![]() DEVICE FOR PREPARING PLASTIC MATERIAL
专利摘要:
The invention relates to a device for pretreating and subsequently conveying or plasticizing plastics with a container (1) having a mixing and / or comminution tool (3) rotatable about an axis of rotation (10), wherein an opening (8) is provided in a side wall (9) ) is formed, through which the plastic material can be carried out, wherein a conveyor (5) is provided, with a in a housing (16) rotating screw (6). The invention is characterized in that the imaginary extension of the longitudinal axis (15) of the conveyor (5) against the conveying direction (17) on the axis of rotation (10) passes, wherein the longitudinal axis (15) on the outlet side to the longitudinal axis (15) parallel radials (11) is offset by a distance (18) and that the L / D ratio of the screw (6) is> 7 and that the angle of attack (y) of the radially outermost mixing and / or crushing tool (3) is the following Relationship met: y = k * d + Kwobeid ... the diameter of the screw (6) in mmK ... a factor in the range of 15 to 35, k ... a factor in the range of 0.08 to 0.2 , 公开号:AT512148A1 申请号:T1503/2011 申请日:2011-10-14 公开日:2013-05-15 发明作者: 申请人:Erema; IPC主号:
专利说明:
......... * 1 * 64 * 01/5/5 Device for processing plastic material! The invention relates to a device according to the preamble of claim 1. Numerous similar devices of various types are known in the prior art, comprising a receptacle or cutting compactor for comminuting, heating, softening and processing a plastic material to be recycled and a conveyor or extruder connected thereto for melting the material prepared in this way. The aim is to obtain a high quality end product, usually in the form of granules. Thus, for example, in EP 123 771 or EP 303 929 devices are described with a receptacle and an extruder connected thereto, wherein the plastic material supplied to the receptacle crushed by rotating the crushing and mixing tools and brought into thrombus circulation and heated simultaneously by the introduced energy , This forms a mixture with sufficiently good thermal homogeneity. This mixture is discharged after appropriate residence time from the receptacle in the screw extruder, promoted and thereby plasticized or melted. The screw extruder is arranged approximately at the height of the crushing tools. In this way, the softened plastic particles are actively pressed or stuffed by the mixing tools into the extruder. However, most of these long-known constructions are not satisfactory in view of the quality of the machined plastic material obtained at the outlet of the screw and / or with regard to the output or throughput of the screw. Of crucial importance for the final quality of the product is, on the one hand, the quality of the pretreated or softened polymer material reaching the conveyor or extruder from the cutter compactor, and, on the other hand, the situation during feeding and conveying or the possible extrusion. Here, inter alia, the length of the individual regions or zones of the screw, as well as the parameters of the screw, e.g. whose thickness, flight depths etc. are relevant. Thus, in the present high speed compressor-conveyor combinations, there are special conditions, since the material entering the conveyor is not introduced directly, untreated and cold, but has already been pretreated in the cutting compressor, i. heated, softened and / or partially crystallized, * etc. has been! (This is crucial for the collection and the quality of the material. The two systems, ie the cutter compactor and the conveyor, influence each other, and the results of the feeding and the further conveying or possible densification depend strongly on the pretreatment and the consistency of the material. An important area is therefore the interface between the cutting compressor and the conveyor, ie the area in which the homogenized pretreated material is transferred from the cutting compressor into the conveyor or extruder. On the one hand, this is a purely mechanical problem because two differently operating devices must be coupled together here. In addition, this interface is also delicate for the polymer material, since the material is usually present in a strongly softened state near the melting region, but must not melt. If the temperature is too low, the throughput and the quality will decrease, the temperature will be too high and in some places an unwanted Aufschmeizung instead, so clogged the feeder. In addition, an accurate metering and feeding of the conveyor is difficult because it is a closed system and no direct access to the feeder, but the feeding of the material from the cutting compressor out, so not directly, for example via a gravi metric dosing influenced can be. It is therefore crucial to make this transition both mechanically considered, so with understanding of the polymer properties, and at the same time to pay attention to the economics of the overall process, so on high throughput and appropriate quality. Here are partly conflicting requirements to consider. The above-mentioned, known from the prior art devices have in common that the conveying or rotating direction of the mixing and crushing tools and thus the direction in which the material particles circulate in the receptacle, and the conveying direction of the extruder substantially equal or in the same direction are. This deliberately chosen arrangement was guided by the desire to stuff the material as possible in the snail or force feeding it. This idea, the particles in Schneckenförderrichtung in the conveyor or. To stuff extruder screw, was also quite obvious and corresponded to the common ideas of the expert, since the particles do not have to reverse their direction of movement and thus no additional force is needed for the reversal of direction. It was doing and at outgoing Further developments have always been aimed at creating the highest possible auger filling and strengthening this stuffing effect. For example, attempts have also been made to conically expand the collection area of the extruder or to curve the comminution tools in a sickle shape so that they can feed the softened material into the screw in a spatula-like manner. Due to the inflow-side displacement of the extruder from a radial to a tangential position to the container, the stuffing effect was further enhanced and the plastic material from the rotating tool even more pressed or pressed into the extruder. Such devices are basically functional and work satisfactorily, albeit with recurrent problems: Thus, for example, with materials having a low energy content, e.g. PET fibers or sheets, or materials having an early tack or softening point, such as e.g. Polylactic acid (PLA), observed over and over again the effect that the conscious same-sense plugging of the plastic material in the intake area of the extruder under pressure leads to premature melting of the material immediately after or in the intake area of the extruder. As a result, on the one hand, the effect of the extruder reduces, and it can also lead to a partial reflux of this melt in the area of the cutting compressor or receiving container, which means that still unmelted flakes adhere to the melt, thereby cooling the melt again and partially solidifies and forms in this way a schwulstartiges structure or conglomerate of partially solidified melt and solid plastic particles. As a result, the intake of the extruder clogged and stick the mixing and crushing tools. As a result, the throughput of the extruder is reduced because there is no longer sufficient filling of the screw. In addition, the mixing and comminution tools can get stuck. As a rule, in such cases, the system must be shut down and completely cleaned. Additionally, problems arise with those polymeric materials that have been heated in the cutter compactor to near their melting range. If the catchment area is overfilled, the material melts and the feeder sinks. Even with, mostly stretched, stripy, fibrous materials with a certain length extension and a small thickness or stiffness, so for example in cut into strips of plastic films, problems arise. This primarily by the fact that the elongated material adheres to the downstream end of the feed opening of the screw, wherein one end of the strip protrudes into the receptacle and the other end in the catchment area. Since both the mixing tools and the screw run in the same direction or exert the same Förderrichtungs- and pressure component on the material, both ends of the strip in the same direction * zug- and pressurized and the strip can not solve. This in turn leads to an accumulation of the material