• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    The invention relates to a photovoltaic element (1) comprising an upper Einbett tolienmaterial (7) and a lower Einbettfolienmaterial (8), wherein between the upper and the lower Einbettfolie material (7, 8) photovoltaic cells (4) are embedded, and a rear side film material (5 ) disposed in the installed position of the photovoltaic element (1) below the lower embedding film material (8), and wherein the back sheet material (5) is formed by a composite film comprising at least one plastic layer (9) and at least one fiber reinforcement (10); / or that at least one of the two Einbettfolienmaterialien (7, 8) has a physically crosslinked plastic.
    公开号:AT517402A1
    申请号:T320/2015
    申请日:2015-05-20
    公开日:2017-01-15
    发明作者:Dipl Ing Dr Brandstätter Andreas；Dipl Ing Grieshofer Hubert
    申请人:Lenzing Plastics Gmbh & Co Kg；
    IPC主号:
    专利说明:

    The invention relates to a photovoltaic element comprising an upper Einbettfoli-enmaterial and a lower Einbettfolienmateriai, wherein between the upper and the lower Einbettfolienmateriai photovoltaic cells are embedded, and a rear side film material, which is arranged in the installed position of the photovoltaic element below the lower embedding film material.
    A commercially available photovoltaic module consists on the front side (the side facing the sun) of a glass pane, in particular a single-pane safety glass (ESG), including a transparent Einbettfolie to einzubet the solar cells and their electrical wiring (soldering tape) towards the glass -ten, underneath the electronics with the solar cells is typically again the same embedding film and the back end forms a Folienla-minat, the so-called backsheet, for example, of a PVF-PET-PVF laminate (polyvinyl fluoride polyethylene terephthalate polyvinyl fluoride- Laminate) is formed. The embedding foils are typically made of EVA (polyethylene-vinyl acetate). All layers are superimposed upon assembly of the modules and thermally laminated together. The EVA is chemically crosslinked. During lamination, the previously milky EVA film forms a clear, three-dimensionally crosslinked and non-fusible plastic layer in which the solar cells are embedded and which is firmly connected to the glass pane and the backsheet. Such a structure is apparent, for example, from "http://www.solarfassade.info/de/grundlagen/komponenten/pvmodule.php".
    Such a structure has essentially two disadvantages resulting from the use of the materials mentioned. On the one hand, the EVA releases acetic acid due to solar radiation. Since acetic acid is known to be corrosive to the solar cells and their wiring, it must be removed from the photovoltaic module. This, in turn, requires that the laminate on the back must be diffusely open, since the acetic acid can not escape via the front glass pane. The diffusibility of the backsheet prevents the weatherproof design of the photovoltaic module. In addition, the crosslinking agents for crosslinking the EVA may form peroxides leading to premature aging.
    On the other hand, the rigidity of the photovoltaic module has so far been controlled mainly by the glass thickness. The backsheet has received little attention in terms of stiffness. Due to differences in thermal expansion between the glass on the front side and the backsheet film, corresponding stresses can arise in the laminate which can be detrimental to the permanent bonding of the laminate.
    The present invention has for its object to improve a photovoltaic element in terms of its durability.
    This object is achieved with the photovoltaic element mentioned above in that the RCickseitenfolienmaterial is formed by a composite film comprising at least one plastic layer and at least one fiber reinforcement and / or that at least one of the two Einbettfolienmaterialien has a physically-crosslinked plastic.
    The fiber reinforcement of the backsheet material can provide improved rigidity and strength, especially at temperatures above room temperature, right up to the lamination temperature. Improved mechanical resistance to damage on the one hand, but also to the stiffer RCick side foil material can reduce the glass thickness and thus the total weight of the photovoltaic element. It has also been shown that this RCick Seitenfolienmaterial has a lower creep than rear side foils of commercial photovoltaic modules. Furthermore, the RCick side foil material has a reduced, adapted to the front glazing, thermal expansion, resulting in temperature changes to less stress in the module structure. For tensions due to different thermal expansions, the cover made of glass and the rear side foil material are primarily responsible, since the two embedding foil materials for the electronics generally ensure an elastic insert and different expansions can be accommodated via these embedding foil materials. Thus, it is advantageous to have the same coefficients of thermal expansion as possible for the two rigid edge layers, the glass cover and the rear side film material. With a fiber reinforcement of the backsheet, the coefficient of thermal expansion of plastic can be reduced and approximated to the value of glass. Thus, a fiber reinforced backsheet construction has less residual stress and less tendency to warp. In addition, the use of the lamination process in the lamination process can be improved. By Faserverstär kung further a flame retardancy of the entire photovoltaic element, in particular the backsheet material, can be achieved, whereby this does not contribute in case of fire in addition to the fire spread. Flammhemmen-de films in photovoltaic modules usually consist of PVF, which has the disadvantage that it comes through the fluorine in the plastic in case of fire to form toxic halogen compounds.
