![]() Multilayer plain bearing element
专利摘要:
The invention relates to a multilayer sliding bearing element (1) having a supporting layer (2) and an aluminum-based alloy layer (3) with aluminum as its main component, the aluminum-based alloy containing between 0% by weight and 7% by weight of tin, between 1, 1 wt .-% and 1.9 wt .-% copper, between 0.4 wt .-% and 1 wt .-% manganese, between 0.05 wt .-% and 0.18 wt .-% cobalt between 0.05% by weight and 0.18% by weight of chromium, between 0.03% by weight and 0.1% by weight of titanium, between 0.05% by weight and 0.18% by weight % Zirconium and between 0 wt .-% and 0.4 wt .-% silicon and the remainder to 100 wt .-% aluminum and optionally from the production of the elements form impurities, with the proviso that in any case tin or Silicon is contained in the aluminum-based alloy. 公开号:AT518875A4 申请号:T50091/2017 申请日:2017-02-06 公开日:2018-02-15 发明作者:Ing Lukas Haedicke Dipl;Ing Dr Sigmar Dominic Josef Janisch Dipl;Ing Dr Alexander Poscher Dipl 申请人:Miba Gleitlager Austria Gmbh; IPC主号:
专利说明:
Summary The invention relates to a multilayer plain bearing element (1) with a support layer (2) and a layer (3) arranged thereon made of an aluminum-based alloy with aluminum as the main component, the aluminum-based alloy between 0% by weight and 7% by weight of tin, between 1.1% % and 1.9% by weight copper, between 0.4% by weight and 1% by weight manganese, between 0.05% by weight and 0.18% by weight cobalt, between 0.05 % And 0.18% by weight of chromium, between 0.03% by weight and 0.1% by weight of titanium, between 0.05% by weight and 0.18% by weight of zirconium and between Contains 0% by weight and 0.4% by weight of silicon and form the remainder to 100% by weight of aluminum as well as any impurities originating from the manufacture of the elements, with the proviso that tin or silicon is contained in the aluminum-based alloy. Fig. 1 1.23 N2016 / 21400 AT-00 The invention relates to a multilayer plain bearing element with a support layer and a layer arranged thereon made of an aluminum-based alloy with aluminum as the main component. The use of aluminum-based alloys in slide bearing technology has been known for a long time and has been widely described in the relevant literature. For example, WO 97/22725 A1 describes an aluminum alloy for a layer of a slide bearing which, as the main alloy element, contains tin and a hard material composed of at least one element from a first element group containing iron, manganese, nickel, chromium, cobalt, copper or platinum, magnesium, antimony where the aluminum alloy from the first element group contains a lot of elements to form intermetallic phases, e.g. Aluminides, is added in the border regions of the matrix and further contains at least one further element from a second manganese, antimony, chromium, tungsten, niobium, vanadium, cobalt, silver, molybdenum or zirconium element group for substituting a part of at least one hard material of the first element group Formation of approximately spherical or cube-shaped aluminides is added. From DE 43 32 433 A1 a multilayer plain bearing is known which has an Al-Sn bearing alloy layer which has a high fatigue resistance and a good fit compared to an associated sliding contact element, a steel support plate and an intermediate bond layer made of a further aluminum alloy, the Al-Sn bearing alloy essentially, based on weight, consists of 7 to 20% Sn and the rest of Al and melting-related impurities and has a hardness of 50 to 80 HV, the intermediate bond layer made of aluminum alloy consisting essentially of min2 / 23 N2016 / 21400-AT-00 least one of the following components, the amount of which is based on the weight: up to 1.7% Mn, up to 1.2% Cu and up to 1.8% Mg and the rest of Al and there are impurities due to melting, and the ratio of the hardness of the intermediate bonding layer made of the aluminum alloy to that of the AlSn bearing alloy, expressed as Vickers hardness (HV), exceeds 70% and is not more than 90%. The Al-Sn alloy can contain at least one of the following components, the amount of which is based on the weight: 0.01 to 3% Mn, Mg, V, Ni, Cr, Zr and / or B, 0.2 to 5% Cu, 0.1 to 3% Pb, 0.1 to 3% Sb and 0.01 to 1% Ti. It can further be provided that the aluminum alloy of the intermediate bond layer has a total of up to 3% by weight of at least one of the elements Si , Cr, Ti and Fe contains. As is known from the last-mentioned DE 43 32 433 A1, an intermediate bond layer, which likewise consists of an aluminum alloy, can be used to improve the adhesive strength of the bearing alloy layer on the steel support plate. Other aluminum alloys have also been used for the intermediate bond layer, such as Al3Sc (WO 00/06788 A1). In addition, versions have been described in the prior art in which the bearing alloy layer is connected to the steel support layer via a binding foil made of pure aluminum. The present invention is based on