in this area, to a narrowing of the cross section of the intake opening and to a poor intake behavior and subsequently to loss of revenue. In addition, the increased feed pressure in this area may lead to melting, which in turn causes the problems mentioned in the introduction. At such co-rotating cutter compressors different extruder or conveyor were connected, the results were basically quite acceptable and appealing. However, the Applicant has made extensive research to further improve the overall system. The present invention has set itself the task of overcoming the disadvantages mentioned and to improve a device of the type described above, that, in addition to the usual materials, even sensitive or strip-like materials easily recovered from the screw and with high material quality, energy-saving and with high and constant throughput can be processed or treated. This object is achieved in a device of the type mentioned by the characterizing features of claim 1. It is initially provided that the imaginary extension of the central longitudinal axis of the conveyor, in particular extruder, if this has only a single screw, or the longitudinal axis of the feed opening nearest screw when it has more than one screw, against the conveying direction of the conveyor on the Rotary axis passes without cutting them, wherein the longitudinal axis of the conveyor, if this has a single screw, or the longitudinal axis of the intake nearest worm downstream in the direction of rotation of the tools to the longitudinal axis parallel, from the axis of rotation of the mixing and / or crushing tool in Conveying direction of the conveyor outwardly directed radials of the container is offset by a distance. Thus, the conveying direction of the mixing tools and the conveying direction of the conveyor is no longer, as known from the prior art, in the same direction, but at least slightly in opposite directions, whereby the initially mentioned Stopfeffekt is reduced. Due to the deliberate reversal of the direction of rotation of the mixing and crushing tools compared to previously known devices, takes the Loading pressure on the catchment area decreases and the risk of overfilling is reduced. Excess material is not stuffed or filled in this way with excessive pressure in the catchment area of the conveyor, but on the contrary excess material is even tending to be removed from there, so that while there is always sufficient material in the catchment area, but almost no pressure or only a small amount Pressure is applied. In this way, the screw can be filled sufficiently and always enough material to move in without causing it to overfill the screw and subsequently to local pressure peaks, where the material could melt. In this way, the melting of the material in the area of the feeder is prevented, which increases the operational efficiency, lengthens the maintenance intervals and reduces the downtime due to possible repairs and cleaning measures. By reducing the feed pressure react slider, with which the degree of filling of the screw can be regulated in a known manner, much more sensitive and the degree of filling of the screw can be adjusted even more accurately. Especially for heavier materials, such as high-density polyethylene (HDPE) or PET regrind, it is easier to find the optimum operating point of the system. In addition, it has proved to be surprisingly advantageous that materials which have already been softened to near melt, are better fed in the counter-rotating operation according to the invention. In particular, when the material is already in doughy or softened state, the screw cuts the material from the doughy ring, which is close to the container wall. In a direction of rotation in the conveying direction of the screw, this ring would rather be pushed further and there could be no scraping by the screw, whereby the indentation would ease. This is avoided by reversing the direction of rotation according to the invention. In addition, in the processing of the above-described streaky or fibrous materials, the formed impurities or accumulations are easily solved or are not even formed because of the direction of rotation of the mixing tools downstream or downstream edge of the opening of the direction vector of the mixing tools and the directional vector of the conveyor in almost opposite or at least slightly opposite directions show, making an elongated strip can not bend and impose around this edge, but is carried along by the Mischtrombe in the receptacle again. Overall, improved by the inventive design * the intake behavior and increases the throughput significantly. The overall system of cutter compactor and conveyor is thus more stable and efficient. Furthermore, the Applicant has found that surprisingly advantageous effects can be achieved by a particular embodiment of the mixing and crushing tools, which have a direct influence on the intake behavior of the conveyor or extruder. Thus, according to the invention, it is further provided that the angle of incidence γ of the leading edge of the radially outermost mixing and / or comminution tool or of the radially outermost tool and / or knife satisfies the relation γ - k * d + K, where d ... the mean Diameter of the screw in the area of the intake opening in mm K ... a factor in the range of 15 to 35, k ... a factor in the range of 0.08 to 0.2. The angle of attack γ is measured in the radially outermost point of the ground nearest mixing and / or crushing tool or the tool and / or knife and that is the angle between the extension of, in particular straight, leading edge and extending through this outermost point radials of the container. In this context, the L / D ratio is in any case greater than or equal to 7, preferably greater than or equal to 10 or even greater, preferably greater than 15. The diameter of the screw is the mean diameter in the region downstream of the intake opening. The circulating in the container tools have on the material both a stuffing into the screw effect and a mixing effect, which circulates and mixes the material in the container. If knives are present, they also have a cutting or crushing effect. This means that the smaller the screw is, the smaller the angle of attack relative to the radial. The smaller the angle of attack, the more the material to be treated is driven around in the cutter compactor and the less it is stuffed into the screw. The larger the angle of attack, the more clogging the tools or knives, thus keeping the material less long in the cutter compactor and the particles are cut less often. The smaller the screw is, the smaller the particles must be, with the already compacted and softened particles behaving fluidly in the region of the intake. This means that the material needs to be re-circulated, which causes the material to be more heavily loaded by the tools and cut by the blades, and consequently the particles become smaller. The tools of systems with smaller screws are therefore more demanding and must be equipped accordingly with a smaller angle of attack. The larger the screw, the more the tool can be stuffing, i. the larger the angle of attack can be, since a larger screw can tolerate larger particles or can attract and process larger particles. The given relationship has found an optimum between cutters and plugs for this particular system. It has surprisingly been found in this context that, due to the caused due to the opposite direction of rotation of the mixing tools gentle stuffing behavior, more aggressive tools can be used in the cutting compressor, which bring more energy into the material. The cutter compactor can therefore be operated at a higher temperature, which in turn has a better homogeneity with reduced residence time result. According to the invention, a particularly good and effective energy input by the particular angle of the tools in combination with their reverse direction of rotation of the tools. In addition, such a combination of a cutting compressor with such hired tools and corresponding direction of rotation and a connected extruder unexpectedly an improved melting performance of the material in the extruder result, since already get well-preheated particles in the screw. As a result, prone inhomogeneities are compensated for and the material entering the worm housing from the container and subsequently compressed and melted has high thermal and mechanical homogeneity. Accordingly, the final quality of the plasticizer or agglomerate at the end of the extruder or Agglomerierschnecke is very high and it can be used screws, which - due to the pretreatment and the feeder - treat