    In turn, the embedding foil material prevents the formation of cleavage products from the polymer during use of the photovoltaic element. It can thus be simplified or improved the construction of the entire photovoltaic element by no longer has to be taken to the outdiffusion of these gap products RCicksicht, so that the Photovoltai-kelement can be made gas-tight overall. In addition, this also simplifies the lamination process itself. By using a physically crosslinked plastic, the lamination time can be reduced since no chemical crosslinking reaction is necessary.
    According to an embodiment variant of the photovoltaic element, it can be provided that the composite foil of the rear side foil material has at least one first, outer plastic layer and at least one second, inner plastic layer, the second, inner plastic layer being less stabilized than the first, outer plastic layer. The advantage here is that the higher stabilized plastic layer, i. the weather-stabilized, outer, first plastic layer with a lower layer thickness can be used on the overall composite, whereby corresponding cost advantages can be realized. The comparatively less stabilized second plastic layer is made thicker than the first plastic layer and ensures the electrical insulation.
    It may further be provided that the composite foil of the rear side foil material contains at least one barrier layer. It is thus possible to better protect the photovoltaic element from the effects of the weather, in particular water vapor entry. Water vapor can lead to fogging of the inside of the glass pane and thus to a reduction of the efficiency up to the failure of the electronics. This embodiment of the photovoltaic element is particularly advantageous in conjunction with the physically crosslinked plastic of the embedding foil material, since this eliminates the need to remove fission products from the embedding material to the outside from the photovoltaic element. There is thus no need to compromise on the barrier properties and permeability of the backsheet material. In addition, the aging behavior of the photovoltaic element can be improved.
    According to a preferred embodiment, it can be provided that the barrier layer is formed by at least one metal foil, in particular an aluminum foil. Thus, not only can the primary barrier function be made available, but in addition the reflection behavior of the backside film material can be improved, so that more sunlight that has passed through the embedding-film material layers is reflected toward the photovoltaic cells, thereby reducing the energy yield of the photovoltaic element can be improved. In addition, by using a metal foil, an improved thermal conductivity of the backsheet material can be achieved, whereby hotspots can be better prevented during operation of the photovoltaic element.
    For the reasons mentioned for the embedding foil material, it is advantageous if the composite foil of the reverse side foil material has a layer of a physically crosslinked plastic.
    The physically crosslinked plastic of the encapsulant material and / or the physical crosslinked plastic of the backsheet material may be an ionomer. It can thus the optical properties, such as refractive index and transmittance, compared to the ethylene-vinyl acetate copolymer films used in the prior art over the entire life of the Photovoltai-kelementes be increased.
    Preferably, the ionomer is a zinc ionomer based on ethylene / methacrylic acid copolymer. Compared to other ionomers, the adhesion to glass surfaces or polyamide can be improved. On the other hand, this ionomer also has good flow properties, high impact strength and low moisture absorption.
    It can further be provided that in each case the individual layers of the embedding film material and / or of the reverse side foil material are joined together with an adhesive, whereby a high temperature resistance and a durable, high adhesion and a good aging behavior of the embedding foil material and / or the backsheet material are achieved can.
    For better adaptation of the thermal expansion behavior of the RCickseitenfolienmaterials to that of the glass cover on the front can be provided that the fiber reinforcement is at least 80 wt .-% of glass fibers be.
    In addition, it can be provided that the fiber reinforcement is formed by a fabric, whereby a further improvement of the mechanical behavior of the RCick side film material can likewise be achieved.
    The fiber reinforcement layer may have a basis weight of between 100 gsm and 250 gsm. It can thus be formed a nearly closed-layer.