the object of creating a multilayer plain bearing element with an aluminum-based alloy, in which the aluminum-based alloy has good adhesion to the support layer and has a low notch effect. The object of the invention is achieved with the multilayer slide bearing element mentioned at the outset, in which the aluminum-based alloy contains between 0% by weight and 7% by weight of tin, between 1.1% by weight and 1.9% by weight of copper, between 0 , 4% by weight and 1% by weight of manganese, between 0.05% by weight and 0.18% by weight of cobalt, between 0.05% by weight and 0.18% by weight of chromium, between 0.03% and 0.1% by weight of titanium, between 0.05% and 0.18% by weight of zirconium and between 0% by weight and 0.4% by weight Contains silicon and the remainder to 100% by weight aluminum as well as Verun3 / 23 originating from the manufacture of the elements N2016 / 21400-AT-00 form cleaning, with the proviso that tin or silicon is contained in the aluminum-based alloy. The advantage here is that the small proportion of the alloy elements present in addition to aluminum and tin in the alloy can reduce the risk of brittle fracture at the interface between the support element and the layer made of the aluminum-based alloy as a result of brittle phases formed. Viewed over time, the aluminum-based alloy thus has a lower tendency to brittle fracture (flaking) and thus better adhesion to the support layer. This effect can be intensified if silicon is contained in the aluminum-based alloy, which, as a reaction inhibitor, improves the avoidance of the formation of brittle phases. However, the relative proportion of silicon in the aluminum-based alloy is not so large that it is tribologically effective, which can prevent the notch effect. The tribological properties of known silicon-free aluminum-based alloys can thus be achieved at least approximately with the aluminum-based alloy, whereby the composite fatigue strength of the multilayer plain bearing element can be improved. According to an embodiment variant of the multilayer plain bearing element, it can be provided that the support layer consists of an iron-based alloy and that the aluminum-based alloy is directly connected to the iron-based support layer and consists of 5% by weight to 7% by weight of tin, 1.1% by weight. up to 1.5% by weight copper, 0.4% by weight to 0.8% by weight manganese, 0.05% by weight to 0.15% by weight cobalt, 0.05% by weight % to 0.15% by weight chromium, 0.03% by weight to 0.10% by weight titanium, 0.05% by weight to 0.15% by weight zirconium, 0.2% by weight -% to 0.4% by weight of silicon and the remainder to 100% by weight of aluminum and any impurities originating from the manufacture of the elements. The above effects can thus be achieved with only a single layer of the aluminum-based alloy. It is furthermore possible for a concentration gradient to be formed for silicon within the layer made of the aluminum-based alloy, with an increasing proportion of silicon in the direction of the support layer. It can be achieved 4.23 N2016 / 21400-AT-00 that the effect of the addition of silicon on the bonding zone between the support layer and the layer made of the aluminum-based alloy is at least largely concentrated, and that the avoidance of the tribological effectiveness of the silicon in the aluminum-based alloy can be realized more easily because of this Areas of the aluminum-based alloy directly adjacent to a sliding partner can be formed silicon-free. According to another embodiment variant, in order to achieve the effects mentioned above, it can be provided that the support layer consists of an iron-based alloy and that the aluminum-based alloy is directly connected to the iron-based support layer and from 1.5% to 1.9% by weight of copper , 0.6% by weight to 1.0% by weight of manganese, 0.08% by weight to 0.18% by weight of cobalt, 0.08% by weight to 0.18% by weight Chromium, 0.03 wt% to 0.10 wt% titanium, 0.08 wt% to 0.18 wt% zirconium, 0.2 wt% to 0.4 wt% % Silicon and the remainder to 100% by weight of aluminum and, where appropriate, impurities originating from the production of the elements and that the layer made of the aluminum-based alloy is connected to a further layer made from a further aluminum-based alloy, the further layer consisting of the further aluminum-based alloy that is silicon free. Another advantage is that the additional layer made of the additional aluminum-based alloy can be better adapted to the tribological requirements of a running layer. In addition, the layer made of the aluminum-based alloy arranged between the support layer and the further layer made of the further aluminum alloy has emergency running properties which counteract a sudden failure of the multilayer plain bearing element as a result of at least partial wear of the further layer arranged above it. According to a further embodiment variant, it is preferably provided that the further