the polymer gently and bring very little cutting power into the material, to melt this. In addition, the throughput consistency is higher over time or the throughput more even and the feeder works reliably without problems in the filling of the screw. Further advantageous embodiments of the invention are described by the following features: A practically advantageous angle of attack is in the range of 20e to 60 °, in particular 30 ° to 50 °. θ * ·· «·· ··· ·· ···· m According to a preferred development, it is advantageous if the angle of attack γ additionally also satisfies the relationship γ = k1 * De + K1, where Db ... is the inner diameter of the circular cylindrical cutting compressor or container in mm or the inner diameter in mm equals one to the same volume converted fictitious circular cylindrical container of the same height, K1 ... a factor in the range of 12 to 40, k1 ... is a factor in the range of 0.005 to 0.015. In cutting systems, ie containers with knives, there is a tendency that the angle of attack of the outermost tools depends on the cutter compressor diameter. The larger the diameter of the container, the greater the angle of attack to the radial and the greater must be the distance of the tool to the cutting compressor wall. The tool then acts more stuffing than circulating. If the distance to the container wall becomes very small, then the particles between the container wall and the tool are tweaked and the disc can block. In this context, it has proved to be advantageous experimentally, if the angle of attack for containers with diameters of less than 750 mm in the range of 20 ° to 35 °, for containers with diameters of 750 mm to 1300 mm in the range of 28 ° to 47 ° and For containers with diameters greater than 1300 mm, the range is 35 ° to 55 °. Especially in this context, it is particularly advantageous if the radial distance of the tool mb, measured from the radially outermost point of the ground nearest mixing and / or crushing tool, or provided there tools and / or knives, or from the defined by this point circle, until to the inner surface of the side wall of the container satisfying the relationship mb = k3 * Db, where Db ... is the inner diameter of a circular cylindrical container in mm or the inner diameter in mm of a same volume volume fictitious circular cylindrical container of the same height, and k3 ... a constant in the range of 0.006 to 0.16. Advantageously, the radial distance of the tool mb is in the range of 15 mm to 120 mm, preferably in the range of 20 mm to 80 mm. The smaller the angle of attack, the closer the tools can approach the container wall. The greater the angle of attack, the more pulling or retracting the cut of the blades, and the further the tools must be spaced from the container wall to prevent jamming and consequent braking by trapped particles. It was found through experiments that at an angle of attack in the range of 20e to 33 °, the minimum radial distance of the tool mb is advantageously in the range of 15 mm to 20 mm, feei a * Anstellwinkel in the range of 45 ° to 60 °, the minimum radial distance of the tool mb is advantageously greater than or equal to 35 mm. Furthermore, the Applicant has found that can be achieved by a special spacing of the mixing and crushing tools relative to the screw advantageous effects that have a direct impact on the intake behavior of the conveyor or extruder. Thus, according to a further advantageous development, it is provided that the smallest possible distance ms between tool and screw is described by the relationship ms ^ k * d + K, where d ... the mean diameter of the screw in the region of the intake opening in mm K2. a factor in the range of 20 to 100, especially 20 to 80, k2 ... is a factor in the range of 0.03 to 0.4, in particular 0.04 to 0.25. Preferably, the distance ms is in the range of 15 mm to 150 mm. The distance ms is measured from the radially outermost point of the lowermost bottom mixing and / or crushing tool, or provided there projecting tools and / or knives, up to a lying on the envelope of the feed opening closest screw point. The distance ms runs along a radial line, which starts from the axis of rotation of the container and passes through the opening and the intake opening to the screw. The distance ms is the minimum distance the tool tip can take to the worm as the tool tip turns past the worm. In a tangential arrangement of the screw to the container during operation, the outermost tool tip moves past the opening or the feed opening. The distance changes continuously and there is a minimum distance ms. According to a further embodiment it is provided that at least one, preferably a plurality, further, radially further inside tools or knives are provided. The angle of attack of any tool or knife, measured as the Angle of incidence γ, at their respectively radially outermost points, between the extension of their, in particular straight, leading edges and the radials passing through this point, is in each case smaller than the angle of attack of the immediately adjacent further outward tool or knife. The other tools or knives are preferably located on the same horizontal plane or arranged on the same carrier disk. Since the angular velocity of the tools is lower in the more inner region of the container, the tools must be aligned radially, in a range of 0 ° to 30 °, preferably 5 ° to 25 °, to accelerate the material in the circumferential direction accordingly. 10 «· · • · · · · · • • «« · · · · · · · · · · · · · · · · · According to an advantageous development of the invention it is provided that the conveyor is arranged on the receptacle, that the scalar product from the tangential to the circle of the radially outermost point of the mixing and / or crushing tool or to the opening passing plastic material and normal to a radial of the receptacle aligned, pointing in the direction of rotation or movement of the mixing and / or crushing tool direction vector (direction vector of the direction of rotation) and the direction vector of the conveying direction of the conveyor in each individual point or in the entire region of the opening or, in each individual point or in the entire area immediately radially in front of the opening, zero or negative. The area immediately radially in front of the opening is defined as the area in front of the opening at which the material is just before passing through the opening but has not yet passed through the opening. In this way, the advantages mentioned above are achieved and effectively avoided any agglomeration caused by stuffing effects in the region of the intake opening. In particular, it does not depend on the spatial arrangement of the mixing tools and the screw to each other, for example, the axis of rotation must not be aligned normal to the bottom surface or to the longitudinal axis of the conveyor or the screw. The direction vector of the direction of rotation and the direction vector of the conveying direction are in one, preferably horizontal. Plane, or in a normal to the rotation axis aligned plane. A further advantageous embodiment results from the fact that the direction vector of the direction of rotation of the mixing and / or crushing tool with the direction vector of the conveying direction of the conveyor includes an angle greater than or equal to 90 and less than or equal to 180 °, wherein the angle at the intersection of the two Direction vectors is measured at the upstream of the rotational or moving direction edge of the opening, in particular in the furthest upstream point on this edge or the opening. As a result, that angle range is described in which the conveyor must be arranged on the receptacle in order to achieve the advantageous effects. In the entire region of the opening or in each individual point of the opening, an at least slight opposing orientation of the forces acting on the material or in extreme cases to a pressure neutral transverse alignment, at any point of the opening is the scalar product of the directional vectors of the mixing tools and the worm positively, not even in a portion of the opening thus occurs to a large stuffing effect. A further advantageous embodiment of the invention provides that the direction vector of the direction of rotation or movement with the direction vector of the direction of conveyance encloses an angle between 170 ° and 180 °, measured in the range of .mu.m.sup.