    For a better understanding of the invention, this will be explained in more detail with reference to the following figures.
    Each shows in a simplified, schematic representation:
    1 shows a detail of a photovoltaic element in cross section;
    FIG. 2 shows the dependence of the refractive index on the temperature of embedding film materials; FIG.
    Fig. 3 shows the transmission spectrum of embedding film materials;
    4 shows the reflection spectrum of embedding film materials;
    Fig. 5 shows the aging behavior of the embedding film material;
    Fig. 6 shows the aging behavior of the backsheet material;
    7 shows the stress-strain curve of various backsheet materials;
    Fig. 8 shows the shrinkage behavior of various backsheet materials.
    By way of introduction, it should be noted that in the embodiments described differently, identical parts are provided with the same reference numerals or the same component designations, wherein the disclosures contained throughout the description can be applied mutatis mutandis to the same parts with the same reference numerals or component names , Also, the location information chosen in the description, such as top, bottom, side, etc. related to the immediately described and illustrated figure and these position information in a change in position mutatis mutandis to transfer to the new location.
    In Fig. 1 is a section of a photovoltaic element 1 in cross-section Darge represents. This photovoltaic element 1 comprises an upper cover element 2, an embedding element 3 arranged underneath and connected to the upper cover element 2, in which a plurality of photovoltaic elements 4 are embedded, and a rear side film material 5 which is connected to the embedding element 3 connected and located below this. Edged, this layer structure can be formed by a frame 6, which is preferably arranged so as to overlap the upper cover element 2 and the back side foil material 3.
    The embedding element 3 comprises at least one upper embedding foil material 7 and at least one lower embedding foil material 8 or consists of the upper and the lower embedding foil material 7, 8.
    The photovoltaic cells 4 and their electrical contacting or wiring, not shown in FIG. 1, are arranged or embedded between the upper and lower embedding foil material 7, 8. For further details on the photovoltaic cells 4, reference is made to the relevant prior art.
    According to a first preferred embodiment variant of the photovoltaic element 1, the rear side film material 5 is formed by a composite film which comprises at least one plastic layer 9 and at least one fiber reinforcement 10.
    In this embodiment, the two Einbettfolienmaterialien 7,8 also consist of the prior art corresponding plastics.
    According to a further embodiment of the photovoltaic element 1, which may be independent of itself, it is provided that at least one of the two embedding film materials 7, 8, preferably both the upper and the lower embedding film material 7, 8, comprises a physically crosslinked plastic, in particular, consists of this. In this case, the two Einbettfolienmaterialien 7, 8 consist of the same plastic. It is also conceivable that these consist of different plastics. In this embodiment, the RCick side sheet material 5 may be formed according to the prior art.
    According to another, possibly independent, preferred variant of the embodiment of the photovoltaic element 1, it is provided that the rear side film material 5 is formed by the composite film comprising the at least one plastic layer 9 and the at least one fiber reinforcement 10, and that at least one of the both Einbettfolienmaterialien 7, 8, preferably both the upper and the lower embedding film material 7, 8, a physically crosslinked plastic, in particular consists of this.
    The fiber reinforcement 10 is preferably formed as a separate layer, which is between the rule of the plastic layer 9 and the lower Einbettfolienmaterial 8 ange-arranged. If cavities are formed in the fiber reinforcement layer, they may also be at least partially filled with the plastic of the plastic layer 9 and / or of the lower embedding film material 8.
    The fiber reinforcement 10 may be formed of fibers and / or filaments selected from a group consisting of or consisting of glass fibers, ara-mid fibers, carbon fibers, mineral fibers such as basalt fibers, turf fibers such as e.g. Hemp, sisal, and combinations thereof.
    Preferably, glass fibers are used as a fiber reinforcement layer. The proportion of the glass fibers on the fiber reinforcement 10 may be at least 80% by weight, in particular at least 90% by weight. The fibers and / or threads of the fiber reinforcement 10 preferably consist exclusively of glass fibers.
    The fibers and / or threads may be present in the fiber reinforcement 10 as a scrim, for example as a nonwoven. However, preference is given to a woven fabric or a knitted fabric made from the fibers and / or threads. It is also possible that the fabric or knitted fabric is only partially present and the remaining areas of the Fa-server reinforcement 10 are formed by a scrim.