aluminum-based alloy of the further layer consists of 5.0% by weight to 7.0% by weight of tin, 1.1% by weight to 1.5% by weight of copper , 0.4% by weight to 0.8% by weight of manganese, 0.05% by weight to 0.15% by weight of cobalt, 0.05% by weight to 0.15% by weight Chromium, 0.03% by weight to 0.1% by weight titanium, 0.05% by weight to 0.15% by weight zirconium and the remainder to 100% by weight aluminum and optionally from the 23.5 N2016 / 21400 AT-00 Production of elements originating from impurities exists. The material compatibility between the two aluminum-based alloys can thus be improved. In this embodiment variant, the aluminum-based alloy of the layer directly connected to the iron-based support layer and the further aluminum-based alloy of the further layer preferably have the same relative proportion in relation to the elements copper, manganese, cobalt, chromium, titanium and zirconium. This results in better material compatibility of the two aluminum-based alloys with one another. According to a further embodiment variant of the multilayer plain bearing element, it can be provided that the ratio of the proportions of titanium to cobalt is between 1: 3 and 3: 1. The aluminum-based alloy thus has a fine-grained structure which has only a slight tendency to recrystallize even under the conditions during use of the multilayer plain bearing element. Intermetallic precipitates are present in the aluminum alloy of the layer directly connected to the iron-based support layer and in the further aluminum alloy of the further layer. It can be provided that an average size of the intermetallic precipitates in the layer of the aluminum alloy directly connected to the iron-based support layer is smaller than an average size of the intermetallic precipitates in the further aluminum alloy of the further layer. It can thus be achieved that the aluminum-based alloy of the layer connected to the iron-based support layer is tougher. This in turn has a positive effect on the ability of the multilayer plain bearing element to be subjected to alternating stresses, since this aluminum-based alloy therefore does not trigger cracks. The notch effect of the intermetallic phases can also be reduced. It is also possible for titanium to be replaced by zirconium and / or scandium up to a maximum of half of the titanium content in the aluminum-based alloy and / or 6.23 N2016 / 21400-AT-00 that at least one element from the group manganese, cobalt and chromium, to the extent of at most half the amount of these elements in the aluminum-based alloy, is replaced by vanadium and / or molybdenum and / or iron. With these design variants, the grain size distribution or the recrystallization behavior of the aluminum-based alloy can be influenced. For a better understanding of the invention, this will be explained in more detail with reference to the following figures. They show (in a simplified, schematic representation): 1 shows a multilayer plain bearing element in a side view; Fig. 2 shows the alternating bending strengths of various aluminum-based alloys. In the introduction, it should be noted that in the differently described embodiments, the same parts are provided with the same reference numerals or the same component names, and the disclosures contained in the entire description can be applied analogously to the same parts with the same reference numerals or the same component names. The location information selected in the description, e.g. above, below, laterally, etc. related to the figure described and illustrated immediately and in the case of a change of position to be transferred to the new position. All information on the quantitative composition of the aluminum-based alloys) is to be understood in% by weight, unless expressly stated otherwise. Fig. 1 shows a multilayer plain bearing element 1 in an oblique view. The multilayer plain bearing element 1 comprises or consists of a support layer 2 and a layer 3 arranged thereon and connected to it. The non-closed multilayer plain bearing element 1 can, in addition to the half-shell version shown, have an angular coverage of at least 7/23 N2016 / 21400-AT-00 at least approximately 180 ° also have a different angular range coverage, for example at least approximately 120 ° or at least approximately 90 °, so that the multi-layer sliding bearing element 1 can also be designed as a third shell or a quarter shell, with corresponding further ones Bearing shells can be combined in a bearing receptacle, the multilayer sliding bearing element 1 according to the invention preferably being installed in the region of the bearing receptacle which is subject to higher loads. However, other design variants of the multilayer plain bearing element 1 are also possible, for example a design as a bearing bush, as indicated by the broken lines in FIG. 1, or a flat design, for example as a thrust washer. The support layer 2 usually consists of a