-1. * ·· + «· 9 * * * i ui 9 · 9 · · · f ··· * · t ··· * ··« Intersection of the two directional vectors in the middle * d * er opening. For example, such an arrangement is true when the conveyor is tangentially positioned on the cutter compactor. To ensure that no excessive stuffing occurs, it may be advantageously provided that the distance or the offset of the longitudinal axis to the radial is greater than or equal to half the inner diameter of the housing of the conveyor or the piebald. Furthermore, it may be advantageous in this sense, the distance or the offset of the longitudinal axis to the radial greater than or equal to 7%, even more advantageously equal to 20%, to dimension the radius of the receptacle. For conveyors with an extended catchment area or a grooved or extended pocket, it may be advantageous if this distance or this offset is greater than or equal to the radius of the receptacle. In particular, this applies to cases in which the conveyor is tangentially connected to the receptacle or tangent to the cross section of the container. It is particularly advantageous if the longitudinal axis of the conveyor or the screw or the longitudinal axis of the intake nearest worm or the inner wall of the housing or the envelope of the pebbles tangent to the inside of the side wall of the container, wherein preferably the worm on its front page a drive is connected and at its opposite front end to a arranged at the front end of the housing outlet opening, in particular an extruder head promotes. At radially offset, but not tangentially arranged, conveyors is advantageously provided that the imaginary extension of the longitudinal axis of the conveyor against the conveying direction, the interior of the receptacle at least partially passes through as a secant. It is advantageous if it is provided that the opening directly and directly and without a longer spacing or transfer distance, e.g. a screw conveyor, is connected to the intake opening. This makes an effective and gentle transfer of material possible. The reversal of the direction of rotation of the circulating in the container mixing and crushing tools can not be done only arbitrarily or accidentally, and you can not rotate the mixing tools in the opposite direction, either in the known devices or in the device according to the invention, especially not, because the mixing and crushing tools are arranged asymmetrically in a certain way so that they act only on a single side or in one direction. If such an apparatus were consciously 12 12 ΜΗ * ··· ♦ · * ·· · If the wrong direction is turned, neither a good oil blast would be formed, nor would the material be sufficiently crushed or heated , Each cutter compressor thus has its fixed predetermined direction of rotation of the mixing and crushing tools, in this context, it is particularly advantageous if it is provided that the front or leading edges of the mixing and / or Crushing tools are designed differently, curved, adjusted or arranged in comparison to the rear or trailing areas in the direction of rotation or movement. The tools and / or knives can either be fastened directly to the shaft or are preferably arranged on a, in particular parallel to the bottom surface, arranged rotatable tool carrier or a carrier disk or formed therein or, optionally in one piece, integrally formed. In principle, the effects mentioned are relevant not only for compressing extruders or agglomerators, but also for non-compressing or less-compressing screw conveyors. Again, local overfeeding is avoided. In a further particularly advantageous embodiment, it is provided that the receptacle is substantially cylindrical with a flat bottom surface and a cylinder jacket-shaped side wall oriented vertically thereto. It is also structurally simple if the axis of rotation coincides with the central center axis of the receptacle. In a further advantageous embodiment it is provided that the axis of rotation or the central center axis of the container are aligned vertically and / or normal to the bottom surface. These special geometries optimize the intake behavior in a structurally stable and simply constructed device. In this context, it is also advantageous to provide that the mixing and / or crushing tool, or if more superimposed mixing and / or crushing tools are provided, the lowest, ground-level mixing and / or crushing tool, and the opening in a small Distance to the bottom surface, in particular in the region of the lowest quarter of the height of the receptacle are arranged. The distance is defined and measured from the lowest edge of the opening or the intake opening to the container bottom in the edge region of the container. Since the corner edge is usually rounded, the distance from the lowest edge of the opening along the imaginary extensions of the side wall down to the imaginary extension of the container bottom is measured outwards. Well suitable distances are 10 to 400 mm. 4 «13 4« 13 * 4 · 4 4 Φ · »• * * * 4 * • * * * * * • Φ 4 ♦ # Φ g φ • · * · · The container need not necessarily have a circular shape, although this shape is advantageous for practical and production reasons Assuming that the height of this notional container is equal to its diameter. Container heights, which in this case substantially exceed the mixing drum (taking into account the safety distance), are not taken into consideration, since this excessive container height is not used and therefore has no influence on the material processing. In the present case, the term conveyor means systems with non-compressing or decompressing screws, that is to say pure conveying screws, as well as systems with compressing screws, ie extruder screws having an agglomerating or plasticizing effect. In the present text, the terms extruder or extruder screw mean both extruders or screws, with which the material is completely or partially melted, as well as extruders, with which the softened material only agglomerates, but is not melted. In Agglomerierschnecken the material is only briefly briefly compressed and sheared, but not plasticized. The Aggiomerierschnecke therefore provides at its output material, which is not completely melted, but consists of only on its surface melted particles, which are zusammengebackt as a sintering. In both cases, however, pressure is applied to the material via the screw and this compacted. In the examples described in the following figures, conveyors with a single screw, for example single-screw or single-screw extruders, are represented throughout. Alternatively, however, the provision of conveyors with more than one screw, for example double or multi-shaft conveyors or extruders, in particular with a plurality of identical screws, which have at least the same diameter d, is also possible. Further features and advantages of the invention will become apparent from the description of the following non-limiting embodiments of the subject invention, which are shown schematically in the drawings and not to scale: Fig. 1 shows a Vertikaischnitt by a device according to the invention with approximately tangentially connected extruder. FIG. 2 shows a horizontal section through the embodiment of FIG. 1. FIG. Fig. 3 shows a further embodiment with minimum offset. Fig. 4 shows a further embodiment with greater displacement. Neither the containers, nor the screws or the mixing tools are to scale in the drawings, either as such, or in relation to each other. Thus, e.g. in reality, the containers are usually larger or the snails longer than shown here. The advantageous cutter-compactor-extruder combination shown in FIGS. 1 and 2 for processing plastic material comprises a circular-cylindrical container or cutter 1 with a flat, horizontal bottom surface 2 and a vertical, cylinder-jacket-shaped Side wall 9 on. At a small distance to the bottom surface 2, at most in about 10 to 20%, possibly less, the height of the side wall 9 - measured from the bottom surface 2 to the top edge of the side wall 9 - is a parallel to the bottom surface 2 aligned, planar support disk or a tool carrier 13, which is rotatable about a central axis of rotation 10, which is also the central center axis of the container 1, in the direction of rotation 12 marked with an arrow 12. The carrier disk 13 is driven by a motor 21 which is located below the container 1. On top of the carrier disk 13 are knives or tools, e.g. Cutting knife, 14 arranged, which together with the carrier plate 13, the mixing and / or crushing tool 3. As indicated schematically, the knives 14 are not arranged symmetrically on the support plate 13, but are particularly formed on their pointing in the direction of rotation or movement 12 front edges 22, employed or arranged to be able to act on the plastic material mechanically specific. The radially outermost edges of the mixing and crushing