    When using a fabric different types of bonding, especially linen, twill or satin weave, possible. Preferably, a plain weave is used.
    The basis weight of the fiber reinforcement 10 may be between 10 g / m2 and 1000 g / m2. For the above reasons it is preferred to use a fiber reinforcement 10 having a basis weight of between 100 g / m 2 and 250 g / m 2.
    It is thus possible to produce a closed layer which makes possible a uniform material connection with the plastic of the embedding film material 7, 8. In addition, properties of the composite film, such as thermal expansion or creep, can be influenced. The stiffness of the fiber reinforcement 10 is, for example, at the third power of its thickness, i. their areal weight, into the overall film composite stiffness.
    But it is also possible to use an open-mesh glass fabric or glass scratches with a surface wiped between 10 g / m2 to 90 g / m2.
    The fiber reinforcement 10 may be formed as a single layer. But it is also possible that the fiber reinforcement 10 has a plurality, optionally separated from each other, individual layers, for example, two or three, wherein at least some of the plurality of individual layers at least partially, preferably entirely, also from the rest of the individual layers of different fibers and / or Threads can exist.
    The plastic layer 9 may consist, for example, of at least 80% by weight, in particular at least 90% by weight, preferably 100% by weight, of a synthetic material selected from the group consisting of or consisting of polyolefins, Plastics based on, for example, polyesters or polyamides.
    It should be noted at this point that a plastic is understood to mean a synthetic or natural polymer made from corresponding monomers.
    In addition to the fiber reinforcement 10 and the (first) plastic layer 9, the composite film of the back side film material 5 can have at least one second plastic layer 11, the second plastic layer being less or not stabilized. In this case - based on the installation position - the less or unstabilized second plastic layer 11 in particular directly above the (higher) stabilized first plastic layer 9 is arranged. The less or unstabilized second plastic layer 11 is thus not directly exposed to the ventilation. Preferably, the less or unstabilized second plastic layer 11 has a higher layer thickness than the first plastic layer 9.
    The plastic layer 11 may consist, for example, of at least 80% by weight, in particular at least 90% by weight, preferably 100% by weight, of a synthetic material selected from the group consisting of or consisting of polyolefins, Plastics based on, for example, polyesters or polyamides.
    In general, the backsheet material can consist of several individual layers, which are connected to one another via adhesives. For this purpose, on the one hand, 2 component adhesive systems based on polyurethane or also hot-adhesive systems are suitable. In addition to adhesives, coextrusion and extrusion coating can also be used as connection options. Of course, a combination is also possible that several plastics are co-extruded and are adhesive-laminated together with an extrusion-coated metal or fiber reinforcement layer.
    It should already be mentioned at this point that the individual layers of the embedding element 3 can also be connected to one another via the aforementioned connection methods.
    According to a further embodiment, it can be provided that the composite film of the backsheet material 5 contains at least one barrier layer 12, as shown in broken lines in FIG. This barrier layer 12 may be formed in particular by at least one meta-foil, in particular an aluminum foil. But there are also other barrier layer materials, such as copper, possible.
    The barrier layer 12 is preferably arranged between the fiber reinforcement 10 and the plastic view 9, but may also be arranged below the first plastic layer 9 or the second plastic layer 11 or between the first and the second plastic layer 9, 11. Optionally, a plurality of barrier layers 12 may be provided or arranged in the backsheet material 5. These multiple barrier layers 12 may in particular be arranged spaced apart in backsheet material 5.
    The barrier layer (s) 12 forms, in particular, a barrier against water vapor penetrating into the photovoltaic element 1 from the outside.
    As already stated above, the photovoltaic element 1 has an embedding element 3 with the two embedding film materials 7, 8. The two Einbettfoli-enmaterialien 7, 8 may be constructed single or multi-layered, wherein the depending Weil single-layered design of the Einbettfolienmaterials 7 and the Einbettfoli-enmaterials 8 is preferred.
    Preferably, at least one of the two Einbettfolienmaterialien 7, 8, preferably both, made of a physically crosslinked plastic. It is therefore added to this no chemical crosslinking agent, so that the finished plastic in the photovoltaic element 1 is also free of such chemical crosslinking agents or fission products thereof.
    The physical crosslinking preferably takes place via ionic bonds in the ionomer, Zn 2+ acting as cation and the carboxyl group of the main chain as anion.