hard material. Bronzes, brass, etc. can be used as materials for the support layer 2, also called the support shell. In the preferred embodiment variant of the invention, the support layer 2 consists of an iron-based material, in particular of a steel. Such structural designs of multilayer plain bearing elements 1 are known in principle from the prior art, so that reference is made to the relevant prior art in this regard. Layer 3 consists of aluminum-based alloy. The aluminum base alloy consists of: % By weight to 7% by weight of tin 1.1 wt% to 1.9 wt% copper 0.4 wt% to 1 wt% manganese 0.05 wt% and 0.18 wt% cobalt 0.05 wt% and 0.18 wt% chromium 0.03 wt% and 0.1 wt% titanium 0.05 wt% and 0.18 wt% zirconium and % By weight and 0.4% by weight of silicon. 8.23 N2016 / 21400 AT-00 The remainder to 100% by weight form the main constituent of the aluminum-based alloy, the aluminum and any impurities originating from the manufacture of the elements. In any case, the aluminum-based alloy contains tin or silicon. The basic effects of the individual alloy elements are sufficiently shown in the prior art and known to the person skilled in the art, so that they are not repeated. The respective proportions of the individual alloy elements in the aluminum-based alloy were chosen for the following reasons, the effect of the added element not being sufficient below the lower limit of the proportion ranges given: % By weight of tin: With more than 7% by weight of tin, the risk of heat crack sensitivity of the aluminum-based alloy increases. 1.9% by weight copper: With more than 1.9% by weight copper, the formability of the aluminum-based alloy is reduced. 0.1% by weight of titanium: With more than 0.1% by weight of titanium, corrosion problems can occur which can reduce the fatigue strength of the aluminum-based alloy. It has also been observed that the squeezing of the tin can be avoided compared to known sputter bearings. Wt% manganese; 0.18% by weight cobalt; 0.18 wt% chromium; 0.18 wt% zirconium; 0.4% by weight silicon: With a proportion of the respective elements of more than the specified upper limits, the sizes of the precipitation increase without additional gain in strength. In addition, the notch effect of the excretions increases. Titan can also be replaced by zirconium and / or scandium up to half of the above-mentioned titanium content in the aluminum-based alloy. 23.9 N2016 / 21400 AT-00 It is also possible for at least one element from the group of manganese, cobalt and chromium to be replaced by vanadium and / or molybdenum and / or iron to the extent of at most half of the above-mentioned proportion of these elements in the aluminum-based alloy. According to a preferred embodiment variant, the multilayer plain bearing element 1 consists of the support layer 2 made of an iron-based alloy, in particular a steel, and the layer 3 arranged directly thereon and connected to the support layer 2 made of the aluminum-based alloy. In this case, the latter preferably consists of 5% by weight to 7% by weight of tin, 1.1% by weight to 1.5% by weight copper, 0.4% by weight to 0.8% by weight manganese, 0.05% by weight to 0.15% by weight cobalt, 0.05% by weight up to 0.15% by weight chromium, 0.03% by weight to 0.10% by weight titanium, 0.05% by weight to 0.15% by weight zirconium, 0.2% by weight % to 0.4% by weight silicon. The remainder to 100% by weight is formed by the aluminum and any impurities that may have come from the manufacture of the elements. In particular, the aluminum-based alloy of this embodiment can consist of 6% by weight of tin, 1.3% by weight of copper, 0.6% by weight of manganese, 0.10% by weight of cobalt, 0.10% by weight of chromium, 0.07% by weight of titanium, 0.10% by weight of zirconium, 0.3% by weight of silicon and the remainder to 100% by weight of aluminum and any impurities originating from the production of the elements. According to a further embodiment variant of the multilayer plain bearing element 1, it can be provided that a concentration gradient is formed for silicon within the layer 3 made of the aluminum-based alloy, with an increasing proportion of silicon in the direction of the support layer 2. For example, the concentration of silicon in layer 3 can be from 0% by weight. -% on the outer, ie of the surface of layer 3 facing away from the support layer 2 increase to a value of 0.3% by weight on the surface adjacent to the support layer 2. The increase in silicon concentration can be linear or exponential or abrupt. According to another embodiment variant of the multilayer plain bearing element 1, it can be provided that the support layer 2 is made of an iron-based alloy 10/23 N2016 / 21400-AT-00 exists and the aluminum-based alloy forming the layer 3 is directly connected to the iron-based support layer 2. A further layer 4 is arranged on this layer 3, as shown in dashed lines in FIG. 1, so that layer 3 is thus arranged between the