tools 3 extend to relatively close, about 5% of the radius 11 of the container 1, to the inner surface of the side wall 9 zoom. The container 1 has at the top a filling opening, through which the material to be processed, e.g. Portions of plastic films, e.g. is inserted by means of a conveyor in the direction of the arrow. Alternatively it can be provided that the container 1 is closed and at least evacuated to a technical vacuum, wherein the material is introduced via a lock systems. This material is collected by the circulating mixing and / or crushing tools 3 and in the form of a 15 • • Μ Mischtrombe 30 swirled up, the good along * Her 'vertifcale'n'Seitenwand 9 rises and falls back almost in the range of the effective container height H by gravity back in and down in the area of the center of the container. The effective height H of the container 1 is approximately equal to its inner diameter D. In the container 1 thus forms a Mischtrombe, in which the material is swirled both from top to bottom and in the direction of rotation 12. Such a device can thus be operated only with the predetermined direction of rotation or movement 12 due to the particular arrangement of the mixing and crushing tools 3 and the knife 14 and the direction of rotation 12 can not be made without further or without additional changes, be reversed. The introduced plastic material! is crushed by the rotating mixing and crushing tools 3, mixed and thereby heated by the introduced mechanical friction energy and softened, but not melted. After a certain residence time in the container 1, the homogenized, softened, doughy but not molten material, as will be discussed in detail below, discharged through an opening 8 from the container 1, brought into the catchment area of an extruder 5 and there by a screw 6th recorded and subsequently melted. At the height of the single crushing and mixing tool 3 in the present case, said opening 8 is formed in the side wall 9 of the container 1, through which the pretreated plastic material from the interior of the container 1 can be discharged. The material is transferred to a single-screw extruder 5 arranged tangentially on the container 1, the housing 16 of the extruder 5 having an intake opening 80 in its casing wall for the material to be detected by the screw 6. Such an embodiment has the advantage that the screw 6 can be driven by the lower front end in the drawing by a drive shown only schematically, so that the upper end of the screw 6 in the drawing can be kept free from the drive. This makes it possible to arrange the outlet opening for the conveyed by the screw 6, plasticized or agglomerated plastic material at this right front end, z, B. in the form of an extruder head, not shown. The plastic material can therefore be conveyed through the outlet opening without deflection by the screw 6, which is not readily possible in the embodiments according to FIGS. 3 and 4. The intake opening 80 communicates with the opening 8 in material conveying or transfer connection and is in the present case directly, directly and without a longer intermediate piece or spacing connected to the opening 8. Only a very short transfer area is provided. In the housing 16, a compressing screw 6 is rotatably supported about its longitudinal axis 15. The longitudinal axis 15 of the screw 6 and the extruder 5 coincide. The extruder 5 conveys the material in the direction of arrow 17. The extruder 5 is a conventional extruder known per se, in which the softened plastic material is compressed and thereby melted, and the melt then emerges on the opposite side of the extruder head. The mixing and / or crushing tools 3 and the blades 14 are at almost the same height or plane as the central longitudinal axis 15 of the extruder 5. The outermost ends of the blades 14 are sufficiently beab from the webs of the screw 6 stood. In the embodiment according to FIGS. 1 and 2, the extruder 5, as mentioned, is tangentially connected to the container 1 or extends tangentially to its cross section. The imaginary extension of the central longitudinal axis 15 of the extruder 5 or the screw 6 against the conveying direction 17 of the extruder 5 to the rear, leads in the drawing next to the axis of rotation 10 over without cutting them. The longitudinal axis 15 of the extruder 5 or the screw 6 is on the outlet side to the longitudinal axis 15 parallel, from the axis of rotation 10 of the mixing and / or crushing tool 3 in the conveying direction 17 of the extruder 5 outwardly directed radials 11 of the container 1 by a distance 18 added. In the present case, the rearward extension of the longitudinal axis 15 of the extruder 5 does not penetrate the interior of the container 1, but runs just past it. The distance 18 is slightly larger than the radius of the container 1. The extruder 5 is thus slightly offset from the outside or the catchment area is slightly deeper. Under the terms "contrary", " opposite " or "opposing" is understood herein to mean any orientation of the vectors to each other which is not acute-angled, as will be explained in detail below. In other words, the scalar product is a directional vector 19 of the direction of rotation 12, which is tangent to the circle of the outermost point of the mixing and / or comminution tool 3 or tangential to the plastic material passing past the opening 8 and the direction of rotation 12 the mixing and / or crushing tools 3, and a direction vector 17 of the conveying direction of the extruder 5, which is parallel to the central longitudinal axis 15 in the conveying direction at each point of the opening 8 and in the region radially immediately in front of the opening 8, zero everywhere or negative, but nowhere positive. 17 «··· In the intake opening in FIGS. 1 and 2, the directional vector of the directional vector 19 of the direction of rotation 12 and the directional vector 17 of the conveying direction in each point of the opening 8 are negative. The angle α between the directional vector 17 of the conveying direction and the directional vector of the direction of rotation 19, measured in the furthest upstream to the direction of rotation 12 point 20 of the opening 8 and at the most upstream edge of the opening 8 is, almost maximum, about 170 ° , If you move along the opening 8 in Fig. 2 down, so in the direction of rotation 12, on, so the obtuse angle between the two direction vectors is always larger. In the middle of the opening 8, the angle between the directional vectors is about 180 ° and the scalar product is maximum negative, further below that the angle is even > 180 ° and the scalar product decreases again, but always remains negative. However, these angles are no longer referred to as angles α, since they are not measured in point 20. A not shown in Fig. 2, measured in the middle or in the center of the opening 8 angle ß between the direction vector of the direction of rotation 19 and the direction vector of the conveying direction 17 is about 178 ° to 180 °. The device according to FIG. 2 represents the first limiting case or extreme value. In such an arrangement, a very gentle stuffing action or a particularly advantageous feeding is possible and such a device is particularly suitable for sensitive materials which are processed near the melting region or for long-strip Good. The angle of attack γ is shown in FIG. 2 and is measured in the radially outermost point 23 of the bottom-nearest mixing and / or comminution tool 3 or of the tool or knife 14. The angle of attack γ is between the extension 24 of the, in Fig. 2 straight, formed as a cutting edge leading edge 22 of the outermost blade and extending through the point 23 Radial 11 of the container 1. In Fig. 2, the angle of attack γ is about 25 °. There are two further radially inner knife 14 is provided in the apparatus of FIG. 2, which are arranged side by side on the same carrier disk 13. The angle of attack of these knives 14 is measured analogously to the angle of attack γ, in each case at their radially outermost points, between the extension of their straight front edges 22 and the radial 11 extending through this point. The angle of attack of the front edge 22 of the central blade 14 is approximately 23 °, the angle of attack of the radially innermost blade 14 is about 22 °. However, Fig. 2 is not to scale. The lower angles of attack take into account the lower angular velocity. The L / D ratio, ie the ratio of the length L of the screw 6, measured from the downstream in the conveying direction of the screw 6 edge 20 'or the most downstream point 20 of the intake port 80, to the end of the screw 6 or to the earliest