    According to a further embodiment variant of the photovoltaic element 1, the rear side film material 5 can also have at least one layer of a physically crosslinked plastic, for example the plastic layer 9 and / or the second plastic layer 11.
    As the physically crosslinked plastic, for example, ionomers, vinyl copolymers, e.g. Polyvinyl butyral or thermoplastic elastomers are used.
    In the preferred embodiment, this physically crosslinked synthetic of the encapsulant sheet material 7 and / or 8 and / or the backsheet material is an ionomer. The embedding film material 7 and / or 8 and / or the Rücksei tenfolienmaterial 5 may consist of at least 80 wt .-%, in particular at least 90 wt .-%, preferably exclusively from the ionomer. It is also possible that the photovoltaic element 1 has more than one layer of an ionomer. For example, the upper embedding film material 7 may be made of a different ionomer than the lower embedding film material 8.
    The ionomer of the encapsulant sheet material 7 and / or 8 and / or the backsheet material 5 may be selected from a group consisting of ionomeric (co) polymers of ethylene and an α, β-unsaturated carboxylic acid or a carboxylic acid anhydride of this carboxylic acid , in particular (co) polymers of ethylene and methacrylic acid.
    Preferably, the ionomer contains carboxylic acid groups which are at least partially neutralized with metal ions selected from the group of sodium, potassium, calcium, magnesium, zinc.
    The ionomer is particularly preferably a zinc ionomer based on ethylene / methacrylic acid copolymer, which is prepared by copolymerization of ethylene with polar acrylic monomers. Compared to other ionomers, the adhesion to glass surfaces or polyamide can be improved. On the other hand, this ionomer also has good flow properties, high impact strength and low moisture absorption.
    It should be noted, however, that in principle it is also possible to use polymers which can be softened by appropriate excitation and crosslink three-dimensionally by heating or after subsequent cooling.
    Preferably, such polymers, the excitation by thermal excitation is possible, since then the pyschsikalische cross-linking can better integrate into the lamination process for the production of the photovoltaic element 1, in particular no additional processing step for the production of the cross-linked plastic is required.
    With regard to the lamination process per se, reference is made to the relevant prior art.
    A possible layer structure for the photovoltaic element 1 is on the outer side (plastic layer 11) made of PET (polyethylene terephthalate), which is optionally equipped with titanium dioxide for better weather resistance and for reflection from the outside. Furthermore, this layer can also be prepared with flame retardants for better flame retardance. In addition to PET, this layer can also consist of fluoropolymers, polyamides or polyolefins. On this and in the direction of the photovoltaic cells 4, a second PET layer (plastic layer 11) for insulation and without or with less stabilization is arranged directly with an adhesive layer or else via coextrusion.
    Another layer bonded via adhesive or extrusion coating is a metal foil layer (barrier layer 12), in particular an aluminum foil layer for better barrier of the foil and for reflection of solar radiation possibly passing next to the photovoltaic cells 4 back to the photovoltaic cells 4 in order to also use this energy. The metal foil layer can also be omitted.
    As the next layer, the fiber reinforcement layer is introduced either on the metal foil or on the PET with adhesive or via extrusion coating. Optionally, the inward termination may be an additional adhesive or extrusion coated, ionomer, EVA, polyvinyl butyral or polyolefin layer which acts as a potting material for the cells.
    An additional fiber fabric can also be introduced between the two PET, or a PET and a PVF layers.
    Thereby, a rigid film structure is created, which is preferably used as Rückseitenfo-lienmaterial 5 in photovoltaic elements 1. Due to the improved thermo-mechanical properties of the backsheet material 5 and the improved barrier performance, the backsheet material 5 can also be used as a backsheet for flexible photovoltaic elements 5. In particular, an improvement of the lamination behavior or the laminate quality can be achieved.
    According to one embodiment variant, the rear side film material 5 may already be equipped with the lower embedding film material 8. This simplifies the assembly process, since in the (lamination) process for the production of the photovoltaic element, one less layer has to be applied and thus the assembly time as well as the possibility of error can be reduced.
    For the evaluation of the materials, various tests were carried out and compared with the state of the technology materials used in such photovoltaic elements 1.
