made available by the condenser. Methane can be generated in the SOEC operating state by a co-electrolysis of water and carbon dioxide and a subsequent catalytic methanation of hydrogen and carbon monoxide, possibly plus carbon dioxide.
    According to a further aspect of the present invention, a motor vehicle is provided with a fuel cell system as described in detail above, which is configured and designed to carry out a method as described above. A motor vehicle according to the invention thus also has the same advantages as have been described in detail with reference to the device according to the invention. The motor vehicle can be used as / 27
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    AVL List GmbH pure fuel cell vehicle or as a hybrid electric vehicle with an internal combustion engine and the fuel cell system according to the invention.
    Further measures improving the invention result from the following description of various exemplary embodiments of the invention, which are shown schematically in the figures. All of the features and / or advantages arising from the claims, the description or the drawing, including structural details and spatial arrangements, can be essential to the invention both individually and in the various combinations.
    Each shows schematically:
    FIG. 1 shows a block diagram for illustrating a fuel cell system according to an embodiment of the present invention, and
    Figure 2 is a temperature diagram for explaining a method according to an embodiment of the present invention.
    1 shows a block diagram to illustrate a fuel cell system 100. The fuel cell system 100 shown in FIG. 1 has a fuel cell stack 1 with an anode section 1a and a cathode section 1b for performing an electrolysis of water in hydrogen and oxygen in a SOEC operating state of the fuel cell system 100. In addition to the SOEC operating state for fuel production, in the present case for hydrogen production, the fuel cell system 100 shown can also be operated in a SOFC operating state for power generation.
    The fuel cell system 100 further has a cathode section supply line 2 for supplying cathode supply gas to the cathode section 1b and a cathode section exhaust line 3 for discharging cathode exhaust gas from the cathode section 1b. Water or a water-containing fluid is used as the cathode supply gas.
    A cathode exhaust gas heat exchanger 4, a burner exhaust gas heat exchanger 5 and an exhaust gas burner 17 are arranged in the cathode exhaust gas supply line 2. Through a cathode section exhaust line 3, cathode exhaust gas can lead to the exhaust burner 17/27
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    AVL List GmbH are managed. The cathode exhaust gas can be burned there, preferably by means of an exhaust gas burner catalyst in the exhaust gas burner 17. The burned cathode exhaust gas can now be passed further through the cathode section exhaust line 3 to the cathode exhaust gas heat exchanger 4, at which it is brought into thermal operative connection with the cathode section supply line 2 and can accordingly be used to heat the cathode supply gas.
    The burner exhaust gas heat exchanger 5 is arranged downstream of a burner 7. The burner 7 is designed to generate a heated burner exhaust gas by combustion of a gas mixture which has oxygen and fuel in the form of hydrogen. The burner 7 is connected to a burner exhaust gas line 6, in which the burner exhaust gas heat exchanger 5 is also arranged. The burner exhaust line 6 is connected to the cathode section supply line 2 in a heat-transferring manner for heating the cathode supply gas.
    The fuel cell system 100 shown in FIG. 1 also has two oxygen supply units 8, 9 with an oxygen supply line 10 for supplying the oxygen to the burner 7. One oxygen supply unit 8 is designed as a blower for the direct supply of fresh or ambient air from the environment 18 of the fuel cell system 100 to the burner 7. The ambient air can be fed to the burner 7 via a fuel cell stack bypass line 19. The other oxygen supply unit 9 can be understood as the anode section 1a or an anode outlet 9, through which the burner 7 can also be supplied with an oxygen-containing gas.
    The fuel cell system 100 also has two fuel sources 11, 12 with a fuel feed line 13 for feeding the fuel into the burner 7. A fuel source is designed in the form of a condenser 12, which is designed for converting cathode exhaust gas into water and hydrogen. The water generated can be led to a cathode gas source. The hydrogen generated can be led out of the fuel cell system 100, to the burner 7 or into a fuel container 11. The fuel tank 11 is accordingly arranged downstream of the condenser 12. The fuel tank 11 can be understood as a further or the second fuel source. The fuel tank 11 can be filled with a defined amount of fuel before the fuel cell system 100 starts.
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    The fuel tank 11 is arranged in a bypass line 14, which forms a bypass to the fuel supply line 13. It is possible to switch between the bypass line 14 and the fuel supply line 13 by means of a valve control as described above.