furthest upstream with respect to the conveying direction of the screw 6 outlet opening 30 in the housing 16 for the melt at the distal distal end 31 of the screw 6, the nominal diameter d of the screw (6) is in Fig. 2 over 15. The radial distance of the tool mb, measured from the radially outermost point 23 or from the outermost tip of the blade 14 or the circle defined thereby, to the inner surface of the side wall 9 of the container 1 is shown by way of example in FIG. This satisfies the relationship mb = k * DB. The tools or knives 14 protrude beyond the carrier disk 13. The smallest possible distance ms between the tool and the screw, measured from the radially outermost point 23 or from the outermost tip of the blade 14 or the circle defined thereby, to the envelope of the screw 6, is likewise shown by way of example in FIG. The distance ms is substantially centered to the length of the inlet opening 80 and on the radial 11, which is aligned at an angle of 90 ° to the longitudinal axis 15 of the extruder 5. If the tool 3 moves further down or up, the distance becomes larger again. At the edges of the intake opening 80, the distance is maximum when the intake opening 80 with its length, as shown in FIG. 2, is symmetrical to the 90 ° radial 11. In FIGS. 3 and 4, the distances mb, ms and the angle of attack γ have not been drawn. FIGS. 3 and 4 serve primarily to illustrate the connection possibilities of the extruder. In Fig. 3, an alternative embodiment is shown, in which the extruder 5 is not connected tangentially, but with its end face 7 to the container 1. The screw 6 and the housing 16 of the extruder 5 are adapted in the region of the opening 8 to the contour of the inner wall of the container 1 and set back flush. No part of the extruder 5 protrudes through the opening 8 into the interior of the container 1. The distance 18 here corresponds to about 5 to 10% of the radius 11 of the container 1 and about half the inner diameter d of the housing 16. This Ausführungsfrom thus represents the second limiting case or extreme value with the smallest possible offset or distance 18, in which the rotary or Bewegungsrichtuiig * W of MiscFi- and / or Zerkieinerungswerkzeuge 3 of the conveying direction 17 of the extruder 5 is at least slightly opposite, and indeed over the entire surface of the opening eighth The scalar product is exactly zero in FIG. 3 at the most upstreammost point 20 located at the most upstream edge of the orifice 8. The angle α between the direction vector 17 of the conveying direction and the direction vector of the direction of rotation 19, measured at point 20 of Fig. 3, exactly 90 °. If you continue along the opening 8 down, ie in the direction of rotation 12, on, so the angle between the direction vectors is always larger and at an obtuse angle > 90 ° and the scalar product becomes negative at the same time. However, at no point or in any area of the opening 8 is the scale product positive or the angle less than 90 °. As a result, local overfeeding can not take place even in a partial region of the opening 8 or, in any region of the opening 8, there can be no harmful inflated tamping action. This also makes a decisive difference to a purely radial arrangement, since at point 20 or at the edge 20 'with a fully radial arrangement of the extruder 5 an angle α < 90 ° and those areas of the opening 8, which are located in the drawing above the radial 11 and upstream or upstream thereof, would have a positive scalar product. This could lead to accumulation of locally melted plastic goods in these areas. FIG. 4 shows a further alternative embodiment in which the extruder 5 is displaced slightly more downstream than in FIG. 3, but not yet tangentially as in FIGS. 1 and 2. In the present case, as in FIG. 3, the extension of the longitudinal axis 15 of the extruder 5, which is intended to be rearward, penetrates the interior of the container 1 in a secant manner. As a result, the opening 8 is wider than in the embodiment according to FIG. The angle α measured at point 20 is about 150 °, whereby compared to the device of Fig. 3, the stuffing effect is reduced, which is more advantageous for certain sensitive polymers. The viewed from the container 1 from right inner edge or the inner wall of the housing 16 connects tangentially to the container 1, whereby, in contrast to Fig. 3 no blunt transitional edge is formed. In this furthest downstream point of the opening 8, in Fig. 4 leftmost, the angle is about 180 °.
权利要求:
Claims (22) [1] 1. A device for pretreating and subsequently conveying, plasticizing or agglomerating plastics, in particular thermoplastic waste plastics for recycling purposes, with a container (1) for the material to be processed, wherein in the container (1) at least one revolving mixing and / or comminution tool (3) rotatable about an axis of rotation (10) for mixing, heating and optionally comminuting the plastic material, wherein the mixing and / or comminuting tool (3) comprises tools and / or knives (14) comprising, with their leading edges (22) in the rotational or movement direction (12) on the plastic material, mixing, crushing, cutting and / or heating, wherein in a side wall (9) of the container (1) in the region of the height of or the bottom, bottom mixing and / or crushing tool (3) an opening (8) is formed through which the pretreated plastic material from the interior of the container (1) can be carried out, wherein at least one conveyor (5), in particular an extruder (5), is provided for receiving the pretreated material, with at least one in a housing (16) rotating, in particular plasticizing or agglomerating , Screw (6), wherein the housing (16) has an on its end face (7) or in its jacket wall inlet opening (80) for the material to be detected by the screw (6), and the feed opening (80) with the opening (8) is connected, characterized in that the imaginary extension of the central longitudinal axis (15) of the conveyor (5) or the feed opening (80) nearest the screw (6) against the conveying direction (17) of the conveyor (5) on the Rotary axis (10) passes without cutting them, wherein the longitudinal axis (15) of the conveyor (5) or of the intake opening (80) nearest the screw (6) on the upstream side or downstream in rotation or movement direction of movement (12) of the mixing and / or crushing tool (3) to the longitudinal axis (15) parallel, from the axis of rotation (10) of the mixing and / or crushing tool (3) in the conveying direction (17) of the conveyor (5) outwardly directed radials (11) of the container (1) is offset by a distance (18), and that the angle of attack (y) of the radially outermost mixing and / or comminuting tool (3) or of the radially outermost tool and / or knife (14) satisfies the following relation: γ = k * d + K 21 ♦ ·· « where d ... the diameter of the screw (6) in mm K ... a factor in the range of 15 to 35, k ... a factor in the range of 0.08 to 0.2, wherein the angle of attack (γ ) in the radially outermost point (23) of the ground nearest mixing and / or crushing tool (3) or the tool and / or knife (14) between the extension (24) of the, in particular straight, leading edge (22) and the by the point (23) extending radials (11), and that the ratio of the length (L) of the screw (6), measured from the downstream in the conveying direction of the screw (6) edge (20 ') or the most downstream Point (20) of the intake opening (80), to the end of the screw (6) or to the earliest, most upstream with respect to the conveying direction of the screw (6) located outlet opening (30) in the housing (16) for the Schmelze when removing containers , distal end (31) of the screw (6), to the nominal diameter (d) of the screw (6) 7, preferably > 10, is. [2] 2. Apparatus according to claim 1, characterized in that the angle of attack γ in the range of 20 ° to 60 °, in particular 30 ° to 50 °. [3] 3. Device according to one of claims 1 to 2, characterized in that the angle of attack (γ) satisfies the following relationship: γ - k1 * DB + K1 where DB ... the inner diameter of the circular cylindrical cutting compressor or container (1) in mm or the inner diameter in mm of a fictitious circular cylindrical container (1) of the same height, K1 ... converted into the same volume of volume is a factor in the range of 12 to 40, k1 ... a factor in the range of 0.005 to 0.015. [4] 4. Device according to one of claims 1 to 3, characterized in that the angle of attack (γ) in containers (1) with diameters (D) of less than 750 mm in the range of 20 ° to 35 °. [5] 5. Device according to one of claims 1 to 4, characterized in that the angle of attack (γ) in