support layer 2 and the further layer 4. The further layer 4 is arranged directly on the layer 3 and connected to it. In contrast to the previous embodiment variant, layer 3, which is directly connected to support layer 2, does not form the running layer of multilayer sliding bearing element 1, but rather a layer with which the further layer 4, which forms the running layer, made of the further aluminum-based alloy is connected to support layer 2 becomes. The aluminum-based alloy of the layer 3 directly connected to the support layer 2 in this case consists of 1.5% by weight to 1.9% by weight of copper, 0.6% by weight to 1.0% by weight of manganese, 0.08 wt% to 0.18 wt% cobalt, 0.08 wt% to 0.18 wt% chromium, 0.03 wt% to 0.10 wt% titanium , 0.08% by weight to 0.18% by weight of zirconium, 0.2% by weight to 0.4% by weight of silicon and the rest to 100% by weight of aluminum and, if appropriate, from the production of the Element-derived impurities. In particular, this aluminum-based alloy of layer 3 can consist of 1.7% by weight copper, 0.8% by weight manganese, 0.13% by weight cobalt, 0.13% by weight chromium, 0.07% by weight. % Titanium, 0.13% by weight zirconium, 0.3% by weight silicon and the remainder to 100% by weight aluminum and, if appropriate, impurities originating from the production of the elements. The further aluminum-based alloy of the further layer 4 is silicon-free except for permissible impurities in the metals from which the aluminum-based alloy is produced. Otherwise, it can consist of an aluminum-based alloy, as is known from the prior art for running layers of slide bearings. However, the further layer 4 preferably consists of a further aluminum-based alloy which consists of 5.0% by weight to 7.0% by weight of tin, 1.1% by weight to 1.5% by weight of copper, 0.4 % By weight to 0.8% by weight of manganese, 0.05% by weight to 0.15% by weight of cobalt, 0.05% by weight to 0.15% by weight of chromium, 03% by weight to 0.1% by weight of titanium, 11/23 N2016 / 21400 AT-00 0.05% by weight to 0.15% by weight of zirconium and the remainder to 100% by weight of aluminum and any impurities originating from the production of the elements. In particular, the further layer 4 consists of a further aluminum-based alloy consisting of 6.0% by weight of tin, 1.3% by weight of copper, 0.6% by weight of manganese, 0.10% by weight of cobalt, 10% by weight of chromium, 0.07% by weight of titanium, 0.10% by weight of zirconium and the remainder to 100% by weight of aluminum and any impurities originating from the production of the elements. It is particularly preferred if the aluminum-based alloy of the layer 3 directly connected to the iron-based support layer 2 and the further aluminum-based alloy of the further layer 4 with respect to the elements copper, manganese, cobalt, chromium, titanium and zirconium have the same relative relative to the respective aluminum content Proportion on, ie that the ratio of the proportions of these elements to the aluminum content in the two aluminum alloys is the same. According to a further embodiment variant of the multilayer plain bearing element 1, it can be provided that the ratio of the proportions of titanium to cobalt between the layer 3 directly connected to the support layer 2 and / or in the further layer 4 connected to the layer 3 1: 3 and 3: 1 is. It can also be provided that intermetallic precipitates are present in the aluminum-based alloy of the layer 3 directly connected to the iron-based support layer 2 and in the further aluminum-based alloy of the further layer 4, with an average size of the intermetallic precipitates in that of the aluminum-based alloy directly with the layer 3 connected to the iron-based support layer 2 is smaller than an average size of the intermetallic precipitates in the further aluminum-based alloy of the further layer 4. The mean size is determined as an arithmetic mean from the micrograph of the respective aluminum-based alloy using the line-cutting method, as is known per se. For this purpose, Li12 / 23 N2016 / 21400-AT-00 with a defined route. A mark is made at every point where the line crosses a grain boundary. The average size of the intermetallic precipitates can be determined analogously to DIN EN ISO 643. It should be mentioned that all the standards cited in the description are to be applied in the version that is valid on the filing date of the subject patent application. The intermetallic precipitates are compounds of the elements copper and / or manganese and / or cobalt and / or chromium and / or titanium and / or zirconium, each with aluminum and / or the elements with one another. For example, these are the intermetallic compounds AI2CU, Al6Mn (Fe, Cr, Co). The average size of 90% of the intermetallic precipitates in the layer 3 directly connected to the support layer 2 can preferably be between 1 pm and 5 pm. The average size of 90% of the intermetallic precipitates