    A heater 15 in the form of an electric heater for heating the burner 7 is arranged on the burner 7. The burner 7 has a burner catalyst in the form of an oxidation catalyst for the combustion of the hydrogen-oxygen mixture. For the combustion, the burner 7 or the oxidation catalyst in the burner 7 can be heated to an activation temperature of approximately 200 ° C. by the heating device 15.
    As can be seen in FIG. 1, the burner exhaust gas can be used not only to heat the cathode feed gas, but also to heat the anode feed gas. For this purpose, the burner exhaust gas can be conducted via a second branch of the burner exhaust gas line 6 to an anode supply gas heat exchanger 21 for heating the anode supply gas. For this purpose, the anode supply gas heat exchanger 20 is thermally operatively connected to an anode section supply line 20.
    A method for heating the fuel cell stack 1 is subsequently described with reference to FIG. 2. The temperature or the temperature profile of the fuel cell stack 1 is represented by the graph T1.
    As shown by the graph P1, the burner 7 or the oxidation catalyst therein is first brought to the desired temperature of approximately 200 ° C. by means of the electrical heating device 15. The fuel cell stack 1 is already slightly heated. The combustion of hydrogen and oxygen in the form of an exothermic reaction in burner 7 can now begin. For this purpose, the burner 7 is supplied with hydrogen by one of the hydrogen sources 11, 12 and oxygen by one of the oxygen supply units 8, 9. The exothermic reaction between hydrogen and oxygen is shown in FIG. 2 by graph P2, which shows the corresponding heat output curve. The water vapor-air mixture generated by this reaction can now heat the cathode supply gas and the anode supply gas and thus the fuel cell stack 1 via the burner exhaust gas heat exchanger 5 and the anode supply gas heat exchanger 21. In the present case, the fuel cell stack 1 is thereby activated at an activation temperature 14/27
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    AVL List GmbH heated to a temperature of approx. 450 ° C. This temperature increase can be seen in the middle section of graph T1. A further increase in temperature of the fuel cell stack 1 is now generated by exothermic reactions on the fuel cell stack 1 or in the vicinity thereof, for example in the exhaust gas burner 17. The associated 5 heating power is represented by graph P3. In this phase, in which the
    If the fuel cell system 100 has reached a desired operating state, the hydrogen supply to the burner 7 can be throttled or stopped.
    In addition to the illustrated embodiments, the invention also permits further design principles. The burner 7 can thus be fed with methane instead of hydrogen 10 as fuel. The electrical heating device 15 can also be arranged within the burner 7, in particular within the burner catalytic converter. As a result, the burner catalytic converter can be heated particularly efficiently.
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    Reference list
    Fuel cell stack
    Anode section
    Cathode section
    Cathode section feed line
    Cathode section exhaust pipe
    Cathode exhaust gas heat exchanger
    Burner exhaust gas heat exchanger
    Burner flue pipe
    burner
    Oxygen supply unit
    Oxygen supply unit
    Oxygen supply line
    Fuel source
    Fuel source
    Fuel supply line
    Bypass line
    Heater
    Cathode gas source
    Exhaust burner (heat exchanger)
    Surroundings
    Fuel cell stack bypass line
    Anode section feed line
    Anode feed gas heat exchanger
    Fuel tank
    Fuel cell system
    权利要求:
    Claims (15)
    [1]
    Claims
    1. A fuel cell system (100), comprising:
    a fuel cell stack (1) with an anode section (1a) and a cathode section (1b) for performing an electrolysis of water in hydrogen and oxygen in a SOEC operating state of the fuel cell system (100),
    a cathode section supply line (2) for supplying cathode supply gas to the cathode section (1b),
    a cathode section exhaust line (3) for discharging cathode exhaust gas from the cathode section (1b),
    a cathode exhaust gas heat exchanger (4) which is arranged in the cathode section exhaust pipe (3) and is in thermal operative connection with the cathode section supply line (2) for heating the cathode supply gas,
    - A burner (7) for generating a heated burner exhaust gas by combustion of a gas mixture having oxygen and fuel, with a burner exhaust gas line (6), in which a burner exhaust gas heat exchanger (5) is arranged and thermally transferring for heating the cathode supply gas the cathode section feed line (2) is connected,
    - At least one oxygen supply unit (8, 9) with an oxygen supply line (10) for supplying the oxygen into the burner (7), and
    - At least one fuel source (11, 12) with a fuel feed line (13) for feeding the fuel into the burner (7).
    [2]
    2. Fuel cell system (100) according to claim 1, characterized in that the at least one fuel source (11, 12) has a fuel tank (22) for storing fuel.