containers (1) with diameters (Db) of 750 mm to 1300 mm in the range of 28 ° to 47 °. [6] 6. Device according to one of claims 1 to 5, characterized in that the angle of attack (γ) in containers (1) with diameters (Db) of greater than 1300 mm in the range of 35 * to 55 °. [7] 7. Device according to one of claims 1 to 6, characterized in that the radial distance of the tool (mb), measured from the radially outermost point (23) of the ground-nearest mixing and / or crushing tool (3), or there provided tools and / or knives (14), or from the circle defined by this point (23), to the inner surface of the side wall (9) of the container (1) satisfies the following relationship: mb = k3 * Db where Db ... the inner diameter of a circular cylindrical Container (1) in mm or the inner diameter in mm of a same volume volume converted fictitious circular cylindrical container of the same height, and k3 ... a constant in the range of 0.006 to 0.16, wherein the radial distance of the tool (mb) is preferably in the range of 15 mm to 120 mm, in particular in the range of 20 mm to 80 mm. [8] 8. The device according to claim 7, characterized in that at an angle of attack (y) in the range of 20 * to 33 °, the minimum radial distance of the tool (mb) is in the range of 15 mm to 20 mm and / or that at an angle of attack (y) in the range of 45 ° to 60 °, the minimum radial distance of the tool (mb) is greater than or equal to 35 mm. 23 ··· »• · · + · • · ♦ · · * · * * * · · · · · · * * · · · ·» · · · · · · · ························································· · · «« «« [9] 9. Device according to one of claims 1 to 8, characterized in that the smallest possible distance (ms) between the tool (3) and screw (6) is described by the following relationship: ms < k2 * d + K2 where d ... the diameter of the screw (6) in mm K2 ... the factor in the range of 20 to 100, in particular 20 to 80, k2 ... the factor in the range of 0.03 to 0.4, in particular 0.04 to 0.25, wherein the distance (ms) is measured between the radially outermost point (23) of the lowest ground mixing and / or crushing tool (3), or there provided tools and / or knives (14), and a lying on the envelope of the feed opening (80) nearest screw (6) point, along a radial (11) extending from the axis of rotation (10) and through the opening (8) and the feed opening (80) passes, wherein the distance (ms) is preferably in the range of 15 mm to 150 mm. [10] 10. Device according to one of claims 1 to 9, characterized in that, preferably located on the same horizontal plane, at least one, preferably a plurality, further, radially further inside tools or knives (14) are provided, wherein the angle of each tool or Knife (14), measured at their respective radially outermost points, between the extension (24) of their, in particular straight, leading edges (22) and extending through this point radials (11), respectively, is smaller than the angle of attack of the adjacent farther out located tool or knife (14), wherein the angle of attack of the radially innermost tool or knife (14) is preferably in the range of 0 ° to 30e. [11] 11. Device according to one of claims 1 to 10, characterized in that for an associated with the container (1) conveyor (5) the scalar product formed from the tangential to the circle of the radially outermost point of the mixing and / or crushing tool ( 3) or tangentially to the plastic material moved past the opening (8) and oriented normal to a radial (11) of the container (1), pointing in the direction of rotation or movement (12) of the mixing and / or comminution tool (3) Direction vector of the direction of rotation (19) and the direction vector (17) of the conveying direction of the conveyor (5) in each individual point or 24 ♦ ········ »t * · · · · · ·« «♦ · · · * In the entire area of the opening (8) or immediately radially in front of the opening * (8), it is zero or negative. [12] 12. Device according to one of claims 1 to 11, characterized in that the direction vector of the direction of rotation (19) of the radially outermost point of the mixing and / or crushing tool (3) and the direction vector (17) of the conveying direction of the conveyor (5) Include angle (a) greater than or equal to 90 ° and less than or equal to 180 °, measured at the intersection of the two directional vectors (17,19) with respect to the direction of rotation or movement (12) of the mixing and / or crushing tool (3) upstream upstream edge (20 ') of the opening (8), in particular in the most upstream point (20) on this edge or the opening (8). [13] 13. Device according to one of claims 1 to 12, characterized in that the direction vector (19) of the rotational or movement direction (12) and the direction vector (17) of the conveying direction of the conveyor (5) an angle (ß) between 170 ° and 180 °, measured at the intersection of the two directional vectors (17,19) in the center of the opening (8). [14] 14. Device according to one of claims 1 to 13, characterized in that the distance (18) is greater than or equal to half the inner diameter of the housing (16) of the conveyor (5) or the screw (6), and / or greater than or equal to 7%, preferably greater than or equal to 20%, of the radius of the container (1) or that the distance (18) is greater than or equal to the radius of the container (1). [15] 15. Device according to one of claims 1 to 14, characterized in that the imaginary extension of the longitudinal axis (15) of the conveyor (5) opposite to the conveying direction in the manner of a secant to the cross section of the container (1) is arranged and the interior of the container ( 1) interspersed at least in sections. [16] 16. Device according to one of claims 1 to 15, characterized in that the conveyor (5) is connected tangentially to the container (1) or tangential to the cross section of the container (1) or that the longitudinal axis (15) of the conveyor (5) or the screw (6) or the longitudinal axis of the screw (6) closest to the intake opening (80) or the inner wall of the housing (16) or the envelope of the check (6) tangentially to the inside of the side wall (9) of the Container (1) extends, wherein preferably the screw (6) on its end face (7) is connected to a drive and at its opposite end to a front end of the housing (16) arranged outlet opening, in particular an extruder head promotes. [17] 17. Device according to one of claims 1 to 16, characterized in that the opening (8) directly and directly and without significant spacing, in particular without transfer path or screw conveyor, with the intake opening (80) is connected. [18] 18. Device according to one of claims 1 to 17, characterized in that the mixing and / or crushing tool (3) tools and / or knives (14), in the rotational or movement direction (12) comminuting the plastic material, acting cutting and heating, the tools and / or knives (14) preferably on or on a, in particular parallel to the bottom surface (12), arranged, rotatable tool carrier (13), in particular a carrier disc (13), are formed or arranged. [19] 19. Device according to one of claims 1 to 18, characterized in that the plastic material acting in the direction of rotation or movement (12) facing front areas or leading edges (22) of the mixing and / or crushing tools (3) or Knife (14) are formed differently, employed, curved and / or arranged in comparison to the in the direction of rotation or movement (12) rear or trailing areas. [20] 20. Device according to one of claims 1 to 19, characterized in that the container (1) is formed substantially circular cylindrical with a flat bottom surface (2) and a vertically oriented cylinder jacket-shaped side wall (9) and / or the axis of rotation (10). the mixing and / or comminution tools (3) coincide with the central center axis of the container (1) and / or the axis of rotation (12) or the central center axis are aligned vertically and / or normal to the bottom surface (2). [21] 21. Device according to one of claims 1 to 20, characterized in that the lowest tool carrier (13) or the lowest of the mixing and / or crushing tools (3) and / or the opening (8) close to the ground at a small distance to the bottom surface ( 2), in particular in the region of the lowest quarter of the height of the container (1), preferably at a distance from the bottom surface (2) of 10 mm to 400 mm are arranged. 26 26 • »* * IM« ♦ »· [22] 22. Device according to one of claims 1 to 21, characterized in that the conveyor (5) is a single screw extruder (6) with a single compressing screw (6) or is a double or multiple screw extruder, wherein the diameters d of the individual screws ( 6) are equal to each other.