in the further layer 4 directly connected to the layer 3 can preferably be between 0.1 pm and 4 pm. The multilayer plain bearing element 1 can be produced using conventional methods known from the prior art. For example, layer 2 can be roll-plated with support layer 2. There is also the possibility that the layer 3 is poured onto the support layer 2. The further layer 4 can be roll-plated with the composite material of the support layer 2 and layer 3. The further layer 4 can also be poured onto the layer 3. In addition, there is also the possibility that in a first step a composite material is produced from the layer 3 and the further layer 4, for example by means of roll cladding, and that this composite material is subsequently connected to the support layer 2, for example by means of roll cladding. 13/23 N2016 / 21400 AT-00 The concentration gradient for silicon mentioned above can be produced via the cooling conditions of the aluminum-based alloy, the casting process itself, by a spraying process, etc. The formation of the above-mentioned sizes of the intermetallic compounds can be achieved by rapid cooling of the aluminum-based alloy. It is known per se to the person skilled in the art that a more fine-grained structure can be achieved by faster cooling, so that explanations about the cooling conditions are unnecessary. It is further possible that the proportion of intermetallic precipitates in layer 3 has a maximum of 5 vol.%, In particular between 1 vol.% And 2 vol.%, And / or the proportion of intermetallic precipitates in layer 4 a maximum of 2% by volume, in particular between 0.5% by volume and 2% by volume. In the context of the invention, in addition to the two-layer or three-layer design of the multilayer plain bearing element 1, there is also the possibility that an inlet layer, for example a pure tin layer, is applied to layer 3 (in the case of the two-layer version) or to the further layer 4 (in the case of the three-layer version) or a layer of lubricating varnish. The following sample multilayer plain bearing elements were produced in the course of the evaluation of the multilayer plain bearing element 1. The alternating bending strength, the tendency to seizure in dynamic load cases and the wear were determined from these. Parameters for the alternating bending strength: 25 Hz, room temperature, flat bending specimens (90 mm x 17.5 mm x 1.82 mm (thereof steel 1.4 mm), central taper L = 28.2 mm, R = 37.5 mm), Max. Bending moment 15 Nm, max. Bending angle 12. Parameters for the tendency to seize: test bearing with 80.5 mm outer diameter; Speed 3000 min-1, oil SAE 10W Shell Rimula, oil inlet at 120 ° C; Counter body steel shaft, increasing load is superimposed with a dynamic load at 50 Hz. 14/23 N2016 / 21400 AT-00 Parameters for wear. Test bearing with 80.5 mm outer diameter; Speed 3000 min-1, oil SAE 10W Shell Rimula, oil inlet at 110 ° C; Counter body steel shaft, 50 Hz dynamic load pressure swelling, max. Amplitude 75 or 100 MPa, test duration 15 h. The wear in pm is evaluated. A support layer 2 made of steel (HB30 = 177-182) was used in each case. The following aluminum-based alloys listed in Table 1 were used for layer 3 in the two-layer embodiment variant. The figures are to be understood in% by weight. Aluminum accounts for the remainder to 100% by weight. The test specimens were produced by roll plating layer 3 onto the support layer 2. Table 1: Compositions of aluminum-based alloys No. sn Cu Mn Co Cr Ti Zr Si 1 5 1.1 0.4 0.05 0.05 0.03 0.05 0.2 2 6 1.3 0.6 0.1 0.1 0.07 0.15 0.3 3 7 1.5 0.8 0.15 0.15 0.1 0.15 0.4 It was found that the multilayer plain bearing elements 1 produced therewith delivered comparable results with respect to wear and tendency to seize, as multilayer plain bearing elements according to the prior art. With regard to the alternating bending strength, however, better results were achieved. Test samples of the three-layer design variant of the multilayer plain bearing were also produced. Again, a steel support layer 2 was used. 15/23 N2016 / 21400 AT-00 The test samples were made by first creating a bimetal strip from layer 3 and layer 4. This bimetallic strip was then roll-plated onto a steel support layer and the composite was heat-treated at 350 ° C. Table 2 shows exemplary embodiments for aluminum-based alloys of layer 4 and table 3 shows exemplary embodiments for aluminum-based alloys of layer 3. An aluminum-based alloy, designated X B in Table 3, of layer 3, an aluminum-based alloy, designated X A in Table 2, was applied as layer 4, so that, for example, example 4, layer 3 includes aluminum base alloy 4 B and layer 4 includes aluminum base alloy 4 A. Table 2: Compositions of layer 4 aluminum base alloys No. sn Cu Mn Co Cr Ti Zr 4 A 6 1.3 0.6 0.1 0.1 0.07 0.1 5A 5 1.1 0.4 0.05 0.05 0.03 0.05 6 A 7 1.5 0.8 0.15 0.15 0.10 0.15 Table 3: Compositions of layer 3 aluminum base alloys No. Cu Mn Co Cr Ti Zr Si 4 B 1.7 0.8 