    Thus, in Fig. 2, the refractive index nD (ordinate) of an embedding foil material 7, 8 of an ethylene / methacrylic acid copolymer-based zinc ionomer (upper curve) is compared with EVA (lower curve) as a function of the temperature (abscissa, [° C]). The measurement was carried out at a wavelength of 589.3 nm and temperatures of 10 ° C to 70 ° C.
    As can be seen from this FIG. 2, with respect to solar glass, which has a refractive index of about 1.49 at room temperature, EVA has a lower refractive index over the temperature range under consideration. The embedded film material 7, 8 made of the zinc ionomer, on the other hand, has a significantly higher refractive index than solar glass. This has a favorable effect with regard to the above-mentioned back reflection.
    FIGS. 3 and 4 show the transmission spectrum or reflection spectrum of the embedding film material 7, 8 (wavelength plotted on the abscissa) from this ionomer. The measurement was carried out by means of UV-VIS-NIR spectrometer with 150 mm Ulbricht sphere. Directed hemispherical transmission (T) and reflectance (R) were recorded in the wavelength range from 250 nm to 2500 nm. The spectra were weighted with the terrestrial solar spectrum AM1.5 in the integration range from 400 nm to 1100 nm.
    In the relevant wavelength range from 400 nm to 1100 nm for photovoltaic elements 1, the ionomer (upper curve in FIG. 3 and lower curve in FIG. 4) has a light transmission T of approximately 90.9% and a light reflection R of approximately 8.7 %, whereas EVA (lower curve in Fig. 3 and upper curve in Fig. 4) has a light transmission T of about 85.8% and a light reflection R of about 12.4%. The light absorption (= 1-T.-R) of the ionomer is thus only 0.4% while that of EVA is 1.8%.
    To determine the aging behavior, an embedded film material 7 of the ionomer was exposed to UV radiation (Q-Sun Xe-1) (ISO 4892-2: 2013).
    The correspondingly measured values are reproduced in FIG. The abscissa is the time in hours in which the Einbettfolienmaterial 7 was exposed to UV irradiation, while on the ordinate in the lower part of the image Yl (Yl = Yellowness Index according to ASTM D1925-70: 1988) and im upper part of the picture T in percent (transmittance) are shown.
    As can be seen from FIG. 5, the transmission behavior of the embedding film material 7 barely decreases over the service life.
    In Fig. 6, the corresponding values for the back sheet material 5 are shown. A glass fabric / aluminum / PET hybrid film was used as the backsheet material 5. The Yellowness Index (YI) according to ASTM D1925-70 and the elongation at break according to ISO 527 were measured. The abscissa of FIG. 6 again shows the time in hours in which the backside film material was exposed to the UV radiation. The ordinate shows the elongation at break ε in percent in the lower part of the picture and the yellowness index in the upper part of the figure
    Finally, in FIGS. 7 and 8, the elongation behavior (in FIG. 7 abscissa in percent) of the backsheet material 5 under tension (in FIG. 7, oridinate [MPa]) and its shrinkage behavior (ordinate in FIG. 8: shrinkage in the longitudinal direction Abscissa in Fig. 8: transverse shrinkage, each in percent). The measurement was carried out according to ISO 527 and the shrinkage was assessed after two hours at 150 ° C. on the basis of 100 × 100 mm 2 film samples.
    Here, FIG. 7 shows the stress-strain behavior of the ionomer (top line) in comparison to I COSOLAR® 2442 (middle line) and ICOSOLAR®AAA 3554 (lowest line). It can be clearly seen that the back sheet material 5 according to the invention can absorb higher voltages than conventional materials used in photovoltaic elements 1 for this purpose.
    It is again evident from FIG. 8 that the back sheet material 5 according to the invention (point with the coordinates [0, 0]) has no (substantial) shrinkage in the transverse or longitudinal direction in comparison with conventionally used materials (hatched area) , The negligible shrinkage compared to commonly used plastic backsheets characterizes the backsheet material 5 according to the invention. This results in clear advantages in terms of handling and lamination of the PV modules.
    The exemplary embodiments show or describe possible variant embodiments of the photovoltaic element 1, it being noted at this point that various combinations of the individual embodiment variants are also possible with one another.
    For the sake of order, it should finally be pointed out that, for a better understanding of the construction of the photovoltaic element 1, this or its constituent parts have been shown partly unevenly and / or enlarged and / or reduced in size.