类似技术:
公开号 | 公开日 | 专利标题 EP2766165B1|2016-02-10|Apparatus for processing plastic material EP2768645B1|2015-12-16|Apparatus for processing plastic material EP2766159B1|2015-12-16|Apparatus for processing plastic material EP2766161B1|2015-12-16|Apparatus for processing plastic material EP2766157B1|2015-12-16|Apparatus for processing plastic material EP2766160B1|2015-12-16|Apparatus for processing plastic material EP2766162B1|2015-12-16|Apparatus for processing plastic material EP2766158B1|2015-12-16|Apparatus for processing plastic material EP2766164B1|2015-12-16|Apparatus for processing plastic material EP2766166B1|2015-12-16|Apparatus for processing plastic material DE202012012574U1|2013-06-10|Device for processing plastic material
同族专利:
公开号 | 公开日 ES2568105T3|2016-04-27| RU2578292C2|2016-03-27| WO2013052987A1|2013-04-18| US20140234461A1|2014-08-21| PL2766165T3|2016-08-31| CN103874568B|2017-03-29| CA2851704C|2018-04-17| KR101706912B1|2017-02-15| BR112014008820A2|2017-04-25| RU2014119282A|2015-11-20| HUE027764T2|2016-11-28| CA2851704A1|2013-04-18| MX2014004446A|2014-09-22| KR20140078745A|2014-06-25| MX346093B|2017-03-07| AT512148B1|2015-02-15| CN103874568A|2014-06-18| JP5961696B2|2016-08-02| AU2012323816B2|2015-08-13| EP2766165A1|2014-08-20| SI2766165T1|2016-06-30| DK2766165T3|2016-03-14| DE202012012571U1|2013-06-10| TWI517957B|2016-01-21| HK1200761A1|2015-08-14| AU2012323816A1|2014-05-15| US9254603B2|2016-02-09| ZA201402095B|2015-03-25| EP2766165B1|2016-02-10| JP2014534096A|2014-12-18| TW201336654A|2013-09-16| UA109835C2|2015-10-12| BR112014008820B1|2020-09-29|
引用文献:
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AT512149B1|2011-10-14|2015-02-15|Erema|DEVICE FOR PREPARING PLASTIC MATERIAL| AT512207B1|2011-10-14|2015-02-15|Erema|DEVICE FOR PREPARING PLASTIC MATERIAL| AT512209B1|2011-10-14|2015-02-15|Erema|DEVICE FOR PREPARING PLASTIC MATERIAL| AT512146B1|2011-10-14|2015-02-15|Erema|DEVICE FOR PREPARING PLASTIC MATERIAL| AT512222B1|2011-10-14|2015-02-15|Erema|DEVICE FOR PREPARING PLASTIC MATERIAL| AT512223B1|2011-10-14|2015-02-15|Erema|DEVICE FOR PREPARING PLASTIC MATERIAL| AT512208B1|2011-10-14|2015-02-15|Erema|DEVICE FOR PREPARING PLASTIC MATERIAL| AT512205B1|2011-10-14|2015-02-15|Erema|DEVICE FOR PREPARING PLASTIC MATERIAL| AT512145B1|2011-10-14|2015-02-15|Erema|DEVICE FOR PREPARING PLASTIC MATERIAL| AT512212B1|2011-10-14|2015-02-15|Erema|DEVICE FOR PREPARING PLASTIC MATERIAL| AT512147B1|2011-10-14|2015-02-15|Erema|DEVICE FOR PREPARING PLASTIC MATERIAL|AT504709B1|2006-11-23|2008-09-15|Erema|METHOD AND DEVICE FOR INTRODUCING ADDITIVES| AT511362B1|2010-04-14|2014-01-15|Erema|DEVICE FOR PREPARING PLASTIC MATERIAL| AT512207B1|2011-10-14|2015-02-15|Erema|DEVICE FOR PREPARING PLASTIC MATERIAL| AT512212B1|2011-10-14|2015-02-15|Erema|DEVICE FOR PREPARING PLASTIC MATERIAL| AT512146B1|2011-10-14|2015-02-15|Erema|DEVICE FOR PREPARING PLASTIC MATERIAL| AT512147B1|2011-10-14|2015-02-15|Erema|DEVICE FOR PREPARING PLASTIC MATERIAL| AT512145B1|2011-10-14|2015-02-15|Erema|DEVICE FOR PREPARING PLASTIC MATERIAL| AT512205B1|2011-10-14|2015-02-15|Erema|DEVICE FOR PREPARING PLASTIC MATERIAL| AT512149B1|2011-10-14|2015-02-15|Erema|DEVICE FOR PREPARING PLASTIC MATERIAL| AT512223B1|2011-10-14|2015-02-15|Erema|DEVICE FOR PREPARING PLASTIC MATERIAL| AT512208B1|2011-10-14|2015-02-15|Erema|DEVICE FOR PREPARING PLASTIC MATERIAL| AT512209B1|2011-10-14|2015-02-15|Erema|DEVICE FOR PREPARING PLASTIC MATERIAL| CN104875300B|2015-06-08|2017-06-20|苏州市湘园特种精细化工有限公司|A kind of horizontal pulverizer for waste old|
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申请号 | 申请日 | 专利标题 ATA1503/2011A|AT512148B1|2011-10-14|2011-10-14|DEVICE FOR PREPARING PLASTIC MATERIAL|ATA1503/2011A| AT512148B1|2011-10-14|2011-10-14|DEVICE FOR PREPARING PLASTIC MATERIAL| KR1020147013024A| KR101706912B1|2011-10-14|2012-10-12|Apparatus for processing plastic material| CN201280050392.1A| CN103874568B|2011-10-14|2012-10-12|For to synthetic material pretreatment and subsequently conveying, plasticizing or the device for coalescing| TW101137649A| TWI517957B|2011-10-14|2012-10-12|Apparatus for the treatment of plastics material| HUE12781263A| HUE027764T2|2011-10-14|2012-10-12|Apparatus for processing plastic material| MX2014004446A| MX346093B|2011-10-14|2012-10-12|Apparatus for processing plastic material.| DE201220012571| DE202012012571U1|2011-10-14|2012-10-12|Device for processing plastic material| US14/351,677| US9254603B2|2011-10-14|2012-10-12|Apparatus for processing plastic material| SI201230548A| SI2766165T1|2011-10-14|2012-10-12|Apparatus for processing plastic material| DK12781263.4T| DK2766165T3|2011-10-14|2012-10-12|An apparatus for processing plastics material| CA2851704A| CA2851704C|2011-10-14|2012-10-12|An apparatus for the pretreatment and subsequent conveying, plastification or agglomeration of thermoplastics| ES12781263.4T| ES2568105T3|2011-10-14|2012-10-12|Device for pretreating synthetic materials| AU2012323816A| AU2012323816B2|2011-10-14|2012-10-12|Apparatus for processing plastic material| JP2014534879A| JP5961696B2|2011-10-14|2012-10-12|Plastic material processing equipment| PL12781263T| PL2766165T3|2011-10-14|2012-10-12|Apparatus for processing plastic material| RU2014119282/05A| RU2578292C2|2011-10-14|2012-10-12|Device for processing polymer material| UAA201404508A| UA109835C2|2011-10-14|2012-10-12|DEVICES FOR PROCESSING OF PLASTIC MATERIALS| PCT/AT2012/050159| WO2013052987A1|2011-10-14|2012-10-12|Apparatus for processing plastic material| BR112014008820-9A| BR112014008820B1|2011-10-14|2012-10-12|DEVICE FOR PRE-TREATMENT AND SUBSEQUENT TRANSPORT, PLASTIFICATION OR AGGLOMERATION OF PLASTICS| EP12781263.4A| EP2766165B1|2011-10-14|2012-10-12|Apparatus for processing plastic material| ZA2014/02095A| ZA201402095B|2011-10-14|2014-03-20|Apparatus for processing plastic material| HK15101125.9A| HK1200761A1|2011-10-14|2015-02-03|Apparatus for processing plastic material| 相关专利
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