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    [3]
    3. Fuel cell system (100) according to one of the preceding claims, characterized in that the at least one fuel source (11, 12) has at least one cathode exhaust gas aftertreatment unit (12), in particular a condenser, which or downstream of the cathode exhaust gas heat exchanger (4) is arranged.
    [4]
    4. The fuel cell system (100) according to claim 3, characterized in that the fuel container (22) is arranged downstream of the at least one cathode exhaust gas aftertreatment unit (12).
    [5]
    5. Fuel cell system (100) according to claim 4, characterized in that the fuel tank (22) in a bypass line (14) which forms a bypass to the fuel supply line (13) is arranged.
    [6]
    6. The fuel cell system (100) according to any one of the preceding claims, characterized in that the burner (7) has a heating device (15), in particular an electric heating device (15) for heating the burner (7).
    [7]
    7. The fuel cell system (100) according to any one of the preceding claims, characterized in that the at least one oxygen supply unit (8, 9) has a fluid delivery unit which for supplying oxygen from the environment of the fuel cell system (100) directly or at least substantially directly upstream of the Burner (7) is arranged.
    [8]
    8. Fuel cell system (100) according to one of the preceding claims, characterized in that the at least one oxygen supply unit (8, 9) is designed in the form of the anode section (1a), the anode section (1a) for providing oxygen-containing fluid to the burner (7 ) is arranged upstream of the burner (7).
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    [9]
    9. Fuel cell system (100) according to one of the preceding claims, characterized in that the burner (7) has a burner catalyst for the combustion of the gas mixture.
    [10]
    10. A method for heating the cathode supply gas in a fuel cell system (100) according to one of the preceding claims, comprising the steps:
    Feeding the cathode feed gas through the cathode section feed line (2) to the cathode section (1b),
    - supplying oxygen through the oxygen supply line (10) to the burner (7),
    - supplying fuel through the fuel supply line (13) to the burner (7),
    - Burning a gas mixture, which has the supplied oxygen and the supplied fuel, in the burner (7), and
    - Feeding a burner exhaust gas, which results from the combustion of the gas mixture, through the burner exhaust gas line (6) from the burner (7) to the burner exhaust gas heat exchanger (5) for heating the cathode supply gas.
    [11]
    11. The method (100) according to claim 10, characterized in that the burner (7) for the combustion of the gas mixture is preheated to a predefined temperature, in particular to a burner catalyst activation temperature at which a predefined catalytic effect of the burner catalyst is achieved.
    [12]
    12. The method (100) according to claim 11, characterized in that the cathode supply gas, after and / or during the heating of the cathode supply gas by the burner exhaust gas, by means of the cathode exhaust gas heat exchanger (4) and / or by means of an exhaust gas burner (17) for burning the cathode exhaust gas, which is arranged downstream of the cathode section (1b) and upstream of the cathode exhaust gas heat exchanger (4) is additionally heated.
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    [13]
    13. The method (100) according to claim 12, characterized in that an operating state of the fuel cell system (100) is determined and, if it is determined that the operating state is in a desired operating state, the supply of fuel to the burner (7) ends becomes.
    [14]
    14. The method (100) according to any one of claims 10 to 13, characterized in that methane or hydrogen is used as fuel, which is generated upstream of the burner (7), in particular by means of the condenser.
    [15]
    15. Motor vehicle with a fuel cell system (100) according to one of claims 1 to 9, which is configured and designed to carry out a method according to one of claims 10 to 14.
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    同族专利:
    公开号 | 公开日
    AT519848B1|2020-03-15|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    EP1941078B1|2005-10-28|2012-04-04|Rolls-Royce Fuel Cell Systems Limited|Electrolysis|
    EP1957694B1|2005-12-01|2016-02-17|LG Fuel Cell Systems Inc.|An electrolysis apparatus|
    WO2016161999A1|2015-04-08|2016-10-13|Sunfire Gmbh|Heat management method in a high-temperature steam electrolysis [soec], solid oxide fuel cell [sofc] and/or reversible high-temperature fuel cell [rsoc], and high-temperature steam electrolysis [soec], solid oxide fuel cell [sofc] and/or reversible high-temperature fuel cell [rsoc] arrangement|AT521903A1|2018-11-27|2020-06-15|Avl List Gmbh|Fuel cell system and method for recirculating exhaust gas in a fuel cell system|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    ATA50308/2017A|AT519848B1|2017-04-13|2017-04-13|Fuel cell system for an SOEC operating state|ATA50308/2017A| AT519848B1|2017-04-13|2017-04-13|Fuel cell system for an SOEC operating state|
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