    LIST OF REFERENCES 1 photovoltaic element 2 cover element 3 embedding element 4 photovoltaic cell 5 backfoil material 6 frame 7 embedding foil material 8 embedding foil material 9 plastic layer 10 fiber reinforcement 11 plastic layer 12 barrier layer
    权利要求:
    Claims (12)
    [1]
    claims
    A photovoltaic element (1) comprising an upper embedding film material (7) and a lower embedding film material (8), wherein between the upper and lower embedding film material (7, 8) photovoltaic cells (4) are embedded, and a back sheet material (5), which in Mounting position of the Photovoltaikelemen-tes (1) below the lower Einbettfolienmaterials (8) is arranged, characterized in that the rear side film material (5) is formed by a composite film comprising at least one plastic layer (9) and at least one fiber reinforcement (10) and / or that at least one of the two Einbettfoli-enmaterialien (7, 8) has a physically crosslinked plastic.
    [2]
    2. Photovoltaic element (1) according to claim 1, characterized in that the composite foil of the backsheet material (5) has at least a first, outlying plastic layer (9) and at least a second, inner plastic layer (11), wherein the second, inner plastic layer (11) is less stabilized than the first, outer plastic layer (9).
    [3]
    3. Photovoltaic element (1) according to claim 1 or 2, characterized in that the composite foil of the backsheet material (5) contains at least one barrier layer (12).
    [4]
    4. Photovoltaic element (1) according to claim 3, characterized in that the barrier layer (12) is formed by at least one metal foil, in particular an aluminum foil.
    [5]
    5. photovoltaic element (1) according to one of claims 1 to 4, characterized in that the composite film of the back sheet material (5) has a layer of a physically crosslinked plastic.
    [6]
    6. Photovoltaic element (1) according to one of claims 1 to 5, characterized in that the physically crosslinked plastic of the embedding film material (7, 8) is an ionomer.
    [7]
    7. photovoltaic element (1) according to claim 5 or 6, characterized in that the physically crosslinked plastic of the back sheet material (5) is an ionomer
    [8]
    8. Photovoltaic element (1) according to claim 6 or 7, characterized in that the ionomer is a zinc ionomer based on ethylene / methacrylic acid copolymer.
    [9]
    9. photovoltaic element (1) according to one of Anspriiche 1 to 8, characterized in that in each case the individual layers of the Einbettfolienmaterials (7, 8) and / or the backsheet material (5) are interconnected with an adhesive.
    [10]
    10. Photovoltaic element (1) according to one of claims 1 to 9, characterized in that the fiber reinforcement (10) consists of at least 80% by weight of glass fibers.
    [11]
    11. Photovoltaic element (1) according to one of Anspriiche 1 to 10, characterized in that the fiber reinforcement (10) is formed by a fabric.
    [12]
    12. Photovoltaic element (1) according to any one of claims 1 to 11, characterized in that one of the fiber reinforcement (10) existing layer has a basis weight between 100 g / m2 and 250 g / m2.