0.13 0.07 0.07 0.13 0.3 5 B 1.5 0.6 0.08 0.08 0.03 0.08 0.2 6 B 1.9 Λ 1.0 0.18 0.18 0.1 0.18 0.4 16/23 N2016 / 21400 AT-00 Representative of these design variants of the multilayer plain bearing element 1, the results of the alternating bending strength, the tendency to seize in dynamic load cases and the wear for the combination steel 4B - 4A (hereinafter AB 4) are shown below. In addition, the following comparative samples were made and the corresponding investigations were carried out. Structure of comparison sample 10 (VM 10): steel - AlZn - AISn25 Structure of comparison sample 11 (VM 11): steel - AI - AISn6Si Structure of comparison sample 12 (VM 12): steel - AI - AISn20Si The results for the alternating bending strengths are shown in FIG. 2, in which the number of stress cycles is plotted on the abscissa and the bending stresses in MPa are plotted on the ordinate. Here mean: Reference numeral 5: embodiment 4, transverse to the rolling direction Reference numeral 6: embodiment 4, longitudinal to the rolling direction Reference numeral 7: comparison pattern 11, transverse to the rolling direction Reference numeral 8: comparison pattern 11, longitudinal to the rolling direction Reference numeral 9: comparison sample 12, transverse to the rolling direction Reference numeral 10: comparison pattern 12, longitudinal to the rolling direction Reference numeral 11: comparison sample 10, along the rolling direction Results of the tendency to seize in dynamic load cases [MPa] FROM 4 VM 10 VM 11 VM 12 144 147 157 137 Results for wear [m]: 17/23 N2016 / 21400 AT-00 FROM 4 VM 10 VM 11 VM 12 1.2 5 2.1 2.8 The exemplary embodiments show or describe possible design variants, it being noted at this point that various combinations of the individual design variants with one another are also possible, in particular with regard to the compositions of layer 3 and layer 4, which are used with one another in a multilayer plain bearing element 1. For the sake of order, it should finally be pointed out that, for a better understanding of the structure of the multilayer plain bearing element 1, it is not necessarily shown to scale. 18/23 N2016 / 21400 AT-00 LIST OF REFERENCE NUMBERS Multilayer plain bearing element backing layer layer Embodiment 4 Embodiment 4 Comparison Pattern 11 Comparison Pattern 11 Comparison Pattern 12 Comparison Pattern 12 Comparison Pattern 10 19/23 N2016 / 21400 AT-00
权利要求:
Claims (10) [1] claims 1. multilayer plain bearing element (1) with a support layer (2) and a layer (3) arranged thereon made of an aluminum-based alloy with aluminum as the main component, characterized in that the aluminum-based alloy is between 0% by weight and 7% by weight of tin, between 1, 1% by weight and 1.9% by weight copper, between 0.4% by weight and 1% by weight manganese, between 0.05% by weight and 0.18% by weight cobalt, between 0.05% by weight and 0.18% by weight chromium, between 0.03% by weight and 0.1% by weight titanium, between 0.05% by weight and 0.18% by weight % Zirconium and between 0% by weight and 0.4% by weight of silicon and form the remainder to 100% by weight of aluminum and any impurities originating from the manufacture of the elements, with the proviso that tin or silicon in any case the aluminum base alloy is included. [2] 2. multilayer plain bearing element (1) according to claim 1, characterized in that the support layer (2) consists of an iron-based alloy and that the aluminum-based alloy is directly connected to the iron-based support layer (2) and from 5 wt .-% to 7 wt .-% % Tin, 1.1% by weight to 1.5% by weight copper, 0.4% by weight to 0.8% by weight manganese, 0.05% by weight to 0.15% by weight % Cobalt, 0.05% to 0.15% chromium, 0.03% to 0.10% titanium, 0.05% to 0.15% by weight. -% zirconium, 0.2 wt .-% to 0.4 wt .-% silicon and the remainder to 100 wt .-% of aluminum as well as any impurities originating from the manufacture of the elements. [3] 3. multilayer plain bearing element (1) according to claim 2, characterized in that a concentration gradient is formed for silicon within the layer (3) made of aluminum-based alloy, with increasing silicon content in the direction of the support layer (2). [4] 4. multilayer plain bearing element (1) according to claim 1, characterized in that the support layer (2) consists of an iron-based alloy and 20/23 N2016 / 21400-AT-00 that the aluminum-based alloy of the layer (3) is directly connected to the iron-based support layer (2) and from 1.5% to 1.9% by weight copper, 0.6% by weight % to 1.0 wt% manganese, 0.08 wt% to 0.18 wt% cobalt, 0.08 wt% to 0.18 wt% chromium, 0.03 wt. % to 0.10% by weight of titanium, 0.08% by weight to 0.18% by weight of zirconium, 0.2% by weight to 0.4% by weight of silicon and the rest to 100% by weight .