    类似技术:
    公开号 | 公开日 | 专利标题
    DE69731799T2|2005-12-01|solar cell module
    DE69819157T2|2004-07-08|ENCLOSURE MATERIAL FOR SOLAR CELL MODULE AND COMPOSITE GLASS
    EP2422976B1|2017-03-08|Photovoltaic multi-layer backsheet, manufacture of same and use of same in the production of photovoltaic modules
    DE69634289T2|2005-12-22|Manufacturing method of a semiconductor device
    EP2442977B1|2017-11-29|Laminated glazing and its use
    AT509091B1|2011-09-15|SOLAR PANEL
    DE102007055733A1|2009-06-10|Photovoltaic modules with reflective adhesive films
    DE112009001575T5|2011-05-05|Layer film for a solar cell and solar cell module with such a
    ES2531104T9|2015-05-22|Photovoltaic modules with polypropylene based backing sheet
    EP2855146A1|2015-04-08|Sunroof comprising an integrated photovoltaic module
    EP1018166A1|2000-07-12|Photovoltaic module and method for producing same
    EP3298631B1|2020-03-04|Photovoltaic element
    DE212012000175U1|2014-05-22|Flexible photovoltaic panels
    EP1102282A1|2001-05-23|Electrical cable
    EP2530742B1|2018-10-17|Solar cell module
    KR101954164B1|2019-03-05|Back sheet for solar cells
    EP3796398A1|2021-03-24|Photovoltaic element
    EP3690960A1|2020-08-05|Solar cell system
    EP2462628B1|2013-05-29|Method for manufacturing photovoltaic modules
    EP3796397A1|2021-03-24|Photovoltaic element
    EP3265509B1|2019-06-19|Back sheet for solar cell
    DE202016008420U1|2017-11-16|laminated pane
    DE102017007676A1|2018-02-22|Multilayer film and photovoltaic module
    EP3690961A1|2020-08-05|Laminated structure and solar power generation system
    DE202011003896U1|2012-06-12|Glass pane arrangement with building-integrated photovoltaic module
    同族专利:
    公开号 | 公开日
    EP3298631A1|2018-03-28|
    WO2016183604A1|2016-11-24|
    AT517402B1|2020-04-15|
    ES2796499T3|2020-11-27|
    EP3298631B1|2020-03-04|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    DE102009014348A1|2008-06-12|2009-12-17|Bayer Materialscience Ag|Lightweight, rigid and self-supporting solar module and a method for its production|
    DE102008062286A1|2008-12-03|2010-06-10|P-D Industriegesellschaft mbH Betriebsstätte: Werk Bitterfeld-Laminate|Solar module has covering layer made of transparent material, photovoltaic layer and base layer made of fiber reinforced material, where base layer of fiber reinforced material, is made of hard glass laminate|
    EP2680317A1|2011-02-23|2014-01-01|Mitsubishi Rayon Co., Ltd.|Solar cell module|
    KR20130062539A|2011-12-05|2013-06-13|도레이첨단소재 주식회사|Back sheet for a solar cell having an excellent heat releasing property and the preparing process thereof|
    WO2013119113A1|2012-02-06|2013-08-15|Universiteit Twente|Encapsulated photovoltaic module|
    WO2014088102A1|2012-12-07|2014-06-12|中興化成工業株式会社|Solar cell integrated film material|
    WO2014154609A1|2013-03-26|2014-10-02|Jiangsu Solarflex Technical Composites Limited|Multi-layer sheet for the back face of a solar module|
    CN104393082A|2014-11-14|2015-03-04|无锡中洁能源技术有限公司|Insulating solar panel back film and preparation method thereof|
    US4636578A|1985-04-11|1987-01-13|Atlantic Richfield Company|Photocell assembly|
    US6114046A|1997-07-24|2000-09-05|Evergreen Solar, Inc.|Encapsulant material for solar cell module and laminated glass applications|
    US20080041442A1|2006-06-21|2008-02-21|Hanoka Jack I|Frameless Photovoltaic Module|
    US8609980B2|2010-07-30|2013-12-17|E I Du Pont De Nemours And Company|Cross-linkable ionomeric encapsulants for photovoltaic cells|
    KR20120132980A|2011-05-30|2012-12-10|엘지전자 주식회사|Solar cell module|
    KR101307425B1|2012-01-13|2013-09-11|도레이첨단소재 주식회사|Low shrinkable encapsulant sheet for solar cell module and solar cell module using the same|
    EP2822043B1|2012-02-29|2016-06-29|Mitsui Chemicals Tohcello, Inc.|Sheet set for solar cell sealing|
    HUE029702T2|2013-10-17|2017-03-28|Das Energy Gmbh|Photovoltaic panel and method for its production|AT522994A1|2019-09-18|2021-04-15|Lenzing Plastics Gmbh & Co Kg|Photovoltaic element|
    AT522993A1|2019-09-18|2021-04-15|Lenzing Plastics Gmbh & Co Kg|Photovoltaic element|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    ATA320/2015A|AT517402B1|2015-05-20|2015-05-20|Photovoltaic element|ATA320/2015A| AT517402B1|2015-05-20|2015-05-20|Photovoltaic element|
    PCT/AT2016/050146| WO2016183604A1|2015-05-20|2016-05-18|Photovoltaic element|
    ES16729749T| ES2796499T3|2015-05-20|2016-05-18|Photovoltaic element|
    EP16729749.8A| EP3298631B1|2015-05-20|2016-05-18|Photovoltaic element|
    [返回顶部]