-% consists of aluminum and any impurities originating from the manufacture of the elements and that a further layer (4) made of a further aluminum-based alloy is connected to the layer (3) made of the aluminum-based alloy, the further layer (4) made of the further aluminum-based alloy exists that is silicon-free. [5] 5. multilayer sliding bearing element (1) according to claim 4, characterized in that the further aluminum-based alloy of the further layer (4) from 5.0 wt .-% to 7.0 wt .-% tin, 1.1 wt .-% to 1 , 5% by weight copper, 0.4% by weight to 0.8% by weight manganese, 0.05% by weight to 0.15% by weight cobalt, 0.05% by weight to 0.15% by weight of chromium, 0.03% by weight to 0.1% by weight of titanium, 0.05% by weight to 0.15% by weight of zirconium and the rest to 100% by weight % consists of aluminum and any impurities originating from the manufacture of the elements. [6] 6. multilayer plain bearing element (1) according to claim 4 or 5, characterized in that the aluminum-based alloy of the directly with the iron-based support layer (2) connected layer (3) and the further aluminum-based alloy of the further layer (4) with respect to the elements copper, manganese , Cobalt, chrome, titanium and zirconium have the same relative proportions based on the respective aluminum content. [7] 7. multilayer plain bearing element (1) according to one of claims 1 to 6, characterized in that the ratio of the proportions of titanium to cobalt is between 1: 3 and 3: 1. [8] 8. multilayer plain bearing element (1) according to any one of claims 4 to 7, characterized in that in the aluminum-based alloy directly with the 21/23 N2016 / 21400-AT-00 iron-based support layer (2) connected layer (3) and in the further aluminum-based alloy of the further layer (4) intermetallic precipitates are respectively present, with an average size of the intermetallic precipitates in that of the aluminum-based alloy directly with the iron-based Support layer (2) connected layer (3) is smaller than an average size of the intermetallic precipitates in the further aluminum-based alloy of the further layer (4). [9] 9. multilayer plain bearing element (1) according to any one of claims 1 to 8, characterized in that titanium is replaced up to a maximum of half of the titanium content in the aluminum-based alloy by zirconium and / or scandium. [10] 10. multilayer plain bearing element (1) according to any one of claims 1 to 9, characterized in that at least one element from the group manganese, cobalt and chromium to the extent of at most half the amount of these elements in the aluminum-based alloy by vanadium and / or molybdenum and / or Iron is replaced. 22/23 N2016 / 21400 AT-00
类似技术:
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同族专利:
公开号 | 公开日 AT518875B1|2018-02-15| BR112019014559A2|2020-02-18| US11137027B2|2021-10-05| CN110199042B|2021-10-29| EP3577244A1|2019-12-11| US20190368545A1|2019-12-05| CN110199042A|2019-09-03| WO2018140997A1|2018-08-09|
引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题 DE10335086A1|2002-08-12|2004-03-04|Daido Metal Co. Ltd., Nagoya|Multi-layer bearing based on aluminum| US20050221110A1|2004-03-31|2005-10-06|Daido Metal Company Ltd.|Plain bearing and method of manufacturing the same| DE112010003120T5|2009-07-29|2013-01-10|Daido Metal Company Ltd.|bearings| US20160091021A1|2014-03-19|2016-03-31|Taiho Kogyo Co., Ltd.|Sliding bearing|EP3825119A1|2019-11-19|2021-05-26|Miba Gleitlager Austria GmbH|Multilayer sliding bearing element|JP2657143B2|1992-10-26|1997-09-24|大同メタル工業株式会社|Multi-layer plain bearing with excellent fatigue resistance and conformability with Al-Sn based bearing alloy sliding layer| AT405296B|1995-12-20|1999-06-25|Miba Gleitlager Ag|SLIDING BEARING MATERIAL FROM ONE UP TO MELTING-BASED IMPURITIES SILICON-FREE ALUMINUM ALLOY| AT407404B|1998-07-29|2001-03-26|Miba Gleitlager Ag|INTERMEDIATE LAYER, IN PARTICULAR BOND LAYER, FROM AN ALUMINUM-BASED ALLOY| JP3958515B2|2000-10-18|2007-08-15|大同メタル工業株式会社|Multilayer bearing and manufacturing method thereof| CN102900767B|2012-09-28|2015-04-22|广州安达精密工业股份有限公司|Bearing bush| EP2985358B1|2014-08-14|2017-05-03|KS Gleitlager GmbH|Friction bearing composite material|DE202020103086U1|2020-05-28|2020-06-16|Ks Gleitlager Gmbh|Metallic plain bearing composite| CN112522548A|2020-11-06|2021-03-19|北京工业大学|Wear-resistant Mg-containing aluminum-tin bearing bush alloy|
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申请号 | 申请日 | 专利标题 ATA50091/2017A|AT518875B1|2017-02-06|2017-02-06|Multilayer plain bearing element|ATA50091/2017A| AT518875B1|2017-02-06|2017-02-06|Multilayer plain bearing element| BR112019014559-1A| BR112019014559A2|2017-02-06|2018-02-05|MULTILAYER SLIDING BEARING ELEMENT| CN201880008007.4A| CN110199042B|2017-02-06|2018-02-05|Multi-layer plain bearing element| EP18721667.6A| EP3577244A1|2017-02-06|2018-02-05|Multi-layer sliding-bearing element| PCT/AT2018/060031| WO2018140997A1|2017-02-06|2018-02-05|Multi-layer sliding-bearing element| US16/477,256| US11137027B2|2017-02-06|2018-02-05|Multi-layer sliding-bearing element| 相关专利
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